US2210014A - Noncorrosive perspiration inhibiting composition - Google Patents
Noncorrosive perspiration inhibiting composition Download PDFInfo
- Publication number
- US2210014A US2210014A US264490A US26449039A US2210014A US 2210014 A US2210014 A US 2210014A US 264490 A US264490 A US 264490A US 26449039 A US26449039 A US 26449039A US 2210014 A US2210014 A US 2210014A
- Authority
- US
- United States
- Prior art keywords
- astringent
- salt
- perspiration
- noncorrosive
- inhibiting composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000002401 inhibitory effect Effects 0.000 title description 9
- 239000000203 mixture Substances 0.000 title description 7
- 230000009972 noncorrosive effect Effects 0.000 title 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 22
- 150000003839 salts Chemical class 0.000 description 17
- 238000002360 preparation method Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 239000002537 cosmetic Substances 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- -1 fatty alcohol compound Chemical class 0.000 description 4
- 159000000011 group IA salts Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N Lactic Acid Natural products CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000004280 Sodium formate Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229940049920 malate Drugs 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 2
- 235000019254 sodium formate Nutrition 0.000 description 2
- 229940095064 tartrate Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 101100440696 Caenorhabditis elegans cor-1 gene Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229940022663 acetate Drugs 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229960005069 calcium Drugs 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- YXVFQADLFFNVDS-UHFFFAOYSA-N diammonium citrate Chemical compound [NH4+].[NH4+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O YXVFQADLFFNVDS-UHFFFAOYSA-N 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940001447 lactate Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- XYSQXZCMOLNHOI-UHFFFAOYSA-N s-[2-[[4-(acetylsulfamoyl)phenyl]carbamoyl]phenyl] 5-pyridin-1-ium-1-ylpentanethioate;bromide Chemical compound [Br-].C1=CC(S(=O)(=O)NC(=O)C)=CC=C1NC(=O)C1=CC=CC=C1SC(=O)CCCC[N+]1=CC=CC=C1 XYSQXZCMOLNHOI-UHFFFAOYSA-N 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- VGBPIHVLVSGJGR-UHFFFAOYSA-N thorium(4+);tetranitrate Chemical compound [Th+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VGBPIHVLVSGJGR-UHFFFAOYSA-N 0.000 description 1
- GTFYTIZAGLSUNG-UHFFFAOYSA-N tris(2-hydroxyethyl)azanium;formate Chemical compound OC=O.OCCN(CCO)CCO GTFYTIZAGLSUNG-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/526—Corrosion inhibitors
Definitions
- the clothing is tion inhibitor, thqapplication of a hot iron, 'as-in 4i; citric, tartaric,
- This invention relates to a 'noncorroeive per spiration inhibiting material and more particu larly to a composition to prevent astringent per- 7 spiration inhibiting compositions from-damaging 8 garment fabrics, or the like.
- a cream perspiration-inhibitor can be formed as follows: a
- astringent salt of a mono basic 10 acid such as aluminum chloride, zinc chloride; thorium nitrate, aluminum nitrate, or the like.
- Dioxan 20 to 40 To this base may beadded 3 parts of the astringent salt with a parts of the salt and from so to so parts of the base.
- Dioxanf' is 1,4 diethylene oxide.
- Suitablesalts are the salts of formic, acetic,
- lactic, and malic acid Ordinarily calcium, sodium, magnesium, or ammonium salts of these acids will be employed.- The invention isnot limited to the completely neutralized salts. For example, ammoniumbi-lactate, ammonium bi-malate, sodium bi-tartrate and diammonium citrate are effective but require larger quantities a of material. with these salts, about 10 to 15 times as much salt is required as aluminum chloride. Triethanolamine formate, or acetate tors can be applied topically in the usual man Jected ,to high temperature.
- theinhibitor will react with liberated free acid without being active with aluminum chloride or the perspiration inhibitor which is prepared either in other astringent
- the corrosion inhibitor is incorporated in the perspiration inhibiting composition, but ordinary perspiration inhibiner and then an application made of the cor- 1 rosion inhibiting material. This is pal'ticularly effective in the case of corrosion, inhibitorsof relatively lowsolubility.
- the amount of therreeien inhibitor em 'ployed' will varywith theastringency, of the perspiration inhibiting compound.
- Aluminum chloride is oneof the most astringent.
- Ammonium salts, such asflammonium iormate, acetate, malate, tartrate, lactate; and oxalate, are generally used in somewhat larger amounts than the corresponding sodium salts.
- astringent salts employed are' the chlorides, nitrates, or sulfates oi aluminum..,ainc, or thorium.
- Other astringent salts are i ehilivalent in action, however.
- the sulfate requires 'very much less inhibiting material than does the chloride.
- a cosmetic astringent preparation containing an astringent material comprising an acidtormate or calcium acetate or sodium acetate may be used.
- a cosmetic astringent-preparation including a salt of aluminum and a strong inorganic acid, and a proportion of an alkaline salt of an aliphatic organic acid having not more than six carbon atoms.
