US2178625A - Fireproofing treatment and composition - Google Patents
Fireproofing treatment and composition Download PDFInfo
- Publication number
- US2178625A US2178625A US18382938A US2178625A US 2178625 A US2178625 A US 2178625A US 18382938 A US18382938 A US 18382938A US 2178625 A US2178625 A US 2178625A
- Authority
- US
- United States
- Prior art keywords
- chlorinated
- water
- composition
- materials
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title description 30
- 238000011282 treatment Methods 0.000 title description 17
- 238000004079 fireproofing Methods 0.000 title description 10
- 239000000463 material Substances 0.000 description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 42
- 239000002904 solvent Substances 0.000 description 23
- 239000011248 coating agent Substances 0.000 description 17
- 238000000576 coating method Methods 0.000 description 17
- 239000003340 retarding agent Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 11
- 230000001680 brushing effect Effects 0.000 description 10
- 239000011148 porous material Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 8
- 229910021538 borax Inorganic materials 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 239000004014 plasticizer Substances 0.000 description 8
- 239000004328 sodium tetraborate Substances 0.000 description 8
- 235000010339 sodium tetraborate Nutrition 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 8
- 238000002485 combustion reaction Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000000979 retarding effect Effects 0.000 description 7
- 239000002023 wood Substances 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 230000037452 priming Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000080 wetting agent Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 150000001642 boronic acid derivatives Chemical class 0.000 description 4
- 229950005499 carbon tetrachloride Drugs 0.000 description 4
- 239000005018 casein Substances 0.000 description 4
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 4
- 235000021240 caseins Nutrition 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000011368 organic material Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000004254 Ammonium phosphate Substances 0.000 description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 3
- 235000019289 ammonium phosphates Nutrition 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 238000011221 initial treatment Methods 0.000 description 3
- 239000006193 liquid solution Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 239000011775 sodium fluoride Substances 0.000 description 3
- 235000013024 sodium fluoride Nutrition 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 241000272525 Anas platyrhynchos Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 2
- 229910001626 barium chloride Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- -1 tungstates Chemical class 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/907—Resistant against plant or animal attack
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
- Y10S428/921—Fire or flameproofing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31801—Of wax or waxy material
- Y10T428/31804—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31844—Of natural gum, rosin, natural oil or lac
- Y10T428/31848—Next to cellulosic
- Y10T428/31851—Natural oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2041—Two or more non-extruded coatings or impregnations
- Y10T442/2098—At least two coatings or impregnations of different chemical composition
- Y10T442/2107—At least one coating or impregnation contains particulate material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2221—Coating or impregnation is specified as water proof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2631—Coating or impregnation provides heat or fire protection
- Y10T442/2664—Boron containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2631—Coating or impregnation provides heat or fire protection
- Y10T442/2672—Phosphorus containing
- Y10T442/268—Phosphorus and nitrogen containing compound
Definitions
- the invention is in the nature oi an improvement in the fireproofing treatment described in our copending applications #165,168, September 22, 1937, and #556,657 filed August 17, 1935.
- the primary 1 solution may be applied by brushing, by impregnation under pressure, or by impregnation by rst subjecting the material to be treated to a vacuum andthen applying the solution by dipping or brushing, etc.
- the invention furthermore particularly relates to a liquid dispersion deposited in the pores, or interstices of an absorbent material to be fireprooied, of one or more fire retarding agents which are soluble and deposited by evaporation of the solvent or to the deposit in the same location of insoluble derivatives of said agents deposited by the use of a second solution, as hereinafter described, the said deposit in each instance being effective mainly in combination with, and when covered by a main coat of a fireproof-Lug composition of the nature disclosed in said applications. This coating may effect partial impregnation with this material due to penetration.
- the primary solution, or priming solution is a water solution of one or more water soluble fireretarding agents. It is essential that it have a high degree of penetration, preferably containing a wetting agent for this purpose.
- a satisfactory priming solution is a water solution, containing 7% borax and 3% boric acid, and a wetting agent-various wetting agents being obtainable commercially.
- a sulphated ester of lauryl alcohol is a satisfactory wetting agent.
- the wetting agent may be 1 or 2% by weight or volume of the solution, or more, if desired.
- the various soluble borates may be substituted. Examples of these are: ammoni um borate, potassium borate.
- borates of ru bidium, caesium and lithium.
- the water soluble borates, phosphates, silicates, tungstates, and various ammonium salts, also soluble halides, such as those of ammonium and sodium, are also satisfactory for this purpose.
- metallic salts satisfactory for this purpose, which are water insoluble, but are soluble in organic solvents.
- these salts are: anhydrous antimony chloride.
- Some of the solvents which may be used for this purpose are: carbon tetra-chloride, ethyl acetate, and other similar solvents.
