US20230080064A1 - Easily-peelable paint composition - Google Patents
Easily-peelable paint composition Download PDFInfo
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- US20230080064A1 US20230080064A1 US17/983,877 US202217983877A US2023080064A1 US 20230080064 A1 US20230080064 A1 US 20230080064A1 US 202217983877 A US202217983877 A US 202217983877A US 2023080064 A1 US2023080064 A1 US 2023080064A1
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- paint composition
- weight
- peelable paint
- peelable
- parts
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- 239000003973 paint Substances 0.000 title claims abstract description 131
- 239000000203 mixture Substances 0.000 title claims abstract description 83
- 239000000463 material Substances 0.000 claims abstract description 37
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 60
- 229920005989 resin Polymers 0.000 claims description 43
- 239000011347 resin Substances 0.000 claims description 43
- 239000000654 additive Substances 0.000 claims description 36
- 230000000996 additive effect Effects 0.000 claims description 36
- 229910010272 inorganic material Inorganic materials 0.000 claims description 28
- 239000011147 inorganic material Substances 0.000 claims description 28
- 239000000049 pigment Substances 0.000 claims description 15
- 239000002562 thickening agent Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000002518 antifoaming agent Substances 0.000 claims description 9
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 9
- 229920002545 silicone oil Polymers 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- 229910052681 coesite Inorganic materials 0.000 claims description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229910052682 stishovite Inorganic materials 0.000 claims description 5
- 229910052905 tridymite Inorganic materials 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000000454 talc Substances 0.000 claims description 4
- 229910052623 talc Inorganic materials 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910001679 gibbsite Inorganic materials 0.000 claims description 3
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- 239000004094 surface-active agent Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
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- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 4
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- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- ZYPDJSJJXZWZJJ-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-piperidin-4-yloxypyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)OC1CCNCC1 ZYPDJSJJXZWZJJ-UHFFFAOYSA-N 0.000 description 1
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- 102000002322 Egg Proteins Human genes 0.000 description 1
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- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
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- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
Definitions
- the present disclosure relates to an easily-peelable paint composition, and more particularly, to an easily-peelable paint composition capable of easily peeling off a coating layer to restore an object to its original condition in a case where a user wants to change the color or design of the object or use the object in its original condition.
- paints are fluid materials that are widely applied onto surfaces of objects to form thin coating layers, and they are dried and hardened over time to not only protect the surfaces of the objects but also enhance an aesthetic value.
- paints are often applied to various structures, including buildings, to not only enhance the appearance of the structures and make them look good but also prevent surface damage, including corrosion, and improve durability.
- paints mainly used for protecting objects and structures are oil paints, enamel paints, and aqueous paints. These paints are effective in not only protecting buildings and materials but also increasing their aesthetic values and improving insulation and heat resistance.
- Typical coating materials such as paints are being developed mainly for the purpose of improving adhesion to objects and structures to improve durability. Therefore, they are not easy to peel off and restoring to the original conditions once dried/hardened after being applied to objects or structures.
- the typical paints cannot be peeled off at all, or the wallpaper will be damaged if such paints are peeled off forcibly. Therefore, restoration to original conditions is not possible with typical paints.
- paints are also often applied on various types of materials, including wood, glass, and etc., but it is difficult to restore the wood, glass, or the like to their original conditions because it is extremely difficult to remove the paints without leaving marks.
- paints or coating materials that can be easily peeled off from surfaces of materials (including, not limited to, paper, wood, glass, or etc.) to allow easy restoration for the materials to their original conditions regardless of space and time.
- An object of the present disclosure is to provide an easily-peelable paint composition capable of not only easily peeling off paints from materials to which the paints are applied for easy restorations to original conditions but also protecting the materials with excellent durability while being applied, and designed as an aqueous type for safe use even in contact with human bodies inside buildings or structures such that the paint composition can be used regardless of location and purpose of use.
- a paint composition that is easy to peel off from an object, the easily-peelable paint composition containing 30 to 80 parts by weight of a polyvinyl butyral (PVB) resin; 1 to 5 parts by weight of an additive including an antifoaming agent; and the balance of an aqueous solvent including water.
- PVB polyvinyl butyral
- the PVB resin may have a molecular weight of 100,000 to 210,000 g/mole, and the PVB resin may have a particle size of 170 to 240 ⁇ m.
- the paint composition may further contain an additional component including latex, an acrylic copolymer, polyvinyl acetate, urethane, or polyvinyl alcohol.
- an additional component including latex, an acrylic copolymer, polyvinyl acetate, urethane, or polyvinyl alcohol.
- a weight ratio of the PVB resin to the additional component in the paint composition may be 9 to 12:1.
- the paint composition may further contain at least one of a releasing additive and an inorganic material.
- the releasing additive may be contained in an amount of 1 to 20 parts by weight, the releasing additive being any one or more selected from the group consisting of a silicone oil, a silicone polymer, a silicone emulsion, a modified silicone oil or polymer, a siloxane or modified siloxane, a silicone rubber, a wax-type additive, a surfactant, an oil, and a silane.
- the inorganic material may be contained in an amount of 5 to 40 parts by weight, the inorganic material being any one or more selected from the group consisting of SiO 2 , CaCO 3 , BaSO 4 , talc, Al(OH) 3 , Al 2 O 3 , and TiO 2 .
- the aqueous solvent may further include any one or more of alcohols, cellosolves, and carbitols.
- the object may be a paper, wood, or glass material.
- the present disclosure relates to an easily-peelable paint composition capable of not only peeling off paints from materials to which the paints are applied for easy restorations to original conditions but also protecting the materials with excellent durability while being applied, such that which easily-peelable paint composition can be used for functional paints.
- the easily-peelable paint composition of the present disclosure is designed eco-friendly as an aqueous type for safe use even in contact with human bodies inside buildings or structures such that the paint composition can be used regardless of location and purpose of use
- the easily-peelable paint of the present disclosure is eco-friendly as a non-toxic material because a coating film formed by applying and drying/hardening the easily-peelable paint can be peeled off, and the peeled-off coating film can be dissolved in alcohol for recycling.
- FIG. 1 shows photographs for conditions of glass before and after peel-off depending on content ratios between PVB and latex.
