US2062346A - Adhesive grease composition - Google Patents

Adhesive grease composition Download PDF

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Publication number
US2062346A
US2062346A US12258A US1225835A US2062346A US 2062346 A US2062346 A US 2062346A US 12258 A US12258 A US 12258A US 1225835 A US1225835 A US 1225835A US 2062346 A US2062346 A US 2062346A
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soap
greases
grease
oil
polymer
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US12258A
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John C Zimmer
Arnold J Morway
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Standard Oil Development Co
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Standard Oil Development Co
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M117/00—Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof
    • C10M117/02—Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
    • C10M129/14—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring containing at least 2 hydroxy groups
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/06—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing butene
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/22—Polyesters
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    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/06—Mixtures of thickeners and additives
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
    • C—CHEMISTRY; METALLURGY
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C10M2207/1225—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic used as thickening agent
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C10M2207/1265—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic used as thickening agent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C10M2207/166—Naphthenic acids used as thickening agents
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C10M2207/186—Tall oil acids used as thickening agents
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    • C10M2207/10—Carboxylix acids; Neutral salts thereof
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    • C10M2207/206—Rosin acids used as thickening agents
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    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/06—Groups 3 or 13

Definitions

  • the present invention relates to improved grease composition, and more specifically to a lubricating grease which has a marked adhesive quality, capable of sticking closely to metal surfaces in motion even under sudden shock, with a strong tendency to string out, and with resistance to the action of water. tion and its method of production will be fully understood from thefollowing description.
  • Adhesive greases have been known to the art, but none of them have been fully satisfactory. They are characterized principally by a strong tendency to adhere to moving metal parts andto permanently string out, without separating from the metal-surfaces. This particular-property insures good lubrication. where there is sudden shock which is apt to causespatteringof ordinary greases, and where there is sufficient centrifugal force to throw ordinary greases away from the metal vsurfacesto be lubricated. Such grease compounds-are to be carefully distinguished from the strongly coherent greases,
  • the present'grease composition is prepared by l the addition of several substances to a hydrocarbon lubricating oil.
  • the oil may be derived used say from to 2000 seconds Saybolt at '100'F., but for most purposes, it is preferable 'to use oils within the range of 200 to 500 sec- The composi They also differ from the but onds at F., varying the amount of the other ingredients slightly so as to give the particular qualities desired for any specific use. While anytype of lubricating oil may be used, it will 1 be understood that in preparing the better grades of grease, the morereflned and better grades of 011 should be used.
  • soap of one of the metals calcium or aluminum which may be in proportion from say 3 or- 4 to 30%, but for most purposes theamount will vary between about5 and 15% by weight.
  • the amount of the soap will depend upon the particular fat or fatty acid employed in its production, although all of the 'usual soap stocks are satisfactory, for example, animal fats, such as tallow,'horse fat and the like; vegetable fats and oils such as cotton seed oil; fish oils, and the fatty acids of commerce, such as stearic and palmitic or mix-' tures there'of. Synthetic acids .produced by the oxidation of hydrocarbon oils or waxes and the like may also be used.
  • the soap may be prepared separately, and added to' the .oil, or,'as is preferable in the case of lime soaps, the saponification may occur after the admixture of the fatty acid or other fatty compound with the hydrocarbon oil.
  • Saturated-fatty acids are preferable, although small amounts ofv unsaturated acids such as oleic' may be added if desired.
  • the third essential ingredient of the present composition is. a small amount of ahighly polymerized .oilsoluble'product. of isobutylene or equivalent materials produced by the polymerization of hydroxy acids such as hydroxy-stearic acid. Both of these polymers are of the linear type, the former produced at extremely low temperatures, say below -40 C.
  • the amount ranges from about 0.1 to 2%, which gives excellent results, and of the two types of polymers mentioned, those made from isobutylene are definitely preferable.
  • the greases containing lime soaps are also preferable to the aluminum soap greases, in particular because of the water resistant properties of the former.
  • glycerine up to 1-5% of the amount of soap, or glycols or higher alcohols, especially with lime soaps; wax or petrolatum and solid fillers such as chalk or graphite.
  • a small amount of water is present, as in most lime soap greases, say 0.2% to. 4 or'5% of the whole, in order to produce a smoothly emuls'ified product.
  • Glycerol is undesirable in the alu minum soap grease.
  • Example I The following example is given to illustrate the method of preparing the grease and to show its composition. 8.9 parts by weight of a parafllne base oil (300 seconds Saybolt at 100 F.) are heated to about 200 F. and .89 part by weight of horse fat is thoroughly incorporated therein. Then .13 part of hydrated lime is slowly added and the fat is saponified by heating to about 350 F. and time is provided for thoroughly dehydrating the mass which is then cooled while stirring, to about 200 F., and .05 part by weight of water is then added. The mass is continuously cooled to about 125 F. at which point about .40 part by weight of a mixture of an isobutylene polymer in lubricating oil is added. The particular polymer added had an average molecular weight of Mineral oil 85.5 Lime soap 1 2.0 Glycerine 1.0 Polymer 1.0
  • a greasecomposition comprising a lubricating oil, less than 30% of a soap of a metal selected from the group consisting of calcium'and aluminum and less than 5% of a linear polymer, selected from the group consisting of polymerized isobutylene and polymerized hydroxy-stearic acid, having an average molecular weight in excess of 30,000.
  • An adherent grease composition comprising a lubricating oil, less than 30% of a lime soap and an oil soluble linear polymer of isobutylene having a molecular weight in excess of 30,000, in proportion from 0.1 to 2%, in uniform admixture.
  • An adherent grease composition comprising a mineral oil, less than 30% of an aluminum soap and an oil soluble linear polymer of isobutylene having a molecular weight in excess of 30,000 in proportion of about .1 to 2.0%, in uniform admix-

