US2153568A - Gas detection apparatus - Google Patents

Gas detection apparatus Download PDF

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Publication number
US2153568A
US2153568A US141990A US14199037A US2153568A US 2153568 A US2153568 A US 2153568A US 141990 A US141990 A US 141990A US 14199037 A US14199037 A US 14199037A US 2153568 A US2153568 A US 2153568A
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United States
Prior art keywords
film
gases
gas
light
roller
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Expired - Lifetime
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US141990A
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Chester W Johnson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHESTER W JOHNSON
INEZ L CRAGIN
RICHARD N DRESSER
Original Assignee
CHESTER W JOHNSON
INEZ L CRAGIN
RICHARD N DRESSER
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Priority to US141990A priority Critical patent/US2153568A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/8483Investigating reagent band
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00Chemistry: analytical and immunological testing
    • Y10T436/20Oxygen containing
    • Y10T436/204998Inorganic carbon compounds
    • Y10T436/205831Carbon monoxide only

Definitions

  • Patented Apr. 11, 1939 UNITED STATES This invention relates to alarm apparatus and more particularly to apparatus for the detection of dangerous or undesirable gases. Frequent disasters, including death and the destructionof property witness the need for and value. of such a paratus.
  • the deadly gases which are of most common interest are carbon monoxide gas and illuminating gas.
  • My invention therefore provides for single alarm units which may be installed in private or public garages, kitchens, or other partsof a residence, and which may be calibrated to function at a predetermined stage of gas concentration prior to the danger point to inhalers, or prior to any danger of combustion of the inflammable gases.
  • my pparatus and the various mechanisms included'therein may be varied as necessary to adapt the vsame to use in coal or other mines. in the holds of ships, or elsewhere, where deadly or inflammable gases are likely to be present.
  • My gas detecting apparatus may be used alone or in combination with a fire alarm apparatus, as
  • While my present alarm system is adapted primarily to be operated directly by these gases when they are present in dangerous concentration, it may also be used in combination with the means set forth in the patent to Hunter and Johnson 1,993,788, of March 12, 1935, for detecting the presence of minute quantities of smoke or gas by a system of concentrating the same until a suflicient density is built up to operate the alarm.
  • the most common deadly gases are colorless, and my invention includes means for causing such a reaction that such gases are either themselves rendered opaque or a film saturated with a solution is turned black by a reaction of the carbon monoxide or other gases with the chemicals of the solution so that its light reflective qualities are lost, the failure of light being the means of starting the system which warns of the presence of the deadly gases.
  • v Fig. 1 is a longitudinal view partly in section of my apparatus
  • Fig; 2 is asimilar transverse view.
  • My invention includes a casing I, within which 55 is mounted on supports 2 a tank adapted to PATENT OFFICE 2,153,558 GAS DETECTION APPARATUS Chester W. Johnson, South Weymonth, Mala,
  • Claim. receive the solution 4 which is fed into the tank 3 from the bottle or other reservoir 5, as and for the purposes hereinafter set forth.
  • a solution which I have used successfully is a mixture of palladium chloride, distilled water and alcohol, 5 the last being added only where freezing of the solution is likely..
  • Awhitefilm such as I use when saturated with such a mixture rapidly changes to black when the carbon monoxide concentration reaches .02 1
  • a rubber covered roller 9 is fixed on a shaft it supported at one end by the bracket 11 and at its other end within the clock mechanism box l2, which standard mechanism (not shown) governs the rotation of the roller 9.
  • On the shaft I9 is 15 mounted a gear ii in mesh with a second gear M which rotates the roller '1.
  • This roller 1 is mounted on a shaft 6 disposed over the tank 3 and is covered by a wick 8, which wick covered roller 1 is immersed in the solution 4 in the tank 2
  • a cloth film l5 from the reel l6, and to which film If! is attached a clamp weight II, the movement of which is controlled by the rubber covered roller 9, which, as indicated above, is retarded by the clock gear mechanism through the shaft ill.
  • the cloth film ii therefore is constantly saturated with the solution 4 by means of the wick covered roll I between which and the rubber covered clock controlled roll 9 it constantly feeds.
  • the film l5 passes over the small roller II from which it is pulled down straight by the weight I! parallel to the front wall la of the casing l.
  • a light 22 is suitably mounted to shine on the moist white film showing through the opening 20 which, so long as it remains white, deflects the light to the photoelectric cell 23 which is mounted in the same electric circuit 24, this also including the solenoid 25. If the reflected light from the film II to the photoelectric cell 23 is interrupted as would happen if the chemical, with which the film I! is saturated, turned the same black as a result of the reaction therewith of a dangerous gas delivered to the opening 20 by the conduit 2
  • the usual battery II is provided to operate the signal 28.
  • the system may be restored to operating condition by lifting the rubber covered roller 0 and allowing the weight II to carry a fresh white section of film to be exposed at the opening 2.
  • the roller 9 may be tightly held down on the roller I by a suitable spring, not shown.
  • My apparatus may be calibrated to feed th him and solution as rapidly or as slowly as desired. In practical use, I have so adjusted the apparatus that about one inch of film I! is moved past the opening 20 every twenty-four hours. I provide the film in foot lengths and one film length and one bottle capacity will operate the machine one week. In some cases and in certain climates or under difierent conditions of humidity, it may be necessary for the film to move faster. The one inch twenty-four hour movement noted above is merely illustrative.
  • Apparatus for detecting the presence of dangerous gases comprising a light reflecting strip impregnated with a solution effective on reaction with such gases to substantially reduce the light reflecting property of the strip, a light source positioned in front of said strip to direct a beam of light diagonally against the front face thereof, a photo-electric cell also disposed in front of said strip and positioned in the path of the light beam reflected from said source by said strip, means to direct air which may contain a dangerous gas against the front of said strip substantially where the light beam strikes said strip, and indicating means controlled by said photoelectric cell.