- FIG. 2 shows photographs for conditions of silk (PVC) wallpaper before and after peel-off depending on content ratios between PVB and latex.
- FIG. 3 shows photographs comparing conditions between a paint A′ to which a PVB resin is added alone, a paint B′ containing a releasing additive, and a paint C′ containing an inorganic material when applied to paper.
- FIG. 4 shows photographs comparing conditions between paper to which a paint A′ to which a PVB resin is added alone, a paint B′ containing a releasing additive, and a paint C′ containing an inorganic material are applied when the p are peeled off from the paper according to the present disclosure.
- the present disclosure relates to an easily-peelable paint composition containing a polyvinyl butyral (PVB) resin, an additive including an antifoaming agent, and water.
- the easily-peelable paint composition may further contain a releasing additive or an inorganic material.
- the easily-peelable paint composition When compared to a typical peelable coating material, the easily-peelable paint composition is capable of protecting a material to which the easily-peelable paint composition is applied with excellent durability, the easily-peelable paint composition can be easily peeled off even from wallpaper for easily restoring the material to its original condition, and the easily-peelable paint composition is formed as an aqueous type for safe use regardless of location and purpose of use, even inside buildings or structures, where the paint composition is likely to be in contact with human bodies.
- the polyvinyl butyral (PVB) resin is dissolved in the water and painted on a surface of a material, and serves to protect the surface after the solvent is dried. It is preferable that the polyvinyl butyral (PVB) resin is easily peelable when a coating film needs to be peeled off after the material has been dried.
- the polyvinyl butyral (PVB) resin is a resin that is excellent in flexibility, tensile strength, and toughness in a water-dispersible form, and is advantageous in that the easily-peelable paint composition can be easily peeled off from the material.
- the polyvinyl butyral (PVB) resin may be prepared by a condensation reaction between PVA and n-butyraldehyde.
- the PVB resin may be in an aqueous or emulsion type, and serves to protect the surface of the material once the solvent is dried after the surface of the material is painted.
- the PVB resin is a resin that is excellent in flexibility, tensile strength, and toughness, making it possible to easily peel the easily-peelable paint composition from the material.
- the structure of the PVB resin may include a butyral group, an acetyl group, and a hydroxyl group represented by Formula 1 below as repeating units.
- the PVB resin may have a structure including a butyral group, an acetyl group, and a hydroxyl group represented by the following Formula 1 as repeating units.
- the PVB resin has a molecular weight of 100,000 to 210,000 g/mole, its peelability and storage stability are excellent, and when the PVB resin has a particle size of 170 to 240 ⁇ m, its peelability and storage stability are further improved.
- the PVB resin contained in the easily-peelable paint composition When an amount of the polyvinyl butyral (PVB) resin contained in the easily-peelable paint composition is less than 30 parts by weight based on the total weight, coating solution stability deteriorates and coating properties are poor, causing a difficulty in forming a coating film. When an amount of the PVB resin contained in the easily-peelable paint composition is more than 80 parts by weight based on the total weight, it is difficult to prepare a paint including a pigment. Accordingly, the PVB resin is contained in the easily-peelable paint composition in an amount of 20 to 80 parts by weight, preferably 35 to 65 parts by weight.
- the easily-peelable paint composition may further include a thickener.
- the thickener serves to improve the storage stability and the viscosity of the composition to improve coating properties.
- Examples of the thickener may include cellulose, an acrylic thickener, a urethane thickener, wax, and clay. These may be used alone or in combination of two or more.
- the thickener When the thickener is contained in an amount of 2 parts by weight or more, viscosity and thixotropic properties are too high to form a coating film. On the other hand, when the thickener is contained in an amount of less than 0.2 parts by weight, viscosity is too low to apply the composition because it may flow down like water. Therefore, it is advantageous that the thickener is contained in the easily-peelable paint composition in an amount of 0.2 to 2 parts by weight, preferably 0.3 to 1.5 parts by weight.
- the additive may include an antifoaming agent and a functional additive other than the antifoaming agent, such as a leveling agent, a wetting dispersant, a preservative, or an antifreezing agent. These may be used alone or in combination of two or more.
- the additive is generally used to uniformly maintain the workability and the physical properties of the easily-peelable paint composition.
- the easily-peelable paint composition of the present disclosure may further include a releasing additive.
- the releasing additive may be included in the easily-peelable paint composition of the present disclosure so that the easily-peelable paint composition can be easily peeled off from the material to which the paint composition is applied, thereby improving peelability.
- the releasing additive which is provided to secure the improvement in peelability of the coating film, may increase releasability or improve the cohesion of the resin to decrease adhesion between the paint and the surface of the material, thereby increasing the peeling effect.
- the releasing additive may be a silicone oil, a silicone polymer, a silicone emulsion, a modified silicone oil or polymer, a siloxane or modified siloxane, a silicone rubber, a wax-type additive, a surfactant, an oil, a silane, or the like.
- the silicone polymer or oil is suitable for the releasing additive contained in the easily-peelable paint composition of the present disclosure. It is preferable that the releasing additive is contained in the easily-peelable paint composition in an amount of 1 to 20 parts by weight, preferably 3 to 15 parts by weight.
- the easily-peelable paint composition of the present disclosure may further contain an inorganic material.
- the inorganic material is contained in the easily-peelable paint composition of the present disclosure so that the easily-peelable paint composition can be easily peeled off from the material to which the paint composition is applied, thereby improving peelability.
- the inorganic material which is provided to secure the peelability of the coating film, may increase the releasability of the easily-peelable paint composition to decrease adhesion between the paint and the surface of the material, thereby increasing the peeling effect.
- the inorganic material may have a paint amount increasing effect, and serve to improve coating properties and improve the strength of the coating film.
- the inorganic material may include any one or a combination selected from the group consisting of SiO 2 , CaCO 3 , BaSO 4 , talc, Al(OH) 3 , and TiO 2 .
- a particle size ( ⁇ m) of the inorganic material may be controlled to increase a support effect and suppress permeability, and a resin/inorganic material ratio may be controlled to improve peelability while maintaining existing physical properties such as durability, strength of coating film, and thickness of coating film.
