US20190203043A1

US20190203043A1 - Copolycarbonate lenses, methods of manufacture, and applications thereof

Info

Publication number: US20190203043A1
Application number: US16/303,229
Authority: US
Inventors: Mark Adrianus Johannes van der Mee; Nathalie Gonzalez Vidal; Fabrizio Micciche; Roland Sebastian Assink; Kazuhiko Mitsui; Johannes de Brouwer; Shahram Shafaei; Hendrikus Petrus Cornelis van Heerbeek; Tamara Marijke Eggenhuisen; Robert Dirk van de Grampel
Original assignee: SABIC Global Technologies BV
Current assignee: SHPP Global Technologies BV
Priority date: 2016-05-27
Filing date: 2017-05-27
Publication date: 2019-07-04
Also published as: CN109153848B; WO2017203497A1; CN109153847B; US10947381B2; WO2017203496A1; EP3464470A1; EP3464469A1; EP3464470B1; EP3464469B1; CN109153847A; US20190300701A1; CN109153848A

Abstract

A copolycarbonate lens formed from a polycarbonate composition comprising: a copolycarbonate comprising bisphenol A carbonate units and of phthalimide carbonate and optionally, a bisphenol A homopolycarbonate; wherein the second carbonate units are present in an amount of 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.7% as determined by high performance liquid chromatography. The polycarbonate composition has: a Vicat B120 of 155° C. or higher; and an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C.

Description

BACKGROUND

This disclosure generally relates to polycarbonate lenses, and more particularly, to copolycarbonate lenses, methods of manufacture, and uses thereof.
Polycarbonates are useful in the manufacture of articles and components for a wide range of applications, from automotive parts to electronic appliances. Because of their beneficial properties such as transparency and impact resistance, polycarbonates have been used in applications such as camera lenses, eyeglass and safety glass lenses, illumination lenses such as light fixtures, flashlight and lantern lenses, and motor vehicle headlight lenses and covers. Since many of the lenses are used in high-temperature environment or have to be processed under abusive conditions, it is desirable for the lenses materials to have the ability to withstand elevated temperatures without deformation or discoloration, and/or ability to maintain good optical properties even when processed under abusive conditions.
Some known “high heat” copolycarbonates can have high glass transition temperatures of 150° C. or higher. But such polycarbonates are typically more yellow after processing and have lower transmission values. There accordingly remains a need for polycarbonate lenses having improved balance of high heat performance and optical properties.

SUMMARY

In an embodiment, a copolycarbonate lens formed from a polycarbonate composition comprises: a copolycarbonate comprising bisphenol A carbonate units and of second carbonate units of the formula
wherein R^aand R^bare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy, each R³is independently a C_1-6alkyl, R⁴is hydrogen, C_2-6alkyl or phenyl optionally substituted with 1 to 5 C_1-6alkyl groups, p, q, and j are each independently 0 to 4; and optionally, a bisphenol A homopolycarbonate; wherein the second carbonate units are present in an amount of 10 to 49 mol %, preferably 13 to 40 mol % or 35 to 49 mol %, more preferably 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.6%, or at least 99.7% as determined by high performance liquid chromatography; and wherein the polycarbonate composition has: a Vicat B 120 of 155° C. or higher, preferably 165° C. or higher, more preferably 180° C. or higher as measured according to ISO 306; and an increase in yellowness index of less than 10, or of less than 7 during 1000 hours of heat aging at 155° C., as measured by ASTM D1925 on a 1 mm thick molded plaque.
In another embodiment, a copolycarbonate lens formed from a polycarbonate composition comprises a copolycarbonate comprising bisphenol A carbonate units and of second carbonate units of the formula
wherein R^aand R^bare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy, each R³is independently a C_1-6alkyl, R⁴is hydrogen, C_2-6alkyl or phenyl optionally substituted with 1 to 5 C_1-6alkyl groups, p, q, and j are each independently 0 to 4; and wherein the second carbonate units are present in an amount of 10 to 49 mol %, preferably 13 to 40 mol % or 35 to 49 mol %, more preferably 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.6%, or at least 99.7% as determined by high performance liquid chromatography; and wherein the polycarbonate composition has: a Vicat B 120 of 155° C. or higher, preferably 165° C. or higher, more preferably 180° C. or higher as measured according to ISO 306; and a yellowness index which is at least 20% or at least 30% lower compared to the same composition having a Bisphenol A purity below 99.6% or below 99.5%, as measured by ASTM D1925 on a 2.5 mm thick molded plaque with a melt temperature of 355° C. and a residence time of 10 min.
The lens can be a molded lens, a thermoformed lens, an extruded lens, a cast lens, or a layer of a multi-layer lens.
In still another embodiment, a method of manufacture of a lens comprises injection molding, injection-compression molding, heat-cool molding, extrusion, rotational molding, blow molding, or thermoforming the above-described polycarbonate composition into the lens.
A device comprising the lens can be a camera, an electronic device, a vehicle, a flashlight, a business machine, a lighting device, an imaging device, a protective article, a vision corrective device, or a toy.
The above described and other features are exemplified by the following detailed description, examples, and claims.

