US20230062079A1 - Hemp composites - Google Patents

Hemp composites Download PDF

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Publication number
US20230062079A1
US20230062079A1 US17/822,304 US202217822304A US2023062079A1 US 20230062079 A1 US20230062079 A1 US 20230062079A1 US 202217822304 A US202217822304 A US 202217822304A US 2023062079 A1 US2023062079 A1 US 2023062079A1
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Prior art keywords
hemp
mixture
composite
oil
paper
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US17/822,304
Inventor
Elham Fini
SK Faisal Kabir
Patrick Fajen
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Arizona Board of Regents of ASU
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Individual
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Filing date
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Priority to US17/822,304 priority Critical patent/US20230062079A1/en
Assigned to ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY reassignment ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FAJEN, PATRICK, KABIR, Sk Faisal, FINI, Elham
Publication of US20230062079A1 publication Critical patent/US20230062079A1/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/14Disintegrating in mills
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C1/00Pretreatment of the finely-divided materials before digesting
    • D21C1/02Pretreatment of the finely-divided materials before digesting with water or steam
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/02Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/18De-watering; Elimination of cooking or pulp-treating liquors from the pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/14Secondary fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07Nitrogen-containing compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21JFIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
    • D21J3/00Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds

Definitions

  • This invention relates to methods of making hemp composites and articles (e.g., hemp-containing paper products) made from the hemp composites.
  • Paper products have a variety of uses.
  • corrugated boxes are used to package goods for transportation.
  • Paper products, including corrugated boxes are usually made with a feedstock including wood from trees (e.g., softwood trees, hardwood trees, or a combination thereof). Trees suitable for the production of paper products typically take about 20 years to reach sufficient size for harvesting.
  • making hemp-containing products includes processing hemp (e.g., hemp stalks), and combining the processed hemp with paper and oil to yield a hemp mixture, removing water from the hemp mixture, and drying the hemp mixture to yield a hemp composite.
  • the paper can be post-consumer recycled paper.
  • a weight ratio of hemp to water in the hemp mixture can be adjusted to achieve a selected elasticity of the hemp composite.
  • the hemp composite is in the form of cardboard (e.g., corrugated cardboard), masonry bricks, concrete masonry units, drywall and gypsum boards, and containers, including food grade and non-food grade containers.
  • making a hemp composite includes processing hemp to yield a processed hemp.
  • the processed hemp includes water.
  • the first general aspect further includes combining the processed hemp with paper and oil to yield a hemp mixture, removing at least some of the water from the hemp mixture, and drying the hemp mixture to yield the hemp composite.
  • Implementation of the first general aspect can include one or more of the following features.
  • the hemp includes hemp stalks.
  • processing the hemp includes shredding and pulverizing the hemp.
  • processing the hemp further includes combining the hemp with boiling water to yield a pulp mixture.
  • processing the hemp further includes breaking down cell walls of the hemp in the pulp mixture.
  • breaking down the cell walls of the hemp includes combining the pulp mixture with sodium bicarbonate.
  • Certain implementations further include adjusting a weight ratio of hemp to water in the pulp mixture to achieve a selected elasticity of the hemp composite.
  • Some implementations further include removing at least some of the water from the pulp mixture to yield a drained pulp mixture.