- the inorganic material may be contained in the easily-peelable paint composition in an amount of 5 to 40 parts by weight, preferably 10 to 30 parts by weight.
- the easily-peelable paint composition having the above-mentioned composition is advantageous in that it can be easily peeled off, if necessary, after being applied to a material such as not only wallpaper but also wood or glass, thereby making it possible to recover the material to its original condition.
- a material such as paper having weak internal cohesion between ingredients of the material with many pores, which may cause interlayer separation, has high adhesion with the paint, making it difficult to peel off a coating layer from the paper.
- the easily-peelable paint composition may further include a pigment for identifying a painted portion.
- the pigment may include an extender pigment, a colored pigment, and a combination thereof.
- the pigment when the pigment is contained in an amount of more than 30 parts by weight, the stability of the paint deteriorates, and the paint fails to play its role properly, as a result peeling off a coating film in a poor state.
- the pigment may be contained in the easily-peelable paint composition in an amount of 5 to 30 parts by weight, preferably 5 to 20 parts by weight.
- the solvent included in the easily-peelable paint composition is used to secure the painting workability of the easily-peelable paint composition.
- the solvent may further include any one or more of cellosolves and carbitols in addition to water. These may be used in combination of two or more. When the solvent is used in the point in a small amount, a drying time may be short, and when the solvent is used in the paint in a large amount, a drying time may be long.
- Example 1 The paint of Example 1 was applied onto a wallpaper specimen at a thickness of 50 to 100 ⁇ m using an airless spray, a roller (brush), or the like, and then dried. A coating film formed after leaving the specimen for 1 month was checked for peelability and physical properties, and the results were obtained as shown in Table 1.
- the physical properties were evaluated in the following manner
- a particle condition of the dried film was evaluated with naked eyes and by touch—good, normal, and bad.
- the paint containing a PVB resin had a certain degree of peelability with respect to the wallpaper, and the paint containing a PVB resin was evaluated as being excellent in terms of strength of coating film, compatibility, gloss, and surface condition. It should be noted that paper has weak internal cohesion with many pores, which may easily cause interlayer separation, and thus has relatively poor peelability as compared with glass or the like.
- the easily-peelable paint composition was tested for physical properties depending on the molecular weight of the PVB, and the results were obtained as shown in Table 3.
- the physical properties of the paint composition were evaluated in the following manner
- a glass transition temperature was measured using differential scanning calorimetry (DSC) equipment.
- peelability When peeling off (removing) the film coated on silk (PVC) wallpaper after 1 day, its condition was evaluated in five stages (evaluated together with a condition of the material after peeling off the film)—peelability ⁇ circle around ( ⁇ ) ⁇ : excellent, ⁇ : good, ⁇ : normal, ⁇ : poor, and ⁇ : bad.
- a PVB emulsion resin having a particle size range as shown in Table 4 below was used in preparing a paint composition of each of Examples 6 to 9 in the same manner as in Experimental Example 2. Thereafter, the respective physical properties of the paint compositions prepared were measured.
- Example 6 70 to 100 ⁇ ⁇ 80 to 100 ⁇
- Example 7 100 to 160 ⁇ ⁇ 110 to 140 ⁇
- Example 8 170 to 240 ⁇ ⁇ 150 to 180 ⁇
- Example 9 240 to 300 ⁇ X 120 to 160 ⁇
- Example 8 in which the PVB resin had a particle size of 170 to 240 ⁇ m, not only the peelability but also the tensile rate and the storage stability were best.
- a vinyl copolymer an acrylic emulsion having a methacryl acid MAA: acryl acid AA: itaconic acid weight ratio of 7:2:1
- a polyacetate emulsion PVAc, acetate content: 7 wt %
- polyvinyl alcohol PVOH
- KSL341 SBR latex emulsion
- FIGS. 1 and 2 show photographs of experiments on peelability and transparency with respect to glass and silk (PVC) wallpaper depending on a content ratio between PVB (Example 8) and latex as listed in Table 9 below.
- An easily-peelable paint composition according to each of Examples 23 to 29 was prepared in the same manner as in Example 22, but with the composition and content described in Table 10 below.
- An easily-peelable paint composition according to each of Examples 31 to 37 was prepared in the same manner as in Example 30, but with the composition and content described in Table 11 below.
- FIGS. 3 and 4 show tests of paints of the present disclosure for peelability when applied to wallpaper.
- a of FIG. 3 and A′ of FIG. 4 show an applied condition and a peeled-off condition of a paint containing no releasing additive and no inorganic material (Example 1), respectively.
- B of FIG. 3 and B′ of FIG. 4 show an applied condition and a peeled-off condition of a paint containing a releasing additive (Example 26), respectively
- C of FIG. 3 and C′ of FIG. 4 show an applied condition and a peeled-off condition of a paint containing an inorganic material as an additive (Example 33), respectively.
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Abstract
Description
- The present disclosure relates to an easily-peelable paint composition, and more particularly, to an easily-peelable paint composition capable of easily peeling off a coating layer to restore an object to its original condition in a case where a user wants to change the color or design of the object or use the object in its original condition.
- In general, paints are fluid materials that are widely applied onto surfaces of objects to form thin coating layers, and they are dried and hardened over time to not only protect the surfaces of the objects but also enhance an aesthetic value. Particularly, such paints are often applied to various structures, including buildings, to not only enhance the appearance of the structures and make them look good but also prevent surface damage, including corrosion, and improve durability.
- Examples of paints mainly used for protecting objects and structures are oil paints, enamel paints, and aqueous paints. These paints are effective in not only protecting buildings and materials but also increasing their aesthetic values and improving insulation and heat resistance.
- Typical coating materials such as paints are being developed mainly for the purpose of improving adhesion to objects and structures to improve durability. Therefore, they are not easy to peel off and restoring to the original conditions once dried/hardened after being applied to objects or structures. In particular, when applied to wallpaper or the like, the typical paints cannot be peeled off at all, or the wallpaper will be damaged if such paints are peeled off forcibly. Therefore, restoration to original conditions is not possible with typical paints.
- Furthermore, paints are also often applied on various types of materials, including wood, glass, and etc., but it is difficult to restore the wood, glass, or the like to their original conditions because it is extremely difficult to remove the paints without leaving marks.
