US2222544A - Formed piece of silver palladium alloys - Google Patents

Formed piece of silver palladium alloys Download PDF

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Publication number
US2222544A
US2222544A US299908A US29990839A US2222544A US 2222544 A US2222544 A US 2222544A US 299908 A US299908 A US 299908A US 29990839 A US29990839 A US 29990839A US 2222544 A US2222544 A US 2222544A
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United States
Prior art keywords
pens
platinum
silver
formed piece
silver palladium
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US299908A
Inventor
Spanner Jakob
Leuser Josef
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHEMICAL MARKETING Co Inc
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CHEMICAL MARKETING Co Inc
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Publication of US2222544A publication Critical patent/US2222544A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C5/00Alloys based on noble metals
    • C22C5/06Alloys based on silver
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C5/00Alloys based on noble metals
    • C22C5/04Alloys based on a platinum group metal

Definitions

  • Our invention relates to formed pieces made from precious metals, such as wires, sheets and the like,.especially pens, fountain pensand the like.
  • pens, fountain pens or the like may be manufactured from alloys containing palladium, silver, copper and, if desired, gold. These alloys are. on the whole very resistant against chemical influences but tend to corrosion by tension. The manifestation of this corrosion of tension will be seen by cracking or falling to powder of alloys owing to theginfluence of atmospherics, acids, salt solutions or the like,
  • Pens, for instance fountain .pens,- proved to are substantially free from the disadvantage of corrosion of tension.
  • the above described alloys do not only avoid the noxious 1 influences of the corrosion of tension but possess even an increased protection against external chemical influences owing to the superficial coating with the above mentioned precious metals. All formed pieces, such as pens, foun- 1 tain pens. or the like which are made in such a way aredistinguished by special durability and resistancy.
  • a pen made of an alloy containing 20-60% palladium, 0-20% copper, 0-10% of a metal from the group consisting of nickel, zinc, iron, cobalt, tin and cadmium, 0-20% platinum, and the remainder substantially all silver.
  • a pen according to claim 5 having thereon a. coating of an alloy of a. metal of the group consisting of gold, platinum and rhodium.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Adornments (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Description

PatentedNov. 19, 194
ESKTP'ATEI '5 OFFICE FORMED PIECEOF SILVER PALLADIUM annoys Jakob Spanner, Neu-Isenburg,.and Josef Leuser,
Piorzlieim, Germany, assignors to Chemical Marketing Company Inc., New York, N. Y., a;
corporation No Drawing. Application October 17, 1939, Serial No. 299,908. In Germany October 19, 1938' 8 Claims.
Our invention relates to formed pieces made from precious metals, such as wires, sheets and the like,.especially pens, fountain pensand the like.
It is known that pens, fountain pens or the like may be manufactured from alloys containing palladium, silver, copper and, if desired, gold. These alloys are. on the whole very resistant against chemical influences but tend to corrosion by tension. The manifestation of this corrosion of tension will be seen by cracking or falling to powder of alloys owing to theginfluence of atmospherics, acids, salt solutions or the like,
sometimes withoutany visible cause. According to our invention this disadvantage may be avoided if formed pieces such as pens, fountain pens or the like are made from alloys with. the following composition:
. Per cent Palladium 20-60 Copper- 0-20 Nickel or zinc, iron, cobalt, tin, cadmium respectively 0-10 Silver Rest The nickel may be replaced by zinc, iron, cobalt, tin, cadmium or the like, either alone or in combination with each other.
Pens, for instance fountain .pens,- proved to are substantially free from the disadvantage of corrosion of tension.
These formed pieces, for instance pens, fountain'pens' or the like, have a very good resistancy also against the influence of ink. This .resistancy may be enhanced even more if these pens are coated with precious metals such as gold, rhodium, other metals of platinum group or alloys, of these precious metals. I
According to our invention the above described alloys do not only avoid the noxious 1 influences of the corrosion of tension but possess even an increased protection against external chemical influences owing to the superficial coating with the above mentioned precious metals. All formed pieces, such as pens, foun- 1 tain pens. or the like which are made in such a way aredistinguished by special durability and resistancy.
What we claim is:
1. Formed pieces made from an alloy containing 20-60% palladium, 0-20% copper, 040% of ametal from the group consisting of nickel, zinc, iron, cobalt, tin and cadmium, 0- 20% platinum, and the remainder substantially all silver.
' 2. Formed piecesmade of an alloy containing 35% palladium, 5% platinum, 10% copper, 0.5% nickel, and 49.5% silver.
3. Formed pieces according to claim 1 having thereon a. coating of a precious metal ofthe group consisting of gold, platinum, and rhodium.
4. Formed pieces according to claim 1, having a coating thereon of an alloy of a metal of the group consisting of gold, platinum and rhodium.;
5. A pen made of an alloy containing 20-60% palladium, 0-20% copper, 0-10% of a metal from the group consisting of nickel, zinc, iron, cobalt, tin and cadmium, 0-20% platinum, and the remainder substantially all silver.
6. A pen made of an alloy containing 35% palladium, 5% platinum, 10% copper, 0.5% nickel, 40
and 49.5% silver.
7. A pen according to claim 5, having thereon a coating of a precious metal ofthe group consisting of gold, platinum, andrhodium.
' 8. A pen according to claim 5, having thereon a. coating of an alloy of a. metal of the group consisting of gold, platinum and rhodium.
' JAKOB SPANNER.
JOSEF LEUSER.
US299908A 1938-10-19 1939-10-17 Formed piece of silver palladium alloys Expired - Lifetime US2222544A (en)

