US2158589A - Method and composition for improving milling products - Google Patents

Method and composition for improving milling products Download PDF

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US2158589A
US2158589A US245505A US24550538A US2158589A US 2158589 A US2158589 A US 2158589A US 245505 A US245505 A US 245505A US 24550538 A US24550538 A US 24550538A US 2158589 A US2158589 A US 2158589A
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flour
peroxide
composition
bleaching
iodate
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Frederic H Penn
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/20Peroxides

Definitions

  • flour is bleached and aged in separate stages of treatment.
  • the ageing is accomplished by treatment with a gaseous maturing agent, such as nitrogen trichloride, and the bleaching by mixing with the flour certain powdered organic peroxides, notably benzoyl peroxide.
  • a gaseous maturing agent such as nitrogen trichloride
  • the bleaching by mixing with the flour certain powdered organic peroxides, notably benzoyl peroxide.
  • the flour is thus improved in the two respects mentioned by the simple expedient of mixing the solid composition therewith and allowing sufficient time for the desired effects to take place.
  • the solid bleaching and ageing composition of my invention comprises a pre-formed mixture of 35 aniodate and an active organicperoxide, that is, an organic peroxide which is sufficiently active in powdered form to effect at least a 90% flour bleach.
  • an active organicperoxide that is, an organic peroxide which is sufficiently active in powdered form to effect at least a 90% flour bleach.
  • Benzoyl peroxide is the. preferred aromatic peroxide of my invention. Cinnamyl peroxide 55 and phenyl acetyl peroxide are other aromatic peroxides which I have found to be of suflicient activity and. flour bleaching power for use with an iodate in accordance with the invention. Suitable active fatty acid peroxides of suflicient bleaching power for my purpose are stearyl per- 5 oxide, lauryl peroxide and palmitic acid peroxide. However, not all aromatic and fatty acid peroxides are operative in my invention; for example, phthalyl peroxide is inadequate in activity and bleaching power for use with the iodate. 10
  • Potassium iodate is the preferred reagent for use with the active aromatic or fatty acid peroxide but other iodates are, of course, suitable, particularly the iodates of the alkali metals and alkaline earth metals such as sodium, calcium, 1 etc.
  • iodates have heretofore been used as dough maturing agents, it is believed to be fairly well recognized in the art that they have no appreciable maturing action when used in solid form upon dry flour which has been bleached or treated with active organic peroxides or other bleaching agents.
  • the iodates in finely divided or powdered form and when employed in admixturewith an active aromatic or fatty acid peroxide, function with the peroxide to bring about a commercially satis factory maturing and bleaching of dry flour.
  • iodates as dough maturing agents, as far as I am aware, it was not heretofore recognized that the iodates, in solid form, would operate to mature dry flour simultaneously with the bleaching thereof by means of an active aromatic or fatty acid peroxide. Nor was it appreciated thatjthis ageing with a powdered iodate could be accomplished without impairment of the bleaching action of the peroxide.
  • the bleaching and ageing composition of this invention is an improvement on the hypochlorite composition of my prior Patent #2,087,547 which is not stable in the presence of air and hence must be handled in closed equipment to avoid reaction and other inconveniences incident to the use of chlorine.
  • the present composition is not open to these objections. It is stable under all ordinary milling conditions and is non-corrosive.
  • the bleaching and ageing composition is fed directly into the flour at any convenient point during the milling operation and intimately mixed therewith, by means of powder feeding machines now used in the mills, in the proportion of about onehalf ounce to 196 pounds of flour.
  • the composition should be in the form of a dry, free-flowing powder.
  • dry powdered commercial grade dicalcium phosphate or other suitable carrier is added to an equal weight of dry commercial grade granular benzoyl peroxide and the mixture ground to the desired fineness. A fineness of about 85% through a 300 mesh sieve is satisfactory.