Description

pr 1 I I c. w. JOHNSON 2,153,568
GAS DETECTION APR A BATUS Filed May 11, 1937 \lllllllllllllllllIlllllllllllli ll INVENTORI (726$ Zer VICE/212.90%
ATTORNEYS.
. Patented Apr. 11, 1939 UNITED STATES This invention relates to alarm apparatus and more particularly to apparatus for the detection of dangerous or undesirable gases. Frequent disasters, including death and the destructionof property witness the need for and value. of such a paratus.
The deadly gases which are of most common interest are carbon monoxide gas and illuminating gas. My invention therefore provides for single alarm units which may be installed in private or public garages, kitchens, or other partsof a residence, and which may be calibrated to function at a predetermined stage of gas concentration prior to the danger point to inhalers, or prior to any danger of combustion of the inflammable gases. Obviously the principles and construction of my pparatus and the various mechanisms included'therein may be varied as necessary to adapt the vsame to use in coal or other mines. in the holds of ships, or elsewhere, where deadly or inflammable gases are likely to be present.
My gas detecting apparatus may be used alone or in combination with a fire alarm apparatus, as
. fire is frequently accompanied or even caused by the presence of explosive gases.
While my present alarm system is adapted primarily to be operated directly by these gases when they are present in dangerous concentration, it may also be used in combination with the means set forth in the patent to Hunter and Johnson 1,993,788, of March 12, 1935, for detecting the presence of minute quantities of smoke or gas by a system of concentrating the same until a suflicient density is built up to operate the alarm.
The most common deadly gases are colorless, and my invention includes means for causing such a reaction that such gases are either themselves rendered opaque or a film saturated with a solution is turned black by a reaction of the carbon monoxide or other gases with the chemicals of the solution so that its light reflective qualities are lost, the failure of light being the means of starting the system which warns of the presence of the deadly gases.
In the accompanying drawing I have shown and in the following specification disclosed a practical embodiment of my invention. In the draw-' ing:
v Fig. 1 is a longitudinal view partly in section of my apparatus, and
Fig; 2 is asimilar transverse view. My invention includes a casing I, within which 55 is mounted on supports 2 a tank adapted to PATENT OFFICE 2,153,558 GAS DETECTION APPARATUS Chester W. Johnson, South Weymonth, Mala,
assignor to Inez L. Cragin, Chester W. Johnson, and Richard N. Dresser, as trustees Application May 11, 1937, Serial No. 141,990
1 Claim. (Cl. 177-311) receive the solution 4 which is fed into the tank 3 from the bottle or other reservoir 5, as and for the purposes hereinafter set forth. A solution which I have used successfully is a mixture of palladium chloride, distilled water and alcohol, 5 the last being added only where freezing of the solution is likely.. Awhitefilm such as I use when saturated with such a mixture rapidly changes to black when the carbon monoxide concentration reaches .02 1 A rubber covered roller 9 is fixed on a shaft it supported at one end by the bracket 11 and at its other end within the clock mechanism box l2, which standard mechanism (not shown) governs the rotation of the roller 9. On the shaft I9 is 15 mounted a gear ii in mesh with a second gear M which rotates the roller '1. This roller 1 is mounted on a shaft 6 disposed over the tank 3 and is covered by a wick 8, which wick covered roller 1 is immersed in the solution 4 in the tank 2 Between the wick covered rollers 1 and rubber covered roller 9 is fed a cloth film l5 from the reel l6, and to which film If! is attached a clamp weight II, the movement of which is controlled by the rubber covered roller 9, which, as indicated above, is retarded by the clock gear mechanism through the shaft ill. The cloth film ii therefore is constantly saturated with the solution 4 by means of the wick covered roll I between which and the rubber covered clock controlled roll 9 it constantly feeds.
As shown in Fig. 1, the film l5 passes over the small roller II from which it is pulled down straight by the weight I! parallel to the front wall la of the casing l.
Extending inwardly from the front wall In of the casing are the inclined walls l9 of a sight opening 29 past which the film i5 travels as it is drawn slowly downward by the weight II.
The portion of the moist film i5 exposed through the opening 20 is directly in line with the delivery. end of a conduit 2| from the air pump and filter, not shown herein but disclosed in said Hunter and Johnson Patent No. 1,993,788. 46 Obviously, my present system is not dependent on the use of a filter although this might be of decided value in removing from the gas dust particles which might tend to clog the conduit or interferewith the delivery of the gas laden air 50 adjacent the wet film ii.
