US2249263A - Apparatus for treating oils - Google Patents
Apparatus for treating oils Download PDFInfo
- Publication number
- US2249263A US2249263A US164659A US16465937A US2249263A US 2249263 A US2249263 A US 2249263A US 164659 A US164659 A US 164659A US 16465937 A US16465937 A US 16465937A US 2249263 A US2249263 A US 2249263A
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- chamber
- oil
- alkali
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- oils
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/02—Refining fats or fatty oils by chemical reaction
- C11B3/06—Refining fats or fatty oils by chemical reaction with bases
Definitions
- This invention is directed to an improved process and apparatus for treating oils, particularly animal and/or vegetable oils containing free fatty acids.
- the present invention involves an improved process for the refining of these oils in which the crude oil, warmed if necessary to give it proper fluidity, and alkali solution, in proper proportion, are passed continuously to a zone in which they are intimately admixed, preferably by positive and relatively violent mechanical agitation, from which zone the intimate mixture flows continuously to a second zone in which it is heated to the desired temperature while being gently agitated, and is then continuously discharged to a centrifugal separator in which refined oil is separated from the soaps formed.
- the present invention likewise involves, from the apparatus standpoint, the means for carrying out the process described and, in particular, a novel type of two-speed agitator in which the continuously flowing mixture of oil and acid is subjected to the two types of agitation described above.
- the I oil and alkali are first continuously intimately admixed by rather violent agitation at, preferably, a relatively low temperature, so that there may be rapid and complete reaction between the alkali and free fatty acids, but as little saponification of the neutral oil as possible.
- the mixture is then continuously heated to a temperature, ranging from about 80 F. to about 140 F., which will cause a more or less complete deemulsification of the oil and alkali solution and facilitate the subsequent separation, butthe mixture being heated is nevertheless subjected to positive, though gentle, agitation, which serves-to insure completion of the reaction and to prevent premature sedimentation or separation.
- Figure 1 of the accompanying drawing illustrates in diagrammatic form apparatus for carrying out this improved process
- Figure 2 is a vertical section through the two-speed agitator used in preference in carrying out the process.
- crude oil from tank I (warmed, if desired, to give it proper fluidity by means of the steam coil 3) flows through valve 5 into the conduit 5 and so into the lower chamber 9 of the mixer.
- a solution of caustic soda, or other alkali or saponifying agent flows through valve l3 into conduit 7, where it mingles with the oil.
- any suitable proportioning device adapted to insure a uniform ratio of oil feed to alkali feed may be used, but this is well known and forms no part of the invention, and I have merely shown the two valves 5 and [3 which may be hand regulated to govern the proportioning.
- the oil and alkali are subjected to intense agitation by means which will be described in detail below, and from this chamber the intimate mixture formed passes to the upper chamber IS in which it is heated to a temperature of, for example F.-140 F., and is subjected to gentle agitation, as will be described in more detail hereinafter.
- the mixture of oil, soap and alkali passes through conduit l! to a centrifugal separator E9 in which the refined oil is separated from the soap and any residual alkali.
- the refined oil, if not sufficiently soap and alkali free, may be given a water wash and aseccnd centrifugal separation by the addition of conventional pieces of equipment.
- the crude oil may be heated in tank I to the desired temperature of 80' F.- F. and the mixture of oil and alkali cooled, rather than heated, in the upper chamber l5.
- a cooling unit in conduit H between chamber l5 and separator IS, in which the mixture is cooled to a temperature which will minimize the solubility of soaps in the Oil.
- Fig. 2 illustrates in detail the construction and operation of the mixer shown diagrammatically in Fig, 1.
- the mixer comprises a lower chamber 9 and an upper chamber Hi.
- upper chamber l5 has a cylindrical inner wall 2
- a hollow vertical shaft 33 passes through a stufling box 35 centrally positioned in the cover 29 and is provided at its outer end with a driving pulley 31.
- Secured to the shaft 33 within the chamber l5 are a plurality of paddles 39, which, in cooperation with vertical wing barangs ll secured to the inner side of the wall 3
- the lower end of shaft 33 is guided and supported by the bearing members 43 and 45 secured to circular plate 41 which also serves to substantially close the bottom of chamber [5.
- Plate 41 rests upon and is secured to a pair of U-shaped frame members 49 which extend downwardly into the lower chamber 9, the outer wall 5
- Chamber 9 is provided with a fluid inlet 55 and a valved outlet 51 used for draining sediment from the mixer.