  • Some cases further include combining the drained pulp mixture with water at ambient temperature to yield the processed hemp.
  • the paper can be shredded.
  • the paper includes post-consumer recycled paper.
  • the oil includes bio-oil.
  • the bio-oil includes amines.
  • Certain implementations further include shaping the hemp mixture before drying the hemp mixture.
  • the hemp composite is oil-infused.
  • An article can be formed from the hemp mixture of the first general aspect.
  • the article is one of cardboard, clay pigeons, masonry bricks, concrete masonry units, gypsum boards, food-grade containers, and non-food grade containers.
  • the cardboard includes a corrugated cardboard box.
  • a hemp composite in a second general aspect, includes hemp, paper, and oil.
  • Implementation of the second general aspect can include one or more of the following features.
  • the hemp includes hemp stalks.
  • the paper includes post-consumer recycled paper.
  • the oil includes bio-oil.
  • An article can include the composite of the second general aspect.
  • the article is one of cardboard, clay pigeons, masonry bricks, concrete masonry units, gypsum boards, food-grade containers, and non-food grade containers.
  • the cardboard includes a corrugated cardboard box.
  • hemp takes only four months to become harvestable, and thus can be harvested about 60 times more than wood trees in the same time span.
  • the combination of hemp and post-consumer recycled paper provides a low-cost, biodegradable, and biologically safe option to address a growing demand for packaging and other products.
  • the hemp composite also decreases the use of trees, thereby increasing the amount of carbon dioxide sequestered from the atmosphere.
  • the hemp composite has carbon-negative characteristics and can absorb select gaseous emissions from the air.
  • FIG. 1 is a flow chart showing steps in the process of making a hemp composite.
  • FIG. 1 shows steps in a process for making a hemp composite.
  • hemp is processed.
  • the hemp can include hemp stalks, hemp shivs, or both. Processing the hemp includes reducing a size of the hemp, combining the hemp with water, and breaking down the cellular structure of the hemp.
  • the processed hemp is combined with paper and oil to yield a hemp mixture.
  • the paper is typically post-consumer recycled paper.
  • the paper can be shredded.
  • the oil can be an amine-rich bio-oil.
  • water is removed from the hemp mixture.
  • a weight ratio of hemp to water in the hemp mixture can be adjusted to achieve a selected elasticity of the hemp composite.
  • the hemp mixture is dried to yield an oil-infused hemp composite.
  • the paper and oil increases the durability, adhesion, and elasticity of the hemp composite.
  • the hemp composite Before drying, the hemp composite can be shaped (e.g., molded) into various articles, such as biodegradable containers and bricks (e.g., terracotta and concrete masonry units) for various types of construction, and clay pigeons.
  • the hemp composite can also be added to drywall, gypsum boards, food-grade containers, and non-food grade containers.
  • hemp is used to make corrugated cardboard (e.g., for use in boxes).
  • hemp stalks are shredded and pulverized.
  • the shredded, pulverized hemp stalks are combined with boiling water and boiled until a pulp mixture is formed (e.g., about one hour).
  • the pulp mixture is treated to break down cell walls of the hemp.
  • treating the pulp mixture includes combining sodium bicarbonate with the boiling pulp mixture. Water is drained from the pulp mixture, and the pulp is combined with water at ambient temperature to yield a washed pulp mixture. Post-consumer recycled paper and amine-rich bio-oils are combined with the washed pulp mixture to yield a hemp mixture.
  • a silk strainer is used to remove water from the hemp mixture and form hemp sheets.
  • the hemp sheets are dried to yield a hemp composite, for example, by laying the sheets on an absorbent material and cold pressing the absorbent material to remove water and promote uniform drying.
  • the hemp composite is rolled and can be stored for later processing in corrugating machinery to yield hemp-containing corrugated cardboard.
  • the hemp-containing corrugated cardboard can provide the same strength as a thicker product made from wood, and provides an environmentally friendly alternative to conventional corrugated cardboard.

