US20210245143A1 - Laminar zinc hydroxide organic-inorganic nanocomposites for use in the removal and degradation of dyes from textile effluents or organic substances - Google Patents
Laminar zinc hydroxide organic-inorganic nanocomposites for use in the removal and degradation of dyes from textile effluents or organic substances Download PDFInfo
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- US20210245143A1 US20210245143A1 US17/241,835 US202117241835A US2021245143A1 US 20210245143 A1 US20210245143 A1 US 20210245143A1 US 202117241835 A US202117241835 A US 202117241835A US 2021245143 A1 US2021245143 A1 US 2021245143A1
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- degradation
- zinc
- zinc hydroxide
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- 239000002114 nanocomposite Substances 0.000 title claims abstract description 38
- 239000000975 dye Substances 0.000 title claims abstract description 37
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 title claims abstract description 27
- 229910021511 zinc hydroxide Inorganic materials 0.000 title claims abstract description 24
- 229940007718 zinc hydroxide Drugs 0.000 title claims abstract description 23
- 239000000126 substance Substances 0.000 title claims abstract description 11
- 239000004753 textile Substances 0.000 title claims abstract description 11
- 238000006731 degradation reaction Methods 0.000 title abstract description 23
- 230000015556 catabolic process Effects 0.000 title abstract description 22
- 239000007787 solid Substances 0.000 claims description 18
- 238000002441 X-ray diffraction Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 31
- 229960000907 methylthioninium chloride Drugs 0.000 abstract description 19
- 239000000463 material Substances 0.000 abstract description 14
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 8
- 239000003295 industrial effluent Substances 0.000 abstract description 5
- 230000000593 degrading effect Effects 0.000 abstract description 4
- 239000002351 wastewater Substances 0.000 abstract description 3
- 150000002894 organic compounds Chemical class 0.000 abstract description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- 239000000243 solution Substances 0.000 description 23
- -1 poly(vinylpyrrolidone) Polymers 0.000 description 19
- 239000000725 suspension Substances 0.000 description 19
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 230000008569 process Effects 0.000 description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 15
- 239000007864 aqueous solution Substances 0.000 description 15
- 238000003756 stirring Methods 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 14
- 238000001179 sorption measurement Methods 0.000 description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 230000001699 photocatalysis Effects 0.000 description 10
- 239000011941 photocatalyst Substances 0.000 description 10
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 239000011787 zinc oxide Substances 0.000 description 8
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 229910000368 zinc sulfate Inorganic materials 0.000 description 7
- 235000021355 Stearic acid Nutrition 0.000 description 6
- 239000000356 contaminant Substances 0.000 description 6
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 6
- 229940012189 methyl orange Drugs 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 239000008117 stearic acid Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000005119 centrifugation Methods 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000011686 zinc sulphate Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 4
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000007146 photocatalysis Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000000862 absorption spectrum Methods 0.000 description 3
- 239000001045 blue dye Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 238000000265 homogenisation Methods 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 238000001782 photodegradation Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229960001763 zinc sulfate Drugs 0.000 description 3
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 2
- RNNZTHKVAQBLJZ-UHFFFAOYSA-N 2-heptan-3-yl-4,4,6-trimethyl-1,3-dioxane Chemical compound CCCCC(CC)C1OC(C)CC(C)(C)O1 RNNZTHKVAQBLJZ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 2
- 230000033558 biomineral tissue development Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 239000000598 endocrine disruptor Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052961 molybdenite Inorganic materials 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- 239000011667 zinc carbonate Substances 0.000 description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 description 1
- YPFZTJUHEMPDNF-UHFFFAOYSA-L C(CCCCCCCCCCCCCCCCC)(=O)O.O[Zn]O Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)O.O[Zn]O YPFZTJUHEMPDNF-UHFFFAOYSA-L 0.000 description 1
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
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- 239000003403 water pollutant Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- VNTDZUDTQCZFKN-UHFFFAOYSA-L zinc 2,2-dimethyloctanoate Chemical compound [Zn++].CCCCCCC(C)(C)C([O-])=O.CCCCCCC(C)(C)C([O-])=O VNTDZUDTQCZFKN-UHFFFAOYSA-L 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 description 1
