US2140316A - Apparatus for converting hydrocarbons - Google Patents
Apparatus for converting hydrocarbons Download PDFInfo
- Publication number
- US2140316A US2140316A US63475A US6347536A US2140316A US 2140316 A US2140316 A US 2140316A US 63475 A US63475 A US 63475A US 6347536 A US6347536 A US 6347536A US 2140316 A US2140316 A US 2140316A
- Authority
- US
- United States
- Prior art keywords
- chamber
- hydrocarbons
- partitions
- zone
- pipe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229930195733 hydrocarbon Natural products 0.000 title description 24
- 150000002430 hydrocarbons Chemical class 0.000 title description 24
- 238000005192 partition Methods 0.000 description 20
- 239000000203 mixture Substances 0.000 description 14
- 239000000567 combustion gas Substances 0.000 description 13
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 239000000446 fuel Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- WIGIZIANZCJQQY-UHFFFAOYSA-N 4-ethyl-3-methyl-N-[2-[4-[[[(4-methylcyclohexyl)amino]-oxomethyl]sulfamoyl]phenyl]ethyl]-5-oxo-2H-pyrrole-1-carboxamide Chemical compound O=C1C(CC)=C(C)CN1C(=O)NCCC1=CC=C(S(=O)(=O)NC(=O)NC2CCC(C)CC2)C=C1 WIGIZIANZCJQQY-UHFFFAOYSA-N 0.000 description 1
- 240000000736 Amomum maximum Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
- C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/50—Furnace black ; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
- C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
- C10G9/38—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours produced by partial combustion of the material to be cracked or by combustion of another hydrocarbon
Definitions
- Fig. 1 is a vertical section through an apparatus embodying the invention
- Fig. 2 is a section on the line 2--2 of Fig.- 1, and
- Fig. 3 is a section on the line 3-3 of Fig. 1.
- the converter comprises a tubular steel casing I within which is arranged a highly refractory tube II, the right hand end of which may be of smaller diameter than the remainder, this tube preferably being composed of material known commercially as alundum.
- the tube II which forms the wall of a reaction chamber C-is supported centrally of the casing III by a cylinder I2 of heat insulating material, such for example, as heat insulating brick, although any other suitable heat insulating material may be used.
- the left hand end of the tube II and cylinder I2 abut against a plate I3 fastened to the shell II) and having a central aperture I4. Fastened to the plate I3 is a closure I5 containing an interiorly threaded boss I 6.
- a cap I1 carried by a plate I8 is connected to the closure I5 by bolts I9, the plate I8 being provided with a central aperture I81: and a plurality of smaller apertures I8b leading into the chamber Ilia.
- the cap I! is provided with an interiorly threaded boss 20 in which is arranged and exteriorly threaded pipe H which extends through the central aperture I8 a, a slight clearance being provided between the pipe and the periphery of the aperture.
- a bushing 22 is threaded into the boss I6 and has its bore in axial alinement with the pipe 2I.
- the pipe 24 leads into'the chamber I'Ia and a pipe 25 is in communication with the pipe 24.
- a metal tube 26 is threaded into the shell I0 and extends through the insulator I2 and refractory tube near the left hand end of the shell.
- a spark gap .21 is mounted in the lower end of the tube 26 and a pipe 28 leads from the chamber Ilia to the upper end of the tube 26.
- a disk 29 of steel wool or the like may be arranged in the chamber Ilia when gas is used as a fuel.
- is attached by bolts to the right hand end of the shell I0.
- 'A pipe 32 for supplying hydrocarbon to the conthe hydrocarbon is defined by two partitions 33 and 34 of refractory material in which are provided alined cylindrical passages of approximately one-half the diameter of the tube I I.
- a series of pockets 35 are provided around the periphery of each end of each passageway so that the effective area-of the two passages is greater at each end than in the middle.
- Fuel is supplied through the pipe 2
- steam maybe introduced into the air by means of the pipe 25.
- the fuel mixture is then discharged through the bushing 22 into the combustion chamber through the aperture I4.
- the tube 28 by-passos a small stream of the combustible mixture from the chamber I6a and this stream is ignited at the spark gap 21 with resultant ignition therein of the fuel mixture passing through the orifice I 4 into the chamber 0.
- the hydrocarbon to be con verted is introduced through the pipe 32 either in the form.
- the temperatures to be maintained in the chamber. C depend upon the reactions desired.
- the amount of steam added to the combustible mixture is dependent upon the hydrocarbon which is to be converted and is limited to the amount required to prevent deposition of free carbon in the tube II.
- the combustion of both the fuel and oxygen in the combustible mixture is complete by reason oi the stoichiometrical proportions and thorough mixing so that there is no free oxygen in the combustion gases and there is, therefore, no possibility-of high temperature reactions involving free oxygen in the reaction.
