US20200368858A1 - Method for manufacturing high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption - Google Patents
Method for manufacturing high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption Download PDFInfo
- Publication number
- US20200368858A1 US20200368858A1 US16/421,779 US201916421779A US2020368858A1 US 20200368858 A1 US20200368858 A1 US 20200368858A1 US 201916421779 A US201916421779 A US 201916421779A US 2020368858 A1 US2020368858 A1 US 2020368858A1
- Authority
- US
- United States
- Prior art keywords
- protective paper
- functions
- heat dissipation
- manufacturing
- heat conduction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001681 protective effect Effects 0.000 title claims abstract description 31
- 230000017525 heat dissipation Effects 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000002131 composite material Substances 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 8
- 238000005096 rolling process Methods 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 4
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- 239000002041 carbon nanotube Substances 0.000 claims description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 4
- ILZSSCVGGYJLOG-UHFFFAOYSA-N cobaltocene Chemical compound [Co+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 ILZSSCVGGYJLOG-UHFFFAOYSA-N 0.000 claims description 4
- KZPXREABEBSAQM-UHFFFAOYSA-N cyclopenta-1,3-diene;nickel(2+) Chemical compound [Ni+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KZPXREABEBSAQM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 230000005670 electromagnetic radiation Effects 0.000 description 4
- 230000020169 heat generation Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000005574 cross-species transmission Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0073—Shielding materials
- H05K9/0081—Electromagnetic shielding materials, e.g. EMI, RFI shielding
- H05K9/0084—Electromagnetic shielding materials, e.g. EMI, RFI shielding comprising a single continuous metallic layer on an electrically insulating supporting structure, e.g. metal foil, film, plating coating, electro-deposition, vapour-deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C3/00—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
- B05C3/02—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
- B05C3/12—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length
- B05C3/125—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length the work being a web, band, strip or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
- B23P15/26—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass heat exchangers or the like
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/02—Constructions of heat-exchange apparatus characterised by the selection of particular materials of carbon, e.g. graphite
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/2039—Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0073—Shielding materials
- H05K9/0081—Electromagnetic shielding materials, e.g. EMI, RFI shielding
- H05K9/0083—Electromagnetic shielding materials, e.g. EMI, RFI shielding comprising electro-conductive non-fibrous particles embedded in an electrically insulating supporting structure, e.g. powder, flakes, whiskers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0073—Shielding materials
- H05K9/0081—Electromagnetic shielding materials, e.g. EMI, RFI shielding
- H05K9/009—Electromagnetic shielding materials, e.g. EMI, RFI shielding comprising electro-conductive fibres, e.g. metal fibres, carbon fibres, metallised textile fibres, electro-conductive mesh, woven, non-woven mat, fleece, cross-linked
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P2700/00—Indexing scheme relating to the articles being treated, e.g. manufactured, repaired, assembled, connected or other operations covered in the subgroups
- B23P2700/10—Heat sinks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4935—Heat exchanger or boiler making
Definitions
- the present invention relates to a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption, which enables to increases efficiency of 3-dimensional heat dissipation and conduction and to significantly absorb electromagnetic radiation.
- the object of the present invention is to provide a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption, which enables to increase efficiency of 3-dimensional heat dissipation and conduction and is to absorb electromagnetic radiation.
- FIG. 1 is a flow chart showing equipment used in the present invention
- FIG. 2 is a flow chart showing a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption according to the present invention.
- FIG. 1 and FIG. 2 a flow chart showing equipment used in the present invention and a flow chart showing a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption according to the present invention are disclosed.
