US20240000695A1 - Cosmetic products including bis-carboxy silicone polymer component - Google Patents
Cosmetic products including bis-carboxy silicone polymer component Download PDFInfo
- Publication number
- US20240000695A1 US20240000695A1 US18/466,404 US202318466404A US2024000695A1 US 20240000695 A1 US20240000695 A1 US 20240000695A1 US 202318466404 A US202318466404 A US 202318466404A US 2024000695 A1 US2024000695 A1 US 2024000695A1
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- US
- United States
- Prior art keywords
- free
- cosmetic
- stick
- bis
- standing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 145
- 229920005573 silicon-containing polymer Polymers 0.000 title claims abstract description 40
- 239000007788 liquid Substances 0.000 claims abstract description 58
- 239000000203 mixture Substances 0.000 claims abstract description 53
- 238000009472 formulation Methods 0.000 claims abstract description 41
- 239000003086 colorant Substances 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 6
- 239000000470 constituent Substances 0.000 claims abstract description 5
- 238000009877 rendering Methods 0.000 claims abstract description 5
- -1 bis-carboxydecyl Chemical group 0.000 claims description 59
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 40
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 28
- 229940008099 dimethicone Drugs 0.000 claims description 25
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 25
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 25
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 21
- 239000000377 silicon dioxide Substances 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 19
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 claims description 14
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 14
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 14
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 14
- 239000004408 titanium dioxide Substances 0.000 claims description 14
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 claims description 14
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 claims description 13
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 13
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 13
- 239000004113 Sepiolite Substances 0.000 claims description 13
- 229920006037 cross link polymer Polymers 0.000 claims description 13
- XJFGDLJQUJQUEI-UHFFFAOYSA-N dodecyl decanoate dodecyl octanoate Chemical compound CCCCCCCCCCCCOC(=O)CCCCCCC.CCCCCCCCCCCCOC(=O)CCCCCCCCC XJFGDLJQUJQUEI-UHFFFAOYSA-N 0.000 claims description 13
- 235000013980 iron oxide Nutrition 0.000 claims description 13
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 claims description 13
- 239000010445 mica Substances 0.000 claims description 13
- 229910052618 mica group Inorganic materials 0.000 claims description 13
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims description 13
- 229960005323 phenoxyethanol Drugs 0.000 claims description 13
- 229920000573 polyethylene Polymers 0.000 claims description 13
- 229910052624 sepiolite Inorganic materials 0.000 claims description 13
- 235000019355 sepiolite Nutrition 0.000 claims description 13
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 claims description 13
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 claims description 12
- 239000003205 fragrance Substances 0.000 claims description 12
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 claims description 12
- 229940057874 phenyl trimethicone Drugs 0.000 claims description 12
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 claims description 12
- 229960002703 undecylenic acid Drugs 0.000 claims description 12
- 125000003545 alkoxy group Chemical group 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 9
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 6
- 238000006386 neutralization reaction Methods 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 125000001188 haloalkyl group Chemical group 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000012669 liquid formulation Substances 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000003755 preservative agent Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000003349 gelling agent Substances 0.000 description 7
- 230000002335 preservative effect Effects 0.000 description 7
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 6
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- 239000004200 microcrystalline wax Substances 0.000 description 5
- 239000004264 Petrolatum Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 235000019808 microcrystalline wax Nutrition 0.000 description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 description 4
- 235000019271 petrolatum Nutrition 0.000 description 4
- 229940066842 petrolatum Drugs 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000008365 aqueous carrier Substances 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 239000012184 mineral wax Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 description 1
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 1
- LYOKOJQBUZRTMX-UHFFFAOYSA-N 1,3-bis[[1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl]oxy]-2,2-bis[[1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl]oxymethyl]propane Chemical compound FC(F)(F)C(C(F)(F)F)(C(F)(F)F)OCC(COC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(COC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)COC(C(F)(F)F)(C(F)(F)F)C(F)(F)F LYOKOJQBUZRTMX-UHFFFAOYSA-N 0.000 description 1
- ZGDOXNSJDDJHRV-UHFFFAOYSA-N 3-hydroxy-4-[(4-methyl-3-sulfophenyl)diazenyl]naphthalene-2-carboxylic acid Chemical compound S(=O)(=O)(O)C1=C(C=CC(=C1)N=NC1=C(C(=CC2=CC=CC=C12)C(=O)O)O)C ZGDOXNSJDDJHRV-UHFFFAOYSA-N 0.000 description 1
- FVKRIDSRWFEQME-UHFFFAOYSA-N 3-methylbutyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCC(C)C FVKRIDSRWFEQME-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DBPRUZCKPFOVDV-UHFFFAOYSA-N Clorprenaline hydrochloride Chemical compound O.Cl.CC(C)NCC(O)C1=CC=CC=C1Cl DBPRUZCKPFOVDV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical group ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 150000001204 N-oxides Chemical group 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229910004679 ONO2 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000005336 allyloxy group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000002102 aryl alkyloxo group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 1
- 125000003828 azulenyl group Chemical group 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000002676 chrysenyl group Chemical group C1(=CC=CC=2C3=CC=C4C=CC=CC4=C3C=CC12)* 0.000 description 1
- 229940096386 coconut alcohol Drugs 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000003678 cyclohexadienyl group Chemical group C1(=CC=CCC1)* 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 150000002081 enamines Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 125000002192 heptalenyl group Chemical group 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000004446 heteroarylalkyl group Chemical group 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000003427 indacenyl group Chemical group 0.000 description 1
- 229940078565 isoamyl laurate Drugs 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002825 nitriles Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000001893 nitrooxy group Chemical group [O-][N+](=O)O* 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 125000004043 oxo group Chemical group O=* 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001725 pyrenyl group Chemical group 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000000565 sulfonamide group Chemical group 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 125000003375 sulfoxide group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001935 tetracenyl group Chemical group C1(=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C12)* 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 125000003960 triphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C3=CC=CC=C3C12)* 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001060 yellow colorant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
Definitions
- Inventive subject matter disclosed herein relates to lipstick and other anhydrous cosmetic embodiments and method embodiments for making lipstick and other anhydrous cosmetics having shiny, transfer resistant properties.
- Materials of lipstick or gloss applied to a person's lips are designed to last for a suitable amount of time. While applied, the material should be comfortable to the user. Some materials can be uncomfortable in that they can cause the user's lips to feel dry. It is desirable therefore to produce materials that are comfortable to the user.
- the present disclosure provides a free-standing cosmetic stick or liquid cosmetic.
- the free-standing cosmetic stick or liquid cosmetic includes a bis-carboxy silicone polymer component, one or more coloring agents, and one or more constituents for rendering the formulation into a solid stick.
- the present disclosure further provides a method of making a free-standing cosmetic stick or liquid cosmetic including a bis-carboxy silicone polymer component, one or more coloring agents, and one or more constituents for rendering the formulation into a solid stick or liquid cosmetic.
- the method includes preparing a formulation comprising the bis-carboxy silicone polymer component and one or more coloring agents.
- the method further includes heating the formulation and forming the formulation into a stick shape or liquid cosmetic to make a formed stick shape.
