US2073033A - Photographic duplicating process - Google Patents

Photographic duplicating process Download PDF

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US2073033A
US2073033A US31609A US3160935A US2073033A US 2073033 A US2073033 A US 2073033A US 31609 A US31609 A US 31609A US 3160935 A US3160935 A US 3160935A US 2073033 A US2073033 A US 2073033A
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layer
dye
gelatin
matrix
image
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US31609A
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Szasz Geza
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/22Subtractive cinematographic processes; Materials therefor; Preparing or processing such materials
    • G03C7/25Dye-imbibition processes; Materials therefor; Preparing or processing such materials

Definitions

  • This invention relates to a photographic procress for duplicating printed matter, maps and other documentary representations having strongly contrasting lines, the process being characterized by a faithful reproduction of the original and the facility or rapidity with which it can be carried out.
  • the invention also includes an improved gelatin matrix for use in the process.
  • a washed out relief matrix is photographically produced in a silver halide gelatin emulsion layer carried by a suitable flexibletransparent base.
  • This silver halide gelatin emulsion layer should 15 be one capable of reproducing strong contrasts.
  • the relief matrix is formed by selectively exposing the light sensitized gelatin layer in accordance with an original representation, and properly developing and treating the selectively exposed layer. This may be accomplished by exposing the gelatin layer to light passed through a photographic negative of the original representation, and then developing the gelatin layer with pyrocateohol developer-free from sulphite or with a similar developer capable of tanning the gelatin layer in proportion to the exposure thereof.
  • the making of the negative from which the matrix is formed may be accomplished photographically, by a reflex copying process or by contact printing.
  • the coloring of the gelatin layer renders it visible and accordingly, the operator can readily determine when all of the unexposed gelatin has been washed away. In this manner, a
  • the coloring substance so employed should be of such a nature that it does not react with the water soluble dyes which may be subsequently used in printing, and I have found that pigments 50 may be employed for this purpose.
  • the pigment may be incorporated in the silver halide gelatin layer by mixing it in the emulsion from which this layer is prepared.
  • the duplicating process may be carried out ac- 55 cording to two different methods of procedure.
  • the washed out relief matrix is colored with water soluble copying dye of high tinctorial power, such as methylene blue or methylene violet.
  • water soluble copying dye of high tinctorial power, such as methylene blue or methylene violet.
  • Such dyes are commonly used in the known hectographic inks. This can be done by the dusting process in which the matrix is moistened, then blotted to remove moisture from the areas not covered by the gelatin layer and then dusted with the dye in powdered form, the excess dry dye being shaken off. The dye adheres to the gelatin coated portions of the matrix which have retained some moisture, but does not adhere to the dry exposed base on which the gelatin is carried.
  • I may employ a dye layer formed of a highly concentrated water soluble dye provided with a binder and if necessary with wetting additions.
  • This dye layer may be formed by coating on a backing of paper or the like, a mixture comprising a dye of high tinctorial power, ,such as methylene blue or methylene violet, a binder, such as japan wax, and a moistening agent, such as glycerin.
  • the dye layer is pressed on to the matrix, the relief image portions of which have been previously moistened, andthe dye is thereby transferred to the relief image.
  • the dye image produced either by the dusting process or the dye layer procedure jdescribed 'above, is then transferred to a second layer of gelatin or similar material having glycerin in-. corporated therein to keep it moist, this being accomplished by-squeezing the matrix against the second layer. This forms on the second'layer printing areas covered with dye.
  • the second gelatin layer forms a printing matrix from which impressions can be made on paper or other material in considerable numbers.
  • a process of duplicating printed matter and other documents having strongly contrasting lines comprising forming a matrix carrying a washed out relief image-by selectively exposing a light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carried on a flexible imperforate support and being capable of reproducing strong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, applying a water soluble dye of high tinctorial power to the relief image of said layer to transfer the dye image thereto and makmatrix, pressing said matrix on a second gelatin ing impressions from the dye image on said second gelatin layer.
  • a process of duplicating printed matter and other documents having strongly contrasting lines comprising forming a matrix carrying a washed out relief image by selectively exposing a colored light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carried on a flexible imperforate support and being capable of reproducing strong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, applying a water soluble dye of high tinctorial' power to the relief image of said matrix, pressing said matrix on a second gelatin layer to transfer'the dye image thereto and making impressions from the dye image on said second gelatin layer.
  • a process of duplicating printed matter and other documents having strongly contrasting lines comprising forming a matrix carrying a washed out relief image by selectively exposing a light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carried on a flexible imperforate support and being capable of reproducing strong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, moistening the-relief image of the matrix, applying to the moistened relief image a dye of high tinctorial power in powdered form, pressing the matrix on a second gelatin layer to transfer the dye image thereto and making impressions from the dye image on said second gelatin layer.
  • a process of duplicating printed matter and other documents having strongly contrasting lines comprising forming a matrix carrying a washed out relief image by selectively exposing a light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carriedon a flexible imperforate support and being capable of reproducingstrong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, pressing a dye layer comprising a water soluble dye of high tinctorial power mixed with a binder and a moistening agent against the relief image of said matrix whereby the dye is applied to the relief image, pressing the matrix on a second gelatin layer to transfer the dye image thereto and making impressions from the dye image on said second gelatin layer.
  • a process of duplicating printed matter and other documents having strongly contrasting lines comprising preparing a negative of the original document, exposing a silver halide gelatin photographic emulsion layer carried on a flexible imperforate support and capable of reproducing strong contrasts to light through said negative, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, thereby forming a matrix constituting a positive washed out gelatin relief image of said original document on said support, moistening said gelatin relief, applying a hectographic ink thereto, transferring said ink from said relief to a hectographic gelatin printing layer, and making copies from the dye image on said hectographic layer.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)