- An example of a solution of a water insoluble salt which may be used for this purpose is anhydrous antimony chloride SbCls. 30% was dissolved in carbon tetra chloride.
- casein, or other nitrogen containing organic compounds may be employed in this way; the following being examples of such solution:
- the material to be treated being impregnated with the primary solution, either by natural penetration, or absorption, or by pressure, or by first treating the material under vacuum, and then applying the solution to it, either by dipping, brushing or spraying, when the cloth, or wood to be treated is thus impregnated, the fire retarding agents are deposited by the gradual evaporation of the solvent, which is ordinarily water, but may be, under some circumstances, a volatile organic solvent forming a dispersion from a water or other solution of the tire retarding material, or in the interstices of the fabric or other product treated.
- the solvent which is ordinarily water, but may be, under some circumstances, a volatile organic solvent forming a dispersion from a water or other solution of the tire retarding material, or in the interstices of the fabric or other product treated.
- the deposit may, if desired, also be accomplished by the application of a second water solution containing chemicals adapted to precipitate the fire retarding agents held in the primary solution already described, particularly the water solutions.
- a second water solution containing chemicals adapted to precipitate the fire retarding agents held in the primary solution already described, particularly the water solutions.
- Such precipitates are in the form of fire retarding agents, having fire retarding properties, and if thus precipitated, would be insoluble in water.
- borax an initial treatment with a water solution of borax, or the equivalent, the borax, or any desired proportion of it, being rendered insoluble and thus precipitated by a subsequent treatment with a water solution of barium chloride, BaClz, or the equivalent.
- the borax solution may be in any desired proportion or concentrated up to the point of saturation, depending upon the desired quantity of the deposit which is, in turn, dependent upon the use to which the product is to be put. The heavier solutions will give the fire retarding effeet.
- the barium chloride used should to best advantage be the chemical equivalent of the borax first introduced. In this way, by the insolubilization any chance that the deposit may be removed 4 by wetting is eliminated.
- the fireproofing compositions of the above cited applications with the volatile solvent therein, suitably proportioned to adapt the composition for brushing, as disclosed in application #165,168, are good examples of fireproofing compositions adapted for use in the main treatment of wood and/or fabrics, which have been treated, as described; with a priming solution.
- the fireproofing composition may be applied by brushing, dipping or spraying.
- a composition which has been found satisfactory for this purpose contains approximately A, or 25% of approximately 60% chlorinated paraffin oil, or similary chlorinated parailin, or rubber.
- two or more chlorinated materials may be used in the same composition.
- 7% chlorinated rubber may be used with 18% chlorinated paraflin, or paraflin oil, the proportions being approximate, and other chlorinated materials being usable in place of chlorinated parafiin, or 10% of chlorinated rubber and or more percent of one or more of the other chlorinated materials will be satisfactory. The highest obtainable chlorination of these materials is desirable.
- Another ingredient is a plasticizer tri-cresyl phosphate, of which, for example, 5% is satisfactory. This may be considerably increased, 10% or even 15% being usable.
- a metal borate of which zinc borate is the most satisfactory, is also included, approximately 15% of this ingredient being employed, and the composition should also contain a pigment and filler, which, as used in the composition, comprises approximately A volatile solvent for the chlorinated material and plasticizer is necessary. This, introduced in suflicient proportions to .give the desired consistency, being regarded as satisfactory, and carbon tetra-chloride having been most generally used. The highest degree of chlorination obtainable, as to the various chlorinated materials, is satisfactory, 60% chlorination being generally regarded as suiiicient.
- solvents ester solvents such as ethyl acetate, chlorinated hydrocarbon solvent, or coal tar solvent, may be used.
- proportions of the formula are subject to main composition, or coating, may consist of a highly chlorinated material, thinned by means of a volatile solvent, or a mixture of these materials, as above suggested, used without the inert materials. fusible or otherwise, but this is mainly in circumstances where tackiness is unobjectionable, and the product is not exposed to the light or weather and less complete protection is desired.
- the main coating in combination with the impregnation with a liquid dispersion of fire retarding agent deposited in the material protected, by absorption of the solution containing this agent and later evaporation of the liquid, the main coating may be used in the form described or in any variation thereof, included within the above cited applications and under these circumstances the composition may be varied by the elimination of the borate, the chlorinated organic material being dissolved in a volatile solvent by which it is thinned to the desired consistency for coating, spraying or dipping.
- This coating composition normally includes a pigment, or filler, not essentially fusible, whereby the chlorinated material is protected from dechlorination.
- the plasticizer is desirable, if not essential, in effecting the adhesion of the composition and the ability to apply it, and in preserving the pliability of the material treated in case it is a fabric. Evaporation of the liquid in the priming solution may take place at any time, but trapping of the water in the material is not desirable.
