US2049793A - Refrigerating apparatus - Google Patents
Refrigerating apparatus Download PDFInfo
- Publication number
- US2049793A US2049793A US624761A US62476132A US2049793A US 2049793 A US2049793 A US 2049793A US 624761 A US624761 A US 624761A US 62476132 A US62476132 A US 62476132A US 2049793 A US2049793 A US 2049793A
- Authority
- US
- United States
- Prior art keywords
- containers
- evaporator
- deflector
- absorbent
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 32
- 239000002250 absorbent Substances 0.000 description 20
- 230000002745 absorbent Effects 0.000 description 20
- 239000003507 refrigerant Substances 0.000 description 14
- 229910021529 ammonia Inorganic materials 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 8
- 229910001628 calcium chloride Inorganic materials 0.000 description 8
- 239000001110 calcium chloride Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
Definitions
- My invention relates to apparatus which oper- I ates by the absorption or adsorption method wherein heat-compression is employed.
- absorption and absorbent as inclusive of the terms adsorption and adsorbent.
- One of the novel and characteristic features of my invention is an improved absorbing and compressing unit wherein the absorbent is contained in a plurality of containers to which in turn heat is applied by means of a heater, such for instance as a gas-burner, relative movement being provided for between the containers and the heater whereby heat is applied in turn to the containers or groups thereof to distill the refrigerant while the absorbing process is proceeding in the case of the remaining containers.
- a heater such for instance as a gas-burner
- Another novel and characteristic feature is the combined absorbent, distilling and condenser unit.
- Fig. l is a View, partly in elevation and partly in vertical section, of the refrigerating apparatus.
- Fig. 2 is a vertical section of the absorption, heating and condensing unit.
- Fig. 3 is a top plan of the unit.
- Fig. 4 is an enlarged sectional detail of one of the double check valves. 7
- l represents a base which is preferably circular and provided with legs '2.
- the base is provided with an annular perimetral seat 3 in which is stepped the lower end of a tubular metallic casing 4 which is provided with an inner lining 5 of heat-insulating 40 material, such as asbestos.
- the base i is provided with an annular flat surface 6 which is provided with a covering 1 of heat-insulating material.
- V represents a metal ring which is fixed in the upper end of the casing 4 and bears on the covering 9.
- the central portion of the base i is dished downwardly and provided with a circular axial opening I I through which the gas burner l2 protrudes upwardly.
- l 3 represents an annular bearing block mounted in the dished portion of the base I and concentrically surrounding the gas burner.
- the annular lower end of a heat deflector I4 is stepped in the bearing block I3, with antifriction members such as balls l5 interposed between the parts.
- the annular upper end of the deflector l4 registers with a ring I6 which is supported 10 from the ring ID by means of the upwardly converging legs ll.
- the deflector l4 and the ring I6 are provided with cross struts l8 with a connecting pin ill at their centers, so that the deflector is rotatably mounted in place.
- the lower tubular end of the deflector I4 is provided with a bevelled ring' gear 20 which meshes with a small bevelled pinion 2
- Power to rotate the deflector may be applied to 20 the shaft 22 from any convenient source.
- an electric or water motor may be used or a motor driven bythe pressure of the gas supply.
- Gas or other suitable fuel is supplied to the burner l2 through the pipe 23 provided with a 25 shut-off valve 24 and a second pressure adjustment valve 25 which is operated by the thermostat 26 contained in the refrigerator chamber or other compartment to be cooled.
- a 25 shut-off valve 24 and a second pressure adjustment valve 25 which is operated by the thermostat 26 contained in the refrigerator chamber or other compartment to be cooled.
- Such chamber is indicated in dotted lines at 21.
- r 28 represents double ball val'Jes which are mounted on the ring [6, there being one valve to each pair of containers. However, a valve foreach container may be provided if desired.
- Each of the valves 28 has two chambers, a lower chamber 29 and an upper chamber 30 connected by a port 3
- the lower chamber is connected by tubes 33 with the top interior of the corresponding pair of containers.
- the lower chambers 29 of the valves 28 are provided with ports 34 guarded by inwardly opening ball valves 35 and said ports are connected by a small tube 36 with the convolution 31 which forms the upper end of the riser tube 38.
- the lower end of the riser tube is connected with the top of the evaporator chamber 39 located in the refrigerator 2'! or the compartment to be refrigerated.
- the tube 38 is preferably provided with an upwardly opening check valve 40.
- the upper chambers 30 of the valves 28 are provided with ports 4
- a tube 45 connects said chamber 44 with the evaporator 39, the intake end of the tube extending upwardly into the chamber 44 and being provided with a float valve 46.