- Thus, to meet the needs for frequent changes in preferences, for unique items and spaces, and for easy usage suitable for DIY, paints or coating materials that can be easily peeled off from surfaces of materials (including, not limited to, paper, wood, glass, or etc.) to allow easy restoration for the materials to their original conditions regardless of space and time.
- An object of the present disclosure is to provide an easily-peelable paint composition capable of not only easily peeling off paints from materials to which the paints are applied for easy restorations to original conditions but also protecting the materials with excellent durability while being applied, and designed as an aqueous type for safe use even in contact with human bodies inside buildings or structures such that the paint composition can be used regardless of location and purpose of use.
- Other objects and technical features of the present disclosure will be presented more specifically by the following description of the disclosure, the claims, and the drawings.
- In accordance with an embodiment of the present disclosure, there is provided a paint composition that is easy to peel off from an object, the easily-peelable paint composition containing 30 to 80 parts by weight of a polyvinyl butyral (PVB) resin; 1 to 5 parts by weight of an additive including an antifoaming agent; and the balance of an aqueous solvent including water.
- The PVB resin may have a molecular weight of 100,000 to 210,000 g/mole, and the PVB resin may have a particle size of 170 to 240 μm.
- The paint composition may further contain an additional component including latex, an acrylic copolymer, polyvinyl acetate, urethane, or polyvinyl alcohol. In this case, a weight ratio of the PVB resin to the additional component in the paint composition may be 9 to 12:1.
- The paint composition may further contain at least one of a releasing additive and an inorganic material.
- The releasing additive may be contained in an amount of 1 to 20 parts by weight, the releasing additive being any one or more selected from the group consisting of a silicone oil, a silicone polymer, a silicone emulsion, a modified silicone oil or polymer, a siloxane or modified siloxane, a silicone rubber, a wax-type additive, a surfactant, an oil, and a silane.
- The inorganic material may be contained in an amount of 5 to 40 parts by weight, the inorganic material being any one or more selected from the group consisting of SiO2, CaCO3, BaSO4, talc, Al(OH)3, Al2O3, and TiO2.
- The aqueous solvent may further include any one or more of alcohols, cellosolves, and carbitols.
- The object may be a paper, wood, or glass material.
- The present disclosure relates to an easily-peelable paint composition capable of not only peeling off paints from materials to which the paints are applied for easy restorations to original conditions but also protecting the materials with excellent durability while being applied, such that which easily-peelable paint composition can be used for functional paints.
- The easily-peelable paint composition of the present disclosure is designed eco-friendly as an aqueous type for safe use even in contact with human bodies inside buildings or structures such that the paint composition can be used regardless of location and purpose of use
- There is another advantage in that the easily-peelable paint of the present disclosure is eco-friendly as a non-toxic material because a coating film formed by applying and drying/hardening the easily-peelable paint can be peeled off, and the peeled-off coating film can be dissolved in alcohol for recycling.
- In addition, by mixing or dispersing an insulating material in the easily-peelable paint of the present disclosure, cold protection and thermal insulation effects can be obtained when the easily-peelable paint with the insulating material is applied to an external window.
-
FIG. 1 shows photographs for conditions of glass before and after peel-off depending on content ratios between PVB and latex. -
FIG. 2 shows photographs for conditions of silk (PVC) wallpaper before and after peel-off depending on content ratios between PVB and latex. -
FIG. 3 shows photographs comparing conditions between a paint A′ to which a PVB resin is added alone, a paint B′ containing a releasing additive, and a paint C′ containing an inorganic material when applied to paper. -
FIG. 4 shows photographs comparing conditions between paper to which a paint A′ to which a PVB resin is added alone, a paint B′ containing a releasing additive, and a paint C′ containing an inorganic material are applied when the p are peeled off from the paper according to the present disclosure. - Hereinafter, preferred embodiments of the present disclosure will be described. However, the embodiments of the present disclosure may be modified in various different forms, and the scope of the present disclosure is not limited to the embodiments to be described below. In addition, the embodiments of the present disclosure are provided to more completely explain the present disclosure to those having ordinary knowledge in the art.
- The present disclosure relates to an easily-peelable paint composition containing a polyvinyl butyral (PVB) resin, an additive including an antifoaming agent, and water. The easily-peelable paint composition may further contain a releasing additive or an inorganic material. When compared to a typical peelable coating material, the easily-peelable paint composition is capable of protecting a material to which the easily-peelable paint composition is applied with excellent durability, the easily-peelable paint composition can be easily peeled off even from wallpaper for easily restoring the material to its original condition, and the easily-peelable paint composition is formed as an aqueous type for safe use regardless of location and purpose of use, even inside buildings or structures, where the paint composition is likely to be in contact with human bodies.
- The polyvinyl butyral (PVB) resin is dissolved in the water and painted on a surface of a material, and serves to protect the surface after the solvent is dried. It is preferable that the polyvinyl butyral (PVB) resin is easily peelable when a coating film needs to be peeled off after the material has been dried. The polyvinyl butyral (PVB) resin is a resin that is excellent in flexibility, tensile strength, and toughness in a water-dispersible form, and is advantageous in that the easily-peelable paint composition can be easily peeled off from the material.
- The polyvinyl butyral (PVB) resin may be prepared by a condensation reaction between PVA and n-butyraldehyde. The PVB resin may be in an aqueous or emulsion type, and serves to protect the surface of the material once the solvent is dried after the surface of the material is painted. The PVB resin is a resin that is excellent in flexibility, tensile strength, and toughness, making it possible to easily peel the easily-peelable paint composition from the material.
- The structure of the PVB resin may include a butyral group, an acetyl group, and a hydroxyl group represented by
Formula 1 below as repeating units. - The PVB resin may have a structure including a butyral group, an acetyl group, and a hydroxyl group represented by the following
Formula 1 as repeating units. - In particular, when the PVB resin has a molecular weight of 100,000 to 210,000 g/mole, its peelability and storage stability are excellent, and when the PVB resin has a particle size of 170 to 240 μm, its peelability and storage stability are further improved.