Abstract

A hemp composite includes hemp, paper, and oil. Making a hemp composite includes processing hemp to yield a processed hemp. The processed hemp includes water. Making a hemp composite further includes combining the processed hemp with paper and oil to yield a hemp mixture, removing at least some of the water from the hemp mixture, and drying the hemp mixture to yield the hemp composite.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • This application claims the benefit of U.S. Patent Application 63/239,212 filed on Aug. 31, 2021, which is incorporated herein by reference in its entirety.
  • TECHNICAL FIELD
  • This invention relates to methods of making hemp composites and articles (e.g., hemp-containing paper products) made from the hemp composites.
  • BACKGROUND
  • Paper products have a variety of uses. In one example, corrugated boxes are used to package goods for transportation. Paper products, including corrugated boxes, are usually made with a feedstock including wood from trees (e.g., softwood trees, hardwood trees, or a combination thereof). Trees suitable for the production of paper products typically take about 20 years to reach sufficient size for harvesting.
  • SUMMARY
  • Inventive aspects of this disclosure include methods of making hemp composites and articles made from hemp composites. In some embodiments, making hemp-containing products includes processing hemp (e.g., hemp stalks), and combining the processed hemp with paper and oil to yield a hemp mixture, removing water from the hemp mixture, and drying the hemp mixture to yield a hemp composite. The paper can be post-consumer recycled paper. A weight ratio of hemp to water in the hemp mixture can be adjusted to achieve a selected elasticity of the hemp composite. In some examples, the hemp composite is in the form of cardboard (e.g., corrugated cardboard), masonry bricks, concrete masonry units, drywall and gypsum boards, and containers, including food grade and non-food grade containers.
  • In a first general aspect, making a hemp composite includes processing hemp to yield a processed hemp. The processed hemp includes water. The first general aspect further includes combining the processed hemp with paper and oil to yield a hemp mixture, removing at least some of the water from the hemp mixture, and drying the hemp mixture to yield the hemp composite.
  • Implementation of the first general aspect can include one or more of the following features.
  • In some cases, the hemp includes hemp stalks. In some implementations, processing the hemp includes shredding and pulverizing the hemp. In certain implementations, processing the hemp further includes combining the hemp with boiling water to yield a pulp mixture. In some cases, processing the hemp further includes breaking down cell walls of the hemp in the pulp mixture. In some implementations, breaking down the cell walls of the hemp includes combining the pulp mixture with sodium bicarbonate. Certain implementations further include adjusting a weight ratio of hemp to water in the pulp mixture to achieve a selected elasticity of the hemp composite. Some implementations further include removing at least some of the water from the pulp mixture to yield a drained pulp mixture. Some cases further include combining the drained pulp mixture with water at ambient temperature to yield the processed hemp. The paper can be shredded. In some implementations, the paper includes post-consumer recycled paper. In some cases, the oil includes bio-oil. In certain implementations, the bio-oil includes amines. Certain implementations further include shaping the hemp mixture before drying the hemp mixture. In some cases, the hemp composite is oil-infused. An article can be formed from the hemp mixture of the first general aspect. In some cases, the article is one of cardboard, clay pigeons, masonry bricks, concrete masonry units, gypsum boards, food-grade containers, and non-food grade containers. In some implementations, the cardboard includes a corrugated cardboard box.
  • In a second general aspect, a hemp composite includes hemp, paper, and oil.
  • Implementation of the second general aspect can include one or more of the following features.
  • In some cases, the hemp includes hemp stalks. In some implementations, the paper includes post-consumer recycled paper. In some implementations, the oil includes bio-oil. An article can include the composite of the second general aspect. In some cases, the article is one of cardboard, clay pigeons, masonry bricks, concrete masonry units, gypsum boards, food-grade containers, and non-food grade containers. In certain implementations, the cardboard includes a corrugated cardboard box.
  • The processes and composites described in this disclosure provide various advantages. For example, hemp takes only four months to become harvestable, and thus can be harvested about 60 times more than wood trees in the same time span. The combination of hemp and post-consumer recycled paper provides a low-cost, biodegradable, and biologically safe option to address a growing demand for packaging and other products. The hemp composite also decreases the use of trees, thereby increasing the amount of carbon dioxide sequestered from the atmosphere. The hemp composite has carbon-negative characteristics and can absorb select gaseous emissions from the air.
