US2118979A - Means for preventing crust formations on the walls of boilers - Google Patents

Means for preventing crust formations on the walls of boilers Download PDF

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US2118979A
US2118979A US733692A US73369234A US2118979A US 2118979 A US2118979 A US 2118979A US 733692 A US733692 A US 733692A US 73369234 A US73369234 A US 73369234A US 2118979 A US2118979 A US 2118979A
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boiler
current
winding
boilers
walls
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US733692A
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Mazza Plinio Sergio Davide
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • C23F13/04Controlling or regulating desired parameters

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  • My invention relates to means for protecting the walls of steam boilers or similar apparatus against scales, incrustations and corrosions.
  • the method according to my invention consists, providing in theseveral parts of the steam boiler or similar apparatus in which incrustations are to be prevented, electric charges which are equal influence of a temperature increase.
  • Hie invention also provides for passing pulsating current or preferably alternating current through the acquires a positive charge which keeps the elecs gr m lly represented at I.
  • Fig. 1 is a diagram showing a simple arrangement for performing themethod according to my invention
  • Fig. 2 diagrammatically shows another arrangement
  • Fig. 3 diagrammatically shows the arrangement of the circuits which lead the electric cur- 10 rent through the boiler
  • Fig. 4 diagrammatically shows the arrangement of the plant with a boiler which is in a position to receive electric charges from an external source
  • Fig. 5 is a diagrammatic view illustrating the 15 movebie ,inounting of the transformer secondary.
  • the boiler or similar apparatus in which incrustations are' to be prevented is dia- On opposite ends of the boiler, and in conveniently deter- 20 mined points of same, are connected the terminals of an electric circuit which include the secondary winding 2 of a transformer.
  • the transformer may be provided with a magnetic core, and the primary 3 is connected with the 5 terminals of a source of alternating current 6 of any voltage and frequency.
  • the transformer ' is electrically connected with a potentiometer l which is fed by a source 5 of direct current hav- 30 ing a suitable voltage.
  • Both windings 2 and I of the transformer are magnetically coupled with each other and the winding 2 is movable relatively to the winding 3, in order that, the electro-dynamic reactions between the coils which 35 are created in both windings, may automatically vary according to the current which flows in the same;
  • the windingl is brought back to its resting position by any suitable means, for instance by gravity or by the action of a direct electric 40 field.
  • the secondary winding 2 is mechanically connected with the arm of the potentiometer I.
  • Fig. 5 illustrates a suitable arrangement wherein the secondary winding is movable relative to the primary winding.
  • the primary winding 3 is stationary and the secondary winding 2 may slide along the magnet core ,3).
  • the weight of the secondary winding is balanced by the counterweight 34 connected therewith bymean's of a flexible wire ll, the latter passing around a pulley g 36 which actuates a cam 31;
  • the cam 3! acts. upon a cbntact arm 38 of the potentiometer 4.-
  • the circuit which permits electric current to how throughthe boiler is arranged in such amanner that the several parts of said boiler are charges which are equal and opposed to. the nat-' ural charges occurring in said boiler.
  • the alternating current has a disintegrating efiect upon the first layers of scale, because it communicates a vibratory movement to the molecules which adhere to the walls and moreover said vibrations, the amplitude of which is a function of the voltage, are larger in the hotter points which are more susceptible to scaling or incrustations.