DETAILED DESCRIPTION

Surprisingly, it has now been found that a copolycarbonate lens having desirable high heat performance and enhanced optical properties can be formed from a polycarbonate composition comprising phthalimidine copolycarbonates such as N-phenylphenolphthaleinylbisphenol, 2,2-bis(4-hydro)-bisphenol A copolycarbonate (“PPPBP-BPA”) and optionally a bisphenol A homopolymer, when one or both of the phthalimidine copolycarbonate and the bisphenol A homopolycarbonate are derived from a high purity bisphenol A. In particular, the polycarbonate composition can not only have good initial color and transmission after molding under standard conditions but also lower color change after heat aging at elevated temperatures. Further, the polycarbonate composition can have improved color after molding at aggressive conditions.
As used herein, phthalimidine copolycarbonates in the polycarbonate compositions from which the lenses are formed are high heat copolycarbonates having a glass transition temperature of 155° C. or higher, and comprising bisphenol A carbonate units and second carbonate units of formula (1)
wherein R^aand R^bare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy, preferably a C_1-3alkyl, each R³is independently a C_1-6alkyl, R⁴is hydrogen, C_1-6or C_2-6alkyl or phenyl optionally substituted with 1 to 5 C_1-6alkyl groups, and p and q are each independently 0 to 4, preferably 0 to 1. For example, the second carbonate units can be of formula (1a)
wherein R⁵is hydrogen, phenyl optionally substituted with up to five C_1-6alkyl groups, or C_1-4alkyl, such as methyl or C_2-4alkyl. In an embodiment, R⁵is hydrogen or phenyl, preferably phenyl. Carbonate units (1a) wherein R⁵is phenyl can be derived from 2-phenyl-3,3′-bis(4-hydroxy phenyl)phthalimidine (also known as 3,3-bis(4-hydroxyphenyl)-2-phenylisoindolin-1-one or N-phenyl phenolphthalein or “PPPBP”).
The optical properties of the polycarbonate composition can be further improved when the bisphenol A carbonate units in the high heat copolycarbonates, in the bisphenol A homopolymer or both, are derived from a bisphenol A monomer having a purity of greater than 99.70% as determined by high performance liquid chromatography (HPLC).
The copolycarbonate comprises from 50 to 90 mole percent (mol %) of the bisphenol A carbonate units and 10 to 50 mol % of the second carbonate units, preferably the copolycarbonate comprises from 60 to 85 mol % of the bisphenol A carbonate units and 15 to 40 mol % of the second carbonate units, and in an embodiment the copolycarbonate comprises from 50 to 70 mol % of the bisphenol A carbonate units and 30 to 50 mol % of the second carbonate units, each based on the total number of carbonate units in the copolycarbonate.
In some embodiments, the high heat copolycarbonates further include at least 5 mol % of third carbonate units different from bisphenol A carbonate units and second carbonate units based on the sum of the moles of the bisphenol A carbonate units, second carbonate units, and third carbonate units. The third carbonate units can have the formula
wherein R^cand R^dare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy, each R⁶is independently C_1-3alkyl or phenyl, preferably methyl, X^ais a C_6-12polycyclic aryl, C_3-18mono- or polycycloalkylene, C_3-18mono- or polycycloalkylidene, -(Q¹)_x-G-(Q²)_y- group wherein Q¹and Q²are each independently a C_1-3alkylene, G is a C_3-10cycloalkylene, x is 0 or 1, and y is 1, or —C(P¹)(P²)— wherein P¹is C_1-12alkyl and P²is C_6-12aryl; and m and n are each independently 0 to 4.
Exemplary third carbonate units include the following
or a combination thereof, wherein R^cand R^dare the same as defined herein for formulas (3) to (7), each R¹is independently hydrogen or C_1-4alkyl, each R²is independently C_1-4alkyl, and g is 0 to 10. Preferably, each R¹is independently hydrogen or methyl, each R²is independently methyl or hydrogen, g is 0 to 2, and m and n are 0. In a specific embodiment the third carbonate units are 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane carbonate units, 1,1-bis(4-hydroxy-3-methylphenyl)cyclohexane, or a combination thereof. Preferably, the third carbonate units are 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane (BPA TMC) carbonate units.
When the third carbonate units are present, the copolycarbonates can comprise 15 to 70 mol % of the bisphenol A carbonate units, 5 to 50 mol % of the second carbonate units, and 5 to 50 mol % of the third carbonate units, each based on the sum of moles of the bisphenol A carbonate units, second carbonate units, and third carbonate units. Preferably, the copolycarbonates comprise 30 to 60 mol % of the bisphenol A carbonate units, 5 to 35 mol % of the second carbonate units, 5 to 35 mol % of the third carbonate units, each based on the sum of the moles of the bisphenol A carbonate units, second carbonate units, and third carbonate units.
In an embodiment, the copolycarbonates are highly random copolymers, which have less than 15 mol % or less than 10 mol % of the second carbonate units directly coupled to another second carbonate unit based on the total number of carbonate units in the copolycarbonates. The molar percent can be determined by nuclear magnetic resonance spectroscopy (NMR). Without wishing to be bound by theory, it is believed that by keeping the randomness of the high heat polymer, the properties of the high heat polymer remains consistent from batch to batch.
To further enhance the optical properties of the thermoplastic compositions, the high heat copolycarbonates are essentially free of certain metal ions, anions, and preferably, low molecular weight molecules (those having a molecular weight of less than 150 Dalton) arising from manufacture of the copolymers. In an embodiment, the copolycarbonates comprise less than 2 ppm of each of triethyl amine, calcium ions, magnesium ions, potassium ions, iron ions, and chloride ions. In another embodiment, the high heat copolycarbonates comprise less than 2 ppm of each chloride, sodium, calcium, iron, nickel, copper, and zinc ions as residual impurities.
In another embodiment, which is preferred, the copolycarbonates have a low residual impurity content, in particular less than 2 ppm by weight of each of lithium, sodium, potassium, calcium, magnesium, ammonium, chloride, bromide, fluoride, nitrite, nitrate, phosphite, phosphate, sulfate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium. It is to be understood that the foregoing residual impurities can exist in the thermoplastic compositions in un-ionized form (for example as triethylamine or formic acid), but are determined based on their ionized form.
The residual impurity content can be determined by methods known in the art, for example those described in 2016/0237210 and U.S. Pat. No. 9,287,471 via ion chromatography. For example, determination can be accomplished via ion exchange, of a sample obtained by dissolving 2.4 gram of copolycarbonate in 20 mL of dichloromethane and extracting with 10 mL of distilled, deionized water for 1 hour. The water layer is analyzed by ion chromatography with respect to the desired anions, cations, and amines, in particular fluoride, acetate, formate, chloride, nitrite, bromide, nitrate, phosphite, sulphate, oxalate, phosphate, citrate, lithium, sodium, potassium, ammonium, magnesium, calcium, and diethylamine, and triethylamine. In another embodiment of quantitative analysis of ions, the sample can be submerged in de-ionized water kept at 55° C. for 24 hours, the anions released into the water then analyzed via ion chromatography, e.g., with a Dionex DX500 Ion Chromatograph. Alternatively, quantitative analysis of metals and other compounds can be carried out by conventional inductively coupled plasma emission spectroscopy (ICP) methods to determine the presence of each constituent to the parts per billion (ppb) level.
The high heat copolycarbonates have a weight average molecular weight of 10,000 to 50,000 Daltons, preferably 16,000 to 30,000 Daltons, as measured by gel permeation chromatography (GPC), using a crosslinked styrene-divinylbenzene column and calibrated to bisphenol A homopolycarbonate references. GPC samples are prepared at a concentration of 1 mg per ml, and are eluted at a flow rate of 1.5 ml per minute.
The high heat copolycarbonates have a high glass transition temperature (Tg). The Tg of the high heat copolycarbonates is 155 to 280° C., more preferably 165 to 260° C., even more preferably 185 to 230° C., determined by differential scanning calorimetry (DSC) as per ASTM D3418 with a 20° C./min heating rate.
The high heat copolycarbonates can have high heat resistance. The heat deflection temperature (HDT) of the high heat copolycarbonates is 145 to 270° C., more preferably 155 to 260° C., even more preferably 175 to 220° C., measured flat on a 80×10×4 mm bar with a 64 mm span at 0.45 MPa according to ISO 75/Bf.
The high heat copolycarbonates can have high Vicat softening temperature. In an embodiment, the high heat copolycarbonates have a Vicat B 120 of 150 to 275° C., preferably 160 to 255° C., even more preferably 180 to 225° C., measured according to ISO 306.
The high heat copolycarbonates can be present in an amount of 10 to 99 weight percent (wt %), 90 to 99.8 wt %, 20 to 80 wt %, 45 to 75 wt %, or 50 to 70 wt % based on the total weight of the polycarbonate compositions. Preferably the second carbonate units of the high heat copolycarbonates are present in the composition in an amount of 10 to 49 mol %, preferably 13 to 40 mol % or 35 to 49 mol %, more preferably 18 to 35 mol % of second carbonate units based on sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate.
The high heat copolycarbonates can be produced using a BPA monomer having both a high level of organic purity (e.g., measured by HPLC of greater than or equal to 99.7 wt %) and a sulfur level of less than or equal to 2 parts per million (ppm) as measured by a commercially available Total Sulfur Analysis based on combustion and coulometric detection. The organic purity can be defined as 100 wt % minus the sum of known and unknown impurities detected using ultraviolet (UV) (see HPLC method in Nowakowska et al., Polish J. Appl. Chem., XI(3), 247-254 (1996)). In addition, an end-capping agent is present during manufacture of the high heat copolycarbonate such that high heat copolycarbonate comprises a free hydroxyl level of less than or equal to 200 ppm, more preferably less than or equal to 150 ppm.
