US2128582A - Photoelectric surface - Google Patents
Photoelectric surface Download PDFInfo
- Publication number
- US2128582A US2128582A US96613A US9661336A US2128582A US 2128582 A US2128582 A US 2128582A US 96613 A US96613 A US 96613A US 9661336 A US9661336 A US 9661336A US 2128582 A US2128582 A US 2128582A
- Authority
- US
- United States
- Prior art keywords
- caesium
- silver
- tube
- photoelectric
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 description 23
- 229910052792 caesium Inorganic materials 0.000 description 22
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 22
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 12
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Substances [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 229910052709 silver Inorganic materials 0.000 description 11
- 239000004332 silver Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 229910052783 alkali metal Inorganic materials 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 8
- 230000035945 sensitivity Effects 0.000 description 8
- 229910001923 silver oxide Inorganic materials 0.000 description 8
- 230000008569 process Effects 0.000 description 6
- 238000005530 etching Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 241000643888 Christisonia Species 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910001942 caesium oxide Inorganic materials 0.000 description 2
- KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- JHKXZYLNVJRAAJ-WDSKDSINSA-N Met-Ala Chemical compound CSCC[C@H](N)C(=O)N[C@@H](C)C(O)=O JHKXZYLNVJRAAJ-WDSKDSINSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/02—Manufacture of electrodes or electrode systems
- H01J9/12—Manufacture of electrodes or electrode systems of photo-emissive cathodes; of secondary-emission electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J40/00—Photoelectric discharge tubes not involving the ionisation of a gas
- H01J40/02—Details
- H01J40/04—Electrodes
- H01J40/06—Photo-emissive cathodes
Definitions
- My invention relates to photoelectric tubes and, more particularly, to a means-and method for obtaining a photoelectric surface of high sensitivity
- Figure' 1 is a diagram showing a tube'and apparatus setup by which the photosurface .of my invention may be formed.
- Figure 2 is a cross-sectional view of the tube shown in Figure 1.
- My method allows the use of excess quantities 'of alkali metal, the sensitization being accomplished' by oxidization of the final deposit.
- I do not remove the excess alkali metal from the tube, but simply change it from a metal to an oxide, the latter being non-conductive, ⁇ thus leakage is eliminated.
- An envelope i is provided with a cathode foundation member 2 and an anode 3.
- the tube is sealed onto an exhaust line 4 to whichoxygen may be supplied through a stopcock or other suitable vmeans 5.
- Caesium metal is placed in a still tube t by which the metal may be Vessel. ,f 'f
- the caesium metal is then distilled in through the still tube 6 in excess quantity, and no attempt need be made to put in any denite quantity, though I usually prefer to admit about twice the amount which would normally be needed.
- the silver turns a bright golden color due to the deposition on the oxide layer of a relatively large amount of metallic caesium.
- the etching step described above prevents such iiow and consequent irregularities.
- the etching insures that the caesium will be deposited uniformly upon the silver oxide.
- the cathode is sensitive only to the point that metallic caesium would give a photoelectric, response and in addition, the walls of the tube have enough metallic caesium thereon to cause sufficient leakage to prevent proper operation of the device.
- I then readmit oxygen'. and the caesiumsurface changes color and appears almost black. Oxygen again is admitted until all conductivity along the Walls of the device is killed. If no convenient connection can be made within the tube to determine Whether or not conductivity across a link is destroyed, then I may prefer to insert a pair of spaced contacts l and d and join them by a circuit concerning a battery 9 and an indieating device ill. necessary in specific cases where contacts for determining leakage cannot readily be obtained with the normal electrode structure.
- the thermionic emission point has been reached, and I have foundthat the peak of the .photoelectric current is reached when the thermionic current lis between zero andl one hundred microamperes from a surface area of apprommately nine' square inches at 200 centigrade.
- the method of forming photoelectrlc surfaces in an envelope comprising depositing a silver surface therein, oxidizing said silver surface admitting an excess of alkali metal, admitting oxygen until all metal other than that directly assoelated withl said silver oxide is changed to alkali metal oxide, and continuing the admission of oxygen until thermionic emission appears from said surface at 200 centigrade.
- a photoelectric surface comprising in order a silver layer, a' silver oxide layer, a caesium metal layer, and a caesium oxide layer.
- a method of preparing a silver surface to receive a deposit of photoelectric material which comprises the step of etching said surface in at hydrogen flame.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Image-Pickup Tubes, Image-Amplification Tubes, And Storage Tubes (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL51128D NL51128C (en:Method) | 1936-08-18 | ||
US96613A US2128582A (en) | 1936-08-18 | 1936-08-18 | Photoelectric surface |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US499891XA | 1936-08-18 | 1936-08-18 | |
US96613A US2128582A (en) | 1936-08-18 | 1936-08-18 | Photoelectric surface |
Publications (1)
Publication Number | Publication Date |
---|---|
US2128582A true US2128582A (en) | 1938-08-30 |
Family
ID=26727781
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US96613A Expired - Lifetime US2128582A (en) | 1936-08-18 | 1936-08-18 | Photoelectric surface |
Country Status (2)
Country | Link |
---|---|
US (1) | US2128582A (en:Method) |
NL (1) | NL51128C (en:Method) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2440917A (en) * | 1946-03-08 | 1948-05-04 | Farnsworth Res Corp | Phototube cathode formation |
US2507359A (en) * | 1943-01-27 | 1950-05-09 | Herbert Friedman | Automatic fire alarm |
US5314363A (en) * | 1993-06-08 | 1994-05-24 | Itt Corporation | Automated system and method for assembling image intensifier tubes |
-
0
- NL NL51128D patent/NL51128C/xx active
-
1936
- 1936-08-18 US US96613A patent/US2128582A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2507359A (en) * | 1943-01-27 | 1950-05-09 | Herbert Friedman | Automatic fire alarm |
US2440917A (en) * | 1946-03-08 | 1948-05-04 | Farnsworth Res Corp | Phototube cathode formation |
US5314363A (en) * | 1993-06-08 | 1994-05-24 | Itt Corporation | Automated system and method for assembling image intensifier tubes |
Also Published As
Publication number | Publication date |
---|---|
NL51128C (en:Method) |
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