US2161970A - Lubricant - Google Patents
Lubricant Download PDFInfo
- Publication number
- US2161970A US2161970A US118921A US11892137A US2161970A US 2161970 A US2161970 A US 2161970A US 118921 A US118921 A US 118921A US 11892137 A US11892137 A US 11892137A US 2161970 A US2161970 A US 2161970A
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- sulfur
- lead
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/043—Sulfur; Selenenium; Tellurium
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/108—Residual fractions, e.g. bright stocks
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
Definitions
- This invention relates to an improved lubricant, more specifically to a lubricant of the type adapted for carrying extremely heavy loads such as are encountered in automotive transmission equipment and other similar heavy duty devices.
- the invention will be fully understood from the following description.
- oils of this range cannot at present be used for making lead compounds.
- Almost all of the present leaded compounds on the contrary show viscosity indices of 50 or below, but it is the object of the present invention to produce oils of at least V. I. and adapted to transmission service.
- oils with viscosity indices above may be used for the present invention, such as are'obtained in synthetic oils prepared by condensation of cracked waxes in presence or absence of aromatic hydrocarbons.
- active leaded compounds with viscosity indices equal to or better than those of Pennsylvania oils can be made using lead oleate, stearate or other fatty acids of which the oleate is at the present time the cheapest and most convenient of the lead compounds, if a suflicient amount of a second or a solubilizing compound is present.
- solubilizing compounds are noted the naphthenic compounds, which are compounds of acids found naturally occurring in certain oils such as those obtained from Russia, Roumania, California and some of the Gulf Coast oils.
- Another class of solubilizing compound is the sulfonic type which other salts of the oleate and sulfonate, for
- solubilized ingredients that is to say, the relation of the solubilizing 25 materials to the normal oleates is not clearly understood, but it is believed that a double salt probably results especially in the case where the acids or their sodium salts are mixed and reaction with a lead compound is then conducted, but it should be understood that the present invention is not to be limited to that particular method of preparation.
- the relative proportions of the lead oleate or other insoluble compound and the solubilizing compound may vary within limits and the most favorable proportion depends on the particular base stockused. In general, if base stocks of higher viscosity index are employed, it is desirable to increase the proportion of the naphthenic or sulfonic solubilizing agent in proportion to the amount of the suitable lead salt.
- the two compounds may be used in proportion of one-third to one part of the solubilizing agent to one part of the lead oleate.
- lead salts are prepared separately and then mixed, it is preferable to use more of the solubilizing agent than where the acids or their sodium salts are mixed and then cooked with litharge or some inorganic lead salt which presumably produces the double salt.
- the final composition should contain from 5 to 20% of the lead compound.
- the base stock used is preferably a heavy residual, for example, a bright stock or a cylinder oil. Pennsylvania or equivalent oils which have .been raised to that grade by solvent extraction, hydrogenation,
- Another ingredient of the present composition is the sulfur, by which is meant freesulfur or organic sulfur, preferably in a corrosive form .and by this latter term it is intended to include free sulfur and those oil soluble compounds of sulfur which will discolor a bright copper strip which is immersed therein. It is not necessary to use vigorously corrosive compounds such as will corrode metal gears or containers. If a base stock should contain an effective quantity of sulfur no more need be added, but insofar as applicants are aware, none of the predominantly parafllnic crudes contain a sufllcient quantity of sulfur'and furthermore such sulfur as is present is non-corrosive so that it is in all cases desirable to add "corrosive sulfur.”
- the corrosive" compounds should be sufficiently high boiling so as not to be lost by evaporation, and some crude oils contain relatively large amounts of such compounds in natural form, particularly those oils obtained from the West Texas fields. Cuts derived from such crudes rich in sulfur may be added to the base stocks so as to obtain a proper amount of corrosive sulfur. Pure compounds may also be used, for example, high molecular weight mercaptans, polysulildes-preferably the trisulfide or higher and the like, as well as free sulfur itself which may be added in small amounts. Olefines, for example obtained from cracked wax, or vegetable, mineral and marine oils, may also be sulfurized by cooking with free sulfur or sulfur chloride and sulfurized terpenes are also employed.