Optionally, the thermoplastic compositions include a bisphenol A homopolycarbonate. The bisphenol A homopolymer carbonate can be derived from a bisphenol A monomer having a purity less than 99.7% determined by HPLC. Alternatively, the bisphenol A homopolycarbonate can be derived from a high purity bisphenol A monomer having a purity equal to or greater than 99.7% determined by HPLC.
It has been found by the inventors hereof that the optical properties of the thermoplastic composition can be further improved using bisphenol A homopolycarbonates having specific additional properties. In an embodiment, the bisphenol A homopolycarbonate is manufactured via an interfacial process using a BPA monomer having both a high level of organic purity (e.g., measured by HPLC of greater than or equal to 99.7 wt %) and a sulfur level of less than or equal to 2 parts per million (ppm) as measured by a commercially available Total Sulfur Analysis based on combustion and coulometric detection. The organic purity can be defined as 100 wt % minus the sum of known and unknown impurities detected using ultraviolet (UV) (see HPLC method in Nowakowska et al., Polish J. Appl. Chem., XI(3), 247-254 (1996)). In addition, an end-capping agent is present during manufacture of the bisphenol A homopolycarbonate such that bisphenol A homopolycarbonate comprises a free hydroxyl level less than or equal to 150 ppm. The bisphenol A homopolycarbonate derived from high purity BPA can also have a sulfur level of less than or equal to 2 parts per million (ppm) as measured by a commercially available Total Sulfur Analysis based on combustion and coulometric detection. Bisphenol A homopolycarbonates of high purity, suitable for use in the present compositions, can also be manufactured via the melt process.
These bisphenol A homopolycarbonates are characterized by specific properties. In particular, the preferred bisphenol A homopolycarbonates have a low yellowness index and are heat stable. For example, a molded sample comprising the bisphenol A homopolycarbonate has a yellowness index (YI) of 2.5 or less, 2.0 or less, 1.5 or less, 1.2 or less, or 1.1 or less as measured by ASTM D1925 on a plaque with 2.5 mm thickness. The bisphenol A homopolycarbonates can further be characterized by a molded sample thereof with a thickness of 2.5 mm having an increase in YI (ΔYI) of less than 12, less than 12, or less than 10 after 5,000 hours of heat aging at 130° C. as measured by ASTM D1925. Alternatively, or in addition, the bisphenol A homopolycarbonates can have an increase in YI (ΔYI) of less than 3, less than 2.5, or less than 2 after 2,000 hours of heat aging at 130° C.
The preferred bisphenol A homopolycarbonates are also transparent in the absence of any light diffusers or other fillers. For example, a molded article of the bisphenol A homopolycarbonate has transmission level greater than or equal to 90.0% at 2.5 millimeter (mm) thickness as measured by ASTM D1003-00, Procedure A, measured, e.g., using a HAZE-GUARD DUAL from BYK-Gardner, using and integrating sphere (0°/diffuse geometry), wherein the spectral sensitivity conforms to the International Commission on Illumination (CIE) standard spectral value under standard lamp D65.
Alternatively, the bisphenol A homopolycarbonate can be derived from a bisphenol A monomer having a purity less than 99.70% determined by HPLC, provided that when the bisphenol A homopolycarbonate is derived from a bisphenol A monomer having a purity of less than 99.70%, the high heat copolycarbonate is derived from a high purity BPA so that the BPA purity of the polycarbonate composition is at least 99.6% or at least 99.7% as determined by HPLC.
As used herein, the bisphenol A purity of the polycarbonate composition refers to the overall purity of the bisphenol A monomer used to prepare the high heat copolycarbonate and the bisphenol A homopolymer, if present. The bisphenol A purity of a polycarbonate composition can be determined by a mild depolymerization followed by a HPLC analysis. For example, about 200 milligrams (mg) of the polycarbonate composition is dissolved in 5 ml of tetrahydrofuran (THF) and 2 ml of a 10% solution of potassium hydroxide diluted in methanol. The depolymerization of copolycarbonate is carried out with the use of these solvents. The solution is shaken for 2 hours. Then, 2 milliliters (ml) of acetic acid are added to protonate the BPA carbonate salts and decrease the pH. The solution is shaken again for half an hour for homogenization and dissolution of all precipitates. The sample is analyzed by HPLC. The wt % of BPA impurities in the polycarbonate composition can be calculated by:
$\begin{matrix} wt % of impurities in BPA = \frac{wt % of impurities * 254}{228} . & (equation 1) \end{matrix}$
In equation 1, wt % of impurities refers to the impurities percent measured by HPLC after depolymerization. Because the BPA molar mass is different from the carbonated BPA, the wt % of impurities is multiplied by 254 grams per mole (g/mol, or Da) and divide by 228 g/mol. 254 g/mol corresponds to the BPA carbonate molar mass and the BPA molar mass is equal to 228 g/mol. The purity of BPA can be determined by subtracting the wt % of calculated BPA impurities from 100.
In an embodiment, the bisphenol A polycarbonate homopolymer is a linear bisphenol A polycarbonate homopolymer having a weight average molecular weight of 10,000 to 100,000 Daltons, specifically 15,000 to 50,000 Daltons, more specifically 17,000 to 35,000 Daltons, as measured by gel permeation chromatography (GPC), using a crosslinked styrene-divinylbenzene column and calibrated to bisphenol A homopolycarbonate references. GPC samples are prepared at a concentration of 1 mg per ml, and are eluted at a flow rate of 1.5 ml per minute.
More than one bisphenol A polycarbonate homopolymer can be present. For example, the polycarbonate compositions can comprise a first bisphenol A polycarbonate homopolymer having a weight average molecular weight of 20,000 Daltons to 25,000 Daltons and a second bisphenol A polycarbonate homopolymer having a weight average molecular weight of 28,000 to 32,000 Daltons, or a second bisphenol A polycarbonate homopolymer having a weight average molecular weight of 16,000 Daltons to 20,000 Daltons, each measured by GPC using bisphenol A homopolycarbonate standards. The weight ratio of the first bisphenol A polycarbonate homopolymer relative to the second bisphenol A polycarbonate homopolymer is 10:1 to 1:10, specifically 5:1 to 1:5, more specifically 3:1 to 1:3 or 2:1 to 1:2.
The polycarbonate homopolymer can be present in an amount of 10 to 90 wt %, preferably 10 to 80 wt %, 10 to 60 wt %, 15 to 50 wt %, or 25 to 55 wt %, or 30 to 50 wt %, each based on the total weight of the polycarbonate composition.
In some embodiments, it can be advantageous to use copolycarbonates and bisphenol A homopolycarbonates with very low residual contents of volatile impurities. For example, the polymer components can have a content of chlorobenzene and other aromatic chlorine compounds of less than 10 ppm, preferably less than 5 ppm and more preferably less than 2 ppm, dichloromethane of less than 1 ppm, preferably less than 0.5 ppm, monohydric phenols such as phenol, tert-butylphenol and cumylphenol of less than 15 ppm, preferably less than 5 ppm and more preferably less than 2 ppm, and alkanes of less than 10 ppm, preferably less than 5 ppm. In other embodiments, the polymers can preferably have residual contents of: carbon tetrachloride of less than 0.01 ppm, diaryl carbonates, in particular diphenyl carbonate and di-tert-butyl phenolcarbonate, of less than 5 ppm, preferably less than 2 ppm, bisphenol A and other bisphenols of less than 5 ppm, preferably less than 2 ppm and more preferably less than 0.5 ppm, sodium and other alkali metals and alkaline earth metals of less than 0.05 ppm, cresols of less than 1 ppm, preferably less than 0.2 ppm, phenolic OH groups of less than 300 ppm, preferably less than 200 ppm, more preferably less than 100 ppm, alkaline earth metals of less than 0.1 ppm, more preferably less than 0.05 ppm, pyridine of less than 1 ppm, preferably less than 0.1 ppm, nonhalogenated aromatic compounds such as xylene and toluene of less than 10 ppm, preferably less than 5 ppm. Methods for obtaining and measuring these amount is described, for example, in US2012/0157653.
The polycarbonates can be manufactured by processes such as interfacial polymerization and melt polymerization, which are known, and are described, for example, in WO 2013/175448 A1 and WO 2014/072923 A1. An end-capping agent (also referred to as a chain stopper agent or chain terminating agent) can be included during polymerization to provide end groups, for example monocyclic phenols such as phenol, p-cyanophenol, and C₁-C₂₂alkyl-substituted phenols such as p-cumyl-phenol, resorcinol monobenzoate, and p- and tertiary-butyl phenol, monoethers of diphenols, such as p-methoxyphenol, monoesters of diphenols such as resorcinol monobenzoate, functionalized chlorides of aliphatic monocarboxylic acids such as acryloyl chloride and methacryoyl chloride, and mono-chloroformates such as phenyl chloroformate, alkyl-substituted phenyl chloroformates, p-cumyl phenyl chloroformate, and toluene chloroformate. Combinations of different end groups can be used. Branched polycarbonate blocks can be prepared by adding a branching agent during polymerization, for example trimellitic acid, trimellitic anhydride, trimellitic trichloride, tris-p-hydroxyphenylethane, isatin-bis-phenol, tris-phenol TC (1,3,5-tris((p-hydroxyphenyl)isopropyl)benzene), tris-phenol PA (4(4(1,1-bis(p-hydroxyphenyl)-ethyl) alpha, alpha-dimethyl benzyl)phenol), 4-chloroformyl phthalic anhydride, trimesic acid, and benzophenone tetracarboxylic acid. The branching agents can be added at a level of 0.05 to 2.0 wt %. Combinations comprising linear polycarbonates and branched polycarbonates can be used.
It has been found that including an acid stabilizer in the polycarbonate compositions can further improve the color stability of the compositions after the compositions are molded under aggressive conditions and/or after the compositions are aged at an elevated temperature for a prolonged period of time.
Any Arrhenius acid (i.e., protic acid) can be used so long as the type and amount selected is such that molding properties are improved, and color and polycarbonate degradation are minimized. Any acid with a pKa of less than or equal to about 5 (measured in water) can be used. Use of a stronger acid, i.e., an acid having a pKa (measured in water) of less or equal to about 2, specifically about 2 to about −1, over a weaker acid, i.e., having a pKa (measured in water) of greater than about 2, specifically greater than about 2 to about 4.5, has a stronger effect on both molding and heat aging. Lower amounts of the stronger acid can therefore be used relative to the weaker acid, for the same color stabilization effect. In one embodiment, a stronger acid having a pKa of less than 2 is used; in other embodiments, a weaker acid having a pKa of greater than 2 is used. In some embodiments, an acid having a pKa of less than 4.5 is used. Exemplary acid stabilizers include Bronsted acid, a Lewis acid, an ester of an acid or an ester thereof containing a sulfur atom, or a combination thereof.