- Another satisfactory composition contains al proximately 27% of 60% or more highly chlorinated paraffin, or the equivalent, 8 or 10% tricresyl phosphate, or equivalent plasticizer, 45 to 50% volatile solvent, which may be carbon tetrachloride, coal tar naphtha, or any of the known volatile solvents of the chlorinated materials and the plasticizers, 4 to 6% of zinc borate, for which equivalents may be substituted, and approximately 15% of pigment and filler.
- the materials composing the composition, or painting composition may be combined in any suitable order, the borate, pigment and filler being preferably pre-ground, or mixed, by passing through or grinding in a paint mill, the solvent as well as the other materials being preferably introduced before passing through the mill, though it is not necessary to introduce all solvent before grinding.
- the chlorinated material in any of the compositions named is combined in a satisfactory manner with the water, or the liquid dispersion of fire retarding ingredients contained in the pores or interstices of the materials treated, by first applying the primary solution by brushing, dipping or spraying, and then coating with the main coating, or treatment composition-4t being understood that the formula of the main coating composition may be varied from the proportions given in one formula to the proportions given in the other, and, to a reasonable extent, above and below these proportions.
- the main treatment composition, or coating which normally has a considerable degree of penetration, so that there is more or less impregnation due to this action, is subject to considerable variation in the proportions and selection of the ingredients.
- sufilcient solvent is used to give the desired consistency, the solids are combined in proportions which may be stated as follows: Highly chlorinated organic material 20 to 60%; borate, or other similarly fusible material, 4 to Pigment and filler, 12
- This composition both coats and impregnates, mingling with the water dispersion or solution of fire retarding materials resulting from the primary treatment.
- the new multiple process including priming by means of a. water or other liquid dispersion of a fire retarding chemical in the pores or interstices of the wood or fabric, together with a coating with or without partial impregnation with the highly chlorinated main coating, or treatment, gives an improved result in the way of fireproofing of wood, heavy duck, and the like, far in advance of any previously suggested.
- the materials thus treated can be destroyed by intense great, but will not support combustion at any
- the method of treating fibrous cellulosic materials, as wood, cotton fabrics and the like which consists in applying a primary treatment of a water solution of a water soluble fire retarding agent, and a wetting agent, which is absorbed by the material, the evaporation of the water forming a deposit of the fire retarding agent in the pores of the treated material, and, subsequently, coating the material by dispersion from a volatile solvent of a substantially 60% chlorinated organic substance, and a fire resisting water insoluble inert mineral solid in a finely divided form, including a low temperature fusible salt suspended in the chlorinated substance.
- the method of treating fibrous cellulose materials to give them fire resisting properties, and also water and mildew resisting properties which comprises impregnating them with a liquid solution containing fire retarding agents, drying the material, and thereby depositing these agents within the pores of the material, and thereafter coating the material with a dispersion from a volatile solvent of the highly chlorinated organic material containing in suspension therein a finely divided solid of fire resisting quality, which protects the chlorinated material from dechlorination.
- the method of treating fibrous cellulosic materials to give them fire, water and mildew resisting properties which comprises impregnating the material with a liquid solution containing fire retarding agents and drying the material thereby depositing the fire retarding agents within the pores of the material, and thereafter sealing the fire retarding agents within the material by coating the material being treated with a substantially 40% to chlorinated organic substance dissolved in a highly volatile solvent, said chlorinated substance containing in suspension a finely divided solid borate, which is substantially insoluble in water and which fuses and forms a fire retarding coating at the combustion temperatures of the cellulosic material being treated and a finely divided solid pigment of an opaque nature and a plasticizer; the chlorinated substance being selected from the group represented by chlorinated rubber, chlorinated paraffin oil, chlorinated vinyl resin, chlorinated tung oil, chlorinated soya, bean oil, chlorinated fish oil. said chlorinated substance being decomposed at the combustion temperatures of the cellulosic materials being treated giving 01! chlorine containing gases,
- the method of treating fibrous cellulosic materials to give them fire, water and mildew resisting properties which comprises impregnating them with a solution containing fire retarding agents and drying the materials thereby depositing these agents within the pores of the material and thereafter sealing the fire retarding agents within the pores of the material and imparting further fire, water and mildew resisting properties to said materials by coating said material with a substantially 40% to 60% chlorinated paraffln mixed with a similarly chlorinated rubber dissolved in a highly volatile solvent of said chlorinated materials the chlorinated materials containing mixed therein in finely divided form, a water insoluble borate which fuses at the combustion temperatures of the treated material, providing a coating which resists the creeping of fire, the chlorinated materials at similar temperatures giving ofi chlorine which prevents flaming, the chlorinated materials also containing mixed therein in finely divided solid form a water insoluble opaque pigment.
