US20210207885A1 - Air separation system - Google Patents
Air separation system Download PDFInfo
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- US20210207885A1 US20210207885A1 US17/142,217 US202117142217A US2021207885A1 US 20210207885 A1 US20210207885 A1 US 20210207885A1 US 202117142217 A US202117142217 A US 202117142217A US 2021207885 A1 US2021207885 A1 US 2021207885A1
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- oxygen
- pressure column
- argon
- flow rate
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04254—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using the cold stored in external cryogenic fluids
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
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- F25J3/04624—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using integrated mass and heat exchange, so-called non-adiabatic rectification, e.g. dephlegmator, reflux exchanger
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- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04654—Producing crude argon in a crude argon column
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- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04654—Producing crude argon in a crude argon column
- F25J3/04666—Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system
- F25J3/04672—Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser
- F25J3/04678—Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser cooled by oxygen enriched liquid from high pressure column bottoms
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04654—Producing crude argon in a crude argon column
- F25J3/04666—Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system
- F25J3/04672—Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser
- F25J3/04703—Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser being arranged in more than one vessel
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
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- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04721—Producing pure argon, e.g. recovered from a crude argon column
- F25J3/04727—Producing pure argon, e.g. recovered from a crude argon column using an auxiliary pure argon column for nitrogen rejection
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04793—Rectification, e.g. columns; Reboiler-condenser
- F25J3/048—Argon recovery
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J3/04763—Start-up or control of the process; Details of the apparatus used
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- F25J2210/40—Air or oxygen enriched air, i.e. generally less than 30mol% of O2
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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Definitions
- the present invention relates to an air separation system for improving the extraction rate of product argon.
- an oxygen-enriched gas-liquid substance containing argon extracted from an air separating device, is sent to an argon distillation column from which high-purity product argon is withdrawn.
- French Patent Publication No. 2964451 discloses an air separating device for the production of products such as oxygen, nitrogen and argon.
- the air separation device comprises a plurality of distillation columns for efficiently producing these products, such as a high pressure distillation column, a low pressure distillation column, and a crude argon distillation column.
- the extraction rate of product argon is controlled by controlling the concentration of oxygen in oxygen-enriched liquid that accumulates in an intermediate stage of the lower-pressure column of the air separating device, to a predetermined concentration.
- the objective of the present invention is to provide an air separation system with which the extraction rate of high-purity product argon that can be withdrawn from the argon distillation column can be improved, even if production quantities such as the quantity of withdrawn product oxygen or the quantity of withdrawn product nitrogen change.
- the inventors of the present invention found that nitrogen (gaseous, liquid, or a mixture thereof) contaminates an argon extraction portion (intermediate stage of distillation portion of lower-pressure column of air separating device) for extracting an oxygen-enriched gas-liquid mixture containing argon, as a result of changes in the state of the lower-pressure column of the air separating device concomitant with changes in production quantities such as the quantity of withdrawn product oxygen or the quantity of withdrawn product nitrogen from the air separating device.
- Nitrogen contamination causes the extraction rate of high-purity product argon that can be withdrawn from the final stage argon distillation column to fluctuate greatly and to decrease. Accordingly, the inventors of the present invention created a novel configuration in order to resolve the abovementioned problem.
- the air separation system of certain embodiments of the present invention is provided with: a main heat exchanger ( 1 ); a higher-pressure column ( 2 ) into which feed air that has passed through the main heat exchanger ( 1 ) is introduced; a first condensing unit ( 3 ) for condensing gas discharged from a column top portion ( 23 ) of the higher-pressure column ( 2 ); a lower-pressure column ( 4 ) into which oxygen-enriched liquid discharged from a column bottom portion ( 21 ) of the higher-pressure column ( 2 ) is introduced; crude argon columns ( 5 , 6 ) into which an argon-containing oxygen-enriched gas-liquid substance discharged from an argon extraction portion, which is an intermediate stage of a distillation portion of the lower-pressure column ( 4 ), is introduced; and a pure argon distillation column ( 8 ) into which an argon-enriched gas-liquid substance discharged from a distillation portion (intermediate stage or upper portion) or a column top portion of the pure argon distill
- the crude argon columns may be separate or may be configured from a single column.
- the air separation system can include: a process control unit ( 201 ) for controlling components (such as the temperatures of heat exchangers, opening and closing of valves, flow regulating valves, pressure regulating valves, compressors, expansion turbine) constituting the air separation system; an oxygen concentration estimating unit ( 202 ) for estimating, by calculation, the oxygen concentration (EC_ 0 2 ) of the oxygen-enriched liquid that accumulates in the column bottom portion ( 21 ) of the higher-pressure column ( 2 ); a flow rate estimating unit ( 203 ) for estimating, by calculation, the flow rate (EF_ 0 2 ) of the oxygen-enriched liquid that has been discharged from the column bottom portion ( 21 ) of the higher-pressure column ( 2 ) and that is to be introduced into the distillation portion of the lower-pressure column ( 3 ); a target temperature calculating unit ( 204 ) for calculating a target temperature (T) of the argon extraction portion on the basis of the flow rate (F_FA) of the feed air that has passed through at
- the target temperature calculating unit ( 204 ) may calculate the target temperature (T) using a statistical method such as multivariate analysis or regression analysis.
