US2177086A

US2177086A - Etching process

Info

Publication number: US2177086A
Application number: US134727A
Authority: US
Inventors: Joseph S Williams
Original assignee: PR Mallory and Co Inc
Current assignee: Duracell Inc USA
Priority date: 1936-02-15
Filing date: 1937-04-03
Publication date: 1939-10-24
Anticipated expiration: 1956-10-24

Description

Oct. 24, 1939. J. 5. WILLIAMS ETCHING PROCESS Original Filed Feb; 15, 1956 2 Sheets-Sheet l INVENTOR- Ja; 5: M'Jliams A TTORNEYS.

Oct. 24, 1939. J. s. WILLIAMS ETCHING PROCES S Original Filed Feb. 15, 1936 2 Sheets-Sheet 2 INVENTOR. J d' nA J: M'j/jam J A TTORNEYS.

Patented Oct. 24, 1939 ETCHING PROCESS Joseph S. Williams, Indianapolis, Ind., assignor to P. R. Mallory a; 00., Inc., Indianapolis, Ind., a corporation of Delaware Original application February 15, 1936, Serial No.

64,012. Divided and this application April 3,

1937, Serial No. 134,727

6 Claims.

This invention relates to methods of etching electrodes for electrolytic condensers and the like.

The present application is a division of my copending application, Serial Number 64,012, filed 5 February 15, 1936, now Patent No. 2,091,576, for

an Improvement in etched electrodes.

An object of the invention is to improve the methods of etching electrodes.

Other objects of the invention will be apparent l drawings taken in connection with the appended claims.

The invention comprises the features of construction, combination of elements, arrangement of parts, and methods of manufacture and operation referred to above or which will be brought out and exemplified in the disclosure hereinafter set forth, including the illustrations in the drawings, the scope of the invention being indicated in the appended claims.

"For a fuller understanding of the nature and objects of the invention as well as for specific fulfillment thereof, reference should be had to the following detailed description taken in connection with the accompanying drawings, in which:

Figure 1 is a face view of a section of an etched electrode arranged according to one form of the invention;

Figure 2 indicates a slightly different construction; Figure 3 is a face view of a narrower electrode; Figure 4 shows a modified form of electrode;

Figure 5 shows a further modification;

Figure 6 represents a still further modification;

Figure 7 is a section of a condenser; and

Figure 8 illustrates an apparatus for etching the electrodes according to the present invention.

While a preferred embodiment of the invention is described herein, it is contemplated that considerable variation may be made in the method of procedure and the construction of parts without departing from the spirit of the invention. In the following description and in the claims, parts will be identified by specific names for convenience, but they are intended to be as generic in their application to similar parts as the art will permit.

Electrodes for electrolytic devices are sometimes etched' to increase their effective surface area. In the case of electrolytic condenser electrodes this materially increases the capacity obtainable per unit area of electrode surface.

In dry electrolytic condensers the electrodes are usually made of thin aluminum foil and are profrom the following description and accompanyingvided with terminals either secured to the foil or comprisingtabs forming an integral part of the electrode foil. It has been found that the etching operation, while materially increasing the capacity, results in a certain amount of weakening of the electrode foil. This weakening, resulting from the reduction in cross section and from increased embrittlement of the foil, renders the tab connections less secure and more liable to failure.

According to one aspect of the present invention selected areas of the electrode are etched to obtain increased effective surface while other areas are left unetched to provide greater strength.

Referring to the drawings, Figure 1 shows a length of etched foil having etched sections In adapted to provide areas of enhanced capacity in the completedcondenser and having unetched strips ll extending across the foil at intervals. Strips ll may be completely unetched, in which case their surfaces may appear the same as that of the original unetched foil, or the strips ll may also be etched, but in a reduced degree, so that they present higher strength than the portions Hi. It is preferred that both faces of the foil be treated similarly so that the difference in regions l0 and l I will also be present on the opposite face.

In using the etched foil for an electrode in a dry electrolytic condenser it may be cut into suitable lengths so as to include one or more of the sections II for the terminal connections. The terminals may be applied to sections ll either before or after cutting the foil into electrode lengths. They may comprise metal strips or wires attached to the foil, for instance in the manner set forth in H. F. Fruth Patent No. 2,020,408 on a Condenser foil terminal, or they may comprise tabs formed directly from the electrode metal itself. These tabs may be formed in one of the ways commonly used in the prior art or they may be formed as indicated in the various figures.

In Figure 1, for example, the tab I2 is formed by cutting a U-shaped slit in one of the sections H and folding out the tab so as to leave an aperture having its edges I3 bounded by the foil. This novel tab, as well as those shown in Figures 2, 5 and 6, is covered in a co-pending application of Omar L. Fluharty, Serial No. 64,052, filed February 15, 1936.

Figure 2 shows an etched foil 20 having unetched sections 2| and indicates how an improved tab 22 can be formed by cutting or punching at 23 so that the entire tab is surrounded by unetched foil.

Figure 3 shows a length of foil having etched sections 30 and long unetched sections 8|. It is also indicated how a folded tab 32 may be formed by folding one of the sections 3| diagonally at 33 and refolding two or three more times as at 34 to give a tab of suitable width.

Figure 4 shows a foil having an etched surface 40 with unetched sections 4! along one edge at intervals. It is also indicated in this figure how a tab 42 can be formed by cutting along two edges 44 of the section 4i and folding diagonally at 43.

Figure 5 shows a foil having etched sections 50 and an unetched section 5| diagonally across the electrode. A tab may be provided by making a U-shaped cut at 53 and folding the tab out as indicated by 52.

In Figure 6 an unetched section BI is left in the etched surface 60 of such shape as to suitably form a tab 62 when a cut is made around the edges.