- the method of treating fibrous cellulosic materials to give them fire, water and mildew resisting properties which comprises impregnating the fibrous cellulosic materials with a liquid solution containing fire retarding agents, drying the materials being treated and thereby depositing the fire retarding agents within the pores of the treated material and thereafter coating and thereby sealing the said materials being treated with a composition containing approximately of substantially 40% to 60% chlorinated organic material consisting of chlorinated rutber and chlorinated parafiin, and a small percentage of plasticizer, the chlorinated material and plasticizer being dissolved in a highly volatile solvent of said materials and containing mixed therein in finely divided form about 15% of zinc borate and 25% of a water insoluble opaque pigment and a filler, the remainder being a solvent of the chlorinated materials which evaporates immediately at normal room temperatures.
Description
Patented Nov. 7, 1939 PATENT OFFICE FEEPROOFING TREATMENT AND COMPOSITION Edwin C. Clayton and Lawrence L. Hefiner, Baltimore, Md., assignors to Wm. E. Hooper & Sons Company, Baltimore, Md., a corporation of Maryland No Drawing. Application January i, 1938, [Serial No. 183,829
9 l ills,
The invention is in the nature oi an improvement in the fireproofing treatment described in our copending applications #165,168, September 22, 1937, and #556,657 filed August 17, 1935.
It relates to an initial, or primary, treatment to precede the application of the fire, water'and mildew proofing composition therein described, and to a multiple treatment consisting of one or more applications of a primary solution of water 10 soluble fire retarding agent, said solution possessing the property of penetration to a high degree, and one or more later applications of one of the compositions of said applications. The primary 1 solution may be applied by brushing, by impregnation under pressure, or by impregnation by rst subjecting the material to be treated to a vacuum andthen applying the solution by dipping or brushing, etc.
The invention furthermore particularly relates to a liquid dispersion deposited in the pores, or interstices of an absorbent material to be fireprooied, of one or more fire retarding agents which are soluble and deposited by evaporation of the solvent or to the deposit in the same location of insoluble derivatives of said agents deposited by the use of a second solution, as hereinafter described, the said deposit in each instance being effective mainly in combination with, and when covered by a main coat of a fireproof-Lug composition of the nature disclosed in said applications. This coating may effect partial impregnation with this material due to penetration. In this way a greatly improved result in the fireproofing of wood, particularly porous inflammable Wood, as wooden shingles, is attained, and the treatment of heavy grades of textiles, as the very heavy grades of cotton duck, is facilitated and rendered much more effective, and is further accomplished at less expense than by the single so process of said application. The unexpected ex= tent of the improvement accomplished has been demonstrated by actual tests. These tests were performed by burning shingles by means of a blow torch. They show the remarkable advance in efficiency gained by the improved treatment. For example, a raw cedar shingle subjected to the flame of a blow torch at eleven inches from the torch to the surface of the shingle, burns freely after twenty seconds exposure. A shingle paintfiil ed with ordinary commercial outside paint bursts into flame after six seconds of similar exposure; both shingles being completely consumed.
A shingle coated and impregnated to the degree of the ordinary absorption incident to brushing the fireproofing composition of the later application, subjected to the same test, emits a dance in ninety seconds, but the flame dies out in twenty-nine seconds after removal of the torch, there being no subsequent spread of combustion. With the torch advanced so that it is about one 5 inch from the shingle, the shingle burns in about eighty seconds, being charred in 15 seconds.
A shingle impregnated by absorption resulting from brushing with the primary solution of the invention, to be further described, and, subsequently treated with a main coat consisting of two brushings of the fireprooiing composition identified above, and slightly impregnated thereby, due to penetration by the composition, when subjected to the action of the torch flame, as in the first two tests above described, i. e., at eleven inches, after two minutes, is discolored, with no flame; in three minutes there is a slight flame, which goes out immediately. When the torch is moved up to within one inch from the shingle for go one-half minute, only the portion in direct contact with the flame, is charred, but is self-extinguished in thirty-one seconds after removal of the torch, the shingle not being destroyed or perforated. When the torch is held in the same position, about one inch from the shingle, for a further exposure of a half minute, the shingle is not destroyed or perforated, but is charred through its entire thickness. Further application of the flame perforates but does not kindle. A shingle treated with two brushings of the primary solution and one brush coat of the fireproofing composition shows signs of burning in forty-five seconds, with the torch at one inch, and is extinguished in twenty-five seconds after removal of the torch. Further exposure of the shingle for thirty seconds in the same way gives signs of burning, the flame being self-extinguished in twenty seconds after the removal of the torch, but in neither instance can the shingle be ignited so that combustion will continue after removal of the torch. By extended application at close range, it can be charred, and even perforated, but it does not support combustion, and does not flame when the torch is removed.