- a shaft 63 passes through the interior of the hollow shaft 33 and enters chamber 9, being guided at its upper end by stuiling box 65 secured in pulley 31, intermediately by bearing member 45 and at its lower end by hearing block 61 secured to the frame members 49.
- a driving pulley 69 is secured to the upper end 01 shaft 93 and a plurality of paddles H to its lower end within chamber 9, the paddles operating between the bailles 59 and co-acting with them to violently agitate the contents of chamber 9.
- a mixer comprising a first chamber, a plurality of vertically spaced horizontal plate baflles provided with central openings positioned therein, an agitator provided with rotatable paddles extending between said plate baflles positioned in said chamber, a second chamber in communication with said first chamber, means positioned in said second chamber for agitating the contents thereof, and means for varying the temperature of the contents of said second chamber.
- a mixer comprising a first chamber, means positioned in said chamber for agitating the contents thereof, a second chamber in communication with said first chamber, a plurality of vertically disposed wing bailles secured to the inner wall of said second chamr ber, rotatable paddles positioned in said second chamber, and means for varying the temperature of the contents of said second chamber.
- a mixer comprising a first chamber, a plurality of vertically spaced horizontal plate bafiies provided with central openings positioned therein, an agitator provided with rotatable paddles extending between said plate baflies positioned in said chamber, a second chamber in communication with said first chamber, a plurality of vertically disposed wing baflles secured to the inner wall of said second chamber, rotatable paddles positioned in said second chamber, and means for varying the temperature of the contents of said second chamber.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
Description
y 15, 1941- a. F. WHEELWRIGHT, JR 2,249,263
APPARATUS FOR TREATING OILS Filed Sept. 20, 1957 Patented July 15, 1941 I APPARATUS FOR TREATING OILS George Frederick Wh'eelwright, 31a, Westfield,
N. 3., assignor to The De Laval Separator Company, New York, N. Y., a corporation of New Jersey Application September 20, 1937, Serial No. 164,659
3 Claims. (01. 259-6) This invention is directed to an improved process and apparatus for treating oils, particularly animal and/or vegetable oils containing free fatty acids.
Vegetable, and occasionally animal, oils containing free fatty acids are customarily refined by intimately mixing the crude oil with a saponifying agent, usually an alkali, as, for example, caustic soda, and then separating the oil from the soaps by settling or centrifugation. The oil is ordinarily heated to temperatures which vary with the duration of the treatment and the character of the oil, and such heating has been carried out at various stages in the course of treatment. Ordinarily this refining process has been practiced largely in batch, but it has been proposed to utilize continuous refining processes.
The present invention involves an improved process for the refining of these oils in which the crude oil, warmed if necessary to give it proper fluidity, and alkali solution, in proper proportion, are passed continuously to a zone in which they are intimately admixed, preferably by positive and relatively violent mechanical agitation, from which zone the intimate mixture flows continuously to a second zone in which it is heated to the desired temperature while being gently agitated, and is then continuously discharged to a centrifugal separator in which refined oil is separated from the soaps formed.
The present invention likewise involves, from the apparatus standpoint, the means for carrying out the process described and, in particular, a novel type of two-speed agitator in which the continuously flowing mixture of oil and acid is subjected to the two types of agitation described above.
In accordance with the present invention the I oil and alkali are first continuously intimately admixed by rather violent agitation at, preferably, a relatively low temperature, so that there may be rapid and complete reaction between the alkali and free fatty acids, but as little saponification of the neutral oil as possible. The mixture is then continuously heated to a temperature, ranging from about 80 F. to about 140 F., which will cause a more or less complete deemulsification of the oil and alkali solution and facilitate the subsequent separation, butthe mixture being heated is nevertheless subjected to positive, though gentle, agitation, which serves-to insure completion of the reaction and to prevent premature sedimentation or separation. Thus a continuous, andso economically advantageous, procinlet 25 and escaping through outlet 21. The,
ess for refining these oils is made to give substantially optimum results.
-Figure 1 of the accompanying drawing illustrates in diagrammatic form apparatus for carrying out this improved process; and Figure 2 is a vertical section through the two-speed agitator used in preference in carrying out the process.
Referring to Fig. 1, crude oil from tank I (warmed, if desired, to give it proper fluidity by means of the steam coil 3) flows through valve 5 into the conduit 5 and so into the lower chamber 9 of the mixer. From tank II a solution of caustic soda, or other alkali or saponifying agent, flows through valve l3 into conduit 7, where it mingles with the oil.