- the process control unit may control the replenishment amount flow rate (flowmeter F 101 and valve 13 ) of liquid nitrogen, and/or the flow rate (flowmeter F 102 and valve V 12 ) of reflux liquid discharged from the column top portion ( 23 ) of the higher-pressure column ( 2 ), such that the measured temperature (T-Ar) of the argon extraction portion reaches a target temperature (Tt).
- the oxygen concentration estimating unit ( 202 ) can estimate the oxygen concentration (EC_ 0 2 ) of the oxygen-enriched liquid by calculating the material balance in the higher-pressure column ( 2 ).
- the flow rate estimating unit ( 203 ) can estimate the flow rate (EF_ 0 2 ) of the oxygen-enriched liquid by calculating the degree of opening of a valve which supplies the oxygen-enriched liquid to the lower-pressure column ( 3 ), and the pressure difference before and after the valve.
- Nitrogen contamination of the argon extraction portion can be prevented, and the argon extraction rate improved, by detecting a decrease in the temperature of the argon extraction portion resulting from a fluctuation in the operating pressure in the lower-pressure column, or a decrease in the temperature of the argon extraction portion due to other causes.
- FIG. 1 is a drawing illustrating a first embodiment of an air separation system.
- FIG. 2 is a drawing illustrating an example of the control elements of the air separation system in FIG. 1 .
- the air separation system is provided with: the main heat exchanger 1 ; the higher-pressure column 2 into which feed air that has passed through the main heat exchanger 1 is introduced via a pipeline L 1 ; the first condensing unit (nitrogen condenser) 3 for condensing higher-pressure column distillate discharged through a pipeline L 231 from the column top portion 23 of the higher-pressure column 2 ; and the lower-pressure column 4 into which oxygen-enriched liquid discharged from the column bottom portion 21 of the higher-pressure column 2 is introduced.
- Feed air introduced into the main heat exchanger 1 branches off midway through the main heat exchanger 1 and is sent to the expansion turbine 10 via a branched pipeline L 11 , and is discharged from the expansion turbine 10 and sent to an intermediate stage 423 of a distillation portion 42 of the lower-pressure column 4 .
- the flow rate (F_FA) of the feed air sent to the expansion turbine 10 is measured using a flowmeter (F 103 ). Measured data are sent to a control device 200 and are stored as time-series data in the memory 208 .
- a liquid surface level gauge (L 101 ) for measuring the liquid surface height of oxygen-enriched liquid is provided in the column bottom portion 21 of the higher-pressure column 2 . Measured data are sent to a control device 200 and are stored as time-series data in the memory 208 .
- the oxygen-enriched liquid discharged from the column bottom portion 21 is subjected to heat exchange in a heat exchanger E 5 , and is then introduced via a pipeline L 2 into a distillation stage that is the same as, or vertically close to, the intermediate stage 423 of the distillation portion 42 of the lower-pressure column 4 into which the feed air discharged from the expansion turbine 10 is introduced.
- a control valve V 11 is provided in the pipeline L 2 , and the control valve V 11 is controlled by the control device 1 in accordance with the measured data from the liquid surface level gauge (L 101 ), thereby regulating the amount of oxygen-enriched liquid that is introduced.
- a flowmeter (F 104 ) for measuring the flow rate (F_ 0 2 ) of the oxygen-enriched liquid that has been discharged from the column bottom portion 21 of the higher-pressure column 2 and that is to be introduced into the distillation portion 42 of the lower-pressure column 4 is provided in the pipeline L 2 . Measured data are sent to a control device 200 and are stored as time-series data in the memory 208 .
- a pressure gauge (P 101 ) is provided in the column top portion 23 of the higher-pressure column 2 to measure the pressure in the column top portion 23 . Measured data are sent to a control device 200 and are stored as time-series data in the memory 208 .
- thermometer (T 101 ) for measuring the distillation atmosphere temperature is provided in the position of the intermediate stage 422 of the distillation portion 42 of the lower-pressure column 4 (below the intermediate stage 423 and above the argon extraction portion 421 ).
- An argon-containing oxygen-enriched gas-liquid substance is introduced via a pipeline L 42 from the argon extraction portion 421 , which is the distillation stage below the intermediate stage 422 , into a column bottom portion 51 of a first crude argon column 5 , or below an intermediate stage of a distillation portion 52 thereof.
- a lower-pressure column distilled gas-liquid substance discharged through a pipeline L 3 from an upper portion of the distillation portion 42 of the lower-pressure column 4 or from a column top portion 44 thereof is subjected to heat exchange in the heat exchanger E 5 , and is then sent to the main heat exchanger 1 .
- a pressure gauge (P 102 ) is provided in the pipeline L 3 to measure the pressure of the lower-pressure column distilled gas-liquid substance. Measured data are sent to a control device 200 and are stored as time-series data in the memory 208 .