The primary solution, or priming solution, is a water solution of one or more water soluble fireretarding agents. It is essential that it have a high degree of penetration, preferably containing a wetting agent for this purpose. An example of a satisfactory priming solution is a water solution, containing 7% borax and 3% boric acid, and a wetting agent-various wetting agents being obtainable commercially. A sulphated ester of lauryl alcohol is a satisfactory wetting agent.
The wetting agent may be 1 or 2% by weight or volume of the solution, or more, if desired. Instead of the mixture of borax and boric acid above described, the various soluble borates may be substituted. Examples of these are: ammoni um borate, potassium borate. Theoretically, in addition to other equivalents available for this purpose, there are certain rare borates not commercially available which would otherwise be satisfactoryfor this purpose as: borates of ru: bidium, caesium and lithium. The water soluble borates, phosphates, silicates, tungstates, and various ammonium salts, also soluble halides, such as those of ammonium and sodium, are also satisfactory for this purpose.
There are also metallic salts satisfactory for this purpose, which are water insoluble, but are soluble in organic solvents. Examples of these salts are: anhydrous antimony chloride. Some of the solvents which may be used for this purpose are: carbon tetra-chloride, ethyl acetate, and other similar solvents.
The following are examples of solutions containing these salts which are satisfactory as primary solutions in the practice of the invention. These examples are numbered to distinguish them and not to indicate the order of pref erence:
1. A solution in water containing of 1% sulphated lauryl alcohol, 20% ammonium phosphate (NH4)2HPO4.
2. Substitute for ammonium phosphate, 20% sodium tungstate NazW4 21120.
3. Substitute for the ammonium phosphate, 20% sodium silicate NazSia.
4. Substitute 20% of ammonium bromide (NH4Br).
5. Substitute instead of the ammonium bromide 20% sodium fluoride NaF.
An example of a solution of a water insoluble salt which may be used for this purpose is anhydrous antimony chloride SbCls. 30% was dissolved in carbon tetra chloride.
It is also found that casein, or other nitrogen containing organic compounds may be employed in this way; the following being examples of such solution:
1. 10% borax, 5% casein, the balance water.
2. Approximately 5% sodium phosphate (Na:
P04) approx. 5% casein, approx. 5% sodium silicate (NazSiOa); approx. of 1% of gardinol, and approx. 84% water.
3. Approximately 7% sodium phosphate, approx. 5% ammonium chloride, approx. 5% ammonium sulphate, and approximately /2% Eardinol and 80% water.
4. Approximately borax, approx. 5% sodium fluoride, and approximately 84% water.
5. Approximately 8% ammonium bromide, approx. 2% ammonium carbonate, approx.'8% sodigum borate (NazBiOii approx. 3% boric acid (H3803) approximately 2% casein; sulphated lauryl alcohol approximately /2%, and approximately 76% water.
In the preferred practice of the invention, the material to be treated being impregnated with the primary solution, either by natural penetration, or absorption, or by pressure, or by first treating the material under vacuum, and then applying the solution to it, either by dipping, brushing or spraying, when the cloth, or wood to be treated is thus impregnated, the fire retarding agents are deposited by the gradual evaporation of the solvent, which is ordinarily water, but may be, under some circumstances, a volatile organic solvent forming a dispersion from a water or other solution of the tire retarding material, or in the interstices of the fabric or other product treated. The deposit may, if desired, also be accomplished by the application of a second water solution containing chemicals adapted to precipitate the fire retarding agents held in the primary solution already described, particularly the water solutions. Such precipitates are in the form of fire retarding agents, having fire retarding properties, and if thus precipitated, would be insoluble in water.
An example of this action is an initial treatment with a water solution of borax, or the equivalent, the borax, or any desired proportion of it, being rendered insoluble and thus precipitated by a subsequent treatment with a water solution of barium chloride, BaClz, or the equivalent. The borax solution may be in any desired proportion or concentrated up to the point of saturation, depending upon the desired quantity of the deposit which is, in turn, dependent upon the use to which the product is to be put. The heavier solutions will give the fire retarding effeet. The barium chloride used should to best advantage be the chemical equivalent of the borax first introduced. In this way, by the insolubilization any chance that the deposit may be removed 4 by wetting is eliminated.
The fireproofing compositions of the above cited applications with the volatile solvent therein, suitably proportioned to adapt the composition for brushing, as disclosed in application #165,168, are good examples of fireproofing compositions adapted for use in the main treatment of wood and/or fabrics, which have been treated, as described; with a priming solution. The fireproofing composition may be applied by brushing, dipping or spraying.
