US2186850A - Color photography - Google Patents

Color photography Download PDF

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Publication number
US2186850A
US2186850A US126842A US12684237A US2186850A US 2186850 A US2186850 A US 2186850A US 126842 A US126842 A US 126842A US 12684237 A US12684237 A US 12684237A US 2186850 A US2186850 A US 2186850A
Authority
US
United States
Prior art keywords
color
methylene group
radical
following formula
substitution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US126842A
Other languages
English (en)
Inventor
Wilmanns Gustav
Bitterfeld Kreis
Sieglitz Adolf
Frohlich Alfred
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
Agfa Ansco Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa Ansco Corp filed Critical Agfa Ansco Corp
Application granted granted Critical
Publication of US2186850A publication Critical patent/US2186850A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/32Colour coupling substances
    • G03C7/36Couplers containing compounds with active methylene groups

Definitions

  • Our present invention relates to the art of color photography.
  • One of its objects is a process of producing photographic color pictures by means of dyestufl components.
  • a further object is the provision of novel photographic materials used for producing the photog.'aphic color pictures. Further objects will be seen from the detailed specification 1'01- lowing hereafter.
  • Patent 1,963,197 or similar processes working with diazonium compounds are used, one obtains by coupling with acetic acid ester anilides yellow dyestufl pictures.
  • This invention is based on the observation that the methylene group in such compounds may be made particularly active if the body is converted into an oxalic acid ester derivative of the compound or derivative thereof.
  • oxalic acid ester derivatives which provisionally maybe regardedas compounds oi. the following structure:
  • behave in the photographic color as do the bodies having the highly reactive methylene groups refered to above.
  • the oxalic acid ester or fluorene of the following formula yields when used as dyestuilf component in' color development a red dyestuii picture of particularly pure tint when dimethylaminoaniline is used as a developer, the oxalic acid ester of indene .cri/
  • the support may either consist of a transparent material as for instance Celluloid,
  • cellulose-acetate or of a light-reflecting material, as for instance paper.
  • An exposed silver halide emulsion layer is developed by means of a developer consisting of a solution of 3 grams of p-aminodimethyl-aniline and 1000 cc. of a 3% soda-solution to which are added 1.5 grams of the oxalic acid ester of fluorene.
  • a color forming developer comprising an aromatic amino developing agent and a compound containing a methylene group activated by substitution of one hydrogen atom thereof by a radical of the following formula wherein R is an alkyl radical.
  • a color forming developer comprising an aromatic amino developing agent and a compound containing a methylene group, said compound being per se insufficiently reactive to form a dye by color forming development but being activated by substitution of one hydrogen atom of the methylene group by a radical of the following formula -o-c-on 3 Ii 0 wherein R is an alkyl radical.
  • a color forming developer comprising an aromatic amino developing agent and a compound selected from the group consisting of fluorene, benzofluorene, indene, dihydroresorcinol, hydroxythionaphthene, diphenyimethane and cyclohexanol, in-which the methylene group is activated by substitution of one hydrogen atom by a radical of the following formula Jc J-oR I 0 0 wherein R is an alkyl radical.
  • R is an alkyl radical

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
US126842A 1936-02-27 1937-02-20 Color photography Expired - Lifetime US2186850A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE201643X 1936-02-27

Publications (1)

Publication Number Publication Date
US2186850A true US2186850A (en) 1940-01-09

Family

ID=5767278

Family Applications (1)

Application Number Title Priority Date Filing Date
US126842A Expired - Lifetime US2186850A (en) 1936-02-27 1937-02-20 Color photography

Country Status (4)

Country Link
US (1) US2186850A (xx)
BE (1) BE420187A (xx)
CH (1) CH201643A (xx)
FR (1) FR818388A (xx)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433632A (en) * 1942-12-23 1947-12-30 Rca Corp Fibrous sheet material for the electrolytic formation of azo dye image records thereon
US2440526A (en) * 1942-12-23 1948-04-27 Nellie W Solomon Fibrous sheet material for the electrolytic formation of an azo dyestuff thereon
US3649285A (en) * 1969-07-16 1972-03-14 Konishiroku Photo Ind Light-sensitive silver halide color photographic materials containing cyan coupler

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433632A (en) * 1942-12-23 1947-12-30 Rca Corp Fibrous sheet material for the electrolytic formation of azo dye image records thereon
US2440526A (en) * 1942-12-23 1948-04-27 Nellie W Solomon Fibrous sheet material for the electrolytic formation of an azo dyestuff thereon
US3649285A (en) * 1969-07-16 1972-03-14 Konishiroku Photo Ind Light-sensitive silver halide color photographic materials containing cyan coupler

Also Published As

Publication number Publication date
CH201643A (de) 1938-12-15
BE420187A (xx)
FR818388A (fr) 1937-09-24

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