- the pipeline L 3 merges with the pipeline L 33 ahead of the heat exchanger E 5 , and vaporised gas-liquid substance discharged from an upper portion of the first condenser 3 merges and is sent together to the heat exchanger E 5 .
- a lower-pressure column top portion distillate discharged through a pipeline L 5 from the column top portion 44 of the lower-pressure column 4 is subjected to heat exchange in the heat exchanger E 5 , and is then sent to the main heat exchanger 1 .
- a higher-pressure column distillate (reflux liquid) discharged through a pipeline L 23 from the column top portion 23 of the higher-pressure column 2 is subjected to heat exchange in the heat exchanger E 5 , and is then sent to the column top portion 44 of the lower-pressure column 4 .
- a flowmeter (F 102 ) for measuring the flow rate of the higher-pressure column distillate, and a control valve V 12 are provided in the pipeline L 23 . Measured data are sent to a control device 200 and are stored as time-series data in the memory 208 .
- the control valve V 12 is controlled by the control device 200 in accordance with the measured data from the flowmeter (F 102 ), thereby regulating the amount of higher-pressure column distillate (reflux liquid) that is introduced.
- Supplementary liquid nitrogen (LIN) is sent to the column top portion 44 of the lower-pressure column 4 via a pipeline L 43 .
- a flowmeter (F 101 ) for measuring the flow rate of the liquid nitrogen, and a control valve V 13 are provided in the pipeline L 43 .
- Measured data are sent to a control device 200 and are stored as time-series data in the memory 208 .
- the control valve V 13 is controlled by the control device 200 in accordance with the measured data from the flowmeter (F 103 ), thereby regulating the amount of liquid nitrogen that is introduced.
- the air separation system is provided with: the first crude argon column 5 in which the argon-containing oxygen-enriched gas-liquid substance discharged from the argon extraction portion 421 of the lower-pressure column 4 is introduced via the pipeline L 42 into the column bottom portion 51 , or below the intermediate stage of the distillation portion 52 ; and a second crude argon column 6 in which an argon-enriched gas-liquid substance discharged via a pipeline L 53 from a column bottom portion 53 of the first crude argon column 5 is introduced into a column bottom portion 61 , or below an intermediate stage of a distillation portion 62 .
- the air separation system is provided with: a third condenser 7 for condensing second crude argon distillate discharged from a column top portion 63 of the second crude argon column 6 ; and a pure argon distillation column 8 in which a high-argon-enriched gas-liquid substance discharged through a pipeline L 63 from the column top portion 63 of the second crude argon column 6 is introduced into an intermediate stage of a distillation portion 82 .
- the argon content concentrations have the following relationship.
- a fourth condenser 83 is provided above the distillation portion 82 of the pure argon column 8 to condense high-purity argon liquid discharged from a column bottom portion 81 .
- the high-purity argon liquid discharged from the column bottom portion 81 of the pure argon column 8 is subjected to heat exchange in a heat exchanger E 6 (or reboiler) and is returned to the column bottom portion 81 .
- the high-purity argon liquid discharged from the column bottom portion 81 of the pure argon column 8 is withdrawn as product argon and is sent to a product tank.
- Valves (such as gate valves, flow-regulating valves, and pressure regulating valves) may be provided in the pipelines and in the lines shown in FIG. 1 .
- compressors pressure regulating devices, flow rate control devices or the like may be provided as necessary in each pipeline to perform pressure regulation or flow rate regulation.
- the control device 200 in FIG. 2 will next be described.
- the control device 200 includes a process control unit 201 , an oxygen concentration estimating unit 202 , a flow rate estimating unit 203 , a target temperature calculating unit 204 , and a memory 208 for storing various types of data (such as setting data, process data, and the measured data discussed hereinabove).
- the process control unit 201 controls components constituting the air separation system (such as the temperatures of the heat exchangers, opening and closing of the valves, the flow regulating valves, the pressure regulating valves, the compressors, and the expansion turbine).
- the oxygen concentration estimating unit 202 estimates the oxygen concentration (EC_ 0 2 ) of the oxygen-enriched liquid that accumulates in the column bottom portion 21 of the higher-pressure column 2 .
- the flow rate estimating unit 203 estimates, by calculation, the flow rate (EF_ 0 2 ) of the oxygen-enriched liquid that has been discharged from the column bottom portion 21 of the higher-pressure column 2 and that is to be introduced into the distillation portion 42 of the lower-pressure column 4 .
- the target temperature calculating unit 204 calculates the target temperature (Tt) of the argon extraction portion 421 on the basis of flow rate (F_FA) of the feed air that has passed through at least a portion of the main heat exchanger 1 and that is to be sent to the expansion turbine 10 , the oxygen concentration (EC- 0 2 ) of the oxygen-enriched liquid, and the flow rate (EF_ 0 2 ) of the oxygen-enriched liquid.
- the target temperature calculating unit 204 calculates the target temperature (Tt) using a statistical method such as multivariate analysis or regression analysis.
- the process control unit 201 controls the replenishment amount flow rate (flowmeter F 101 and valve V 13 ) of liquid nitrogen, and/or the flow rate (flowmeter F 102 and valve V 12 ) of the higher-pressure column distillate (reflux liquid) discharged from the column 23 of the higher-pressure column 2 , such that the measured temperature (T 101 ) of the argon extraction portion 421 reaches the target temperature (Tt).