- the method further includes cooling the formed stick. or liquid cosmetic
- the present disclosure further provides a cosmetic formulation comprising: Raw Material Name wt %
- the present disclosure further provides a cosmetic formulation comprising:
- a non-neutralized bis-carboxy silicone polymer component e.g., bis-carboxydecyl dimethicone
- values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited.
- a range of “about 0.1% to about 5%” or “about 0.1% to 5%” should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, 3.3% to 4.4%) within the indicated range.
- the acts can be carried out in any order without departing from the principles of the disclosure, except when a temporal or operational sequence is explicitly recited. Furthermore, specified acts can be carried out concurrently unless explicit claim language recites that they be carried out separately. For example, a claimed act of doing X and a claimed act of doing Y can be conducted simultaneously within a single operation, and the resulting process will fall within the literal scope of the claimed process.
- substituted refers to the state in which one or more hydrogen atoms contained therein are replaced by one or more non-hydrogen atoms.
- functional group or “substituent” as used herein refers to a group that can be or is substituted onto a molecule or onto an organic group.
- substituents or functional groups include, but are not limited to, a halogen (e.g., F, Cl, Br, and I); an oxygen atom in groups such as hydroxy groups, alkoxy groups, aryloxy groups, aralkyloxy groups, oxo(carbonyl) groups, carboxyl groups including carboxylic acids, carboxylates, and carboxylate esters; a sulfur atom in groups such as thiol groups, alkyl and aryl sulfide groups, sulfoxide groups, sulfone groups, sulfonyl groups, and sulfonamide groups; a nitrogen atom in groups such as amines, hydroxyamines, nitriles, nitro groups, N-oxides, hydrazides, azides, and enamines; and other heteroatoms in various other groups.
- a halogen e.g., F, Cl, Br, and I
- an oxygen atom in groups such as hydroxy groups, al
- Non-limiting examples of substituents that can be bonded to a substituted carbon (or other) atom include F, Cl, Br, I, OR, OC(O)N(R) 2 , CN, NO, NO 2 , ONO 2 , azido, CF 3 , OCF 3 , R, O (oxo), S (thiono), C(O), S(O), methylenedioxy, ethylenedioxy, N(R) 2 , SR, SOR, SO 2 R, SO 2 N(R) 2 , SO 3 R, C(O)R, C(O)C(O)R, C(O)CH 2 C(O)R, C(S)R, C(O)OR, OC(O)R, C(O)N(R) 2 , OC(O)N(R) 2 , C(S)N(R) 2 , (CH 2 ) 0-2 N(R)C(O)R, (CH 2 )N(R)N(R) 2
- Representative substituted aryl groups can be mono-substituted or substituted more than once, such as, but not limited to, a phenyl group substituted at any one or more of 2-, 3-, 4-, 5-, or 6-positions of the phenyl ring, or a naphthyl group substituted at any one or more of 2- to 8-positions thereof.
- alkoxy refers to an oxygen atom connected to an alkyl group, including a cycloalkyl group, as are defined herein.
- linear alkoxy groups include but are not limited to methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, and the like.
- branched alkoxy include but are not limited to isopropoxy, sec-butoxy, tert-butoxy, isopentyloxy, isohexyloxy, and the like.
- cyclic alkoxy include but are not limited to cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, and the like.
- An alkoxy group can include about 1 to about 12, about 1 to about 20, or about 1 to about 40 carbon atoms bonded to the oxygen atom, and can further include double or triple bonds, and can also include heteroatoms.
- an allyloxy group or a methoxyethoxy group is also an alkoxy group within the meaning herein, as is a methylenedioxy group in a context where two adjacent atoms of a structure are substituted therewith.
- the polymers described herein can terminate in any suitable way.
- the polymers can terminate with an end group that is independently chosen from a suitable polymerization initiator, —H, —OH, a substituted or unsubstituted (C 1 -C 20 )hydrocarbyl (e.g., (C 1 -C 10 )alkyl or (C 6 -C 20 )aryl) interrupted with 0, 1, 2, or 3 groups independently selected from —O—, substituted or unsubstituted —NH—, and —S—, a poly(substituted or unsubstituted (C 1 -C 20 )hydrocarbyloxy), and a poly(substituted or unsubstituted (C 1 -C 20 )hydrocarbylamino).
- a suitable polymerization initiator e.g., —OH, a substituted or unsubstituted (C 1 -C 20 )hydrocarbyl (e.g.
- COCO-CAPRYLATE/CAPRATE is understood to refer to a mixture of esters of coconut alcohol with caprylic acid and capric acid.
- D&C RED NO. 7 CALCIUM LAKE is understood to refer to a calcium salt of 4-(o-sulfo-p-tolylazo)-3-hydroxy-2-naphthoic acid.
- FD&C YELLOW NO. 5 ALUMINUM LAKE is understood to refer to a yellow colorant
- QUATERNIUM-90 MONTMORILLONITE is understood to refer to a reaction product of bentonite and quaternium-90.
- BHT butylated hydroxytoluene
- OZOKERITE is understood to refer a naturally occurring mineral wax or paraffin.
- a free-standing cosmetic stick or liquid cosmetic can include many different components.
- the free-standing cosmetic stick or liquid cosmetic can include a bis-carboxy silicone polymer component.
- the bis-carboxy polymer component can include one or more polymers.
- the one or more polymers can be in a range of from about 5 wt % to about 30 wt % of the bis-carboxy silicone polymer component, about 10 wt % to about 20 wt %, or less than, equal to, or greater than about 5 w %, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, or about 20 wt %.
- the bis-carboxy silicone polymer can include one or more polymers.
- the one or more polymers can be in a range of from about 8 wt % to about 20 wt % of the free-standing cosmetic stick, or about 9 wt % to about 15 wt %, or less than, equal to, or greater than about 8 wt %, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, or about 20 wt %.
- the one or more polymers can include a compound having a structure according to Formula I:
- R is independently chosen from substituted or unsubstituted —OH, (C 1 -C 40 )alkyl, (C 1 -C 40 )alkenyl, (C 1 -C 40 )alkoxy, (C 1 -C 40 )haloalkyl, and (C 4 -C 2 )aryl.
- the value x is any positive integer equal to or greater than 1 and n is any positive integer equal to or greater than 1.
- the value x can be in range of from about 1 to about 20, about 8 to about 10, or less than, equal to, or greater than about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10.
- n can be in a range of from about 1 to about 100, about 20 to about 50, or less than, equal to, or greater than about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, or about 100.
- the structure according to Formula II can be referred to as bis-carboxydecyl dimethicone.
- the free-standing color cosmetic stick or cosmetic liquids can include components to impart color in the formulation.
- suitable examples of color forming components include silica, kaolin, talc, mica, titanium dioxide, iron oxide, black oxide, and polymethylsisesquioxane.
- the free-standing cosmetic stick or cosmetic liquids can further include components such as, isoamyl (isopentyl) laurate.
- Isoamyl laurate is a multifunctional emollient, which provides an excellent silicone feeling and a good skin compatibility.