- the method comprises the following steps of:
- thermal conductive composite is made by is made by fully mixing one or more of graphene oxide, expanded graphite and oxidized carbon nanotube with a metal salt and a nano-scale magnetic metal oxide, and wherein the metal salt is one or more of iron, cobalt, nickel, organic iron, organic nickel, organic cobalt, ferrocene, nickelocene and cobaltocene;
- step (d) synchronously driving a roller for rolling the hybrid material by a rolling mechanism ( 4 ) to form a protective paper having a dense structure; preferably, the step (d) is repeated several times to achieve the dense structure;
- the protective paper has the metal salt, e.g. one or more of iron, cobalt, nickel, organic iron, organic nickel, organic cobalt, ferrocene, nickelocene, cobaltocene and the like, which can be decomposed into pure iron, cobalt or nickel at a high temperature to act as a catalyst for the graphene oxide, expanded graphite or oxidized carbon nanotube.
- the protective paper can form long graphene or carbon nanotube by a higher temperature of at least 400° C., so that the protective paper has a higher and long-lasting elasticity, which can rebound at least 50%. Accordingly, the protective paper can be reused and has high efficiency of 3-dimensional heat dissipation and conduction as well as efficient absorption of electromagnetic radiation.
- the present invention has the advantages of improving efficiency of 3-dimensional heat dissipation and conduction of the electronic components and significantly absorbing electromagnetic radiation, so the present invention has increased practicality for the overall implementation
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Thermal Sciences (AREA)
- Electromagnetism (AREA)
- General Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
Abstract
Description
- The present invention relates to a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption, which enables to increases efficiency of 3-dimensional heat dissipation and conduction and to significantly absorb electromagnetic radiation.
- With the rapid development of technology, the volume of electronic components tends to be decreased, and the density and performance of electronic components per unit area become increased. As a result, a total heat generation of the electronic component is yearly increased, and a traditional heat dissipating device cannot afford to dissipate the total heat generation quickly. If the heat generated by the electronic component is not removed efficiently, it will leads to an electronic ionization and a thermal stress situation of the electronic component, which reduces an overall stability and a service life of the electronic component. Accordingly, it is imperative to dissipate the heat generated from the electronic component to prevent a overheat situation thereof In addition, constantly increasing the frequency and transmission speed of electronic components also results in serious situations of electromagnetic interference and electromagnetic wave spillover.
- In view of the above-mentioned problems, the object of the present invention is to provide a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption, which enables to increase efficiency of 3-dimensional heat dissipation and conduction and is to absorb electromagnetic radiation.
-
FIG. 1 is a flow chart showing equipment used in the present invention; -
FIG. 2 is a flow chart showing a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption according to the present invention. - Hereinafter, an exemplary embodiment of the present invention will be described in detail with reference to the accompanying drawings.
- As showed in
FIG. 1 andFIG. 2 , a flow chart showing equipment used in the present invention and a flow chart showing a method for manufacturing a high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption according to the present invention are disclosed. The method comprises the following steps of: - (a) transferring a substrate by a feeding mechanism (1), wherein the substrate is a fiber mesh fabric, a non-woven fabric, a carbon fiber fabric or a carbon fiber non-woven fabric;
- (b) evenly distributing a thermal conductive composite in a feed tank (2) over the substrate to form a hybrid material, wherein the thermal conductive composite is made by is made by fully mixing one or more of graphene oxide, expanded graphite and oxidized carbon nanotube with a metal salt and a nano-scale magnetic metal oxide, and wherein the metal salt is one or more of iron, cobalt, nickel, organic iron, organic nickel, organic cobalt, ferrocene, nickelocene and cobaltocene;
- (c) leveling the hybrid material by a leveling mechanism (3) to flat a surface of the hybrid material;
- (d) synchronously driving a roller for rolling the hybrid material by a rolling mechanism (4) to form a protective paper having a dense structure; preferably, the step (d) is repeated several times to achieve the dense structure;
- (e) rolling up the protective paper by a receiving mechanism (5); and
- (f) cutting the protective paper into a size as needed to be further placed inside a vacuum furnace, evacuating the vacuum furnace to have a negative pressure of at least 0.001 Pa, heating the vacuum furnace to a temperature of at least 400° C. at a heating rate of 50° C. per minute, maintaining the temperature of at least 400° C. for at least 4 hours in the vacuum furnace, and naturally cooling the protective paper down to a temperature of 100° C. As a result, the preparation of the protective paper is completed, and the prepared protective paper is taken out from the vacuum furnace.
