US2066918A - Light-sensitive material and a proc - Google Patents
Light-sensitive material and a proc Download PDFInfo
- Publication number
- US2066918A US2066918A US2066918DA US2066918A US 2066918 A US2066918 A US 2066918A US 2066918D A US2066918D A US 2066918DA US 2066918 A US2066918 A US 2066918A
- Authority
- US
- United States
- Prior art keywords
- light
- silver
- diazo
- picture
- sensitive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 21
- 238000000034 method Methods 0.000 description 24
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 24
- 230000008569 process Effects 0.000 description 23
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 20
- -1 amino diazo com pounds Chemical class 0.000 description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 12
- 150000008049 diazo compounds Chemical class 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 229910052709 silver Inorganic materials 0.000 description 12
- 239000004332 silver Substances 0.000 description 12
- 229910001961 silver nitrate Inorganic materials 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- 150000003378 silver Chemical class 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- 150000001555 benzenes Chemical class 0.000 description 6
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 125000003282 alkyl amino group Chemical group 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 230000001603 reducing effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- KSOWMDCLEHRQPH-UHFFFAOYSA-N 4-diazocyclohexa-1,5-dien-1-amine Chemical compound NC1=CCC(=[N+]=[N-])C=C1 KSOWMDCLEHRQPH-UHFFFAOYSA-N 0.000 description 2
- OHNKSVVCUPOUDJ-UHFFFAOYSA-N 5-nitro-1h-indene Chemical compound [O-][N+](=O)C1=CC=C2CC=CC2=C1 OHNKSVVCUPOUDJ-UHFFFAOYSA-N 0.000 description 2
- XEOVXGQVNWVRKG-UHFFFAOYSA-N 6-diazo-3-(diethylamino)cyclohexa-2,4-diene-1-carboxylic acid Chemical compound [N+](=[N-])=C1C(C=C(C=C1)N(CC)CC)C(=O)O XEOVXGQVNWVRKG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000001828 Gelatine Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- FRHBOQMZUOWXQL-UHFFFAOYSA-L ammonium ferric citrate Chemical compound [NH4+].[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FRHBOQMZUOWXQL-UHFFFAOYSA-L 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- JOYKCMAPFCSKNO-UHFFFAOYSA-N chloro benzenesulfonate Chemical compound ClOS(=O)(=O)C1=CC=CC=C1 JOYKCMAPFCSKNO-UHFFFAOYSA-N 0.000 description 2
- 229960004642 ferric ammonium citrate Drugs 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004313 iron ammonium citrate Substances 0.000 description 2
- 235000000011 iron ammonium citrate Nutrition 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 2
- YHYKLKNNBYLTQY-UHFFFAOYSA-N 1,1-diphenylhydrazine Chemical compound C=1C=CC=CC=1N(N)C1=CC=CC=C1 YHYKLKNNBYLTQY-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- MNURPFVONZPVLA-UHFFFAOYSA-N 2-chlorobenzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1Cl MNURPFVONZPVLA-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
- G03C1/62—Metal compounds reducible to metal
Definitions
- the present invention relates to light-sensitive material, capable of yielding positive pictures from a negative original and to a process of producing pictures therefrom.
- One object of the present invention is lightsensitive materials which are prepared by applying silver salts in mixture with light-sensitive diazo compounds upon or in a suitable support.
- the light-sensitive materials thus obtained yield rather good silverpictures, after exposure to light, after-treatment with alkalies or the like and fixation.
- All silver salts which are watersoluble may be used for the present invention, as for instance, silver nitrate.
- diazo compounds there may be used all such stable, light-sensitive diazo compounds. as yield, when exposed to light, decomposition products capable of exercizing a reducing-action on the exposed silver salt.
- Such di- 20 azo compounds are, for instance, amino diazo com pounds of the benzene or naphthalene series, which may be substituted in the nucleus or in the amino group, for instance, by alkyl, hydroxy groups, carboxy groups, sulfo groups, halogen or the like.
- the amino diazo compounds of the benzene series useful in the present invention are preferably obtained from amino compounds of the following general formula: R-NH2 wherein R stands for a benzeneor a naphthaleneradical being substituted in the nucleus by hydroxy, halogen, alkyl, oxalkyl, oxaryl, oxaralkyl.
- diazo compounds may be used as such, or in the form of salts, such as, for instance, sulfates, chlorobenzene-sulfonates, or the like.
- Another object of the present invention is the process of preparing pictures from the light-sen-
- the material is exposed to light under a design and thereby is obtained a positive picture from a negative design and vice versa.