- the float valve controls the supply of condensed refrigerant to the vaporator 39.
- the deflector I4 is preferably of cast metal and of substantially the contour illustrated in the drawings, having its front side opened with out-turned vertical edge portions 47 which pass in close proximity to the walls of the containers 8 as the deflector rotates.
- the open front of the deflector is preferably of sufiicient width to span two of the containers 8 at one time. If desired the open front of the deflector may be of proper Width to span but one container, but a better action is obtained by coupling up a pair of the containers to each double ball valve 28.
- the closed seat or rear wall of the deflector is bowed forwardly intermediate of its ends, as illustrated at 48, thus forcing the rising products of combustion to impinge against and flow around the walls of the containers.
- the deflector I4 is so arranged that while it revolves it directs the products of combustion against and in contact with the containers 8 in turn while shielding the remainder of the containers from the impact and effect of the heat.
- the float valve chamber 44 is preferably provided with a filling opening in its top for the introduction of the refrigerant, said opening being closed by a gas-tight. screw plug 49.
- any suitable absorbent for the refrigerant may be used, such, for instance, as calcium chloride or silver chloride or an adsorbent such, for instance, as charcoal, may be used.
- adsorbent such as charcoal
- the containers 8 are filled with the calcium chloride and ammonia gas is passed through the apparatus until all the air has been displaced by the ammonia and the calcium chloride has absorbed all of the latter which it will take up.
- the float valve chamber may then be partly filled with liquid ammonia.
- the ammonia is at the same pressure throughout the whole apparatus and is distributed as follows. A considerable part of the total amount is absorbed by the calcium chloride in the containers 8 and there is a little liquid ammonia in the float valve chamber 44, while the rest of the apparatus is filled with ammonia gas.
- the ammonia gas is condensed into a liquid and flows by gravity into the float valve chamber 44 Where it accumulates until there is sufficient depth of liquid ammonia to open the float valve 46 and permit the liquid to overflow through the tubes 45 into the evaporator 39.
- the deflector is slowly revolving and by the time a sufficient amount of ammonia has been distilled out of the first pair of containers the deflector is moved to the next container and the ammonia gas is now being distilled out of the second container. In this manner part of the ammonia is distilled out of all of the containers in turn.
- the open front of the deflector passes a container the latter begins to cool and when the temperature of the calcium chloride falls sufiiciently the pressure in the container is lowered below that in the evaporator and the ammonia gas rises from the evaporator through the riser 38, the small tube 36, past the ball Valve 35 and through the tube 33 to the container where it is absorbed by the calcium chloride.
- the deflector is rotated at a slow rate so that the above described action will take place.
- a full rotation of the deflector may be accomplished in a period of substantially three hours.
- the containers are heated one after the other as the deflector slowly revolves, and as a container is heated the pressure of the ammonia increases until it is sufficient to condense the ammonia in the condenser to liquid form.
- the float valve allows the liquid to pass into the evaporator where the ammonia is returned to gaseous form and as the calcium chloride in the containers cools the pressure in the containers falls below'that in the evaporator, so that the ammonia gas is delivered to the containers and is again absorbed.
- the pressure in the condenser is higher than in the evaporator and the ammonia is condensed to liquid form at the higher pressure and evaporated again at the lower pressure in the evaporator, the process being continuous.
- the intensity of the heat applied in turn to the containers 8 is automatically controlled by the thermostat valve 25, the operation of which is in turn controlled bythe temperature in the refrigerator 21.
- the thermostat valve 25 As the temperature falls the valve 25 and the gas pipe 23 are turned so as to reduce the fuel supply, and as the temperature rises in the refrigerator 21 the valve 25 is automatically opened to a greater degree to increase the fuel supply and thus intensify the heat in the revolving deflector I4.
- is such that the desired rate of rotation of the containers is obtained.
- Such rotative movement may be continuous or step by step as may be desired.
- the burner maybe moved, or the containers may be moved relative to the heat-deflector or to the burner.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Sorption Type Refrigeration Machines (AREA)
Description
Aug. 4, 1936. c, ARMOR 2,049,793
REFRIGERAT ING APPARATUS Filed July 26, 1932 2 Sheets-Sheet l 6 I 1 I 28 43 I .1 I I 539 I INVENTOR Aug, 4, 1936. J. c. ARMOR 2,049,793
REFRIGERATING AP AAAAAA s Filed July 26, 1932 2 Sheets-Sheet 2 Patented Aug. 4, 1936 NHTED STATE rATENT OFFICE 7 Claims.