  • dry powdered potassium iodate in the proportion of six parts iodate to 90 parts of the peroxide-phosphate mixture, The resultant mixture is then ready; for use as a flour bleaching and ageing composition in the manner already described.
  • the proportion of peroxide, iodate, and carrier, as well as the amount of the composition required for effective bleaching and ageing, should be determined by test in each particular case.
  • the proportion of iodate may be increased to as much as 9 parts or reduced to about 3 parts of the iodate to 90 parts of the peroxide-phosphate mixture.
  • the proportion of 6 parts potassium iodate with 90 parts of the mixture of equal weights of benzoyl peroxide and dicalcium phosphate is satisfactory for many of the various grades of flour.
  • the proportions here stated are, of course, by weight.
  • the composition of this invention improves the baking qualities of flour to a greater extent than has heretofore been accomplished to my knowledge.
  • Loaf volume is one of the best indicators for determining the value of the baking qualities of flour.
  • the volume of the baked loaf of bread is measured in cubic centimeters and denotes the exact size of the loaf produced.
  • Small volume as obtained with untreated or unmatured flour, indicates low baking strength while large volume indicates high baking strength which is apparently brought about by the maturing of the
  • Table I deals with a blend of hard and soft wheat flour and Table II with hard wheat baker flour. The tables show the amounts of benzoyl peroxide and potassium iodate used in the tests.
  • peroxides as active and as having substantial flour bleaching properties in order to distinguish from those aromatic and fatty acid peroxides, such as phthalyl peroxide, which are of insufiicient activity and bleaching power to eifect a commercial bleach.
  • substantial flour bleaching properties is meant the ability to bleach flour satisfactorily for commercial purposes, that is, to effect at least a 90% bleach.
  • the inorganic peroxides and the organic peroxides not of aromatic or fatty acid derivation are entirely too inactive for use with the iodates in accordance with this invention.
  • a method for improving wheat flour and other milling products which comprises intimately mixing with the dry milling product a powdered iodate and a powdered active organic peroxide selected from the group consisting of the aromatic and fatty acid peroxides having substantial flour bleaching properties, and subjecting the milling product in 'dry form to the simultaneous action of the iodate and peroxide for a sufficient time to bleach and mature the product.
  • a method for improving wheat flour and other milling products which comprises intimately mixing with the dry milling product a powdered iodate and a powdered active aromatic peroxide having substantial flour bleaching properties, and subjecting the milling product in dry form to the simultaneous action of the iodate and peroxide for a sufficient time to bleach and mature the product.
  • a method for improving wheat flour and other milling products which comprises intimately mixing with the dry milling product a powdered iodate and a powdered active fatty acid peroxide having substantial flour bleaching properties, and subjectingthe milling product in dry form to the simultaneous action of the iodate and peroxide for a suificient time to bleach and mature the product.
  • a method for improving wheat flour and other milling products which comprises intimately mixing powdered benzoyl peroxide and a powdered iodate with the dry milling product and subjecting the latter in dry form to the simultaneous action of the peroxide and iodate for a sufiicient time to bleach and mature the milling r, product.
  • a method for improving wheat flour and other milling products which comprises intimately mixing powdered benzoyl peroxide and potassium iodate with the dry milling product and subjecting the latter in dry form to the simultaneous action of the peroxide and iodate for a sufficient time to bleach and mature the milling product.
  • a flour bleaching and ageing composition comprising a dry, free-flowing powdered mixture of an iodate and an active organic peroxide selected from the group consisting of the aromatic and fatty acid peroxides having substantial flour bleaching properties.
  • a -fiour bleaching and ageing composition comprising a dry, free-flowing powdered mixture of an iodate and an active aromatic peroxide having substantial flour bleaching properties.
  • a flour bleaching and ageing composition comprising a dry, free-flowing powdered mixture of an iodate and an active fatty acid peroxide having substantial flour bleaching properties.