- the temperature at which the combustion gases contact with the hydrocarbon is substantially the flame temperature of the combustible mixture inasmuch as no quenching of the gases is effected before contact.
- the heat absorption by the hydrocarbons is maximum by reason of the high temperature of contact and the immediate intimate and uniform admixture of the combustion gases with the hydrocarbons.
- the combustion gases are introduced into the receiving zone without substantial temperature change and the maximum temperature attained by the mixture of hydrocarbons and combustion gases is of the order of 2500 F. depending upon the type of hydrocarbons and the ratio of hydrocarbons to combustion gases. Throughout the mixture of combustion gases and hydrocarbons in the reaction zone, there is a very decided temperature gradient. As typical of this temperature gradient, the temperature registered by a thermocouple T1 in one run was approximately 1400 F.
- thermocouple T2 While the temperature registered by a thermocouple T2 was approximately 1000 F. However, this temperature difference is'not the full measure of the temperature gradient since both thermocouples are spaced from the ends of the reaction zone.
- a device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, .an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone of the same cross-section as said chamber, and means for introducing hydrocarbons into said receiving zone, each partition having a single passageway of substantially less cross-section than said zone and of greater length in the direction of flow through said chamber. than the distance between said partitions.
- a device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone, and means for introducing hydrocarbons into said receiving zone, said partitions having cylindrical passages leading to and from said zone and being of larger effective diameter at their ends than intermediate the same.
- a device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone, and means for introducing hydrocarbons into said receiving zone, said partitions having cylindrical passages leading to' and from said zone and'having a series of peripheral pockets opening endwise and inwardly to effect variation inthe effective area of said passageways throughout their length.
- a device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone, and means for introducing hydrocarbons into said receiving zone, said partitions having cylindrical passages leading to and from said zone and having a series of short peripheral channels extending inwardly from each face of the partitions.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
Dec. 13, 1938. J. P4 FURLONG APPARATUS FOR CONVERTING HYDROCARBONS Original Filed Feb. 12, 1936 ATTORNEYS.
Patented Dec. 13, 1938 UNITED STATES PATENT OFFICE APPARATUS. FOR. CONVERTING HYDRO-I OARBONS Joseph P. Furlong, Pawtucket, R. 1., assignor to Amarel Corporation, Newark, N. J., a corporation of Delaware Application February 12, 1936, Serial No. 63,475
Renewed July 9, 1938 g 4 Claims. (01. 196104)' width defining a zone into which the hydrocarbon is introduced either in liquid or vapor form. Combustion gases are provided by burning a stoichiometrical mixture of air and fuel supplied to the combustion chamber and the gases thus formed are directed through openings in said partitions of substantially less area than the area of the combustion chamber. As the combustion gases enter and depart'from the zone between the partitions, a great deal of turbulences is eifected with the result that the combustion gases are immediately, intimately and uniformly mixed with the hydrocarbon vapors, thus facilitating the heat absorption by the hydrocarbons from the gases.
Other objects, novel features and advantages of this invention will become apparent from the following specification and accompanying drawing, wherein:
Fig. 1 is a vertical section through an apparatus embodying the invention;
Fig. 2 is a section on the line 2--2 of Fig.- 1, and
Fig. 3 is a section on the line 3-3 of Fig. 1.
The converter comprises a tubular steel casing I within which is arranged a highly refractory tube II, the right hand end of which may be of smaller diameter than the remainder, this tube preferably being composed of material known commercially as alundum. The tube II which forms the wall of a reaction chamber C-is supported centrally of the casing III by a cylinder I2 of heat insulating material, such for example, as heat insulating brick, although any other suitable heat insulating material may be used. The left hand end of the tube II and cylinder I2 abut against a plate I3 fastened to the shell II) and having a central aperture I4. Fastened to the plate I3 is a closure I5 containing an interiorly threaded boss I 6. Also, a cap I1 carried by a plate I8 is connected to the closure I5 by bolts I9, the plate I8 being provided with a central aperture I81: and a plurality of smaller apertures I8b leading into the chamber Ilia. The cap I! is provided with an interiorly threaded boss 20 in which is arranged and exteriorly threaded pipe H which extends through the central aperture I8 a, a slight clearance being provided between the pipe and the periphery of the aperture. A bushing 22 is threaded into the boss I6 and has its bore in axial alinement with the pipe 2I. The pipe 24 leads into'the chamber I'Ia and a pipe 25 is in communication with the pipe 24. A metal tube 26 is threaded into the shell I0 and extends through the insulator I2 and refractory tube near the left hand end of the shell. A spark gap .21 is mounted in the lower end of the tube 26 and a pipe 28 leads from the chamber Ilia to the upper end of the tube 26.