- the free-standing cosmetic stick can further include ingredients such as petrolatum is also known as perfecta; saxoline; VASELINE; PARAFFIN; PARAFIN; cosmoline; FEMA 3216; WAX WHITE; PARAFFINE.
- Petrolatum has a CAS No. of 8009-03-8. Petrolatum is a purified mixture of semisolid saturated hydrocarbons having the general formula C(n)H(2n+2).
- the free-standing cosmetic stick can also include microcrystalline wax.
- the microcrystalline wax is a hardening wax and has a melting point ranging from 85° C. to 95° C. A hardness of the microcrystalline wax ranges from 6 to 14 decimillimeters (dmm).
- the microcrystalline wax is added to the free-standing cosmetic stick formulation as a granule, pellet, slab or liquid bulk.
- ozokerite wax which is a naturally occurring, light yellow to dark brown mineral wax composed of solid paraffinic hydrocarbons.
- free-standing cosmetic stick or cosmetic liquids it may be desirable for free-standing cosmetic stick or cosmetic liquids to be color free. This can be the case, for example, when the free-standing cosmetic stick or cosmetic liquids is used as a foundation.
- petrolatum can be in a range of from 5 wt % to about 6 wt %.
- the free-standing cosmetic stick or cosmetic liquids can also include Carnauba wax and Candelilla wax in concentrations that total about 4 wt % to about 6 wt % of the free-standing stick formulation.
- a formulation that includes dimethicone/divinyl dimethicone/Silsesquioxane crossploymer; Copernecia and Cerafera wax is added to the foundation and blush formulation embodiments in a concentration of 3 to 4 percent by weight to impart an effective degree of transfer to a user's skin.
- the free-standing cosmetic stick or cosmetic liquid formulation can include polyglycerol-3 diisostearate.
- the polyglycerol-3 diisostearate acts as a thickener and an emulsifier.
- the free-standing cosmetic stick or cosmetic liquid formulation is free of volatile components.
- a formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
- another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include bis-carboxydecyl dimethicone; a colorant or collection of colorants; a structuring agent or collection of structuring agents; a preservative or collection of preservatives; a solvent or collection of solvents; a gelling agent or collection of gelling agents.
- another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
- another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
- the free-standing cosmetic stick or cosmetic liquid formulation can be made according to any suitable method.
- An example of a suitable method includes making the free-standing cosmetic stick or cosmetic liquid formulation with a hot pour technique.
- the hot pour technique can be especially useful to formulate free-standing cosmetic sticks without any volatile ingredients.
- the method can include preparing a formulation including any combination of the ingredients described herein.
- the ingredients, including the non-neutralized bis-carboxy silicone polymer component can be mixed together and heated to form a molten mixture.
- the mixture can be heated in a mold, that generally conforms to a desired shape of the stick (e.g., a generally bullet shaped stick), or the mixture can be heated and subsequently deposited in the mold. After a suitable amount of time, the mold is cooled to harden the mixture.
- the hardened mixture can, optimally, be heat treated with a flame. Heat treating can help to remove imperfections in the stick or give a shiny finish.
- Embodiment 2 provides the free-standing cosmetic stick or liquid of Embodiment 1, wherein the bis-carboxy silicone polymer component comprises one or more polymers.
- Embodiment 4 provides the free-standing cosmetic stick or liquid of any one of Embodiments 2 or 3, wherein the one or more polymers are substantially free of neutralization.
- Embodiment 6 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-6, wherein the bis-carboxy silicone polymer is free of a base.
- Embodiment 8 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-7, wherein the bis-carboxy silicone polymer component comprises one or more polymers having a structure according to Formula I:
- Embodiment 10 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-9, wherein a concentration the bis-carboxy silicone polymer is in a range of from about 5 wt % to about 40 wt %.
- Embodiment 12 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-11, wherein the bis-carboxy silicone polymer is bis-carboxydecyl dimethicone.
- Embodiment 14 provides the free-standing cosmetic stick or liquid of Embodiment 12, wherein the free-standing cosmetic stick comprises:
- Embodiment 15 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-14, wherein the free-standing cosmetic stick or cosmetic liquid formulation is chosen from lip stick or lip gloss.
- Embodiment 17 provides a method of making the free-standing cosmetic stick or liquid of any one Embodiments 1-15, the method comprising:
- Embodiment 18 provides the method of Embodiment 17, wherein the bis-carboxy silicone component is added to the formulation as a non-aqueous phase.
- Embodiment 19 provides a cosmetic formulation comprising:
- Embodiment 20 provides a cosmetic formulation comprising:
- Embodiment 21 provides a cosmetic formulation comprising:
- Embodiment 23 provides a cosmetic formulation comprising:
Abstract
The present disclosure provides a free-standing cosmetic stick or a liquid cosmetic. The free-standing cosmetic stick or liquid cosmetic includes a bis-carboxy silicone polymer component, one or more coloring agents, and one or more constituents for rendering the formulation into a solid stick or liquid cosmetic.
Description
- This application is a continuation of U.S. patent application Ser. No. 16/641,767, filed Feb. 25, 2020, which application is a U.S. National Stage Filing under 35 U.S.C. 371 from International Application No. PCT/US2018/047779, filed on Aug. 23, 2018, and published as WO 2019/040767 on Feb. 28, 2019, which application claims the benefit of priority to U.S. Provisional Patent Application Ser. No. 62/550,187 entitled “FREE-STANDING COSMETIC STICKS INCLUDING BIS-CARBOXY SILICONE POLYMER COMPONENT,” filed Aug. 25, 2017, the disclosures of which are incorporated herein in their entirety by reference.
- Inventive subject matter disclosed herein relates to lipstick and other anhydrous cosmetic embodiments and method embodiments for making lipstick and other anhydrous cosmetics having shiny, transfer resistant properties.
- Materials of lipstick or gloss applied to a person's lips are designed to last for a suitable amount of time. While applied, the material should be comfortable to the user. Some materials can be uncomfortable in that they can cause the user's lips to feel dry. It is desirable therefore to produce materials that are comfortable to the user.
- The present disclosure provides a free-standing cosmetic stick or liquid cosmetic. The free-standing cosmetic stick or liquid cosmetic includes a bis-carboxy silicone polymer component, one or more coloring agents, and one or more constituents for rendering the formulation into a solid stick.