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
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Description

Patented Maiy 16, 1939 PATENT OFFICE METHOD AND COMPOSITION FOR IMPROV- I ING MILLING PRODUCTS Frederic H. Penn, Dallas, Tex.
No Drawing.
Application December 13, 1938,
Serial No. 245,505 10 Claims. (01. 99-232) My invention relates to the improvement of wheat flour and other milling products, including the baking and keeping qualities thereof, and more particularly has reference to a method and composition for the simultaneous bleaching and ageing or maturing of flour and the like. This application is a continuation-in-part of my ear lier application Serial #227,016, filed August 26, 1938.
According to present commercial practice, flour is bleached and aged in separate stages of treatment. The ageing is accomplished by treatment with a gaseous maturing agent, such as nitrogen trichloride, and the bleaching by mixing with the flour certain powdered organic peroxides, notably benzoyl peroxide. While the last-mentioned step is relatively simple, the gas treatment is quite cumbersome, requiring special contacting apparatus and corrosion-resistant o equipment and accurate control over the gas which presents many hazards and difficulties in use.
It is an object of this invention to bleach and age flour and the like in a single operation and 25 to provide a finely divided or powdered composition which, when intimately mixed with the. flour, functions to effect a simultaneous bleach-' ing andageing of the milling product. The flour is thus improved in the two respects mentioned by the simple expedient of mixing the solid composition therewith and allowing sufficient time for the desired effects to take place.
The solid bleaching and ageing composition of my invention comprises a pre-formed mixture of 35 aniodate and an active organicperoxide, that is, an organic peroxide which is sufficiently active in powdered form to effect at least a 90% flour bleach. I have found that only certain aromatic and fatty acid peroxides are sufficiently active to 40 cooperate with the iodates to effect the simultaneous bleaching and maturing of dry flour or other milling product.
It has heretofore been proposed to treat flour with hydrogen peroxide and other inorganic 5 peroxides and also certain inactive organic peroxides, such,as acetone peroxide and urea peroxide, in combination with various oxidizing agents, including iodates. However, these inorganic and inactive organic peroxides are not 50 suitable in the present invention since they do not function with the iodates tosimultaneously bleach and age flour and the like.
Benzoyl peroxide is the. preferred aromatic peroxide of my invention. Cinnamyl peroxide 55 and phenyl acetyl peroxide are other aromatic peroxides which I have found to be of suflicient activity and. flour bleaching power for use with an iodate in accordance with the invention. Suitable active fatty acid peroxides of suflicient bleaching power for my purpose are stearyl per- 5 oxide, lauryl peroxide and palmitic acid peroxide. However, not all aromatic and fatty acid peroxides are operative in my invention; for example, phthalyl peroxide is inadequate in activity and bleaching power for use with the iodate. 10
Potassium iodate is the preferred reagent for use with the active aromatic or fatty acid peroxide but other iodates are, of course, suitable, particularly the iodates of the alkali metals and alkaline earth metals such as sodium, calcium, 1 etc.
Although iodates have heretofore been used as dough maturing agents, it is believed to be fairly well recognized in the art that they have no appreciable maturing action when used in solid form upon dry flour which has been bleached or treated with active organic peroxides or other bleaching agents. However, I have found that the iodates, in finely divided or powdered form and when employed in admixturewith an active aromatic or fatty acid peroxide, function with the peroxide to bring about a commercially satis factory maturing and bleaching of dry flour. Notwithstanding the known use of iodates as dough maturing agents, as far as I am aware, it was not heretofore recognized that the iodates, in solid form, would operate to mature dry flour simultaneously with the bleaching thereof by means of an active aromatic or fatty acid peroxide. Nor was it appreciated thatjthis ageing with a powdered iodate could be accomplished without impairment of the bleaching action of the peroxide.