  • The details of one or more embodiments of the subject matter of this disclosure are set forth in the accompanying drawings and the description. Other features, aspects, and advantages of the subject matter will become apparent from the description, the drawings, and the claims.
  • BRIEF DESCRIPTION OF DRAWINGS
  • FIG. 1 is a flow chart showing steps in the process of making a hemp composite.
  • DETAILED DESCRIPTION
  • FIG. 1 shows steps in a process for making a hemp composite. In 102, hemp is processed. The hemp can include hemp stalks, hemp shivs, or both. Processing the hemp includes reducing a size of the hemp, combining the hemp with water, and breaking down the cellular structure of the hemp. In 104, the processed hemp is combined with paper and oil to yield a hemp mixture. The paper is typically post-consumer recycled paper. The paper can be shredded. The oil can be an amine-rich bio-oil. In 106, water is removed from the hemp mixture. A weight ratio of hemp to water in the hemp mixture can be adjusted to achieve a selected elasticity of the hemp composite. In 108, the hemp mixture is dried to yield an oil-infused hemp composite. The paper and oil increases the durability, adhesion, and elasticity of the hemp composite.
  • Before drying, the hemp composite can be shaped (e.g., molded) into various articles, such as biodegradable containers and bricks (e.g., terracotta and concrete masonry units) for various types of construction, and clay pigeons. The hemp composite can also be added to drywall, gypsum boards, food-grade containers, and non-food grade containers. The strength of hemp at the cellular level, which exceeds that of wood, contributes to the strength and durability of these products.
  • In one embodiment of process 100, hemp is used to make corrugated cardboard (e.g., for use in boxes). In this embodiment, hemp stalks are shredded and pulverized. The shredded, pulverized hemp stalks are combined with boiling water and boiled until a pulp mixture is formed (e.g., about one hour). The pulp mixture is treated to break down cell walls of the hemp. In one example, treating the pulp mixture includes combining sodium bicarbonate with the boiling pulp mixture. Water is drained from the pulp mixture, and the pulp is combined with water at ambient temperature to yield a washed pulp mixture. Post-consumer recycled paper and amine-rich bio-oils are combined with the washed pulp mixture to yield a hemp mixture. A silk strainer is used to remove water from the hemp mixture and form hemp sheets. The hemp sheets are dried to yield a hemp composite, for example, by laying the sheets on an absorbent material and cold pressing the absorbent material to remove water and promote uniform drying. The hemp composite is rolled and can be stored for later processing in corrugating machinery to yield hemp-containing corrugated cardboard. The hemp-containing corrugated cardboard can provide the same strength as a thicker product made from wood, and provides an environmentally friendly alternative to conventional corrugated cardboard.
  • Although this disclosure contains many specific embodiment details, these should not be construed as limitations on the scope of the subject matter or on the scope of what may be claimed, but rather as descriptions of features that may be specific to particular embodiments. Certain features that are described in this disclosure in the context of separate embodiments can also be implemented, in combination, in a single embodiment. Conversely, various features that are described in the context of a single embodiment can also be implemented in multiple embodiments, separately, or in any suitable sub-combination. Moreover, although previously described features may be described as acting in certain combinations and even initially claimed as such, one or more features from a claimed combination can, in some cases, be excised from the combination, and the claimed combination may be directed to a sub-combination or variation of a sub-combination.
  • Particular embodiments of the subject matter have been described. Other embodiments, alterations, and permutations of the described embodiments are within the scope of the following claims as will be apparent to those skilled in the art. While operations are depicted in the drawings or claims in a particular order, this should not be understood as requiring that such operations be performed in the particular order shown or in sequential order, or that all illustrated operations be performed (some operations may be considered optional), to achieve desirable results.
  • Accordingly, the previously described example embodiments do not define or constrain this disclosure. Other changes, substitutions, and alterations are also possible without departing from the spirit and scope of this disclosure.

