US20200330828A1 - Multi-piece solid golf ball - Google Patents

Multi-piece solid golf ball Download PDF

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Publication number
US20200330828A1
US20200330828A1 US16/843,263 US202016843263A US2020330828A1 US 20200330828 A1 US20200330828 A1 US 20200330828A1 US 202016843263 A US202016843263 A US 202016843263A US 2020330828 A1 US2020330828 A1 US 2020330828A1
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United States
Prior art keywords
ball
hardness
core
shore
golf ball
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US16/843,263
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English (en)
Inventor
Hideo Watanabe
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Bridgestone Sports Co Ltd
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Bridgestone Sports Co Ltd
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Assigned to BRIDGESTONE SPORTS CO., LTD. reassignment BRIDGESTONE SPORTS CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: WATANABE, HIDEO
Publication of US20200330828A1 publication Critical patent/US20200330828A1/en
Abandoned legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/007—Characteristics of the ball as a whole
    • A63B37/0077—Physical properties
    • A63B37/0087—Deflection or compression
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/0022—Coatings, e.g. paint films; Markings
    • A63B37/00222—Physical properties, e.g. hardness
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/0023—Covers
    • A63B37/0029—Physical properties
    • A63B37/0031—Hardness
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/005—Cores
    • A63B37/006—Physical properties
    • A63B37/0062—Hardness
    • A63B37/0063—Hardness gradient
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/005—Cores
    • A63B37/006—Physical properties
    • A63B37/0065—Deflection or compression
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/007—Characteristics of the ball as a whole
    • A63B37/0077—Physical properties
    • A63B37/0092—Hardness distribution amongst different ball layers
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/007—Characteristics of the ball as a whole
    • A63B37/0077—Physical properties
    • A63B37/0092—Hardness distribution amongst different ball layers
    • A63B37/00921—Hardness distribution amongst different ball layers whereby hardness of the cover is higher than hardness of the intermediate layers
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/005—Cores
    • A63B37/006—Physical properties
    • A63B37/0062—Hardness
    • A63B37/00621—Centre hardness
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/005—Cores
    • A63B37/006—Physical properties
    • A63B37/0062—Hardness
    • A63B37/00622—Surface hardness
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00—Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003—Golf balls
    • A63B37/007—Characteristics of the ball as a whole
    • A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
    • A63B37/0075—Three piece balls, i.e. cover, intermediate layer and core

Definitions

  • This invention relates to a golf ball having a core, an intermediate layer and a cover which is intended for amateur golfers whose head speeds are not fast.
  • a multi-piece solid golf ball having a core, an intermediate layer and a cover when the ball has a basic structure wherein a polyurethane material is used as the resin material of the cover and the deflection of the ball when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf) is at least 3.6 mm, that is, when the golf ball is of a type that has a relatively low compression and a urethane cover, and moreover when the golf ball is produced in such a way that the ball has a surface hardness on the Shore C hardness scale which is higher than that of the sphere consisting of the core encased by the intermediate layer (intermediate layer-encased sphere), the golf ball exhibits a good flight performance when hit with a driver (W#1) or a number six iron (middle/long iron) by golfers whose head speeds are not fast, enables a good, soft feel to be obtained
  • the invention provides a multi-piece solid golf ball having a core, an intermediate layer and a cover, wherein the cover is formed primarily of a polyurethane material, the ball has a higher surface hardness on the Shore C hardness scale than the sphere obtained by encasing the core with the intermediate layer (intermediate layer-encased sphere), and the ball has a deflection of at least 3.6 mm when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf).
  • the core has a surface hardness and a center hardness such that the difference therebetween, expressed on the Shore C hardness scale, is at least 16.
  • the core has a deflection of at least 3.8 mm when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf).
  • the time t 1 required from contact initiation between the driver and the ball for deformation of the ball to reach a maximum value and the time t 2 required from the state of maximum golf ball deformation for the ball and the driver to separate have a ratio t 2 /t 1 therebetween of at least 1.20.
  • the sum of deformation times t 1 and t 2 is preferably from 660 to 800 microseconds.
  • the cover has a surface on which a coating layer is formed, which coating layer has a Shore C hardness of from 50 to 70.
  • the value obtained by subtracting the Shore C hardness of the coating layer from the core center hardness (Shore C hardness) is preferably at least 0.
  • the golf ball of the invention has an excellent flight performance when struck by golfers whose head speeds are not very fast and moreover has a good, soft feel at impact, making it suitable for use by amateur golfers.
  • the golf ball of the invention does not scuff easily, enabling its prolonged use.
  • FIG. 1 is a schematic cross-sectional view of a golf ball according to an embodiment of the invention.
  • the multi-piece solid golf ball of the invention has a core, an intermediate layer and a cover.
  • the golf ball G has a core 1 , an intermediate layer 2 encasing the core 1 , and a cover 3 encasing the intermediate layer 2 .
  • the cover 3 serves as the outermost layer in the layer structure of the golf ball. Numerous dimples D are typically formed on the surface of the cover (outermost layer) 3 so as to enhance the aerodynamic properties of the ball.
  • a coating layer 4 is formed on the surface of the cover 3 .