My invention relates to apparatus which oper- I ates by the absorption or adsorption method wherein heat-compression is employed.
For the sake of brevity I use herein the terms absorption and absorbent as inclusive of the terms adsorption and adsorbent.
One of the novel and characteristic features of my invention is an improved absorbing and compressing unit wherein the absorbent is contained in a plurality of containers to which in turn heat is applied by means of a heater, such for instance as a gas-burner, relative movement being provided for between the containers and the heater whereby heat is applied in turn to the containers or groups thereof to distill the refrigerant while the absorbing process is proceeding in the case of the remaining containers.
Another novel and characteristic feature is the combined absorbent, distilling and condenser unit.
Other novel features of construction and arrangement of parts will appear from the following description.
In the accompanying drawings, wherein I have illustrated a practical embodiment of the principles of my invention, Fig. l is a View, partly in elevation and partly in vertical section, of the refrigerating apparatus.
Fig. 2 is a vertical section of the absorption, heating and condensing unit.
Fig. 3 is a top plan of the unit.
Fig. 4 is an enlarged sectional detail of one of the double check valves. 7
Referring to the drawings, l represents a base which is preferably circular and provided with legs '2. The base is provided with an annular perimetral seat 3 in which is stepped the lower end of a tubular metallic casing 4 which is provided with an inner lining 5 of heat-insulating 40 material, such as asbestos.
The base i is provided with an annular flat surface 6 which is provided with a covering 1 of heat-insulating material.
8 represents a plurality of containers arranged in annular series on thesurface 6 .and shown as twelve in number. Thesecontainers are preferably tubular and set on end. An annular covering 9 of heat-insulating material is superimposed on the tops of the containers. 7
it] represents a metal ring which is fixed in the upper end of the casing 4 and bears on the covering 9. V
The central portion of the base i is dished downwardly and provided with a circular axial opening I I through which the gas burner l2 protrudes upwardly.
The annular lower end of a heat deflector I4 is stepped in the bearing block I3, with antifriction members such as balls l5 interposed between the parts. The annular upper end of the deflector l4 registers with a ring I6 which is supported 10 from the ring ID by means of the upwardly converging legs ll. The deflector l4 and the ring I6 are provided with cross struts l8 with a connecting pin ill at their centers, so that the deflector is rotatably mounted in place.
The lower tubular end of the deflector I4 is provided with a bevelled ring' gear 20 which meshes with a small bevelled pinion 2| mounted on and driven by the shaft 22.
Power to rotate the deflector may be applied to 20 the shaft 22 from any convenient source. Thus an electric or water motor may be used or a motor driven bythe pressure of the gas supply.
Gas or other suitable fuel is supplied to the burner l2 through the pipe 23 provided with a 25 shut-off valve 24 and a second pressure adjustment valve 25 which is operated by the thermostat 26 contained in the refrigerator chamber or other compartment to be cooled. Such chamber is indicated in dotted lines at 21.
Each of the valves 28 has two chambers, a lower chamber 29 and an upper chamber 30 connected by a port 3| which is closed by an upwardly opening ball valve 32.
The lower chamber is connected by tubes 33 with the top interior of the corresponding pair of containers.
The lower chambers 29 of the valves 28 are provided with ports 34 guarded by inwardly opening ball valves 35 and said ports are connected by a small tube 36 with the convolution 31 which forms the upper end of the riser tube 38. The lower end of the riser tube is connected with the top of the evaporator chamber 39 located in the refrigerator 2'! or the compartment to be refrigerated. -The tube 38 is preferably provided with an upwardly opening check valve 40.
The upper chambers 30 of the valves 28 are provided with ports 4| which are connected by the tubes 42 with the top convolution of the condenser tube 43 which is coiled about the casing 4 and it has its lower end communicating with the top of the float valve chamber 44. A tube 45 connects said chamber 44 with the evaporator 39, the intake end of the tube extending upwardly into the chamber 44 and being provided with a float valve 46.
The float valve controls the supply of condensed refrigerant to the vaporator 39.
It will be understood that an expansion valve of any approved type may be substituted for the float valve mechanism above described.
The deflector I4 is preferably of cast metal and of substantially the contour illustrated in the drawings, having its front side opened with out-turned vertical edge portions 47 which pass in close proximity to the walls of the containers 8 as the deflector rotates. The open front of the deflector is preferably of sufiicient width to span two of the containers 8 at one time. If desired the open front of the deflector may be of proper Width to span but one container, but a better action is obtained by coupling up a pair of the containers to each double ball valve 28.