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DE2222544X 1938-10-19

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3226309A (en) * 1962-01-10 1965-12-28 Leesona Corp Method of electro-deposition of a palladium-silver alloy
US3310718A (en) * 1964-04-07 1967-03-21 Nytronics Inc Impedance element with alloy connector
US3413115A (en) * 1966-01-20 1968-11-26 James E. Webb Brazing alloy
US3907556A (en) * 1972-02-11 1975-09-23 Haas Carl Alloys for tension bands
US3929475A (en) * 1974-08-05 1975-12-30 Williams Gold Refining Co Tarnish resistant silver based dental casting alloy having superior improved ductility and work hardening characteristics
US3929474A (en) * 1974-08-05 1975-12-30 Williams Gold Refining Co Tarnish resistant silver based dental casting alloy capable of bonding to porcelain
US4396578A (en) * 1982-01-27 1983-08-02 Bales Randy L White gold jewelry alloy
US4400350A (en) * 1982-09-29 1983-08-23 W. C. Heraeus Gmbh Palladium dental alloy
US5484569A (en) * 1994-08-12 1996-01-16 The J. M. Ney Company Silver palladium alloy
US5833774A (en) * 1997-04-10 1998-11-10 The J. M. Ney Company High strength silver palladium alloy
US20090218647A1 (en) * 2008-01-23 2009-09-03 Ev Products, Inc. Semiconductor Radiation Detector With Thin Film Platinum Alloyed Electrode
DE102009022357A1 (en) * 2009-05-18 2010-11-25 Heimerle + Meule Gmbh Palladium jewelery alloy

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3226309A (en) * 1962-01-10 1965-12-28 Leesona Corp Method of electro-deposition of a palladium-silver alloy
US3310718A (en) * 1964-04-07 1967-03-21 Nytronics Inc Impedance element with alloy connector
US3413115A (en) * 1966-01-20 1968-11-26 James E. Webb Brazing alloy
US3907556A (en) * 1972-02-11 1975-09-23 Haas Carl Alloys for tension bands
US3929475A (en) * 1974-08-05 1975-12-30 Williams Gold Refining Co Tarnish resistant silver based dental casting alloy having superior improved ductility and work hardening characteristics
US3929474A (en) * 1974-08-05 1975-12-30 Williams Gold Refining Co Tarnish resistant silver based dental casting alloy capable of bonding to porcelain
US4396578A (en) * 1982-01-27 1983-08-02 Bales Randy L White gold jewelry alloy
US4400350A (en) * 1982-09-29 1983-08-23 W. C. Heraeus Gmbh Palladium dental alloy
US5484569A (en) * 1994-08-12 1996-01-16 The J. M. Ney Company Silver palladium alloy
WO1996005330A1 (en) * 1994-08-12 1996-02-22 The J.M. Ney Company Silver palladium alloy
US5833774A (en) * 1997-04-10 1998-11-10 The J. M. Ney Company High strength silver palladium alloy
US20090218647A1 (en) * 2008-01-23 2009-09-03 Ev Products, Inc. Semiconductor Radiation Detector With Thin Film Platinum Alloyed Electrode
US8896075B2 (en) 2008-01-23 2014-11-25 Ev Products, Inc. Semiconductor radiation detector with thin film platinum alloyed electrode
DE102009022357A1 (en) * 2009-05-18 2010-11-25 Heimerle + Meule Gmbh Palladium jewelery alloy

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