- The present disclosure further provides a method of making a free-standing cosmetic stick or liquid cosmetic including a bis-carboxy silicone polymer component, one or more coloring agents, and one or more constituents for rendering the formulation into a solid stick or liquid cosmetic. The method includes preparing a formulation comprising the bis-carboxy silicone polymer component and one or more coloring agents. The method further includes heating the formulation and forming the formulation into a stick shape or liquid cosmetic to make a formed stick shape. The method further includes cooling the formed stick. or liquid cosmetic
- The present disclosure further provides a cosmetic formulation comprising: Raw Material Name wt %
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 7-13 C9-12 ALKANE 7-13 CAPRYLYL GLYCOL 0.05-0.70 COCO-CAPRYLATE/CAPRATE 0.5-2.0 D&C RED NO. 7 CALCIUM LAKE 2-6 FD&C YELLOW NO. 5 ALUMINUM LAKE 0.5-1.5 FRAGRANCE 0.05-0.70 HDI/TRIMETHYLOL HEXYLLACTONE 0.50-2.00 CROSSPOLYMER IRON OXIDES 0.5-1.5 ISODODECANE 30-45 MICA 0.50-1.50 PHENOXYETHANOL 0.10-0.70 PHENYL TRIMETHICONE 2.00-6.00 POLYETHYLENE 5.00-15.00 POLYPROPYLENE 1.00-7.00 QUATERNIUM-90 MONTMORILLONITE 1.00-2.00 QUATERNIUM-90 SEPIOLITE 2.00-7.00 SILICA 0.01-0.070 SILICA DIMETHYL SILYLATE 0.20-0.70 TITANIUM DIOXIDE 0.50-1.50 TRIETHOXYCAPRYLYLSILANE 0.02-0.07 TRIMETHYLSILOXYSILICATE 1.5-4.5 UNDECYLENIC ACID 0.04-1.00 - The present disclosure further provides a cosmetic formulation comprising:
-
Raw Material Name wt % BHT 0.000001-0.000006 BIS-CARBOXYDECYL DIMETHICONE 10.00-20.00 C9-12 ALKANE 14.00-20.00 CAPRYLYL GLYCOL 0.05-3.50 COCO-CAPRYLATE/CAPRATE 1.00-2.50 D&C RED NO. 7 CALCIUM LAKE 1.00-3.00 FD&C YELLOW NO. 5 ALUMINUM LAKE 1.50-3.50 FRAGRANCE 0.02-0.60 HDI/TRIMETHYLOL HEXYLLACTONE 1.00-2.00 CROSSPOLYMER IRON OXIDES 1.00-3.00 ISODODECANE 20.00-25.00 MICA 0.10-0.70 OZOKERITE 1.00-3.00 PHENOXYETHANOL 0.10-0.40 PHENYL TRIMETHICONE 2.00-7.00 POLYETHYLENE 10.00-19.00 QUATERNIUM-90 MONTMORILLONITE 0.50-1.00 QUATERNIUM-90 SEPIOLITE 0.15-0.40 SILICA 0.01-0.07 TITANIUM DIOXIDE 3.00-9.00 TRIETHOXYCAPRYLYLSILANE 0.10-0.50 TRIMETHYLSILOXYSILICATE 0.10-0.90 UNDECYLENIC ACID 0.05-0.20 - There are various reasons to use the free-standing cosmetic sticks or cosmetic formulations of the present disclosure including the following non-limiting reasons. One reason is that the presence of a non-neutralized bis-carboxy silicone polymer component (e.g., bis-carboxydecyl dimethicone) makes the cosmetic application feel more comfortable and less dry on a user's lips than a corresponding formulation including a neutralized bis-carboxy silicone polymer.
- Reference will now be made in detail to certain embodiments of the disclosed subject matter, examples of which are illustrated in part in the accompanying drawings. While the disclosed subject matter will be described in conjunction with the enumerated claims, it will be understood that the exemplified subject matter is not intended to limit the claims to the disclosed subject matter.
- Throughout this document, values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a range of “about 0.1% to about 5%” or “about 0.1% to 5%” should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, 3.3% to 4.4%) within the indicated range. The statement “about X to Y” has the same meaning as “about X to about Y,” unless indicated otherwise. Likewise, the statement “about X, Y, or about Z” has the same meaning as “about X, about Y, or about Z,” unless indicated otherwise.
- In this document, the terms “a,” “an,” or “the” are used to include one or more than one unless the context clearly dictates otherwise. The term “or” is used to refer to a nonexclusive “or” unless otherwise indicated. The statement “at least one of A and B” has the same meaning as “A, B, or A and B.” In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for the purpose of description only and not of limitation. Any use of section headings is intended to aid reading of the document and is not to be interpreted as limiting; information that is relevant to a section heading may occur within or outside of that particular section.
- In the methods described herein, the acts can be carried out in any order without departing from the principles of the disclosure, except when a temporal or operational sequence is explicitly recited. Furthermore, specified acts can be carried out concurrently unless explicit claim language recites that they be carried out separately. For example, a claimed act of doing X and a claimed act of doing Y can be conducted simultaneously within a single operation, and the resulting process will fall within the literal scope of the claimed process.
- The term “about” as used herein can allow for a degree of variability in a value or range, for example, within 10%, within 5%, or within 1% of a stated value or of a stated limit of a range, and includes the exact stated value or range.
- The term “substantially” as used herein refers to a majority of, or mostly, as in at least about 50%, 60%, 70%, 80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at least about 99.999% or more, or 100%.
- The term “substituted” as used herein in conjunction with a molecule or an organic group as defined herein refers to the state in which one or more hydrogen atoms contained therein are replaced by one or more non-hydrogen atoms. The term “functional group” or “substituent” as used herein refers to a group that can be or is substituted onto a molecule or onto an organic group. Examples of substituents or functional groups include, but are not limited to, a halogen (e.g., F, Cl, Br, and I); an oxygen atom in groups such as hydroxy groups, alkoxy groups, aryloxy groups, aralkyloxy groups, oxo(carbonyl) groups, carboxyl groups including carboxylic acids, carboxylates, and carboxylate esters; a sulfur atom in groups such as thiol groups, alkyl and aryl sulfide groups, sulfoxide groups, sulfone groups, sulfonyl groups, and sulfonamide groups; a nitrogen atom in groups such as amines, hydroxyamines, nitriles, nitro groups, N-oxides, hydrazides, azides, and enamines; and other heteroatoms in various other groups. Non-limiting examples of substituents that can be bonded to a substituted carbon (or other) atom include F, Cl, Br, I, OR, OC(O)N(R)2, CN, NO, NO2, ONO2, azido, CF3, OCF3, R, O (oxo), S (thiono), C(O), S(O), methylenedioxy, ethylenedioxy, N(R)2, SR, SOR, SO2R, SO2N(R)2, SO3R, C(O)R, C(O)C(O)R, C(O)CH2C(O)R, C(S)R, C(O)OR, OC(O)R, C(O)N(R)2, OC(O)N(R)2, C(S)N(R)2, (CH2)0-2N(R)C(O)R, (CH2)0-2N(R)N(R)2, N(R)N(R)C(O)R, N(R)N(R)C(O)OR, N(R)N(R)CON(R)2, N(R)SO2R, N(R)SO2N(R)2, N(R)C(O)OR, N(R)C(O)R, N(R)C(S)R, N(R)C(O)N(R)2, N(R)C(S)N(R)2, N(COR)COR, N(OR)R, C(═NH)N(R)2, C(O)N(OR)R, and C(═NOR)R, wherein R can be hydrogen or a carbon-based moiety; for example, R can be hydrogen, (C1-C100)hydrocarbyl, alkyl, acyl, cycloalkyl, aryl, aralkyl, heterocyclyl, heteroaryl, or heteroarylalkyl; or wherein two R groups bonded to a nitrogen atom or to adjacent nitrogen atoms can together with the nitrogen atom or atoms form a heterocyclyl.