  • the core has a diameter which is preferably at least 37.1 mm, more preferably at least 37.7 mm, and even more preferably at least 38.1 mm.
  • the upper limit is preferably 39.9 mm or less, more preferably 39.3 mm or less, and even more preferably 38.7 mm or less.
  • the core has a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf) which, although not particularly limited, is preferably at least 3.8 mm, more preferably at least 4.2 mm, and even more preferably at least 4.5 mm.
  • the upper limit is preferably 6.0 mm or less, more preferably 5.8 mm or less, and even more preferably 5.5 mm or less.
  • the core deflection is too large, i.e., when the core is too soft, the rebound may be too low, resulting in a poor flight, the feel at impact may be too soft, or the durability to cracking on repeated impact may worsen.
  • the core hardnesses mentioned below refer to values on the Shore C hardness scale. These Shore C hardnesses are hardness values measured with a Shore C durometer in general accordance with ASTM D2240.
  • the core has a center hardness (Cc) which is preferably at least 46, more preferably at least 48, and even more preferably at least 50.
  • Cc center hardness
  • the upper limit is preferably 60 or less, more preferably 58 or less, and even more preferably 56 or less.
  • the core has a surface hardness (Cs) which is preferably at least 64, more preferably at least 66, and even more preferably at least 68.
  • the upper limit is preferably 80 or less, more preferably 77 or less, and even more preferably 75 or less. Hardnesses outside of this range may lead to the same undesirable results as mentioned above for the core center hardness (Cc).
  • the difference between the core surface hardness (Cs) and the core center hardness (Cc) is preferably at least 16, more preferably at least 17, and even more preferably at least 18.
  • the upper limit is preferably 30 or less, more preferably 25 or less, and even more preferably 20 or less. When this value is too small, the ball spin rate-lowering effect on shots with a driver is inadequate, as a result of which a good distance may not be achieved.
  • the core is formed of a single layer or a plurality of layers of rubber material.
  • a rubber composition can be prepared as this core-forming rubber material by using a base rubber as the chief component and including together with this other ingredients such as a co-crosslinking agent, an organic peroxide, an inert filler and an organosulfur compound. It is preferable to use polybutadiene as the base rubber.
  • polystyrene-butadiene rubbers examples include BR01, BR51 and BR730 (all products of JSR Corporation).
  • the proportion of polybutadiene within the base rubber is preferably at least 60 wt %, and more preferably at least 80 wt %.
  • Rubber ingredients other than the above polybutadienes may be included in the base rubber, provided that doing so does not detract from the advantageous effects of the invention.
  • rubber ingredients other than the above polybutadienes include other polybutadienes and also other diene rubbers, such as styrene-butadiene rubbers, natural rubbers, isoprene rubbers and ethylene-propylene-diene rubbers.
  • co-crosslinking agents examples include unsaturated carboxylic acids and metal salts of unsaturated carboxylic acids.
  • unsaturated carboxylic acids include acrylic acid, methacrylic acid, maleic acid and fumaric acid. The use of acrylic acid or methacrylic acid is especially preferred.
  • Metal salts of unsaturated carboxylic acids are exemplified by, without particular limitation, the above unsaturated carboxylic acids that have been neutralized with desired metal ions.
  • Specific examples include the zinc salts and magnesium salts of methacrylic acid and acrylic acid. The use of zinc acrylate is especially preferred.
  • the unsaturated carboxylic acid and/or metal salt thereof is included in an amount, per 100 parts by weight of the base rubber, which is typically at least 5 parts by weight, preferably at least 10 parts by weight, and more preferably at least 13 parts by weight.
  • the amount included is typically not more than 60 parts by weight, preferably not more than 50 parts by weight, and more preferably not more than 40 parts by weight. Too much may make the core too hard, giving the ball an unpleasant feel at impact, whereas too little may lower the rebound.
  • the organic peroxide may be used as the organic peroxide.
  • examples of such products that may be suitably used include Percumyl D, Perhexa C-40 and Perhexa 3M (all from NOF Corporation), and Luperco 231XL (from AtoChem Co.). One of these may be used alone, or two or more may be used together.
  • the amount of organic peroxide included per 100 parts by weight of the base rubber is preferably at least 0.1 part by weight, more preferably at least 0.3 part by weight, even more preferably at least 0.5 part by weight, and most preferably at least 0.6 part by weight.
  • the upper limit is preferably not more than 5 parts by weight, more preferably not more than 4 parts by weight, even more preferably not more than 3 parts by weight, and most preferably not more than 2.5 parts by weight. When too much or too little is included, it may not be possible to obtain a ball having a good feel, durability and rebound.
  • an antioxidant may be optionally included.
  • suitable commercial antioxidants include Nocrac NS-6 and Nocrac NS-30 (both available from Ouchi Shinko Chemical Industry Co., Ltd.). One of these may be used alone, or two or more may be used together.
  • the amount of antioxidant included per 100 parts by weight of the base rubber is set to preferably at least 0.05 part by weight, and more preferably at least 0.1 part by weight.
  • the upper limit is set to preferably not more than 3 parts by weight, more preferably not more than 2 parts by weight, even more preferably not more than 1 part by weight, and most preferably not more than 0.5 part by weight. Too much or too little antioxidant may make it impossible to achieve a suitable ball rebound and durability.
