US2132929A - Spinning solution - Google Patents
Spinning solution Download PDFInfo
- Publication number
- US2132929A US2132929A US177824A US17782437A US2132929A US 2132929 A US2132929 A US 2132929A US 177824 A US177824 A US 177824A US 17782437 A US17782437 A US 17782437A US 2132929 A US2132929 A US 2132929A
- Authority
- US
- United States
- Prior art keywords
- halogenated
- cation
- active
- viscose
- tertiary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009987 spinning Methods 0.000 title description 17
- 239000000243 solution Substances 0.000 description 36
- 229920000297 Rayon Polymers 0.000 description 28
- 239000007859 condensation product Substances 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 13
- 239000001993 wax Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 12
- -1 diaryl sulphides Chemical class 0.000 description 10
- 229930195733 hydrocarbon Natural products 0.000 description 10
- 150000002430 hydrocarbons Chemical class 0.000 description 10
- 235000019271 petrolatum Nutrition 0.000 description 10
- 239000003208 petroleum Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000010687 lubricating oil Substances 0.000 description 7
- 235000011837 pasties Nutrition 0.000 description 7
- 150000003512 tertiary amines Chemical class 0.000 description 7
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical class [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 150000003003 phosphines Chemical class 0.000 description 6
- 150000003568 thioethers Chemical class 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000004627 regenerated cellulose Substances 0.000 description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- 230000026030 halogenation Effects 0.000 description 4
- 238000005658 halogenation reaction Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- OUULRIDHGPHMNQ-UHFFFAOYSA-N stibane Chemical class [SbH3] OUULRIDHGPHMNQ-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004264 Petrolatum Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- VUEDNLCYHKSELL-UHFFFAOYSA-N arsonium Chemical compound [AsH4+] VUEDNLCYHKSELL-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229940066842 petrolatum Drugs 0.000 description 3
- 239000003209 petroleum derivative Substances 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- HISNRBVYBOVKMB-UHFFFAOYSA-N stibonium Chemical compound [SbH4+] HISNRBVYBOVKMB-UHFFFAOYSA-N 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical class C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 150000003752 zinc compounds Chemical class 0.000 description 2
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001251 acridines Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 150000005053 phenanthridines Chemical class 0.000 description 1
- 150000005041 phenanthrolines Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- JVANLUCASVHWEW-UHFFFAOYSA-N pyridazine Chemical class N1=C=C=C=C=N1 JVANLUCASVHWEW-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 125000005259 triarylamine group Chemical group 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
Definitions
- a tertiary base selected from the group consisting of amines, phosphines, arsines and stibines, or with an organic sulphide selected from the group consisting of dialkyl sulphides,
- Petroleum consists of complex mixtures of hydrocarbons concerning the chemical nature of which there is very little information, although 35 there are indications that all of these materials contain members of the methane series, the 'polymethylene series and the benzene series of hydrocarbons.
- the difierence between petroleums' of various sources resides in the proporm tions of the difiercnt types of hydrocarbons and in the chemical nature and amounts of their impurities.
- Pennsylvania oil for example, contains a large proportion of methane hydrocarbons and practically no impurities of sulphur or ii nitrogen compounds. About thirty hydrocarbons have been isolated and identified with certainty.
- Distillation is the principal method used in sep-' arating crude petroleum into useful components.
- the distilled fractions from crude petroleum so are casinghead gasoline, gasoline, kerosene, gas
- Petrolatum (Vaseline) is a pasty mixture of hydrocarbons similar to parailln while liquid petrolatum is a high boiling petroleum distillate.
- Ozokerite is a natural paraflin wax originating in Galicia; in bleached form it is termed ceresin.
- All of these petroleum hydrocarbons may be halogenated in conventional manner in the presenceor absence of catalysts to form halogenated hydrocarbon mixtures adapted to be condensed with the tertiary bases and organic sulphides, set forth above.
- the hydrocarbonaceous materials i.
- crude petroleums, casinghead gasolines, gasolins, kerosenes, gas oil, lubricating oils, pasty and liquid petrolatums and paraflin waxes, 26 to be halogenated may first be dissolved in carbon tetrachloride, etc., and subsequently chlorine, bromine, etc., in gaseous form introduced therein until the heat of reaction abates.