- The protective paper has the metal salt, e.g. one or more of iron, cobalt, nickel, organic iron, organic nickel, organic cobalt, ferrocene, nickelocene, cobaltocene and the like, which can be decomposed into pure iron, cobalt or nickel at a high temperature to act as a catalyst for the graphene oxide, expanded graphite or oxidized carbon nanotube. Additionally, in a carbon source environment, the protective paper can form long graphene or carbon nanotube by a higher temperature of at least 400° C., so that the protective paper has a higher and long-lasting elasticity, which can rebound at least 50%. Accordingly, the protective paper can be reused and has high efficiency of 3-dimensional heat dissipation and conduction as well as efficient absorption of electromagnetic radiation.
- Compared with the technique available now, the present invention has the advantages of improving efficiency of 3-dimensional heat dissipation and conduction of the electronic components and significantly absorbing electromagnetic radiation, so the present invention has increased practicality for the overall implementation
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US16/421,779 US10857632B1 (en) | 2019-05-24 | 2019-05-24 | Method for manufacturing high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US16/421,779 US10857632B1 (en) | 2019-05-24 | 2019-05-24 | Method for manufacturing high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption |
Publications (2)
Publication Number | Publication Date |
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US20200368858A1 true US20200368858A1 (en) | 2020-11-26 |
US10857632B1 US10857632B1 (en) | 2020-12-08 |
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US16/421,779 Active 2039-08-19 US10857632B1 (en) | 2019-05-24 | 2019-05-24 | Method for manufacturing high-efficiency protective paper having functions of heat dissipation, heat conduction and electromagnetic absorption |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113816365A (en) * | 2021-06-24 | 2021-12-21 | 浙江理工大学 | Graphene film preparation method |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5284701A (en) * | 1991-02-11 | 1994-02-08 | Ashland Oil, Inc. | Carbon fiber reinforced coatings |
US20120282453A1 (en) * | 2011-05-05 | 2012-11-08 | North Carolina State University | Carbon nanotube composites and methods and apparatus for fabricating same |
US9486821B2 (en) * | 2012-09-28 | 2016-11-08 | Nissan Motor Co., Ltd. | Coating apparatus for applying coating material onto sheet member |
US8871296B2 (en) * | 2013-03-14 | 2014-10-28 | Nanotek Instruments, Inc. | Method for producing conducting and transparent films from combined graphene and conductive nano filaments |
US10109386B2 (en) * | 2013-05-17 | 2018-10-23 | Heraeus Medical Components Llc | Impregnation of a non-conductive material with an intrinsically conductive polymer through in-situ polymerization |
US20160215441A1 (en) * | 2013-08-09 | 2016-07-28 | Florida State University Research Foundation, Inc. | Conductive Composite Materials Containing Multi-Scale High Conductive Particles and Methods |
US20150274924A1 (en) * | 2014-04-01 | 2015-10-01 | Council Of Scientific & Industrial Research | Electrostatic dissipative foams and process for the preparation thereof |
US9793024B2 (en) * | 2015-07-22 | 2017-10-17 | The Boeing Company | Electrically conductive coating materials, electrically conductive coating systems, and methods including the same |
US10758936B2 (en) * | 2015-12-08 | 2020-09-01 | The Boeing Company | Carbon nanomaterial composite sheet and method for making the same |
CN107474290A (en) * | 2017-08-25 | 2017-12-15 | 中信戴卡股份有限公司 | A kind of method for Treatment of Carbon composite material surface |
US11492708B2 (en) * | 2018-01-29 | 2022-11-08 | The Boeing Company | Cold spray metallic coating and methods |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113816365A (en) * | 2021-06-24 | 2021-12-21 | 浙江理工大学 | Graphene film preparation method |
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