- When an amount of the polyvinyl butyral (PVB) resin contained in the easily-peelable paint composition is less than 30 parts by weight based on the total weight, coating solution stability deteriorates and coating properties are poor, causing a difficulty in forming a coating film. When an amount of the PVB resin contained in the easily-peelable paint composition is more than 80 parts by weight based on the total weight, it is difficult to prepare a paint including a pigment. Accordingly, the PVB resin is contained in the easily-peelable paint composition in an amount of 20 to 80 parts by weight, preferably 35 to 65 parts by weight.
- The easily-peelable paint composition may further include a thickener. The thickener serves to improve the storage stability and the viscosity of the composition to improve coating properties. Examples of the thickener may include cellulose, an acrylic thickener, a urethane thickener, wax, and clay. These may be used alone or in combination of two or more.
- When the thickener is contained in an amount of 2 parts by weight or more, viscosity and thixotropic properties are too high to form a coating film. On the other hand, when the thickener is contained in an amount of less than 0.2 parts by weight, viscosity is too low to apply the composition because it may flow down like water. Therefore, it is advantageous that the thickener is contained in the easily-peelable paint composition in an amount of 0.2 to 2 parts by weight, preferably 0.3 to 1.5 parts by weight.
- The additive may include an antifoaming agent and a functional additive other than the antifoaming agent, such as a leveling agent, a wetting dispersant, a preservative, or an antifreezing agent. These may be used alone or in combination of two or more. The additive is generally used to uniformly maintain the workability and the physical properties of the easily-peelable paint composition.
- In addition, the easily-peelable paint composition of the present disclosure may further include a releasing additive. The releasing additive may be included in the easily-peelable paint composition of the present disclosure so that the easily-peelable paint composition can be easily peeled off from the material to which the paint composition is applied, thereby improving peelability.
- The releasing additive, which is provided to secure the improvement in peelability of the coating film, may increase releasability or improve the cohesion of the resin to decrease adhesion between the paint and the surface of the material, thereby increasing the peeling effect. Preferably, the releasing additive may be a silicone oil, a silicone polymer, a silicone emulsion, a modified silicone oil or polymer, a siloxane or modified siloxane, a silicone rubber, a wax-type additive, a surfactant, an oil, a silane, or the like. However, if a releasing additive other than the silicone oil or polymer is used as the releasing additive for improving peelability, the releasing additive needs to be used in an excess, which causes a peelable paint to have problems in terms of durability, thickness of coating film, strength of coating film, and the like. Thus, the silicone polymer or oil (modified silicone oil or polymer) is suitable for the releasing additive contained in the easily-peelable paint composition of the present disclosure. It is preferable that the releasing additive is contained in the easily-peelable paint composition in an amount of 1 to 20 parts by weight, preferably 3 to 15 parts by weight.
- In addition, the easily-peelable paint composition of the present disclosure may further contain an inorganic material. The inorganic material is contained in the easily-peelable paint composition of the present disclosure so that the easily-peelable paint composition can be easily peeled off from the material to which the paint composition is applied, thereby improving peelability.
- The inorganic material, which is provided to secure the peelability of the coating film, may increase the releasability of the easily-peelable paint composition to decrease adhesion between the paint and the surface of the material, thereby increasing the peeling effect. In addition to the peeling effect, the inorganic material may have a paint amount increasing effect, and serve to improve coating properties and improve the strength of the coating film. Preferably, the inorganic material may include any one or a combination selected from the group consisting of SiO2, CaCO3, BaSO4, talc, Al(OH)3, and TiO2.
- A particle size (μm) of the inorganic material may be controlled to increase a support effect and suppress permeability, and a resin/inorganic material ratio may be controlled to improve peelability while maintaining existing physical properties such as durability, strength of coating film, and thickness of coating film. The inorganic material may be contained in the easily-peelable paint composition in an amount of 5 to 40 parts by weight, preferably 10 to 30 parts by weight.
- The easily-peelable paint composition having the above-mentioned composition is advantageous in that it can be easily peeled off, if necessary, after being applied to a material such as not only wallpaper but also wood or glass, thereby making it possible to recover the material to its original condition. It should be noted that a material such as paper having weak internal cohesion between ingredients of the material with many pores, which may cause interlayer separation, has high adhesion with the paint, making it difficult to peel off a coating layer from the paper.
- In addition, the easily-peelable paint composition may further include a pigment for identifying a painted portion. Examples of the pigment may include an extender pigment, a colored pigment, and a combination thereof. In a case where the pigment is contained in the easily-peelable paint composition, when the pigment is contained in an amount of more than 30 parts by weight, the stability of the paint deteriorates, and the paint fails to play its role properly, as a result peeling off a coating film in a poor state. Thus, the pigment may be contained in the easily-peelable paint composition in an amount of 5 to 30 parts by weight, preferably 5 to 20 parts by weight.
- The solvent included in the easily-peelable paint composition is used to secure the painting workability of the easily-peelable paint composition. Preferably, the solvent may further include any one or more of cellosolves and carbitols in addition to water. These may be used in combination of two or more. When the solvent is used in the point in a small amount, a drying time may be short, and when the solvent is used in the paint in a large amount, a drying time may be long.
- While stirring 70 g of PC-2 as a water-dispersible PVB resin, 10 g of a water-dispersible white pigment capable of exhibiting color was added. Thereafter, 15 g of water was added and mixed well for 10 minutes. While stirring continuously, 4 g of TT-935D was added as a thickener to increase a viscosity of a paint, and an rpm of a stirrer was increased to facilitate the mixing. After stirring at a high speed for 30 to 60 minutes or more, 1 g of F-810 was mixed as an antifoaming agent suppressing bubbles and destroying generated bubbles, and then stirred at a high speed for 30 minutes or more to prepare a paint of Example 1.
- [Experimental Results]
- The paint of Example 1 was applied onto a wallpaper specimen at a thickness of 50 to 100 μm using an airless spray, a roller (brush), or the like, and then dried. A coating film formed after leaving the specimen for 1 month was checked for peelability and physical properties, and the results were obtained as shown in Table 1. The physical properties were evaluated in the following manner
- * Measurement of Peelability: When peeling off (removing) the film coated on the wallpaper after 1 day, its condition was evaluated in five stages (evaluated together with a condition of the material after peeling off the film)—5: excellent, 4: good, 3: normal, 2: poor, and 1: bad.
