US20210079429A1 - Multiple tank high solids anaerobic digester - Google Patents

Multiple tank high solids anaerobic digester Download PDF

Info

Publication number
US20210079429A1
US20210079429A1 US17/039,907 US202017039907A US2021079429A1 US 20210079429 A1 US20210079429 A1 US 20210079429A1 US 202017039907 A US202017039907 A US 202017039907A US 2021079429 A1 US2021079429 A1 US 2021079429A1
Authority
US
United States
Prior art keywords
digester
digestate
stage
outer portion
tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US17/039,907
Inventor
Juan Carlos Josse
Christian Friedl
Martin Bayer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anaergia Inc
Original Assignee
Anaergia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anaergia Inc filed Critical Anaergia Inc
Priority to US17/039,907 priority Critical patent/US20210079429A1/en
Publication of US20210079429A1 publication Critical patent/US20210079429A1/en
Assigned to ANAERGIA INC. reassignment ANAERGIA INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BAYER, MARTIN, FRIEDL, CHRISTIAN, JOSSE, JUAN CARLOS
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/023Methane
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/286Anaerobic digestion processes including two or more steps
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2866Particular arrangements for anaerobic reactors
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/34Internal compartments or partitions
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/58Reaction vessels connected in series or in parallel
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/02Percolation
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/18External loop; Means for reintroduction of fermented biomass or liquid percolate
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P1/00Preparation of compounds or compositions, not provided for in groups C12P3/00 - C12P39/00, by using microorganisms or enzymes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/005Processes using a programmable logic controller [PLC]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/44Time
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/02Fluid flow conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/10Energy recovery
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies

Definitions

  • This specification relates to anaerobic digestion.
  • Anaerobic digestion is typically done in a single tank or in two tanks connected in series.
  • the tanks are typically cylindrical and mixed so as to operate as a continuously stirred tank reactor (CSTR). Where two tanks are used, the effluent from the upstream tank flows to the downstream tank. In some cases, two tanks are used to separate the process into an acid phase and a gas or methanogenic phase. In such a phased digestion system, the volume of the acid phase tank is much lower than that of the gas phase tank.
  • CSTR continuously stirred tank reactor
  • feedstock to an anaerobic digester have such a high solids concentration that the feedstock cannot be pumped.
  • These types of feedstock referred to as stackable feedstock, may be still be transferred to an anaerobic digester but they are very difficult to mix.
  • the feedstock could be diluted, but this would require a source of water for dilution, increase the size of digester required, and lower the reaction rate in the digester.
  • An anaerobic digestion system described in this specification is designed to treat a high solids feedstock with minimal, if any, dilution.
  • the system may receive a pumpable feedstock such as a slurry or sludge alone or in combination with a stackable substrate.
  • the system comprises two digester stages that operate in series.
  • substrate being digested in the digester called digestate
  • the digestate may flow around the raceway and pass by a feed inlet multiple times before leaving the first stage.
  • An inlet to a passageway from the first stage to the second stage is preferably located near, but upstream of, the feed inlet.
  • Partially digested substrate flows to the second stage, which is operated as a stirred reactor.
  • a side stream mixing loop may withdraw digestate with fibrous material from near the free surface of the digestate, chop the fibers, and return the digestate with chopped fibers to a lower elevation within the digestate.
  • An inlet to the side stream mixing loop may comprise a crust breaker.
  • the two stages of the digester may be constructed within a single circular tank.
  • An internal wall separates a ring shaped outer portion from a cylindrical inner portion of the tank.
  • the outer ring provides the first stage, where partial digestion occurs.
  • the internal cylindrical portion is the second stage of the digester, where the digestion is completed.
  • the solids content and viscosity in the first stage are higher than in the second stage as a result of partial digestion of the volatile solids in the feedstock in the first stage. With further digestion in the second stage, the solids content and viscosity of the digestate are further reduced, facilitating mixing.
  • a portion of the digestate from the second stage tank can be recirculated to the first stage tank if needed to reduce the solids content with difficult-to-digest feedstocks.
  • the process is not primarily intended to separate the digester into an acid phase and a gas or methanogenic phase, but rather to facilitate mixing with high solids content feedstocks.
  • the volume of the first stage tank may be 40% or more, or 40 to 50%, of the total digester volume.
  • the first stage of the digester with flow in one direction around a path or raceway, is able to process very high-solids feedstocks with minimal or no dilution. Reduced dilution allows digestion to occur in a shorter hydraulic retention time, which in turn allows for a lower digester volume for a given feed rate.
  • the tank-in-tank configuration described above may be more difficult to construct than a single tank but it creates a compact two stage reactor since there is no space lost in between the two portions of the tank. Heat losses are also reduced since the internal concrete wall insulates the contents of the second stage digester.
  • the digester may operate in a thermophilic temperature range. Accordingly, the tank-in-tank configuration could be advantageous in two stage digesters generally, particularly large digesters. Large digesters may include digesters that, when fed maize silage at 30 to 35% DS, make enough biogas to produce of 500 kW or more, or 800 kW or more, of electricity with a gas engine generator that is about 40% efficient in converting the gas to electricity.
  • FIG. 1 is a schematic elevation view of an anaerobic digestion system.
  • FIG. 2 is a schematic plan view of the anaerobic digestion system of FIG. 1 .
  • FIGS. 3A to 3B are a side view ( FIG. 3A ) and a front view ( FIG. 3B ) of a crust breaker of the anaerobic digestion system of FIG. 1 .
  • FIGS. 1 and 2 show an anaerobic digestion system 100 .
  • the system 100 is able to digest an organic feedstock (alternatively called a substrate) with a high solids content that is stackable and not pumpable.
  • Stackable feedstocks include, without limitation, silage from maize, grass, wheat or other grains, high solids manures such as from poultry layers, ensilaged sugar cane leaves or other crop residuals, dewatered sugar beet pulp cake, sugar cane processing filter cake, sugar cane ensilaged leaves, grape pomace, fruit peels and other high solids substrates from the food processing and meat processing industry, and wet distillers grain from the bioethanol industry.
  • the system 100 can also digest a pumpable feedstock, and combinations of a stackable feedstock with a pumpable feedstock, such as a liquid substrate, a slurry or a sludge.
  • the system 100 in FIG. 1 consists of digester ( 25 ) having two stages connected in series. In the digester ( 25 ), both stages are contained within a covered cylindrical tank ( 27 ).
  • An internal wall ( 28 ) separates a ring shaped outer portion of the tank ( 27 ) which provides a first stage ( 5 ), from a cylindrical inner portion of the tank ( 27 ) which provides the second stage ( 6 ).
  • the inner and outer portions of tank ( 27 ) may also be referred to as inner and outer tanks, with a shared common wall, or as a tank within a tank.
  • the first stage ( 5 ) provides a flow path in the form of an endless loop, or raceway.
  • the second stage ( 6 ) provides an undivided mixing area.
  • a passageway ( 29 ) allows partially digested substrate to flow through the internal wall ( 28 ), from the first stage ( 5 ) to the second stage ( 6 ). Digestion is started in the first stage ( 5 ) and completed in the second stage ( 6 ).
  • first stage tank may be located separate from a second stage tank.
  • a first stage tank might also have another shape that creates a raceway.
  • a rectangular tank preferably with semi-circular ends, can be fitted with a lengthwise divider.
  • the first stage ( 5 ) operates with digestate circulating in direction ( 26 ), moved by a first set ( 7 ) of mixers.
  • the digestate is mixed as it moves in direction ( 26 ).
  • the average flow is primarily in direction ( 26 ).
  • the first stage ( 5 ) operates somewhat like a plug flow reactor in that there is a gradient in reaction products between the inlet and the outlet of the first stage ( 5 ).
  • the first stage ( 5 ) also has some characteristics of a continuously stirred tank reactor (CSTR).
  • a particle of recirculating substrate passes the feed inlet, on average, many times, for example 20 or more or between 20 and 30, before exiting from the first stage ( 5 ).
  • the second stage ( 6 ) operates generally like a CSTR.
  • the solids content and viscosity in the first stage ( 5 ) are higher than in the second stage ( 6 ) as a result of partial digestion of the volatile solids in the feedstock in the first stage ( 5 ). As digestion continues in the second stage ( 6 ), the solids content and viscosity of the digestate are further reduced, which makes it easier to mix the digestate. A portion of the digestate from the second stage ( 6 ) can be recirculated to the first stage tank if needed to reduce the solids content in the first stage ( 5 ) with difficult-to-digest substrates. Typically the volume of the first stage ( 5 ) is 40 to 50% of the total volume of the digester ( 25 ).
  • one or more stackable substrates (A) are received in a solids feeder ( 1 ).
  • Substrates with a solids content in excess of 40% dried solids (DS) can be fed.
  • the solids feeder ( 1 ) can be loaded with a front end loader, or it can be installed below grade such that it can be fed from a dump truck.
  • the solids feeder ( 1 ) may provide enough storage volume for about 12 to 24 hours worth of stackable substrate (A) to be fed to the digester tank ( 25 ).
  • Solids feeders ( 1 ) such as those sold by UTS Products GmbH of Germany have a live rubber belt bottom resting on closely spaced rollers.
  • the stackable substrate (A), alternatively called feedstock, is driven forward and passed through milling drums that grind and loosen the stackable substrate (A), which then drops onto a belt or chain conveyor ( 2 ).
  • the conveyor ( 2 ) drops the stackable substrate (A) into the hopper of an auger ( 3 ).
  • the auger ( 3 ) discharges the stackable substrate (A) about 0.6 m below the free surface of the digestate in the first stage ( 5 ). This inhibits biogas escape from the digester ( 25 ).
  • the solids feeder ( 1 ) may contain load cells that are used to quantify the amount of stackable substrate (A) fed. This feature can be used in an automatic feed control system.
  • the solids feeder ( 1 ) may be programmed for automatic intermittent feed, supplying an equal fraction of the total daily feed at predetermined time intervals. For example, substrate may be fed for 10 minutes once every 30 or 40 minutes, of for 15 minutes once every hour.
  • One or more pumpable substrates (B), with lower solids content than the stackable substrates (A), may be fed to the digester ( 25 ) alone or in combination with one or more stackable substrates (A).
  • Examples of pumpable substrates (B) include cow or pig manure, food waste slurry, and restaurant grease.
  • Pumpable substrates (B) are stored in a mixed tank ( 4 ) and fed with a pump ( 15 ), such as a centrifugal chopper pumps or a positive displacement pump. The pumpable substrate (B) is preferably fed when the first set of mixers ( 7 ) are operating.
  • the inlet point for pumpable substrates (B) may be between the inlet point for the stackable substrates (A) feed point and a first mixer ( 7 ) downstream of the inlet point for the stackable substrates (A).
  • the digester ( 25 ) preferably also receives a daily dose of micronutrients, which may be diluted and sprayed onto the solids stackable substrate (A).
  • the first set of mixers ( 7 ) preferably all operate at the same time but intermittently. Mixer operation preferably coincides with feeding stackable substrates (A).
  • the first set of mixers ( 7 ) may operate, for example, for 15 minutes every hour or 10 minutes every 30 or 40 minutes, or according to other mixing regimes that can be preset in a programmable logic controller. There can be between three and six mixers in the first set of mixers ( 7 ), depending on the tank ( 27 ) diameter and the solids content of the digestate.
  • Tank ( 27 ) sizes may range, for example, from a 26 m outer diameter with a 16 m diameter internal wall ( 28 ), to as large as a 46 m outer tank diameter with a 32 m diameter internal wall ( 28 ).
  • the first stage ( 5 ) may range from 5 m to 7 m in width.
  • the tank ( 27 ) is covered, usually with a membrane cover or concrete, or with a combination of these covers.
  • the first stage ( 5 ) has a concrete cover ( 17 ).
  • the second stage ( 6 ) shown has a double membrane cover ( 13 ) that acts as a gas holder, but can also have a concrete cover.
  • Maximum depths of the tank ( 27 ) is preferably about 12 m.
  • the walls of the tank ( 27 ) and the internal wall ( 28 ) can be made of concrete or with coated carbon steel sections bolted together.
  • the preferred mixers ( 7 ) are 22 kW hydraulic power driven submersible mixers manufactured by UTS Products GmbH. These mixers ( 7 ) have three blade rotors ( 8 ) with a 960 mm diameter and operate at 170 rpm.
  • the mixers ( 7 ) are driven by a hydraulic motor. Hydraulic power is produced by a hydraulic power unit (HPU) with a hydraulic pump and an oil reservoir and valves. The HPU is located outside of the tank ( 27 ) in an equipment room adjacent to the digester ( 25 ).
  • the mixers ( 7 ) are mounted on square stainless steel guide columns ( 22 ). Access to a mixer ( 7 ) is through a service box ( 10 ) located on top of the mixer ( 7 ) and attached to the digester cover ( 17 ), ( 13 ). Suitable service boxes ( 10 ) are also manufactured by UTS Products GmbH.
  • the mixers ( 7 ) move the thick, viscous digestate in direction ( 26 ) around the endless path or raceway defined by the outer wall of tank ( 27 ) and the internal wall ( 28 ).