  • organosulfur compound may be included in the core in order to impart a good resilience.
  • the organosulfur compound is not particularly limited, provided it can enhance the rebound of the golf ball.
  • Exemplary organosulfur compounds include thiophenols, thionaphthols, halogenated thiophenols, and metal salts of these.
  • pentachlorothiophenol pentafluorothiophenol, pentabromothiophenol, p-chlorothiophenol
  • the zinc salt of pentachlorothiophenol the zinc salt of pentafluorothiophenol, the zinc salt of pentabromothiophenol, the zinc salt of p-chlorothiophenol
  • any of the following having 2 to 4 sulfur atoms diphenylpolysulfides, dibenzylpolysulfides, dibenzoylpolysulfides, dibenzothiazoylpolysulfides and dithiobenzoylpolysulfides.
  • the use of the zinc salt of pentachlorothiophenol is especially preferred.
  • the amount of organosulfur compound included per 100 parts by weight of the base rubber is 0 part by weight or more, and it is recommended that the amount be preferably at least 0.1 part by weight, and more preferably at least 0.2 part by weight, and that the upper limit be preferably not more than 5 parts by weight, more preferably not more than 3 parts by weight, and even more preferably not more than 2 parts by weight.
  • Including too much organosulfur compound may make a greater rebound-improving effect (particularly on shots with a W#1) unlikely to be obtained, may make the core too soft or may worsen the feel of the ball at impact. On the other hand, including too little may make a rebound-improving effect unlikely.
  • Another compounding ingredient typically included with the base rubber is an inert filler, preferred examples of which include zinc oxide, barium sulfate and calcium carbonate. One of these may be used alone, or two or more may be used together.
  • the amount of inert filler included per 100 parts by weight of the base rubber is preferably at least 1 part by weight, and more preferably at least 5 parts by weight.
  • the upper limit is preferably not more than 50 parts by weight, more preferably not more than 40 parts by weight, and even more preferably not more than 35 parts by weight. Too much or too little inert filler may make it impossible to obtain a proper weight and a suitable rebound.
  • the core can be produced by vulcanizing/curing the rubber composition containing the above ingredients.
  • the core can be produced by intensively mixing the rubber composition using a mixing apparatus such as a Banbury mixer or a roll mill, subsequently compression-molding or injection-molding the mixture in a core mold, and then suitably heating and thereby curing the resulting molded body under conditions sufficient to allow the organic peroxide or co-crosslinking agent to act, such as at a temperature of between 100 and 200° C., preferably between 140 and 180° C., for 10 to 40 minutes.
  • the core may consist of a single layer alone, or may be formed as a two-layer core consisting of an inner core layer and an outer core layer.
  • the inner core layer and outer core layer materials may each be composed primarily of the above-described rubber material.
  • the rubber material making up the outer core layer encasing the inner core layer may be the same as or different from the inner core layer material. The details here are the same as those given above for the ingredients of the core-forming rubber material.
  • the intermediate layer has a material hardness on the Shore D hardness scale which, although not particularly limited, is preferably at least 44, more preferably at least 50, and even more preferably at least 53.
  • the upper limit is preferably not more than 60, more preferably not more than 58, and even more preferably not more than 56.
  • the Shore C hardness is preferably at least 68, more preferably at least 76, and even more preferably at least 80.
  • the upper limit is preferably not more than 89, more preferably not more than 87, and even more preferably not more than 84.
  • the sphere obtained by encasing the core with the intermediate layer (intermediate layer-encased sphere) has a surface hardness, expressed on the Shore D scale, of preferably at least 50, more preferably at least 56, and even more preferably at least 59.
  • the upper limit is preferably not more than 66, more preferably not more than 64, and even more preferably not more than 62.
  • the Shore C hardness is preferably at least 74, more preferably at least 82, and even more preferably at least 86.
  • the upper limit is preferably not more than 95, more preferably not more than 93, and even more preferably not more than 90.
  • the spin rate of the ball on full shots may rise excessively, resulting in a poor distance, or the initial velocity of the ball may be low, as a result of which a good distance may not be achieved on full shots.
  • the material and surface hardnesses are too high, the durability to cracking on repeated impact may worsen or the feel at impact may worsen.
  • the intermediate layer has a thickness of preferably at least 0.9 mm, more preferably at least 1.1 mm, and even more preferably at least 1.3 mm.
  • the upper limit in the intermediate layer thickness is preferably not more than 1.8 mm, more preferably not more than 1.6 mm, and even more preferably not more than 1.4 mm.
  • thermoplastic resins particularly ionomer resins and highly neutralized resin materials that are employed as cover stock in golf balls, may be suitably used as the material that forms the intermediate layer.
  • a commercial product may be used as the ionomer resin.
  • a high-acid ionomer resin having an acid content of at least 18 wt % blended into an ordinary ionomer resin may be used as the resin material for the cover.
  • the amount of such a high-acid ionomer resin included is too high, the durability to cracking under repeated impact may worsen.
  • the highly neutralized resin material is exemplified by resin compositions containing as the essential ingredients:
  • A a base resin of (a-1) an olefin-unsaturated carboxylic acid random copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid random copolymer mixed with (a-2) an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random terpolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random terpolymer in a weight ratio between 100:0 and 0:100, and
  • Components A to D in the intermediate layer-forming resin material described in, for example, JP-A 2010-253268 may be advantageously used as above components A to D.