A composition which has been found satisfactory for this purpose contains approximately A, or 25% of approximately 60% chlorinated paraffin oil, or similary chlorinated parailin, or rubber. In any of the formulas to be given, two or more chlorinated materials may be used in the same composition. For example: 7% chlorinated rubber may be used with 18% chlorinated paraflin, or paraflin oil, the proportions being approximate, and other chlorinated materials being usable in place of chlorinated parafiin, or 10% of chlorinated rubber and or more percent of one or more of the other chlorinated materials will be satisfactory. The highest obtainable chlorination of these materials is desirable.
Another ingredient is a plasticizer tri-cresyl phosphate, of which, for example, 5% is satisfactory. This may be considerably increased, 10% or even 15% being usable. A metal borate, of which zinc borate is the most satisfactory, is also included, approximately 15% of this ingredient being employed, and the composition should also contain a pigment and filler, which, as used in the composition, comprises approximately A volatile solvent for the chlorinated material and plasticizer is necessary. This, introduced in suflicient proportions to .give the desired consistency, being regarded as satisfactory, and carbon tetra-chloride having been most generally used. The highest degree of chlorination obtainable, as to the various chlorinated materials, is satisfactory, 60% chlorination being generally regarded as suiiicient. As solvents ester solvents, such as ethyl acetate, chlorinated hydrocarbon solvent, or coal tar solvent, may be used.
The proportions of the formula are subject to main composition, or coating, may consist of a highly chlorinated material, thinned by means of a volatile solvent, or a mixture of these materials, as above suggested, used without the inert materials. fusible or otherwise, but this is mainly in circumstances where tackiness is unobjectionable, and the product is not exposed to the light or weather and less complete protection is desired.
When the painting composition is used, as a main coating, in combination with the impregnation with a liquid dispersion of fire retarding agent deposited in the material protected, by absorption of the solution containing this agent and later evaporation of the liquid, the main coating may be used in the form described or in any variation thereof, included within the above cited applications and under these circumstances the composition may be varied by the elimination of the borate, the chlorinated organic material being dissolved in a volatile solvent by which it is thinned to the desired consistency for coating, spraying or dipping. This coating composition normally includes a pigment, or filler, not essentially fusible, whereby the chlorinated material is protected from dechlorination. The plasticizer is desirable, if not essential, in effecting the adhesion of the composition and the ability to apply it, and in preserving the pliability of the material treated in case it is a fabric. Evaporation of the liquid in the priming solution may take place at any time, but trapping of the water in the material is not desirable.
Another satisfactory composition contains al proximately 27% of 60% or more highly chlorinated paraffin, or the equivalent, 8 or 10% tricresyl phosphate, or equivalent plasticizer, 45 to 50% volatile solvent, which may be carbon tetrachloride, coal tar naphtha, or any of the known volatile solvents of the chlorinated materials and the plasticizers, 4 to 6% of zinc borate, for which equivalents may be substituted, and approximately 15% of pigment and filler.
The materials composing the composition, or painting composition, may be combined in any suitable order, the borate, pigment and filler being preferably pre-ground, or mixed, by passing through or grinding in a paint mill, the solvent as well as the other materials being preferably introduced before passing through the mill, though it is not necessary to introduce all solvent before grinding.
The chlorinated material in any of the compositions named is combined in a satisfactory manner with the water, or the liquid dispersion of fire retarding ingredients contained in the pores or interstices of the materials treated, by first applying the primary solution by brushing, dipping or spraying, and then coating with the main coating, or treatment composition-4t being understood that the formula of the main coating composition may be varied from the proportions given in one formula to the proportions given in the other, and, to a reasonable extent, above and below these proportions.
The main treatment composition, or coating, which normally has a considerable degree of penetration, so that there is more or less impregnation due to this action, is subject to considerable variation in the proportions and selection of the ingredients. It being understood that sufilcient solvent is used to give the desired consistency, the solids are combined in proportions which may be stated as follows: Highly chlorinated organic material 20 to 60%; borate, or other similarly fusible material, 4 to Pigment and filler, 12
to 45%; Dlasticizer, 12 to 25%. This composition both coats and impregnates, mingling with the water dispersion or solution of fire retarding materials resulting from the primary treatment.
The new multiple process, including priming by means of a. water or other liquid dispersion of a fire retarding chemical in the pores or interstices of the wood or fabric, together with a coating with or without partial impregnation with the highly chlorinated main coating, or treatment, gives an improved result in the way of fireproofing of wood, heavy duck, and the like, far in advance of any previously suggested. The materials thus treated can be destroyed by intense great, but will not support combustion at any We have thus described a fireproofing treatment embodying our invention, the description being specific and in detail in order that the invention, and the means of applying and using the same, may be fully understood; however, the specific terms herein are used descriptively rather than in a limiting sense.