  • a first mixer ( 7 ) is placed about 2 to 3 m downstream of auger ( 3 ), which provides the inlet for the stackable solids (A).
  • This first mixer ( 7 ) is located close to the surface of the digestate, at the minimum mixer allowable depth, and has a rotor ( 8 ) higher than the rotors ( 8 ) of other mixers ( 7 ) in the first stage ( 5 ).
  • Rotors ( 8 ) of the other mixers ( 7 ) in the first stage are placed at different heights, moving deeper the farther they are located from the first mixer ( 7 ) in the direction ( 26 ). This facilitates vertical transport of the digestate as it moves along the raceway towards the passageway ( 29 ).
  • the raceway configuration allows the first stage ( 5 ) to operate at a solids content and viscosity that could not be easily mixed in a circular tank. This is possible because the digestate in the first stage ( 5 ) moves primarily in a single direction ( 26 ), with some vertical mixing due to the position of the mixers ( 7 ).
  • the first stage ( 5 ) operates as a “first in, first out”, or plug-flow, reactor within a single course around the raceway.
  • Substrate components such as proteins, sugars, starch, and fat decompose within a few hours in the first stage ( 5 ). As these components decompose, the viscosity of newly fed stackable substrates (A) decreases.
  • Newly fed stackable substrates (A) are also blended with recirculating digestate as it moves back towards the auger ( 3 ).
  • the more readily digestable fraction of the substrate sinks in the first stage ( 5 ) as it moves along the raceway facilitated by its loss of viscosity.
  • This sunken fraction reaches the passageway ( 29 ) after fewer rotations around the raceway.
  • the auger ( 3 ) is located downstream of the passageway ( 29 ) but preferable by an angular displacement of 60 degrees or less.
  • a side stream mixing loop ( 31 ) with a chopper pump ( 16 ) takes digestate from the tank ( 27 ) through an intake (F) and returns digestate with chopped fibers to the tank ( 27 ).
  • the intake (F) is preferably located near the free surface of the digestate, for example within one meter of the free surface.
  • the digestate preferably returns to the tank ( 27 ) at a lower location, for example around mid depth of the tank ( 27 ).
  • the chopped fibers are preferably not moved all of the way to the bottom of the tank ( 27 ) because there is less mixing there and it is undesirable to transfer the fibers to the second stage ( 6 ) except in a mixture with more nearly liquid digestate.
  • the digestate with chopped fibers is preferably also returned downstream of the inlet (F).
  • the outlet from the chopper pump ( 16 ) may be located upstream of the first mixer ( 7 ) after the auger ( 3 ), and upstream or downstream of the auger ( 3 ). This moves undigested fibers deeper in the digestate to facilitate their digestion and eventual transfer to the second stage ( 6 ). From the second stage ( 6 ) undigested fibers can be removed from the digester ( 25 ) to avoid an accumulation of non-digestible fiber in the digester ( 25 ).
  • Fibers and other solids may form a crust on the surface of the digestate in the first stage ( 5 ).
  • the crust moves along the raceway following the direction of sludge circulation.
  • the intake (F) may be connected to a crust breaker ( 30 ) installed near the surface of the digestate placed perpendicular to the raceway.
  • the crust breaker is generally in the form of a trough.
  • One side ( 40 ) of the crust breaker ( 30 ) faces into the direction ( 26 ) of flow in the raceway. This side ( 40 ) has fingers ( 42 ) that break the floating crust.
  • the mixers ( 7 ) have high pumping rates and move large volumes of digestate along the raceway.
  • the flow may be in the order of 5,000 to 7,000 m3/h.
  • the flow rate is a function of the solids content.
  • the flow rate of in the raceway is at least about 10 times higher than the stackable substrate (A) feed flow rate.
  • ammonium carbonate is a strong buffering system that provides alkalinity. Additionally some biogas is produced from hydrogen, which also increases alkalinity. The digestate is higher in alkalinity when it returns to the substrate inlet. This brings alkalinity to where is most needed to avoid changes in pH. The local increase in alkalinity enhances process stability, which allows higher organic loadings in the first stage ( 5 ) with minimal risk of acid accumulation or pH depression.
  • the digester ( 25 ) may operate with as high as 17% dried solids (DS) in the first stage ( 5 ) and 14% DS in the second stage ( 6 ) within a thermophilic temperature range, for example at about 55 degrees C.
  • a mesophilic temperature range for example about 38 to 40 degrees C.
  • the maximum recommended solids content is 14% DS for the first stage ( 5 ) and 10% DS for the second stage ( 6 ).
  • first stage ( 5 ) digestate With high solids substrates that leave a large fraction of undigested residue (usually non degradable volatile solids), such as grass silage, dilution of the first stage ( 5 ) digestate may be required. This can be done by recirculating a portion of the lower solids content digestate from the lower half of the second stage ( 6 ). Usually in this section of the second stage ( 6 ) the solids content is lower. First stage ( 5 ) dilution can also be accomplished by returning more filtrate (H) from dewatering the second stage digestate (D) than is desired for fiber removal with biomass return (as will be described below) to the first stage.
  • Effluent digestate (D) is removed from the digester ( 25 ) by a pump ( 14 ). A portion of the waste digestate is permanently removed from the digester ( 25 ) to provide a mass balance of inlets and outlets. A further portion of the effluent digestate (D) is sent to a dewatering unit ( 18 ), such as a screw press, to provide additional removal of undigested fibers. Filtrate (H) from this portion of the effluent digestate (D) returns from the dewatering unit ( 18 ) through a filtrate return line ( 32 ) to the first stage ( 5 ). In this way, essentially undigestible, or poorly digestible, solids are removed from the digestate while filtrate (H) containing biomass and more readily digestible solids is retained in the digester ( 25 ).
  • Screw presses may have wedge wire screens with openings under 1000 microns that retain partially digested fibers and other solids.
  • Separated solids (G) are temporarily stored in a clamp ( 19 ) and can be composted or further heat dried for use as fertilizer pellets or fuel.
  • the dewatering unit ( 18 ) allows bacterial mass to pass with the filtrate (H). A portion of this bacterial mass is returned with the filtrate (H) to the first stage ( 5 ). This return of viable anaerobic bacteria helps extend the bacterial solids retention time and avoid washout. Removing solids while retaining bacteria is particularly beneficial in highly loaded digesters operating at relatively low hydraulic retention times, such as less than 24 days HRT for a mesophilic digester, and less than 18 days HRT for a thermophilic digester.
  • the daily substrate flow that enters the digester ( 25 ) must also be removed daily as biogas and separated solids (G). Therefore a waste portion (I) of the dewatering filtrate, or waste portion (J) of the effluent digestate (D), or both, is discharged.
  • the waste portion (I) of the dewatering filtrate can be used as liquid fertilizer for land application or treated further to remove nutrients and organic matter to make it suitable for discharge if there is no land available for application.
  • digestate land application is not possible during Winter Season, and regulations require digestate storage for 180 days.
  • a digestate storage tank with intermittent mixing is constructed.
  • the waste portion (J) is regularly transferred to this tank.
  • the storage tank is covered, for example with a gas holding membrane cover. During storage there is still some additional volatile solids destruction and biogas is produced.
  • the gas space of the digestate storage tank is connected with the digester ( 25 ).
  • the second stage ( 6 ) effluent digestate pumping system preferably has two inlet ports with selection between them provided by a valve ( 33 ).
  • An upper inlet port ( 21 ) is near the surface of the digestate and removes digestate with higher fiber content. This digestate typically goes to the dewatering unit ( 18 ).
  • a second, lower, inlet port ( 20 ) is located in the lower half of the second stage ( 6 ), preferably just above the bottom.
  • This lower port ( 20 ) removes digestate with less fiber and lower solids content.
  • This digestate may be treated as waste portion (J) digestate that goes to a digestate storage tank or fields for land application, or it may be returned to the first stage ( 5 ) for dilution if needed.
  • the digester ( 25 ) may operate with about one meter of head space above the liquid level.
  • the head spaces of the first stage ( 5 ) and second stage ( 6 ) are connected with large openings ( 12 ) through the internal wall ( 28 ), such that the membrane cover ( 13 ) of the second stage ( 6 ) allows constant pressure storage of the gas produced in both stages.
  • Biogas (E) is extracted from connections in the service boxes ( 10 ). This provides adequate distance from the free surface of the digestate to the gas outlet, which limits the potential for foam carryover.
  • the gas pressure is boosted for use in engines, other combined heat and power (CHP) generation systems, or systems to upgrade the biogas to pipeline quality renewable natural gas.
  • CHP combined heat and power
  • the passageway ( 29 ) has an inlet near the bottom of the first stage ( 5 ). Flow through the passageway ( 29 ) may be by gravity with the first stage digestate (C) flowing through an internal riser portion ( 9 ) of the passageway into the second stage ( 6 ) driven by the differential head of the digestate in the two tanks.
  • the free surface of the digestate is usually about 20 to 30 cm higher in the first stage ( 5 ).
  • the solids content of the first stage digestate (C) is higher than about 12% in mesophilic operation, it is too viscous and the small head differential across the internal wall ( 18 ) is not sufficient to overcome friction losses in the passageway ( 29 ).
  • the flow is helped by pressurizing and injecting a controlled amount of biogas near the bottom of the riser portion ( 9 ) to create a gas lift pump.
  • an chopper pump my be used to transfer digestate from the first ( 5 ) to the second stage ( 6 ).
  • the second stage ( 6 ) operates generally like a CSTR.
  • a second set of mixers ( 7 ) installed around the perimeter of the internal wall ( 18 ) generate a swirling motion in the second stage ( 6 ), and also provide vertical mixing as shown by the arrows in FIGS. 1 and 2 .
  • the rotors ( 8 ) are pointed toward the center of the tank ( 27 ) but with a 5 to 10 degree offset. This produces the swirl or spinning motion.
  • the second stage ( 6 ) requires three 22 kW mixers ( 7 ) for diameters between 16 and 32 meters and depths from 8 to 12 m, when operating with 8 to 10% solids content in either the thermo- or meso-philic range. Higher solids content may require four mixers ( 7 ). If the digestate is more than 6 m deep, some rotors ( 8 ) may be placed are at a higher level. If the digestate is 6 m deep or less, all rotors ( 18 ) at located about one third up from the bottom.
  • Digestate is taken from the second stage tank ( 6 ) by pump ( 14 ) through inlet ports ( 20 ) or ( 21 ).
  • Anaerobic digestion is an exothermic process.
  • high solids digesters the significant energy density of the substrate and the reduced amount of water added for dilution result in a noticeable temperature increase compared to the temperature of the substrate (A), (B).
  • the tank ( 27 ) has insulation on the external wall.
  • the tank-in-tank configuration particularly when constructed with concrete, reduces heat losses from the internal tank, as the internal wall ( 18 ) and outer ring act insulators.
  • heating may be required and can be provided using hot water heating pipes installed inside the tank ( 27 ), along the outer wall and the internal wall ( 18 ). Hot water, for example from a combined heat and power (CHP) unit burning the biogas (E), is circulated through the heating pipes.
  • CHP combined heat and power
  • second stage tank digestate is pumped from the bottom half of the tank ( 27 ) through a HEX, where heat is transferred from hot water produced by the CHP unit or a hot water boiler. Heated second stage digestate is circulated into the first stage digester. This contributes to dilute the first stage solids content and to transport heat.
  • HEX tube-in-tube heat exchangers