Acid stabilizers can include, in an embodiment, phosphoric acid; phosphorus acid; hypophosphorous acid; pyrophosphoric acid; polyphosphoric acid; an organo sulfonic stabilizer; sulfurous acids; ammonium salts of sulfuric acids, halogenated carboxylic acids such as, for example, trifluoroacetic acid, trichloroacetic acid, and the like. In an exemplary embodiment, a useful weaker acid is phosphoric acid or phosphorous acid, and a useful stronger acid is p-toluenesulfonic acid.
The organosulfonic stabilizer can be an aryl or aliphatic sulfonic acid, including a polymer thereof, an aryl or an aliphatic sulfonic acid anhydride, or an aryl or aliphatic ester of an aryl or aliphatic sulfonic acid, or a polymer thereof. In particular, the organosulfonic stabilizer is a C_1-30alkyl sulfonic acid, a C_6-30aryl sulfonic acid, a C_7-30alkylarylene sulfonic acid, a C_7-30arylalkylene sulfonic acid, or an aromatic sulfonic acid polymer; an anhydride of a C_1-30alkyl sulfonic acid, a C_6-30aryl sulfonic acid, a C_7-30alkylarylene sulfonic acid, or a C_7-30arylalkylene sulfonic acid; or a C_6-30aryl ester of a C_1-30alkyl sulfonic acid, a C_6-30aryl sulfonic acid, a C_7-30alkylarylene sulfonic acid, a C_7-30arylalkylene sulfonic acid, or an aromatic sulfonic acid polymer; or a C_1-30aliphatic ester of a C_1-30alkyl sulfonic acid, a C_6-30aryl sulfonic acid, a C_7-30alkylarylene sulfonic acid, a C_7-30arylalkylene sulfonic acid, or an aromatic sulfonic acid polymer. A combination of one or more of the foregoing can be used.
In preferred embodiments, the organosulfonic stabilizers are represented by formula (8)
In formula (8), R⁷is each independently a C_1-30alkyl, C_6-30aryl, C_7-30alkylarylene, C_7-30arylalkylene, or a polymer unit derived from a C_2-32ethylenically unsaturated aromatic sulfonic acid or its corresponding C_1-32alkyl ester. The C_2-32ethylenically unsaturated aromatic sulfonic acid can be of the formula
wherein R⁹is hydrogen or methyl, and R⁸is as defined in formula (8). Preferably the ethylenically unsaturated group and the sulfonic acid or ester group are located para on the phenyl ring.
Further in formula (8), R⁸is hydrogen; or R⁸is C_1-30alkyl; or R⁸is a group of the formula —S(═O)₂—R⁷. When R⁸is a group of the formula —S(═O)₂—R⁷, each R⁷in the compound of formula (8) can be the same or different, but preferably each R⁷is the same.
In an embodiment in formula (8), R⁷is a C_6-12aryl, C_7-24alkylarylene, or a polymer unit derived from a C_2-14ethylenically unsaturated aromatic sulfonic acid or its ester; and R⁸is hydrogen, C_1-24alkyl, or a group of the formula —S(═O)₂—R⁷wherein R⁷is a C_6-12aryl or C_7-24alkylarylene.
In a preferred embodiment, R⁷is a C_7-10alkylarylene or a polymer unit derived from a C_2-14ethylenically unsaturated aromatic sulfonic acid, and R⁸is a hydrogen, C_1-25alkyl, or a group of the formula —S(═O)₂—R⁷wherein R⁷is a C_7-10alkylarylene. In a specific embodiment, R⁷is a C_7-10alkylarylene and R⁸is a hydrogen or C_1-6alkyl. In still another embodiment, R⁷is a C_7-10alkylarylene and R⁸is a hydrogen or C_12-25alkyl, or R⁸is a C_14-20alkyl.
In specific embodiment, R⁷is a polymer unit derived from a C_2-14ethylenically unsaturated aromatic sulfonic acid, preferably p-styrene sulfonic acid or para-methyl styrene sulfonic acid, such that in formula (8) R⁸is hydrogen.
In an embodiment, the organosulfonic stabilizer is a C_1-10alkyl ester of a C_7-12alkylarylene sulfonic acid, preferably of p-toluene sulfonic acid. More preferably the stabilizer is a C_1-6alkyl ester of p-toluene sulfonic acid, and even more preferably is butyl tosylate.
In another embodiment, the organosulfonic stabilizer is an anhydride of a C_7-12alkylarylene sulfonic acid, preferably para-toluene sulfonic anhydride.
In still another embodiment, R⁷is a C_11-24alkylarylene sulfonic acid, and R⁸is hydrogen. Alternatively, R⁷is a C_16-22alkylarylene sulfonic acid, and R⁸is hydrogen.
The acid stabilizer can be used in an amount of 2 ppm to 25 ppm, preferably 4 ppm to 15 ppm or 6 ppm to 12 ppm, or 1 ppm to 40 ppm, 4 ppm to 20 ppm or 6 ppm to 10 ppm by weight based on the total weight of the polycarbonate composition.
The polycarbonate composition can also contain an epoxy additive. Epoxy compounds useful as additives include epoxy modified acrylic oligomers or polymers (such as a styrene-acrylate-epoxy polymer, prepared from for example a combination of: a substituted or unsubstituted styrene such as styrene or 4-methylstyrene; an acrylate or methacrylate ester of a C_1-22alkyl alcohol such as methyl acrylate, methyl methacrylate, ethyl acrylate, butyl acrylate, or the like; and an epoxy-functionalized acrylate such as glycidyl acrylate, glycidyl methacrylate, 2-(3,4-epoxycyclohexyl)ethyl acrylate, 2-(3,4-epoxycyclohexyl)ethyl methacrylate, or the like), or an epoxy carboxylate oligomer based on cycloaliphatic epoxides (such as, for example, 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexylcarboxylate, or the like). Specific commercially available exemplary epoxy functionalized stabilizers include Cycloaliphatic Epoxide Resin ERL-4221 supplied by Union Carbide Corporation (a subsidiary of Dow Chemical), Danbury, Conn.; and epoxy modified acrylates such as JONCRYL ADR-4300 and JONCRYL ADR-4368, available from BASF. Epoxy additives are typically used in amounts of up to 1 wt %, specifically 0.001 to 1 wt %, more specifically 0.001 to 0.5 wt %, based on the total weight of the polycarbonate composition. In an embodiment, the epoxy additive can be included in an amount of 0.001 to 0.3 wt %, specifically 0.01 to 0.3 wt %, and more specifically 0.1 to 0.3 wt %, based on the total weight of the polycarbonate composition. Use of greater amounts of epoxy compound may cause more splay, i.e., mold lines which fan outward from the point of injection into the mold, and observable to the unaided eye in molded articles comprising the polycarbonate composition.
The polycarbonate compositions can include various additives ordinarily incorporated into polymer compositions of this type, with the proviso that the additive(s) are selected so as to not significantly adversely affect the desired properties of the polycarbonate composition, in particular melt flow, thermal, transparency, and surface properties. Such additives can be mixed at a suitable time during the mixing of the components for forming the composition. Additives include fillers, reinforcing agents, antioxidants, heat stabilizers, light stabilizers, ultraviolet (UV) light stabilizers, plasticizers, lubricants, mold release agents, antistatic agents, colorants such as titanium dioxide, carbon black, and organic dyes, surface effect additives, radiation stabilizers, flame retardants, anti-drip agents, and impact modifiers. In an embodiment, the polycarbonate composition further comprises a processing aid, a heat stabilizer, an ultraviolet light absorber, a colorant, a flame retardant, an impact modifier, or a combination thereof. A combination of additives can be used, for example a combination of a heat stabilizer, mold release agent, and ultraviolet light stabilizer. In general, the additives are used in the amounts generally known to be effective. For example, the total amount of the additives (other than any impact modifier, filler, or reinforcing agents) can be 0 to 5 wt % or 0.01 to 5 wt %, based on the total weight of the polycarbonate composition.
Antioxidant additives include organophosphites such as tris(nonyl phenyl)phosphite, tris(2,4-di-t-butylphenyl)phosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite, distearyl pentaerythritol diphosphite; alkylated monophenols or polyphenols; alkylated reaction products of polyphenols with dienes, such as tetrakis[methylene(3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane; butylated reaction products of para-cresol or dicyclopentadiene; alkylated hydroquinones; hydroxylated thiodiphenyl ethers; alkylidene-bisphenols; benzyl compounds; esters of beta-(3,5-di-tert-butyl-4-hydroxyphenyl)-propionic acid with monohydric or polyhydric alcohols; esters of beta-(5-tert-butyl-4-hydroxy-3-methylphenyl)-propionic acid with monohydric or polyhydric alcohols; esters of thioalkyl or thioaryl compounds such as distearylthiopropionate, dilaurylthiopropionate, ditridecylthiodipropionate, octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, pentaerythrityl-tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate; amides of beta-(3,5-di-tert-butyl-4-hydroxyphenyl)-propionic acid, or combinations comprising at least one of the foregoing antioxidants. Antioxidants are used in amounts of 0.01 to 0.1 parts by weight, based on 100 parts by weight of the total composition, excluding any filler.
Heat stabilizer additives include organophosphites such as triphenyl phosphite, tris-(2,6-dimethylphenyl)phosphite, tris-(mixed mono- and di-nonylphenyl)phosphite; phosphonates such as dimethylbenzene phosphonate, phosphates such as trimethyl phosphate, or combinations comprising at least one of the foregoing heat stabilizers. Heat stabilizers are used in amounts of 0.01 to 0.1 parts by weight, based on 100 parts by weight of the total composition, excluding any filler.
Light stabilizers, including ultraviolet light (UV) absorbers, can also be used. Light stabilizers include benzotriazoles such as 2-(2-hydroxy-5-methylphenyl)benzotriazole and 2-(2-hydroxy-5-tert-octylphenyl)-benzotriazole, 2-hydroxy-4-n-octoxy benzophenone, or combinations comprising at least one of the foregoing light stabilizers. UV absorbing additives include hydroxybenzophenones; hydroxybenzotriazoles; hydroxybenzotriazines; cyanoacrylates; oxanilides; benzoxazinones; 2-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)-phenol (CYASORB* 5411); 2-hydroxy-4-n-octyloxybenzophenone (CYASORB* 531); 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)-phenol (CYASORB* 1164); 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) (CYASORB* UV-3638); 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane (UVINUL* 3030); 2,2′-(1,4-phenylene) bis(4H-3,1-benzoxazin-4-one); 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane; phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)-(TINUVIN* 234); BCAP bismalonate from Clariant; nano-size inorganic materials such as titanium oxide, cerium oxide, and zinc oxide, all with particle size less than or equal to 100 nanometers, or combinations comprising at least one of the foregoing UV absorbers. Light stabilizers are used in amounts of 0.01 to 5 parts by weight, based on 100 parts by weight of the polycarbonate composition, excluding any filler.