  • a non-ionomeric thermoplastic elastomer may be included in the intermediate layer material.
  • the amount of non-ionomeric thermoplastic elastomer included is preferably from 0 to 50 parts by weight per 100 parts by weight of the total amount of the base resin.
  • thermoplastic elastomers include polyolefin elastomers (including polyolefins and metallocene polyolefins), polystyrene elastomers, diene polymers, polyacrylate polymers, polyamide elastomers, polyurethane elastomers, polyester elastomers and polyacetals.
  • additives may be suitably included in the intermediate layer material.
  • pigments, dispersants, antioxidants, ultraviolet absorbers and light stabilizers may be added.
  • the amount added per 100 parts by weight of the overall base resin is preferably at least 0.1 part by weight, and more preferably at least 0.5 part by weight.
  • the upper limit is preferably not more than 10 parts by weight, and more preferably not more than 4 parts by weight.
  • the cover has a material hardness on the Shore D scale which, although not particularly limited, is preferably at least 47, more preferably at least 51, and even more preferably at least 55.
  • the upper limit is preferably not more than 70, more preferably not more than 65, and even more preferably not more than 60.
  • the Shore C hardness is preferably at least 72, more preferably at least 78, and even more preferably at least 83.
  • the upper limit is preferably not more than 100, more preferably not more than 96, and even more preferably not more than 89.
  • the surface hardness of the cover (also referred to herein as the “ball surface hardness”) on the Shore D hardness scale is preferably at least 53, more preferably at least 57, and even more preferably at least 61.
  • the upper limit is preferably not more than 76, more preferably not more than 71, and even more preferably not more than 66.
  • the Shore C surface hardness is preferably at least 80, more preferably at least 86, and even more preferably at least 91.
  • the upper limit is preferably not more than 100, more preferably not more than 98, and even more preferably not more than 96.
  • the cover has a thickness of preferably at least 0.3 mm, more preferably at least 0.5 mm, and even more preferably at least 0.7 mm.
  • the upper limit in the cover thickness is preferably not more than 1.2 mm, more preferably not more than 1.0 mm, and even more preferably not more than 0.8 mm.
  • thermoplastic resins employed as cover stock in golf balls may be used as the cover material, although the use of urethane resin as the chief material is preferable to ionomer resin and the like because it does not scuff easily and the spin rate does not become too high, resulting in a superior flight.
  • a material that is composed primarily of a thermoplastic polyurethane and more preferable to form the cover of a resin composition in which the main components are (I) a thermoplastic urethane and (II) a polyisocyanate compound.
  • the weight of components (I) and (II) combined be at least 60%, and preferably at least 70%, of the overall amount of the cover-forming resin composition.
  • Components (I) and (II) are described below.
  • the thermoplastic polyurethane (I) has a structure which includes soft segments composed of a polymeric polyol (polymeric glycol) that is a long-chain polyol, and hard segments composed of a chain extender and a polyisocyanate compound.
  • the long-chain polyol serving as a starting material may be any that has hitherto been used in the art relating to thermoplastic polyurethanes, and is not particularly limited.
  • Illustrative examples include polyester polyols, polyether polyols, polycarbonate polyols, polyester polycarbonate polyols, polyolefin polyols, conjugated diene polymer-based polyols, castor oil-based polyols, silicone-based polyols and vinyl polymer-based polyols. These long-chain polyols may be used singly, or two or more may be used in combination. Of these, in terms of being able to synthesize a thermoplastic polyurethane having a high rebound resilience and excellent low-temperature properties, a polyether polyol is preferred.
  • chain extender that has hitherto been employed in the art relating to thermoplastic polyurethanes may be suitably used as the chain extender.
  • low-molecular-weight compounds with a molecular weight of 400 or less which have on the molecule two or more active hydrogen atoms capable of reacting with isocyanate groups are preferred.
  • the chain extender include 1,4-butylene glycol, 1,2-ethylene glycol, 1,3-butanediol, 1,6-hexanediol and 2,2-dimethyl-1,3-propanediol.
  • the chain extender is preferably an aliphatic diol having 2 to 12 carbon atoms, and more preferably 1,4-butylene glycol.
  • any polyisocyanate compound hitherto employed in the art relating to thermoplastic polyurethanes may be suitably used without particular limitation as the polyisocyanate compound.
  • use may be made of one or more selected from the group consisting of 4,4′-diphenylmethane diisocyanate, 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, p-phenylene diisocyanate, xylylene diisocyanate, 1,5-naphthylene diisocyanate, tetramethylxylene diisocyanate, hydrogenated xylylene diisocyanate, dicyclohexylmethane diisocyanate, tetramethylene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, norbornene diisocyanate, trimethylhexamethylene diisocyanate and dimer acid diisocyanate.
  • thermoplastic polyurethane serving as component (I).
  • Illustrative examples include Pandex® T-8295, Pandex® T-8290 and Pandex® T-8260 (all from DIC Covestro Polymer, Ltd.).