Any suitable proportioning device adapted to insure a uniform ratio of oil feed to alkali feed may be used, but this is well known and forms no part of the invention, and I have merely shown the two valves 5 and [3 which may be hand regulated to govern the proportioning.
In the lower chamber 9 of the mixer the oil and alkali are subjected to intense agitation by means which will be described in detail below, and from this chamber the intimate mixture formed passes to the upper chamber IS in which it is heated to a temperature of, for example F.-140 F., and is subjected to gentle agitation, as will be described in more detail hereinafter. From the chamber the mixture of oil, soap and alkali passes through conduit l! to a centrifugal separator E9 in which the refined oil is separated from the soap and any residual alkali. The refined oil, if not suficiently soap and alkali free, may be given a water wash and aseccnd centrifugal separation by the addition of conventional pieces of equipment.
If desired, although I consider it less preferable, the crude oil may be heated in tank I to the desired temperature of 80' F.- F. and the mixture of oil and alkali cooled, rather than heated, in the upper chamber l5. Or it may prove desirable to introduce a cooling unit in conduit H between chamber l5 and separator IS, in which the mixture is cooled to a temperature which will minimize the solubility of soaps in the Oil.
Fig. 2 illustrates in detail the construction and operation of the mixer shown diagrammatically in Fig, 1. As indicated, the mixer comprises a lower chamber 9 and an upper chamber Hi. The
upper chamber l5 has a cylindrical inner wall 2| and outer wall 23, between which heating or cooling fiuid is circulated, entering through the chamber I5 is closed at the top by a cover 29 welded or otherwise secured to the wall 2| and provided with an outlet3l through which liquid may leave the chamber [5. A hollow vertical shaft 33 passes through a stufling box 35 centrally positioned in the cover 29 and is provided at its outer end with a driving pulley 31. Secured to the shaft 33 within the chamber l5 are a plurality of paddles 39, which, in cooperation with vertical wing baiiles ll secured to the inner side of the wall 3|, serve on rotation of shaft 33 to impart a gentle agitation to the contents of chamber I5 and deflect the flowing liquid toward the center of the chamber. The lower end of shaft 33 is guided and supported by the bearing members 43 and 45 secured to circular plate 41 which also serves to substantially close the bottom of chamber [5.
Positioned within chamber 9 and secured in place in the frame members 49 are a plurality of annular plate baflles 59 provided with central openings St. A shaft 63 passes through the interior of the hollow shaft 33 and enters chamber 9, being guided at its upper end by stuiling box 65 secured in pulley 31, intermediately by bearing member 45 and at its lower end by hearing block 61 secured to the frame members 49. A driving pulley 69 is secured to the upper end 01 shaft 93 and a plurality of paddles H to its lower end within chamber 9, the paddles operating between the bailles 59 and co-acting with them to violently agitate the contents of chamber 9.
In operation the oil and alkali solution flow through inlet. 55 into the lower chamber 9 and are there violently agitated and intimately admixed by the paddles II which are driven at a high rate of speed through shaft 63 and pulley 69. The mixture flows upwardly through the openings 6| in the baffles 59 and is each time beaten thoroughly by the paddles H. The mixture then escapes from chamber 9 through clearance 13 into chamber i5, where it is gently agitated and through shaft 33 and pulley 31. As the mixture passes slowly through chamber l5 it is heated by means of steam or other heating fluid circulated in the space between walls 2| and 23. The mixture heated to the temperature which will best promote separation in the centrifugal separator then passes out of the mixer through outlet 3|.
It will be understood that the details hereinbefore set forth are merely illustrative of my invention and may be readily modified, and that accordingly they are in no way in limitation of the invention as herein broadly described and claimed.
What I claim and desire to protect by Letters Patent is:
1. In apparatus for the continuous refining of vegetable and animal oils, a mixer comprising a first chamber, a plurality of vertically spaced horizontal plate baflles provided with central openings positioned therein, an agitator provided with rotatable paddles extending between said plate baflles positioned in said chamber, a second chamber in communication with said first chamber, means positioned in said second chamber for agitating the contents thereof, and means for varying the temperature of the contents of said second chamber.
