US2134346A - Washing and cleansing compositions - Google Patents
Washing and cleansing compositions Download PDFInfo
- Publication number
- US2134346A US2134346A US685189A US68518933A US2134346A US 2134346 A US2134346 A US 2134346A US 685189 A US685189 A US 685189A US 68518933 A US68518933 A US 68518933A US 2134346 A US2134346 A US 2134346A
- Authority
- US
- United States
- Prior art keywords
- washing
- acid
- sodium salt
- sulphuric
- meta
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005406 washing Methods 0.000 title description 33
- 239000000203 mixture Substances 0.000 title description 18
- 159000000000 sodium salts Chemical class 0.000 description 35
- 239000002253 acid Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 150000002148 esters Chemical class 0.000 description 19
- 238000002360 preparation method Methods 0.000 description 19
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical class OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 13
- -1 aliphatic amines Chemical class 0.000 description 12
- 150000007513 acids Chemical class 0.000 description 10
- 150000007824 aliphatic compounds Chemical class 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 8
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 7
- 235000019983 sodium metaphosphate Nutrition 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 238000009736 wetting Methods 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001447 alkali salts Chemical class 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 229920002955 Art silk Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical class C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WLXGQMVCYPUOLM-UHFFFAOYSA-N 1-hydroxyethanesulfonic acid Chemical compound CC(O)S(O)(=O)=O WLXGQMVCYPUOLM-UHFFFAOYSA-N 0.000 description 1
- GKGVPDQNHDBNDR-UHFFFAOYSA-N 2,2-dichlorooctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(Cl)(Cl)C(O)=O GKGVPDQNHDBNDR-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- MEFNVSITOPKYCS-UHFFFAOYSA-N 2-octylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(CCCCCCCC)=CC=C21 MEFNVSITOPKYCS-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- SSILHZFTFWOUJR-UHFFFAOYSA-N hexadecane-1-sulfonic acid Chemical class CCCCCCCCCCCCCCCCS(O)(=O)=O SSILHZFTFWOUJR-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920005547 polycyclic aromatic hydrocarbon Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/05—Organic amine, amide, or n-base containing
Definitions
- the quantity of alkali salts of metaphosphoric acid contained in the compositions according to the present invention generally amounts to between about 10 and about 200 per cent of the weight of the aforesaid sulphuric acid derivatives, the preferred compositions containing about equal parts by weight of either components.
- the said components may be mixed with each other or added to the water in any sequence in suitable proportions, and in this manner washing preparations or washing liquors of high waEhing power are obtained.
- washing textiles -especially in hard water, excellently washed goods are obtained which are distinguished by a specially soft touch.
- the compositions according to this invention are therefore especially suitable for the treatment of fabrics from or containing cotton and artificial silk fabrics, but may also be employed with advantage for the treatment of other textile materials.
- the said compositions may also be employed for washing articles of all other kinds, as for example furniture, floor coverings, or windows, and for washing animal hair.
- Glaubers salt such as sodium perborate or sodium hydrosulphite
- solvents such as cyclohexanol, cyclohexanone, monoalkyl or monoaryl esters of glycols, such as cresyl or xylenyl ethers of ethylene glycol, or
- chlorinated hydrocarbons such as carbon tetrachloride, trichlorethylene and the like.
- the first bath contains per litre of water 0.75 gram of the sodium salt of tetradecyl alcohol acid sulphuric ester
- the second bath contains the same quantity of a mixture of equal parts of tertiary sodium phosphate and the said sodium salt of the acid sulphuric ester of tetradecyl alcohol
- the third bath contains the same quantity of a mixture of equal parts of sodium metaphosphate and the said sodium salt of the acid sulphuric ester of etradecyl alcohol.
- the first and second baths only remove 43.2 and 50.0 per cent, respectively, of the oil originalhr present on the cloth
- the third bath removes 71.0 per cent of the oil. It is quite obvious that such a large increase of the degreasing effect is something quite unusual in the art.