' A disk 29 of steel wool or the like may be arranged in the chamber Ilia when gas is used as a fuel. A'plate 30 provided with a discharge conduit 3| is attached by bolts to the right hand end of the shell I0.
'A pipe 32 for supplying hydrocarbon to the conthe hydrocarbon is defined by two partitions 33 and 34 of refractory material in which are provided alined cylindrical passages of approximately one-half the diameter of the tube I I. Around the periphery of each end of each passageway is provided a series of pockets 35 so that the effective area-of the two passages is greater at each end than in the middle. Thesepockets open toward the ends of the passageway and toward the interior thereof and are effective to create substantial turbulence in the gases passing therethrough.
Fuel is supplied through the pipe 2| to the chamber I61; and air is supplied to the chamber IIa through the pipe 24 and passes through apertures IIla and I8b into the chamber Ilia in which the air and fuel are thoroughly and intimately admixed. If desired, steam maybe introduced into the air by means of the pipe 25. The fuel mixture is then discharged through the bushing 22 into the combustion chamber through the aperture I4. The tube 28 by-passos a small stream of the combustible mixture from the chamber I6a and this stream is ignited at the spark gap 21 with resultant ignition therein of the fuel mixture passing through the orifice I 4 into the chamber 0. The hydrocarbon to be con verted is introduced through the pipe 32 either in the form. of liquid or vapor and is discharged into the receiving zone between the partitions 33 and 34 where it mixes with the combustion gases entering this zone through the opening in partition 33. The mixed combustion gases and hydrocarbon vapors flow through the passage in the partition 34 into the chamber C. The turbulence given the combustion gases by passage through the partition 33 and the turbulence given the mixture of gases and vapors by passagev through the partition 34 immediately eflect intimate and uniform admixture of the gases and vapors so that the heat absorption by the hydrocarbon vapors is at a. maximum. This condition promotes the desired reactions and facilitates the conversion of the hydrocarbons. After the desired conversion has been effected, the combined gases and vapors are discharged through the pipe 3| and if desired are cooled by vapors or liquid introduced through the pipe 36.
The temperatures to be maintained in the chamber. C depend upon the reactions desired. The amount of steam added to the combustible mixture is dependent upon the hydrocarbon which is to be converted and is limited to the amount required to prevent deposition of free carbon in the tube II. The combustion of both the fuel and oxygen in the combustible mixture is complete by reason oi the stoichiometrical proportions and thorough mixing so that there is no free oxygen in the combustion gases and there is, therefore, no possibility-of high temperature reactions involving free oxygen in the reaction. The temperature at which the combustion gases contact with the hydrocarbon is substantially the flame temperature of the combustible mixture inasmuch as no quenching of the gases is effected before contact. The heat absorption by the hydrocarbons is maximum by reason of the high temperature of contact and the immediate intimate and uniform admixture of the combustion gases with the hydrocarbons.
While the invention has been described as embodied in apparatus provided merely with a pair of partitions forming a single zone, it is to be understood that the invention contemplates as well an apparatus equipped with several partitions defining a plurality of receiving zones to any one of which or to all of which hydrocarbons may be supplied as described.
The combustion gases are introduced into the receiving zone without substantial temperature change and the maximum temperature attained by the mixture of hydrocarbons and combustion gases is of the order of 2500 F. depending upon the type of hydrocarbons and the ratio of hydrocarbons to combustion gases. Throughout the mixture of combustion gases and hydrocarbons in the reaction zone, there is a very decided temperature gradient. As typical of this temperature gradient, the temperature registered by a thermocouple T1 in one run was approximately 1400 F.
while the temperature registered by a thermocouple T2 was approximately 1000 F. However, this temperature difference is'not the full measure of the temperature gradient since both thermocouples are spaced from the ends of the reaction zone.
I claim:
1. A device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, .an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone of the same cross-section as said chamber, and means for introducing hydrocarbons into said receiving zone, each partition having a single passageway of substantially less cross-section than said zone and of greater length in the direction of flow through said chamber. than the distance between said partitions.
2. A device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone, and means for introducing hydrocarbons into said receiving zone, said partitions having cylindrical passages leading to and from said zone and being of larger effective diameter at their ends than intermediate the same.
3. A device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone, and means for introducing hydrocarbons into said receiving zone, said partitions having cylindrical passages leading to' and from said zone and'having a series of peripheral pockets opening endwise and inwardly to effect variation inthe effective area of said passageways throughout their length.
4. A device of the character described comprising an elongated chamber, means for introducing combustible mixture into said chamber at one end thereof, an outlet at the other end of said chamber, a pair of partitions in said chamber defining a receiving zone, and means for introducing hydrocarbons into said receiving zone, said partitions having cylindrical passages leading to and from said zone and having a series of short peripheral channels extending inwardly from each face of the partitions.