Flame retardants can also be used. Flame retardants include flame retardant salts such as alkali metal salts of perfluorinated C_1-16alkyl sulfonates such as potassium perfluorobutane sulfonate (Rimar salt), potassium perfluoroctane sulfonate, tetraethylammonium perfluorohexane sulfonate, potassium diphenylsulfone sulfonate (KSS), and the like, sodium benzene sulfonate, sodium toluene sulfonate (NATS) and the like; and salts formed by reacting for example an alkali metal or alkaline earth metal (for example lithium, sodium, potassium, magnesium, calcium and barium salts) and an inorganic acid complex salt, for example, an oxo-anion, such as alkali metal and alkaline-earth metal salts of carbonic acid, such as Na₂CO₃, K₂CO₃, MgCO₃, CaCO₃, and BaCO₃or fluoro-anion complex such as Li₃AlF₆, BaSiF₆, KBF₄, K₃AlF₆, KAlF₄, K₂SiF₆, and/or Na₃AlF₆or the like. Rimar salt and KSS and NATS, alone or in combination with other flame retardants, are particularly useful in the compositions disclosed herein. Flame retardant salts are typically used in amounts of 0.01 to 1.0 parts by weight, based on 100 parts by weight of the polycarbonate composition.
Organophosphorus flame retardants can be used. Organophosphorus compounds include aromatic organophosphorus compounds having at least one organic aromatic group and at least one phosphorus-containing group, as well as organic compounds having at least one phosphorus-nitrogen bond.
In the aromatic organophosphorus compounds that have at least one organic aromatic group, the aromatic group can be a substituted or unsubstituted C_3-30group containing one or more of a monocyclic or polycyclic aromatic moiety (which can optionally contain with up to three heteroatoms (N, O, P, S, or Si)) and optionally further containing one or more nonaromatic moieties, for example alkyl, alkenyl, alkynyl, or cycloalkyl. The aromatic moiety of the aromatic group can be directly bonded to the phosphorus-containing group, or bonded via another moiety, for example an alkylene group. The aromatic moiety of the aromatic group can be directly bonded to the phosphorus-containing group, or bonded via another moiety, for example an alkylene group. In an embodiment the aromatic group is the same as an aromatic group of the polycarbonate backbone, such as a bisphenol group (e.g., bisphenol A), a monoarylene group (e.g., a 1,3-phenylene or a 1,4-phenylene), or a combination thereof.
The phosphorus-containing group can be a phosphate (P(═O)(OR)₃), phosphite (P(OR)₃), phosphonate (RP(═O)(OR)₂), phosphinate (R₂P(═O)(OR)), phosphine oxide (R₃P(═O)), or phosphine (R₃P), wherein each R in the foregoing phosphorus-containing groups can be the same or different, provided that at least one R is an aromatic group. A combination of different phosphorus-containing groups can be used. The aromatic group can be directly or indirectly bonded to the phosphorus, or to an oxygen of the phosphorus-containing group (i.e., an ester).
In an embodiment the aromatic organophosphorus compound is a monomeric phosphate. Representative monomeric aromatic phosphates are of the formula (GO)₃P═O, wherein each G is independently an alkyl, cycloalkyl, aryl, alkylarylene, or arylalkylene group having up to 30 carbon atoms, provided that at least one G is an aromatic group. Two of the G groups can be joined together to provide a cyclic group. In some embodiments G corresponds to a monomer used to form the polycarbonate, e.g., resorcinol. Exemplary phosphates include phenyl bis(dodecyl) phosphate, phenyl bis(neopentyl) phosphate, phenyl bis(3,5,5′-trimethylhexyl) phosphate, ethyl diphenyl phosphate, 2-ethylhexyl di(p-tolyl) phosphate, bis(2-ethylhexyl) p-tolyl phosphate, tritolyl phosphate, bis(2-ethylhexyl) phenyl phosphate, tri(nonylphenyl) phosphate, bis(dodecyl) p-tolyl phosphate, dibutyl phenyl phosphate, 2-chloroethyl diphenyl phosphate, p-tolyl bis(2,5,5′-trimethylhexyl) phosphate, 2-ethylhexyl diphenyl phosphate, and the like. A specific aromatic phosphate is one in which each G is aromatic, for example, triphenyl phosphate, tricresyl phosphate, isopropylated triphenyl phosphate, and the like.
Di- or polyfunctional aromatic phosphorus-containing compounds are also useful, for example, compounds of the formulas below
wherein each G¹is independently a C_1-30hydrocarbyl; each G²is independently a C_1-30hydrocarbyl or hydrocarbyloxy; each X is independently a bromine or chlorine; m is 0 to 4, and n is 1 to 30. Di- or polyfunctional aromatic phosphorus-containing compounds of this type include resorcinol tetraphenyl diphosphate (RDP), the bis(diphenyl) phosphate of hydroquinone and the bis(diphenyl) phosphate of bisphenol A, respectively, their oligomeric and polymeric counterparts, and the like.
Specific aromatic organophosphorus compounds have two or more phosphorus-containing groups, and are inclusive of acid esters of the formula (9)
wherein R¹⁶, R¹⁷, R¹⁸, and R¹⁹are each independently C_1-8alkyl, C_5-6cycloalkyl, C_6-20aryl, or C_7-12arylalkylene, each optionally substituted by C_1-12alkyl, specifically by C_1-4alkyl and X is a mono- or poly-nuclear aromatic C₆-30 moiety or a linear or branched C_2-30aliphatic radical, which can be OH-substituted and can contain up to 8 ether bonds, provided that at least one of R¹⁶, R¹⁷, R¹⁸, R¹⁹, and X is an aromatic group. In some embodiments R¹⁶, R¹⁷, R¹⁸, and R¹⁹are each independently C_1-4alkyl, naphthyl, phenyl(C_1-4)alkylene, or aryl groups optionally substituted by C_1-4alkyl. Specific aryl moieties are cresyl, phenyl, xylenyl, propylphenyl, or butylphenyl. In some embodiments X in formula (9) is a mono- or poly-nuclear aromatic C_6-30moiety derived from a diphenol. Further in formula (9), n is each independently 0 or 1; in some embodiments n is equal to 1. Also in formula (9), q is from 0.5 to 30, from 0.8 to 15, from 1 to 5, or from 1 to 2. Specifically, X can be represented by the following divalent groups (9), or a combination comprising one or more of these divalent groups.
In these embodiments, each of R¹⁶, R¹⁷, R¹⁸, and R¹⁹can be aromatic, i.e., phenyl, n is 1, and p is 1-5, specifically 1-2. In some embodiments at least one of R¹⁶, R¹⁷, R¹⁸, R¹⁹, and X corresponds to a monomer used to form the polycarbonate, e.g., bisphenol A or resorcinol. In another embodiment, X is derived especially from resorcinol, hydroquinone, bisphenol A, or diphenylphenol, and R¹⁶, R¹⁷, R¹⁸, R¹⁹, is aromatic, specifically phenyl. A specific aromatic organophosphorus compound of this type is resorcinol bis(diphenyl phosphate), also known as RDP. Another specific class of aromatic organophosphorus compounds having two or more phosphorus-containing groups are compounds of formula (10)
wherein R¹⁶, R¹⁷, R¹⁸, R¹⁹, n, and q are as defined for formula (9) and wherein Z is C_1-7alkylidene, C_1-7alkylene, C_5-12cycloalkylidene, —O—, —S—, —SO₂—, or —CO—, specifically isopropylidene. A specific aromatic organophosphorus compound of this type is bisphenol A bis(diphenyl phosphate), also known as BPADP, wherein R¹⁶, R¹⁷, R¹⁸, and R¹⁹are each phenyl, each n is 1, and q is from 1 to 5, from 1 to 2, or 1.
Organophosphorus compounds containing at least one phosphorus-nitrogen bond includes phosphazenes, phosphorus ester amides, phosphoric acid amides, phosphonic acid amides, phosphinic acid amides, and tris(aziridinyl) phosphine oxide. Phosphazenes (11) and cyclic phosphazenes (12)
in particular can used, wherein w1 is 3 to 10,000 and w2 is 3 to 25, specifically 3 to 7, and each R^wis independently a C_1-12alkyl, alkenyl, alkoxy, aryl, aryloxy, or polyoxyalkylene group. In the foregoing groups at least one hydrogen atom of these groups can be substituted with a group having an N, S, O, or F atom, or an amino group. For example, each R^wcan be a substituted or unsubstituted phenoxy, an amino, or a polyoxyalkylene group. Any given R^wcan further be a crosslink to another phosphazene group. Exemplary crosslinks include bisphenol groups, for example bisphenol A groups. Examples include phenoxy cyclotriphosphazene, octaphenoxy cyclotetraphosphazene decaphenoxy cyclopentaphosphazene, and the like. A combination of different phosphazenes can be used. A number of phosphazenes and their synthesis are described in H. R. Allcook, “Phosphorus-Nitrogen Compounds” Academic Press (1972), and J. E. Mark et al., “Inorganic Polymers” Prentice-Hall International, Inc. (1992).
Depending on the particular organophosphorus compound used, the polycarbonate compositions can comprise 0.5 to 15 wt % or 3.5 to 12 wt % of the organophosphorus flame retardant, each based on the total weight of the composition. Specifically, the organophosphorus compounds can be bisphenol A bis(diphenyl phosphate), triphenyl phosphate, resorcinol bis(diphenyl phosphate), tricresyl phosphate, or a combination thereof.
The polycarbonate compositions can further comprise a cyclic siloxane and/or a linear siloxane to impart fire/flame-retardant properties. The cyclic siloxane can include those with the general formula below
wherein R is each independently C_1-36alkyl, fluorinated or perfluorinated C_1-36alkyl, C_1-36alkoxy, C_6-14aryl, aryloxy of 6 to 14 carbon atoms, arylalkoxy of 7 to 36 carbon atoms, or C_1-36alkyl-substituted aryl of 6 to 14 carbon atoms. In an embodiment, at least one R may be a phenyl. Examples of cyclic siloxanes include, but not limited to, a cyclic phenyl containing siloxane, octaphenylcyclotetrasiloxane, hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, trimethyltriphenylcyclotrisiloxane, and tetramethyltetraphenylcyclotetrasiloxane. Octaphenylcyclotetrasiloxane is specifically mentioned.
Linear siloxanes can also be used. The linear siloxanes can be a linear phenyl containing siloxane such as a poly(phenylmethylsiloxane). In an embodiment, the polycarbonate compositions contain 0.01% to 1% of a cyclic siloxane, a linear siloxane, or a combination thereof.