- SRWMQSFFRFWREA-UHFFFAOYSA-M zinc formate Chemical compound [Zn+2].[O-]C=O SRWMQSFFRFWREA-UHFFFAOYSA-M 0.000 description 1
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
- VCQWRGCXUWPSGY-UHFFFAOYSA-L zinc;2,2,2-trifluoroacetate Chemical compound [Zn+2].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F VCQWRGCXUWPSGY-UHFFFAOYSA-L 0.000 description 1
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 description 1
- RXBXBWBHKPGHIB-UHFFFAOYSA-L zinc;diperchlorate Chemical compound [Zn+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O RXBXBWBHKPGHIB-UHFFFAOYSA-L 0.000 description 1
- RXVCGIUUXRUUMT-UHFFFAOYSA-N zinc;ethyl hexanoate Chemical compound [Zn+2].CCCCCC(=O)OCC RXVCGIUUXRUUMT-UHFFFAOYSA-N 0.000 description 1
- NHXVNEDMKGDNPR-UHFFFAOYSA-N zinc;pentane-2,4-dione Chemical compound [Zn+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O NHXVNEDMKGDNPR-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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Abstract
The present invention relates to a method for removing dyes from textile effluents and other organic substances using nanocomposites based on zinc hydroxides and carboxylic acids capable of adsorbing and degrading. More specifically, the present invention consists of a method to generate new zinc hydroxide-based materials, which allows removal and degradation of methylene blue and other organic compounds from wastewater from industrial effluents, particularly those from textile industry.
Description
- This application is a continuation of U.S. application Ser. No. 16/223,779, filed Dec. 18, 2018, which claimed the benefit of priority of U.S. Provisional Patent Application No. 62/609,770, filed on Dec. 22, 2017, each of which are incorporated herein in its entirety for all purposes.
- The present invention relates to a method for removing dyes from textile effluents and other organic substances using nanocomposites based on zinc hydroxides and carboxylic acids capable of adsorbing and degrading. More specifically, the present invention consists of a method to generate new zinc hydroxide-based materials, which allows removal and degradation of methylene blue and other organic compounds from wastewater from industrial effluents, particularly those from textile industry.
- Dye removal from industrial effluents, specifically from textile industry, is particularly important because of its effects on public health and decreasing water resources availability. It is estimated that textile production (2017) amount to 100 billion kilograms per year using 9.8 trillion gallons of water and more than 500,000 tons of dyes and pigments (in a 1:20 dye:water ratio) to this end. Although this is an old problem, nowadays we are still looking for more efficient and environmentally friendly solutions.
- Nowadays, the environmental problems associated with hazardous waste and toxic water pollutants have attracted a lot of attention. Wastewater derived from the manufacture of textiles, paper and other industrial processes contains non-biodegradable residual dyes. Release of toxic and potential carcinogenic substances, such as aqueous phase dyes, creates serious environmental contamination problems. Various chemical and physical processes have been developed such as coagulation/flocculation, activated carbon adsorption, reverse osmosis and ultrafiltration techniques to eliminate color from textile effluents. However, these techniques do not destroy contaminants, since they only transfer non-biodegradable matter to sludge, resulting in a new type of pollution, which requires additional treatment. Therefore, attention must be focused on techniques that lead to the total removal of dye molecules. There are many approximations reported in literature and in patent documents, for example, application WO2004089525 A2 is related to catalysts for photochemical processes which aims the environmental decontamination, being their characteristic a very superior photocatalytical efficiency when compared with the observed for pure titanium oxides. The composites, object of the invention, are a combination of TiO2 with a photosensitiser dye, capable to mediate photocatalytical processes using the incident radiation in wavelength ranges incapable to promote the excitation of the pure photocatalyst.
- Patent application No. US 20130109357 A1 is related to a new magnetic dye-absorbing catalyst, which is the modification of the conventional magnetic photocatalyst. The catalyst consists of a composite particle that has a core-shell structure, with a magnetic particle as a core and a dye adsorbent (which can also exhibit photocatalytic activity) as a shell. Patent application No. US 20150315048 A1 relates to a material consisting of hard fibers on which nanoparticles of metals or metal oxides, preferably period IV transition metal oxides, are deposited using different techniques, said material being used in the degradation and removal of contaminants found in liquid matrices. The invention also relates to a method for in situ synthesis thereof.
