US2044246A - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
- Publication number
- US2044246A US2044246A US644078A US64407832A US2044246A US 2044246 A US2044246 A US 2044246A US 644078 A US644078 A US 644078A US 64407832 A US64407832 A US 64407832A US 2044246 A US2044246 A US 2044246A
- Authority
- US
- United States
- Prior art keywords
- parts
- water
- composition
- cleaning
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 31
- 238000004140 cleaning Methods 0.000 title description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000004615 ingredient Substances 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- -1 hydrocarbon chloride Chemical class 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 239000010665 pine oil Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 4
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 4
- 235000019801 trisodium phosphate Nutrition 0.000 description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 235000021588 free fatty acids Nutrition 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229960002969 oleic acid Drugs 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001481789 Rupicapra Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
Definitions
- the present invention relates, generally, to a cleaning composition for use with or without water; and, more particularly, the present invention relates to cleaning compositions adapted 6 to emulsify quickly with water and to be easily rinsed or washed off with water.
- An object of the present invention is to provide a cleaning composition in liquid form which emulsifles easily and quickly with water and 10 which can be used with or without water for various purposes such as cleaning clothing, carpets, and the hands, automobile bodies and other painted or lacquered surfaces, for the de-gumming of silk, wool and so on after weaving and 16 which can be easily and completely washed off after the cleaning process.
- Another'object of the invention is to provide a cleaning composition for removing dirt and grease.
- the cleaning composition of the present invention comprises essentially the following in- 95 gradients, each having a purpose or function as hereinafter set forth: water, soap and sulfonated vegetable oil, hydrocarbon chloride, petroleum spirit and trisodium phosphate.
- the water is used as a solvent for the soap.
- the soap serves,
- the hydrocarbon chloride serves for cutting grease and dirt in the 35 cleansing operation.
- the petroleum spirit also serves to dissolve greases and cut dirt and further serves to protect the hands, paint and varnish surfaces and so on toning down the action of the hydrocarbon chloride and restricting the action 40 of the latter to the dissolving of grease.
- the sulfonated oil facilitates the formation of an emulsion of the ingredients named, particularly on the addition of water in a small or large quantity during the application of the composition 5 and during the rinsing or washing of the composition from the clean surface or body.
- the trisodium phosphate increases the rinsibility of the composition from the washed surface, fabric, and so on by softening the water.
- the mixture of these ingredients is usually cloudy, the ingredients separating into layers.
- the cleaning composition can be used in this state, intermixture being obtained by occasional shaking.
- To produce a permanently unclouded 55 mixture or solution I add a small quantity of an organic material having an unsaturated carbon conjugation such as oleic acid, red oil, white oleicacid, pine oil, rosin oil, rosin, cotton seed oil or facts, and so on.
- an organic material having an unsaturated carbon conjugation such as oleic acid, red oil, white oleicacid, pine oil, rosin oil, rosin, cotton seed oil or facts, and so on.
- To get a clear, light colored mixture or solution I use pine oil or white 5 oleic acid.
- the free fatty acid material can be added after all the other ingredients are put together and is added in small quantities until the mixture clears up to the appearance of a clear solution.
- the amount of free fatty acid necessary 25 is about to 2%%, more or less, for example, depending on the actual ingredients used and the quantities of each used.
- the petroleum spirit can be gasoline, kerosene, crude oil, fuel oil and so on; and the hydrocarbon chloride can be 30 carbon tetrachloride, trichlorethylene and so on.
- Example 1 An example of the composition of the present invention is as follows, the proportions of the ingredients being given in parts by weight: soap about 5 parts, water about 35 to parts, Turkey red oil (75%) about 15 to parts, trichlorethylene about 20 to parts, petroleum spirit about 25 to 50 parts and trisodium phosphate about 2 parts, and suiilcient pine oil to clarify the mixture, say about l of the rest of the composition.
- the composition of this example is suitable for general use.
- Example 2 An example of a composition for use for washing automobiles, buses or other painted or varnished surfaces is as follows: wa-
- Example 3 An example of the composition of the present invention to be used as a liquid hand soap is as follows: water about 12% parts, soap about 5 parts, Turkey red oil about 25 parts,
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
Description
Patented June 16, 1936 UNITED STATES PATENT OFFICE No Drawing. Application November 23, 1932, Serial No. 644,078
The present invention relates, generally, to a cleaning composition for use with or without water; and, more particularly, the present invention relates to cleaning compositions adapted 6 to emulsify quickly with water and to be easily rinsed or washed off with water.
An object of the present invention is to provide a cleaning composition in liquid form which emulsifles easily and quickly with water and 10 which can be used with or without water for various purposes such as cleaning clothing, carpets, and the hands, automobile bodies and other painted or lacquered surfaces, for the de-gumming of silk, wool and so on after weaving and 16 which can be easily and completely washed off after the cleaning process.
Another'object of the invention is to provide a cleaning composition for removing dirt and grease.
90 Other objects and advantages of the present invention will be apparent from the following disclosure and from the accompanying claim.
The cleaning composition of the present invention comprises essentially the following in- 95 gradients, each having a purpose or function as hereinafter set forth: water, soap and sulfonated vegetable oil, hydrocarbon chloride, petroleum spirit and trisodium phosphate. The water is used as a solvent for the soap. The soap serves,
30 among other functions, to form a film or scum on the surface of the applied composition to prevent evaporation of the hydrocarbon chloride and the petroleum spirit. The hydrocarbon chloride serves for cutting grease and dirt in the 35 cleansing operation. The petroleum spirit also serves to dissolve greases and cut dirt and further serves to protect the hands, paint and varnish surfaces and so on toning down the action of the hydrocarbon chloride and restricting the action 40 of the latter to the dissolving of grease. The sulfonated oil facilitates the formation of an emulsion of the ingredients named, particularly on the addition of water in a small or large quantity during the application of the composition 5 and during the rinsing or washing of the composition from the clean surface or body. The trisodium phosphate increases the rinsibility of the composition from the washed surface, fabric, and so on by softening the water.