- the necessary amount of corrosive sulfur is from .3 ,to 1.0% depending on the service and should be determined by the difference between total sulfur before and after heating with a finely divided metal such as copper which gives the amount of truly corrosive sulfur. More corrosive sulfur'may be added if desired say up to 3 or even 5% but this shows] little advantage over 1 or 1.5%.
- Non-corrosive sulfur is not nearly so effective for the present purpose as the corrosive" variety and in providing the proper amount of corrosive sulfur only that portion which is truly "corrosive should be taken into account. It will be understood that corrosive selenium and tellurium compounds may be used along with or in place of the sulfur.
- Example 1 To parts by weight of a base stock of sec. Saybolt viscosity at 21051". and 100 .V. 1., is added 11 parts of a mixture of lead o'leate and lead naphthenate in equal proportions. To this is added 6% of a sulfurized pine oil, 5% of The final ,rn'ixture is;the fol- Gravity 20.2
- Example 2 To the base oil used in Example 1 is added 10 parts of a compounding agent made by adding sodium oleate and sodium sulfonate in weight proportion of 2 to 1 and precipitating the lead compound with an excess of lead acetate. About 30% of a sulfur compound made by heating 2 parts of chlorinated paraflln wax (25% Cl.) with 1 part of sodium polysulfide is then added. The sulfur compound should have an analysis of 2.4% total sulfur and .75% corrosive sulfur.
- a compounding agent made by adding sodium oleate and sodium sulfonate in weight proportion of 2 to 1 and precipitating the lead compound with an excess of lead acetate.
- a sulfur compound made by heating 2 parts of chlorinated paraflln wax (25% Cl.) with 1 part of sodium polysulfide is then added.
- the sulfur compound should have an analysis of 2.4% total sulfur and .75% corrosive sulfur.
- the finished oil was stable and had a viscosity index of substantially 100.
- the present invention is not to be limited to any theory of the extreme pressure characteristics nor to the causes or effect of the solubilizing agents, nor to any particular solubilizing agents,
- An improved lubricatingoilfor extreme pressure service comprising a lubricating oil base characterized by a viscosity index of at least 80 and a viscosity above 75 sec. Saybolt at 210 F., a lead salt of a higher fatty acid normally insoluble in the oil and a solubilizing agent therefor in proportion of about to 1 part per part of the lead salt, selected from'the group consisting of sulfonic and naphthenic acids, and their heavy metal salts, the lead salt amounting to 5 to 20% ofthe final composition and a sulphur compound in quantity sufficient to furnish .3 to 3.0% of corrosive sulphur.
- An improved lubricating oil for extreme pressure service comprising a heavy viscous hydrocarbon lubricating oil base characterized by a viscosity index of at least 80 and enterprisecosity of above 75 seconds Saybolt at 210 F., lead oleate and a solubilizing compound therefor in propordrocarbon lubricating oil base characterized by a a viscosity index of at least 80 and a viscosity of above seconds Saybolt at 210 F., lead oleate and a ,solubilizing compound therefor in proportion from to 1 part per part of lead oleate selected from the group consisting of sulfonic and naphthenic acids and theirgheavy metal salts,
- the lead compound amounting to 5 to 20% of the final composition and a sulfur compound sumcient to furnish from 0.3 to 1.0% of corrosive" sulfur.
- An improved lubricating oil for extreme pressure service comprising a heavy viscous hydro; carbon lubricating oil base characterized by a viscosity index between about and and a viscosity of above 75seconds Saybolt at 210 F., lead oleate and a solubilizing compound therefor in proportion from $4, to 1 part per part of lead oleate selected from the group consisting of sulfonic and naphthenic acids and their heavy metal salts, the lead compound amounting to 5 to 20% of the final composition and a sulfur compound sufficient to furnish from 0.3 to 5% of corrosive sulfur.