- Comparative example Process control to keep the concentration of the oxygen-enriched liquid constant was performed as in a conventional case.
- Control was performed such that the temperature of the argon extraction portion reached the target temperature.
- “Comprising” in a claim is an open transitional term which means the subsequently identified claim elements are a nonexclusive listing (i.e., anything else may be additionally included and remain within the scope of “comprising”). “Comprising” as used herein may be replaced by the more limited transitional terms “consisting essentially of” and “consisting of” unless otherwise indicated herein.
- Providing in a claim is defined to mean furnishing, supplying, making available, or preparing something. The step may be performed by any actor in the absence of express language in the claim to the contrary.
- Optional or optionally means that the subsequently described event or circumstances may or may not occur.
- the description includes instances where the event or circumstance occurs and instances where it does not occur.
- Ranges may be expressed herein as from about one particular value, and/or to about another particular value. When such a range is expressed, it is to be understood that another embodiment is from the one particular value and/or to the other particular value, along with all combinations within said range.
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Abstract
The air separation system can include: a process control unit 201 for controlling components constituting the air separation system; an oxygen concentration estimating unit 202 for estimating, by calculation, the oxygen concentration of oxygen-enriched liquid that accumulates in a column bottom portion of the higher-pressure column; a flow rate estimating unit for estimating, by calculation, the flow rate of oxygen-enriched liquid that has been discharged from the column bottom portion of the higher-pressure column and that is to be introduced into a distillation portion of the lower-pressure column; and a target temperature calculating unit for calculating a target temperature of an argon extraction portion on the basis of the flow rate of feed air that has passed through at least a portion of the main heat exchanger 1 and that is to be sent to an expansion turbine, the oxygen concentration of the oxygen-enriched liquid, and the flow rate of the oxygen-enriched liquid.
Description
- This application claims the benefit of priority under 35 U.S.C. § 119 (a) and (b) to Japanese patent application No. JP2020-000482, filed Jan. 6, 2020, the entire contents of which are incorporated herein by reference.
- The present invention relates to an air separation system for improving the extraction rate of product argon.
- Conventionally, an oxygen-enriched gas-liquid substance containing argon, extracted from an air separating device, is sent to an argon distillation column from which high-purity product argon is withdrawn.
- For example, French Patent Publication No. 2964451 discloses an air separating device for the production of products such as oxygen, nitrogen and argon. The air separation device comprises a plurality of distillation columns for efficiently producing these products, such as a high pressure distillation column, a low pressure distillation column, and a crude argon distillation column.
- Conventionally, the extraction rate of product argon is controlled by controlling the concentration of oxygen in oxygen-enriched liquid that accumulates in an intermediate stage of the lower-pressure column of the air separating device, to a predetermined concentration.
- However, since the state of the lower-pressure column of the air separating device varies in accordance with changes in production quantities, such as the quantity of withdrawn product oxygen or the quantity of withdrawn product nitrogen from the air separating device, the extraction rate of high-purity product argon that can be withdrawn from the final stage argon distillation column varies greatly.
- In view of the circumstances described hereinabove, the objective of the present invention is to provide an air separation system with which the extraction rate of high-purity product argon that can be withdrawn from the argon distillation column can be improved, even if production quantities such as the quantity of withdrawn product oxygen or the quantity of withdrawn product nitrogen change.
- The inventors of the present invention found that nitrogen (gaseous, liquid, or a mixture thereof) contaminates an argon extraction portion (intermediate stage of distillation portion of lower-pressure column of air separating device) for extracting an oxygen-enriched gas-liquid mixture containing argon, as a result of changes in the state of the lower-pressure column of the air separating device concomitant with changes in production quantities such as the quantity of withdrawn product oxygen or the quantity of withdrawn product nitrogen from the air separating device. Nitrogen contamination causes the extraction rate of high-purity product argon that can be withdrawn from the final stage argon distillation column to fluctuate greatly and to decrease. Accordingly, the inventors of the present invention created a novel configuration in order to resolve the abovementioned problem.
- The air separation system of certain embodiments of the present invention is provided with: a main heat exchanger (1); a higher-pressure column (2) into which feed air that has passed through the main heat exchanger (1) is introduced; a first condensing unit (3) for condensing gas discharged from a column top portion (23) of the higher-pressure column (2); a lower-pressure column (4) into which oxygen-enriched liquid discharged from a column bottom portion (21) of the higher-pressure column (2) is introduced; crude argon columns (5, 6) into which an argon-containing oxygen-enriched gas-liquid substance discharged from an argon extraction portion, which is an intermediate stage of a distillation portion of the lower-pressure column (4), is introduced; and a pure argon distillation column (8) into which an argon-enriched gas-liquid substance discharged from a distillation portion (intermediate stage or upper portion) or a column top portion of the pure argon distillation columns (5, 6) is introduced.
- The crude argon columns may be separate or may be configured from a single column.