  • thermoplastic elastomer other than the above thermoplastic polyurethanes may also be optionally included as a separate component, i.e., component (III), together with above components (I) and (II).
  • component (III) By including this component (III) in the above resin blend, the flowability of the resin blend can be further improved and properties required of the golf ball cover material, such as resilience and scuff resistance, can be increased.
  • compositional ratio of above components (I), (II) and (III) is not particularly limited. However, to fully elicit the advantageous effects of the invention, the compositional ratio (I):(II):(III) is preferably in the weight ratio range of from 100:2:50 to 100:50:0, and more preferably from 100:2:50 to 100:30:8.
  • thermoplastic polyurethane various additives other than the ingredients making up the above thermoplastic polyurethane may be optionally included in this resin blend.
  • additives other than the ingredients making up the above thermoplastic polyurethane may be optionally included in this resin blend.
  • pigments, dispersants, antioxidants, light stabilizers, ultraviolet absorbers and internal mold lubricants may be suitably included.
  • multi-piece solid golf balls in which the above-described core, intermediate layer and cover (outermost layer) are formed as successive layers may be carried out by a customary method such as a known injection molding process.
  • a multi-piece golf ball can be obtained by injection-molding the intermediate layer material over the core so as to obtain an intermediate layer-encased sphere, and then injection-molding the cover material over the intermediate layer-encased sphere.
  • the golf ball can be produced by using two half-cups that have been pre-molded into hemispherical shapes to envelope the core or the intermediate layer-encased sphere with the respective encasing member (i.e., the intermediate layer or the cover) and then molding under applied heat and pressure.
  • the golf ball of the invention has a deflection when compressed under a final load of 130 kgf from an initial load of 10 kgf which is preferably at least 3.6 mm, more preferably at least 3.9 mm, and even more preferably at least 4.2 mm.
  • the upper limit is preferably not more than 5.0 mm, more preferably not more than 4.7 mm, and even more preferably not more than 4.4 mm.
  • this value is too small, the spin rate of the ball may rise excessively so that a sufficient distance is not achieved on full shots, or a soft, comfortable feel at impact may not be obtained.
  • this value is too large, the durability to cracking under repeated impact may worsen or the initial velocity on actual shots may decrease and a good distance may not be obtained, particularly on shots with a driver (W#1).
  • the value obtained by subtracting the surface hardness of the intermediate layer-encased sphere from the surface hardness of the ball, expressed on the Shore C hardness scale, must be larger than 0, and is preferably at least 2, and more preferably at least 4.
  • the upper limit in this surface hardness difference is preferably not more than 15, more preferably not more than, and even more preferably not more than 6.
  • the number of dimples arranged on the cover surface is preferably at least 250, more preferably at least 270, and even more preferably at least 300.
  • the upper limit is preferably not more than 370, more preferably not more than 350, and even more preferably not more than 340.
  • the dimple shapes may be of one type or may be a combination of two or more types suitably selected from among, for example, circular shapes, oval shapes, various polygonal shapes, dewdrop shapes and other noncircular shapes.
  • the dimple diameter may be set to from about 2.5 mm to about 6.5 mm, and the dimple depth may be set to from 0.08 mm and up to 0.30 mm.
  • the dimple coverage ratio on the spherical surface of the golf ball i.e., the dimple surface coverage SR, which is the sum of the individual dimple surface areas, each defined by the flat plane circumscribed by the edge of a dimple, as a percentage of the spherical surface area of the ball were the ball to have no dimples thereon, to be set to from 60% to 90%.
  • V 0 defined as the spatial volume of the individual dimples below the flat plane circumscribed by the dimple edge, divided by the volume of the cylinder whose base is the flat plane and whose height is the maximum depth of the dimple from the base, to be set to from 0.35 to 0.80.
  • VR the ratio of the sum of the volumes of the individual dimples, each formed below the flat plane circumscribed by the edge of a dimple, with respect to the volume of the ball sphere were the ball surface to have no dimples thereon, to be set to from 0.6 to 1.0%. Outside of the above ranges in these respective values, the resulting trajectory may not allow a good distance to be achieved and so the ball may fail to travel a fully satisfactory distance.
  • the coefficient of drag CD or the coefficient of lift CL it is preferable to suitably adjust the coefficient of drag CD or the coefficient of lift CL, and especially preferable to set the coefficient of drag CD under high-velocity conditions to a low value and the coefficient of lift CL under low-velocity conditions to a high value.
  • the coefficient of lift CL when the Reynolds number is 70,000 and the spin rate is 2,000 rpm just prior to the ball reaching the highest point on its trajectory to be held to preferably at least 70%, and more preferably at least 75%, of the coefficient of lift CL shortly before this when the Reynolds number is 80,000 and the spin rate is 2,000 rpm.
  • the coefficient of drag CD it is desirable for the coefficient of drag CD to be 0.225 or less when the Reynolds number is 180,000 and the spin rate is 2,520 rpm immediately after launch of the ball when it is struck.
  • the dimples may be configured as follows. Two neighboring non-dimple regions on the surface of the ball (which regions are referred to below as “lands”) can be made contiguous with each other at vertices thereof. Alternatively, lands having substantially concave polygonal shapes can be made contiguous, at some or all vertices thereon, with neighboring lands.