- An improved lubricating oil for extreme pressure service comprising a heavy viscous hydrocarbon lubricating oil base characterized by a viscosity index between about 80 and 100 and a viscosity of above 75 seconds Saybolt at 210 F., lead oleate and a solubilizing compound therefor in proportion from 5 to 1 part per part of lead oleate selected from the group consisting of sulfonic and naphthenic acids and their heavy metal of the final composition and a sulfur compound suflicient to furnish from 0.3 to 1.0% of "corrosive sulfur.
- the lead compound amounting to 5 to 20%
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- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
Patented June 13, 1939 UNITED STATES- PATENT OFFICE LUBRICANT" Delaware No Drawing. Application January 2, 1937, Serial No. 118,921
5 Claims.
This invention relates to an improved lubricant, more specifically to a lubricant of the type adapted for carrying extremely heavy loads such as are encountered in automotive transmission equipment and other similar heavy duty devices. The invention will be fully understood from the following description. I
During the last few years there has been an increasing demand for transmission oils capable of withstanding heavy tooth and bearing pressures. In the automotive field the demand is becoming more insistent due to the greater use of worm and helical gear transmission. Leaded compounds have been used for this service, but there is great difficulty in obtaining a suitable compound capable of withstanding the heavy loads and which will not settle out or tend to harden and resinify. The tendency to drop out is especially to be noted where an oil base stock of high quality is used. For example, relatively stable oils can be produced in base stocks of low viscosity index, but if high viscosity index oils are used the difiiculty of producing a suitable oil becomes much greater. Naturally occurring hydrocarbon lubricating oils have viscosity indices up to about 110 V. I. and the oils of this range cannot at present be used for making lead compounds. Almost all of the present leaded compounds on the contrary show viscosity indices of 50 or below, but it is the object of the present invention to produce oils of at least V. I. and adapted to transmission service. Even oils with viscosity indices above may be used for the present invention, such as are'obtained in synthetic oils prepared by condensation of cracked waxes in presence or absence of aromatic hydrocarbons.
It has been found that active leaded compounds with viscosity indices equal to or better than those of Pennsylvania oils can be made using lead oleate, stearate or other fatty acids of which the oleate is at the present time the cheapest and most convenient of the lead compounds, if a suflicient amount of a second or a solubilizing compound is present. Among the solubilizing compounds are noted the naphthenic compounds, which are compounds of acids found naturally occurring in certain oils such as those obtained from Russia, Roumania, California and some of the Gulf Coast oils. Another class of solubilizing compound is the sulfonic type which other salts of the oleate and sulfonate, for
example, and to react with lead acetate or 15 nitrate, at an elevated temperature so as to produce the corresponding lead compounds and to remove the sodium. acetate or nitrate, as the case may be. It is also possible to separately produce the lead oleate and the naphthenic or sulfonic acids which include the acid, lead and other oil soluble salts of said acid, and to mix these materials with the oil base stock.
- The exact nature of the solubilized ingredients, that is to say, the relation of the solubilizing 25 materials to the normal oleates is not clearly understood, but it is believed thata double salt probably results especially in the case where the acids or their sodium salts are mixed and reaction with a lead compound is then conducted, but it should be understood that the present invention is not to be limited to that particular method of preparation. The relative proportions of the lead oleate or other insoluble compound and the solubilizing compound may vary within limits and the most favorable proportion depends on the particular base stockused. In general, if base stocks of higher viscosity index are employed, it is desirable to increase the proportion of the naphthenic or sulfonic solubilizing agent in proportion to the amount of the suitable lead salt. Ordinarily the two compounds may be used in proportion of one-third to one part of the solubilizing agent to one part of the lead oleate. If lead salts are prepared separately and then mixed, it is preferable to use more of the solubilizing agent than where the acids or their sodium salts are mixed and then cooked with litharge or some inorganic lead salt which presumably produces the double salt. The final composition should contain from 5 to 20% of the lead compound.