- Example 1 White body linen or household linen is boiled for an hour in a washing liquor containing in each litre of water oi 15 hardness (German scale according to which 1 hardness means the equivalent of one part by weight of CaO in 100,000 parts of water) 1 gram of the sodium salt of oleic-N-methyl taurlde' (British specification No. 341,053), 2 grams of sodium carbonate and 2 grams of sodium metaphosphate. A pure white odourless linen is obtained.
- Example 2 Artificial silk stockings from viscose, containing strains of mineral oil from wearing are washed in a washing liquor containing in each litre of water of 15 hardness (German scale according to which 1 hardness means the equivalent of one part by weight of CaO in 100,000 parts of water) 1 gram of the reaction product of. dichlor-stearic acid and mono-ethanol amine sulphuric acid sodium salt, 0.5 gram of sodium meta-phosphate and'0.5 gram of sodium carbonate for half an hour at 60 C. while keeping the stockings in vigorous movement. The washed stockings are entirely free from stains and can be dyed without any trouble.
- Example 3 Suint wool is washed at C. in a washing liquor containing in each litre of water 1 gram of the sodium salt of the acid sulphuric ester of octodecyl alcohol, 2 grams of sodium carbonate and 1 gram of potassium meta-phosphate.
- An open, pure wool practically free from fat is *ob- -tained which may be spun without appreciable waste.
- Example 4 washed fabrics are quite free from impurities and retain their original lustre and softness without injury to the shade of colour.
- Example 6 For the cleaning of metal and glass articles, floor-coverings and lacquered articles, a mixture of the following composition is suitable:-
- Suint wool is washed at from 45 to 50 C. in 50 times its weight of a liquor containing 2 grams of the sodium salt of octyl naphthalene sulphonic acid and 0.25 gram of sodium meta-phosphate per litre of water. A pure wool free from fat is obtained.
- a washing and cleansing preparation essen tially consisting of an alkali metal salt of a water soluble derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and between about 10 and about 200 per cent of said alkali metal salt, of an alkali salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium salt of a water soluble sulphuric derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and the sodium salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium salt of a water soludium salt, of the sodium salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium salt of an acid sulphuric ester of an aliphatic alcohol containing at least carbon atoms and the sodium salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium salt of an acid sulphuric ester of an aliphatic alcohol containing at least 10 carbon atoms and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium salt of a sulfonated condensation product of an alkylol amine and a fatty acid containing at least 8 carbon atoms, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of metaphosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium saltoi a sulfonated ester of an alkylol amine and a fatty acid containing at least 8 carbon atoms, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting oi a sodium salt of a sulfonated ester of an alkylol amine and a chlorinated fatty acid containing at least 8 carbon atoms, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium salt oi a condensation product of oleic acid and an alkyl-sulfonic acid, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of the sodium salt of N-oleic-N- methyl tauride and between about 10 and about 200 per cent of K said sodium salt, of the sodium salt of meta-phosphoric acid.
- Theprocess which comprises treating soiled materials with an aqueous bath of a washing and cleansing preparation essentially consisting of a water soluble sulphuric derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and a water soluble salt of meta-phosphoric acid.
- a washing and cleansing preparation essentially consisting of a sodium salt of a sulphonated ester of an alkylol amine and a fatty acid containing at least 8 carbon atoms and sodium metaphosphate.
- a washing and cleansing preparation essentially consisting of the sodium salt of N-oleic-N- methyl tauride and sodium meta-phosphate.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Patented Oct. 25, 1938 UNITED STATES wasnmc arm cmansmc comosmons Fritz Siefert, Mannheim, rlnany, assignmto Ge I. G. Farbenindustrle Aktiengesellschait, Frank iort-on-the-Main, Germany No Drawing. Application August 15, 1983, Serial No. 685,189. In Germany September 8, 1932 Claims.
The present invention relates to washing and cleansing compositions.
I have found that particularly emcient and valuable washing and cleansing compositions can be obtained by incorporating known washing agents of the class of sulphuric derivatives of aliphatic compounds containing at least 8 carbon atoms with water-soluble salts of meta-phosphoric acid.