JOSEPH P. FURLONG.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63475A US2140316A (en) | 1936-02-12 | 1936-02-12 | Apparatus for converting hydrocarbons |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63475A US2140316A (en) | 1936-02-12 | 1936-02-12 | Apparatus for converting hydrocarbons |
Publications (1)
Publication Number | Publication Date |
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US2140316A true US2140316A (en) | 1938-12-13 |
Family
ID=22049454
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US63475A Expired - Lifetime US2140316A (en) | 1936-02-12 | 1936-02-12 | Apparatus for converting hydrocarbons |
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US (1) | US2140316A (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2440423A (en) * | 1944-05-04 | 1948-04-27 | Columbian Carbon | Apparatus for manufacture of carbon black |
US2499437A (en) * | 1944-09-12 | 1950-03-07 | Columbian Carbon | Apparatus for manufacture of carbon black |
US2519696A (en) * | 1949-07-29 | 1950-08-22 | Jr John B Orr | Tube cracking furnace |
US2769692A (en) * | 1952-05-06 | 1956-11-06 | Columbian Carbon | Carbon black process and apparatus |
US2781251A (en) * | 1951-01-15 | 1957-02-12 | Phillips Petroleum Co | Quench for furnace type reactors |
US2805981A (en) * | 1953-03-20 | 1957-09-10 | Phillips Petroleum Co | Process and apparatus for flash distillation |
US2813012A (en) * | 1955-03-31 | 1957-11-12 | United Gas Improvement Co | Method of making combustible gas |
US2851337A (en) * | 1951-08-22 | 1958-09-09 | Columbian Carbon | Carbon black process |
US2926077A (en) * | 1955-05-02 | 1960-02-23 | Totzek Friedrich | Process of thermally cracking liquid hydrocarbons |
DE974763C (en) * | 1950-12-23 | 1961-04-20 | Didier Werke Ag | Process for the production of hydrogen or hydrogen-containing gases from methane or similar hydrocarbons |
US3222136A (en) * | 1962-11-13 | 1965-12-07 | Ashland Oil Inc | Carbon black apparatus |
US3523770A (en) * | 1967-11-09 | 1970-08-11 | Howe Baker Eng | Flame splitting arrangement |
US3615213A (en) * | 1969-05-01 | 1971-10-26 | Air Reduction | Method and apparatus for the production of carbon black |
US4002431A (en) * | 1975-12-19 | 1977-01-11 | United Technologies Corporation | Nitrous oxide decomposition reactor |
-
1936
- 1936-02-12 US US63475A patent/US2140316A/en not_active Expired - Lifetime
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2440423A (en) * | 1944-05-04 | 1948-04-27 | Columbian Carbon | Apparatus for manufacture of carbon black |
US2499437A (en) * | 1944-09-12 | 1950-03-07 | Columbian Carbon | Apparatus for manufacture of carbon black |
US2519696A (en) * | 1949-07-29 | 1950-08-22 | Jr John B Orr | Tube cracking furnace |
DE974763C (en) * | 1950-12-23 | 1961-04-20 | Didier Werke Ag | Process for the production of hydrogen or hydrogen-containing gases from methane or similar hydrocarbons |
US2781251A (en) * | 1951-01-15 | 1957-02-12 | Phillips Petroleum Co | Quench for furnace type reactors |
US2851337A (en) * | 1951-08-22 | 1958-09-09 | Columbian Carbon | Carbon black process |
US2769692A (en) * | 1952-05-06 | 1956-11-06 | Columbian Carbon | Carbon black process and apparatus |
US2805981A (en) * | 1953-03-20 | 1957-09-10 | Phillips Petroleum Co | Process and apparatus for flash distillation |
US2813012A (en) * | 1955-03-31 | 1957-11-12 | United Gas Improvement Co | Method of making combustible gas |
US2926077A (en) * | 1955-05-02 | 1960-02-23 | Totzek Friedrich | Process of thermally cracking liquid hydrocarbons |
DE1238005B (en) * | 1955-05-02 | 1967-04-06 | Koppers Gmbh Heinrich | Process for the production of low molecular weight, in particular high-ethylene hydrocarbons |
US3222136A (en) * | 1962-11-13 | 1965-12-07 | Ashland Oil Inc | Carbon black apparatus |
US3523770A (en) * | 1967-11-09 | 1970-08-11 | Howe Baker Eng | Flame splitting arrangement |
US3615213A (en) * | 1969-05-01 | 1971-10-26 | Air Reduction | Method and apparatus for the production of carbon black |
US4002431A (en) * | 1975-12-19 | 1977-01-11 | United Technologies Corporation | Nitrous oxide decomposition reactor |
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