Although I do not wish to limit the invention to any particular theory of operation, I believe 40 that the highly active peroxides employed in the composition of my invention function as activators or accelerators for the iodates, in addition to bleaching the flour. This theory seems to explain why the iodates in solid form mature the dry flour when used simultaneously or in admixture with the active aromatic and fatty acid peroxides whereas they have no noticeable maturing action when applied to flour which has previously been bleached by means of the per- 5 oxide. I believe that I am the first to recognize this phenomenon respecting the eflicient functioning of powdered iodates as maturing agents in dry flour by virtue of their admixture with the active aromatic and fatty acid peroxides.
I am aware that sodium chlorate has heretofore been mentioned as an activator for certain organic peroxides and that the chlorates have been grouped with the iodates as suitable oxidizing agents in the treatment of animal and vegetable matter, including flour. However, the chlorates are not the equivalent of the iodates of my invention since, as shown by the experimental data hereinafter included, sodium chlorate, in combination with benzoyl peroxide, was found to have no maturing action.
The bleaching and ageing composition of this invention is an improvement on the hypochlorite composition of my prior Patent #2,087,547 which is not stable in the presence of air and hence must be handled in closed equipment to avoid reaction and other inconveniences incident to the use of chlorine. The present composition is not open to these objections. It is stable under all ordinary milling conditions and is non-corrosive.
In practicing the method of this invention, the bleaching and ageing composition is fed directly into the flour at any convenient point during the milling operation and intimately mixed therewith, by means of powder feeding machines now used in the mills, in the proportion of about onehalf ounce to 196 pounds of flour. For thorough distribution of such small amounts of the composition in the flour, the composition should be in the form of a dry, free-flowing powder. A
' satisfactory bleaching and ageing is obtained by exposure of the flour to the action of the composition for about 24 hours.
As illustrative of the preparation of a preferred composition, dry powdered commercial grade dicalcium phosphate or other suitable carrier is added to an equal weight of dry commercial grade granular benzoyl peroxide and the mixture ground to the desired fineness. A fineness of about 85% through a 300 mesh sieve is satisfactory. With the powder thus obtained there is now mixed commercial grade dry powdered potassium iodate in the proportion of six parts iodate to 90 parts of the peroxide-phosphate mixture, The resultant mixture is then ready; for use as a flour bleaching and ageing composition in the manner already described.
Since there are many grades of flour, the proportion of peroxide, iodate, and carrier, as well as the amount of the composition required for effective bleaching and ageing, should be determined by test in each particular case. In some instances, for certain kinds of flour, the proportion of iodate may be increased to as much as 9 parts or reduced to about 3 parts of the iodate to 90 parts of the peroxide-phosphate mixture. Ordinarily the proportion of 6 parts potassium iodate with 90 parts of the mixture of equal weights of benzoyl peroxide and dicalcium phosphate is satisfactory for many of the various grades of flour. The proportions here stated are, of course, by weight.
The composition of this invention improves the baking qualities of flour to a greater extent than has heretofore been accomplished to my knowledge. Loaf volume is one of the best indicators for determining the value of the baking qualities of flour. The volume of the baked loaf of bread is measured in cubic centimeters and denotes the exact size of the loaf produced. Small volume, as obtained with untreated or unmatured flour, indicates low baking strength while large volume indicates high baking strength which is apparently brought about by the maturing of the The following tabluations show, by comparison, the advantages and superiority of my composition over present practice in the art. Table I deals with a blend of hard and soft wheat flour and Table II with hard wheat baker flour. The tables show the amounts of benzoyl peroxide and potassium iodate used in the tests. In each case where benzoyl peroxide was employed, it was mixed with an equal weight of di-calcium phosphate as a carrier. This is not indicated in the tables for the sake of simplification. The laboratory tests were performed on amounts of fresh milled flour such that the treatments corresponded to the use of about /2 ounce of the compositions per 196 pound barrel of flour.