To better direct. the products of combustion against the containers the closed seat or rear wall of the deflector is bowed forwardly intermediate of its ends, as illustrated at 48, thus forcing the rising products of combustion to impinge against and flow around the walls of the containers.
The deflector I4 is so arranged that while it revolves it directs the products of combustion against and in contact with the containers 8 in turn while shielding the remainder of the containers from the impact and effect of the heat.
The float valve chamber 44 is preferably provided with a filling opening in its top for the introduction of the refrigerant, said opening being closed by a gas-tight. screw plug 49.
Any suitable absorbent for the refrigerant may be used, such, for instance, as calcium chloride or silver chloride or an adsorbent such, for instance, as charcoal, may be used. There are many substances which may be used as the refrigerant. Thus I may and prefer to use ammonia.
With the use of calcium chloride as an absorbent and ammonia as a refrigerant the action of my apparatus is as follows.
The containers 8 are filled with the calcium chloride and ammonia gas is passed through the apparatus until all the air has been displaced by the ammonia and the calcium chloride has absorbed all of the latter which it will take up. The float valve chamber may then be partly filled with liquid ammonia.
Before lighting the gas burner and starting the deflector to rotate, for initiating the refrigerating cycle, the ammonia is at the same pressure throughout the whole apparatus and is distributed as follows. A considerable part of the total amount is absorbed by the calcium chloride in the containers 8 and there is a little liquid ammonia in the float valve chamber 44, while the rest of the apparatus is filled with ammonia gas.
When the burner is lighted and the deflector is started to rotate the products of combustion pass up the deflector and are caused to impinge on and circulate around the container or containers adjacent to the open front of the deflector. Thus such containers are heated and the ammonia is distilled out of the absorbent, thereby increasing the pressure in the container and causing the ammonia gas to flow out through the tubes 33 to the double check valve 28 and past the ball valve 32 into the chamber 30, whence it passes through the small tube 42 into the condenser 43. Within the condenser the ammonia gas is condensed into a liquid and flows by gravity into the float valve chamber 44 Where it accumulates until there is sufficient depth of liquid ammonia to open the float valve 46 and permit the liquid to overflow through the tubes 45 into the evaporator 39.
In the meantime the deflector is slowly revolving and by the time a sufficient amount of ammonia has been distilled out of the first pair of containers the deflector is moved to the next container and the ammonia gas is now being distilled out of the second container. In this manner part of the ammonia is distilled out of all of the containers in turn.
As soon as the open front of the deflector passes a container the latter begins to cool and when the temperature of the calcium chloride falls sufiiciently the pressure in the container is lowered below that in the evaporator and the ammonia gas rises from the evaporator through the riser 38, the small tube 36, past the ball Valve 35 and through the tube 33 to the container where it is absorbed by the calcium chloride.
The deflector is rotated at a slow rate so that the above described action will take place. In the refrigerating apparatus shown in the drawings, a full rotation of the deflector may be accomplished in a period of substantially three hours.
During the normal operation of the apparatus the containers are heated one after the other as the deflector slowly revolves, and as a container is heated the pressure of the ammonia increases until it is sufficient to condense the ammonia in the condenser to liquid form. The float valve allows the liquid to pass into the evaporator where the ammonia is returned to gaseous form and as the calcium chloride in the containers cools the pressure in the containers falls below'that in the evaporator, so that the ammonia gas is delivered to the containers and is again absorbed. Thus the pressure in the condenser is higher than in the evaporator and the ammonia is condensed to liquid form at the higher pressure and evaporated again at the lower pressure in the evaporator, the process being continuous.
The intensity of the heat applied in turn to the containers 8 is automatically controlled by the thermostat valve 25, the operation of which is in turn controlled bythe temperature in the refrigerator 21. As the temperature falls the valve 25 and the gas pipe 23 are turned so as to reduce the fuel supply, and as the temperature rises in the refrigerator 21 the valve 25 is automatically opened to a greater degree to increase the fuel supply and thus intensify the heat in the revolving deflector I4.
The ratio of the teeth of gear 20 to those of the pinion 2| is such that the desired rate of rotation of the containers is obtained. Such rotative movement may be continuous or step by step as may be desired.
It will be understood that instead of the heatdeflector being moved, the burner maybe moved, or the containers may be moved relative to the heat-deflector or to the burner.