  • the length of the outer periphery of a land can be set to from 1.6 mm to 19.4 mm, and the length of the outer periphery of a dimple can be set to from 3.2 mm to 38.8 mm.
  • the entire surface of the dimple can be made a smooth curved surface.
  • a single dimple may be arranged so as to be contiguous with four or more such lands.
  • a single dimple may be arranged so as to be contiguous with six or fewer such lands.
  • the number of lands may be set to from 434 to 863.
  • the lands may be given shapes that are inscribed within triangles.
  • a coating layer may be formed on the surface of the cover.
  • This coating layer can be applied using various types of coatings. Because the coating must be capable of enduring the harsh conditions of golf ball use, it is desirable to use a coating composition in which the chief component is a urethane coating composed of a polyol and a polyisocyanate.
  • the polyol component is exemplified by acrylic polyols and polyester polyols. These polyols include modified polyols. To further increase workability, other polyols may also be added.
  • polyester polyols it is suitable to use two types of polyester polyols together as the polyol component.
  • a polyester polyol in which a cyclic structure has been introduced onto the resin skeleton may be used as the polyester polyol of component (a).
  • polyester polyols obtained by the polycondensation of a polyol having an alicyclic structure, such as cyclohexane dimethanol, with a polybasic acid and polyester polyols obtained by the polycondensation of a polyol having an alicyclic structure with a diol or triol and a polybasic acid.
  • a polyester polyol having a branched structure may be used as the polyester polyol of component (b).
  • polyester polyols having a branched structure such as NIPPOLAN 800 from Tosoh Corporation.
  • the polyisocyanate is exemplified by, without particular limitation, commonly used aromatic, aliphatic, alicyclic and other polyisocyanates. Specific examples include tolylene diisocyanate, diphenylmethane diisocyanate, xylylene diisocyanate, tetramethylene diisocyanate, hexamethylene diisocyanate, lysine diisocyanate, isophorone diisocyanate, 1,4-cyclohexylene diisocyanate, naphthalene diisocyanate, trimethylhexamethylene diisocyanate, dicyclohexylmethane diisocyanate and 1-isocyanato-3,3,5-trimethyl-4-isocyanatomethylcyclohexane. These may be used singly or in admixture.
  • organic solvents may be mixed into the coating composition.
  • organic solvents include aromatic solvents such as toluene, xylene and ethylbenzene; ester solvents such as ethyl acetate, butyl acetate, propylene glycol methyl ether acetate and propylene glycol methyl ether propionate; ketone solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone and cyclohexanone; ether solvents such as diethylene glycol dimethyl ether, diethylene glycol diethyl ether and dipropylene glycol dimethyl ether; alicyclic hydrocarbon solvents such as cyclohexane, methyl cyclohexane and ethyl cyclohexane; and petroleum hydrocarbon solvents such as mineral spirits.
  • the thickness of the coating layer made of the coating composition is typically from 5 to 40 ⁇ m, and preferably from 10 to 20 ⁇ m.
  • coating layer thickness refers to the coating thickness obtained by averaging the measurements taken at a total of three places: the center of a dimple and two places located at positions between the dimple center and the dimple edge.
  • the coating layer made of the above coating composition has an elastic work recovery that is preferably at least 60%, and more preferably at least 80%.
  • the coating layer has a high elasticity and so the self-repairing ability is high, resulting in an outstanding abrasion resistance.
  • the performance attributes of golf balls coated with this coating composition can be improved. The method of measuring the elastic work recovery is described below.
  • the elastic work recovery is one parameter of the nanoindentation method for evaluating the physical properties of coating layers, this being a nanohardness test method that controls the indentation load on a micro-newton ( ⁇ N) order and tracks the indenter depth during indentation to a nanometer (nm) precision.
  • ⁇ N micro-newton
  • nm nanometer
  • prior methods only the size of the deformation (plastic deformation) mark corresponding to the maximum load could be measured.
  • the nanoindentation method the relationship between the indentation load and the indentation depth can be obtained by continuous automated measurement.
  • the hardness of the coating layer is preferably at least 40, and more preferably at least 60.
  • the upper limit is preferably not more than 95, and more preferably not more than 85.
  • This Shore M hardness is obtained in general accordance with ASTM D2240.
  • the hardness of the coating layer, expressed on the Shore C hardness scale is preferably at least 50 and has an upper limit of preferably not more than 70. This Shore C hardness is obtained in general accordance with ASTM D2240.
  • coating layer hardnesses that are higher than these ranges the coating may become brittle when the ball is repeatedly struck, which may make it incapable of protecting the cover layer.
  • coating layer hardnesses that are lower than the above range are undesirable because the ball surface scuffs more readily upon striking a hard object.
  • the difference between the core center hardness Cc and Hc is preferably 0 or more, and more preferably 5 or more.
  • the upper limit is preferably not more than 25, and more preferably not more than 15.
  • the formation of a coating layer on the surface of golf balls manufactured by a commonly known method can be carried out via the steps of preparing the coating composition at the time of application, applying the composition to the golf ball surface by a conventional coating operation, and drying the applied composition.
  • the coating method is not particularly limited. For example, spray painting, electrostatic painting or dipping may be suitably used.
