US2076572A - Free cutting alloys - Google Patents

Description

Patented Apr. 13, 1937 UNITED STATES 2,076,572 FREE-CUTTING ALLOYS Louis W. Kcmpf and Walter A. Dean, Cleveland, Ohio, 'assignors to Aluminum Company of America, Pittsburgh, Pa., a corporation 'of Pennsylvania No Drawing. Application December 28, 1935.

Serial No. 56,546

Claims. (01. 75-440) The invention relates to aluminum base alloys and is particularly concerned with aluminum base alloys containing copper, tin and zinc.

Aluminum base alloys containing between 3 per 5 cent'and 12 per cent of copper havebeen widely used heretofore. The copper imparts good casting characteristics and increases the tensile strength, yield strength, .and hardness of the alloy. In the lower portion of the copper range the alloy may be mechanically deformed by the well known commercial processes such as rolling, forging, drawing, or extrusion. Alloys containing more than about 6 per cent copper are generally used in the cast condition. Throughout the en- 15 tire range of 3 to 12 per cent copper, however, the

alloys are susceptible to variations and improvements in their physical properties by thermal treatments.

The physical properties of the foregoing type of aluminum-copper alloy in the solution heat treated and aged conditions are greatly improved by the 'addition of from 0.005 to 0.1 per cent of tin as described in co-pending application No. 606,756 and U. S. Patent 2,022,686, issued December 3, 1935. The small amount of tin is particularly useful in increasing the yield strength of the heat treated and aged alloy. The use of tin in the aforesaid proportions does not substantially change the working characteristics. of the alloy whereas special precautions must be taken to roll or forge alloys containing a larger amount of tin. The strength of the alloy, and to some extent its casting qualities, may be further improved by the addition of 0.1 to 3 per cent of zinc. Be-

cause of the high strength which is attainable in these alloys when heat treated and aged, they are generally used in this condition. Our invention which is described hereinbelow, is directed to improving the machining quality of such alloys.

There are, however, some applications wherein aluminum-copper-tin-zinc alloys as hereinabove disclosed might be conveniently and profitably used except for an inherent disadvantage which militates against their use in the production of certain articles requiring exacting machining operations. Mechanical cutting operations such as drilling, shaping, or lathe-cutting are successfully carried out only by using certain precautions which increase the cost of production and perhaps favor the choice of another metal.

or alloy which can be machined more readily but which is .not so desirable in other respects, as for example, in physical properties. When alloys are difficult to machine this disadvantage becomes 65 evident, in many cases, through rapid wear'of the cutting tool edge, so that frequent tool re-sharpening is required. Despite continual lubrication the machined surface is roughand irregular, and the chip has a tendency to form a continuous curl or spiral which often fouls the tool or the moving 5 parts of the machine; It is immediately apparent that there is need for an alloy of good working characteristics and satisfactory physical properties, yet possessing such favorable machining properties that the complete machining opera- 10 tions may be performed economically and successfully and may be productive of a pleasing surface appearance.

Accordingly an object of our invention is the provision of an aluminum base alloy containing 15 from about 3 per cent to about 12 per cent of copper, from about 0.005 to about 0.1 per cent of tin, and from about 0.1 per cent to about 3.0 per cent of zinc which may be readily and economically machined. 20

Our invention resides in the discovery that the I foregoing object is effected by the addition of two or more of the elements lead, thallium, cadmiumorbismuth. The aluminum-copper-tin-zinc alloys to which these elements are added in the 25 proportions'specified below, are known as free cutting or free machining alloys because they can be machined more rapidly than similar a1- loys without these elements and yet have as good or a better finished surface. tended series of investigations we have discovered that these four metals when added to aluminum-copper-tin-zinc alloys, form a class of alloying elements by reason of their favorable effect upon the machining properties of these 5 alloys. In recognition of this effect we term lead, thallium, cadmium and bismuth free machining elements. We have further discovered that the simultaneous presence of two or more of these elements is productive of an improvement 40 in free machining characteristics which is considerably greater than that caused by the presence of the same total amount of a single free machining element. For example, the addition of 0.5 per cent of lead and 0.5 per cent of bis- 45 muth to an aluminum base alloy containing about 5 per cent of copper, 0.05 per cent of tin, and 1.5 per cent of zinc effects a greater improvement in machining quality than does the addition of 1.0 per cent of either lead or bismuth 50 singly.

These four elements, we believe, are unique with respect to their effect on the machining characteristics of aluminum-copper-tin-zinc alloys. It is a fortunate circumstance, therefore,

After an exthat they are also of relatively low melting point,

a fact which makes possible their addition to molten aluminum in the pure state, without the intervention of so-called rich alloys. As a mat- 5 ter of fact, we have observed that of all the metals whose melting point is lower than about 327 C., the melting point of lead, the four elements we have selected are the only ones, with the exception of tin which is not desired in this alloy in free cutting amounts, which are commercially suitable and which impart free cutting characteristics but do not have an undesirable effect on the fundamental physical properties of the base alloy.