Figure 7 shows a dry electrolytic condenser comprising a container 63 in which a condenser section 65 is enclosed, the section 65 comprising a pair of etched foils having unetched or partially etched sections for terminals as shown in the previous figures. The foil electrodes are spaced from each other and include between them an electrolyte adapted to maintain a currentblocking film thereon. At least one of the elec trodes may preferably be film-formed before assembly. Condenser section 65 is embedded in pitch 64. A cover 68 is provided on container 63 and a pair of terminals 66a and 61a project therethrough. Tabs 66 and El are connected to the two electrodes, respectively, in one of the ways indicated in the preceding figures and are secured, respectively, to terminals 66a and Ella.

In order to prevent the attack of the foil sections selected for tabs during etching of the rest of the foil the sections may be kept from dipping into the etching bath or they may be treated or immunized to prevent or impede the attack of the etching medium. This may be done, for ex-- ample, by coating the sections with a layer of paraffin or other immunizing substance, covering with a layer of paper or other sheet material adapted to retard etching action or by forming an integral film on the surface in a manner similar to that used in "anodising" or in film-forming the electrodes of electrolytic con-' densers. It has also been found that etching can be inhibited by drying the foil section in air between the cleaning and etching steps.

Figure 8 shows a continuous process galvanic etching apparatus similar to that set forth in J. M. Booe Patentv 2,052,962 for Process of etching, but having added means for immunizing predetermined sections of the foil to the etching medium. As indicated in this figure unetched foil H is unwound from roll 10 and passes through a cleaning solution 12, such as caustic, in tank 13, the foil being guided by roller 14. On emerging from the cleaning solution the foil passes over roller 15 and into a tank 11 of wash water 16 guided by roller I8.

The foil then passes up over rollers 19 and and then down into another tank 93 of wash water 92, guided by roller 94. An apparatus 8| is provided between rollers 19 and 80 for immunizing the predetermined sections which are to remain unetched.

Immunizing apparatus 8| comprises a pair of

felt rollers

82 and 83 saturated with a suitable material for immunizing the foil. Roller 82 is supported on a lever arm 84 pivoted at 85 and provided with a small roller 86 adapted to ride on a cam 81.

Cam 8'! is driven by bevel gears 88 which are, in turn, driven by the driving means 88 which also draws the foil through the apparatus. An adjustable speed regulator is provided between drive means 89 and bevel gears 88 so that the speed of the cam 81 can be controlled to give any desired spacing between the unetched sec-, tions. The regulator 90 may also provide for variable speed during each revolution of the cam to give. any desired length to the immunized sections.

If it is desired to form an anodized film on the foil for immunization the

rollers

82 and 83 may be saturated with a film-forming electrolyte, such as a solution of borax and boric acid. A D. C. generator 9! has one terminal connected to the foil ll through roller 19 and the other terminal connected to the metal hubs of

rollers

82 and 83, the foil being connected to the positive terminal.

In operation the cam 81 presses roller 82 down onto the foil H at predetermined intervals, the foil being displaced sufiiciently to make contact also with roller 83. The sections of foil contac-ted by

rollers

82 and 83 will become filmed with a thin layer which will prevent any substantial etching of these sections.

After having the predetermined sections inrmunized and passing through the second tank of wash water the foil is led up over roller and then passes through etching tank 9'! having an etching bath 96 therein. The foil passes between a pair of screens, one screen 99 being carried by three rollers lull, I M and I02 and the other being mounted on the periphery of large roller 98. The etching bath, in co-operation with the screens causes an etching of the untreated areas of the foil surface but the immunized sections remain unattached, or substantially so.

' Upon leaving the etching tank the foil passes over roller I03 and through wash water M4 in tank H15 and wash water M8 in tank I09, guided by rollers I06, I01, H0 and Hi. The foil is then wound onto roll H2, the mandrel therefor being driven by drive means 89 through bevel gears H3 and H4.

Instead of using a forming solution on rollers- 82 and 83 they can be heated and soaked in melted paraffin for coating onto the foil. In this case generator 9| will not be required. Etching can also be inhibited by covering sections of the foil with strips of paper which will separate the foil and the wire screens.

While the present invention, as to its objects and advantages, has been described herein as carried out in specific embodiments thereof, it is not desired to be limited thereby but it is intended to cover the invention broadly within the spirit and scope of the appended claims.

What is claimed is:

1. The method of preparing electrodes for electrolytic devices which comprises immunizing a predetermined section of an electrode metal surface to etching action, exposing the metal surface to an etching medium so as to etch the portions of said surface which have not been imthe unprotected areas and then forming an electrode terminal out of the unetched portions.

3. The method of preparing electrodes of film forming metal which comprises forming a pro tective film on a predetermined section of the surface of said metal, then exposing the surface to an etching medium and then forming an electrode terminal out of the unetched portions.

4. The method of preparing electrodes of metal foil for electrolytic devices which comprises immunizing areas of said foil to etching action, then immersing said foil in an etching bath and then forming an electrode terminal out of the unetched portions.

5. The method of preparing electrodes of aluminum foil which comprises immunizing predetermined areas of said foil to embrittlement resulting from etching, then immersingthe foil in an etching bath and then forming an electrode terminal out of the unetched portions.

6. The method of preparing electrodes for dryelectrolytic condensers which comprises passing a continuous strip of foil of film-forming metal through a first position, immunizing uniformly spaced areas of said foil as it passes through said position and then passing said foil through an etching bath adapted to etch said foil where it is not immunized, and then forming an electrode terminal within the immunized portion of said foiL' JOSEPH S. WILLIAMS.