Abstract

A multi-stage anaerobic digester is designed to treat a high solids, stackable feedstock. The system may also receive a pumpable feedstock such as a slurry or sludge. In a first stage, the digestate circulates in one direction around a raceway such that the digestate may pass a feed inlet multiple times before leaving the first tank. An optional side stream loop withdraws fibrous material from near the top of the raceway and return digestate with chopped fibers, preferably lower and further along the raceway. An outlet from the raceway located near, but upstream of, the feed inlet discharges partially digested substrate to a second stage, which is operated as a stirred tank reactor. The two stages may be provided in a single tank with an internal wall separating a ring shaped outer portion from a cylindrical inner portion. The digester may be operated in a thermophilic temperature range.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a continuation of U.S. patent application Ser. No. 15/628,189; filed Jun. 20, 2017, which is a division of U.S. patent application Ser. No. 14/352,477; filed Dec. 10, 2014, which issued as U.S. Pat. No. 9,719,111 and which is a National Stage Entry of International Application No. PCT/CA2011/001315, filed Nov. 30, 2011, which is a non-provisional application of U.S. Application Ser. No. 61/548,919, filed Oct. 19, 2011. U.S. Application Ser. No. 61/548,919 is incorporated by reference.
  • FIELD
  • This specification relates to anaerobic digestion.
  • BACKGROUND
  • Anaerobic digestion is typically done in a single tank or in two tanks connected in series. The tanks are typically cylindrical and mixed so as to operate as a continuously stirred tank reactor (CSTR). Where two tanks are used, the effluent from the upstream tank flows to the downstream tank. In some cases, two tanks are used to separate the process into an acid phase and a gas or methanogenic phase. In such a phased digestion system, the volume of the acid phase tank is much lower than that of the gas phase tank.
  • INTRODUCTION TO THE INVENTION
  • Some types of feedstock to an anaerobic digester have such a high solids concentration that the feedstock cannot be pumped. These types of feedstock, referred to as stackable feedstock, may be still be transferred to an anaerobic digester but they are very difficult to mix. The feedstock could be diluted, but this would require a source of water for dilution, increase the size of digester required, and lower the reaction rate in the digester. An anaerobic digestion system described in this specification is designed to treat a high solids feedstock with minimal, if any, dilution. Optionally, the system may receive a pumpable feedstock such as a slurry or sludge alone or in combination with a stackable substrate.
  • The system comprises two digester stages that operate in series. In a first stage, substrate being digested in the digester, called digestate, circulates in one direction around an endless loop, alternatively called a raceway. The digestate may flow around the raceway and pass by a feed inlet multiple times before leaving the first stage. An inlet to a passageway from the first stage to the second stage is preferably located near, but upstream of, the feed inlet. Partially digested substrate flows to the second stage, which is operated as a stirred reactor.
  • Optionally, a side stream mixing loop may withdraw digestate with fibrous material from near the free surface of the digestate, chop the fibers, and return the digestate with chopped fibers to a lower elevation within the digestate. An inlet to the side stream mixing loop may comprise a crust breaker.
  • The two stages of the digester may be constructed within a single circular tank. An internal wall separates a ring shaped outer portion from a cylindrical inner portion of the tank. The outer ring provides the first stage, where partial digestion occurs. The internal cylindrical portion is the second stage of the digester, where the digestion is completed. The solids content and viscosity in the first stage are higher than in the second stage as a result of partial digestion of the volatile solids in the feedstock in the first stage. With further digestion in the second stage, the solids content and viscosity of the digestate are further reduced, facilitating mixing. A portion of the digestate from the second stage tank can be recirculated to the first stage tank if needed to reduce the solids content with difficult-to-digest feedstocks.
  • The process is not primarily intended to separate the digester into an acid phase and a gas or methanogenic phase, but rather to facilitate mixing with high solids content feedstocks. Accordingly, the volume of the first stage tank may be 40% or more, or 40 to 50%, of the total digester volume. The first stage of the digester, with flow in one direction around a path or raceway, is able to process very high-solids feedstocks with minimal or no dilution. Reduced dilution allows digestion to occur in a shorter hydraulic retention time, which in turn allows for a lower digester volume for a given feed rate.
  • The tank-in-tank configuration described above may be more difficult to construct than a single tank but it creates a compact two stage reactor since there is no space lost in between the two portions of the tank. Heat losses are also reduced since the internal concrete wall insulates the contents of the second stage digester. The digester may operate in a thermophilic temperature range. Accordingly, the tank-in-tank configuration could be advantageous in two stage digesters generally, particularly large digesters. Large digesters may include digesters that, when fed maize silage at 30 to 35% DS, make enough biogas to produce of 500 kW or more, or 800 kW or more, of electricity with a gas engine generator that is about 40% efficient in converting the gas to electricity.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic elevation view of an anaerobic digestion system.
  • FIG. 2 is a schematic plan view of the anaerobic digestion system of FIG. 1.
  • FIGS. 3A to 3B are a side view (FIG. 3A) and a front view (FIG. 3B) of a crust breaker of the anaerobic digestion system of FIG. 1.
  • DETAILED DESCRIPTION
  • FIGS. 1 and 2 show an anaerobic digestion system 100. The system 100 is able to digest an organic feedstock (alternatively called a substrate) with a high solids content that is stackable and not pumpable. Stackable feedstocks include, without limitation, silage from maize, grass, wheat or other grains, high solids manures such as from poultry layers, ensilaged sugar cane leaves or other crop residuals, dewatered sugar beet pulp cake, sugar cane processing filter cake, sugar cane ensilaged leaves, grape pomace, fruit peels and other high solids substrates from the food processing and meat processing industry, and wet distillers grain from the bioethanol industry. The system 100 can also digest a pumpable feedstock, and combinations of a stackable feedstock with a pumpable feedstock, such as a liquid substrate, a slurry or a sludge.
  • The system 100 in FIG. 1 consists of digester (25) having two stages connected in series. In the digester (25), both stages are contained within a covered cylindrical tank (27). An internal wall (28) separates a ring shaped outer portion of the tank (27) which provides a first stage (5), from a cylindrical inner portion of the tank (27) which provides the second stage (6). The inner and outer portions of tank (27) may also be referred to as inner and outer tanks, with a shared common wall, or as a tank within a tank. The first stage (5) provides a flow path in the form of an endless loop, or raceway. The second stage (6) provides an undivided mixing area. A passageway (29) allows partially digested substrate to flow through the internal wall (28), from the first stage (5) to the second stage (6). Digestion is started in the first stage (5) and completed in the second stage (6).
  • Other tank configurations might also be used. For example, a first stage tank may be located separate from a second stage tank. A first stage tank might also have another shape that creates a raceway. For example, a rectangular tank, preferably with semi-circular ends, can be fitted with a lengthwise divider.
  • The first stage (5) operates with digestate circulating in direction (26), moved by a first set (7) of mixers. The digestate is mixed as it moves in direction (26). There may be small or local mixing flows that are oblique or even backwards relative to direction (26) and disturbances where feed enters the first stage (5) or digestate exists from the first stage (5). However, the average flow is primarily in direction (26). Within a single trip of digestate around the raceway, the first stage (5) operates somewhat like a plug flow reactor in that there is a gradient in reaction products between the inlet and the outlet of the first stage (5). However, since the recirculating flow rate is larger than the feed flow rate, the first stage (5) also has some characteristics of a continuously stirred tank reactor (CSTR). A particle of recirculating substrate passes the feed inlet, on average, many times, for example 20 or more or between 20 and 30, before exiting from the first stage (5). The second stage (6) operates generally like a CSTR.
  • The solids content and viscosity in the first stage (5) are higher than in the second stage (6) as a result of partial digestion of the volatile solids in the feedstock in the first stage (5). As digestion continues in the second stage (6), the solids content and viscosity of the digestate are further reduced, which makes it easier to mix the digestate. A portion of the digestate from the second stage (6) can be recirculated to the first stage tank if needed to reduce the solids content in the first stage (5) with difficult-to-digest substrates. Typically the volume of the first stage (5) is 40 to 50% of the total volume of the digester (25).