I claim:
1. In refrigerating apparatus to be operated on the absorbent principle, the combination with an evaporator, of a plurality of absorbent containers connected in parallel to the evaporator to receive refrigerant from the latter, heating means for distilling the absorbed refrigerant from the containers, means for producing relative movement between the containers and the heating means, an insulating casing surrounding the containers, and a condenser coil having one end communicating with the containers and the other end with the evaporator, said coil being wound about the casing.
2. In refrigerating apparatus to be operated on the absorbent principle, the combination with an evaporator, of a plurality of absorbent containers arranged in annular series and connected in parallel to the evaporator to receive refrigerant from the latter, a single heating means to distill the absorbed refrigerant from the containers and located at the center of said series, means for producing relative movement between the heating means and the containers, and a condenser coil connecting the containers to the evaporator, said coil being wound about the containers.
3. In refrigerating apparatus to be operated on the absorbent principle, the combination with an evaporator, of a plurality of absorbent containers arranged in annular series and connected in parallel to the evaporator to receive refrigerant from the latter, a single heating means to distill the absorbed refrigerant from the containers and located at the center of said series, means for producing relative movement between the heating means and the containers, an insulated casing for the containers, and a condenser coil wound about the casing and connecting the containers to the evaporator.
4. In refrigerating apparatus to be operated on the absorbent principle, the combination with an evaporator, a condenser and a plurality of absorbent containers arranged in annular series and connected in parallel with the evaporator and condenser, of a tubular heating flue mounted axially of said series and having a heatescape opening in its side wall, means for relative rotary movement between the tubular heating flue and the series of containers whereby the latter are in turn alternately heated and allowed to cool for the purpose described, said opening being of such limited width circumferentially of the flue that materially less than one-half of the total number of the containers are heated simultaneously, and a continuously eifective source of heat supply disposed axially of said flue.
5. In refrigerating apparatus to be operated on the absorbent principle, the combination with an evaporator, a condenser and a plurality of absorbent containers arranged in annular series v and connected in parallel with the evaporator i and condenser, of a tubular flue mounted axially of said series and having a heat escape opening in its side wall, a source of heat located at the lower end of said flue, and means for relative rotary movement between the series of containers and the flue whereby the containers are in turn alternately heated and allowed to cool for the purpose described, said opening being of such limited width circumferentially of the flue that materially less than one-half of the total number of the containers are heated simultaneously.
6. In refrigerating apparatus to be operated on the absorbent principle, the combination withan evaporator, a condenser and a plurality of absorbent containers arranged in annular series and connected in parallel with the evaporator and condenser, of a tubular flue mounted axially of said series and having a heat escape opening in its side wall, a source of heat at the lower end of the flue, and means to rotate the flue on its longitudinal axis whereby the containers are in turn alternately heated and allowed tocool for the purpose described, said opening being of such limited width circumferentially of the flue that materially less than one-half of the total number of the containers are heated simultaneously.
7. In refrigerating apparatus to be operated on the absorbent principle, the combination with an evaporator, of a plurality of absorbent containers connected in parallel-to the evaporator to receive refrigerant from the latter, heating means for distilling the absorbed refrigerant from the containers, means for producing relative movement between the containers and the heating means, and a condenser coil having one end communicating with the containers and the other end with the evaporator, said coil being Wound around the containers.
JAMES C. ARMOR.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US624761A US2049793A (en) | 1932-07-26 | 1932-07-26 | Refrigerating apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US624761A US2049793A (en) | 1932-07-26 | 1932-07-26 | Refrigerating apparatus |
Publications (1)
Publication Number | Publication Date |
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US2049793A true US2049793A (en) | 1936-08-04 |
Family
ID=24503218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US624761A Expired - Lifetime US2049793A (en) | 1932-07-26 | 1932-07-26 | Refrigerating apparatus |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2871674A (en) * | 1956-12-12 | 1959-02-03 | Sulo C Koivisto | Portable refrigeration unit |
WO1993013368A1 (en) * | 1991-12-31 | 1993-07-08 | Tecnicas Empresariales Para La Comercializacion De Productos Ecologicos Y Medioambientales, S.L. (T .E.C.P.E.M.A) | System and device for refrigeration by adsorption |
-
1932
- 1932-07-26 US US624761A patent/US2049793A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2871674A (en) * | 1956-12-12 | 1959-02-03 | Sulo C Koivisto | Portable refrigeration unit |
WO1993013368A1 (en) * | 1991-12-31 | 1993-07-08 | Tecnicas Empresariales Para La Comercializacion De Productos Ecologicos Y Medioambientales, S.L. (T .E.C.P.E.M.A) | System and device for refrigeration by adsorption |
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