- a cosmetic astringent preparation including v aluminum chloride and an inhibiting proportion 0! an alkaline salt of an aliphatic organic acid having not more than six carbon atoms.
- a cosmetic astringent preparation including aluminum chloride and at least an equal proportion of a soluble alkaline salt of an aliphatic organic acid having not morethan six carbon atomsa 5.
- a cosmetic astringent preparation including an acid-reacting aluminum salt and at least an equal proportion oi. a soluble salt of an-aliphatic organic acid having not more than six carbon atoms and a metal of the group consisting of the alkali and alkaline earth metals.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
' 16 n. the clothing is tion inhibitor, thqapplication of a hot iron, 'as-in 4i; citric, tartaric,
relatedness, m
lvonooaaosrva me oom'osmon PATE l nt-1 w Kellie name-m. aaeigncrto 'rhe' Pharm- Oraft Re. 264, v scu (cuss-so) This invention relates to a 'noncorroeive per spiration inhibiting material and more particu larly to a composition to prevent astringent per- 7 spiration inhibiting compositions from-damaging 8 garment fabrics, or the like. g
Many preparations are known inthe art for corporations corporationmall 27,1939, m
As an example of the-invention, a cream perspiration-inhibitor can be formed as follows: a
treatingslrln areas to eliminate the unpleasant Y eifects of perspiration. Most of thesepreparations contain an astringent salt of a mono basic 10 acid, such as aluminum chloride, zinc chloride; thorium nitrate, aluminum nitrate, or the like.
One difllculty in the use of such'preparations isdue to the fact at the material brushes of! on the clothing of the wearer and damages the fabric.
riot washed free of the perspirapressing the goods, wllldestroy the fabric, ap-
base comprising from 10 to 30 parts of "tegacid" or ;aquarol and'from 0 to 20 parts of petrolatum is melted by heating it to about 90 C. From 1 40 to 70 parts of boiling water is stirredinto the composition and then it is permitted to cool. Into this base maybe stirred dry aluminum chloride crystals (AlCl'aGHz-O) using about parts of the base to'from 1 to 10 parts of aluminum chloride. The crystals immediately softenthe base and permit the composition-to be stirred easily,
and later the material will set into the-consistency of a cream which is an effective perspiration-.- inhibitor. To the composition thus formed a salt,
- such as sodium formate is added. About equal patently through the liberation of a free-acid which almost immediately destroys rayon and some other fabricscommonly used in wearing apparel- Even where the goods are not ironed, the astringent salt will rot the clothing.
This dlfllculty is overcome by the present inven'-' tion through the use of a salt of analkali metal.
parts of sodium formate are added compared to the aluminum chloride. Smaller amounts, however, will give some protection. "Tegacid is the trade name for a mixture of glycerol monostearate or alkalineeatth metal and an organic acid. In
order to be completely eifectivesuch materials should, of course, be highly'water soluble, and the lower the corrosion inhibiting properties thereof,
the greater must be the solubility. These salts .have the peculiar property of being able to neutraliae the potential corrosiveness of astringent liquid form, asacream. or in solid form.
and a wetting agent presumably of "the sulfated fatty alcohol compound type. .Aquarol is a similar compound. I
A formula for analcohol base vehicle is as m Parts follows: I v
Candelilla wax 3 to 8 Castoro 1 -3to8 Isopropyl alcohol. 40 to 60 Dioxan" 20 to 40 To this base may beadded 3 parts of the astringent salt with a parts of the salt and from so to so parts of the base. Dioxanf' is 1,4 diethylene oxide.
It has been found that the'astringent salt such as aluminum chloride will not react with the alkaline salt before the combination is sub- Suitablesalts are the salts of formic, acetic,
lactic, and malic acid. Ordinarily calcium, sodium, magnesium, or ammonium salts of these acids will be employed.- The invention isnot limited to the completely neutralized salts. For example, ammoniumbi-lactate, ammonium bi-malate, sodium bi-tartrate and diammonium citrate are effective but require larger quantities a of material. with these salts, about 10 to 15 times as much salt is required as aluminum chloride. Triethanolamine formate, or acetate tors can be applied topically in the usual man Jected ,to high temperature. Apparently theinhibitor will react with liberated free acid without being active with aluminum chloride or the perspiration inhibitor which is prepared either in other astringent In the example given the corrosion inhibitor is incorporated in the perspiration inhibiting composition, but ordinary perspiration inhibiner and then an application made of the cor- 1 rosion inhibiting material. This is pal'ticularly effective in the case of corrosion, inhibitorsof relatively lowsolubility.
The amount of therreeien inhibitor em 'ployed' will varywith theastringency, of the perspiration inhibiting compound. Aluminum chloride is oneof the most astringent. For one I part of aluminum chloride, one part of. sodium chloride, two partsoiRochelle salts, of sodium citrate, of sodium tartrate bigmagnesium acetate, or calcium lactate, shouldfipe employed. Ammonium salts, such asflammonium iormate, acetate, malate, tartrate, lactate; and oxalate, are generally used in somewhat larger amounts than the corresponding sodium salts.