- the. picture is treated with alkali or substances having an alkaline action, such as, for instance, ammonia, soda, borax, sodium acetate or the like, alone or in mixture with one another, and then subjected to a washing or fixating process, for instance, with sodium thiosulfate, in order to remove the substances which have not reacted.
- the formation of the picture probably takes place in such a way,.that the light acts upon the diazo compound which is rather sensitive to light, whereby the latter yields a. decomposition prodnot.
- This product which preferably has a reducing action, acts upon the silver salt with the formation of metallic silver, which action is completed by the subsequent treatment with a substance of alkaline action.
- the silver picture thus obtained is then fixed in the usual manner.
- the light-sensitive material can be prepared according to one of the methods usually employed in diazo type printing and in photography. It is possible, for instance, simply to apply an aqueous or an aqueous-alcoholic solution of the mixtures of diazo compounds and silver salts on a base, for instance, paper, gelatinized paper or a film from a cellulose derivative or cellulose hydrate; the preservatives known from the photoprinting industry, such as, for instance, metal salts, acids, dextrine, starch etc. may be added.
- the lightsensitive substances can also be applied on a base in a colloid, such as, for instance, gelatine, in a manner customary in the photographic industry.
- the proportion of the diazo salts and silver salts may vary within wide limits. According to the quantities of the two constituents, the kind of the diazo compounds, the silver salts and the substances added to the layer, and according to the after-treatment with alkaline agents, the tones vary from brown to black, and the gradation of the pictures varies, too.
- Other light-sensitive substances such as, for instance, ferric ammonium citrate, may be mixed with the layers, whereby more dark brown picturesare obtained.
- Ferric ammonium citrate has already been used together with silver salts for the preparation of light-sensitive layers, but when using the same quantities of silver, there cannot be obtained such rich and deep tones as according'to the present process.
- Lightsensitive material sensitized by means of a mixture of a water-soluble silver salt and a light-sensitive aromatic amino diazo compound of the benzene .series, the silver salt being used in sufiicient quantity to produce a silver picture.
- a process of preparing positive pictures from a negative design which comprises exposing to light under the design a light-sensitive material sensitized by means of a mixture of a water-soluble silver salt and a light-sensitive aromatic amino diazo compound of the benzene series, the
- silver salt being used in sufficient quantity to produce a silver picture, subjecting the picture thus obtained to the action of a. substance of alkaline acticnand then toa fixing process.
- a process of preparing positive pictures from a negative design which comprises exposing to light under the design a light-sensitive material sensitized by means of a mixture of silver nitrate and 1-diazo-4-diethylaminobenzene-2-carboxylic acid, subjecting the picture thus obtained to the action of a substance of alkaline action and then to a fixing process.
- a process of preparing positive pictures from a negative design which comprises exposing to light under the design a light-sensitive material sensitized by means of a mixture of silver nitrate and 4-diazodiphenylamine, subjecting the picture thus obtained to the action of a substance of alkaline action and then to a fixing process.
- a process of preparing positive pictures from a negative design which comprises exposing to light under the design a light-sensitive material sensitized by means of a mixture of silver nitrate and 1-diazo-4-aminobenzene, subjecting the picture thus obtained to the action of a substance of alkaline action and then to a fixing process.
- Light-sensitive material sensitized by means of a water-soluble silver salt and a light-sensitive aromatic diazo compound, the light decomposition products of which have reducing properties for the exposed silver salt, the silver salt being used in sufiicient quantity to produce a silver picture.
- Light-sensitive material sensitized by means of a. water-soluble silver salt and a light-sensitive aromatic diazo compound, which is substituted in the para-position to the diazo group by an amino group, the silver salt being used in sufiicient quantity to produce a silver picture.
- a process of preparing positive pictures from a negative design which comprises exposing to )ight under the design a light-sensitive material sensitized by means of a mixture of a watersoluble silver salt and a light-sensitive aromatic diazo compound, the light decomposition products of which have reducing properties for the exposed silver salt, the silver salt being used in sufficient quantity to produce a silver picture, and subjecting the picture thus obtained to the action of a substance of alkaline action and then to a fixing process.
- a process of preparing positive pictures from a negative design which comprises exposing to .light under the design a light-sensitive rnaterial sensitized. by means of a water-soluble silver salt and a light-sensitive aromatic diazo compound, which is substituted in the para-position to the diazo group by an amino group, the silver salt being used in sufficient quantity to produce a silver picture, and subjecting the picture thus obtained to the action of a substance of alkaline action and then to a' fixing process.