- State of the art document “IV Congreso Nacional de Nanotecnología 2016, Propiedades Fotocatalíticas de Nano-compositos laminares de ZnO/MoS2, F. Duran, E. Benavente and G. González discloses preliminary results of the behavior of nanocomposites formed by ZnO (carboxylic acid) and MoS2 (exfoliated) lamellar hybrids as photocatalysts in the degradation of the methylene blue dye under visible light. This document does not interfere with the present patent application.
- In addition, document entitled “Methylene blue dye degradation using C-100 polymeric material modified with ZnO nanoparticles” has been published in the state of the art. In this work, the ZnO nanoparticles were incorporated inside C-100 as a kind of ion exchange material by impregnation with 8% Zn(CH3COO)2 solution (2). The modified material after Zn2+ loading was then treated with a solution of 5% sodium hydroxide to precipitate zinc hydroxide species on the surface of the C-100 exchanger as well as inside the internal pores of the polymeric matrix. After precipitation of zinc hydroxide, the materials were exposed to roasted vapor for an hour on the intermittent periods of time to form a zinc oxide. The synthesized samples with different ZnO loadings were denoted as Zn-HCIX and characterized using X-ray diffraction, energy-dispersive X-ray spectroscopy, scanning electron microscope, and the tunneling electron microscope. The synthesized materials were applied in the photocatalytic degradation of methylene blue dye in aqueous medium using UV irradiation (wavelength=254 nm) under different experimental conditions. The data obtained indicate that the synthesized materials possess a very good adsorption capacity as well as excellent catalytic activity toward the removal of methylene blue.
- However, there are no examples using the materials or procedures described by the present patent application. The most frequent is dye removal from industrial effluents using adsorbent materials from various origins. Photocatalytic mineralization of methylene blue is widely known, this dye is frequently used as a model molecule for organic pollutants. There is a plethora of scientific works in which a variety of different photocatalysts are used, including TiO2 and ZnO. The majority of the reports focus on testing the photocatalytic activity of the materials by kinetic evaluation of the methylene blue discoloration processes and not on the joint effect of adsorption removal and definitive elimination of the contaminant by photocatalysis.
- The present invention uses -innocuous to health, environmentally benign, abundant and low cost- precursors that synergistically generate products having a high dye adsorption capacity and good photocatalytic mineralization using ultraviolet or solar light. The dual property of the nanocomposites, adsorbent/photocatalyst, allows both in situ dye removal from aqueous solutions thereof (adsorption+degradation) and use of ex situ processes wherein contaminant adsorption and photocatalytic destruction thereof is carried out in different facilities and places.
- In other words, the cited prior art does not disclose a method for adsorbing/degrading dyes in industrial effluents and/or nanocomposite compounds based on zinc hydroxide and carboxylic acids such as those described by the present patent application, wherein the proposed technology allows to eliminate methylene blue and other dyes present in industrial aqueous waste, mainly in those from textile industry.
- This technology can be used for adsorbing/degrading other organic molecules of environmental interest which are chemically active such as drugs, pesticides, fertilizers, antibiotics, volatile organic compounds (VOC), endocrine-disrupting chemicals (EDCs) such as bisphenol A and those new organic contaminants that have not been yet identified, all dispersed and/or dissolved in water and effluent.
- The photocatalyst can be reused several times after the absorbed species photodegradation process.