TABLE I Blend of hard and soft wheat flour Loaf Crumb Texcolor ture Untreated 682 92 95 Mill treated nitrogen trichloride and benzoyl peroxide 602 98 98 Laboratory treated 45 gm. benzoyl peroxide and 3 gm. potassium iodate. 630 99 99 Laboratory treated 45 gm. benzoyl peroxide 538 97 95 Laboratory treated 46 gm. benzoyl peroxide 20 gm. sodium chlorate 560 97 95 TABLE II Hard wheat baker flour Loaf Crumb Texcolor ture Untreated 598 92 95 Mill treated nitrogen trichloride and benzoyl peroxide 68l 97 98 Laboratory treated 45 gm. benzoyl peroxide and 3 gm. potassium iodate- 758 99 99 Laboratory treated 45 gm. benzoyl peroxide 560 95 95 Laboratory treated 45 gm. benzoyl peroxide and 20 gm. sodium chlorate 580 95 95 It will be observed from these tables that with the compositions of this invention there was obtained about twice as much improvement as with the two-stage nitrogen trichloride, benzoyl peroxide method now in general use for bleaching and ageing flour. It will also be noted that no maturing was obtained with a composition containing as much as 20 parts sodium chlorate to 45 parts benzoyl peroxide.
In the appended claims, I have characterized the peroxides as active and as having substantial flour bleaching properties in order to distinguish from those aromatic and fatty acid peroxides, such as phthalyl peroxide, which are of insufiicient activity and bleaching power to eifect a commercial bleach. By substantial flour bleaching properties is meant the ability to bleach flour satisfactorily for commercial purposes, that is, to effect at least a 90% bleach. The inorganic peroxides and the organic peroxides not of aromatic or fatty acid derivation are entirely too inactive for use with the iodates in accordance with this invention.
Having described my invention, I claim:
1. A method for improving wheat flour and other milling products which comprises intimately mixing with the dry milling product a powdered iodate and a powdered active organic peroxide selected from the group consisting of the aromatic and fatty acid peroxides having substantial flour bleaching properties, and subjecting the milling product in 'dry form to the simultaneous action of the iodate and peroxide for a sufficient time to bleach and mature the product.
2. A method for improving wheat flour and other milling products which comprises intimately mixing with the dry milling product a powdered iodate and a powdered active aromatic peroxide having substantial flour bleaching properties, and subjecting the milling product in dry form to the simultaneous action of the iodate and peroxide for a sufficient time to bleach and mature the product.
3. A method for improving wheat flour and other milling products which comprises intimately mixing with the dry milling product a powdered iodate and a powdered active fatty acid peroxide having substantial flour bleaching properties, and subjectingthe milling product in dry form to the simultaneous action of the iodate and peroxide for a suificient time to bleach and mature the product.
4. A method for improving wheat flour and other milling products which comprises intimately mixing powdered benzoyl peroxide and a powdered iodate with the dry milling product and subjecting the latter in dry form to the simultaneous action of the peroxide and iodate for a sufiicient time to bleach and mature the milling r, product.
5. A method for improving wheat flour and other milling products which comprises intimately mixing powdered benzoyl peroxide and potassium iodate with the dry milling product and subjecting the latter in dry form to the simultaneous action of the peroxide and iodate for a sufficient time to bleach and mature the milling product.
6. A flour bleaching and ageing composition comprising a dry, free-flowing powdered mixture of an iodate and an active organic peroxide selected from the group consisting of the aromatic and fatty acid peroxides having substantial flour bleaching properties.
7. A -fiour bleaching and ageing composition comprising a dry, free-flowing powdered mixture of an iodate and an active aromatic peroxide having substantial flour bleaching properties.
8. A flour bleaching and ageing composition comprising a dry, free-flowing powdered mixture of an iodate and an active fatty acid peroxide having substantial flour bleaching properties.
iodate.
FREDERIC H. PENN.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2952545A (en) * 1958-01-09 1960-09-13 Pfrengle Otto Baking aids and use of same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2952545A (en) * 1958-01-09 1960-09-13 Pfrengle Otto Baking aids and use of same

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