' The base stock used is preferably a heavy residual, for example, a bright stock or a cylinder oil. Pennsylvania or equivalent oils which have .been raised to that grade by solvent extraction, hydrogenation,
destructive hydrogenation or other processes of this type may also be used. In short, as a base stock it is preferred to use heavy residuals of a predominantly and strongly parafllnic structure as. indicated by a viscosity index of 80 to or even above 95, and with a viscosity upwards of 75 Saybolt viscosity at 210 F., as high as may be necessary for the particular service. The particular viscosity used depends naturally on the service to which the oil is adapted.
Another ingredient of the present composition is the sulfur, by which is meant freesulfur or organic sulfur, preferably in a corrosive form .and by this latter term it is intended to include free sulfur and those oil soluble compounds of sulfur which will discolor a bright copper strip which is immersed therein. It is not necessary to use vigorously corrosive compounds such as will corrode metal gears or containers. If a base stock should contain an effective quantity of sulfur no more need be added, but insofar as applicants are aware, none of the predominantly parafllnic crudes contain a sufllcient quantity of sulfur'and furthermore such sulfur as is present is non-corrosive so that it is in all cases desirable to add "corrosive sulfur."
The corrosive" compounds should be sufficiently high boiling so as not to be lost by evaporation, and some crude oils contain relatively large amounts of such compounds in natural form, particularly those oils obtained from the West Texas fields. Cuts derived from such crudes rich in sulfur may be added to the base stocks so as to obtain a proper amount of corrosive sulfur. Pure compounds may also be used, for example, high molecular weight mercaptans, polysulildes-preferably the trisulfide or higher and the like, as well as free sulfur itself which may be added in small amounts. Olefines, for example obtained from cracked wax, or vegetable, mineral and marine oils, may also be sulfurized by cooking with free sulfur or sulfur chloride and sulfurized terpenes are also employed. The necessary amount of corrosive sulfur" is from .3 ,to 1.0% depending on the service and should be determined by the difference between total sulfur before and after heating with a finely divided metal such as copper which gives the amount of truly corrosive sulfur. More corrosive sulfur'may be added if desired say up to 3 or even 5% but this shows] little advantage over 1 or 1.5%. Non-corrosive sulfur is not nearly so effective for the present purpose as the corrosive" variety and in providing the proper amount of corrosive sulfur only that portion which is truly "corrosive should be taken into account. It will be understood that corrosive selenium and tellurium compounds may be used along with or in place of the sulfur. While the leaded compounds above show some extreme pressure qualities themselves, this is feeble at best without the addition of sulfur. In addition to the lead compounds, stabilizers and sulfur compounds, there may also be added materials of the "oiliness increasing class, by which is meant fatty oils, acids, or esters which increase the lubricating value "of the compounds. These materials may be added in relatively small amounts, say 2 to 5%. The following examples illustrate the composition of the properties of our improved lubricants:
cor'rosive sulfur. lowing composition:
I desirable to claim all novelty Example 1 To parts by weight of a base stock of sec. Saybolt viscosity at 21051". and 100 .V. 1., is added 11 parts of a mixture of lead o'leate and lead naphthenate in equal proportions. To this is added 6% of a sulfurized pine oil, 5% of The final ,rn'ixture is;the fol- Gravity 20.2
Viscosity at 100 F ec.Saybolt 1290 Viscosity at 210 F Q do 99.8 Viscosity index 93 Percent lead 1 3.1 Percent sulfur (corrosive) Q3 .was run without the addition of either the lead compounds or the sulfur. In the Almen test the oil carried only. 5 weights and the pin was sheared.
Example 2 To the base oil used in Example 1 is added 10 parts of a compounding agent made by adding sodium oleate and sodium sulfonate in weight proportion of 2 to 1 and precipitating the lead compound with an excess of lead acetate. About 30% of a sulfur compound made by heating 2 parts of chlorinated paraflln wax (25% Cl.) with 1 part of sodium polysulfide is then added. The sulfur compound should have an analysis of 2.4% total sulfur and .75% corrosive sulfur.