  • Fig. 2 diagrammatically shows another embodiment which is more adaptable to cases when the boiler or other similar apparatus may be submitted to difi'er'ences of potential, as for example boilers of locomotives which roll on a rightof-way of an electrified railway line and where a current of a high intensity flows in the rails.
  • the source of. current 6 is still connected with the primary winding 3 of a transformer.
  • the secondary winding 2 isadapted to be rotated relative to the primary.
  • a rectifier I enables the alternatin current of source 6 to be transformed into a direct current, said current being suitably filtered by a choke coil 8 and condensers 9. Said direct current passes into thepotentiometer l the arm of which is still connected with middle part of the secondarywinding 2.
  • Thesecondary 2 is connected with the windings i0 and H, one of which, for instance the winding ll, may be variablycoupled with a third winding is in a manner similar to that described in connection with winding 2 relative to the winding 3.
  • the coil I2 is connected across the potentiometer 4 so that direct current flows therein.
  • the winding H is mechanically connected with the arms of two potentiometers i3, ll, in which also flows a direct current coming from the rectifier.
  • the windings II, II, and the potentiometers l3, ll, are adapted to be connected with the boiler at Ii.
  • the coupling of windings 2, 3 of the transformer may also be modified as in the preceding embodiment, so that the changes of voltage, also cause the operation of the potentiometer 4.
  • the current which fiows through winding il induces therein a field which reacts upon the field produced in winding ii. If the current is alternating and without any effect upon the scaling phenomena of the boiler, the coupling between the windings Ii and I2 is not altered which leaves the potentiometers II, II, in com position. If such current is direct. the field of the winding ll reacts upon. the field of winding l2 and modifies the coupling between both of said windings and consequently operates the potentiometers l3 and I4 so as to cause the boiler to receive a current which cancels the occasional current which was flowing through the same.
  • Fig. 3 diagrammatically shows the 'eie'otrie" ment of a boiler 2
  • This arrangement has the drawbackin that the appearance of charges-upon the boiler walls causes a current to take place, which may oppose the effects of the current employed according to my method.
  • auxiliary current sources 23 are located in suitable determined places. Such sources have a suitable voltage for producing a current, which is opposite to the current, towards 'the boiler from the hull.
  • the plant may be provided with thermionic lamps for regulating the current sent into the boiler.
  • My invention applies for preventing incrustations and corrosions of boilers or similar apparatiisofanytypeandforanyuse.
  • Means for protecting the walls of boilers and similar apparatus against scale, incrustations and corrosions comprising a transformer including primary and secondary windings, a boiler connected with said secondary winding, a potentiometer connected with the central point of said secondary winding, said secondary winding being movable relatively to the primary winding in response to temperature difierences in said boiler, and means for transmitting movement of said secondary winding to said potentiometer to vary the adjustment of the latter.
  • a boiler including primary and secondary windings, the secondary winding being connected with said boiler and being movable relative to the primary winding, means for impressing an electric charge on said boiler, and means connecting said movable secondary winding with said charge impressing means to regulate the latter.
  • v and similar apparatus against scale, incrustations and corrosions comprising a boiler, a transformer including primary and secondary windings, the secondary winding being connected with said boiler and being movable relatively to the primary winding, means for impressing an electric charge on said boiler, and means connecting said movable secondary winding'with said charge impressing means to regulate the latter,