- In another embodiment, the air separation system can include: a process control unit (201) for controlling components (such as the temperatures of heat exchangers, opening and closing of valves, flow regulating valves, pressure regulating valves, compressors, expansion turbine) constituting the air separation system; an oxygen concentration estimating unit (202) for estimating, by calculation, the oxygen concentration (EC_0 2) of the oxygen-enriched liquid that accumulates in the column bottom portion (21) of the higher-pressure column (2); a flow rate estimating unit (203) for estimating, by calculation, the flow rate (EF_0 2) of the oxygen-enriched liquid that has been discharged from the column bottom portion (21) of the higher-pressure column (2) and that is to be introduced into the distillation portion of the lower-pressure column (3); a target temperature calculating unit (204) for calculating a target temperature (T) of the argon extraction portion on the basis of the flow rate (F_FA) of the feed air that has passed through at least a portion of the main heat exchanger (1) and that is to be sent to an expansion turbine (10), the oxygen concentration (EC-0 2) of the oxygen-enriched liquid, and the flow rate (EF_0 2) of the oxygen-enriched liquid; and a memory (208) for storing various types of data.
- The target temperature calculating unit (204) may calculate the target temperature (T) using a statistical method such as multivariate analysis or regression analysis.
- The process control unit may control the replenishment amount flow rate (flowmeter F101 and valve 13) of liquid nitrogen, and/or the flow rate (flowmeter F102 and valve V12) of reflux liquid discharged from the column top portion (23) of the higher-pressure column (2), such that the measured temperature (T-Ar) of the argon extraction portion reaches a target temperature (Tt).
- The oxygen concentration estimating unit (202) can estimate the oxygen concentration (EC_0 2) of the oxygen-enriched liquid by calculating the material balance in the higher-pressure column (2).
- The flow rate estimating unit (203) can estimate the flow rate (EF_0 2) of the oxygen-enriched liquid by calculating the degree of opening of a valve which supplies the oxygen-enriched liquid to the lower-pressure column (3), and the pressure difference before and after the valve.
- Nitrogen contamination of the argon extraction portion can be prevented, and the argon extraction rate improved, by detecting a decrease in the temperature of the argon extraction portion resulting from a fluctuation in the operating pressure in the lower-pressure column, or a decrease in the temperature of the argon extraction portion due to other causes.
- Further developments, advantages and possible applications of the invention can also be taken from the following description of the drawing and the exemplary embodiments. All features described and/or illustrated form the subject-matter of the invention per se or in any combination, independent of their inclusion in the claims or their back-references.
- [
FIG. 1 ] is a drawing illustrating a first embodiment of an air separation system. - [
FIG. 2 ] is a drawing illustrating an example of the control elements of the air separation system inFIG. 1 . - Several modes of embodiment of the present invention will be described below. The modes of embodiment described below are exemplary descriptions of the present invention. The present invention is in no way limited by the following modes of embodiment, and also includes a number of variant modes which are implemented within a scope that does not alter the essential point of the present invention. It should be noted that the constituent elements described below are not all limited to being essential constituent elements of the present invention.
- The air separation system in
embodiment 1 will be described with reference toFIG. 1 . - The air separation system is provided with: the
main heat exchanger 1; the higher-pressure column 2 into which feed air that has passed through themain heat exchanger 1 is introduced via a pipeline L1; the first condensing unit (nitrogen condenser) 3 for condensing higher-pressure column distillate discharged through a pipeline L231 from the column top portion 23 of the higher-pressure column 2; and the lower-pressure column 4 into which oxygen-enriched liquid discharged from thecolumn bottom portion 21 of the higher-pressure column 2 is introduced. - Feed air introduced into the
main heat exchanger 1 branches off midway through themain heat exchanger 1 and is sent to theexpansion turbine 10 via a branched pipeline L11, and is discharged from theexpansion turbine 10 and sent to anintermediate stage 423 of adistillation portion 42 of the lower-pressure column 4. - The flow rate (F_FA) of the feed air sent to the
expansion turbine 10 is measured using a flowmeter (F103). Measured data are sent to acontrol device 200 and are stored as time-series data in thememory 208. - A liquid surface level gauge (L101) for measuring the liquid surface height of oxygen-enriched liquid is provided in the
column bottom portion 21 of the higher-pressure column 2. Measured data are sent to acontrol device 200 and are stored as time-series data in thememory 208. - The oxygen-enriched liquid discharged from the
column bottom portion 21 is subjected to heat exchange in a heat exchanger E5, and is then introduced via a pipeline L2 into a distillation stage that is the same as, or vertically close to, theintermediate stage 423 of thedistillation portion 42 of the lower-pressure column 4 into which the feed air discharged from theexpansion turbine 10 is introduced. A control valve V11 is provided in the pipeline L2, and the control valve V11 is controlled by thecontrol device 1 in accordance with the measured data from the liquid surface level gauge (L101), thereby regulating the amount of oxygen-enriched liquid that is introduced. - A flowmeter (F104) for measuring the flow rate (F_0 2) of the oxygen-enriched liquid that has been discharged from the