The finished oil was stable and had a viscosity index of substantially 100.
The present application is a continuation in part of a prior application Serial No. 710,720 filed February, 10, 1934.
The present invention is not to be limited to any theory of the extreme pressure characteristics nor to the causes or effect of the solubilizing agents, nor to any particular solubilizing agents,
but only to the following claims in which it is inherent in the invention We claim:
1. An improved lubricatingoilfor extreme pressure service comprising a lubricating oil base characterized by a viscosity index of at least 80 and a viscosity above 75 sec. Saybolt at 210 F., a lead salt of a higher fatty acid normally insoluble in the oil and a solubilizing agent therefor in proportion of about to 1 part per part of the lead salt, selected from'the group consisting of sulfonic and naphthenic acids, and their heavy metal salts, the lead salt amounting to 5 to 20% ofthe final composition and a sulphur compound in quantity sufficient to furnish .3 to 3.0% of corrosive sulphur.
2. An improved lubricating oil for extreme pressure service comprising a heavy viscous hydrocarbon lubricating oil base characterized by a viscosity index of at least 80 and aviscosity of above 75 seconds Saybolt at 210 F., lead oleate and a solubilizing compound therefor in propordrocarbon lubricating oil base characterized by a a viscosity index of at least 80 and a viscosity of above seconds Saybolt at 210 F., lead oleate and a ,solubilizing compound therefor in proportion from to 1 part per part of lead oleate selected from the group consisting of sulfonic and naphthenic acids and theirgheavy metal salts,
the lead compound amounting to 5 to 20% of the final composition and a sulfur compound sumcient to furnish from 0.3 to 1.0% of corrosive" sulfur.
4. An improved lubricating oil for extreme pressure service comprising a heavy viscous hydro; carbon lubricating oil base characterized by a viscosity index between about and and a viscosity of above 75seconds Saybolt at 210 F., lead oleate and a solubilizing compound therefor in proportion from $4, to 1 part per part of lead oleate selected from the group consisting of sulfonic and naphthenic acids and their heavy metal salts, the lead compound amounting to 5 to 20% of the final composition and a sulfur compound sufficient to furnish from 0.3 to 5% of corrosive sulfur.
5. An improved lubricating oil for extreme pressure service comprising a heavy viscous hydrocarbon lubricating oil base characterized by a viscosity index between about 80 and 100 and a viscosity of above 75 seconds Saybolt at 210 F., lead oleate and a solubilizing compound therefor in proportion from 5 to 1 part per part of lead oleate selected from the group consisting of sulfonic and naphthenic acids and their heavy metal of the final composition and a sulfur compound suflicient to furnish from 0.3 to 1.0% of "corrosive sulfur.
' FLOYD L. MILLER.
CHARIEB F. SMITH.
salts, the lead compound amounting to 5 to 20%
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US118921A US2161970A (en) | 1937-01-02 | 1937-01-02 | Lubricant |
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Application Number | Priority Date | Filing Date | Title |
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US118921A US2161970A (en) | 1937-01-02 | 1937-01-02 | Lubricant |
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US2161970A true US2161970A (en) | 1939-06-13 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2856362A (en) * | 1956-04-24 | 1958-10-14 | Exxon Research Engineering Co | Lubricating compositions |
US4824413A (en) * | 1988-05-09 | 1989-04-25 | Those Characters From Cleveland | Toy vehicle with rotatable power pack |
-
1937
- 1937-01-02 US US118921A patent/US2161970A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2856362A (en) * | 1956-04-24 | 1958-10-14 | Exxon Research Engineering Co | Lubricating compositions |
US4824413A (en) * | 1988-05-09 | 1989-04-25 | Those Characters From Cleveland | Toy vehicle with rotatable power pack |
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