What we claim and desire to secure by Letters Patent is:
l. The method of treating fibrous cellulosic materials, as wood, cotton fabrics and the like, which consists in applying a primary treatment of a water solution of a water soluble fire retarding agent, and a wetting agent, which is absorbed by the material, the evaporation of the water forming a deposit of the fire retarding agent in the pores of the treated material, and, subsequently, coating the material by dispersion from a volatile solvent of a substantially 60% chlorinated organic substance, and a fire resisting water insoluble inert mineral solid in a finely divided form, including a low temperature fusible salt suspended in the chlorinated substance.
2. The method of treating fibrous cellulose materials to give them fire resisting properties, and also water and mildew resisting properties which comprises impregnating them with a liquid solution containing fire retarding agents, drying the material, and thereby depositing these agents within the pores of the material, and thereafter coating the material with a dispersion from a volatile solvent of the highly chlorinated organic material containing in suspension therein a finely divided solid of fire resisting quality, which protects the chlorinated material from dechlorination.
3. The method of treating fibrous cellulosic materials to give them fire, water and mildew resisting properties which comprises impregnating the material with a liquid solution containing fire retarding agents and drying the material thereby depositing the fire retarding agents within the pores of the material, and thereafter sealing the fire retarding agents within the material by coating the material being treated with a substantially 40% to chlorinated organic substance dissolved in a highly volatile solvent, said chlorinated substance containing in suspension a finely divided solid borate, which is substantially insoluble in water and which fuses and forms a fire retarding coating at the combustion temperatures of the cellulosic material being treated and a finely divided solid pigment of an opaque nature and a plasticizer; the chlorinated substance being selected from the group represented by chlorinated rubber, chlorinated paraffin oil, chlorinated vinyl resin, chlorinated tung oil, chlorinated soya, bean oil, chlorinated fish oil. said chlorinated substance being decomposed at the combustion temperatures of the cellulosic materials being treated giving 01! chlorine containing gases, said chlorinated material being solid or semi-solid at normal room temperatures and the volatile solvent being quickly evaporated at such temperatures.
4. The fire, water and mildew resisting fibrous cellulosic materials having substantially the properties of the product resulting from treatment by the process of claim 3.
5. The method of treating fibrous cellulosic materials to give them fire, water and mildew resisting properties which comprises impregnating them with a solution containing fire retarding agents and drying the materials thereby depositing these agents within the pores of the material and thereafter sealing the fire retarding agents within the pores of the material and imparting further fire, water and mildew resisting properties to said materials by coating said material with a substantially 40% to 60% chlorinated paraffln mixed with a similarly chlorinated rubber dissolved in a highly volatile solvent of said chlorinated materials the chlorinated materials containing mixed therein in finely divided form, a water insoluble borate which fuses at the combustion temperatures of the treated material, providing a coating which resists the creeping of fire, the chlorinated materials at similar temperatures giving ofi chlorine which prevents flaming, the chlorinated materials also containing mixed therein in finely divided solid form a water insoluble opaque pigment.
6. The fire, water and mildew resisting fibrous cellulosic materials having substantially the properties of the product resulting from the treatment by the process of claim 5.
7. The method of treating fibrous cellulosic materials to give them fire, water and mildew resisting properties which comprises impregnating the fibrous cellulosic materials with a liquid solution containing fire retarding agents, drying the materials being treated and thereby depositing the fire retarding agents within the pores of the treated material and thereafter coating and thereby sealing the said materials being treated with a composition containing approximately of substantially 40% to 60% chlorinated organic material consisting of chlorinated rutber and chlorinated parafiin, and a small percentage of plasticizer, the chlorinated material and plasticizer being dissolved in a highly volatile solvent of said materials and containing mixed therein in finely divided form about 15% of zinc borate and 25% of a water insoluble opaque pigment and a filler, the remainder being a solvent of the chlorinated materials which evaporates immediately at normal room temperatures.
8. The fire, water and mildew resisting fibrous cellulosic material, having substantially the properties of the product resulting from treatment by the process of claim 7.
9. The fire, water and mildew resisting fibrous cellulosic material, having substantially the properties of the product resulting from treatment by the process of claim 2.
EDWIN C. CLAYTON. LAWRENCE L. HEFFNER.
