US2140551A - Chlorination of acetylene - Google Patents
Chlorination of acetylene Download PDFInfo
- Publication number
- US2140551A US2140551A US190133A US19013338A US2140551A US 2140551 A US2140551 A US 2140551A US 190133 A US190133 A US 190133A US 19013338 A US19013338 A US 19013338A US 2140551 A US2140551 A US 2140551A
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- US
- United States
- Prior art keywords
- acetylene
- carbon tetrachloride
- per cent
- reaction
- chlorination
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
- C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
- l acetylene.
Patented Dec. 20, 1938 UNITED. STATES auolssi nLomNa'noN on. ACETYLENE John 1!. Reilly, Midland, Mich., assignor to The Dow Chemical Company, Midland, Mich., a corporation of Michigan No Drawing.
4 Claim.
This invention relates to a method for the chlorination of'acetylene and particularly to such a process wherein the danger of combustion and explosion incident to most such processes may be 8 avoided, and from which tetrachloroethylene may be obtained as the principal product.
It is well known that the monochloro-acetylene which may be produced constitutes a definite explosion hazard in the direct chlorination of Other of the possible acetylene chlorination products, however, are desirable articles of commerce. Among the products which may be produced by the direct chlorination of acetylene are dichloro-acetylene, acetylene dichloride (symll metrical dichloroethylene), acetylene tetrachloride, trichloroethylene, and tetrachloroethylene.
It is possible under some conditions to produce hexachloroethane, and if the acetylene molecule is disrupted during the chlorination process, carbon tetrachloride may be produced. Among the most valuable of these products is tetrachloroethylene. It is, therefore, much to bedesired that a process be provided whereby acetylene may be chlorinated directly under conditions which will produce tetrachloroethylene or other valuable products without encountering the explosion hazard previously mentioned. Such is the object of the present invention.
I have now found that acetylene may be chlo- 80 rinated principally to tetrachloroethylene without danger of combustion or explosion by passing a stream of acetylene into contact with gaseous chlorine, in the presence of the vapors of a chlorinated aliphatic hydrocarbon, under the surface 85 of and in contact with a bath of molten metal chlorides maintained at a temperature from about 175 to 250 C. and preferably between about 190 and 210 C. The weight ratio of chlorine to acetylene is preferably between 4:1 and 6:1
40 although other proportions may be employed without materially aflecting the nature of the chlorinated products obtained.
The chlorinated aliphatic hydrocarbons used as diluents to suppress combustion and prevent explosions in the chlorination of acetylene may be selected from a rather large group, suitable examples of which are chloroform, carbon tetrachloride, trichloroethylene, tetrachloroethylene, and similar readily volatile, substantially nonflammable, chlorinated lower aliphatic hydrocarbons.
The molten metal chloride bath in which the reaction is carried out may consist of one or more of the chlorides of aluminum, potassium, sodium,
iron, bismuth, zinc, or other metals, provided that entering into the reactionis converted into tetra- Application February 11, 193:, Serial No. 190.1:3
such chloride or mixture of ii-ides are properly 1 sum etthe'reactiontem f t The eutectic mixture of; arts of aluminum chloride; 30 parts of sodium chloride, and 10 parts of ierrie chloride by weightis especially suitable l since it has a melting point of about 150 C. and a boiling point above 1000' Cl" Another satisfactory salt bath comprises 30 parts of sodium chloride, and parts of aluminum chloride by weight.
Owing to the heat generated in the chlorination 10 of acetylene it is seldom necessary to employ an external source of heat after the reaction has started. It may become n essary to cool the reaction vessel when high ates of flow of the reactants are employed.
The following examples illustrate the practice of my invention:
Example 1 chloride, sodium chloride and ferric chloride at a temperature between 220 and 250 C. Chlorine in the amount of 0.07 pound per minute was led through a separate tube to an equal depth in the same bath where it was released so as to contact and mix with the aforesaid mixture of acetylene and carbon tetrachloride vapor. The reaction products flashed from the bath, were collected, condensed, washed to remove hydrogen chloride. dried, and fractionally distilled. Analysis, based on boiling point and specific gravity of the fractions of the distillate, showed the product of reaction to contain 23.2 per cent carbon tetrachloride, 2.8 per cent ethylene chloride, 54 per cent tetrachloroethylene, and a small amount of a high boiling residue which was not analyzed. About 10 per cent of the gaseous reactants were unaccounted for in this particular'run- The amount of carbon tetrachloride recovered was almost identical with that originally employed as a diluent of the acetylene. It appears, therefore, that by far the largest proportion of the acetylene chloroethylene. Example 2 A mixture of 0.05 pound per minute of acetylene, and 0.056 pound per minute of carbon tetrachloride vapor was reacted in a manner analogous to that described above with 0.07 pound per minute of chlorine under the surface of a molten metal chloride bath at a temperature in the range from to 210 C. Chlorine constituted 53.6 55
' per cent.
lene 11.5 per cent, and carbon tetrachloride 42.9 An analysis of the collected condensate from the reaction mixture showed it to consist of carbon tetrachloride, tetrachloroethylene, and a small amount of a high boiling residue. The weight of carbon tetrachloride recoveredl was vper cent of the original weight of reactants, and
tetrachloroethylene accounted for 25 per cent of the weight of reactants. It is seen that 17 per cent more carbon tetrachloride was recovered from the reaction than was employed as the diluent. The conditions employed appearv to favor the formation of tetrachloroethylene and carbon tetrachloride from acetylene.