The polycarbonate compositions can be manufactured by various methods known in the art. For example, powdered polycarbonate, and other optional components are first blended, optionally with any fillers, in a high speed mixer or by hand mixing. The blend is then fed into the throat of a twin-screw extruder via a hopper. Alternatively, at least one of the components can be incorporated into the composition by feeding it directly into the extruder at the throat and/or downstream through a sidestuffer, or by being compounded into a masterbatch with a desired polymer and fed into the extruder. The extruder is generally operated at a temperature higher than that necessary to cause the composition to flow. The extrudate can be immediately quenched in a water bath and pelletized. The pellets so prepared can be one-fourth inch long or less as desired. Such pellets can be used for subsequent molding, shaping, or forming.
The polycarbonate compositions can have a glass transition temperature of 155° C. or higher, preferably 155° C. to 280° C., more preferably 165° C. to 260° C., and even more preferably 185° C. to 230° C., determined by differential scanning calorimetry (DSC) as per ASTM D3418 with a 20° C./min heating rate.
The polycarbonate compositions can have high heat resistance. The heat deflection temperature (HDT) of the polycarbonate compositions is 150° C. or higher, preferably 150 to 270° C., more preferably 155 to 260° C., even more preferably 175 to 220° C., measured flat on a 80×10×4 mm bar with a 64 mm span at 0.45 MPa according to ISO 75/Bf.
The polycarbonate compositions can have high Vicat softening temperature. In an embodiment, the polycarbonate compositions have a Vicat B 120 of a Vicat B 120 of 155° C. or higher, preferably 165° C. or higher, more preferably 180° C. or higher as measured according to ISO 306.
The polycarbonate compositions can have excellent transparency. In an embodiment, the polycarbonate compositions have a haze less of less than 1.5, more preferably less than 1.0, more preferably less than 0.5%, and a transmission greater than 86%, more preferably greater than 88%, more preferably greater than 89%, even more preferably greater than 90%, each measured according to ASTM D1003-00 using the color space CIE1931 (Illuminant C and a 2° observer) with a 1.0 mm thickness. The polycarbonate compositions can have a haze of less than 1.5, or less than 1.0 and a total transmission greater than 84% or greater than 86%, each measured according to ASTM D1003-00 using the color space CIE1931 (Illuminant C and a 2° observer) on a molded plaque with a 3.0 mm thickness. The polycarbonate compositions are molded under standard molding conditions in range of 300 to 350° C. depending on the glass transition temperature of the composition. For example, the polycarbonate compositions are molded at a temperature of 100° C. to 175° C. above the glass transition temperature of the polycarbonate composition for a residence time of 2 to 20 minutes.
The polycarbonate compositions can have excellent transparency in the infrared wavelength range. In an embodiment, the polycarbonate compositions have a transmission at wavelength of 940 nm of greater than 88%, or greater than 89% or greater than 90% measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on a molded plaque with a thickness of 1 mm; and a refractive index of greater than 1.59 or greater than 1.60 at 587.6 nm or a refractive index of greater than 1.57 or greater than 1.58 at 940 nm measured according to IS 489 on a molded plaque with a thickness of 1 mm. The compositions can have a transmission at wavelength of 840 nm of greater than 88.0%, preferably greater than 89.0%, more preferably greater than 90.0%, as measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on 1 mm. The compositions have a transmission at wavelength of 550 nm of greater than 85%, or greater than 87% or greater than 88% measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on a molded plaque with a thickness of 1 mm; and the compositions can have a transmission at wavelength of 400 nm of greater than 75%, or greater than 80% or greater than 85% measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on a molded plaque with a thickness of 1 mm. In still another embodiment, the compositions have a transmission at wavelength of 1310 nm of greater than 87%, preferably greater than 88.0%, more preferably greater than 89.0%, as measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on 1 mm.
The polycarbonate compositions have an Abbe number of less than 32 or less than 30 measured according to ISO 489 on a molded plaque with a thickness of 1 mm.
The polycarbonate compositions have a melt volume flow rate (MVR) greater than 10 cc/min or greater than 12 cc/min or greater than 15 cc/min, measured at 330° C./2.16 Kg at 360 second dwell according to ISO 1133.
The polycarbonate compositions have an Izod notched impact energy of at least 6 kJ/m², or of at least 8 kJ/m², as measured at 23° C. according to ISO 180/1A using a multipurpose test specimen in accordance with ISO 3167 TYPE A. The polycarbonate compositions can have an Izod notched impact energy of at least 70 J/m, or of at least 88 J/m, as measured at 23° C. according to ASTM D256.
The polycarbonate compositions have excellent color stability during exposure for prolonged time at elevated temperatures in the absence of moisture, referred to further as heat ageing. The polycarbonate compositions can have an increase in yellowness index of less than 5, less than 4, more preferably less than 3, during 1500 hours of heat aging at 140° C., as measured by ASTM D1925 on a 1.0 mm thick molded plaque. The polycarbonate compositions have an increase in yellowness index of less than 15, equal to or less than 10, or equal to or less than 7 during 1000 hours of heat aging at 155° C., as measured by ASTM D1925 on a 1 mm thick molded plaque. In an embodiment, the polycarbonate compositions can have an increase in yellowness index of less than 10, more preferably less than 8, more preferably less than 6, during 1500 hours of heat aging at 155° C., as measured by ASTM D1925 on a 1.0 mm thick molded plaque. The polycarbonate compositions can have an increase in yellowness index of less than 20, more preferably less than 10, more preferably less than 5, during 1000 hours of heat aging at 160° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque. In still another embodiment, the polycarbonate compositions can have an increase in yellowness index of less than 20, more preferably less than 10, more preferably less than 5, during 500 hours of heat aging at 170° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque.
The polycarbonate compositions have excellent color stability during exposure for prolonged time at elevated temperatures in the presence of moisture, referred to further as hydro ageing. In an embodiment, the polycarbonate compositions have an increase in yellowness index of less than 5, more preferably less than 3, more preferably less than 1, after 1000 hours of hydro ageing at 80° C. and 85% relative humidity, as measured by ASTM D1925 on a 2.5 mm thick molded plaque. In another embodiment, the polycarbonate compositions have an increase in yellowness index of less than 0.5, or of less than 0.3 after 100 hours of hydro ageing at 121° C. in an autoclave, as measured by ASTM D1925 on a 2.5 mm thick molded plaque.
The polycarbonate compositions have excellent color stability during exposure for prolonged time to autoclave conditions or multiple cycle of autoclave sterilization. In an embodiment, the polycarbonate compositions have an increase in yellowness index of less than 2, more preferably less than 1, after 100 hours of autoclaving at 121° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque. In another embodiment, the polycarbonate compositions have an increase in yellowness index of less than 5, more preferably less than 3, more preferably less than 1, after 100 hours of autoclaving at 134° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque. In an embodiment, the polycarbonate compositions have an increase in yellowness index of less than 10, more preferably less than 5, more preferably less than 3, after 100 hours of autoclaving at 143° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque.
The polycarbonate compositions can have excellent color after molding under demanding conditions. In an embodiment, the polycarbonate compositions have a yellowness index of less than 20, more preferably less than 10, more preferably less than 5, more preferably less than 3, as measured by ASTM D1925 on a 2.5 mm plaque. For example, the polycarbonate compositions are molded at a temperature of 100 to 175° C. above the glass transition temperature of the polycarbonate composition for a residence time of 2 to 20 minutes. Typical conditions would be molding at melt temperatures of 350° C. or higher and residence times of 3 min or longer.
In an embodiment, the polycarbonate composition has a yellowness index which is at least 20% or at least 30% lower compared to the same composition having a Bisphenol A purity below 99.6% or below 99.5%, as measured by ASTM D1925 on a 2.5 mm thick molded plaque with a melt temperature of 355° C. and a residence time of 10 min. In another embodiment, the polycarbonate compositions have a yellowness index of less than 10 measured according to ASTM D1925 on a plaque of 2.5 mm thickness molded at a temperature of 355° C. for a residence time of 10 minutes.
The polycarbonate compositions can have a change in yellowness index of less than 100%, more preferably less than 50%, more preferably less than 30%, following molding under aggressive conditions as compared to a reference article of an identical composition molded under standard process conditions, when tested at thickness of 2.5 mm determined according to ASTM D1925. As used herein, aggressive molding conditions include a molding temperature of equal to or greater than 330° C., and standard molding conditions include a molding temperature of less than 330° C.
The polycarbonate compositions can have a yellowness index (YI) determined according to ASTM D1925 at least 30% lower, more preferably at least 50% lower, more preferably at least 75% lower, as compared to a reference sample of an otherwise identical composition
A molded part of the composition with a thickness of 2.5 mm has a yellowness index (YI) determined according to ASTM D1925 at least 30% lower, more preferably at least 50% lower, more preferably at least 75% lower, as compared to the same composition having a Bisphenol A purity below 99.6% or below 99.5%, following molding at a temperature of equal to or greater than 330° C. for a residence time of 10 minutes.