column bottom portion 21 of the higher-pressure column 2 and that is to be introduced into thedistillation portion 42 of the lower-pressure column 4 is provided in the pipeline L2. Measured data are sent to acontrol device 200 and are stored as time-series data in thememory 208. - A pressure gauge (P101) is provided in the column top portion 23 of the higher-pressure column 2 to measure the pressure in the column top portion 23. Measured data are sent to a
control device 200 and are stored as time-series data in thememory 208. - Higher-pressure column distillate (reflux liquid) discharged through a pipeline L25 from the column top portion 23 of the higher-pressure column 2 is sent to the
main heat exchanger 1. - A thermometer (T101) for measuring the distillation atmosphere temperature is provided in the position of the
intermediate stage 422 of thedistillation portion 42 of the lower-pressure column 4 (below theintermediate stage 423 and above the argon extraction portion 421). An argon-containing oxygen-enriched gas-liquid substance is introduced via a pipeline L42 from the argon extraction portion 421, which is the distillation stage below theintermediate stage 422, into acolumn bottom portion 51 of a firstcrude argon column 5, or below an intermediate stage of a distillation portion 52 thereof. - A lower-pressure column distilled gas-liquid substance discharged through a pipeline L3 from an upper portion of the
distillation portion 42 of the lower-pressure column 4 or from acolumn top portion 44 thereof is subjected to heat exchange in the heat exchanger E5, and is then sent to themain heat exchanger 1. A pressure gauge (P102) is provided in the pipeline L3 to measure the pressure of the lower-pressure column distilled gas-liquid substance. Measured data are sent to acontrol device 200 and are stored as time-series data in thememory 208. - The pipeline L3 merges with the pipeline L33 ahead of the heat exchanger E5, and vaporised gas-liquid substance discharged from an upper portion of the first condenser 3 merges and is sent together to the heat exchanger E5.
- A lower-pressure column top portion distillate discharged through a pipeline L5 from the
column top portion 44 of the lower-pressure column 4 is subjected to heat exchange in the heat exchanger E5, and is then sent to themain heat exchanger 1. - A higher-pressure column distillate (reflux liquid) discharged through a pipeline L23 from the column top portion 23 of the higher-pressure column 2 is subjected to heat exchange in the heat exchanger E5, and is then sent to the
column top portion 44 of the lower-pressure column 4. A flowmeter (F102) for measuring the flow rate of the higher-pressure column distillate, and a control valve V12, are provided in the pipeline L23. Measured data are sent to acontrol device 200 and are stored as time-series data in thememory 208. The control valve V12 is controlled by thecontrol device 200 in accordance with the measured data from the flowmeter (F102), thereby regulating the amount of higher-pressure column distillate (reflux liquid) that is introduced. - Supplementary liquid nitrogen (LIN) is sent to the
column top portion 44 of the lower-pressure column 4 via a pipeline L43. A flowmeter (F101) for measuring the flow rate of the liquid nitrogen, and a control valve V13, are provided in the pipeline L43. Measured data are sent to acontrol device 200 and are stored as time-series data in thememory 208. The control valve V13 is controlled by thecontrol device 200 in accordance with the measured data from the flowmeter (F103), thereby regulating the amount of liquid nitrogen that is introduced. - A gas-liquid substance discharged through a pipeline L4 from a
column bottom portion 41 of the lower-pressure column 4 and a gas-liquid substance discharged through a pipeline L31 from a top portion of the first condenser 3 merge and are sent to themain heat exchanger 1. - Further, the air separation system is provided with: the first
crude argon column 5 in which the argon-containing oxygen-enriched gas-liquid substance discharged from the argon extraction portion 421 of the lower-pressure column 4 is introduced via the pipeline L42 into thecolumn bottom portion 51, or below the intermediate stage of the distillation portion 52; and a second crude argon column 6 in which an argon-enriched gas-liquid substance discharged via a pipeline L53 from acolumn bottom portion 53 of the firstcrude argon column 5 is introduced into a column bottom portion 61, or below an intermediate stage of adistillation portion 62. - Further, the air separation system is provided with: a third condenser 7 for condensing second crude argon distillate discharged from a
column top portion 63 of the second crude argon column 6; and a pure argon distillation column 8 in which a high-argon-enriched gas-liquid substance discharged through a pipeline L63 from thecolumn top portion 63 of the second crude argon column 6 is introduced into an intermediate stage of adistillation portion 82. - The argon content concentrations have the following relationship.
- Argon-containing oxygen-enriched gas-liquid substance<argon-enriched gas-liquid substance <second crude argon distillate<high-argon-enriched gas-liquid substance
- A
fourth condenser 83 is provided above thedistillation portion 82 of the pure argon column 8 to condense high-purity argon liquid discharged from acolumn bottom portion 81. The high-purity argon liquid discharged from thecolumn bottom portion 81 of the pure argon column 8 is subjected to heat exchange in a heat exchanger E6 (or reboiler) and is returned to thecolumn bottom portion 81. The high-purity argon liquid discharged from thecolumn bottom portion 81 of the pure argon column 8 is withdrawn as product argon and is sent to a product tank. - Valves (such as gate valves, flow-regulating valves, and pressure regulating valves) may be provided in the pipelines and in the lines shown in
FIG. 1 . - Further, compressors, pressure regulating devices, flow rate control devices or the like may be provided as necessary in each pipeline to perform pressure regulation or flow rate regulation.