The said sulphuric acid derivatives comprise true sulphonic acids" and acid sulphuric esters of said aliphatic compounds, as well as watersoluble salts of said esters and acids. Consequently, whenever the term sulphuric acid derivatives of aliphatic, compounds" is hereinafter employed, it is intended to mean the free sulphonic acids and theacid sulphuric esters as well as the water-soluble salts thereof. The said water-soluble salts preferably are alkali salts, i. e. ammonium, alkali metal (Na, K, Li) and the salts derived from aliphatic amines, such as the alkylol amines, for example mono-, diand triethanol amines.
The water-soluble salts of metaphosphorlc acid comprise the same alkali constituents as the water-soluble salts of the aforesaid sulphonic acids and sulphuric esters.
Examples of sulphuric acid derivatives suitable for the purpose of the present invention are the alkali salts of cetyl sulphonic acid, hydroxyoctodecane sulphonic acid, sulphonic acids of lauric, palmitic and margaric acid, sulphonic acids of fatty acid mixtures obtainable by saponiiication of fatty oils and fats, such as coconut oil, palmkernel oil, soya bean oil or cotton seed oil, alkali salts of oleic hydroxyethane sulphonic acid or N-oleic-N-methyl taurine and the like. The said sulphonic acids may be prepared, inter alia, according to the process described in the British 0 specifications Nos.343,899 and 341,053. The said sulphonic acids also comprise those derived from halogenated, moreparticularly chlorinated, fatty acids of the kind described. Suitable salts of sulphuric esters are more particularly those of aliphatic alcohols contaning at least 10 carbon atoms, such as decyl, dodecyl, tetradecyl, octodecyl and oleyl alcohols, which alcohols may also contain one or more chlorine atoms in their molecule. Particularly valuable compositions are obtained by incorporating the said salts of metaphosphoric acid with the sulphonated mixtures of alcohols obtainable by the liquid phase oxidation of par afiin wax according to Patent No. 1,908,376. The said sulphonic acids of aliphatic compounds containing at least 8 carbon atoms may also be substituted by polynuclear aromatic hydrocarbon radicles, in which case the sulpuhonic acid groups may be fixed to the aromatic nucleus, such as is the case for example with monoor polyoctylnaphthalene sulphonic acids. Very valuable compositions may also be prepared from esters, amides and ester amides, obtainable by condensing a hydroxyalkyl amine with a higher aliphatic acid containing sulphuric acid groups, for example according to the British Patent No. 306,116, and from the sulphonated condensation products of hydroxylalkyl ethers with fatty acids: containing at least 8 carbon atoms, which may be prepared according to the British Patent No. 364,104. The said sulphuric acid derivatives also comprisethe sulphonated fatty acid compounds, containing chlorine, which may be obtained according to the British Patent No. 389,543, and the acid sulphuric esters of halogen derivatives of hydroxylated aliphatic hydrocarbons obtainable according to the British Patent No. 394,043.
The quantity of alkali salts of metaphosphoric acid contained in the compositions according to the present invention generally amounts to between about 10 and about 200 per cent of the weight of the aforesaid sulphuric acid derivatives, the preferred compositions containing about equal parts by weight of either components. The said components may be mixed with each other or added to the water in any sequence in suitable proportions, and in this manner washing preparations or washing liquors of high waEhing power are obtained. When washing textiles,-especially in hard water, excellently washed goods are obtained which are distinguished by a specially soft touch. The compositions according to this invention are therefore especially suitable for the treatment of fabrics from or containing cotton and artificial silk fabrics, but may also be employed with advantage for the treatment of other textile materials. The said compositions may also be employed for washing articles of all other kinds, as for example furniture, floor coverings, or windows, and for washing animal hair.
Other additional substances may be added to the said preparations of washing liquors, as for example Glaubers salt, water-glass, substances having an oxidizing or reducing action, such as sodium perborate or sodium hydrosulphite, solvents, such as cyclohexanol, cyclohexanone, monoalkyl or monoaryl esters of glycols, such as cresyl or xylenyl ethers of ethylene glycol, or
chlorinated hydrocarbons, such as carbon tetrachloride, trichlorethylene and the like.