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FIG. 1 : Shows a structure and organization model of zinc hydroxide organic-inorganic nanocomposites. -
FIG. 2 : Shows X-ray diffraction patterns of zinc hydroxide nanocomposites with myristic (LZH-M), palmitic (LZH-P) and stearic (LZH-S) carboxylic acids. The box shows the area at a wider angle. -
FIG. 3 : FTIR spectra of (A) myristic (MA) palmitic (PA) and stearic (SA) carboxylic acids and (B) zinc hydroxide nanocomposites made with 3 long chain carboxylic acids, LZH-M, LZH-P and LZH-S. -
FIG. 4 : Comparison of the FTIR spectra for the zinc hydroxide and stearic acid (LZH-S) nanocomposite and commercial surfactant (AE) and that exposed to the same synthesis conditions of the composites (AE*). -
FIG. 5 : High resolution SEM (A-C) and (D) TEM images obtained for the zinc hydroxide and myristic acid nanocomposite (C14H28O2). -
FIG. 6 : Thermogravimetric curves and their derivatives for zinc hydroxides (A) without addition of surfactants and in nanocomposites with (B) stearic acid, (C) palmitic acid and (D) myristic acid, respectively. -
FIG. 7 : Images of a laminar zinc hydroxide nanocomposite obtained using stearic acid; (A) No dye addition, (B) After the dark stirring process and (C) sample recovered after UV light irradiation for 300 minutes. -
FIG. 8 : Removal of methylene blue from an aqueous solution by contacting with a laminar zinc hydroxide, LZH-S in this case, in the absence of light. -
FIG. 9 : Evolution of methylene blue (MB) absorption spectra versus irradiation time, using LZH-S as photocatalyst. -
FIG. 10 : (A) Cycles of reuse and (B) X-ray diffraction pattern for LZH-S after the photocatalytic process. This remains unchanged. -
FIG. 11 : Removal of Congo Red (CR) from an aqueous solution by contacting with a laminar zinc hydroxide, LZH-S in this case, in the presence of light. - The present invention describes a method of preparing laminar zinc hydroxide organic-inorganic nanocomposites comprising several steps.
- a) Dissolving in a vessel at least one zinc salt, oxide or hydroxide in distilled water until reaching a molar concentration of 0.1 to 5.0 M, wherein the zinc salt is selected from, but not limited to, zinc chloride (ZnCl2), Zinc cyanide (Zn(CN)2), Zinc sulphate (ZnSO4), zinc nitrate (Zn(NO3)2), zinc acetate (Zn(CH3COO)2), zinc carbonate (ZnCO3), zinc acetylacetonate (C5H7ZnO2), zinc perchlorate (Zn(ClO4)2), zinc stearate, salts of zinc-ethylenediamine, zinc trifluoroacetylacetonate(II), zinc hexafluoroacetylacetonate, zinc formate(II), zinc(II) methacrylate, zinc neodecanoate, zinc(II) ethylhexanoate, zinc trifluoroacetate(II), and other zinc sources such as zinc oxide (ZnO), zinc hydroxide (Zn(OH)2).
- b) Dissolving in a vessel at least one carbonate of alkali metals, alkaline earth metals, other metals and metalloids in distilled water until reaching a molar concentration of 0.1 to 5.0 M, wherein the carbonate is selected from, but not limited to, Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, and metals such as Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Al, Ga, In, Pb, Bi, Sn, Ge, As, Sb, Ag, Au, Hg, Cd, Mo, Re, W, Nb, Ru, Rh and Zr.
- c) Forming a suspension by dropwise adding to a volume of the aqueous solution prepared in step (a), a volume of the aqueous carbonate solution prepared in step (b).
- d) The suspension obtained in step c) was heated at 15-120° C. and left under constant stirring ranging from 5 to 10,000 rpm for a homogenization time between 0.1 min and 24 hours.
- e) An alkali solution at a molar concentration of 0.1 to 12.0 M is dropwise added to the reaction mixture of step d), until the mixture is adjusted to a pH between 4 and 12.5; wherein the alkali is selected from sodium hydroxide (NaOH), potassium hydroxide (KOH), lithium hydroxide (LiOH), magnesium hydroxide (Mg(OH)2), barium hydroxide (Ba(OH)2), calcium hydroxide (Ca(OH)2) including Arrhenius bases.
- f) The suspension obtained in step e) is maintained at a temperature of 15-120° C. under constant stirring ranging from 5 to 10,000 rpm for a homogenization time between 0.1 min and 24 hours.