The polycarbonate compositions can have good flame retardant properties. Flammability tests are performed following the procedure of Underwriter's Laboratory Bulletin 94 entitled “Tests for Flammability of Plastic Materials for Parts in Devices and Appliances” (ISBN 0-7629-0082-2), Fifth Edition, Dated Oct. 29, 1996, incorporating revisions through and including Dec. 12, 2003. Several ratings can be applied based on the rate of burning, time to extinguish, ability to resist dripping, and whether or not drips are burning. According to this procedure, materials can be classified as HB, V0, UL94 V1, V2, VA and/or VB. In an embodiment, the polycarbonate compositions have a UL94-V0 rating at a thickness of 2.5 mm or higher; or a UL94-V2 rating at a thickness of 0.8 mm to 1.5 mm.
The polycarbonate compositions can be provided as pellets, and are useful to form lenses by a variety of methods. All known methods can be used. Exemplary methods include via multi-cavity tools; molding such as injection molding, gas assist injection molding, vacuum molding, extrusion, compression molding, calendaring, rotary molding, heat/cool molding, blow molding, overmolding, transfer molding, cavity molding, thermoforming, or casting.
Advantageously, the lenses have no significant part distortion or discoloration when the lenses are subjected to a secondary operation such as over-molding, lead-free soldering, low temperature soldering, or coating with high temperature curing, or a combination thereof. High temperature cure of a coating can be, for example, 100° C. or higher, for example 100 to 250° C. In some embodiments, “no significant part distortion” includes a volume distortion of less than 10 volume percent (vol %), or less than 5 vol %, or less than 1 vol %. Significant discoloration can be detected by the unaided eye at a distance of 18 inches. The polycarbonate compositions, which has good flow (MVR) for excellent mold filling properties while maintaining desirable mechanical properties can, in the manufacture of lenses, provide a high degree of reproducibility for successive lenses molded from the polycarbonate composition.
The lenses can be defined by several dimensional features such as thickness, effective lens area, diameter of an effective lens area, and an overall diameter. Lens thickness, as defined herein, is measured at the center of the lens (i.e., along the z axis, orthogonal to the diameter of the lens which is measured in the x-y plane of the lens). Since lenses have curvature, the thickness of the lens may vary along the contour of the surface. Also, depending upon the type of the lens (convex, concave, etc.) the variation of the thickness can differ widely. In an embodiment, the lens has a thickness of a thickness of 0.1 mm to 50 cm, or 0.1 mm to 10 cm, 0.1 mm to 1 cm, or 0.1 mm to 0.5 cm, or 0.1 mm to 50 mm, measured at the thickest part of the lens. In a specific embodiment, the lens has a thickness of 0.25 to 2.5 mm, or 0.5 to 2.4 mm, or 0.8 to 2.3 mm, measured at the center of the lens.
The size of the lens is characterized by the term “effective lens area”, which is defined as the area of the lens where the curvature is positive, and hence light which is refracted through this area is usable in actual imaging. “Curvature” as defined herein, is the reciprocal of the optical radius of the lens (as defined by the light path). For example a flat surface has infinite radius and therefore zero curvature. For those lenses that include a flat portion around the periphery of the lens, which is used for mounting the lens into the optical assembly, this flat portion is not considered part of the effective lens area. A typical lens has at least two surfaces, a first and a second surface. On the first (incident) surface, light enters the lens and exits through the second (refractive) surface. One or both of these surfaces may have a curvature. The effective lens area as defined above may be the same for the first and second surfaces, or may be different for the first and second surfaces. Where different, the larger value of the effective surface area for the first and second surfaces is considered to be the effective lens area for the overall lens. The lens can have an effective lens area of 0.2 mm²to 10 m², or 0.2 mm²to 1 m², or 0.2 mm²to 10 cm², or 0.2 mm²to 5 mm², or 0.2 mm²to 100 mm²
Effective lens area diameter as defined herein describes the diameter measured at the outermost periphery of the effective (optically useable) area of the lens; whereas overall diameter of the lens is the diameter which includes the non-optically relevant flat portion. The lenses disclosed herein can have a diameter of an effective lens area of 0.1 mm to 500 cm, or 0.25 mm to 50 cm, or 0.5 mm to 1 cm, or 0.5 mm to 10 mm; or an overall diameter of 0.1 mm to 2 m, or 0.25 mm to 100 cm, or 0.5 mm to 2 cm, or 0.5 mm to 20 mm.
The lens can have an overall diameter of 0.1 mm to 500 cm, or 0.25 mm to 100 cm, or 0.5 mm to 2 cm, or 0.5 mm to 20 mm.
The lenses can have surface textures such as a macrotexture, a microtexture, a nanotexture, or a combination thereof on a surface of the lenses. Textures can be imparted to the lenses using methods known in the art including but not limited to calendaring or embossing techniques. In an embodiment, the lenses can pass through a gap between a pair of rolls with at least one roll having an embossed pattern thereon, to transfer the embossed pattern to a surface of the lenses. Textures can be applied to control gloss or reflection.
The shape of the lenses is not particularly limited. The lenses can also have different types. For example, the lenses can be a flat or planar lens, a curved lens, a cylindrical lens, a toric or sphero-cylindrical lens, a fresnel lens, a convex lens, a biconvex lens, a concave lens, a biconcave lens, a convex-concave lens, a plano-convex lens, a plano-concave lens, a lenticular lens, a gradient index lens, an axicon lens, a conical lens, an astigmatic lens, an aspheric lens, a corrective lens, a diverging lens, a converging lens, a compound lens, a photographic lens, a doublet lens, a triplet lens, an achromatic lens, or a multi-array lens.
The lenses can further comprise an indicia or a coating disposed on at least a portion of one or both sides of the copolycarbonate lens to impart additional properties such as scratch resistance, ultra violet light resistance, aesthetic appeal, hydrophilicity, hydrophobicity, and the like. In an embodiment, the coating is a hard coat, a UV protective coat, an anti-refractive coat, an anti-reflective coat, a scratch resistant coat, a hydrophobic coat, a hydrophilic coat, or a combination comprising at least one of the foregoing.
Coatings can be applied through standard application techniques such as overmolding, rolling, spraying, dipping, brushing, flow coating, wiping, knife coating, notch coating, reverse roll coating, gravure coating, soaking, bar coating, flood coating, spin coating or combinations comprising at least one of the foregoing application techniques.
The coating can be in any suitable form including a continuous or discontinuous layer (e.g., in a pattern, dots, stripes and swirls) and can be the result of multiple layers disposed on top of one another.
The coating can be applied at any thickness as long as the coating does not substantially change the appearance and optical characteristics of the lenses. In an embodiment, the coating has a thickness of from 1 micron to 100 microns, from 1 micron to 10 microns, from 2 microns to 5 microns, 20 Angstroms to 1 micron, or even from 40 nanometers to 100 nanometers.
Depending on the applications, at least a portion of a surface of the lens is metallized in some embodiments. A metal layer can be disposed onto the surface of the lenses with the aid of electrocoating deposition, physical vapor deposition, or chemical vapor deposition or a suitable combination of these methods. Sputtering processes can also be used. The metal layer resulting from the metallizing process (e.g., by vapor deposition) can be 0.001 to 50 micrometers (μm) thick. Chrome, nickel, aluminum, and the like can be listed as examples of vaporizing metals. Aluminum vapor deposition is used in one embodiment as metal vapor deposition. The surface of the molded substrate can be treated with plasma, cleaned, or degreased before vapor deposition in order to increase adhesion.
The lenses can have low birefringence, which means that the lenses can have low light distortion and a better quality image.
Exemplary lenses include a camera lens, a sensor lens, an illumination lens, a safety glass lens, an ophthalmic corrective lens, or an imaging lens.
The foregoing types of lenses can be used in a wide variety of applications. For example, the camera lens can be a mobile phone camera lens, a table camera lens, a security camera lens, a mobile phone camera lens, a tablet camera lens, a laptop camera lens, a security camera lens, a camera sensor lens, or a vehicle camera lens (e.g., an automotive camera lens).
The sensor lens can be a motion detector lens, a proximity sensor lens, a gesture control lens, an infrared sensor lens, or a camera sensor lens.
The illumination lens can be an indoor lighting lens, an outdoor lighting lens, vehicle headlamp lens, a vehicle foglight lens, a vehicle rearlight lens, a vehicle running light lens, a vehicle foglight lens, a vehicle interior lens, an a light emitting diode (LED) lens, or an organic light emitting diode (OLED) lens.
The safety glass lens is a glasses lens, a goggles lens, a visor, a helmet lens, or other protective gear.
The ophthalmic corrective lens can be incorporated into monocles, corrective glasses (including bifocals, trifocals, progressive lens, and the like), contact lenses, and the like.
The imaging lens can be a scanner lens, a projector lens, a magnifying glass lens, a microscope lens, a telescope lens, a security lens, reading glasses lens, and the like.
Accordingly, the lenses can be incorporated into a wide variety of devices, including a camera (including reflex cameras), an electronic device (such as mobile phones, tablets, laptop computers, and desk computers), a vehicle (which as used herein refers to any transportation devices, for example bicycles, scooters, motorcycles, automobiles, buses, trains, boats, ships, and aircraft) a flashlight, a business machine (such as a copier or a scanner), a lighting device (including indoor lighting such as table lamps and ceiling lights, outdoor lighting such as floodlights and streetlights, vehicle headlights, rearlights, side lights, running lights, foglights, and interior lights), an imaging device (such as a microscope, a telescope, a projector, a security lens (e.g. in a door), or reading glasses), a safety article (such as goggles, glasses, and headgear such as helmets), a vision corrective article (glasses or contact lens), or a toy.
The polycarbonate compositions are further illustrated by the following non-limiting examples.