The following unexpectedly good results obtainable by washing with the said new compositions become evident by the following comparisons: Ladies dress-cloth impregnated with 5 per cent by weight of olive oil is treated for 5 minutes at between and C. with 10 times its weight of a degreasing bath. The first bath contains per litre of water 0.75 gram of the sodium salt of tetradecyl alcohol acid sulphuric ester, the second bath contains the same quantity of a mixture of equal parts of tertiary sodium phosphate and the said sodium salt of the acid sulphuric ester of tetradecyl alcohol, and the third bath contains the same quantity of a mixture of equal parts of sodium metaphosphate and the said sodium salt of the acid sulphuric ester of etradecyl alcohol. Whereas by the said treatment the first and second baths only remove 43.2 and 50.0 per cent, respectively, of the oil originalhr present on the cloth, the third bath removes 71.0 per cent of the oil. It is quite obvious that such a large increase of the degreasing effect is something quite unusual in the art.
The following examples will further illustrate the nature of this invention but the invention is not restricted to these examples.
Example 1 White body linen or household linen is boiled for an hour in a washing liquor containing in each litre of water oi 15 hardness (German scale according to which 1 hardness means the equivalent of one part by weight of CaO in 100,000 parts of water) 1 gram of the sodium salt of oleic-N-methyl taurlde' (British specification No. 341,053), 2 grams of sodium carbonate and 2 grams of sodium metaphosphate. A pure white odourless linen is obtained.
Example 2 Artificial silk stockings from viscose, containing strains of mineral oil from wearing are washed in a washing liquor containing in each litre of water of 15 hardness (German scale according to which 1 hardness means the equivalent of one part by weight of CaO in 100,000 parts of water) 1 gram of the reaction product of. dichlor-stearic acid and mono-ethanol amine sulphuric acid sodium salt, 0.5 gram of sodium meta-phosphate and'0.5 gram of sodium carbonate for half an hour at 60 C. while keeping the stockings in vigorous movement. The washed stockings are entirely free from stains and can be dyed without any trouble.
Example 3 Suint wool is washed at C. in a washing liquor containing in each litre of water 1 gram of the sodium salt of the acid sulphuric ester of octodecyl alcohol, 2 grams of sodium carbonate and 1 gram of potassium meta-phosphate. An open, pure wool practically free from fat is *ob- -tained which may be spun without appreciable waste.
Example 4 washed fabrics are quite free from impurities and retain their original lustre and softness without injury to the shade of colour.
Example 5 hardness of the washing water plays no part in the washing process.
Example 6 For the cleaning of metal and glass articles, floor-coverings and lacquered articles, a mixture of the following composition is suitable:-
40 parts by weight of the mixture of sodium salts of the acid sulphuric esters of the alcohols corresponding to the fatty acids contained in coconut or palm kernel oils,
10 parts by weight of sodium meta-phosphate and 50 parts by weight of Glaubers salt.
By dissolving this mixture in water, an excellent cleaning agent is obtained.
Ezample 7 Suint wool is washed at from 45 to 50 C. in 50 times its weight of a liquor containing 2 grams of the sodium salt of octyl naphthalene sulphonic acid and 0.25 gram of sodium meta-phosphate per litre of water. A pure wool free from fat is obtained.
What I claim is:-
l. A washing and cleansing preparation essentially consisting of a water soluble sulphuric derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and a water soluble salt of meta-phosphoric acid.
2. A washing and cleansing preparation essentially consisting of a water soluble sulphuric derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and between about 10 and about 200 per cent of said derivative, of a water soluble salt of meta-phosphoric acid.
3. A washing and cleansing preparation essentially consisting of an alkali metal salt of a water soluble sulphuric derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and an alkali metal salt of meta phosphoric acid.
4. A washing and cleansing preparation essen tially consisting of an alkali metal salt of a water soluble derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and between about 10 and about 200 per cent of said alkali metal salt, of an alkali salt of meta-phosphoric acid.