- g) A volume of a molecular or polymeric surfactant solution at a molar concentration of 0.1 to 12.0 M is added, wherein the surfactant is selected from, but not limited to, those with linear, branched or aromatic hydrocarbon chains having 2 or more carbon atoms, having hydrophilic groups such as carboxylic acids and their derivatives, primary and secondary amines, salts of ammonium, amides, thiols, sulfonates, ethers, esters, alcohols, aldehydes, phosphates, and mixtures thereof; in addition the polymeric surfactant is selected from polymers: poly(vinylpyrrolidone) (PVP), polyvinyl alcohol, polycarbonates, polyphenols, polyethylene glycol and polyols such as ethylene glycol, diethylene glycol, triethylene glycol, propylene glycols, alkyldiols as butanediols, dipropylene glycol and polyethylene glycols, chitosan and derivatives thereof, polyacids and derivatives thereof, mercaptoalkanoates, and oxybenzoic acids. Polyacids herein include, but are not limited to, any one or more selected from a group of poly(acrylic acid), poly(maleic acid), poly(methyl methacrylate), poly(acrylic acid-co-methacrylic acid), poly(acrylic acid-co-maleic acid), and poly(acrylamide-co-acrylic acid), cellulose acetates, polyvinyl acetates, polysulfone, polyphenyl sulfones, polyether sulfones, polyketones, polyether ketones, polyesters, polyacetates, polymers and copolymers of two or more of these and the derivatives including, without limitations, any or more of those selected from a group of ammonium, sodium or potassium poly acid salts.
- h) The resulting suspension in step g) is maintained at a temperature of 15-120° C. under constant stirring ranging from 5 to 10,000 rpm for a homogenization time between 0.1 min and 24 hours.
- i) The resulting suspensions in step h) is maintained at a temperature of 15-120° C. for a time between 0.1 min and 72 hours.
- j) The solids obtained in step i) are separated by decantation, filtration, evaporation or centrifugation from 5 to 100,000 rpm for a centrifugation time between 0.1 min and 24 hours, and the precipitate is washed from 1 to 20 times with water and/or a solvent such as, but not limited to, acetone or alcohol, ether, or a mixture thereof.
- k) Drying the products obtained from step (j) in an oven at a temperature of 10° C.-200° C., preferably at 60° C. for 48 hours or under vacuum with a pressure between 0.0001 bar and 10.0 bar, or with IR lamp.
- The method of the present invention produces nanolamellar solids (nanocomposites) with a stacked layer structure which includes inorganic sheets and other hydrophobic parts or zones (see
FIG. 1 ). These nanocomposites have the ability to adsorb/degrade organic substances that can be dissolved and/or dispersed into water with the help of a light energy source. The hydrophobic interlaminar areas are responsible for contaminant adsorption while the zinc hydroxide inorganic nanolamines are responsible for the degradation with the help of light energy. - Removal of dyes or organic substances involves 2 independent processes that run sequentially:
-
- (i) Adsorption of dye or organic substances in the nanocomposite, in an aqueous medium.
- (ii) Degradation of dye or organic substances adsorbed by heterogeneous photocatalysis.
- Degradation or removal of the dye or organic substances occurs with step (ii) by light excitation, whereby the product can be reused. In other words, the nanocomposite can be recovered and reused several times.
- The light energy source can be natural, such as the sun, or artificial with a power between 0.1 to 200 W such as, but not limited to, lamps LEDs, OLEDs, xenon-mercury, xenon, mercury halides, noble gases, or mixture thereof. This will excite the material generating the degradation of the adsorbed dye and the dye remaining in the solution. This process is attributed to the production of highly active radical species on the surface of the solids (photocatalyst) used.
- The original laminar zinc hydroxide organic-inorganic nanocomposite is white; the dye adsorption is then easily detectable by the color change solid in the solid after the adsorption process while the solid recovered after the photocatalytic degradation in the presence of light is white (see sequence in
FIG. 7 ). Image 7B shows the presence of dye in the solid by a color change, color which disappears completely after irradiation. - Given the independence of i) absorption and ii) degradation processes, these can occur in situ or in different places, which opens the possibility of first extracting the pollutants in the effluents and removing them through photocatalysis in different sites.