- X stands fora diazo group
- Y stands for a member of the group consisting of hydrogen and an alkyl-amino group
- Z stands for a member of the group consisting of hydrogen, hydroxy, amino, alkyl-amino,andaryl-aminoof the benzene series, only one of the substituents Z and Y standing for hydrogen, the silver salt being used in sufficient quantity to produce a silver picture.
- a process of preparing positive pictures from a negative design which comprises exposing to light under the design, a light-sensitive material sensitized by means of a water-soluble silver salt and a light-sensitive diazo compound of the benzene series conforming to the following structural formula:
- X stands for a diazo group
- Y stands for a, member of the group consisting of hydrogen and an alkyl-amino group
- Z stands for a member of the group consisting of hydrogen, hy droxy, amino, alkyl-amino, and aryl-amino of the benzene series, only one of the substituents Z and Y standing for hydrogen, the silver salt being used in sufficient quantity to produce a silver picture and subjecting the picture, thus obtained, to the action of a substance of alkaline action and, then, to a fixing process.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK0122203 | 1931-09-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2066918A true US2066918A (en) | 1937-01-05 |
Family
ID=7245047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2066918D Expired - Lifetime US2066918A (en) | 1931-09-21 | Light-sensitive material and a proc |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US2066918A (en, 2012) |
| FR (1) | FR744706A (en, 2012) |
| GB (1) | GB391677A (en, 2012) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2618555A (en) * | 1949-04-09 | 1952-11-18 | Kalle & Co Ag | Process for positive diazotype and negative metal reduction images and light-sensitive material therefor |
| US2741558A (en) * | 1952-03-11 | 1956-04-10 | Grinten Chem L V D | Process for the manufacture of diazotype copies |
| US2773768A (en) * | 1951-03-20 | 1956-12-11 | Grinten Chem L V D | Light-sensitive diazotype material |
| US2780547A (en) * | 1954-06-30 | 1957-02-05 | Bruning Charles Co Inc | Diazotype photoprinting materials and processes for preparing same |
| US2929709A (en) * | 1951-07-10 | 1960-03-22 | Philips Corp | Photographic process |
| US2952538A (en) * | 1950-07-25 | 1960-09-13 | Philips Corp | Photographic process |
| US3007795A (en) * | 1955-02-11 | 1961-11-07 | Agfa Ag | Process for the production of laterally non-reversed positive copies by heat development |
| US3409438A (en) * | 1963-08-26 | 1968-11-05 | Minnesota Mining & Mfg | Photosensitive heat developable copysheet |
| US4066456A (en) * | 1974-12-10 | 1978-01-03 | Gaf Corporation | Incorporated carboxy substituted p-phenylenediamine color developer |
-
0
- FR FR744706D patent/FR744706A/fr not_active Expired
- US US2066918D patent/US2066918A/en not_active Expired - Lifetime
-
1932
- 1932-09-21 GB GB26288/32A patent/GB391677A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2618555A (en) * | 1949-04-09 | 1952-11-18 | Kalle & Co Ag | Process for positive diazotype and negative metal reduction images and light-sensitive material therefor |
| US2952538A (en) * | 1950-07-25 | 1960-09-13 | Philips Corp | Photographic process |
| US2773768A (en) * | 1951-03-20 | 1956-12-11 | Grinten Chem L V D | Light-sensitive diazotype material |
| US2929709A (en) * | 1951-07-10 | 1960-03-22 | Philips Corp | Photographic process |
| US2741558A (en) * | 1952-03-11 | 1956-04-10 | Grinten Chem L V D | Process for the manufacture of diazotype copies |
| US2780547A (en) * | 1954-06-30 | 1957-02-05 | Bruning Charles Co Inc | Diazotype photoprinting materials and processes for preparing same |
| US3007795A (en) * | 1955-02-11 | 1961-11-07 | Agfa Ag | Process for the production of laterally non-reversed positive copies by heat development |
| US3409438A (en) * | 1963-08-26 | 1968-11-05 | Minnesota Mining & Mfg | Photosensitive heat developable copysheet |
| US4066456A (en) * | 1974-12-10 | 1978-01-03 | Gaf Corporation | Incorporated carboxy substituted p-phenylenediamine color developer |
Also Published As
| Publication number | Publication date |
|---|---|
| GB391677A (en) | 1933-05-04 |
| FR744706A (en, 2012) | 1933-04-26 |
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