Example 3 In a manner similar to that described in the preceding examples, acetylene tetrachloride was employed as the chlorinated aliphatic hydrocarbon diluent in place of the carbon tetrachloride previously employed. 66 per cent by weight of the reaction mixture consisted of chlorine supplied at a rate of 0.07 pound per minute 14 per cent of the reactants was acetylene supplied at the rate of 0.015 pound per minute and diluted with 0.021 pound per minute of acetlyene tetrachloride, which represented 20 per cent-of the weight of the ternary reaction mixture. The temperature of the molten metal chloride bath was held at or near 210 C. Analysis oi the condensed reaction products showed them to contain carbon tetrachloride 8 per cent, trichloroethylene 21.6 per cent, tetrachloroethylene 34 per cent, and acetylene tetrachloride 115.4 per cent. About of the acetylene tetrachloride employed as a diluent in the reaction was converted to other chlorination products. The largest proportion of the acetylene employed was converted to tetrachloroethylcne while smaller amounts were converted to trichloroethylene and of the chlorinated aliphatic hydrocarbon empioyed as the diluent in the reaction, some carbon tetrachloride appears to be formed in every instance. Carbon tetrachloride is the preferred diluent during the reaction because, next to the more expensive chloroform, it is the lowest boiling of the completely nonfiammable chlorinated aliphatic hydrocarbons and may be most readily separated by distillation from other volatile products of the reaction.
Other modes of applying the principle of my invention may be employed instead of the one explained, change being made as regards the process herein disclosed, provided the step or reagents stated by any of the following claims or the equivalent of such stated step or reagents be employed. 7
I therefore particularly point out and distinctly claim as my invention:--
1. The process which comprises reacting chlorine with acetylene in the presence of the vapors of a nonflammable chlorinated lower aliphatic hydrocarbon, and in contact with molten metal chlorides at a temperature between about and 250 C.
2. The process which comprises diluting acetylene with the vapors of a nonfiammable chlorinatcd lower aliphatic hydrocarbon, and passing the mixture in contact with gaseous chlorine under the surface of a molten metal chloride bath at a temperature between 1'75 and 250 C.
3. The process which comprises diluting acetylene with the vapors of carbon tetrachloride, and passing the mixture in contact with gaseous chlorine under the surface of a molten metal chloride bath at a temperature between 175 and 250 C.
4. The process which comprises diluting acetylene with the vapors of a nonfiammable chlorinated lower aliphatic hydrocarbon, passing the mixture under the surface of a molten metal chloride bath at a temperature between 175 and 250 (2., there chlorinating the mixture with gaseous chlorine, and separating tetrachloroethylene from the reaction product.
JOHN H. REILLY.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US190133A US2140551A (en) | 1938-02-11 | 1938-02-11 | Chlorination of acetylene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US190133A US2140551A (en) | 1938-02-11 | 1938-02-11 | Chlorination of acetylene |
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US2140551A true US2140551A (en) | 1938-12-20 |
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US190133A Expired - Lifetime US2140551A (en) | 1938-02-11 | 1938-02-11 | Chlorination of acetylene |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2461142A (en) * | 1944-08-26 | 1949-02-08 | Du Pont | Production of beta-trichlorethane |
US2520712A (en) * | 1948-08-10 | 1950-08-29 | Shell Dev | Catalytic purification of unsaturated hydrocarbons |
US2538723A (en) * | 1940-08-07 | 1951-01-16 | Donau Chemie Ag | Process for producing perchlorethylene |
US2549565A (en) * | 1946-02-11 | 1951-04-17 | Roland G Benner | Method of fluorinating organic compounds with molten silver fluorides |
US2952713A (en) * | 1958-11-10 | 1960-09-13 | Detrex Chem Ind | Process for the separation of chlorinated hydrocarbon components |
-
1938
- 1938-02-11 US US190133A patent/US2140551A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2538723A (en) * | 1940-08-07 | 1951-01-16 | Donau Chemie Ag | Process for producing perchlorethylene |
US2461142A (en) * | 1944-08-26 | 1949-02-08 | Du Pont | Production of beta-trichlorethane |
US2549565A (en) * | 1946-02-11 | 1951-04-17 | Roland G Benner | Method of fluorinating organic compounds with molten silver fluorides |
US2520712A (en) * | 1948-08-10 | 1950-08-29 | Shell Dev | Catalytic purification of unsaturated hydrocarbons |
US2952713A (en) * | 1958-11-10 | 1960-09-13 | Detrex Chem Ind | Process for the separation of chlorinated hydrocarbon components |
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