  • the thickness relationships and hardness relationships among the various layers it is preferable to optimize the thickness relationships and hardness relationships among the various layers, and also to optimize the surface hardnesses and deflections of the respective layer-encased spheres.
  • the combined thickness of the cover and the intermediate layer is preferably at least 1.4 mm, more preferably at least 1.7 mm, and even more preferably at least 2.0 mm.
  • the upper limit in this combined thickness is preferably not more than 2.8 mm, more preferably not more than 2.5 mm, and even more preferably not more than 2.3 mm.
  • the surface hardness relationship between the intermediate layer-encased sphere and the core is preferably set within a specific range. That is, the value obtained by subtracting the core surface hardness from the surface hardness of the intermediate layer-encased sphere, expressed on the Shore C hardness scale, is preferably at least 1, more preferably at least 5, and even more preferably at least 10.
  • the upper limit is preferably not more than 32, more preferably not more than 27, and even more preferably not more than 22. When this value is too large, the durability to cracking on repeated impact may worsen. On the other hand, when this value is too small, the spin rate on full shots may rise and a good distance may not be achieved.
  • the hardness relationship between the intermediate layer material and the cover material is preferably set within a specific range. That is, the value obtained by subtracting the intermediate layer material hardness from the cover material hardness, expressed on the Shore C hardness scale, is preferably at least 1, more preferably at least 2, and even more preferably at least 4.
  • the upper limit in this value is preferably not more than 18, more preferably not more than 12, and even more preferably not more than 6.
  • the value A-B is preferably at least 0.2 mm, more preferably at least 0.4 mm, and even more preferably at least 0.6 mm.
  • the upper limit is preferably not more than 1.5 mm, more preferably not more than 1.2 mm, and even more preferably not more than 0.9 mm.
  • the time t 1 required from contact initiation between the driver and the ball for deformation of the ball to reach a maximum value and the time t 2 required from the state of maximum golf ball deformation for the ball and the driver to separate preferably have a ratio t 2 /t 1 therebetween of at least 1.20.
  • a golf swing robot is fitted with a metal head driver (W#1) produced by Bridgestone Sports Co., Ltd. under the product name PHYZ (loft angle, 10.5°) and the golf ball is struck at a head speed (HS) of 40 m/s.
  • the golf ball during impact is photographed using a high-speed video camera (FASTCAM SA-Z, from Photron, Ltd.), the captured images are analyzed and the above deformation times t 1 and t 2 are determined.
  • FASTCAM SA-Z high-speed video camera
  • the instant at which the diameter of the golf ball in the direction of flight from the plane of contact between the clubface and the golf ball reaches a minimum is treated as the moment of greatest deformation by the golf ball.
  • Deformation time t 1 is preferably at least 210 microseconds, more preferably at least 250 microseconds, and even more preferably at least 280 microseconds.
  • the upper limit is preferably not more than 380 microseconds, more preferably not more than 350 microseconds, and even more preferably not more than 320 microseconds. When this value is too small, the feel at impact may worsen. On the other hand, when this value is too large, the initial velocity may be low and a good distance may not be achieved.
  • Deformation time t 2 is preferably at least 330 microseconds, more preferably at least 360 microseconds, and even more preferably at least 390 microseconds.
  • the upper limit is preferably not more than 540 microseconds, more preferably not more than 510 microseconds, and even more preferably not more than 480 microseconds. When this value is too small, the feel at impact may worsen. On the other hand, when this value is too large, the initial velocity may be low and a good distance may not be achieved.
  • the ratio of deformation time t 2 to deformation time t 1 is preferably at least 1.20, more preferably at least 1.30, and even more preferably at least 1.40.
  • the upper limit is preferably not more than 1.80, more preferably not more than 1.70, and even more preferably not more than 1.60. When this value is too small, the feel at impact may worsen. On the other hand, when this value is too large, the initial velocity may be low and a good distance may not be achieved.
  • the sum of deformation times t 1 and t 2 is preferably at least 660 microseconds, more preferably at least 680 microseconds, and even more preferably at least 700 microseconds.
  • the upper limit is preferably not more than 800 microseconds, more preferably not more than 780 microseconds, and even more preferably not more than 760 microseconds. When this value is too small, the feel at impact may worsen. On the other hand, when this value to is too large, the initial velocity may be low and a good distance may not be achieved.
  • the multi-piece solid golf ball of the invention can be made to conform to the Rules of Golf for play.
  • the inventive ball may be formed to a diameter which is such that the ball does not pass through a ring having an inner diameter of 42.672 mm and is not more than 42.80 mm, and to a weight which is preferably between 45.0 and 45.93 g.
  • Solid cores were produced by preparing rubber compositions for the respective Examples and Comparative Examples shown in Table 1, and then molding/vulcanizing the compositions under vulcanization conditions of 155° C. and 15 minutes.
  • An intermediate layer was formed by injection molding Resin Material No. 1 formulated as shown in Table 2 over the core, thereby giving an intermediate layer-encased sphere (except in Comparative Example 4).
  • a cover was formed by injection molding Resin Material No. 2, No. 3 or No. 4 formulated as shown in Table 2 over the intermediate layer-encased sphere obtained above.
  • a plurality of given dimples common to all the Examples and Comparative Examples were formed at this time on the cover surface.