- The
control device 200 inFIG. 2 will next be described. - The
control device 200 includes aprocess control unit 201, an oxygenconcentration estimating unit 202, a flowrate estimating unit 203, a targettemperature calculating unit 204, and amemory 208 for storing various types of data (such as setting data, process data, and the measured data discussed hereinabove). - The
process control unit 201 controls components constituting the air separation system (such as the temperatures of the heat exchangers, opening and closing of the valves, the flow regulating valves, the pressure regulating valves, the compressors, and the expansion turbine). - The oxygen
concentration estimating unit 202 estimates the oxygen concentration (EC_0 2) of the oxygen-enriched liquid that accumulates in thecolumn bottom portion 21 of the higher-pressure column 2. - The flow
rate estimating unit 203 estimates, by calculation, the flow rate (EF_0 2) of the oxygen-enriched liquid that has been discharged from thecolumn bottom portion 21 of the higher-pressure column 2 and that is to be introduced into thedistillation portion 42 of the lower-pressure column 4. - The target
temperature calculating unit 204 calculates the target temperature (Tt) of the argon extraction portion 421 on the basis of flow rate (F_FA) of the feed air that has passed through at least a portion of themain heat exchanger 1 and that is to be sent to theexpansion turbine 10, the oxygen concentration (EC-0 2) of the oxygen-enriched liquid, and the flow rate (EF_0 2) of the oxygen-enriched liquid. The targettemperature calculating unit 204 calculates the target temperature (Tt) using a statistical method such as multivariate analysis or regression analysis. - The
process control unit 201 controls the replenishment amount flow rate (flowmeter F101 and valve V13) of liquid nitrogen, and/or the flow rate (flowmeter F102 and valve V12) of the higher-pressure column distillate (reflux liquid) discharged from the column 23 of the higher-pressure column 2, such that the measured temperature (T101) of the argon extraction portion 421 reaches the target temperature (Tt). - The effect on the argon extraction rate was verified using the configuration in
FIG. 1 . - Comparative example: Process control to keep the concentration of the oxygen-enriched liquid constant was performed as in a conventional case.
- Exemplary embodiment: Control was performed such that the temperature of the argon extraction portion reached the target temperature.
- An improvement in the argon extraction rate of 9% on average was seen using the exemplary embodiment exhibited compared with the comparative example.
- While the invention has been described in conjunction with specific embodiments thereof, it is evident that many alternatives, modifications, and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, it is intended to embrace all such alternatives, modifications, and variations as fall within the spirit and broad scope of the appended claims. The present invention may suitably comprise, consist or consist essentially of the elements disclosed and may be practiced in the absence of an element not disclosed. Furthermore, if there is language referring to order, such as first and second, it should be understood in an exemplary sense and not in a limiting sense. For example, it can be recognized by those skilled in the art that certain steps can be combined into a single step.
- The singular forms “a”, “an” and “the” include plural referents, unless the context clearly dictates otherwise.
- “Comprising” in a claim is an open transitional term which means the subsequently identified claim elements are a nonexclusive listing (i.e., anything else may be additionally included and remain within the scope of “comprising”). “Comprising” as used herein may be replaced by the more limited transitional terms “consisting essentially of” and “consisting of” unless otherwise indicated herein.
- “Providing” in a claim is defined to mean furnishing, supplying, making available, or preparing something. The step may be performed by any actor in the absence of express language in the claim to the contrary.
- Optional or optionally means that the subsequently described event or circumstances may or may not occur. The description includes instances where the event or circumstance occurs and instances where it does not occur.
- Ranges may be expressed herein as from about one particular value, and/or to about another particular value. When such a range is expressed, it is to be understood that another embodiment is from the one particular value and/or to the other particular value, along with all combinations within said range.
- All references identified herein are each hereby incorporated by reference into this application in their entireties, as well as for the specific information for which each is cited.
-
- 1 Main heat exchanger
- 2 Higher-pressure column
- 21 Column bottom portion
- 22 Distillation portion
- 23 Column top portion
- 3 First condenser
- 4 Lower-pressure column
- 41 Column bottom portion
- 42 Distillation portion
- 44 Column top portion
- 5 First crude argon column
- 6 Second crude argon column
- 7 Third condenser
- 8 Pure argon column
- 83 Fourth condenser
- 10 Expansion turbine
- E5 Heat exchanger
- E6 Heat exchanger
Claims (2)
1. An air separation system comprising:
a main heat exchanger;
a higher-pressure column into which feed air that has passed through the main heat exchanger is introduced,
a first condensing unit for condensing gas discharged from a column top portion of the higher-pressure column,
a lower-pressure column into which oxygen-enriched liquid discharged from a column bottom portion of the higher-pressure column is introduced, and
a crude argon column into which an argon-containing oxygen-enriched gas-liquid substance discharged from an argon extraction portion, which is an intermediate stage of a distillation portion of the lower-pressure column, is introduced, and also provided with:
a process control unit for controlling components constituting the air separation system;
an oxygen concentration estimating unit for estimating, by calculation, the oxygen concentration of the oxygen-enriched liquid that accumulates in the column bottom portion of the higher-pressure column;
a flow rate estimating unit for estimating, by calculation, the flow rate of the oxygen-enriched liquid that has been discharged from the column bottom portion of the higher-pressure column and that is to be introduced into the distillation portion of the lower-pressure column; and
a target temperature calculating unit for calculating a target temperature of the argon extraction portion on the basis of the flow rate of the feed air that has passed through at least a portion of the main heat exchanger and that is to be sent to the expansion turbine, the oxygen concentration of the oxygen-enriched liquid, and the flow rate of the oxygen-enriched liquid.