  • In the system 100 of FIGS. 1 and 2, one or more stackable substrates (A) are received in a solids feeder (1). Substrates with a solids content in excess of 40% dried solids (DS) can be fed. The solids feeder (1) can be loaded with a front end loader, or it can be installed below grade such that it can be fed from a dump truck. The solids feeder (1) may provide enough storage volume for about 12 to 24 hours worth of stackable substrate (A) to be fed to the digester tank (25). Solids feeders (1) such as those sold by UTS Products GmbH of Germany have a live rubber belt bottom resting on closely spaced rollers. The stackable substrate (A), alternatively called feedstock, is driven forward and passed through milling drums that grind and loosen the stackable substrate (A), which then drops onto a belt or chain conveyor (2). The conveyor (2) drops the stackable substrate (A) into the hopper of an auger (3). The auger (3) discharges the stackable substrate (A) about 0.6 m below the free surface of the digestate in the first stage (5). This inhibits biogas escape from the digester (25). The solids feeder (1) may contain load cells that are used to quantify the amount of stackable substrate (A) fed. This feature can be used in an automatic feed control system. The solids feeder (1) may be programmed for automatic intermittent feed, supplying an equal fraction of the total daily feed at predetermined time intervals. For example, substrate may be fed for 10 minutes once every 30 or 40 minutes, of for 15 minutes once every hour.
  • One or more pumpable substrates (B), with lower solids content than the stackable substrates (A), may be fed to the digester (25) alone or in combination with one or more stackable substrates (A). Examples of pumpable substrates (B) include cow or pig manure, food waste slurry, and restaurant grease. Pumpable substrates (B) are stored in a mixed tank (4) and fed with a pump (15), such as a centrifugal chopper pumps or a positive displacement pump. The pumpable substrate (B) is preferably fed when the first set of mixers (7) are operating. The inlet point for pumpable substrates (B) may be between the inlet point for the stackable substrates (A) feed point and a first mixer (7) downstream of the inlet point for the stackable substrates (A). The digester (25) preferably also receives a daily dose of micronutrients, which may be diluted and sprayed onto the solids stackable substrate (A).
  • The first set of mixers (7) preferably all operate at the same time but intermittently. Mixer operation preferably coincides with feeding stackable substrates (A). The first set of mixers (7) may operate, for example, for 15 minutes every hour or 10 minutes every 30 or 40 minutes, or according to other mixing regimes that can be preset in a programmable logic controller. There can be between three and six mixers in the first set of mixers (7), depending on the tank (27) diameter and the solids content of the digestate. Tank (27) sizes may range, for example, from a 26 m outer diameter with a 16 m diameter internal wall (28), to as large as a 46 m outer tank diameter with a 32 m diameter internal wall (28). The first stage (5) may range from 5 m to 7 m in width.
  • The tank (27) is covered, usually with a membrane cover or concrete, or with a combination of these covers. In FIG. 1, the first stage (5) has a concrete cover (17). The second stage (6) shown has a double membrane cover (13) that acts as a gas holder, but can also have a concrete cover. Maximum depths of the tank (27) is preferably about 12 m. The walls of the tank (27) and the internal wall (28) can be made of concrete or with coated carbon steel sections bolted together.
  • The preferred mixers (7) are 22 kW hydraulic power driven submersible mixers manufactured by UTS Products GmbH. These mixers (7) have three blade rotors (8) with a 960 mm diameter and operate at 170 rpm. The mixers (7) are driven by a hydraulic motor. Hydraulic power is produced by a hydraulic power unit (HPU) with a hydraulic pump and an oil reservoir and valves. The HPU is located outside of the tank (27) in an equipment room adjacent to the digester (25). The mixers (7) are mounted on square stainless steel guide columns (22). Access to a mixer (7) is through a service box (10) located on top of the mixer (7) and attached to the digester cover (17), (13). Suitable service boxes (10) are also manufactured by UTS Products GmbH.
  • In the first stage (5), the mixers (7) move the thick, viscous digestate in direction (26) around the endless path or raceway defined by the outer wall of tank (27) and the internal wall (28). A first mixer (7) is placed about 2 to 3 m downstream of auger (3), which provides the inlet for the stackable solids (A). This first mixer (7) is located close to the surface of the digestate, at the minimum mixer allowable depth, and has a rotor (8) higher than the rotors (8) of other mixers (7) in the first stage (5). Rotors (8) of the other mixers (7) in the first stage are placed at different heights, moving deeper the farther they are located from the first mixer (7) in the direction (26). This facilitates vertical transport of the digestate as it moves along the raceway towards the passageway (29).
  • The raceway configuration allows the first stage (5) to operate at a solids content and viscosity that could not be easily mixed in a circular tank. This is possible because the digestate in the first stage (5) moves primarily in a single direction (26), with some vertical mixing due to the position of the mixers (7). The first stage (5) operates as a “first in, first out”, or plug-flow, reactor within a single course around the raceway. Substrate components such as proteins, sugars, starch, and fat decompose within a few hours in the first stage (5). As these components decompose, the viscosity of newly fed stackable substrates (A) decreases. Newly fed stackable substrates (A) are also blended with recirculating digestate as it moves back towards the auger (3). The more readily digestable fraction of the substrate sinks in the first stage (5) as it moves along the raceway facilitated by its loss of viscosity. This sunken fraction reaches the passageway (29) after fewer rotations around the raceway. To ensure that newly fed stackable substrate (A) makes at least one nearly complete rotation around the raceway, the auger (3) is located downstream of the passageway (29) but preferable by an angular displacement of 60 degrees or less.
  • The fibers and other less digestable components of the stackable substrates (A) tend to float or are pushed up by evolving biogas bubbles and stay longer in the first stage (5). As a result, there is less undigested material exiting to the second stage (6). The first stage (5) self-selects a longer solids retention time for the less digestable material. However, the fibers must be moved eventually to the second stage (6). A side stream mixing loop (31) with a chopper pump (16) takes digestate from the tank (27) through an intake (F) and returns digestate with chopped fibers to the tank (27). The intake (F) is preferably located near the free surface of the digestate, for example within one meter of the free surface. The digestate preferably returns to the tank (27) at a lower location, for example around mid depth of the tank (27). The chopped fibers are preferably not moved all of the way to the bottom of the tank (27) because there is less mixing there and it is undesirable to transfer the fibers to the second stage (6) except in a mixture with more nearly liquid digestate. The digestate with chopped fibers is preferably also returned downstream of the inlet (F). The outlet from the chopper pump (16) may be located upstream of the first mixer (7) after the auger (3), and upstream or downstream of the auger (3). This moves undigested fibers deeper in the digestate to facilitate their digestion and eventual transfer to the second stage (6). From the second stage (6) undigested fibers can be removed from the digester (25) to avoid an accumulation of non-digestible fiber in the digester (25).
  • Fibers and other solids may form a crust on the surface of the digestate in the first stage (5). The crust moves along the raceway following the direction of sludge circulation. The intake (F) may be connected to a crust breaker (30) installed near the surface of the digestate placed perpendicular to the raceway. Referring to FIGS. 3A and 3B, the crust breaker is generally in the form of a trough. One side (40) of the crust breaker (30) faces into the direction (26) of flow in the raceway. This side (40) has fingers (42) that break the floating crust. Broken pieces of crust and other digestate falls into the trough and are sucked out by the chopper pump (16) to be reintroduced downstream and deeper into the raceway. Crust and digestate may be allowed to temporarily accumulate in the crust breaker with a level sensor in the trough used to start and stop the chopper pump (16).
  • The mixers (7) have high pumping rates and move large volumes of digestate along the raceway. The flow may be in the order of 5,000 to 7,000 m3/h. The flow rate is a function of the solids content. The flow rate of in the raceway is at least about 10 times higher than the stackable substrate (A) feed flow rate. As newly fed stackable substrate (A) moves from the feed inlet point to the passageway (29) it hydrolizes and is partially digested. The front end of the raceway, just after the substrate inlets, creates acidity as volatile fatty acids are formed. As digestion of the newly fed substrate (A)) continues along the raceway, proteins and organic nitrogen are converted to ammonia as organic matter breaks down, and ammonia reacts with the carbon dioxide produced in the digestion process and forms ammonium carbonate. Ammonium carbonate is a strong buffering system that provides alkalinity. Additionally some biogas is produced from hydrogen, which also increases alkalinity. The digestate is higher in alkalinity when it returns to the substrate inlet. This brings alkalinity to where is most needed to avoid changes in pH. The local increase in alkalinity enhances process stability, which allows higher organic loadings in the first stage (5) with minimal risk of acid accumulation or pH depression.