50 The mixture of these ingredients is usually cloudy, the ingredients separating into layers. The cleaning composition can be used in this state, intermixture being obtained by occasional shaking. To produce a permanently unclouded 55 mixture or solution I add a small quantity of an organic material having an unsaturated carbon conjugation such as oleic acid, red oil, white oleicacid, pine oil, rosin oil, rosin, cotton seed oil or facts, and so on. To get a clear, light colored mixture or solution I use pine oil or white 5 oleic acid. The free fatty acid material can be added after all the other ingredients are put together and is added in small quantities until the mixture clears up to the appearance of a clear solution. With white oleic acid about 10 eight fluid ounces, more or less, are required to clear five gallons of the mixture of ingredients, the exact amount depending on the source and state of the ingredients because of variations in materials from different commercial sources and I5 batches. -As the mixture clears up it thickens to a good body but not of too high viscosity. The free fatty acid can be still added, after the clear and bodied state has been reached, through a small practical range after which further addi- 2 tion of fatty acid causes cloudiness which is' accompanied by a loss of body or thinning of the liquid and a separation to a state similar to that in which it was ,before any fatty acid was added. The amount of free fatty acid necessary 25 is about to 2%%, more or less, for example, depending on the actual ingredients used and the quantities of each used. The petroleum spirit can be gasoline, kerosene, crude oil, fuel oil and so on; and the hydrocarbon chloride can be 30 carbon tetrachloride, trichlorethylene and so on.
Example 1.-.An example of the composition of the present invention is as follows, the proportions of the ingredients being given in parts by weight: soap about 5 parts, water about 35 to parts, Turkey red oil (75%) about 15 to parts, trichlorethylene about 20 to parts, petroleum spirit about 25 to 50 parts and trisodium phosphate about 2 parts, and suiilcient pine oil to clarify the mixture, say about l of the rest of the composition. The composition of this example is suitable for general use.
Example 2.-An example of a composition for use for washing automobiles, buses or other painted or varnished surfaces is as follows: wa-
ter 12 parts, soap about 5 parts, Turkey red oil (75%) about 25 parts, trichlorethylene about 35 parts, kerosene about 35 parts and trisodium phosphate about 2 parts, and suiiicient pine oil to clarify the mixture, say about 1%% of the rest of the composition.
Example 3.An example of the composition of the present invention to be used as a liquid hand soap is as follows: water about 12% parts, soap about 5 parts, Turkey red oil about 25 parts,
trichioretiulene about 20; parts; kerosene about -suiilcient white oleicacid or pine oil to clarify .sitionoi Example 1 is mixed with ac to 25 vol- 1 7 umes of water, an emulsion, being formed im :mediateiy and the am unt of water determined 7 4 by the condition of the to be cleaned:
: brush; :then rinsed or: with water bymeansot ya hose.- Aiter, completely washing thecleaninl' mixture cit/the last rinse water-can be left-to dry by'evaporation becausea: uniform thinnlm oi water isieit :on theclean surface which will I evaporate :to dryness uniformly and without 50 part-s,;tris0dium phosphate about, 2 parts, and
the composition.-.. l ;l
= 4 In using thecomposition of the invention for r cleaning automobiles, buses and other painted or varnished surfaces agiven volume of the compo:
"Ihis mixture is applied witha long haired softieaving streaks ormarksi Aclean shiny surface will be given without the necessity of wiping dry or polishing with a cloth or chamois. f clean- 7 in; mixture will be completely and easily removed by the rinse waterbecause the'trisodium 'phosphateaids insoitening the water whereby the cleaning mixturewill be taken up and Turkey 7 7 7 red oiiiacilitates and makes possible a-sponta 2 I neous and permanent emulsion oi composition with the waters In the use of; Example 3 the higher percentagesoisoap canbe usedto'givea heavier lather or increase thebodyoithe composition. 7 7 7 7 7 Having thus described my inventionwhat 110 claim and wish to protect by Letters Patent is--' A ,permanentlyclear liquid, cleaning compo- 7 i7 sition which is adapted for use with water,- f
comprising in parts by a weight, soap about 5 the cleaning 5
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US644078A US2044246A (en) | 1932-11-23 | 1932-11-23 | Cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US644078A US2044246A (en) | 1932-11-23 | 1932-11-23 | Cleaning composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2044246A true US2044246A (en) | 1936-06-16 |
Family
ID=24583359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US644078A Expired - Lifetime US2044246A (en) | 1932-11-23 | 1932-11-23 | Cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2044246A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2493460A (en) * | 1947-06-02 | 1950-01-03 | Jr Fred Bresee | Spray residue removal composition and method |
| US2583165A (en) * | 1948-12-30 | 1952-01-22 | Solventol Chemical Products In | Cleaning composition |
| US3609089A (en) * | 1967-08-22 | 1971-09-28 | Grace W R & Co | Process for cleaning road vehicles and composition |
-
1932
- 1932-11-23 US US644078A patent/US2044246A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2493460A (en) * | 1947-06-02 | 1950-01-03 | Jr Fred Bresee | Spray residue removal composition and method |
| US2583165A (en) * | 1948-12-30 | 1952-01-22 | Solventol Chemical Products In | Cleaning composition |
| US3609089A (en) * | 1967-08-22 | 1971-09-28 | Grace W R & Co | Process for cleaning road vehicles and composition |
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