US2097121A - Process for prevention and removal of foam in the manufacture of paper - Google Patents

Process for prevention and removal of foam in the manufacture of paper Download PDF

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Publication number
US2097121A
US2097121A US85806A US8580636A US2097121A US 2097121 A US2097121 A US 2097121A US 85806 A US85806 A US 85806A US 8580636 A US8580636 A US 8580636A US 2097121 A US2097121 A US 2097121A
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Prior art keywords
foam
paper
manufacture
preventing
removal
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Expired - Lifetime
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US85806A
Inventor
Fromm Richard
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Lehmann and Voss and Co
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Lehmann and Voss and Co
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/12Defoamers

Definitions

  • This invention relates to improvements in paper manufacture and is more particularly concerned with removing foam formed during the manufacture of paper and/or preventing the 5 formation of such foam.
  • foam may be removed or formation of foam prevented through the use of small quantities of phosphatides, particularly vegetable phosphatides.
  • the action is entirely as different from that of oils.
  • the action of the latter is more of a mechanical nature and the formation of foam is prevented only when a thick enough layer of oil has formed on the liquid, whereas, when phosphatides are used, the surface so tension of the foam, that is, of the surface active particles, is reduced.
  • the phosphatides, thin, are preferably used in solution.
  • the solution may be added to the pulp or aqueous suspension of fibrous material to prevent foam formation, or added after formation of foam to remove the same.
  • a process for preventing or removing foam during the manufacture of paper which comprises, introducing a material consisting essentially of a phosphatide to the aqueous suspension of fibrous material, and thereby preventing or removing foam.
  • a process for preventing or removing foam during the manufacture of paper which comprises introducing phosphatides in aqueous solution to the aqueous suspension of fibrous material, and thereby preventing or removing foam.
  • a process for preventing or removing foam during the manufacture of paper which comprises introducing a small quantity of vegetable phosphatides in aqueous solution to the aqueous suspensionof fibrous material, and thereby preventing or removing foam.
  • a process for preventing or removing foam during the manufacture of paper which comprises, introducing a substantially oil free solution of phosphatides to the aqueous suspension of fibrous material, and thereby preventing or removing foam.

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  • Paper (AREA)

Description

Patented Oct. 26, 1937 raocnss son. raavnmon OIFOAMINTHE PAPER Richard Fromm. Hamburg, Germany,
Lehman Germany No Drawing.
AND REMOVAL MANUFACTURE OI assis'norto Com Hambm'a',
Application June 17, 1936, Serial In Germany June 28, 1935 4 Claims. (CI- 92-21) This invention relates to improvements in paper manufacture and is more particularly concerned with removing foam formed during the manufacture of paper and/or preventing the 5 formation of such foam.
At various manufacturing phases in the paper industry, a heavy formation of foam often takes place through the presence of surface active substances which is very objectionable. To avoid this, various expedients have been resorted to, for example, ether has been poured on the material or oil has been added to the paper pulp. Both of these prior processes have disadvantages, ether being inflammable and toxic and oils causing spots on'the finished paper. More recently attempts have been made to solve the foam problem and to overcome these disadvantages, by the use of solutions of oils in organic solvents. However, relatively large quantities of these expensive sub-- stances are required.
I have found that foam may be removed or formation of foam prevented through the use of small quantities of phosphatides, particularly vegetable phosphatides. The action is entirely as different from that of oils. The action of the latter is more of a mechanical nature and the formation of foam is prevented only when a thick enough layer of oil has formed on the liquid, whereas, when phosphatides are used, the surface so tension of the foam, that is, of the surface active particles, is reduced.
The phosphatides, thin, are preferably used in solution.
which may comprise leci- Such a solution is practically free from oil, and the to danger of spots such as are caused by oils or mixtures of oils with volatileorganic solvents, is entirely avoided.
The solution may be added to the pulp or aqueous suspension of fibrous material to prevent foam formation, or added after formation of foam to remove the same.
when the first drop of the solution is added,
' the foam bubbles burst and it requires but very small quantities to remove the foam completely. In the manufacture of paper, if the formation of foam takes place, such as, during the washing of rags, during the treatment of old paper, or at the strainer, such foam may be removed immediately by the addition of grams of a 10% aqueous solution of vegetable phosphatides. The process of my invention, however, is not limited to the foregoing quantity and solution concentration which are exemplary o Having described my invention, I claim:
1. A process for preventing or removing foam during the manufacture of paper, which comprises, introducing a material consisting essentially of a phosphatide to the aqueous suspension of fibrous material, and thereby preventing or removing foam.
2. A process for preventing or removing foam during the manufacture of paper which comprises introducing phosphatides in aqueous solution to the aqueous suspension of fibrous material, and thereby preventing or removing foam.
8. A process for preventing or removing foam during the manufacture of paper which comprises introducing a small quantity of vegetable phosphatides in aqueous solution to the aqueous suspensionof fibrous material, and thereby preventing or removing foam.
4. A process for preventing or removing foam during the manufacture of paper, which comprises, introducing a substantially oil free solution of phosphatides to the aqueous suspension of fibrous material, and thereby preventing or removing foam.
RICHARD FROM.
US85806A 1935-06-26 1936-06-17 Process for prevention and removal of foam in the manufacture of paper Expired - Lifetime US2097121A (en)

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DE2097121X 1935-06-26

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2429030A (en) * 1941-08-22 1947-10-14 West Virgin A Pulp And Paper C Methods of suppressing foam on paper stock
US2442768A (en) * 1939-11-24 1948-06-08 Dearborn Chemicals Co Method of conditioning water
US2639989A (en) * 1946-04-25 1953-05-26 United States Gypsum Co Treatment of cellulosic pulps
US2645617A (en) * 1948-11-06 1953-07-14 Gen Aniline & Film Corp Paper pulp foam inhibitor
US2923688A (en) * 1958-01-29 1960-02-02 American Cyanamid Co Composition of matter for the control of foam
US3146158A (en) * 1962-04-30 1964-08-25 Kimberly Clark Co Inhibiting foaming of cellulose slurries containing wet strength resins
US20110278496A1 (en) * 2010-05-14 2011-11-17 Arr-Maz Custom Chemicals, Inc. Defoaming composition for high acid strength media

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2442768A (en) * 1939-11-24 1948-06-08 Dearborn Chemicals Co Method of conditioning water
US2429030A (en) * 1941-08-22 1947-10-14 West Virgin A Pulp And Paper C Methods of suppressing foam on paper stock
US2639989A (en) * 1946-04-25 1953-05-26 United States Gypsum Co Treatment of cellulosic pulps
US2645617A (en) * 1948-11-06 1953-07-14 Gen Aniline & Film Corp Paper pulp foam inhibitor
US2923688A (en) * 1958-01-29 1960-02-02 American Cyanamid Co Composition of matter for the control of foam
US3146158A (en) * 1962-04-30 1964-08-25 Kimberly Clark Co Inhibiting foaming of cellulose slurries containing wet strength resins
US20110278496A1 (en) * 2010-05-14 2011-11-17 Arr-Maz Custom Chemicals, Inc. Defoaming composition for high acid strength media
US9144758B2 (en) * 2010-05-14 2015-09-29 Arr-Maz Custom Chemicals, Inc. Defoaming composition for high acid strength media

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