5. A washing and cleansing preparation essentially consisting of a sodium salt of a water soluble sulphuric derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and the sodium salt of meta-phosphoric acid.
6. A washing and cleansing preparation essentially consisting of a sodium salt of a water soludium salt, of the sodium salt of meta-phosphoric acid.
7. A washing and cleansing preparation essentially consisting of a sodium salt of an acid sulphuric ester of an aliphatic alcohol containing at least carbon atoms and the sodium salt of meta-phosphoric acid.
8. A washing and cleansing preparation essentially consisting of a sodium salt of an acid sulphuric ester of an aliphatic alcohol containing at least 10 carbon atoms and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
9. A washing and cleansing preparation essentially consisting of a sodium salt of an acid sulphuric ester of a chlorinated aliphatic alcohol containing at least 10 carbon atoms and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
10. A washing and cleansing preparation essentially consisting of a sodium salt of a sulfonated condensation product of an alkylol amine and a fatty acid containing at least 8 carbon atoms, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of metaphosphoric acid.
11. A washing and cleansing preparation essentially consisting of a sodium saltoi a sulfonated ester of an alkylol amine and a fatty acid containing at least 8 carbon atoms, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
12. A washing and cleansing preparation essentially consisting oi a sodium salt of a sulfonated ester of an alkylol amine and a chlorinated fatty acid containing at least 8 carbon atoms, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
' 13. A washing and cleansing preparation essentially consisting of a sodium salt oi a condensation product of oleic acid and an alkyl-sulfonic acid, and between about 10 and about 200 per cent of said sodium salt, of the sodium salt of meta-phosphoric acid.
14. A washing and cleansing preparation essentially consisting of the sodium salt of N-oleic-N- methyl tauride and between about 10 and about 200 per cent of K said sodium salt, of the sodium salt of meta-phosphoric acid.
15. Theprocess which comprises treating soiled materials with an aqueous bath of a washing and cleansing preparation essentially consisting of a water soluble sulphuric derivative of an aliphatic compound containing at least 8 carbon atoms and having detergent and wetting properties and a water soluble salt of meta-phosphoric acid.
16. A washing and cleansing preparation essentially consisting of a sodium salt of a sulphonated ester of an alkylol amine and a fatty acid containing at least 8 carbon atoms and sodium metaphosphate.
1'7. A washing and cleansing preparation essentially consisting of the sodium salt of N-oleic-N- methyl tauride and sodium meta-phosphate.
FRI'I'Z SIEFERT.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI45264D DE725820C (en) | 1932-09-07 | 1932-09-07 | Methods of washing and cleaning |
| GB30296/32A GB408708A (en) | 1932-09-07 | 1932-10-28 | Improvements in cleaning agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2134346A true US2134346A (en) | 1938-10-25 |
Family
ID=25981710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US685189A Expired - Lifetime US2134346A (en) | 1932-09-07 | 1933-08-15 | Washing and cleansing compositions |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2134346A (en) |
| DE (1) | DE725820C (en) |
| FR (1) | FR760236A (en) |
| GB (1) | GB408708A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2471645A (en) * | 1946-08-30 | 1949-05-31 | Clorox Chemical Co | Detergent composition |
| US2542831A (en) * | 1945-10-23 | 1951-02-20 | Socony Vacuum Oil Co Inc | Mineral oil composition and improving agent therefor |
| US2542385A (en) * | 1946-10-12 | 1951-02-20 | Gen Aniline & Film Corp | Detergent composition |
| US2545357A (en) * | 1946-06-04 | 1951-03-13 | American Cyanamid Co | Detergent composition and method of preparing same |
| US2618607A (en) * | 1952-11-18 | Liquid | ||
| US2625515A (en) * | 1953-01-13 | Cleaning | ||
| US3108080A (en) * | 1955-09-23 | 1963-10-22 | Purex Corp Ltd | Process for removal of radioactive contaminants |
| US3111218A (en) * | 1958-05-26 | 1963-11-19 | United States Steel Corp | Method of drawing wire and a lubricant therefor |
| CN107090360A (en) * | 2017-04-06 | 2017-08-25 | 安徽万宝玻璃有限公司 | A kind of glass cleaner and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE750286C (en) * | 1935-05-02 | 1945-01-03 | Kalle & Co Ag | Soap-free detergents |
| DE746448C (en) * | 1940-07-27 | 1944-08-05 | Albert Ag Chem Werke | Method of washing |
| DE967894C (en) * | 1942-11-01 | 1957-12-27 | Benckiser Gmbh Joh A | Detergents and detergents for automatic dishwashers |
| DE2934484A1 (en) * | 1979-08-25 | 1981-03-26 | Van Baerle & Co KG, 64579 Gernsheim | LIQUID, LOW-PHOSPHATE AND ENVIRONMENTALLY FRIENDLY DETERGENT |
-
1932
- 1932-09-07 DE DEI45264D patent/DE725820C/en not_active Expired
- 1932-10-28 GB GB30296/32A patent/GB408708A/en not_active Expired
-
1933
- 1933-08-15 US US685189A patent/US2134346A/en not_active Expired - Lifetime
- 1933-09-01 FR FR760236D patent/FR760236A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2618607A (en) * | 1952-11-18 | Liquid | ||
| US2625515A (en) * | 1953-01-13 | Cleaning | ||
| US2542831A (en) * | 1945-10-23 | 1951-02-20 | Socony Vacuum Oil Co Inc | Mineral oil composition and improving agent therefor |
| US2545357A (en) * | 1946-06-04 | 1951-03-13 | American Cyanamid Co | Detergent composition and method of preparing same |
| US2471645A (en) * | 1946-08-30 | 1949-05-31 | Clorox Chemical Co | Detergent composition |
| US2542385A (en) * | 1946-10-12 | 1951-02-20 | Gen Aniline & Film Corp | Detergent composition |
| US3108080A (en) * | 1955-09-23 | 1963-10-22 | Purex Corp Ltd | Process for removal of radioactive contaminants |
| US3111218A (en) * | 1958-05-26 | 1963-11-19 | United States Steel Corp | Method of drawing wire and a lubricant therefor |
| CN107090360A (en) * | 2017-04-06 | 2017-08-25 | 安徽万宝玻璃有限公司 | A kind of glass cleaner and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| FR760236A (en) | 1934-02-19 |
| DE725820C (en) | 1942-09-30 |
| GB408708A (en) | 1934-04-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2134346A (en) | Washing and cleansing compositions | |
| US2486922A (en) | Stabilized detergent composition | |
| US2486921A (en) | Detergent composition | |
| US2267205A (en) | Detergent | |
| US3325404A (en) | Composition for simultaneously laundering and softening fabrics | |
| JPS5833280B2 (en) | Ekita Senjiyouzai Sobutsu | |
| GB1565808A (en) | Fabric softeners and detergent compositions containing imidazolines derivatives | |
| US2335194A (en) | Cleansing process and product | |
| CH676994A5 (en) | ||
| JPH03123634A (en) | Storage-stable aqueous wetting agent producing fewer bubbles in use | |
| US1911289A (en) | Method of cleaning fabrics | |
| US3897347A (en) | Washing agents containing a textile softener and process of washing and softening textiles | |
| US2383740A (en) | Detergent composition | |
| DE1072348B (en) | laundry detergent | |
| US3554784A (en) | Softening of textile materials | |
| US3897348A (en) | Surface treating compositions containing surface active ammonioamidate compounds | |
| US1914331A (en) | Treatment of textile materials with aqueous liquids | |
| US1935217A (en) | Washing and cleansing textile fibers | |
| US3468697A (en) | Method of treating textile articles which are usually laundered | |
| US3067144A (en) | Detergent composition | |
| US2229649A (en) | Sulphated methyl heptadecenyl carbinol | |
| US2236617A (en) | Treatment of textiles | |
| GB343872A (en) | Improvements in the manufacture and production of wetting, cleansing and dispersing agents | |
| US3018251A (en) | Dry cleaning compositions | |
| US2334852A (en) | Textile wetting and softening bath |