Description

Patented Mar. 9, 1937 Geza Szasz,'Berlin, Germany No Drawing. Application July is, 1935, Serial No. 31,609. In Germany February 21, 1935 .5 Claims.
This invention relates to a photographic procress for duplicating printed matter, maps and other documentary representations having strongly contrasting lines, the process being characterized by a faithful reproduction of the original and the facility or rapidity with which it can be carried out. The invention also includes an improved gelatin matrix for use in the process.
In carrying out the process of the invention, a washed out relief matrix is photographically produced in a silver halide gelatin emulsion layer carried by a suitable flexibletransparent base. This silver halide gelatin emulsion layer should 15 be one capable of reproducing strong contrasts.
In general, the relief matrix is formed by selectively exposing the light sensitized gelatin layer in accordance with an original representation, and properly developing and treating the selectively exposed layer. This may be accomplished by exposing the gelatin layer to light passed through a photographic negative of the original representation, and then developing the gelatin layer with pyrocateohol developer-free from sulphite or with a similar developer capable of tanning the gelatin layer in proportion to the exposure thereof. The unexposed and untanned gelatin isthen washed out with warm water and a true image of the original, in the form of a washed out relief, is therebyobtained. The making of the negative from which the matrix is formed may be accomplished photographically, by a reflex copying process or by contact printing.
In accordance with the invention, I prefer to slightly color the silver halide gelatin layer forming the matrix with a suitable substance, as by this means I can accurately control the formation of the washed out relief to a remarkable de- 40 gree. The coloring of the gelatin layer renders it visible and accordingly, the operator can readily determine when all of the unexposed gelatin has been washed away. In this manner, a
matrix comprising a highly accurate and faithful image of the original is obtained.
The coloring substance so employed should be of such a nature that it does not react with the water soluble dyes which may be subsequently used in printing, and I have found that pigments 50 may be employed for this purpose. The pigment may be incorporated in the silver halide gelatin layer by mixing it in the emulsion from which this layer is prepared.
The duplicating process may be carried out ac- 55 cording to two different methods of procedure.
(Cl. ll-31.5)
According to one embodiment of the invention, the washed out relief matrix, produced as described above, is colored with water soluble copying dye of high tinctorial power, such as methylene blue or methylene violet. Such dyes are commonly used in the known hectographic inks. This can be done by the dusting process in which the matrix is moistened, then blotted to remove moisture from the areas not covered by the gelatin layer and then dusted with the dye in powdered form, the excess dry dye being shaken off. The dye adheres to the gelatin coated portions of the matrix which have retained some moisture, but does not adhere to the dry exposed base on which the gelatin is carried. As an alternative to the dusting process of dye application, I may employ a dye layer formed of a highly concentrated water soluble dye provided with a binder and if necessary with wetting additions. This dye layer may be formed by coating on a backing of paper or the like, a mixture comprising a dye of high tinctorial power, ,such as methylene blue or methylene violet, a binder, such as japan wax, and a moistening agent, such as glycerin.
The dye layer is pressed on to the matrix, the relief image portions of which have been previously moistened, andthe dye is thereby transferred to the relief image.
The dye image, produced either by the dusting process or the dye layer procedure jdescribed 'above, is then transferred to a second layer of gelatin or similar material having glycerin in-. corporated therein to keep it moist, this being accomplished by-squeezing the matrix against the second layer. This forms on the second'layer printing areas covered with dye. The second gelatin layer forms a printing matrix from which impressions can be made on paper or other material in considerable numbers.
I claim:
1. A process of duplicating printed matter and other documents having strongly contrasting lines, comprising forming a matrix carrying a washed out relief image-by selectively exposing a light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carried on a flexible imperforate support and being capable of reproducing strong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, applying a water soluble dye of high tinctorial power to the relief image of said layer to transfer the dye image thereto and makmatrix, pressing said matrix on a second gelatin ing impressions from the dye image on said second gelatin layer. 2. A process of duplicating printed matter and other documents having strongly contrasting lines, comprising forming a matrix carrying a washed out relief image by selectively exposing a colored light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carried on a flexible imperforate support and being capable of reproducing strong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, applying a water soluble dye of high tinctorial' power to the relief image of said matrix, pressing said matrix on a second gelatin layer to transfer'the dye image thereto and making impressions from the dye image on said second gelatin layer.
3. A process of duplicating printed matter and other documents having strongly contrasting lines, comprising forming a matrix carrying a washed out relief image by selectively exposing a light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carried on a flexible imperforate support and being capable of reproducing strong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, moistening the-relief image of the matrix, applying to the moistened relief image a dye of high tinctorial power in powdered form, pressing the matrix on a second gelatin layer to transfer the dye image thereto and making impressions from the dye image on said second gelatin layer.
4. A process of duplicating printed matter and other documents having strongly contrasting lines, comprising forming a matrix carrying a washed out relief image by selectively exposing a light sensitized silver halide gelatin layer in accordance with an original representation, said layer being carriedon a flexible imperforate support and being capable of reproducingstrong contrasts, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, pressing a dye layer comprising a water soluble dye of high tinctorial power mixed with a binder and a moistening agent against the relief image of said matrix whereby the dye is applied to the relief image, pressing the matrix on a second gelatin layer to transfer the dye image thereto and making impressions from the dye image on said second gelatin layer.
5. A process of duplicating printed matter and other documents having strongly contrasting lines, comprising preparing a negative of the original document, exposing a silver halide gelatin photographic emulsion layer carried on a flexible imperforate support and capable of reproducing strong contrasts to light through said negative, tanning the exposed portions of said layer with a developer and washing out the unexposed portions thereof, thereby forming a matrix constituting a positive washed out gelatin relief image of said original document on said support, moistening said gelatin relief, applying a hectographic ink thereto, transferring said ink from said relief to a hectographic gelatin printing layer, and making copies from the dye image on said hectographic layer.
GEZA SZASZ.
US31609A 1935-02-21 1935-07-16 Photographic duplicating process Expired - Lifetime US2073033A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2738727A (en) * 1951-05-07 1956-03-20 Block & Anderson Ltd Methods of preparing master copies for hectographic printing
US2852371A (en) * 1956-11-20 1958-09-16 Eastman Kodak Co Photographic duplicating process
US2898852A (en) * 1957-06-10 1959-08-11 Eastman Kodak Co Photomechanical spirit duplicating process
US2903964A (en) * 1955-01-24 1959-09-15 Eastman Kodak Co Photographic spirit duplicating process
US2949849A (en) * 1955-07-27 1960-08-23 Haloid Xerox Inc Stencil master making
US2955531A (en) * 1956-05-02 1960-10-11 Haloid Xerox Inc Stencil master formation
US3060025A (en) * 1959-11-03 1962-10-23 Du Pont Photopolymerization process of image reproduction
US3060026A (en) * 1961-01-09 1962-10-23 Du Pont Photopolymerization process of image reproduction
US3076406A (en) * 1954-09-28 1963-02-05 Dick Co Ab Duplicating method and element for use therein
US3088402A (en) * 1960-03-31 1963-05-07 Columbia Ribbon & Carbon Duplicating
US3093068A (en) * 1955-01-03 1963-06-11 Xerox Corp Method and apparatus for pattern reproduction
US3109367A (en) * 1955-01-03 1963-11-05 Xerox Corp Method for pattern reproduction
US3109366A (en) * 1955-01-03 1963-11-05 Xerox Corp Method for pattern reproduction
US3129661A (en) * 1960-03-31 1964-04-21 Columbia Ribbon & Carbon Novel duplicating processes
US3143066A (en) * 1954-01-05 1964-08-04 Xerox Corp Production of duplicating masters