Claims (25)

What is claimed is:
1. A method of making a hemp composite, the method comprising:
processing hemp to yield a processed hemp, wherein the processed hemp comprises water;
combining the processed hemp with paper and oil to yield a hemp mixture;
removing at least some of the water from the hemp mixture; and
drying the hemp mixture to yield the hemp composite.
2. The method of claim 1, wherein the hemp comprises hemp stalks.
3. The method of claim 1, wherein processing the hemp comprises shredding and pulverizing the hemp.
4. The method of claim 3, wherein processing the hemp further comprises combining the hemp with boiling water to yield a pulp mixture.
5. The method of claim 4, wherein processing the hemp further comprises breaking down cell walls of the hemp in the pulp mixture.
6. The method of claim 5, wherein breaking down the cell walls of the hemp comprises combining the pulp mixture with sodium bicarbonate.
7. The method of claim 4, further comprising adjusting a weight ratio of hemp to water in the pulp mixture to achieve a selected elasticity of the hemp composite.
8. The method of claim 4, further comprising removing at least some of the water from the pulp mixture to yield a drained pulp mixture.
9. The method of claim 8, further comprising combining the drained pulp mixture with water at ambient temperature to yield the processed hemp.
10. The method of claim 1, wherein the paper is shredded.
11. The method of claim 10, wherein the paper comprises post-consumer recycled paper.
12. The method of claim 1, wherein the oil comprises bio-oil.
13. The method of claim 12, wherein the bio-oil comprises amines.
14. The method of claim 1, further comprising shaping the hemp mixture before drying the hemp mixture.
15. The method of claim 1, wherein the hemp composite is oil-infused.
16. An article formed from the hemp mixture of claim 1.
17. The article of claim 16, wherein the article is one of cardboard, clay pigeons, masonry bricks, concrete masonry units, gypsum boards, food-grade containers, and non-food grade containers.
18. The article of claim 17, wherein the cardboard comprises a corrugated cardboard box.
19. A hemp composite comprising:
hemp;
paper; and
oil.
20. The composite of claim 19, wherein the hemp comprises hemp stalks.
21. The composite of claim 19, wherein the paper comprises post-consumer recycled paper.
22. The composite of claim 19, wherein the oil comprises bio-oil.
23. An article comprising the composite of claim 19.
24. The article of claim 23, wherein the article is one of cardboard, clay pigeons, masonry bricks, concrete masonry units, gypsum boards, food-grade containers, and non-food grade containers.
25. The article of claim 24, wherein the cardboard comprises a corrugated cardboard box.
US17/822,304 2021-08-31 2022-08-25 Hemp composites Pending US20230062079A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6225437B1 (en) * 1999-06-24 2001-05-01 Albemarle Corporation Sizing agents of enhanced performance capabilities
US8512521B2 (en) * 2009-04-09 2013-08-20 Kemira Oyj Product for the sizing of paper
US20170306564A1 (en) * 2016-04-25 2017-10-26 Ecolab Usa Inc. Methods and compositions for enhancing sizing in papermaking process
US20180179447A1 (en) * 2015-06-12 2018-06-28 Netternergy B.V. System and method for the conversion of biomass, and products thereof
US20190264385A1 (en) * 2018-02-26 2019-08-29 David Pauwels Methods for preparing cannabis hurd fiber, purified cannabis hurd fiber, and articles containing the purified cannabis hurd fiber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6225437B1 (en) * 1999-06-24 2001-05-01 Albemarle Corporation Sizing agents of enhanced performance capabilities
US8512521B2 (en) * 2009-04-09 2013-08-20 Kemira Oyj Product for the sizing of paper
US20180179447A1 (en) * 2015-06-12 2018-06-28 Netternergy B.V. System and method for the conversion of biomass, and products thereof
US20170306564A1 (en) * 2016-04-25 2017-10-26 Ecolab Usa Inc. Methods and compositions for enhancing sizing in papermaking process
US20190264385A1 (en) * 2018-02-26 2019-08-29 David Pauwels Methods for preparing cannabis hurd fiber, purified cannabis hurd fiber, and articles containing the purified cannabis hurd fiber

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SMOOK, HANDBOOK FOR PULP & PAPER TECHNOLOGISTS, 1992, ANGUS WILDE PUBLISHING, SECOND EDITION, CH. 13 (Year: 1992) *

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