2. In apparatus for the continuous refining of vegetable and animal oils, a mixer comprising a first chamber, means positioned in said chamber for agitating the contents thereof, a second chamber in communication with said first chamber, a plurality of vertically disposed wing bailles secured to the inner wall of said second chamr ber, rotatable paddles positioned in said second chamber, and means for varying the temperature of the contents of said second chamber.
3. In apparatus for the continuous refining of vegetable and animal 'oils, a mixer comprising a first chamber, a plurality of vertically spaced horizontal plate bafiies provided with central openings positioned therein, an agitator provided with rotatable paddles extending between said plate baflies positioned in said chamber, a second chamber in communication with said first chamber, a plurality of vertically disposed wing baflles secured to the inner wall of said second chamber, rotatable paddles positioned in said second chamber, and means for varying the temperature of the contents of said second chamber.
GEORGE FREDERICK WHEELWRIGHT, JR.
Priority Applications (1)
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US164659A US2249263A (en) | 1937-09-20 | 1937-09-20 | Apparatus for treating oils |
Applications Claiming Priority (1)
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US164659A US2249263A (en) | 1937-09-20 | 1937-09-20 | Apparatus for treating oils |
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US2249263A true US2249263A (en) | 1941-07-15 |
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US164659A Expired - Lifetime US2249263A (en) | 1937-09-20 | 1937-09-20 | Apparatus for treating oils |
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Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2759711A (en) * | 1952-10-01 | 1956-08-21 | Exxon Research Engineering Co | Mixing apparatus |
US3462128A (en) * | 1965-10-13 | 1969-08-19 | Dunlop Co Ltd | Metering and mixing device |
US4576483A (en) * | 1983-07-21 | 1986-03-18 | Mathis System-Technik Gmbh | Apparatus for mixing and metering flowable solid materials |
US4708489A (en) * | 1984-06-04 | 1987-11-24 | Wizards Ice Cream & Confectionery Shoppe, Ltd. | Blending machine |
US5061456A (en) * | 1987-08-25 | 1991-10-29 | Stranco, Inc. | Polymer activation apparatus |
US5135968A (en) * | 1990-10-10 | 1992-08-04 | Stranco, Ltd. | Methods and apparatus for treating wastewater |
US5252635A (en) * | 1987-08-25 | 1993-10-12 | Stranco, Inc. | Polymer activation method using two separate mixing zones |
US5284627A (en) * | 1987-08-25 | 1994-02-08 | Stranco, Inc. | Polymer activation apparatus |
US5316031A (en) * | 1987-08-25 | 1994-05-31 | Brazelton Carl L | Valve with independent control of discharge through plurality of orifices |
US5338779A (en) * | 1992-09-18 | 1994-08-16 | Stranco, Inc | Dry polymer activation apparatus and method |
US6409926B1 (en) | 1999-03-02 | 2002-06-25 | United States Filter Corporation | Air and water purification using continuous breakpoint halogenation and peroxygenation |
US6419817B1 (en) | 2000-06-22 | 2002-07-16 | United States Filter Corporation | Dynamic optimization of chemical additives in a water treatment system |
US6423234B1 (en) | 1999-03-02 | 2002-07-23 | United States Filter Corporation | Air and water purification using continuous breakpoint halogenation |
US20030038277A1 (en) * | 2001-08-09 | 2003-02-27 | Roy Martin | Calcium hypochlorite of reduced reactivity |
US20030160004A1 (en) * | 2002-02-26 | 2003-08-28 | Roy Martin | Free radical generator and method |
US20030160005A1 (en) * | 2002-02-26 | 2003-08-28 | Roy Martin | Enhanced air and water purification using continuous breakpoint halogenation with free oxygen radicals |
US6620315B2 (en) | 2001-02-09 | 2003-09-16 | United States Filter Corporation | System for optimized control of multiple oxidizer feedstreams |
US6645400B2 (en) | 2000-06-22 | 2003-11-11 | United States Filter Corporation | Corrosion control utilizing a hydrogen peroxide donor |
US6716359B1 (en) | 2000-08-29 | 2004-04-06 | United States Filter Corporation | Enhanced time-based proportional control |
US20080245737A1 (en) * | 2007-04-03 | 2008-10-09 | Siemens Water Technologies Corp. | Method and system for providing ultrapure water |