- The term “alkyl” as used herein refers to straight chain and branched alkyl groups and cycloalkyl groups having from 1 to 40 carbon atoms, 1 to about 20 carbon atoms, 1 to 12 carbons or, in some embodiments, from 1 to 8 carbon atoms. Examples of straight chain alkyl groups include those with from 1 to 8 carbon atoms such as methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, and n-octyl groups. Examples of branched alkyl groups include, but are not limited to, isopropyl, iso-butyl, sec-butyl, t-butyl, neopentyl, isopentyl, and 2,2-dimethylpropyl groups. As used herein, the term “alkyl” encompasses n-alkyl, isoalkyl, and anteisoalkyl groups as well as other branched chain forms of alkyl. Representative substituted alkyl groups can be substituted one or more times with any of the groups listed herein, for example, amino, hydroxy, cyano, carboxy, nitro, thio, alkoxy, and halogen groups.
- The term “alkenyl” as used herein refers to straight and branched chain and cyclic alkyl groups as defined herein, except that at least one double bond exists between two carbon atoms. Thus, alkenyl groups have from 2 to 40 carbon atoms, or 2 to about 20 carbon atoms, or 2 to 12 carbon atoms or, in some embodiments, from 2 to 8 carbon atoms. Examples include, but are not limited to vinyl, —CH═CH(CH3), —CH═C(CH3)2, —C(CH3)=CH2, —C(CH3)═CH(CH3), —C(CH2CH3)=CH2, cyclohexenyl, cyclopentenyl, cyclohexadienyl, butadienyl, pentadienyl, and hexadienyl among others.
- The term “aryl” as used herein refers to cyclic aromatic hydrocarbon groups that do not contain heteroatoms in the ring. Thus aryl groups include, but are not limited to, phenyl, azulenyl, heptalenyl, biphenyl, indacenyl, fluorenyl, phenanthrenyl, triphenylenyl, pyrenyl, naphthacenyl, chrysenyl, biphenylenyl, anthracenyl, and naphthyl groups. In some embodiments, aryl groups contain about 6 to about 14 carbons in the ring portions of the groups. Aryl groups can be unsubstituted or substituted, as defined herein. Representative substituted aryl groups can be mono-substituted or substituted more than once, such as, but not limited to, a phenyl group substituted at any one or more of 2-, 3-, 4-, 5-, or 6-positions of the phenyl ring, or a naphthyl group substituted at any one or more of 2- to 8-positions thereof.
- The term “alkoxy” as used herein refers to an oxygen atom connected to an alkyl group, including a cycloalkyl group, as are defined herein. Examples of linear alkoxy groups include but are not limited to methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, and the like. Examples of branched alkoxy include but are not limited to isopropoxy, sec-butoxy, tert-butoxy, isopentyloxy, isohexyloxy, and the like. Examples of cyclic alkoxy include but are not limited to cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, and the like. An alkoxy group can include about 1 to about 12, about 1 to about 20, or about 1 to about 40 carbon atoms bonded to the oxygen atom, and can further include double or triple bonds, and can also include heteroatoms. For example, an allyloxy group or a methoxyethoxy group is also an alkoxy group within the meaning herein, as is a methylenedioxy group in a context where two adjacent atoms of a structure are substituted therewith.
- The term, “free of neutralization” as used herein refers to a bis-carboxy polymer component that is disposed in a non-aqueous carrier or emulsifier substantially free of a base, such as sodium hydroxide or potassium hydroxide.
- The polymers described herein can terminate in any suitable way. In some embodiments, the polymers can terminate with an end group that is independently chosen from a suitable polymerization initiator, —H, —OH, a substituted or unsubstituted (C1-C20)hydrocarbyl (e.g., (C1-C10)alkyl or (C6-C20)aryl) interrupted with 0, 1, 2, or 3 groups independently selected from —O—, substituted or unsubstituted —NH—, and —S—, a poly(substituted or unsubstituted (C1-C20)hydrocarbyloxy), and a poly(substituted or unsubstituted (C1-C20)hydrocarbylamino).
- The term “stick” as used herein, refers to cosmetic compositions molded into the form of a stick. For some embodiments, the compositions are heated until molten and then poured into a mold and cooled. Stick embodiments also include anhydrous compositions capable of being formed into sticks.
- The term “COCO-CAPRYLATE/CAPRATE” is understood to refer to a mixture of esters of coconut alcohol with caprylic acid and capric acid.
- The term “D&C RED NO. 7 CALCIUM LAKE” is understood to refer to a calcium salt of 4-(o-sulfo-p-tolylazo)-3-hydroxy-2-naphthoic acid.
- The term “FD&C YELLOW NO. 5 ALUMINUM LAKE” is understood to refer to a yellow colorant
- The term “QUATERNIUM-90 MONTMORILLONITE” is understood to refer to a reaction product of bentonite and quaternium-90.
- The term “BHT” is understood to refer to butylated hydroxytoluene
- The term “OZOKERITE” is understood to refer a naturally occurring mineral wax or paraffin.
- Embodiments of the invention are described in sufficient detail to enable those skilled in the art to practice the invention. Other embodiments may be utilized and structural, logical, chemical, and other changes may be made without departing from the spirit or scope of the invention discussed herein. The following detailed description is, therefore, not to be taken in a limiting sense, and the scope of the invention discussed herein is defined only by the appended claims.
- According to various embodiments, a free-standing cosmetic stick or liquid cosmetic (e.g., lip stick or lip gloss) can include many different components. For example, the free-standing cosmetic stick or liquid cosmetic can include a bis-carboxy silicone polymer component. The bis-carboxy polymer component can include one or more polymers. The one or more polymers can be in a range of from about 5 wt % to about 30 wt % of the bis-carboxy silicone polymer component, about 10 wt % to about 20 wt %, or less than, equal to, or greater than about 5 w %, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, or about 20 wt %. The bis-carboxy polymer component is disposed in a non-aqueous carrier or emulsifier and is substantially free of a base (e.g., sodium hydroxide or potassium hydroxide). The bis-carboxy polymer component is accordingly free of neutralization. As understood, neutralization is a chemical reaction in which an acid and a base react quantitatively with each other. As an example, in a reaction in water, neutralization results in there being no excess of hydrogen or hydroxide ions present in the solution.
- It has been surprisingly found that including the bis-carboxy silicone polymer in the free-standing cosmetic stick or cosmetic liquid results in a product that users find more comfortable than a corresponding free-standing cosmetic stick or cosmetic liquid that includes a neutralized bis-carboxy silicone polymer. For example, users have found that the instant free-standing cosmetic sticks or cosmetic liquids can provide increased comfort and feel less drying. This result is surprising in part because bis-carboxy silicone polymers are typically included in formulations in a neutralized or aqueous state.
- According to various embodiments, the bis-carboxy silicone polymer can include one or more polymers. The one or more polymers can be in a range of from about 8 wt % to about 20 wt % of the free-standing cosmetic stick, or about 9 wt % to about 15 wt %, or less than, equal to, or greater than about 8 wt %, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, or about 20 wt %.