  • The digester (25) may operate with as high as 17% dried solids (DS) in the first stage (5) and 14% DS in the second stage (6) within a thermophilic temperature range, for example at about 55 degrees C. In a mesophilic temperature range, for example about 38 to 40 degrees C., the maximum recommended solids content is 14% DS for the first stage (5) and 10% DS for the second stage (6). These limits are to achieve adequate mixing in both stages using the mixers (7) described above. Thermophilic operation allows higher solids content because at increased temperature the viscosity drops for the same solids content, which facilitates mixing. With high solids substrates that leave a large fraction of undigested residue (usually non degradable volatile solids), such as grass silage, dilution of the first stage (5) digestate may be required. This can be done by recirculating a portion of the lower solids content digestate from the lower half of the second stage (6). Usually in this section of the second stage (6) the solids content is lower. First stage (5) dilution can also be accomplished by returning more filtrate (H) from dewatering the second stage digestate (D) than is desired for fiber removal with biomass return (as will be described below) to the first stage.
  • Effluent digestate (D) is removed from the digester (25) by a pump (14). A portion of the waste digestate is permanently removed from the digester (25) to provide a mass balance of inlets and outlets. A further portion of the effluent digestate (D) is sent to a dewatering unit (18), such as a screw press, to provide additional removal of undigested fibers. Filtrate (H) from this portion of the effluent digestate (D) returns from the dewatering unit (18) through a filtrate return line (32) to the first stage (5). In this way, essentially undigestible, or poorly digestible, solids are removed from the digestate while filtrate (H) containing biomass and more readily digestible solids is retained in the digester (25).
  • Screw presses may have wedge wire screens with openings under 1000 microns that retain partially digested fibers and other solids. Separated solids (G) are temporarily stored in a clamp (19) and can be composted or further heat dried for use as fertilizer pellets or fuel. The dewatering unit (18) allows bacterial mass to pass with the filtrate (H). A portion of this bacterial mass is returned with the filtrate (H) to the first stage (5). This return of viable anaerobic bacteria helps extend the bacterial solids retention time and avoid washout. Removing solids while retaining bacteria is particularly beneficial in highly loaded digesters operating at relatively low hydraulic retention times, such as less than 24 days HRT for a mesophilic digester, and less than 18 days HRT for a thermophilic digester.
  • The daily substrate flow that enters the digester (25) must also be removed daily as biogas and separated solids (G). Therefore a waste portion (I) of the dewatering filtrate, or waste portion (J) of the effluent digestate (D), or both, is discharged. The waste portion (I) of the dewatering filtrate can be used as liquid fertilizer for land application or treated further to remove nutrients and organic matter to make it suitable for discharge if there is no land available for application.
  • In agricultural areas that supply crop silage for digestion, nutrients are preferably returned to the soil. This is accomplished by diverting a waste portion (J) of the effluent digestate (D) to tanker trucks (22) for land application. In some countries, digestate land application is not possible during Winter Season, and regulations require digestate storage for 180 days. When this is the case, a digestate storage tank with intermittent mixing is constructed. The waste portion (J) is regularly transferred to this tank. The storage tank is covered, for example with a gas holding membrane cover. During storage there is still some additional volatile solids destruction and biogas is produced. The gas space of the digestate storage tank is connected with the digester (25).
  • In the second stage (6) there are usually undigested fibers that have gone through the process. It is important to remove these fibers from the digester (25) in the effluent digestate (D). Fibers accumulate near the surface of the digestate in the second stage (6) pushed up by gas bubbles. The second stage (6) effluent digestate pumping system preferably has two inlet ports with selection between them provided by a valve (33). An upper inlet port (21) is near the surface of the digestate and removes digestate with higher fiber content. This digestate typically goes to the dewatering unit (18). A second, lower, inlet port (20) is located in the lower half of the second stage (6), preferably just above the bottom. This lower port (20) removes digestate with less fiber and lower solids content. This digestate may be treated as waste portion (J) digestate that goes to a digestate storage tank or fields for land application, or it may be returned to the first stage (5) for dilution if needed.
  • The digester (25) may operate with about one meter of head space above the liquid level. The head spaces of the first stage (5) and second stage (6) are connected with large openings (12) through the internal wall (28), such that the membrane cover (13) of the second stage (6) allows constant pressure storage of the gas produced in both stages. Biogas (E) is extracted from connections in the service boxes (10). This provides adequate distance from the free surface of the digestate to the gas outlet, which limits the potential for foam carryover. The gas pressure is boosted for use in engines, other combined heat and power (CHP) generation systems, or systems to upgrade the biogas to pipeline quality renewable natural gas.
  • The passageway (29) has an inlet near the bottom of the first stage (5). Flow through the passageway (29) may be by gravity with the first stage digestate (C) flowing through an internal riser portion (9) of the passageway into the second stage (6) driven by the differential head of the digestate in the two tanks. The free surface of the digestate is usually about 20 to 30 cm higher in the first stage (5). When the solids content of the first stage digestate (C) is higher than about 12% in mesophilic operation, it is too viscous and the small head differential across the internal wall (18) is not sufficient to overcome friction losses in the passageway (29). In this case, the flow is helped by pressurizing and injecting a controlled amount of biogas near the bottom of the riser portion (9) to create a gas lift pump. Optionally, an chopper pump my be used to transfer digestate from the first (5) to the second stage (6).
  • The second stage (6) operates generally like a CSTR. A second set of mixers (7) installed around the perimeter of the internal wall (18) generate a swirling motion in the second stage (6), and also provide vertical mixing as shown by the arrows in FIGS. 1 and 2. The rotors (8) are pointed toward the center of the tank (27) but with a 5 to 10 degree offset. This produces the swirl or spinning motion. The second stage (6) requires three 22 kW mixers (7) for diameters between 16 and 32 meters and depths from 8 to 12 m, when operating with 8 to 10% solids content in either the thermo- or meso-philic range. Higher solids content may require four mixers (7). If the digestate is more than 6 m deep, some rotors (8) may be placed are at a higher level. If the digestate is 6 m deep or less, all rotors (18) at located about one third up from the bottom.
  • In the second stage (6), digestion continues and the solids content of the digestate lowers. All second set mixers (7) operate intermittently at the same time. Mixing may occur for 10 or 15 minutes every 30 to 60 minutes, preferably and after mixing in the first stage (5) occurs. This way, the same hydraulic power units employed to power the first set of mixers (7) can be used to power the second set of mixers (7). Other mixing regimes can also be programmed in the control system depending on the type of substrate. Digestate is taken from the second stage tank (6) by pump (14) through inlet ports (20) or (21).
  • Anaerobic digestion is an exothermic process. In high solids digesters the significant energy density of the substrate and the reduced amount of water added for dilution result in a noticeable temperature increase compared to the temperature of the substrate (A), (B). The tank (27) has insulation on the external wall. The tank-in-tank configuration, particularly when constructed with concrete, reduces heat losses from the internal tank, as the internal wall (18) and outer ring act insulators. However, heating may be required and can be provided using hot water heating pipes installed inside the tank (27), along the outer wall and the internal wall (18). Hot water, for example from a combined heat and power (CHP) unit burning the biogas (E), is circulated through the heating pipes. Other configurations, for example with external tube-in-tube heat exchangers (HEX) with large openings are also possible. In this case second stage tank digestate is pumped from the bottom half of the tank (27) through a HEX, where heat is transferred from hot water produced by the CHP unit or a hot water boiler. Heated second stage digestate is circulated into the first stage digester. This contributes to dilute the first stage solids content and to transport heat.
  • The system 100 described above is merely one example of an anaerobic digestion system and is not meant to limit the invention. The invention is defined by the following claims.