- * Measurement of Strength of Coating Film: An elasticity and a tearing condition of the dried film when pulled were evaluated in five stages—5: excellent, 4: good, 3: normal, 2: poor, and 1: bad.
- * Measurement of Smoothness of Coating Film: A surface smoothness and an applied condition of the dried film were evaluated with naked eyes in five stages—5: excellent, 4: good, 3: normal, 2: poor, and 1: bad.
- * Measurement of Compatibility: The final paint was stored in a transparent sample container, and its sedimentation, layer separation, and emulsion condition were measured—{circle around (◯)}: excellent, ◯: good, ⋄: normal, Δ: poor, and ×: bad.
- * Measurement of Gloss: A glossiness of the dried film was measured in four stages—gloss {circle around (◯)}: high gloss, ◯: egg shell gloss, Δ: semi gloss, and ×: matt.
- * Measurement of Surface Condition: A particle condition of the dried film was evaluated with naked eyes and by touch—good, normal, and bad.
-
TABLE 1 Strength of Smoothness of Surface Peelability coating film coating film Compatibility Gloss condition Example 1 2 5 3 ⊚ ⊚ good - As shown in Table 1 above, it was confirmed that the paint containing a PVB resin had a certain degree of peelability with respect to the wallpaper, and the paint containing a PVB resin was evaluated as being excellent in terms of strength of coating film, compatibility, gloss, and surface condition. It should be noted that paper has weak internal cohesion with many pores, which may easily cause interlayer separation, and thus has relatively poor peelability as compared with glass or the like.
- While stirring 60 g of a PVB emulsion resin having a molecular weight as shown in Table 2 below, 11 g of water was added and mixed for 10 minutes. Thereafter, 1 g of F-810 (Tego) was mixed as an antifoaming agent suppressing bubbles and destroying generated bubbles while stirring continuously and stirred at a high speed for 30 minutes or more to prepare a paint composition of each of Examples 2 to 5 according to the present disclosure.
-
TABLE 2 Molecular weight Classification of PVB (g/mole) Example 2 100,000 to 160,000 Example 3 160,000 to 210,000 Example 4 50,000 to 90,0000 Example 5 220,000 to 280,000 - The easily-peelable paint composition was tested for physical properties depending on the molecular weight of the PVB, and the results were obtained as shown in Table 3. The physical properties of the paint composition were evaluated in the following manner
- * Measurement of Transparency: A transparent condition of the film was measured using a transmittance, and determined in five stages (relative evaluation)—transmittance {circle around (◯)}: excellent, ◯: good, ⋄: normal, Δ: poor, and ×: bad.
- * Measurement of Storage Stability: The final paint was stored in a transparent sample container, and its sedimentation, layer separation, emulsion condition, and the like were measured—storage stability {circle around (◯)}: excellent, ◯: good, ⋄: normal, Δ: poor, and ×: bad.
- * Measurement of Tensile Rate: A length to which the dried film (20*100 mm) is stretched when pulled was compared by %.
- * Measurement of Glass Transition Temperature: A glass transition temperature was measured using differential scanning calorimetry (DSC) equipment.
- * Measurement of Peelability: When peeling off (removing) the film coated on silk (PVC) wallpaper after 1 day, its condition was evaluated in five stages (evaluated together with a condition of the material after peeling off the film)—peelability {circle around (◯)}: excellent, ◯: good, ⋄: normal, Δ: poor, and ×: bad.
-
TABLE 3 Classifi- Storage Tensile Tg cation Transparency stability rate (° C.) Peelability Example 2 ⊚ ⊚ 160 to 180 70 to 76 ⊚ Example 3 ⊚ ⊚ 160 to 180 70 to 76 ⊚ Example 4 ⊚ ◯ 120 to 150 65 to 72 ⋄ Example 5 ⋄ ⋄ 140 to 160 77 to 84 ◯ - Referring to the experimental results of Table 3 above, it was confirmed that in Examples 2 and 3, in which the PVB resin had a molecular weight of 100,000 to 210,000 g/mole, the peeling effect was excellent, and the storage stability and the tensile rate were also best. On the other hand, it was confirmed that in Examples 4 and 5, in which the PVB resin had a molecular weight of less than 100,000 g/mole or more than 210,000 g/mole, the peeling and storage stability effects were relatively poor.
- In order to analyze physical properties of a paint composition depending on a particle size of a PVB resin having a molecular weight of 100,000 to 160,000 g/mole, a PVB emulsion resin having a particle size range as shown in Table 4 below was used in preparing a paint composition of each of Examples 6 to 9 in the same manner as in Experimental Example 2. Thereafter, the respective physical properties of the paint compositions prepared were measured.
-
TABLE 4 Classifi- Particle Storage Tensile cation size μm Transparency stability rate Peelability Example 6 70 to 100 ◯ ◯ 80 to 100 ⋄ Example 7 100 to 160 ⋄ ◯ 110 to 140 ◯ Example 8 170 to 240 ⋄ ⊚ 150 to 180 ⊚ Example 9 240 to 300 Δ X 120 to 160 Δ - Referring to the experimental results of Table 4 above, it was confirmed that in Example 8, in which the PVB resin had a particle size of 170 to 240 μm, not only the peelability but also the tensile rate and the storage stability were best.
- In order to check components that may be further contained, in addition to the PVB resin (Example 8), in the easily-peelable paint composition according to the present disclosure, a vinyl copolymer (an acrylic emulsion having a methacryl acid MAA: acryl acid AA: itaconic acid weight ratio of 7:2:1), a polyacetate emulsion (PVAc, acetate content: 7 wt %), polyvinyl alcohol (PVOH), or an SBR latex emulsion (KSL341) was mixed in a weight ratio as shown in each of Tables 5 to 8 below, and then a paint composition of each of Examples 10 to 21 was prepared in the same manner as in Experimental Example 3. Thereafter, the respective physical properties of the paint compositions prepared were measured in the same manner as described in Experimental Example 3, and a strength of coating film, which was added, was measured in the following manner
- * Strength of Coating Film: An elasticity, a tearing condition, and the like of the dried film when pulled were evaluated in five stages—strength of coating film {circle around (◯)}: excellent, ◯: good, ⋄: normal, Δ: poor, and ×: bad.
-
TABLE 5 PVB:acrylic resin Strength Classifi- (weight Transpar- Storage of coating cation ratio) ency stability film Peelability Example 10 9:01 ⋄ ⋄ ⋄ ◯ Example 11 7:03 X X X X Example 12 5:05 X X X X -
TABLE 6 PVB:PVAc Strength Classifi- (weight Transpar- Storage of coating cation ratio) ency stability film Peelability Example 13 9:1 ⋄ ◯ ⋄ ⋄ Example 14 7:3 Δ Δ Δ Δ Example 15 5:5 X X X X -
TABLE 7 PVB:PVOH Strength Classifi- (weight Transpar- Storage of coating cation ratio) ency stability film Peelability Example 16 9:1 ⊚ ◯ ◯ ⊚ Example 17 7:3 ◯ ⋄ Δ ◯ Example 18 5:5 ◯ ⋄ Δ ◯ -
TABLE 8 PVB:latex Strength Classifi- (weight Transpar- Storage of coating cation ratio) ency stability film Peelability Example 19 9:1 ⊚ ◯ ⊚ ◯ Example 20 7:3 ◯ ⋄ ⋄ ⋄ Example 21 5:5 ⋄ ⋄ ⋄ X - Referring to Tables 5 to 8, it was confirmed that, when the PVOH or latex component was mixed with the PVB resin in a predetermined weight ratio, the same or better effect was caused in terms of any one or more of transparency, storage stability, strength of coating film, and storage stability. In particular, it was seen that when the weight ratio of PVB:PVOH or PVB:latex was 9:1, the best peeling effect was caused among used mixtures. Meanwhile, it was confirmed that the effect might be reduced in terms of any one or more of transparency, storage stability, strength of coating film, and storage stability as the additional component content increases above a predetermined standard and the PVB content decreases below a predetermined level.
FIGS. 1 and 2 show photographs of experiments on peelability and transparency with respect to glass and silk (PVC) wallpaper depending on a content ratio between PVB (Example 8) and latex as listed in Table 9 below. -
TABLE 9 PVB:latex Classification (weight ratio) #1 PVB alone #11 PVB:latex = 9:1 #12 PVB:latex = 7:3 #13 PVB:latex = 5:5 - As shown in
FIG. 1 , with respect to the glass, it was confirmed that the transparency was excellent in the following order: #1>#11>#12>#13, and the peelability was excellent in the following order: #1>#11>#12>>#13. As shown inFIG. 2 , with respect to the silk (PVC) wallpaper, the transparency was excellent in the following order: #1>#11>#12>#13, and the peelability was excellent in the following order: #1>>#11>>#12>>>#13. - While stirring 60 g of PC-2 (Shark-Solutions) as a water-dispersible PVB resin, 15 g of a water-dispersible white pigment (Wooshin Pigment) capable of exhibiting color and characteristics of an inorganic material was added. Thereafter, 11 g of water was added and mixed well for 10 minutes. While stirring continuously, 5.5 g of TT-935D (Dow Chemical) was added as a thickener to increase a viscosity of a paint, and an rpm of a stirrer was increased to facilitate the mixing. After stirring at a high speed for 30 to 60 minutes or more, 7.5 g of PMX200F (Saehan Silichem) was mixed as a silicone releasing additive capable of improving peelability, and 1 g of F-810 (Tego) was mixed as an antifoaming agent suppressing bubbles and destroying generated bubbles, and then stirred at a high speed for 30 minutes or more to prepare an easily-peelable paint composition according to the present disclosure.
- An easily-peelable paint composition according to each of Examples 23 to 29 was prepared in the same manner as in Example 22, but with the composition and content described in Table 10 below.
-
TABLE 10 Classification Antifoaming Resin H2O Thickener Pigment agent Releasing additive Material name White PC-2 — TT-935D pigment F-810 PMX200F MEM3345 PMX50 HV495 PMX0345 PMX0245 Example 22 60 11 5.5 15 1.0 7.5 Example 23 60 11 5.5 15 1.0 7.5 Example 24 60 11 5.5 15 1.0 20 Example 25 60 11 5.5 15 1.0 25 Example 26 60 9 5 15 1.0 10 Example 27 60 9 5 15 1.0 10 Example 28 60 9 5 15 1.0 10 Example 29 60 9 5 15 1.0 10 - While stirring 60 g of PC-2 (Shark-Solutions) as a water-dispersible PVB resin, 20 g of a water-dispersible white pigment (Wooshin Pigment) capable of exhibiting color and characteristics of an inorganic material was added. Thereafter, 14 g of water was added and mixed well for 10 minutes. While stirring continuously, 3 g of TT-935D (Dow Chemical) was added as a thickener to increase a viscosity of a paint and an rpm of a stirrer was increased to facilitate the mixing. After stirring at a high speed for 30 to 60 minutes or more, 2 g of SiO2 (5 μm) (SOLVAY) was added as an inorganic material capable of improving peelability and improving coating properties of the paint and stirred at a high speed for 60 minutes or more, and then 1 g of F-810 (Tego) was mixed as an antifoaming agent suppressing bubbles and destroying generated bubbles and stirred at a high speed for 30 minutes or more to prepare an easily-peelable paint composition according to the present disclosure.
- An easily-peelable paint composition according to each of Examples 31 to 37 was prepared in the same manner as in Example 30, but with the composition and content described in Table 11 below.