Priority Applications (1)
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US18382938 US2178625A (en) | 1938-01-07 | 1938-01-07 | Fireproofing treatment and composition |
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US18382938 US2178625A (en) | 1938-01-07 | 1938-01-07 | Fireproofing treatment and composition |
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US2178625A true US2178625A (en) | 1939-11-07 |
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US18382938 Expired - Lifetime US2178625A (en) | 1938-01-07 | 1938-01-07 | Fireproofing treatment and composition |
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Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2519388A (en) * | 1948-12-09 | 1950-08-22 | American Cyanamid Co | Treatment of fibrous cellulosic materials to impart flame resistance thereto, compositions therefor, and products thereof |
US2520103A (en) * | 1949-02-15 | 1950-08-22 | American Cyanamid Co | Method of treating fibrous cellulosic materials to impart flame resistance thereto, compositions therefor, and products thereof |
US2536978A (en) * | 1949-12-07 | 1951-01-02 | American Cyanamid Co | Oil-in-water type emulsion for flameproofing fabrics |
US2536988A (en) * | 1949-12-07 | 1951-01-02 | American Cyanamid Co | Flame resistant and mildew resistant composition for cellulose fibers and fabrics |
US2553781A (en) * | 1950-04-14 | 1951-05-22 | Lockport Cotton Batting Co | Flame resistant cellulose fibrous materials and method of making same |
US2557993A (en) * | 1948-07-30 | 1951-06-26 | Lockport Cotton Batting Co | Process of removing mineral oil from vegetable fibers |
US2640000A (en) * | 1947-06-07 | 1953-05-26 | Diamond Alkali Co | Flameproofing method and product |
US2867549A (en) * | 1956-03-06 | 1959-01-06 | Albemarle Paper Mfg Company | Process for flameproofing paper |
DE971399C (en) * | 1949-07-06 | 1959-01-22 | Hoechst Ag | Wood preservative for wet woods |
US2884343A (en) * | 1954-08-12 | 1959-04-28 | Thermoid Company | Flame and heat resistant asbestos textile base material |
US2948641A (en) * | 1957-07-22 | 1960-08-09 | Thermoid Company | Flame retarding composition and fabric treated therewith |
US3897387A (en) * | 1973-05-23 | 1975-07-29 | Shaughnessy James D O | Fire retardant agent |
US3944688A (en) * | 1973-10-23 | 1976-03-16 | Pennwalt Corporation | Method for the manufacture of water-repellent, fire-resistant nonwoven fabrics |
USRE30193E (en) * | 1973-05-23 | 1980-01-15 | Fire retardant agent | |
US5391246A (en) * | 1991-12-09 | 1995-02-21 | Stephens; William G. | Fire prevention in the application of roofing |
US7752775B2 (en) | 2000-03-10 | 2010-07-13 | Lyden Robert M | Footwear with removable lasting board and cleats |
-
1938
- 1938-01-07 US US18382938 patent/US2178625A/en not_active Expired - Lifetime
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2640000A (en) * | 1947-06-07 | 1953-05-26 | Diamond Alkali Co | Flameproofing method and product |
US2557993A (en) * | 1948-07-30 | 1951-06-26 | Lockport Cotton Batting Co | Process of removing mineral oil from vegetable fibers |
US2519388A (en) * | 1948-12-09 | 1950-08-22 | American Cyanamid Co | Treatment of fibrous cellulosic materials to impart flame resistance thereto, compositions therefor, and products thereof |
US2520103A (en) * | 1949-02-15 | 1950-08-22 | American Cyanamid Co | Method of treating fibrous cellulosic materials to impart flame resistance thereto, compositions therefor, and products thereof |
DE971399C (en) * | 1949-07-06 | 1959-01-22 | Hoechst Ag | Wood preservative for wet woods |
US2536978A (en) * | 1949-12-07 | 1951-01-02 | American Cyanamid Co | Oil-in-water type emulsion for flameproofing fabrics |
US2536988A (en) * | 1949-12-07 | 1951-01-02 | American Cyanamid Co | Flame resistant and mildew resistant composition for cellulose fibers and fabrics |
US2553781A (en) * | 1950-04-14 | 1951-05-22 | Lockport Cotton Batting Co | Flame resistant cellulose fibrous materials and method of making same |
US2884343A (en) * | 1954-08-12 | 1959-04-28 | Thermoid Company | Flame and heat resistant asbestos textile base material |
US2867549A (en) * | 1956-03-06 | 1959-01-06 | Albemarle Paper Mfg Company | Process for flameproofing paper |
US2948641A (en) * | 1957-07-22 | 1960-08-09 | Thermoid Company | Flame retarding composition and fabric treated therewith |
US3897387A (en) * | 1973-05-23 | 1975-07-29 | Shaughnessy James D O | Fire retardant agent |
USRE30193E (en) * | 1973-05-23 | 1980-01-15 | Fire retardant agent | |
US3944688A (en) * | 1973-10-23 | 1976-03-16 | Pennwalt Corporation | Method for the manufacture of water-repellent, fire-resistant nonwoven fabrics |
US5391246A (en) * | 1991-12-09 | 1995-02-21 | Stephens; William G. | Fire prevention in the application of roofing |
US7752775B2 (en) | 2000-03-10 | 2010-07-13 | Lyden Robert M | Footwear with removable lasting board and cleats |
US8209883B2 (en) | 2000-03-10 | 2012-07-03 | Robert Michael Lyden | Custom article of footwear and method of making the same |
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