  • Coating Composition I shown in Table 3 below was applied with an air spray gun onto the surface of the cover (outermost layer) on which numerous dimples had been formed, thereby producing golf balls having a 15 ⁇ m-thick coating layer thereon.
  • a reactor equipped with a reflux condenser, a dropping funnel, a gas inlet and a thermometer was charged with 140 parts by weight of trimethylolpropane, 95 parts by weight of ethylene glycol, 157 parts by weight of adipic acid and 58 parts by weight of 1,4-cyclohexanedimethanol, following which the temperature was raised to between 200 and 240° C. under stirring and the reaction was effected by 5 hours of heating.
  • Polyester Polyol (A) synthesized above was dissolved in butyl acetate, thereby preparing a varnish having a nonvolatiles content of 70 wt %.
  • the base resin for Coating Composition I in Table 3 was prepared by mixing 23 parts by weight of the above polyester polyol solution together with 15 parts by weight of Polyester Polyol (B) (the saturated aliphatic polyester polyol NIPPOLAN 800 from Tosoh Corporation; weight-average molecular weight (Mw), 1,000; 100% solids) and the organic solvent. This mixture had a nonvolatiles content of 38.0 wt %.
  • the elastic work recovery of the coating material was measured using a coating sheet having a thickness of 50 ⁇ m.
  • the ENT-2100 nanohardness tester from Erionix Inc. was used as the measurement apparatus, and the measurement conditions were as follows.
  • Indenter Berkovich indenter (material: diamond; angle ⁇ : 65.03°)
  • the elastic work recovery was calculated as follows, based on the indentation work W elast (Nm) due to spring-back deformation of the coating and on the mechanical indentation work W total (Nm).
  • the Shore C hardness and Shore M hardness in Table 3 above were determined by fabricating the material being tested into 2 mm thick sheets and stacking three such sheets together to form test specimens. Measurements were taken using a Shore C durometer and a Shore M durometer in accordance with ASTM D2240.
  • the diameter at five random places on the surface was measured after holding the test specimen isothermally at 23.9 ⁇ 1° C. for at least 3 hours. Using the average of these measurements as the measured value for a single core or intermediate layer-encased sphere, the average diameter for ten such spheres was determined.
  • the diameter at 15 random dimple-free areas was measured after holding the test specimen isothermally at 23.9 ⁇ 1° C. for at least 3 hours. Using the average of these measurements as the measured value for a single ball, the average diameter for ten balls was determined.
  • a sphere i.e., a core, an intermediate layer-encased sphere or a ball
  • the deflection refers in each case to a measured value obtained after holding the test specimen isothermally at 23.9° C.
  • the instrument used was a high-load compression tester available from MU Instruments Trading Corporation. Measurement was carried out with the pressing head moving downward at a speed of 4.7 mm/s.
  • the indenter of a durometer was set substantially perpendicular to the spherical surface of the core, and the surface hardness of the core on the Shore C hardness scale was measured in accordance with ASTM D2240.
  • the core center hardness was measured by perpendicularly pressing the indenter of a durometer against the center portion in the flat cross-sectional plane obtained by cutting the core into hemispheres. Measurement results are indicated as Shore C hardness values.
  • the resin materials for each layer were molded into sheets having a thickness of 2 mm and left to stand for at least two weeks, following which the Shore C and Shore D hardnesses were measured in accordance with ASTM D2240.
  • the surface hardnesses were measured by perpendicularly pressing an indenter against the surfaces of the respective spheres.
  • the surface hardnesses of the balls (covers) were values measured at dimple-free areas (lands) on the surface of the ball.
  • Shore D hardnesses were measured with a type D durometer in accordance with ASTM D2240, and Shore C hardnesses were measured with a type C durometer in accordance with ASTM D2240.
  • a golf swing robot was fitted with a metal head driver (W#1) produced by Bridgestone Sports Co., Ltd. under the product name PHYZ (loft angle, 10.5°) and the golf ball was struck at a head speed (HS) of 40 m/s.
  • the golf ball during impact was photographed using a high-speed video camera (FASTCAM SA-Z, from Photron, Ltd.), the captured images were analyzed and the following two times were measured in microseconds: the time t 1 required from contact initiation between the driver and the ball for deformation of the ball to reach a maximum value and the time t 2 required from the state of maximum golf ball deformation for the golf ball and the driver to separate.
  • the instant at which the diameter of the golf ball in the direction of flight from the plane of contact between the clubface and the golf ball reached a minimum was treated as the moment of greatest deformation by the golf ball.
  • PHYZ The clubs referred to in the above table as “PHYZ” were the PHYZ Driver (loft angle, 10.5°) and the PHYZ Iron I#6, both manufactured by Bridgestone Sports Co., Ltd.
  • a wedge having a loft angle of 52° and square grooves etched into the clubface was mounted on a golf swing robot, and the scuff resistance of the ball when struck at a head speed (HS) of 40 m/s was rated according to the following criteria.
  • the cover material was composed primarily of an ionomer resin. As a result, the ball had an inferior scuff resistance and the distance was somewhat poor.
  • the ball had a two-piece construction consisting of a core encased by a single-layer cover. As a result, the ball had a high spin rate and the distance was inferior.

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