Claims (18)

What is claimed is:
1. An anaerobic digester comprising,
a) a covered cylindrical tank; and
b) an interior wall dividing the cylindrical tank into an outer portion and a cylindrical inner portion.
2. The digester of claim 1 further comprising a passageway between the outer portion and the inner portion.
3. The digester of claim 1 wherein the outer portion is ring shaped.
4. The digester of claim 1 further comprising a set of mixers spaced around the outer portion and oriented to direct digestate in one direction around the outer portion.
5. The digester of claim 1 further comprising an inlet for adding a substrate to the outer portion.
6. The digester of claim 5 wherein a first of the set of mixers located closest to the inlet in the one direction has a mixing blade that is located higher than the mixing blades of other mixers in the set of mixers.
7. The digester of claim 6 wherein the height of the mixing blades decreases from the height of the mixing blades of the first mixer along the one direction.
8. The digester of claim 1 further comprising a side stream in which digestate is withdrawn from a location within one meter of the free surface of the digestate in the outer portion and the withdrawn digestate is returned to the outer portion at a lower elevation than the withdrawal location.
9. The digester of claim 8 wherein the withdrawn digestate is returned to the outer portion at a position displaced in the one direction away from the withdrawal location.
10. The digester of claim 8 wherein the side stream comprises a chopper pump.
11. The digester of claim 8 wherein an inlet to the side stream comprises a crust breaker.
12. The digester of claim 1 wherein the outer portion has at least 40% of the volume of the digester.
13. The digester of claim 1 further comprising an inlet adapted to introduce a stackable substrate into the outer portion and further comprising a second inlet adapted to introduce a pumpable substrate into the outer portion.
14. The digester of claim 2 wherein the passageway comprises a riser such that digestate flows upwards while moving from the outer portion to the cylindrical inner portion.
15. The digester of claim 1 further comprising an outlet for removing substrate from the outer portion.
16. The digester of claim 1 further comprising an inlet for adding a substrate to the outer portion and an outlet for removing substrate from the outer portion.
17. The digester of claim 16 wherein the outlet is downstream from the inlet.
18. The digester of claim 1 wherein the inner portion is an undivided inner portion.
US17/039,907 2011-10-19 2020-09-30 Multiple tank high solids anaerobic digester Pending US20210079429A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US17/039,907 US20210079429A1 (en) 2011-10-19 2020-09-30 Multiple tank high solids anaerobic digester

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161548919P 2011-10-19 2011-10-19
PCT/CA2011/001315 WO2013056337A1 (en) 2011-10-19 2011-11-30 Multiple tank high solids anaerobic digester
US201414352477A 2014-12-10 2014-12-10
US15/628,189 US10829788B2 (en) 2011-10-19 2017-06-20 Multiple tank high solids anaerobic digester
US17/039,907 US20210079429A1 (en) 2011-10-19 2020-09-30 Multiple tank high solids anaerobic digester

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US15/628,189 Continuation US10829788B2 (en) 2011-10-19 2017-06-20 Multiple tank high solids anaerobic digester

Publications (1)

Publication Number Publication Date
US20210079429A1 true US20210079429A1 (en) 2021-03-18

Family

ID=48140252

Family Applications (3)

Application Number Title Priority Date Filing Date
US14/352,477 Active 2032-05-14 US9719111B2 (en) 2011-10-19 2011-11-30 Multiple tank high solids anaerobic digester
US15/628,189 Active 2032-03-06 US10829788B2 (en) 2011-10-19 2017-06-20 Multiple tank high solids anaerobic digester
US17/039,907 Pending US20210079429A1 (en) 2011-10-19 2020-09-30 Multiple tank high solids anaerobic digester

Family Applications Before (2)

Application Number Title Priority Date Filing Date
US14/352,477 Active 2032-05-14 US9719111B2 (en) 2011-10-19 2011-11-30 Multiple tank high solids anaerobic digester
US15/628,189 Active 2032-03-06 US10829788B2 (en) 2011-10-19 2017-06-20 Multiple tank high solids anaerobic digester

Country Status (4)

Country Link
US (3) US9719111B2 (en)
EP (1) EP2768965B1 (en)
DE (1) DE202011110507U1 (en)
WO (1) WO2013056337A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202011110507U1 (en) * 2011-10-19 2014-06-03 Anaergia Inc. Multiple anaerobic fermenter for high solids content
CN105441317B (en) * 2016-01-07 2017-10-27 江苏省农业科学院 For the continuous dynamic anaerobic ferment devices of multi-element material high concentration and its application
CA3023182C (en) 2016-05-17 2023-04-04 Anaergia Inc. Sewage sludge processing with multi-stage thermophilic digester
DE102017010229A1 (en) * 2017-11-06 2019-05-09 Michael Niederbacher Plug flow fermenter of a biogas plant
US11739016B2 (en) 2018-10-10 2023-08-29 3D Renewables, LLC Automated zero waste systems and methods
US11111168B1 (en) * 2020-04-07 2021-09-07 Ovivo Inc. Tank with membrane cover and draft tube mixer
FR3120234B1 (en) 2021-02-26 2023-08-04 Methamax Device for biogas production tank or pre-pit with multifunction pump