The total amount of free machining elements should not be less than about 0.05 per cent since below this amount'there is scarcely any advantageous effect. We have determined that a maximum limit of about 6 per cent total of two or more of the free machining elements is suflicient for satisfactory commercial results, since although the free machining efiect persists beyond this amount, certain of the other physical properties may be unfavorably afiected.

Aluminum-copper-tin-zinc alloys containing two or more of the free machining elements, lead, thallium, cadmium and bismuth maybemachined more rapidly, with less tool wear, less tool sharpening, better quality of chip and better machined surface than the same base alloys without the free machining additions, and in fact better than thesame base alloys containing an equivalent total amount of a single free machining element. Since aluminum base alloys containing from 3 to 12 per cent of copper have a wide variety of applications we list several alloys each of which may be said tobe preferred for a particular purpose. As an alloy for mechanical deformation we suggest an aluminum base alloy containing 5 per cent of copper, 0.05 per cent of tin, 1.5 per cent of zinc, and a total of 1 per cent of free cutting constituents, for example, 0.5 per cent of bismuth and 0.5 per cent of cadmium, the balance being aluminum. For-an alloy with excellent casting characteristics to be used in the unworked condition we suggest an alloy containing 10 per cent of copper, 0.05 per cent of tin, 2.0 per cent of zinc and a total of 3 per cent of free machining elements, the balance being aluminum.

For certain purposes, notably the improvement of tensile strength, hardness and grain structure, the alloys as hereinabove disclosed may be improved by the addition of one or more of the group of elements composed of molybdenum, va-

nadium, titanium, tungsten, zirconium, and chromium. From 0.05 to 1 per cent of any one of these elements may be'used alone, but if more than one is employed the total amount should not exceed about 2 per cent.

It is characteristic of the elements lead, tin, thallium, cadmium, and bismuth that they form with aluminum a series of alloys of limited liquid solubility. We have reason to believe that the free machining elementsare the only ele- 65 ments which exhibit this characteristic, with the possible exception of several'metals which are not regarded as having any commercial promise as additions .to aluminum base alloys. Within the range disclosed and claimed however the 70 free machining elements may be added without unusual difficulty. We suspect that this char acteristic feature of the disclosed elements may be one of the significant factors which contribute to their free machining effect. We believe that this effect is further strengthened by distributing the free machining constituent relatively homogeneously throughout the solid matrix, since these free machining constituents are also practically insoluble in the solid aluminum base.

The free machining alloys which have been described hereinabove may be subjected to the thermal treatments, well known in the art to improve their strength and hardness. We have found that a solution heat treatment and subsequent aging does not impair the free machining quality of the alloys andin many instances the treatment even tends to improve this property. For many purposes a relatively high strength and hardness are necessary to the successful performance of the machined article and hence the alloy must be heat treated. V This treatment is generally applied prior to the machining operation.

As hereinabove indicated the free machining elements, by reason of their low melting point, may be added to the molten aluminum alloy in pure metallic form. However, since some diiilculty may be encountered in introducing them in the higher percentages of our disclosed range we prefer to use the method which is more fully described in U. S. Patent No. 1,959,029, issued March 15, 1934. Briefly it involves heating the melt to a somewhat higher temperature than is customary, and'vigorously stirring it in excess of a critical period of time.

The term aluminum as used herein and in the appended claims embraces the usual impurities found in aluminum-ingot of commercial grade or picked up in the course of the ordinary handling operations incident to melting practice.

We claim: r

1. An aluminum base alloy consisting of about 5 percent copper, 0.05 per cent tin, 1.5 per cent zinc, 0.5 per cent lead and 0.5 per cent bismuth, the balance being aluminum.

2. An aluminum base alloy consisting of about 5 per cent copper, 0.05 per cent tin, 1.5 per cent zinc, 0.5 per cent bismuth and 0.5 per cent cadmium, the balance being aluminum.

3. A free cutting alloy containing from 3 to 12 per cent of copper, from 0.005 to 0.1 per cent of tin, from 0.1 to 3 per cent of zinc and a total of from 0.05 to 6 per cent of at least two of the elements from the following metals, lead, thallium, cadmium, and bismuth, to improve its machining properties, the balance being substantially aluminum.

4. A free cutting alloy containing from 3 to 12 per cent of copper, from 0.005 to 0.1 per cent of tin, 0.1 to 3 per cent of zinc, from 0.05 to 2 per cent of hardening metal from the group composed of molybdenum, vanadium, titanium, tungsten, zirconium and chromium, and a total of from 0.05 to 6 per cent of at least two of the elements from the following metals lead, thallium. cadmium, and bismuth, to improve its machining properties, the balance being substantially aluminum.

5. An aluminum base alloy consisting of about 5 per cent copper, 0.05 per cent tin, 1.5 per cent zinc, 0.5'per cent cadmium, and 0.5 per cent lead, the balance being aluminum.

LOUIS W. KEMPF. WALTER A. DEAN.