- Halogenated compounds; containing about to 40% of 30 halogen may be obtained in this manner.
- Chlorafin is a very suitable raw material for myproceu.
- Trialkyl amines are for example: Trialkyl amines; dialkyl-aryi amines, alkyl-diaryl amines, triaryl amines, pyridine, substituted pyridines, pyridazine,' pyrimidine, pyrazine, triaaole, oxazole, tetrazole, quinoline, substituted quinolines, acridine, substituted acridines, phenanthridines,
- phenanthrolines, phenazine, picoline, substituted are obtained which are capable of preventing the incrustation of spinnerets and spinneret holes' through which viscose solutions are extruded into' picolines, trialkyljphosphines, diali'ryl-aryl phosphines, eZlkyl-diaryl phosphines, triaryl phosphines, trialkyl arsines, dialkyl-aryl arsines, aikyl-diaryl arsines, triaryl arsines, trialkyl stibiines, dialkyl-aryl stibines, triaryl stlbins, etc.
- Organic sulphides suitable for being condensed with these halogenated petroleum hydrocarbons are dialkyl sulphides. ,al kyl-aryl; sulphides and I diaryl sulphides. Thus, during such condensations cation-active ammonium, phosphonium,
- Cation-active compounds are surface-active compounds which carry in the cation a hydrocarbon chain having eight or more carbon atoms. They are particularly advantageous because they may be used in neutral salt, alkaline and acidic aqueous solutions and also in hard water.
- anion-active compounds are surfaceactive compounds which carry in the anion a more or less extended hydrocarbon They flocculate in neutral salt, alkaline and acidic aqueous solutions, and also in 'hard water.
- the inert solvent may subsequently be removed from the condensation products by distillation and the unreacted base or sulphide separated from the condensation products -by distillation, extraction; etc.
- the crude incrustation inhibitors may contain a number of diilferent condensation products which need not be separated from each other.
- the crude condensation productsjincrus- .tation inhibitors) containing surface-active and surface-inagetive constituents may be added for reasons of economy without further purification to viscose solutions or spin baths (setting baths).
- Example I 7 About 10 grams of a halogenated petroleum are with about 50 grams of trietlianolamine and heated under reflux at a moderate tempera-- ture, i. e., a temperature at wlgich'the raw mate-' rials as well as condensatio' products formed therefrom remain stable, until condensation iscomplete. About 0.410 1 gram of the reddishbrown condensation product are added to one liter of a viscose solution of conventional concentfation and maturity. This solution is then extruded into an acid spin bath, such as, for example,- a glucose bath, a magnesium-zinc bath, etc.
- an acid spin bath such as, for example,- a glucose bath, a magnesium-zinc bath, etc.
- spinnerets and'spinneret holes remain clean on prolonged spinning;
- Other ammonium as well as phosphonium, arsonium, stibonium and sulphonium compounds, prepared as set forth above, may be usedWvith equal success.
- Example II The cation -active compound is added to b0 the. viscose solution andthe spin bath following Examples I and H. 1
- tertiary amine selected from the group consist- ;ing of amines, phosphines, arsines and stibines or an organic sulphide selected from the group con', sisting of dialkyl sulphides, diaryl sulphides and alkyl-aryl sulphides under substantially. anhydrous conditions, provided.
- these cation-active compounds aresufliciently soluble in either viscose solutions or spin baths to furnish cations therein. 1 I Modifications. ormyinvention will readily be 7 ansaoao 1.
- spinning solution for the production artificial products comprising a viscose solution and a cation-active condensation product of a halogenated hydrocarbonaceous material selected from the group consisting of halogenated crude petroleums, halogenated gasolines. halogenated kerosenes, halogenated lubricating oils, halogen-L ated pasty petrolatums, halogenated liquid petrolatums and halogenated paraflln waxes and a tertiary base selected from the group consisting of tertiary amines, tertiary phosphines, tertiary arsines and tertiary stibines, said condensation product being s'ufllciently soluble in said viscose solution to become cation-active therein.
- a halogenated hydrocarbonaceous material selected from the group consisting of halogenated crude petroleums, halogenated gasolines.