- According to various embodiments, the one or more polymers can include a compound having a structure according to Formula I:
- In Formula I, at each occurrence R is independently chosen from substituted or unsubstituted —OH, (C1-C40)alkyl, (C1-C40)alkenyl, (C1-C40)alkoxy, (C1-C40)haloalkyl, and (C4-C2)aryl. At each occurrence, the value x is any positive integer equal to or greater than 1 and n is any positive integer equal to or greater than 1. As an example, the value x can be in range of from about 1 to about 20, about 8 to about 10, or less than, equal to, or greater than about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10. As an example, the value n can be in a range of from about 1 to about 100, about 20 to about 50, or less than, equal to, or greater than about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, or about 100.
- In some embodiments the free-standing color cosmetic stick or cosmetic liquids includes a compound having the structure according to Formula II:
- The structure according to Formula II, can be referred to as bis-carboxydecyl dimethicone.
- In addition to the bis-carboxy silicone polymer component the free-standing color cosmetic stick or cosmetic liquids can include components to impart color in the formulation. Suitable examples of color forming components include silica, kaolin, talc, mica, titanium dioxide, iron oxide, black oxide, and polymethylsisesquioxane.
- The free-standing cosmetic stick or cosmetic liquids can further include components such as, isoamyl (isopentyl) laurate. Isoamyl laurate is a multifunctional emollient, which provides an excellent silicone feeling and a good skin compatibility. The free-standing cosmetic stick can further include ingredients such as petrolatum is also known as perfecta; saxoline; VASELINE; PARAFFIN; PARAFIN; cosmoline; FEMA 3216; WAX WHITE; PARAFFINE. Petrolatum has a CAS No. of 8009-03-8. Petrolatum is a purified mixture of semisolid saturated hydrocarbons having the general formula C(n)H(2n+2).
- The free-standing cosmetic stick can also include microcrystalline wax. If present, the microcrystalline wax is a hardening wax and has a melting point ranging from 85° C. to 95° C. A hardness of the microcrystalline wax ranges from 6 to 14 decimillimeters (dmm). The microcrystalline wax is added to the free-standing cosmetic stick formulation as a granule, pellet, slab or liquid bulk.
- Another ingredient that can be added is ozokerite wax, which is a naturally occurring, light yellow to dark brown mineral wax composed of solid paraffinic hydrocarbons.
- In some examples, it may be desirable for free-standing cosmetic stick or cosmetic liquids to be color free. This can be the case, for example, when the free-standing cosmetic stick or cosmetic liquids is used as a foundation. In these examples petrolatum can be in a range of from 5 wt % to about 6 wt %.
- In additional examples, the free-standing cosmetic stick or cosmetic liquids can also include Carnauba wax and Candelilla wax in concentrations that total about 4 wt % to about 6 wt % of the free-standing stick formulation. A formulation that includes dimethicone/divinyl dimethicone/Silsesquioxane crossploymer; Copernecia and Cerafera wax is added to the foundation and blush formulation embodiments in a concentration of 3 to 4 percent by weight to impart an effective degree of transfer to a user's skin.
- In additional examples, the free-standing cosmetic stick or cosmetic liquid formulation can include polyglycerol-3 diisostearate. The polyglycerol-3 diisostearate acts as a thickener and an emulsifier. In additional examples, the free-standing cosmetic stick or cosmetic liquid formulation is free of volatile components.
- Specific formulations of the free-standing cosmetic stick or cosmetic liquid formulation embodiments are as follows and are presented to exemplify embodiments but not limit them. According to various embodiments a formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 7-13 C9-12 ALKANE 7-13 CAPRYLYL GLYCOL 0.05-0.70 COCO-CAPRYLATE/CAPRATE 0.5-2.0 D&C RED NO. 7 CALCIUM LAKE 2-6 FD&C YELLOW NO. 5 ALUMINUM LAKE 0.5-1.5 FRAGRANCE 0.05-0.70 HDI/TRIMETHYLOL HEXYLLACTONE 0.50-2.00 CROSSPOLYMER IRON OXIDES 0.5-1.5 ISODODECANE 30-45 MICA 0.50-1.50 PHENOXYETHANOL 0.10-0.70 PHENYL TRIMETHICONE 2.00-6.00 POLYETHYLENE 5.00-15.00 POLYPROPYLENE 1.00-7.00 QUATERNIUM-90 MONTMORILLONITE 1.00-2.00 QUATERNIUM-90 SEPIOLITE 2.00-7.00 SILICA 0.01-0.070 SILICA DIMETHYL SILYLATE 0.20-0.70 TITANIUM DIOXIDE 0.50-1.50 TRIETHOXYCAPRYLYLSILANE 0.02-0.07 TRIMETHYLSILOXYSILICATE 1.5-4.5 UNDECYLENIC ACID 0.04-1.00 - According to various embodiments, another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
-
Raw Material Name wt % BHT 0.000001-0.000006 BIS-CARBOXYDECYL DIMETHICONE 10.00-20.00 C9-12 ALKANE 14.00-20.00 CAPRYLYL GLYCOL 0.05-3.50 COCO-CAPRYLATE/CAPRATE 1.00-2.50 D&C RED NO. 7 CALCIUM LAKE 1.00-3.00 FD&C YELLOW NO. 5 ALUMINUM LAKE 1.50-3.50 FRAGRANCE 0.02-0.60 HDI/TRIMETHYLOL HEXYLLACTONE 1.00-2.00 CROSSPOLYMER IRON OXIDES 1.00-3.00 ISODODECANE 20.00-25.00 MICA 0.10-0.70 OZOKERITE 1.00-3.00 PHENOXYETHANOL 0.10-0.40 PHENYL TRIMETHICONE 2.00-7.00 POLYETHYLENE 10.00-19.00 QUATERNIUM-90 MONTMORILLONITE 0.50-1.00 QUATERNIUM-90 SEPIOLITE 0.15-0.40 SILICA 0.01-0.07 TITANIUM DIOXIDE 3.00-9.00 TRIETHOXYCAPRYLYLSILANE 0.10-0.50 TRIMETHYLSILOXYSILICATE 0.10-0.90 UNDECYLENIC ACID 0.05-0.20 - According to various embodiments, another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include bis-carboxydecyl dimethicone; a colorant or collection of colorants; a structuring agent or collection of structuring agents; a preservative or collection of preservatives; a solvent or collection of solvents; a gelling agent or collection of gelling agents.
- According to various embodiments, another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 16.00% Colorant 11.4%-17.00% Structuring Agent 14.80%-22.70% preservative 0.20%-0.50% solvent 34.40%-51.6% - According to various embodiments, another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 13.00% Colorant 6.40%-9.60% Gelling Agent 13.60%-20.50% preservative 0.20%-0.50% solvent 39.70%-59.6% - According to various embodiments, another formulation of the free-standing cosmetic stick or cosmetic liquid formulation can include:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 14.00% Colorant 7.20%-10.80% Gelling Agent 4.8%-7.20% Structuring Agent 8.00%-12.00% preservative 0.20%-0.50% solvent 31.00%-49.00% - Examples of solvents that may be included in the solvent component include a C9-C12 Alkane and isododecane. Examples of structuring agents include hdi/trimethylol hexyllactone crosspolymer, polyethylene, silica, triethoxycaprylylsilane, and trimethylsiloxysilicate. Examples of gelling agents include polypropylene, quaternium-90 montmorillonite, and quaternium-90 sepiolite. Examples of preservatives include phenoxyethanol. Examples of colorants include D&C red no. 7 calcium lake, Fd&C yellow no. 5 aluminum lake, and titanium dioxide.