The usual astringent salts employed are' the chlorides, nitrates, or sulfates oi aluminum..,ainc, or thorium. Other astringent salts are i ehilivalent in action, however. The sulfate requires 'very much less inhibiting material than does the chloride.
This application is-a continuation in part of my copending application Ser. No. 219,880, filed July 18, 1938.
The foregoing detailed description ha.s been given for cleamess of understandingonly, and no unnecessary limitations should be understood therefrom.
Iclaim:
1. A cosmetic astringent preparation containing an astringent material comprising an acidtormate or calcium acetate or sodium acetate may be used. For the same amount (ifaluminum -2. A cosmetic astringent-preparation including a salt of aluminum and a strong inorganic acid, and a proportion of an alkaline salt of an aliphatic organic acid having not more than six carbon atoms.
3. A cosmetic astringent preparation including v aluminum chloride and an inhibiting proportion 0! an alkaline salt of an aliphatic organic acid having not more than six carbon atoms.
4. A cosmetic astringent preparation including aluminum chloride and at least an equal proportion of a soluble alkaline salt of an aliphatic organic acid having not morethan six carbon atomsa 5. A cosmetic astringent preparation including an acid-reacting aluminum salt and at least an equal proportion oi. a soluble salt of an-aliphatic organic acid having not more than six carbon atoms and a metal of the group consisting of the alkali and alkaline earth metals.
20 6. The cosmetic preparation as set forth in S. The cosmetic preparation as set forth in 25
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US264490A US2210014A (en) | 1939-03-27 | 1939-03-27 | Noncorrosive perspiration inhibiting composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US264490A US2210014A (en) | 1939-03-27 | 1939-03-27 | Noncorrosive perspiration inhibiting composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2210014A true US2210014A (en) | 1940-08-06 |
Family
ID=23006295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US264490A Expired - Lifetime US2210014A (en) | 1939-03-27 | 1939-03-27 | Noncorrosive perspiration inhibiting composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2210014A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2586288A (en) * | 1948-12-11 | 1952-02-19 | Colgate Palmolive Peet Co | Aluminum sulfamate antiperspirant |
| DE945945C (en) * | 1949-07-26 | 1956-11-15 | Henkel & Cie Gmbh | laundry detergent |
| US3009860A (en) * | 1957-06-14 | 1961-11-21 | Chattanooga Medicine Co | Zirconyl trichloro aluminate and method of making the same |
| US3923971A (en) * | 1973-09-13 | 1975-12-02 | Alexandre Seilinger | Antiperspirant and deodorant composition containing lamellar substances |
| US4027007A (en) * | 1970-12-09 | 1977-05-31 | Colgate-Palmolive Company | Antiperspirants formulated with borax |
| US4089942A (en) * | 1976-01-29 | 1978-05-16 | L'oreal | Deodorant composition and process |
| US4551330A (en) * | 1983-06-30 | 1985-11-05 | Helene Curtis Industries, Inc. | Skin and hair conditioner compositions and conditioning method |
| US5643559A (en) * | 1991-10-30 | 1997-07-01 | Colgate-Palmolive Company | Deodorant compositions comprising inhibitors of odor-producing axillary bacterial exoenzymes |
| US5911975A (en) * | 1995-10-13 | 1999-06-15 | Colgate-Palmolive Company | Antiperspirant and deodorant compositions containing poly(ethenylformamide) thickening agent |
-
1939
- 1939-03-27 US US264490A patent/US2210014A/en not_active Expired - Lifetime
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2586288A (en) * | 1948-12-11 | 1952-02-19 | Colgate Palmolive Peet Co | Aluminum sulfamate antiperspirant |
| DE945945C (en) * | 1949-07-26 | 1956-11-15 | Henkel & Cie Gmbh | laundry detergent |
| US3009860A (en) * | 1957-06-14 | 1961-11-21 | Chattanooga Medicine Co | Zirconyl trichloro aluminate and method of making the same |
| US4027007A (en) * | 1970-12-09 | 1977-05-31 | Colgate-Palmolive Company | Antiperspirants formulated with borax |
| US3923971A (en) * | 1973-09-13 | 1975-12-02 | Alexandre Seilinger | Antiperspirant and deodorant composition containing lamellar substances |
| US4089942A (en) * | 1976-01-29 | 1978-05-16 | L'oreal | Deodorant composition and process |
| US4551330A (en) * | 1983-06-30 | 1985-11-05 | Helene Curtis Industries, Inc. | Skin and hair conditioner compositions and conditioning method |
| US5643559A (en) * | 1991-10-30 | 1997-07-01 | Colgate-Palmolive Company | Deodorant compositions comprising inhibitors of odor-producing axillary bacterial exoenzymes |
| US5676937A (en) * | 1991-10-30 | 1997-10-14 | Colgate-Palmolive Company | Deodorant compositions comprising inhibitors of odor-producing axillary bacterial exoenzymes |
| US5911975A (en) * | 1995-10-13 | 1999-06-15 | Colgate-Palmolive Company | Antiperspirant and deodorant compositions containing poly(ethenylformamide) thickening agent |
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