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TABLE 11 Classification Antifoaming Resin H2O Thickener Pigment agent Inorganic material Material name White SiO2 CaCO3 CaCO3 BaSO4 BaSO4 PC-2 — TT-935D pigment F-810 (5 μm) (5 μm) (20 μm) (2 μm) (10 μm) Talc Example 30 60 14 3 20 1.0 3 Example 31 60 15 2 20 1.0 3 Example 32 60 9.5 5 18 1.0 7.5 Example 33 60 9.5 5 17 1.0 7.5 Example 34 60 7 5 17 1.0 10 Example 35 60 7 5 17 1.0 10 Example 36 60 7 5 17 1.0 10 Example 37 60 7 5 17 1.0 10 - The paint of each of Examples 22 to 29 and Examples 30 to 37 according to Experimental Examples 5 and 6, respectively, was applied onto a wallpaper specimen at a thickness of 50 to 100 μm using an airless spray, a roller (brush), or the like, and then dried. A coating film formed after leaving the specimen for 1 month was checked for peelability and physical properties. The physical properties were evaluated in the same manner as in Experimental Example 1, and the evaluation results are shown in Table 12 for [an easily-peelable paint containing a releasing additive] and Table 13 for [an easily-peelable paint containing an inorganic material]. (The higher the number, the better the peelability and the strength of the coating film:
scores 1 to 5.) -
TABLE 12 Strength of Surface Compat- Peelability coating film condition ibility Gloss Example 22 3 2 Stained Δ X Example 23 1 4 Good ◯ ◯ Example 24 3 1 Good Δ Δ Example 25 3 1 Good Δ Δ Example 26 3 2 Slightly ◯ ⊚ stained Example 27 1 4 Slightly X ⊚ stained Example 28 4 1 Slightly ◯ ⊚ stained Example 29 4 1 Slightly ◯ ⊚ stained -
TABLE 13 Strength of Smoothness of Peelability coating film coating film Compatibility Gloss Liquid state Example 30 2 2 1 ◯ X Creamy Example 31 3 2 3 X X Liquid Example 32 3 4 2 ⊚ ⊚ Creamy Example 33 3 4 3 ⊚ ⊚ Liquid Example 34 4 3 2 ⊚ Δ Creamy Example 35 4 3 2 ⊚ Δ Creamy Example 36 4 3 2 ⊚ Δ Creamy Example 37 3 3 3 ⊚ ◯ Liquid - Referring to Tables 12 and 13, it was confirmed that when the releasing additive or the inorganic material was contained, better peelability was caused. (The peeling effect was higher than that in Example 1, in which the releasing additive or the inorganic material was not contained.)
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FIGS. 3 and 4 show tests of paints of the present disclosure for peelability when applied to wallpaper. A ofFIG. 3 and A′ ofFIG. 4 show an applied condition and a peeled-off condition of a paint containing no releasing additive and no inorganic material (Example 1), respectively. - B of
FIG. 3 and B′ ofFIG. 4 show an applied condition and a peeled-off condition of a paint containing a releasing additive (Example 26), respectively, and C ofFIG. 3 and C′ ofFIG. 4 show an applied condition and a peeled-off condition of a paint containing an inorganic material as an additive (Example 33), respectively. - Based thereon as well, it can be seen that the peeling effect is better with respect to wallpaper when at least the releasing additive or the inorganic material is contained.
- Although the easily-peelable paint composition according to the present disclosure has been described above, the present disclosure is not limited to the above-described embodiments and may be modified in various forms within the scope of the technical spirit to which the present disclosure falls.
Claims (7)
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KR20210081338 | 2021-06-23 | ||
KR10-2021-0081338 | 2021-06-23 | ||
PCT/KR2021/008556 WO2022025466A1 (en) | 2020-07-27 | 2021-07-06 | Peelable paint composition |
US202217625943A | 2022-01-10 | 2022-01-10 | |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6964989B1 (en) * | 1998-07-08 | 2005-11-15 | Ashland Inc. | Peelable coating composition |
US8524825B2 (en) * | 2007-02-08 | 2013-09-03 | Valspar Sourcing, Inc. | Peel-coat compositions |
WO2018067859A1 (en) * | 2016-10-06 | 2018-04-12 | Cal-West Specialty Coatings, Inc. | Protective coating systems for paint booths that resist discoloration |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05112742A (en) * | 1991-10-21 | 1993-05-07 | Denki Kagaku Kogyo Kk | Easily peelable coating composition |
JP3121085B2 (en) * | 1991-12-18 | 2000-12-25 | 電気化学工業株式会社 | Easy release coating composition |
JP3107030B2 (en) | 1997-03-14 | 2000-11-06 | 鹿島建設株式会社 | How to clean the structure surface |
US20010046595A1 (en) * | 1999-12-14 | 2001-11-29 | Moran James R. | Intrusion resistant glass laminates |
JP3669263B2 (en) * | 2000-10-16 | 2005-07-06 | 松下電工株式会社 | Polyester molding material for tableware and tableware |
JP2005145752A (en) * | 2003-11-14 | 2005-06-09 | Tdk Corp | Ceramic green sheet for manufacturing laminated chip electronic component, and method of manufacturing ceramic green sheet |
JP2006096794A (en) | 2004-09-28 | 2006-04-13 | Solar:Kk | Coating agent composition for coloring |
EP2089222A4 (en) | 2006-11-10 | 2010-12-01 | Cal West Specialty Coatings In | Peel-off coating compositions |
KR100773783B1 (en) | 2006-12-27 | 2007-11-12 | (주)디피아이 홀딩스 | Paint for forming the exfditation coating layer and method of forming the exfditation coating layer |
CN103146514B (en) * | 2013-03-27 | 2014-11-26 | 江松节 | Degreasing detergent |
JP6434437B2 (en) | 2016-03-24 | 2018-12-05 | 藤森工業株式会社 | Release film with excellent releasability |
KR101714740B1 (en) * | 2016-05-17 | 2017-03-09 | 주식회사 노루알앤씨 | Aqueous peelable paint composition including polyurethane water-dispersion |
KR102276125B1 (en) * | 2017-10-19 | 2021-07-13 | 한국조선해양 주식회사 | Aqueous peelable paint composition including urea modified polyurethane water-dispersion and method for preparing the same |
CN110452627A (en) * | 2018-05-07 | 2019-11-15 | 上海纳尔实业股份有限公司 | PP gum pad pasting and its manufacturing method |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6964989B1 (en) * | 1998-07-08 | 2005-11-15 | Ashland Inc. | Peelable coating composition |
US8524825B2 (en) * | 2007-02-08 | 2013-09-03 | Valspar Sourcing, Inc. | Peel-coat compositions |
WO2018067859A1 (en) * | 2016-10-06 | 2018-04-12 | Cal-West Specialty Coatings, Inc. | Protective coating systems for paint booths that resist discoloration |
Non-Patent Citations (1)
Title |
---|
Machine translation of KR 100773783 B1, published 2007-11-12. * |
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