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2738727A (en) * 1951-05-07 1956-03-20 Block & Anderson Ltd Methods of preparing master copies for hectographic printing
US3143066A (en) * 1954-01-05 1964-08-04 Xerox Corp Production of duplicating masters
US3076406A (en) * 1954-09-28 1963-02-05 Dick Co Ab Duplicating method and element for use therein
US3109367A (en) * 1955-01-03 1963-11-05 Xerox Corp Method for pattern reproduction
US3109366A (en) * 1955-01-03 1963-11-05 Xerox Corp Method for pattern reproduction
US3093068A (en) * 1955-01-03 1963-06-11 Xerox Corp Method and apparatus for pattern reproduction
US2903964A (en) * 1955-01-24 1959-09-15 Eastman Kodak Co Photographic spirit duplicating process
US2949849A (en) * 1955-07-27 1960-08-23 Haloid Xerox Inc Stencil master making
US2955531A (en) * 1956-05-02 1960-10-11 Haloid Xerox Inc Stencil master formation
US2852371A (en) * 1956-11-20 1958-09-16 Eastman Kodak Co Photographic duplicating process
US2898852A (en) * 1957-06-10 1959-08-11 Eastman Kodak Co Photomechanical spirit duplicating process
US3060025A (en) * 1959-11-03 1962-10-23 Du Pont Photopolymerization process of image reproduction
US3088402A (en) * 1960-03-31 1963-05-07 Columbia Ribbon & Carbon Duplicating
US3129661A (en) * 1960-03-31 1964-04-21 Columbia Ribbon & Carbon Novel duplicating processes
US3060026A (en) * 1961-01-09 1962-10-23 Du Pont Photopolymerization process of image reproduction

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