- Photocatalyst can be reused several times after the absorbed species photodegradation process.
- To 10.0 mL of an aqueous solution of 1.0 M zinc sulfate (ZnSO4) was dropwise added 5.0 mL of a 1.0 M sodium carbonate (Na2CO3) aqueous solution. A white suspension was immediately formed after addition. This was left under constant stirring at 600 rpm for 10 minutes at 55° C. Then, 10.0 mL of a 1.0 M sodium hydroxide (NaOH) aqueous solution was dropwise added until obtaining a suspension with pH equal to 9. The latter was left under constant stirring at 600 rpm for 10 minutes at the same temperature. In the final step, 5.0 mL of a previously prepared 0.4 M myristic acid solution was added using a 1:1 v/v water: acetone mixture as solvent, in a water bath. The resulting suspensions were left under constant stirring at 600 rpm for 48 h at 55° C. After that, suspensions were left standing for 24 h at room temperature. The obtained solids were separated by centrifugation at 6,000 rpm and washed 3 times with a 1:1 water: acetone solution. Finally, the products were dried in an oven at 60° C. for 48 h and grinded in an agate mortar. This process produced lamellar solids with a stacked layer structure (
FIG. 1 ). - Nanocomposites obtained have a novel structure of stacked sheets formed by inorganic layers of zinc hydroxides intercalated with carboxylate anions, as illustrated in the scheme of
FIG. 1 . Product lamellar structure was determined by X-ray diffraction (FIG. 2 ). Product interlaminal distances are shown in Table 1. The presence of intercalated carboxylate anions was confirmed by FT-IR spectroscopy (FIGS. 3 and 4 ). Product lamellar morphology can be clearly seen in the scanning and transmission electron microscopy micrographs (FIG. 5 ). - Nature and composition of the solids was investigated by thermal analysis (
FIG. 6 ). This product allows the adsorption of the dye in the solid, favored by the presence of the organic component, as well as the degradation thereof by ultraviolet or solar light excitation (photocatalysis) of the inorganic phase. Thus, these products have an adsorbent and photocatalyst dual capacity. - The methodology used for dye degradation is described below. 90 mg of nanocomposite is dispersed in 1.0 mL of ethanol. This suspension is added to 50 mL of methylene blue aqueous solution with a 0.00001 M concentration and is left under stirring at 600 rpm for 30 minutes. This time is sufficient to obtain a maximum dye adsorption on the solid surface. The absorption removal rate of the dye from the aqueous sample with addition of a laminar zinc hydroxide composite prepared with stearic acid (LZH-S) in the dark, is approximately 50% (
FIG. 8 ). The aforementioned graph shows that dye removal from the solution occurs within the first 30 minutes and then remain constant over time. - Degradation kinetics of Methylene Blue (MB) in solution under light irradiation in the presence of catalyst was monitored by observing Methylene Blue absorption spectrum, and its solution concentration was determined by absorption intensity at 665 nm (
FIG. 9 ). It is observed that the dye in solution is completely degraded at 5-6 hours. - Catalyst can be reused several times after the absorbed species photodegradation process. To that end, three experiments were made using the same nanocomposite sample. The capacity of the catalyst after 3 cycles was reduced by 2% compared to the original (
FIG. 10 ). - To 10.0 mL of 1.0 M zinc sulfate (ZnSO4) aqueous solution was dropwise added 5.0 mL of a 1.0 M sodium carbonate (Na2CO3) aqueous solution. A white precipitate immediately formed after addition. The resulting suspension was left under constant stirring at 600 rpm for 10 minutes at 55° C. Then, 10.0 mL of a 1.0 M sodium hydroxide (NaOH) aqueous solution was dropwise added until obtaining a suspension with pH equal to 9. The latter was left under constant stirring at 600 rpm for 10 minutes at the same temperature. In the final step, 5.0 mL of a previously prepared 0.4 M stearic acid solution was added using a 1:1 v/v water: acetone mixture as solvent, in a water bath. The resulting suspensions were left under constant stirring at 600 rpm for 48 h at 55° C. After that, the suspensions were left standing for 24 h at room temperature. The obtained solids were separated by centrifugation at 6,000 rpm and washed 3 times with a 1:1 water: acetone solution. Finally, the products were dried in an oven at 60° C. for 48 h and grinded in an agate mortar. This process produced lamellar solids with a stacked layer structure (
FIG. 1 ). - For methyl orange degradation, 90 mg of nanocomposite is dispersed in 1.0 mL of ethanol. This suspension is added to 50 mL of methyl orange aqueous solution at a 0.00001 M concentration and it is left under stirring at 600 rpm for 360 minutes. This time is sufficient to obtain a maximum dye adsorption on the solid surface. The absorption removal rate of the dye from the aqueous sample with addition of a laminar zinc hydroxide composite prepared with stearic acid (LZH-S) in the dark, is approximately 50%. Dye removal from solution occurs within the first 30 minutes, to then remain constant over time.