A light 22 is suitably mounted to shine on the moist white film showing through the opening 20 which, so long as it remains white, deflects the light to the photoelectric cell 23 which is mounted in the same electric circuit 24, this also including the solenoid 25. If the reflected light from the film II to the photoelectric cell 23 is interrupted as would happen if the chemical, with which the film I! is saturated, turned the same black as a result of the reaction therewith of a dangerous gas delivered to the opening 20 by the conduit 2|, the solenoid 2| would move the contacts 26 to contact the contacts 21 to complete a circuit 28 to a bell or other alarm signal 29. The usual battery II is provided to operate the signal 28.
Slow movement of the film I! is necessary to prevent the gradual discoloration of the same by a constant low but not dangerous amount, for instance, of carbon monoxide gas. If however the gas concentration should increase to the poisoning stage, the fllm Ii would darken and the failure of the reflected light would operate the photoelectric cell. The inclined or beveled frame I! of the sight 011811 118 ll m y be P n black, so that only the white fllm will reflect the light to the cell 23.
After an alarm has been given as a result of the discoloration of the fllm IS, the system may be restored to operating condition by lifting the rubber covered roller 0 and allowing the weight II to carry a fresh white section of film to be exposed at the opening 2.. I
The roller 9 may be tightly held down on the roller I by a suitable spring, not shown.
My apparatus may be calibrated to feed th him and solution as rapidly or as slowly as desired. In practical use, I have so adjusted the apparatus that about one inch of film I! is moved past the opening 20 every twenty-four hours. I provide the film in foot lengths and one film length and one bottle capacity will operate the machine one week. In some cases and in certain climates or under difierent conditions of humidity, it may be necessary for the film to move faster. The one inch twenty-four hour movement noted above is merely illustrative.
What I therefore claim and desire to secure by Letters Patent is:
Apparatus for detecting the presence of dangerous gases comprising a light reflecting strip impregnated with a solution effective on reaction with such gases to substantially reduce the light reflecting property of the strip, a light source positioned in front of said strip to direct a beam of light diagonally against the front face thereof, a photo-electric cell also disposed in front of said strip and positioned in the path of the light beam reflected from said source by said strip, means to direct air which may contain a dangerous gas against the front of said strip substantially where the light beam strikes said strip, and indicating means controlled by said photoelectric cell.
CHESTER W. JOHNSON.
US141990A 1937-05-11 1937-05-11 Gas detection apparatus Expired - Lifetime US2153568A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2554414A (en) * 1945-07-12 1951-05-22 Phillips Petroleum Co Apparatus for determining a chemically reactive gas
US2591691A (en) * 1946-07-05 1952-04-08 Glenn C Forrester Method for determining breath alcohol content
US2602729A (en) * 1941-10-30 1952-07-08 Curry Manfred Apparatus for determining the concentration of a chemically active gas in an atmosphere
US2613126A (en) * 1946-02-18 1952-10-07 Beckman Recording apparatus for recording gas concentrations in the atmosphere
US2622015A (en) * 1947-09-10 1952-12-16 Douglas Pole Welman Automatic gas recorders
US2721495A (en) * 1952-03-06 1955-10-25 Gen Electric Method and apparatus for detecting minute crystal forming particles suspended in a gaseous atmosphere
US2738257A (en) * 1954-06-14 1956-03-13 William K Darby Composition, method, and device for detecting carbon monoxide
US2787782A (en) * 1955-06-13 1957-04-02 William H Rosenblum Gas-responsive signal actuator
US2855280A (en) * 1956-06-15 1958-10-07 Mine Safety Appliances Co Colorimetric determination
US3276004A (en) * 1963-04-29 1966-09-27 Du Pont Apparatus for detecting gas
US3305852A (en) * 1963-12-09 1967-02-21 Dow Chemical Co Cumulative detector for chlorine gas
US3693327A (en) * 1970-12-30 1972-09-26 Israel Herbert Scheinberg Filters and carbon monoxide indicators
US4617277A (en) * 1984-03-23 1986-10-14 The Babcock & Wilcox Company Process and apparatus for monitoring ambient carbon monoxide
US5733505A (en) * 1995-03-14 1998-03-31 Goldstein; Mark K. Non-regenerating carbon monoxide sensor
US6426703B1 (en) 1997-08-07 2002-07-30 Brk Brands, Inc. Carbon monoxide and smoke detection apparatus