US20110024365A1 (en) * | 2009-07-30 | 2011-02-03 | Zhee Min Jimmy Yong | Baffle plates for an ultraviolet reactor |
US20110180485A1 (en) * | 2006-06-06 | 2011-07-28 | Fluid Lines | Ultraviolet light activated oxidation process for the reduction of organic carbon in semiconductor process water |
US20110209530A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Method for measuring a concentration of a compound in a liquid stream |
US20110210077A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Method and system for providing ultrapure water |
US20110210266A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Method of irradiating a liquid |
US20110210048A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | System for controlling introduction of a reducing agent to a liquid stream |
US20110210267A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Actinic radiation reactor |
US8877067B2 (en) | 2011-05-26 | 2014-11-04 | Evoqua Water Technologies Llc | Method and arrangement for a water treatment |
US9725343B2 (en) | 2007-04-03 | 2017-08-08 | Evoqua Water Technologies Llc | System and method for measuring and treating a liquid stream |
US10343939B2 (en) | 2006-06-06 | 2019-07-09 | Evoqua Water Technologies Llc | Ultraviolet light activated oxidation process for the reduction of organic carbon in semiconductor process water |
US10494281B2 (en) | 2015-01-21 | 2019-12-03 | Evoqua Water Technologies Llc | Advanced oxidation process for ex-situ groundwater remediation |
US11161762B2 (en) | 2015-01-21 | 2021-11-02 | Evoqua Water Technologies Llc | Advanced oxidation process for ex-situ groundwater remediation |
-
1937
- 1937-09-20 US US164659A patent/US2249263A/en not_active Expired - Lifetime
Cited By (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2759711A (en) * | 1952-10-01 | 1956-08-21 | Exxon Research Engineering Co | Mixing apparatus |
US3462128A (en) * | 1965-10-13 | 1969-08-19 | Dunlop Co Ltd | Metering and mixing device |
US4576483A (en) * | 1983-07-21 | 1986-03-18 | Mathis System-Technik Gmbh | Apparatus for mixing and metering flowable solid materials |
US4708489A (en) * | 1984-06-04 | 1987-11-24 | Wizards Ice Cream & Confectionery Shoppe, Ltd. | Blending machine |
US5316031A (en) * | 1987-08-25 | 1994-05-31 | Brazelton Carl L | Valve with independent control of discharge through plurality of orifices |
US5061456A (en) * | 1987-08-25 | 1991-10-29 | Stranco, Inc. | Polymer activation apparatus |
US5252635A (en) * | 1987-08-25 | 1993-10-12 | Stranco, Inc. | Polymer activation method using two separate mixing zones |
US5284627A (en) * | 1987-08-25 | 1994-02-08 | Stranco, Inc. | Polymer activation apparatus |
US5284626A (en) * | 1987-08-25 | 1994-02-08 | Stranco, Inc. | Polymer activation apparatus |
US5135968A (en) * | 1990-10-10 | 1992-08-04 | Stranco, Ltd. | Methods and apparatus for treating wastewater |
US5338779A (en) * | 1992-09-18 | 1994-08-16 | Stranco, Inc | Dry polymer activation apparatus and method |
US6409926B1 (en) | 1999-03-02 | 2002-06-25 | United States Filter Corporation | Air and water purification using continuous breakpoint halogenation and peroxygenation |
US6423234B1 (en) | 1999-03-02 | 2002-07-23 | United States Filter Corporation | Air and water purification using continuous breakpoint halogenation |
US6419817B1 (en) | 2000-06-22 | 2002-07-16 | United States Filter Corporation | Dynamic optimization of chemical additives in a water treatment system |
US6645400B2 (en) | 2000-06-22 | 2003-11-11 | United States Filter Corporation | Corrosion control utilizing a hydrogen peroxide donor |
US6716359B1 (en) | 2000-08-29 | 2004-04-06 | United States Filter Corporation | Enhanced time-based proportional control |
US6620315B2 (en) | 2001-02-09 | 2003-09-16 | United States Filter Corporation | System for optimized control of multiple oxidizer feedstreams |
US6623647B2 (en) | 2001-02-09 | 2003-09-23 | United States Filter Corporation | Methods of optimized control of multiple oxidizer feedstreams |
US20030038277A1 (en) * | 2001-08-09 | 2003-02-27 | Roy Martin | Calcium hypochlorite of reduced reactivity |
US6776926B2 (en) | 2001-08-09 | 2004-08-17 | United States Filter Corporation | Calcium hypochlorite of reduced reactivity |