- The free-standing cosmetic stick or cosmetic liquid formulation can be made according to any suitable method. An example of a suitable method includes making the free-standing cosmetic stick or cosmetic liquid formulation with a hot pour technique. The hot pour technique can be especially useful to formulate free-standing cosmetic sticks without any volatile ingredients. The method can include preparing a formulation including any combination of the ingredients described herein. The ingredients, including the non-neutralized bis-carboxy silicone polymer component, can be mixed together and heated to form a molten mixture. The mixture can be heated in a mold, that generally conforms to a desired shape of the stick (e.g., a generally bullet shaped stick), or the mixture can be heated and subsequently deposited in the mold. After a suitable amount of time, the mold is cooled to harden the mixture. The hardened mixture can, optimally, be heat treated with a flame. Heat treating can help to remove imperfections in the stick or give a shiny finish.
- The terms and expressions that have been employed are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the embodiments of the present disclosure. Thus, it should be understood that although the present disclosure has been specifically disclosed by specific embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those of ordinary skill in the art, and that such modifications and variations are considered to be within the scope of embodiments of the present disclosure.
- The following exemplary embodiments are provided, the numbering of which is not to be construed as designating levels of importance:
- Embodiment 1 provides a free-standing cosmetic stick or liquid comprising:
-
- a bis-carboxy silicone polymer component;
- one or more coloring agents; and
- one or more constituents for rendering the formulation into a solid stick.
- Embodiment 2 provides the free-standing cosmetic stick or liquid of Embodiment 1, wherein the bis-carboxy silicone polymer component comprises one or more polymers.
- Embodiment 3 provides the free-standing cosmetic stick or liquid of Embodiment 2, wherein the one or more polymers are in a range of from about 50 wt % to about 100 wt % of the bis-carboxy silicone polymer component.
- Embodiment 4 provides the free-standing cosmetic stick or liquid of any one of Embodiments 2 or 3, wherein the one or more polymers are substantially free of neutralization.
- Embodiment 5 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-4, wherein the bis-carboxy silicone polymer component is disposed in a non-aqueous solution.
- Embodiment 6 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-6, wherein the bis-carboxy silicone polymer is free of a base.
- Embodiment 7 provides the free-standing cosmetic stick or liquid of Embodiment 6, wherein the base is chosen from sodium hydroxide, potassium hydroxide, or a mixture thereof.
- Embodiment 8 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-7, wherein the bis-carboxy silicone polymer component comprises one or more polymers having a structure according to Formula I:
-
- wherein at each occurrence R is independently chosen from substituted or unsubstituted —OH, (C1-C40)alkyl, (C1-C40)alkenyl, (C1-C40)alkoxy, (C1-C40)haloalkyl, and (C4-C12)aryl the value x is any positive integer equal to or greater than 1 and n is any positive integer equal to or greater than 1.
- Embodiment 9 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-8, wherein the bis-carboxy silicone polymer comprises one or more polymers having a structure according to Formula II:
- Embodiment 10 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-9, wherein a concentration the bis-carboxy silicone polymer is in a range of from about 5 wt % to about 40 wt %.
- Embodiment 11 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-9, wherein a concentration the bis-carboxy silicone polymer is in a range of from about 8 wt % to about 20 wt %.
- Embodiment 12 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-11, wherein the bis-carboxy silicone polymer is bis-carboxydecyl dimethicone.
- Embodiment 13 provides the free-standing cosmetic stick of Embodiment 12, wherein the free-standing cosmetic stick comprises:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 7-13 C9-12 ALKANE 7-13 CAPRYLYL GLYCOL 0.05-0.70 COCO-CAPRYLATE/CAPRATE 0.5-2.0 D&C RED NO. 7 CALCIUM LAKE 2-6 FD&C YELLOW NO. 5 ALUMINUM LAKE 0.5-1.5 FRAGRANCE 0.05-0.70 HDI/TRIMETHYLOL HEXYLLACTONE 0.50-2.00 CROSSPOLYMER IRON OXIDES 0.5-1.5 ISODODECANE 30-45 MICA 0.50-1.50 PHENOXYETHANOL 0.10-0.70 PHENYL TRIMETHICONE 2.00-6.00 POLYETHYLENE 5.00-15.00 POLYPROPYLENE 1.00-7.00 QUATERNIUM-90 MONTMORILLONITE 1.00-2.00 QUATERNIUM-90 SEPIOLITE 2.00-7.00 SILICA 0.01-0.070 SILICA DIMETHYL SILYLATE 0.20-0.70 TITANIUM DIOXIDE 0.50-1.50 TRIETHOXYCAPRYLYLSILANE 0.02-0.07 TRIMETHYLSILOXYSILICATE 1.5-4.5 UNDECYLENIC ACID 0.04-1.00 - Embodiment 14 provides the free-standing cosmetic stick or liquid of Embodiment 12, wherein the free-standing cosmetic stick comprises:
-
Raw Material Name wt % BHT 0.000001-0.000006 BIS-CARBOXYDECYL DIMETHICONE 10.00-20.00 C9-12 ALKANE 14.00-20.00 CAPRYLYL GLYCOL 0.05-3.50 COCO-CAPRYLATE/CAPRATE 1.00-2.50 D&C RED NO. 7 CALCIUM LAKE 1.00-3.00 FD&C YELLOW NO. 5 ALUMINUM LAKE 1.50-3.50 FRAGRANCE 0.02-0.60 HDI/TRIMETHYLOL HEXYLLACTONE 1.00-2.00 CROSSPOLYMER IRON OXIDES 1.00-3.00 ISODODECANE 20.00-25.00 MICA 0.10-0.70 OZOKERITE 1.00-3.00 PHENOXYETHANOL 0.10-0.40 PHENYL TRIMETHICONE 2.00-7.00 POLYETHYLENE 10.00-19.00 QUATERNIUM-90 MONTMORILLONITE 0.50-1.00 QUATERNIUM-90 SEPIOLITE 0.15-0.40 SILICA 0.01-0.07 TITANIUM DIOXIDE 3.00-9.00 TRIETHOXYCAPRYLYLSILANE 0.10-0.50 TRIMETHYLSILOXYSILICATE 0.10-0.90 UNDECYLENIC ACID 0.05-0.20 - Embodiment 15 provides the free-standing cosmetic stick or liquid of any one of Embodiments 1-14, wherein the free-standing cosmetic stick or cosmetic liquid formulation is chosen from lip stick or lip gloss.
- Embodiment 16 provides the free-standing cosmetic stick or liquid of any one of Embodiments 4-15, wherein as applied to a user, the free-standing cosmetic stick or liquid is perceived as less drying and more comfortable than a corresponding free-standing cosmetic stick that includes neutralized bis-carboxy silicone polymers.