- halogenated kerosenes halogenated lubric
- a spinning solution for the production; or artificial products comprising a viscose solution and a cation-active condensation" product of a halogenated paraiiln wax and triethanolamlne.
- a spinning solution for the production of artificial products comprising one liter of a viscose solution and about 0.4 to 1.0 gram of 9. cation-active condensation product of a halogenated hydrocarbonaceous material selected from the group consisting oi halogenated crude petroleums, halogenated gasolines; kerosenes, halogenated lubricating oils, halogenated pasty petrolatums, halogenated liquid pet.- rolatums and halogenated paramn waxu and a tertiary base selected from the group consisting of tertiary amines, tertiary phosphines, tertiary arsines and tertiary stibines, said condensation product being sufliciently soluble in said viscose solution to become cation-active therein.
- a halogenated hydrocarbonaceous material selected from the group consisting oi halogenated crude petroleums, halogenated gasolines; kerosenes, halogen
- a spinning solution for the production of artificial products comprising one liter oi a viscose solution and about 0.4 to 1.0 gramoi a ca tion-active condensation product of a halogenated paraffin wax and triethanolamine.
- halogenated kerosenes halogenated lubricating oils, halogenated pasty petrolatmns, halogenated liquid and halogenated paraiiin waxes andatertiarybaseselected iromthegroup consisting oi tertiary amines, tertiary phosphines.
- tertiary arsinesandtertlarystibinesin asumcient amount to diminish the lustre thereof.
- a soft-lustre regenerated cellulose containing-a finely divided cation-active condensation product oi. a halogenated paramn' wax and triethanolamine in a suilcient amount to diminish the lustre thereof.
- a spinning solution for the production of artificial products comprising a viscose solution and a cation-active condensation product of a chicrinated paraiiin wax and .a tertiary amine, said condensation product being suiiiciently soluble in said viscose solution therein.
- a spinning solution for the production oi. artificial products comprising one "liter of a viscose solution and about 0.4 to 1.0 gram. of a' cation-active condensation product of a. chlorin-' ated paraiiin wax and triethanolamine.
- a spinning solution for the production of artificial products comprising one liter of a viscose solution and about 0.4 to 1.0 gram 01' .a cation-active condensation product 01' a chlorinated paraflln warand a tertiary amine, said condensation product being suiiioiently soluble in said viscose solution to become cation-active thel'eln.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE431416D BE431416A (enrdf_load_stackoverflow) | 1937-12-02 | ||
| US177825A US2132930A (en) | 1937-12-02 | 1937-12-02 | Viscose spinning solution |
| US177824A US2132929A (en) | 1937-12-02 | 1937-12-02 | Spinning solution |
| FR846622D FR846622A (fr) | 1937-12-02 | 1938-11-25 | Procédé pour améliorer l'opération de filage dans la production de la rayonne à partir de la viscose |
| GB34322/38A GB521727A (en) | 1937-12-02 | 1938-11-25 | Improved process for producing filaments, threads and the like cellulose products from viscose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US177824A US2132929A (en) | 1937-12-02 | 1937-12-02 | Spinning solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2132929A true US2132929A (en) | 1938-10-11 |
Family
ID=22650110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US177824A Expired - Lifetime US2132929A (en) | 1937-12-02 | 1937-12-02 | Spinning solution |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2132929A (enrdf_load_stackoverflow) |
| BE (1) | BE431416A (enrdf_load_stackoverflow) |
| FR (1) | FR846622A (enrdf_load_stackoverflow) |
| GB (1) | GB521727A (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2428387A (en) * | 1943-07-16 | 1947-10-07 | Rayonier Inc | Processing of refined chemical pulp into viscose by adding cation active sulphonium compounds |
| BE487186A (enrdf_load_stackoverflow) * | 1948-02-09 |
-
0
- BE BE431416D patent/BE431416A/xx unknown
-
1937
- 1937-12-02 US US177824A patent/US2132929A/en not_active Expired - Lifetime
-
1938
- 1938-11-25 GB GB34322/38A patent/GB521727A/en not_active Expired
- 1938-11-25 FR FR846622D patent/FR846622A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE431416A (enrdf_load_stackoverflow) | |
| FR846622A (fr) | 1939-09-21 |
| GB521727A (en) | 1940-05-29 |
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