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

Patented Dec. 1, 1936 PATENT OFFICE 4 12,002,346 ammsrvn GREASE comrosmon.
John C. Zimmer, Hillside, and Arnold J. Moi-way,
Roselle, N. .L, assignors to Standard .011 Development Company, a corporation of Delaware No Drawing. Application March 21, 1935,
Serial No. 12,258
,50lalms.
The present invention relates to improved grease composition, and more specifically to a lubricating grease which has a marked adhesive quality, capable of sticking closely to metal surfaces in motion even under sudden shock, with a strong tendency to string out, and with resistance to the action of water. tion and its method of production will be fully understood from thefollowing description.
Adhesive greases have been known to the art, but none of them have been fully satisfactory. They are characterized principally by a strong tendency to adhere to moving metal parts andto permanently string out, without separating from the metal-surfaces. This particular-property insures good lubrication. where there is sudden shock which is apt to causespatteringof ordinary greases, and where there is sufficient centrifugal force to throw ordinary greases away from the metal vsurfacesto be lubricated. Such grease compounds-are to be carefully distinguished from the strongly coherent greases,
adherent.
. Heretofore rubber has been used in preparing adherent greases, but such compositions are notvery stable during storage and tend to deterio-' rate quite rapidly when left in open containers or in use; also they have been found to become gummy and resinous and separate oil.
The greases described in the present specifi- ,cationshow littleornone of the abovedefects.
They are extremely stable and retain their strong adherent properties. They are also waterresistant and remain perfectly uniform-over long periods of time.
The present'grease composition is prepared by l the addition of several substances to a hydrocarbon lubricating oil. The oil may be derived used say from to 2000 seconds Saybolt at '100'F., but for most purposes, it is preferable 'to use oils within the range of 200 to 500 sec- The composi They also differ from the but onds at F., varying the amount of the other ingredients slightly so as to give the particular qualities desired for any specific use. While anytype of lubricating oil may be used, it will 1 be understood that in preparing the better grades of grease, the morereflned and better grades of 011 should be used.
To the oil is added soap of one of the metals calcium or aluminum which may be in proportion from say 3 or- 4 to 30%, but for most purposes theamount will vary between about5 and 15% by weight.' To some extent the amount of the soap will depend upon the particular fat or fatty acid employed in its production, although all of the 'usual soap stocks are satisfactory, for example, animal fats, such as tallow,'horse fat and the like; vegetable fats and oils such as cotton seed oil; fish oils, and the fatty acids of commerce, such as stearic and palmitic or mix-' tures there'of. Synthetic acids .produced by the oxidation of hydrocarbon oils or waxes and the like may also be used. The soap may be prepared separately, and added to' the .oil, or,'as is preferable in the case of lime soaps, the saponification may occur after the admixture of the fatty acid or other fatty compound with the hydrocarbon oil. Saturated-fatty acids are preferable, although small amounts ofv unsaturated acids such as oleic' may be added if desired. The third essential ingredient of the present composition is. a small amount of ahighly polymerized .oilsoluble'product. of isobutylene or equivalent materials produced by the polymerization of hydroxy acids such as hydroxy-stearic acid. Both of these polymers are of the linear type, the former produced at extremely low temperatures, say below -40 C. by the action of boron fluoride, and the latter at about 200 C. with a small amount of adipic acid as a catalyst. There is, of course an entire range of isobutylene 'polymers, from viscous oils to hard,'.'horn-like solids. The low molecular weight polymers are definitely'undesired and unfit for the present purposes because they have too great a. softening effect and because an amount su-flicient to give the desired adherentquality is incompatible with the amount of the soap used.' Suitable polymers of either of the above types fall within the range of molecular weights in excess of 30,000 or 40,000 up to say 300,000 or higher. While molecular weight of such materials is often diflicult to determine accurately, it is possible to determine their thickening effect on tetrahydronaphthalene and suitable high molecular weight polymers when dissolved in that solvent in proportion of 2.8% concentration by weight are found to produce a solution having a viscosity, as measured at 20 C., from 30 to 200 times as viscous as water at 20 C. Polymers having less thickening power than this are of little or no value for the present purposes. The amount of polymer used is in'all cases less than about 5% and the amount may vary depending on the particular quality desired in the final product and on the molecular weight or thickening power of the particular polymer. In general, the amount ranges from about 0.1 to 2%, which gives excellent results, and of the two types of polymers mentioned, those made from isobutylene are definitely preferable. The greases containing lime soaps are also preferable to the aluminum soap greases, in particular because of the water resistant properties of the former.
Other materials may be added to the grease for various purposes. For example, glycerine up to 1-5% of the amount of soap, or glycols or higher alcohols, especially with lime soaps; wax or petrolatum and solid fillers such as chalk or graphite. Ordinarily a small amount of water is present, as in most lime soap greases, say 0.2% to. 4 or'5% of the whole, in order to produce a smoothly emuls'ified product. Glycerol is undesirable in the alu minum soap grease.
Example I The following example is given to illustrate the method of preparing the grease and to show its composition. 8.9 parts by weight of a parafllne base oil (300 seconds Saybolt at 100 F.) are heated to about 200 F. and .89 part by weight of horse fat is thoroughly incorporated therein. Then .13 part of hydrated lime is slowly added and the fat is saponified by heating to about 350 F. and time is provided for thoroughly dehydrating the mass which is then cooled while stirring, to about 200 F., and .05 part by weight of water is then added. The mass is continuously cooled to about 125 F. at which point about .40 part by weight of a mixture of an isobutylene polymer in lubricating oil is added. The particular polymer added had an average molecular weight of Mineral oil 85.5 Lime soap 1 2.0 Glycerine 1.0 Polymer 1.0
Water .5
formula except that one part contained aluminum soap with rubber and the isobutylene polymer respectively and the other part with lime soap and rubber and the polymer respectively. The amounts of the rubber and polymer were .5%.
These four samples were then left in open containers and inspected each day. The inspection was to test the permanence of the adhesiveness. After 4- days the lime soap-rubber grease had badly deteriorated and was no longer adhesive. The aluminum soap-rubber grease deteriorated to about the same extent in 6 days, but the two samples containing the isobutylene polymer even after standing 4 months had apparently lost none of their adhesiveness.
On placing fresh samples of these greases in closed cans it was found that the rubber greases developed hard non-adhesive skins within a short time but the isobutylene polymer greases showed no such tendency.
This invention is not to be limited by any theory or the examples given by way of illustration, but only by the following claims in which it is our intention to claim all novelty inherent in the process.
We claim:
'1. A greasecomposition comprising a lubricating oil, less than 30% of a soap of a metal selected from the group consisting of calcium'and aluminum and less than 5% of a linear polymer, selected from the group consisting of polymerized isobutylene and polymerized hydroxy-stearic acid, having an average molecular weight in excess of 30,000.
2. .An adherent grease composition comprising a lubricating oil, less than 30% of a lime soap and an oil soluble linear polymer of isobutylene having a molecular weight in excess of 30,000, in proportion from 0.1 to 2%, in uniform admixture.
3. A composition according to claim 2 in which the lime soap is present in amount from about 5 4. An adherent grease composition comprising a mineral oil, less than 30% of an aluminum soap and an oil soluble linear polymer of isobutylene having a molecular weight in excess of 30,000 in proportion of about .1 to 2.0%, in uniform admix-
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2443698A (en) * 1946-08-28 1948-06-22 Wedgeplug Valve Co Inc Grinding compositions
US2449580A (en) * 1945-12-29 1948-09-21 Standard Oil Dev Co Lubricating grease composition
US2468956A (en) * 1946-10-17 1949-05-03 Socony Vacuum Oil Co Inc Core oils
US2969325A (en) * 1955-09-08 1961-01-24 Texaco Inc Method for improving yield of sodium base greases
US2978410A (en) * 1957-11-27 1961-04-04 Union Oil Co Corrosion-resistant grease
US3211650A (en) * 1962-03-15 1965-10-12 Cato Oil And Grease Company In Lubricating grease and method of making the same
US4840739A (en) * 1987-03-17 1989-06-20 Shin-Etsu Chemical Co., Ltd. Adhesive grease composition comprising a random copolymer of ethylene and an alpha-olefin
US20070129267A1 (en) * 2005-12-05 2007-06-07 Mishra Gopal S Lubricating grease composition

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2449580A (en) * 1945-12-29 1948-09-21 Standard Oil Dev Co Lubricating grease composition
US2443698A (en) * 1946-08-28 1948-06-22 Wedgeplug Valve Co Inc Grinding compositions
US2468956A (en) * 1946-10-17 1949-05-03 Socony Vacuum Oil Co Inc Core oils
US2969325A (en) * 1955-09-08 1961-01-24 Texaco Inc Method for improving yield of sodium base greases
US2978410A (en) * 1957-11-27 1961-04-04 Union Oil Co Corrosion-resistant grease
US3211650A (en) * 1962-03-15 1965-10-12 Cato Oil And Grease Company In Lubricating grease and method of making the same
US4840739A (en) * 1987-03-17 1989-06-20 Shin-Etsu Chemical Co., Ltd. Adhesive grease composition comprising a random copolymer of ethylene and an alpha-olefin
US20070129267A1 (en) * 2005-12-05 2007-06-07 Mishra Gopal S Lubricating grease composition
US7767634B2 (en) 2005-12-05 2010-08-03 Indian Oil Corporation Limited Lubricating grease composition

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