- Embodiment 17 provides a method of making the free-standing cosmetic stick or liquid of any one Embodiments 1-15, the method comprising:
-
- preparing a formulation comprising:
- the bis-carboxy silicone polymer component; and
- one or more coloring agents; and
- heating the formulation and forming the formulation into a stick shape to make a formed stick shape; and
- cooling the formed stick.
- preparing a formulation comprising:
- Embodiment 18 provides the method of Embodiment 17, wherein the bis-carboxy silicone component is added to the formulation as a non-aqueous phase.
- Embodiment 19 provides a cosmetic formulation comprising:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 7-13 C9-12 ALKANE 7-13 CAPRYLYL GLYCOL 0.05-0.70 COCO-CAPRYLATE/CAPRATE 0.5-2.0 D&C RED NO. 7 CALCIUM LAKE 2-6 FD&C YELLOW NO. 5 ALUMINUM LAKE 0.5-1.5 FRAGRANCE 0.05-0.70 HDI/TRIMETHYLOL HEXYLLACTONE 0.50-2.00 CROSSPOLYMER IRON OXIDES 0.5-1.5 ISODODECANE 30-45 MICA 0.50-1.50 PHENOXYETHANOL 0.10-0.70 PHENYL TRIMETHICONE 2.00-6.00 POLYETHYLENE 5.00-15.00 POLYPROPYLENE 1.00-7.00 QUATERNIUM-90 MONTMORILLONITE 1.00-2.00 QUATERNIUM-90 SEPIOLITE 2.00-7.00 SILICA 0.01-0.070 SILICA DIMETHYL SILYLATE 0.20-0.70 TITANIUM DIOXIDE 0.50-1.50 TRIETHOXYCAPRYLYLSILANE 0.02-0.07 TRIMETHYLSILOXYSILICATE 1.5-4.5 UNDECYLENIC ACID 0.04-1.00 - Embodiment 20 provides a cosmetic formulation comprising:
-
Raw Material Name wt % BHT 0.000001-0.000006 BIS-CARBOXYDECYL DIMETHICONE 10.00-20.00 C9-12 ALKANE 14.00-20.00 CAPRYLYL GLYCOL 0.05-3.50 COCO-CAPRYLATE/CAPRATE 1.00-2.50 D&C RED NO. 7 CALCIUM LAKE 1.00-3.00 FD&C YELLOW NO. 5 ALUMINUM LAKE 1.50-3.50 FRAGRANCE 0.02-0.60 HDI/TRIMETHYLOL HEXYLLACTONE 1.00-2.00 CROSSPOLYMER IRON OXIDES 1.00-3.00 ISODODECANE 20.00-25.00 MICA 0.10-0.70 OZOKERITE 1.00-3.00 PHENOXYETHANOL 0.10-0.40 PHENYL TRIMETHICONE 2.00-7.00 POLYETHYLENE 10.00-19.00 QUATERNIUM-90 MONTMORILLONITE 0.50-1.00 QUATERNIUM-90 SEPIOLITE 0.15-0.40 SILICA 0.01-0.07 TITANIUM DIOXIDE 3.00-9.00 TRIETHOXYCAPRYLYLSILANE 0.10-0.50 TRIMETHYLSILOXYSILICATE 0.10-0.90 UNDECYLENIC ACID 0.05-0.20 - Embodiment 21 provides a cosmetic formulation comprising:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 16.00% Colorant 11.4%-17.00% Structuring Agent 14.80%-22.70% preservative 0.20%-0.50% solvent 34.40%-51.6% - Embodiment 22 provides a cosmetic formulation comprising:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 13.00% Colorant 6.40%-9.60% Gelling Agent 13.60%-20.50% preservative 0.20%-0.50% solvent 39.70%-59.6% - Embodiment 23 provides a cosmetic formulation comprising:
-
Raw Material Name wt % BIS-CARBOXYDECYL DIMETHICONE 14.00% Colorant 7.20%-10.80% Gelling Agent 4.8%-7.20% Structuring Agent 8.00%-12.00% preservative 0.20%-0.50% solvent 31.00%-49.00% - All publications, patents and patent applications are incorporated herein by reference. While in the foregoing specification this invention has been described in relation to certain preferred embodiments thereof, and many details have been set forth for purposes of illustration, it will be apparent to those skilled in the art that the invention is susceptible to additional embodiments and that certain of the details described herein may be varied considerably without departing from the basic principles of the invention.
Claims (20)
1. A free-standing cosmetic stick or cosmetic liquid comprising:
a bis-carboxy silicone polymer component;
one or more coloring agents; and
one or more constituents for rendering the formulation into a solid stick or cosmetic liquid.
2. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein the bis-carboxy silicone polymer component comprises one or more polymers.
3. The free-standing cosmetic stick or cosmetic liquid of claim 2 , wherein the one or more polymers are in a range of from about 5 wt % to about 30 wt % of the bis-carboxy silicone polymer component.
4. The free-standing cosmetic stick or cosmetic liquid of claim 2 , wherein the one or more polymers are substantially free of neutralization.
5. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein the bis-carboxy silicone polymer component is disposed in a non-aqueous solution.
6. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein the bis-carboxy silicone polymer is free of a base.
7. The free-standing cosmetic stick or cosmetic liquid of claim 6 , wherein the base is chosen from sodium hydroxide, potassium hydroxide, or a mixture thereof.
8. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein the bis-carboxy silicone polymer component comprises one or more polymers having a structure according to Formula I:
10. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein a concentration the bis-carboxy silicone polymer is in a range of from about 5 wt % to about 30 wt %.
11. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein a concentration the bis-carboxy silicone polymer is in a range of from about 8 wt % to about 20 wt %.
12. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein the bis-carboxy silicone polymer is bis-carboxydecyl dimethicone.
13. The free-standing cosmetic stick or cosmetic liquid of claim 12 , wherein the free-standing cosmetic stick comprises:
14. The free-standing cosmetic stick or cosmetic liquid of claim 12 , wherein the free-standing cosmetic stick comprises:
15. The free-standing cosmetic stick or cosmetic liquid of claim 1 , wherein the free-standing cosmetic stick or cosmetic liquid is chosen from lip stick or lip gloss.
16. The free-standing cosmetic stick or cosmetic liquid of claim 4 , wherein as applied to a user, the free-standing cosmetic stick or cosmetic liquid is perceived as less drying and more comfortable than a corresponding free-standing cosmetic stick or cosmetic liquid that includes neutralized bis-carboxy silicone polymers.
17. A method of making the free-standing cosmetic stick of claim 1 , the method comprising:
preparing a formulation comprising:
the bis-carboxy silicone polymer component; and
one or more coloring agents; and
heating the formulation and forming the formulation into a stick shape to make a formed stick shape; and
cooling the formed stick.
18. The method of claim 17 , wherein the bis-carboxy silicone component is added to the formulation as a non-aqueous phase.
19. A cosmetic formulation comprising:
20. A cosmetic formulation comprising:
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2018
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2023
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WO2019040767A1 (en) | 2019-02-28 |
US11793744B2 (en) | 2023-10-24 |
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