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Ac-Ac Conversion (AREA)
  • Control Of Steam Boilers And Waste-Gas Boilers (AREA)

Description

May 31, 1938. P. s. MAZZA 1 ,9
MEANS FOR PREVENTING CRUST FORMATION S ON THE WALLS OF BOILERS Filed July 3, 1934 Patented May 3.1, 1938 UNITED STATES' PATENT OFFlCE- MEANS FOR PREVENTING oaUs'r roar muons N 'rna WALLS or normas Plinio Sergio Davide Mam. Paris, France- I .Applicaiionluly a. 1934. Serial No. 733,692
I In France July-19, 1m
4 Claims. .(Cl. 2iM-25) My invention relates to means for protecting the walls of steam boilers or similar apparatus against scales, incrustations and corrosions.
It has already been proposed, for preventing 5 the formation ofboiler scales, to apply a source of electric current for causing, the neutralization cathodes of thermionic tubes. When said electrons have moved out of the metal, said metal trons at an infinitely small distance away from the wall. The negative charges of said electrons act upon the positive charges of the anions of salts and acids which are dissolved in the water of the boiler and, attract the same towards the wall. The equilibrium between all those forces is realized when anions have reached the wall upon which they strongly adhere. The positive charges of the wall act in the same manner upon the cations. The equilibrium or cancellation of charges is realized when said cations have placed themselves above the bed of anions. All charges being cancelled, the metal continues emitting electrons and the above described phenomenon occurs again indefinitely.
The method according to my invention consists, providing in theseveral parts of the steam boiler or similar apparatus in which incrustations are to be prevented, electric charges which are equal influence of a temperature increase. Hie invention also provides for passing pulsating current or preferably alternating current through the acquires a positive charge which keeps the elecs gr m lly represented at I.
but opposite to those which appear under the' embodiment of plant which realizes the method according to my invention:-
Fig. 1 is a diagram showing a simple arrangement for performing themethod according to my invention, 5
Fig. 2 diagrammatically shows another arrangement,
Fig. 3' diagrammatically shows the arrangement of the circuits which lead the electric cur- 10 rent through the boiler,
Fig. 4 diagrammatically shows the arrangement of the plant with a boiler which is in a position to receive electric charges from an external source,
Fig. 5 is a diagrammatic view illustrating the 15 movebie ,inounting of the transformer secondary. In Fig. 1, the boiler or similar apparatus in which incrustations are' to be prevented, is dia- On opposite ends of the boiler, and in conveniently deter- 20 mined points of same, are connected the terminals of an electric circuit which include the secondary winding 2 of a transformer. The transformer may be provided with a magnetic core, and the primary 3 is connected with the 5 terminals of a source of alternating current 6 of any voltage and frequency. -The approximate mid-point. of the secondary 2,0! the transformer 'is electrically connected with a potentiometer l which is fed by a source 5 of direct current hav- 30 ing a suitable voltage. Both windings 2 and I of the transformer are magnetically coupled with each other and the winding 2 is movable relatively to the winding 3, in order that, the electro-dynamic reactions between the coils which 35 are created in both windings, may automatically vary according to the current which flows in the same; The windingl is brought back to its resting position by any suitable means, for instance by gravity or by the action of a direct electric 40 field. The secondary winding 2 is mechanically connected with the arm of the potentiometer I.
Fig. 5 illustrates a suitable arrangement wherein the secondary winding is movable relative to the primary winding. The primary winding 3 is stationary and the secondary winding 2 may slide along the magnet core ,3). The weight of the secondary winding is balanced by the counterweight 34 connected therewith bymean's of a flexible wire ll, the latter passing around a pulley g 36 which actuates a cam 31; The cam 3! acts. upon a cbntact arm 38 of the potentiometer 4.- The circuit which permits electric current to how throughthe boiler is arranged in such amanner that the several parts of said boiler are charges which are equal and opposed to. the nat-' ural charges occurring in said boiler. Thus the electric field which keeps theelectrons near the boiler wall is cancelled and the electrons are attracted far away from the wall by the anions of salts. The charges of the electrons are cancelled. and the salts which precipitate deposit themselves on the bottom of the boiler in the form of a mud which does not adhere to the metal.
Furthermore, the alternating current has a disintegrating efiect upon the first layers of scale, because it communicates a vibratory movement to the molecules which adhere to the walls and moreover said vibrations, the amplitude of which is a function of the voltage, are larger in the hotter points which are more susceptible to scaling or incrustations.
The current which flows through the boiler is maintained constant as a result of the self regulation obtained with the transformer 2. 3. Each change of working conditions in the boiler causes a change of voltage at the terminals of the secondary I of the transformer, and a corresponding' change of voltage. due to the modification of flux and the displacement of said secondary winding relatively to the primary winding by reason of theelectro-dynamical reactions between the currents which flow in bothwindings. The reactions are balanced as above described, either by the weight of winding 2 or by a direct current magnetic field, or a counterweight as shown in Fig. 5.
Owing to the fact that the winding 2 is mechanically connected with the arm of the potentiometer l, the self regulation applies also to the direct current voltage supplied to the boiler.