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5275722A (en) * 1992-02-25 1994-01-04 Beard Harold J Oxidation ditch wastewater treatment and denitrification system
DE19714342C1 (en) * 1997-04-08 1998-10-01 Uts Umwelt Technik Sued Gmbh Methane gas generator assembly has raised enclosed gas-sealed dome
US6592762B2 (en) * 2001-08-29 2003-07-15 United States Filter Corporation Process for treating BOD-containing wastewater
EP1717305A1 (en) * 2005-04-25 2006-11-02 U.T.S. Umwelt-Technik-Süd GmbH Manhole for a fermenter in a biogas facility
US20060289356A1 (en) * 2005-05-13 2006-12-28 Burnett Clyde H Digesters
DE102007005069A1 (en) * 2007-01-26 2008-07-31 Uts Biogastechnik Gmbh Biogas plant for continuous single step working process, has main fermenter container and post fermenter container, where both containers have gas proof container cover and gas tank, and are assembled in fermenter network
EP2270128A1 (en) * 2009-06-29 2011-01-05 Uts Biogastechnik Gmbh Biogas facility and manhole for a biogas facility
US20140329306A1 (en) * 2011-11-17 2014-11-06 Anaergia Inc. Anaerobic digester service device with a separation curtain
US10829788B2 (en) * 2011-10-19 2020-11-10 Anaergia Inc. Multiple tank high solids anaerobic digester

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2430519A (en) * 1942-03-19 1947-11-11 Edward B Mallory Regenerative digester
FR2481874A1 (en) * 1980-05-12 1981-11-13 Rambaud Michel Methane prodn. plant utilising fermenting organic waste - has aerobic pre-fermentation zone inside anaerobic vessel
US4323367A (en) * 1980-06-23 1982-04-06 Institute Of Gas Technology Gas production by accelerated in situ bioleaching of landfills
SU1599320A1 (en) * 1988-11-21 1990-10-15 Харьковский политехнический институт им.В.И.Ленина Methane tank
JP4304348B2 (en) 1997-09-22 2009-07-29 独立行政法人理化学研究所 DNA isolation method
US6342378B1 (en) 1998-08-07 2002-01-29 The Regents Of The University Of California Biogasification of solid waste with an anaerobic-phased solids-digester system
US20020105855A1 (en) * 2001-01-24 2002-08-08 Richard Behnke Storage/treatment tank mixing system
US6982035B1 (en) 2004-03-29 2006-01-03 O'keefe David M Biphase orbicular biodigester
US7160457B2 (en) * 2004-10-07 2007-01-09 Black & Veatch Holding Corp. Digester cover
AT503653B1 (en) 2006-09-21 2007-12-15 Arc Austrian Res Centers Gmbh Biogas production plant with two fermentation chambers, includes gas line from first chamber into riser tube in second chamber, to induce circulation and mixing of fermentation medium
BE1017390A3 (en) 2006-12-07 2008-08-05 Organic Waste Systems Nv METHOD AND APPARATUS FOR ANAEROBIC CONFIGURATION OF ORGANIC MATERIAL.
EP1985692A1 (en) 2007-04-23 2008-10-29 UTS Biogastechnik GmbH Biogas facility for producing biogas in a single step flow method
US8759068B2 (en) * 2008-01-02 2014-06-24 Missing Link Technologies, L.L.C. System for fermentation using algae

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5275722A (en) * 1992-02-25 1994-01-04 Beard Harold J Oxidation ditch wastewater treatment and denitrification system
DE19714342C1 (en) * 1997-04-08 1998-10-01 Uts Umwelt Technik Sued Gmbh Methane gas generator assembly has raised enclosed gas-sealed dome
US6592762B2 (en) * 2001-08-29 2003-07-15 United States Filter Corporation Process for treating BOD-containing wastewater
EP1717305A1 (en) * 2005-04-25 2006-11-02 U.T.S. Umwelt-Technik-Süd GmbH Manhole for a fermenter in a biogas facility
US20060289356A1 (en) * 2005-05-13 2006-12-28 Burnett Clyde H Digesters
DE102007005069A1 (en) * 2007-01-26 2008-07-31 Uts Biogastechnik Gmbh Biogas plant for continuous single step working process, has main fermenter container and post fermenter container, where both containers have gas proof container cover and gas tank, and are assembled in fermenter network
EP2270128A1 (en) * 2009-06-29 2011-01-05 Uts Biogastechnik Gmbh Biogas facility and manhole for a biogas facility
US10829788B2 (en) * 2011-10-19 2020-11-10 Anaergia Inc. Multiple tank high solids anaerobic digester
US20140329306A1 (en) * 2011-11-17 2014-11-06 Anaergia Inc. Anaerobic digester service device with a separation curtain

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
Machine Translation of DE 102007005069 A1 (Year: 2022) *
Machine translation of EP 2270128 A1 (Year: 2023) *
Translation of DE 19714342 C1 (Year: 2023) *
Translation of EP 1717305 A1 (Year: 2023) *

Also Published As

Publication number Publication date
EP2768965B1 (en) 2022-09-28
DE202011110507U1 (en) 2014-06-03
US9719111B2 (en) 2017-08-01
EP2768965A1 (en) 2014-08-27
US20170283833A1 (en) 2017-10-05
US10829788B2 (en) 2020-11-10
US20150111271A1 (en) 2015-04-23
EP2768965A4 (en) 2015-05-27
WO2013056337A1 (en) 2013-04-25

Similar Documents

Publication Publication Date Title
US20210079429A1 (en) Multiple tank high solids anaerobic digester
KR101092017B1 (en) The Working Method of Continuous Thermophilic Anaerobic Co-Phase Digestion System using Waste Activated Sludge
CN108998359B (en) Anaerobic reactor for producing biogas by mixed fermentation of pig manure and straws
US9409806B2 (en) System and method for thermophilic anaerobic digester process
US11312932B2 (en) Method and device for producing biogas
WO2012005833A1 (en) Organic substrate treatment system
EP2831003B1 (en) Apparatus for the production of biogas and related method
US10005995B2 (en) System and method for thermophilic anaerobic digester process
US20120171742A1 (en) Method and Apparatus for Treating Fermentable Substances
US7927848B2 (en) Method and apparatus for production of biogas from an organic material
CN107683329A (en) Improved biogas production system and preparation method thereof
RU2399184C1 (en) Biogas complex
CN114214175A (en) Dry-type anaerobic fermentation device and method for straws
KR101278514B1 (en) Methane gas production system using multi-stage anaerobic digester
CN220643084U (en) Back mixing and discharging device for dry anaerobic system
RU2427998C1 (en) Biogas complex
CN219399985U (en) Pretreatment system for mixed, homogenized and continuous feeding of multi-element raw materials for anaerobic fermentation
CN212560231U (en) Two-phase dry type fermentation biogas production device for organic waste
RU108446U1 (en) Biogas plant for anaerobic digestion of organic waste
CN217202699U (en) Dry-type anaerobic fermentation device for straws
DE102011012285B4 (en) Hybrid fermentation
RU97026U1 (en) BIOGAS COMPLEX
Kurmanov The biogas production effectiveness increase
CN114008004A (en) Anaerobic biogas facility and digestion process
RU85293U1 (en) BIOGAS COMPLEX

Legal Events

Date Code Title Description
AS Assignment

Owner name: ANAERGIA INC., CANADA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:JOSSE, JUAN CARLOS;FRIEDL, CHRISTIAN;BAYER, MARTIN;SIGNING DATES FROM 20170608 TO 20170621;REEL/FRAME:055702/0452

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED