US2238018A - Ornamentation of ceramic ware - Google Patents
Ornamentation of ceramic ware Download PDFInfo
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- US2238018A US2238018A US244819A US24481938A US2238018A US 2238018 A US2238018 A US 2238018A US 244819 A US244819 A US 244819A US 24481938 A US24481938 A US 24481938A US 2238018 A US2238018 A US 2238018A
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- United States
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- size
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- ware
- drying
- oil
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- Expired - Lifetime
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- 239000000919 ceramic Substances 0.000 title description 12
- 238000005034 decoration Methods 0.000 description 36
- 239000000341 volatile oil Substances 0.000 description 32
- 238000001035 drying Methods 0.000 description 25
- 238000004144 decalcomania Methods 0.000 description 19
- 238000000034 method Methods 0.000 description 19
- 239000002904 solvent Substances 0.000 description 17
- 239000007788 liquid Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- 238000010304 firing Methods 0.000 description 13
- 239000003981 vehicle Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 8
- 239000010931 gold Substances 0.000 description 8
- 229910052737 gold Inorganic materials 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 7
- 239000003086 colorant Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 5
- 239000000020 Nitrocellulose Substances 0.000 description 4
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 4
- 229920000180 alkyd Polymers 0.000 description 4
- DWPDSISGRAWLLV-JHZYRPMRSA-L calcium;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Ca+2].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O.C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O DWPDSISGRAWLLV-JHZYRPMRSA-L 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 229920001220 nitrocellulos Polymers 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- PCYQQSKDZQTOQG-NXEZZACHSA-N dibutyl (2r,3r)-2,3-dihydroxybutanedioate Chemical compound CCCCOC(=O)[C@H](O)[C@@H](O)C(=O)OCCCC PCYQQSKDZQTOQG-NXEZZACHSA-N 0.000 description 3
- -1 fatty acid modified glyceryl phthalate Chemical class 0.000 description 3
- 239000000944 linseed oil Substances 0.000 description 3
- 235000021388 linseed oil Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- MXHKJQTYOAFPBY-UHFFFAOYSA-N 2-(2,3-dihydroxypropoxycarbonyl)benzoic acid Chemical compound OCC(O)COC(=O)C1=CC=CC=C1C(O)=O MXHKJQTYOAFPBY-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000010643 fennel seed oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000010668 rosemary oil Substances 0.000 description 2
- 229940058206 rosemary oil Drugs 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- NKMZBGMEVYDZSR-UHFFFAOYSA-N 4-butoxy-2,3-dihydroxy-4-oxobutanoic acid Chemical compound CCCCOC(=O)C(O)C(O)C(O)=O NKMZBGMEVYDZSR-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical class CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- HCUOPEBHVAVNIE-UHFFFAOYSA-N bis(3-methylbutyl) oxalate Chemical compound CC(C)CCOC(=O)C(=O)OCCC(C)C HCUOPEBHVAVNIE-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical compound CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000010672 sassafras oil Substances 0.000 description 1
- CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Definitions
- Certain size compositions within the scope of the invention may be more resistant to water after they have been dried beyond the tacky state. In such case the drying is partly or entirely carried out before washing oil the decalcomania backing.
- Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of a fatty acid modified glyceryl phthalate, a cellulosic resin, a minor amount of a plasticizerand a solvent for the composition, drying to a tacky state, applying a decalcomania decoration while said size is in such tacky state, further drying beyond the tacky state and removing the decalcomania backing, applying a color decoration at least a part of which overlies said size and which is dissolved in an essential oil vehicle and thereafter firing the ware.
- Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of an alkyd resin, a cellulose resin of the class consisting of cellulose nitrate, cellulose acetate and ethyl and benzyl celluloses, a minor amount of an organic plasticizer, in which said resins are soluble and a solvent for the composition, drying to a tacky state, applying decalcomania decoration, drying beyond the tacky state and washing off the backing of the decalcomania, applying a decoration at least a part of which overlies said sizeand which is carried by an essential oil vehicle and thereafter firing the ware.
- Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of an alkyd resin, cellulose nitrate, a minor amount of an organic plasticizer, in which said resins are soluble and a solvent for the composition, drying to a tacky state, applying decalcomania decoration, drying beyond the tacky state and washing off the backing 01' the decalcomania, applying a decoration at least a part of which overlies said size and which is carried by an essential oil vehicle and thereafter firing the ware.
- Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of an alkyd resin, cellulose acetate, a minor amount of an organic plasticizer, in which said resins are soluble and a solvent for the composition, drying to a tacky state, applying decalcomania decoration, drying beyond the tacky state and washing of! the back-' ing of the decalcomania, applying a decoration at least a part of which overlies said size and which is carried by an essential oil vehicle and thereafter firing the ware.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Decoration By Transfer Pictures (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
Patented Apr. 8, 1941 UNITED STATES PATENT OFFICE ORNAMENTATION OF CERAMIC WARE No Drawing. Application December 9, 1938, Serial No. 244,819
17 Claim.
This invention relates to the production of ornamented ceramic ware and, particularly to a method of over glaze decoration of such ware, making possible the application of both decalcomania decorations and metallic lustre and other similar decorations without an intermediate firing operation.
It has been the custom to apply a linseed oil rosin size to the glazed ware, then the decalcomania decoration; then fire off the size, apply the metallic lustre or other color of the type which is applied in an essential oil vehicle and again fire. In this particular art, the term size refers to a material which, in drying, develops temporarily a tackiness which is lost on further drying. With the linseed oil varnish size now used, the intermediate firing operation is necessary to prevent the development of defects in the decoration such as bleeding, feathering, streaking, discoloration, etc. It is the object of the present invention to provide a process permitting the successful elimination of the firing step intermediate between the application to the ware of the two types of decoration.
Decalcomania decorations are designs in ceramic colors and vitreous fluxlng material carried by paper backings and secured thereto by water soluble adhesive material. They are applied by first covering the were to be decorated, in the region where the design is to be applied, with a water insoluble size, applying the decalcomania to the size and then washing off thepaper and soluble adhesive with water and firing on the design to remove the size and establish a ceramic bond between the colored design and the glaze of the ware.
Metallic lustres and a number of other colors are applied as liquids, containing, as indicated, the desired colors, usually metallic compounds, in essential oil solvents, together with a flux adapted to establish a ceramic bond with the glaze of the ware upon firing.
I have now discovered that by proper manipulation and the use of proper materials, satisfactory results may be produced, without the intermediate firing step.
In accordance with the preferred practice of the invention, I apply to the glazed were a special size composition and dry the same to a tacky" or sticky condition, expelling most of the solvent. I then apply the decalcomania, wash away the paper backing and soluble adhesive and further dry the size beyond the tacky condition. Certain size compositions within the scope of the invention may be more resistant to water after they have been dried beyond the tacky state. In such case the drying is partly or entirely carried out before washing oil the decalcomania backing. I then apply the metallic lustre or other color of the liquid or essential oil carried type and fire the ware in the usual manner. The lustre or like liquid color may be applied over'the size or on the uncoated glaze or partly over the size and partly on the glaze.
It is my belief that the essential feature of the new size composition is that it be capable, under the conditions of the process, of developing the requisite tack and then becoming inert to the essential oils which are used in the liquid colors; and that the essential feature of the manipulation is that it develop the proper tackiness of the size for application of the decalcomania decoration and then, after such decoration has been applied, the inertness necessary to resist attack by the essential oil vehicle of the lustre.
The lustres usually contain resinates dissolved in a. vehicle of an essential oil blend. Liquid bright gold, for example, is a gold-suliur-resinate suspended in an essential oil blend, for example:
Grams Gold reslnate with 45 per cent gold 26'7 Rosemary oil 230 Fennel oil 98 It may also contain small amounts of resinates of other metals for special color effects, asphalts, resin and other essential oils, such as oil of laven der. Bright platinum and other liquid bright metalsglikewise, usually contain the metal resinates in an essential oil blend.
Colors as. applied for certain types of decoration' other than decalcomania designs, are essentially inorganic compounds of metals which are suspended in an essential oil vehicle and are applied to the glazed ware by various means in this liquid state. Various ceramic fluxing agents are also usually present with the coloring compounds to render them active and fusible with the glaze on the ware.
The essential oils, and other constituents of the vehicle, which are likely to be used in liquid colors and lustres, and the attack of which must be withstood by the properly dried size are:
Oil of lavender Oil of rosemary Oil of fennel Oil of clove Oil of Sassafras Oil of turpentine Linseed oil Tung oil have discovered that a composition including one or more materials from each of three classes is quite satisfactory.
CLASS I GLYcEaYL-PHTHALIc ANHYDRIDE BESINS RESINS) A. Modified by fatty acid For example, a mixed glycerlde of phthalic acid and castor oil fatty acid corresponding to 65% glyceryl-phthalate resin and 35% castor oil fatty acid glyceride. This material contains of toluol as a solvent and is sold underthe trade name Rezyl 53." This material is further identified as follows: Sp. G., 1.15; acid No. 18 to 24; refractive index, 1.5; consistency at 20 0., liquid.
(ALKYD B. Unmodified For example, Beckosol 1307 which is 50 per cent glyceryl-phthalate and 50 per cent xylene solvent. (This material has .an undesirably high solvent content and "preferably is reduced to 25 to per cent solvent before use.)
. CLASS II I 1 CEIZLQLosn Res ns A. Ce'llulosehitrate B. Cellulose acetate C. Benzyl cellulose D. Ethyl cellulose CLASS III PLASTICIZERS (SoLvEN'rs FOR CLASSES I AND II) A. Dibutyl tartrate (B. P. 292-312 C., M.,
P. 16-19 C.) B. Butyl carbitol acetate (B. P. 245 C.) C. Iso amyl oxalate D. Butyl tartrate E. Dibutyl phthalate EXAMPLES OF SIZE COMPOSITIONS The foregoing resin mixtures are dissolved in any suitable solvent, the following being pre ferred. The solvent is not very critical, very little of it remaining at the time of application of the metallic lustre or colored decoration.
Solvent A Toluene cc 10 Methyl isobutyl ketone cc 15 Butyl acetate cc l0 Ethylene glycol monoethyl ether ....cc-.. 7 75 Solvent B Toluene cc 10 Xylene cc 10 Ethyl carbonate cc 10 Butyl propionate cc 20 Cellusolve acetate cc 4 plasticizer, in which said resins are soluble anda solvent for the composition, drying to a tacky state, applying decalcomania decoration, drying beyond the tacky state and washing oil the backing of the decalcomania, applying a decoration at least a part of which overlies said size and which is carried by an essential oil vehicle and thereafter firing the ware.
y A process as recited in claim 1, characterized in that the essential oil decoration contains a metallic resinate.-
3. A process as recited in'claim 1, characterized in that the essential oil decoration is'liquid bright gold.
4. Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of a fatty acid modified glyceryl phthalate, a cellulosic resin, a minor amount of a plasticizerand a solvent for the composition, drying to a tacky state, applying a decalcomania decoration while said size is in such tacky state, further drying beyond the tacky state and removing the decalcomania backing, applying a color decoration at least a part of which overlies said size and which is dissolved in an essential oil vehicle and thereafter firing the ware.
5. A process as recited in claim 4, characterized in that the essential oil decoration is a metallic lustre.
6. A process as recited in claim 4, characterized in that the size contains castor oil fatty acid modified glyceryl phthalate, cellulose nitrate and dibutyl tartrate.
7. A process as recited in claim 4, characterized in that the size contains castor oil fatty acid modified glyceryl phthalate, cellulose nitrate and dibutyl tartrate, and said essential oil decoration is liquid bright gold.
8. Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of an alkyd resin, a cellulose resin of the class consisting of cellulose nitrate, cellulose acetate and ethyl and benzyl celluloses, a minor amount of an organic plasticizer, in which said resins are soluble and a solvent for the composition, drying to a tacky state, applying decalcomania decoration, drying beyond the tacky state and washing off the backing of the decalcomania, applying a decoration at least a part of which overlies said sizeand which is carried by an essential oil vehicle and thereafter firing the ware.
9. A process as recited in claim 8, characterized in that the essential oil decoration contains a metallic resinate.
10. A process as recited in claim 8, characterized in that the essential oil decoration is liquid bright gold.
11. Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of an alkyd resin, cellulose nitrate, a minor amount of an organic plasticizer, in which said resins are soluble and a solvent for the composition, drying to a tacky state, applying decalcomania decoration, drying beyond the tacky state and washing off the backing 01' the decalcomania, applying a decoration at least a part of which overlies said size and which is carried by an essential oil vehicle and thereafter firing the ware.
12. Process of ornamenting glazed ceramic ware comprising applying thereto a size having the property of drying to a tacky state and upon further drying becoming inert to essential oils, said size consisting essentially of an alkyd resin, cellulose acetate, a minor amount of an organic plasticizer, in which said resins are soluble and a solvent for the composition, drying to a tacky state, applying decalcomania decoration, drying beyond the tacky state and washing of! the back-' ing of the decalcomania, applying a decoration at least a part of which overlies said size and which is carried by an essential oil vehicle and thereafter firing the ware.
13. A process as recited in claim 11, characterized in that the essential oil decoration contains a metallic resinate.
14. A process as recited in claim 11, characterized in that the essential oil decoration is liquid bright gold.
15. A process as recited in claim 12, characterized in that the essential oil decoration contains a metallic resinate.
16. A process as recited in claim 12, characterized in that the essential oil decoration is liquid bright gold.
1'7. A process of ornamenting ceramic ware comprising applying thereto a size characterized in that in drying it passes through a tacky state and then upon further drying becomes inert to essential oil solvents, drying such size to such tacky state, applying a decalcomania decoration over such size while it is in such tacky state, drying such size to the inert state and then applying thereover a color decoration in an essential oil solvent to which such size is inert and thereafter firing the ware, whereby a firing step between said decaloomania decoration and said color decoration is eliminated and with production of ware carrying a color decoration free from bleeding, feathering and streaking.
WILLIAM H. EARHART.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US244819A US2238018A (en) | 1938-12-09 | 1938-12-09 | Ornamentation of ceramic ware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US244819A US2238018A (en) | 1938-12-09 | 1938-12-09 | Ornamentation of ceramic ware |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2238018A true US2238018A (en) | 1941-04-08 |
Family
ID=22924228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US244819A Expired - Lifetime US2238018A (en) | 1938-12-09 | 1938-12-09 | Ornamentation of ceramic ware |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2238018A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2476570A (en) * | 1947-01-24 | 1949-07-19 | Socony Vacuum Oil Co Inc | Decoration of ceramic ware |
-
1938
- 1938-12-09 US US244819A patent/US2238018A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2476570A (en) * | 1947-01-24 | 1949-07-19 | Socony Vacuum Oil Co Inc | Decoration of ceramic ware |
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