- Degradation kinetics of Methyl Orange (MO) in solution under light irradiation in the presence of catalyst was monitored by observing Methyl Orange absorption spectrum and its solution concentration was determined by absorption intensity at 665 nm. It is observed that the dye in solution is completely degraded.
- To 10.0 mL of an aqueous solution of 1.0 M zinc sulfate (ZnSO4) was dropwise added 5.0 mL of a 1.0 M sodium carbonate (Na2CO3) aqueous solution. A white precipitate immediately formed after addition. The resulting suspension was left under constant stirring at 600 rpm for 10 minutes at 55° C. Then, 10.0 mL of a 1.0 M sodium hydroxide (NaOH) aqueous solution was dropwise added until obtaining a suspension with pH equal to 9. The latter was left under constant stirring at 600 rpm for 10 minutes at the same temperature. In the final step, 5.0 mL of the previously prepared 0.4 M palmitic acid solution was added using a 1:1 v/v water: acetone mixture as solvent, in a water bath. The resulting suspensions were left under constant stirring at 600 rpm for 48 h at 55° C. After that, the suspensions were left standing for 24 h at room temperature. The obtained solids were separated by centrifugation at 6,000 rpm and washed 3 times with a 1:1 water: acetone solution. Finally, the products were dried in an oven at 60° C. for 48 h and grinded in an agate mortar. This process produced lamellar solids with a stacked layer structure (
FIG. 1 ). - 90 mg of zinc hydroxide-palmitic acid nanocomposite and a 1×10−5 mol/L methylene blue solution were used. UV-Vis irradiation (immersion lamp) was used. Nanocomposites absorbed in the dark more than 50% and the total degradation was achieved after 300 min of irradiation (
FIG. 11 ). - Three nanocomposites of zinc hydroxide with carboxylic acids (myristic, palmitic and stearic) were prepared using this technology. Distances were found to be directly dependent on the surfactant being used as shown by the difference in interlaminal distances. Table 1 shows the results of the X-ray diffraction analysis of the 3 nanocomposites used in examples 1, 2 and 3 (
FIG. 2 ). -
TABLE 1 Molecular Total length surfactant d001 R—COO— Composite formula (nm) (nm) LZH-S C18H36O2 4.294 2.360 LZH-P C16H32O2 4.264 2.110 LZH-M C14H28O2 3.409 1.860 - 90 mg of zinc hydroxide—myristic acid nanocomposite and a 3×10−5 mol/L Congo Red solution were used. UV-Vis irradiation (immersion lamp) was used. Nanocomposites absorbed in the dark more than 60% and the total degradation was achieved after 300 min of irradiation (
FIG. 11 ). The experimental procedure was carried out following the methodology of examples 1 and 2, but using Congo Red as a test molecule.
Claims (2)
1. Nanocomposites of hybrid organic-inorganic zinc hydroxide, wherein said nanocomposites are laminar solids with stacked structure of hybrid layers, wherein each layer comprises two individual inorganic sheets of zinc hydroxide having a X-ray diffraction pattern in 2 theta, wherein the number of harmonics in the reflections are between 001 up to 10 (0010).
2. The nanocomposites of claim 1 , wherein said nanocomposites are used for the removal of dyes from textile effluents or other organic substances.
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