2. The air separation system according to claim 1 , wherein the process control unit is configured to control a replenishment amount flow rate of liquid nitrogen, and/or the flow rate of reflux liquid, such that the measured temperature of the argon extraction portion reaches the target temperature.
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JP2020-000482 | 2020-01-06 | ||
JP2020000482A JP7378695B2 (en) | 2020-01-06 | 2020-01-06 | air separation system |
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US20210207885A1 true US20210207885A1 (en) | 2021-07-08 |
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US17/142,217 Abandoned US20210207885A1 (en) | 2020-01-06 | 2021-01-05 | Air separation system |
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US (1) | US20210207885A1 (en) |
EP (1) | EP3845848A1 (en) |
JP (1) | JP7378695B2 (en) |
CN (1) | CN113074515A (en) |
SG (1) | SG10202100029UA (en) |
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CN114183996B (en) * | 2021-11-04 | 2023-06-02 | 灵谷化工集团有限公司 | Liquefied argon preparation method for optimizing driving time of argon system |
JP7133735B1 (en) | 2022-03-07 | 2022-09-08 | レール・リキード-ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | air separator |
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US5313800A (en) * | 1993-02-01 | 1994-05-24 | Praxair Technology, Inc. | Process for maximizing the recovery of argon from an air separation system at high argon recovery rates |
US5406800A (en) * | 1994-05-27 | 1995-04-18 | Praxair Technology, Inc. | Cryogenic rectification system capacity control method |
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US20130053998A1 (en) * | 2011-08-25 | 2013-02-28 | Ashish Singhal | Air separation plant control |
US20210080171A1 (en) * | 2019-09-18 | 2021-03-18 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | High-purity oxygen production system |
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US2934908A (en) * | 1954-08-16 | 1960-05-03 | Union Carbide Corp | High argon recovery using proper shelf-top pinch principle |
JPH03244990A (en) * | 1990-02-22 | 1991-10-31 | Sumitomo Metal Ind Ltd | Control of nitrogen concentration in material argon |
JPH04359786A (en) * | 1991-06-04 | 1992-12-14 | Hitachi Ltd | Control method of air separator |
JP2714527B2 (en) * | 1993-06-22 | 1998-02-16 | 株式会社神戸製鋼所 | Operation control method and device for air separation device |
US6138474A (en) * | 1999-01-29 | 2000-10-31 | Air Products And Chemicals, Inc. | Argon production control through argon inventory manipulation |
FR2964451B3 (en) | 2011-12-05 | 2012-10-12 | Air Liquide | INSTALLATION FOR SEPARATING AN AIR GAS BY CRYOGENIC SEPARATION |
JP6440232B1 (en) * | 2018-03-20 | 2018-12-19 | レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | Product nitrogen gas and product argon production method and production apparatus thereof |
-
2020
- 2020-01-06 JP JP2020000482A patent/JP7378695B2/en active Active
- 2020-12-22 EP EP20216694.8A patent/EP3845848A1/en not_active Withdrawn
- 2020-12-31 CN CN202011636741.0A patent/CN113074515A/en not_active Withdrawn
-
2021
- 2021-01-04 SG SG10202100029UA patent/SG10202100029UA/en unknown
- 2021-01-05 US US17/142,217 patent/US20210207885A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US5313800A (en) * | 1993-02-01 | 1994-05-24 | Praxair Technology, Inc. | Process for maximizing the recovery of argon from an air separation system at high argon recovery rates |
US5406800A (en) * | 1994-05-27 | 1995-04-18 | Praxair Technology, Inc. | Cryogenic rectification system capacity control method |
US6347534B1 (en) * | 1999-05-25 | 2002-02-19 | Air Liquide Process And Construction | Cryogenic distillation system for air separation |
US20130053998A1 (en) * | 2011-08-25 | 2013-02-28 | Ashish Singhal | Air separation plant control |
US20210080171A1 (en) * | 2019-09-18 | 2021-03-18 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | High-purity oxygen production system |
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EP3845848A1 (en) | 2021-07-07 |
JP7378695B2 (en) | 2023-11-14 |
SG10202100029UA (en) | 2021-08-30 |
CN113074515A (en) | 2021-07-06 |
JP2021110466A (en) | 2021-08-02 |
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