Since the electrical resistance of metal increases with the temperature and since the circuit which feeds the boiler with current is arranged in such a manner that all its'parts are connected in series and in an order corresponding to their increasing temperature, a second regulation will thus be obtained and hence the hottest metallic parts which emit the larger quantity of electrons will receive a higher voltage, so that the charges which occur in said parts of the boiler will always be exactly balanced or destroyed.
Fig. 2 diagrammatically shows another embodiment which is more adaptable to cases when the boiler or other similar apparatus may be submitted to difi'er'ences of potential, as for example boilers of locomotives which roll on a rightof-way of an electrified railway line and where a current of a high intensity flows in the rails. In this modification, the source of. current 6 is still connected with the primary winding 3 of a transformer. The secondary winding 2 isadapted to be rotated relative to the primary.
A rectifier I enables the alternatin current of source 6 to be transformed into a direct current, said current being suitably filtered by a choke coil 8 and condensers 9. Said direct current passes into thepotentiometer l the arm of which is still connected with middle part of the secondarywinding 2.
Thesecondary 2 is connected with the windings i0 and H, one of which, for instance the winding ll, may be variablycoupled with a third winding is in a manner similar to that described in connection with winding 2 relative to the winding 3. The coil I2 is connected across the potentiometer 4 so that direct current flows therein. The winding H is mechanically connected with the arms of two potentiometers i3, ll, in which also flows a direct current coming from the rectifier. The windings II, II, and the potentiometers l3, ll, are adapted to be connected with the boiler at Ii. The coupling of windings 2, 3 of the transformer may also be modified as in the preceding embodiment, so that the changes of voltage, also cause the operation of the potentiometer 4.
If a current flowing in the boiler is in a position to trouble or even to cancel the current which is sent by the winding I, the current which fiows through winding il induces therein a field which reacts upon the field produced in winding ii. If the current is alternating and without any effect upon the scaling phenomena of the boiler, the coupling between the windings Ii and I2 is not altered which leaves the potentiometers II, II, in com position. If such current is direct. the field of the winding ll reacts upon. the field of winding l2 and modifies the coupling between both of said windings and consequently operates the potentiometers l3 and I4 so as to cause the boiler to receive a current which cancels the occasional current which was flowing through the same.
' Fig. 3 diagrammatically shows the 'eie'otrie" ment of a boiler 2| mounted in the hull of a ship and electrically connected with the hull II and consequently with the sea 22. This arrangement has the drawbackin that the appearance of charges-upon the boiler walls causes a current to take place, which may oppose the effects of the current employed according to my method. For remedying this drawback, auxiliary current sources 23 are located in suitable determined places. Such sources have a suitable voltage for producing a current, which is opposite to the current, towards 'the boiler from the hull.
The arrangement of the several parts of boilers which are locatedrin series in the circuit is obtained by the tentative method and obviously diifers according to the type of boiler.
The plant may be provided with thermionic lamps for regulating the current sent into the boiler.
My invention applies for preventing incrustations and corrosions of boilers or similar apparatiisofanytypeandforanyuse.
What I claim is:--
1. Means for protecting the walls of boilers of the secondary winding to said potentiometer to vary the adjustment of the latter.
2. Means for protecting the walls of boilers and similar apparatus against scale, incrustations and corrosions, comprising a transformer including primary and secondary windings, a boiler connected with said secondary winding, a potentiometer connected with the central point of said secondary winding, said secondary winding being movable relatively to the primary winding in response to temperature difierences in said boiler, and means for transmitting movement of said secondary winding to said potentiometer to vary the adjustment of the latter.
3. Means for protecting the walls of boilers,'
and similar apparatus against scale, incrustations and corrosions comprising a boiler, a transformer including primary and secondary windings, the secondary winding being connected with said boiler and being movable relative to the primary winding, means for impressing an electric charge on said boiler, and means connecting said movable secondary winding with said charge impressing means to regulate the latter.
4. Means for protecting the walls of boilers,
v and similar apparatus against scale, incrustations and corrosions comprising a boiler, a transformer including primary and secondary windings, the secondary winding being connected with said boiler and being movable relatively to the primary winding, means for impressing an electric charge on said boiler, and means connecting said movable secondary winding'with said charge impressing means to regulate the latter,
said charge impressing means being connected
US733692A 1933-07-19 1934-07-03 Means for preventing crust formations on the walls of boilers Expired - Lifetime US2118979A (en)

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FR2630100B1 (en) * 1988-04-15 1991-11-08 Freyne Claude METHOD AND DEVICE FOR TREATING WATER IN THE DISTRIBUTION NETWORK BY MODULATED DURATION ELECTRIC PULSES
CH682149A5 (en) * 1990-11-26 1993-07-30 Aquasal Kalkschutzanlagen Ag

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