US20040224088A1 (en) * | 2001-08-09 | 2004-11-11 | United States Filter Corporation | Calcium hypochlorite of reduced reactivity |
US6991735B2 (en) | 2002-02-26 | 2006-01-31 | Usfilter Corporation | Free radical generator and method |
US20050109709A1 (en) * | 2002-02-26 | 2005-05-26 | Usfilter Corporation | Enhanced air and water purification using continuous breakpoint halogenation with free oxygen radicals |
US20030160004A1 (en) * | 2002-02-26 | 2003-08-28 | Roy Martin | Free radical generator and method |
US7108781B2 (en) | 2002-02-26 | 2006-09-19 | Usfilter Corporation | Enhanced air and water purification using continuous breakpoint halogenation with free oxygen radicals |
US7285223B2 (en) | 2002-02-26 | 2007-10-23 | Siemens Water Technologies Holding Corp. | Enhanced air and water purification using continuous breakpoint halogenation with free oxygen radicals |
US20030160005A1 (en) * | 2002-02-26 | 2003-08-28 | Roy Martin | Enhanced air and water purification using continuous breakpoint halogenation with free oxygen radicals |
US10550020B2 (en) | 2006-06-06 | 2020-02-04 | Evoqua Water Technologies Llc | Ultraviolet light activated oxidation process for the reduction of organic carbon in semiconductor process water |
US10343939B2 (en) | 2006-06-06 | 2019-07-09 | Evoqua Water Technologies Llc | Ultraviolet light activated oxidation process for the reduction of organic carbon in semiconductor process water |
US8652336B2 (en) | 2006-06-06 | 2014-02-18 | Siemens Water Technologies Llc | Ultraviolet light activated oxidation process for the reduction of organic carbon in semiconductor process water |
US20110180485A1 (en) * | 2006-06-06 | 2011-07-28 | Fluid Lines | Ultraviolet light activated oxidation process for the reduction of organic carbon in semiconductor process water |
US20080245737A1 (en) * | 2007-04-03 | 2008-10-09 | Siemens Water Technologies Corp. | Method and system for providing ultrapure water |
US8741155B2 (en) | 2007-04-03 | 2014-06-03 | Evoqua Water Technologies Llc | Method and system for providing ultrapure water |
US20110210266A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Method of irradiating a liquid |
US20110210048A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | System for controlling introduction of a reducing agent to a liquid stream |
US20110210267A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Actinic radiation reactor |
US20110209530A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Method for measuring a concentration of a compound in a liquid stream |
US20080245738A1 (en) * | 2007-04-03 | 2008-10-09 | Siemens Water Technologies Corp. | Method and system for providing ultrapure water |
US20110210077A1 (en) * | 2007-04-03 | 2011-09-01 | Siemens Water Technologies Corp. | Method and system for providing ultrapure water |
US8753522B2 (en) | 2007-04-03 | 2014-06-17 | Evoqua Water Technologies Llc | System for controlling introduction of a reducing agent to a liquid stream |
US9764968B2 (en) | 2007-04-03 | 2017-09-19 | Evoqua Water Technologies Llc | Method and system for providing ultrapure water |
US8961798B2 (en) | 2007-04-03 | 2015-02-24 | Evoqua Water Technologies Llc | Method for measuring a concentration of a compound in a liquid stream |
US9365436B2 (en) | 2007-04-03 | 2016-06-14 | Evoqua Water Technologies Llc | Method of irradiating a liquid |
US9365435B2 (en) | 2007-04-03 | 2016-06-14 | Evoqua Water Technologies Llc | Actinic radiation reactor |
US9725343B2 (en) | 2007-04-03 | 2017-08-08 | Evoqua Water Technologies Llc | System and method for measuring and treating a liquid stream |
US20110024365A1 (en) * | 2009-07-30 | 2011-02-03 | Zhee Min Jimmy Yong | Baffle plates for an ultraviolet reactor |
US8591730B2 (en) | 2009-07-30 | 2013-11-26 | Siemens Pte. Ltd. | Baffle plates for an ultraviolet reactor |
US8877067B2 (en) | 2011-05-26 | 2014-11-04 | Evoqua Water Technologies Llc | Method and arrangement for a water treatment |
US10494281B2 (en) | 2015-01-21 | 2019-12-03 | Evoqua Water Technologies Llc | Advanced oxidation process for ex-situ groundwater remediation |
US11161762B2 (en) | 2015-01-21 | 2021-11-02 | Evoqua Water Technologies Llc | Advanced oxidation process for ex-situ groundwater remediation |
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