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2602729A (en) * 1941-10-30 1952-07-08 Curry Manfred Apparatus for determining the concentration of a chemically active gas in an atmosphere
US2554414A (en) * 1945-07-12 1951-05-22 Phillips Petroleum Co Apparatus for determining a chemically reactive gas
US2613126A (en) * 1946-02-18 1952-10-07 Beckman Recording apparatus for recording gas concentrations in the atmosphere
US2591691A (en) * 1946-07-05 1952-04-08 Glenn C Forrester Method for determining breath alcohol content
US2622015A (en) * 1947-09-10 1952-12-16 Douglas Pole Welman Automatic gas recorders
US2721495A (en) * 1952-03-06 1955-10-25 Gen Electric Method and apparatus for detecting minute crystal forming particles suspended in a gaseous atmosphere
US2738257A (en) * 1954-06-14 1956-03-13 William K Darby Composition, method, and device for detecting carbon monoxide
US2787782A (en) * 1955-06-13 1957-04-02 William H Rosenblum Gas-responsive signal actuator
US2855280A (en) * 1956-06-15 1958-10-07 Mine Safety Appliances Co Colorimetric determination
US3276004A (en) * 1963-04-29 1966-09-27 Du Pont Apparatus for detecting gas
US3305852A (en) * 1963-12-09 1967-02-21 Dow Chemical Co Cumulative detector for chlorine gas
US3693327A (en) * 1970-12-30 1972-09-26 Israel Herbert Scheinberg Filters and carbon monoxide indicators
US4617277A (en) * 1984-03-23 1986-10-14 The Babcock & Wilcox Company Process and apparatus for monitoring ambient carbon monoxide
US5733505A (en) * 1995-03-14 1998-03-31 Goldstein; Mark K. Non-regenerating carbon monoxide sensor
US6426703B1 (en) 1997-08-07 2002-07-30 Brk Brands, Inc. Carbon monoxide and smoke detection apparatus
US6819252B2 (en) 1997-08-07 2004-11-16 Brk Brands, Inc. Carbon monoxide and smoke detection apparatus

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