EXAMPLES

The materials used in the Examples are described in Table 1.

TABLE 1

Component	Chemical Description	Source

CPC-1	PPP-BP (N-phenylphenolphthaleinylbisphenol, 2,2-bis(4-hydro) - bisphenol A	SABIC
	copolycarbonate, 33 mol % PPP-BP, Mw = 21-25 kDa as determined by GPC using
	bisphenol A polycarbonate standards, para-cumylphenol (PCP) end-capped, with BPA
	carbonate units derived from BPA having 99.4-99.5% purity
CPC-2	PPP-BP (N-phenylphenolphthaleinylbisphenol, 2,2-bis(4-hydro) - Bisphenol A	SABIC
	polycarbonate copolymer, 33 mol % PPP-BP, Mw = 22-23 kDa as determined by GPC using
	BPA polycarbonate standards, para-cumylphenol (PCP) end-capped, with BPA carbonate
	units derived from BPA having 99.7% purity
PC-1A	Linear Bisphenol A polycarbonate, produced via interfacial polymerization from BPA	SABIC
	having a purity of 99.4-99.5% wt % determined by HPLC, Mw = 30-31 kDa as determined
	by GPC using BPA polycarbonate standards, phenol end-capped
PC-1B	Linear Bisphenol A polycarbonate, produced via interfacial polymerization from BPA	SABIC
	having a purity of 99.7 wt % determined by HPLC, Mw = 30-31 kDa as determined by GPC
	using BPA polycarbonate standards, phenol end-capped
PC-2A	Linear Bisphenol A polycarbonate, produced via interfacial polymerization from BPA	SABIC
	having a purity of 99.4-99.5% wt % determined by HPLC, Mw = 22-23 kDa as determined
	by GPC using BPA polycarbonate standards, PCP end-capped
PC-2B	Linear Bisphenol A polycarbonate, produced via interfacial polymerization from BPA	SABIC
	having a purity of 99.7 wt % determined by HPLC, Mw = 22-23 kDa as determined by GPC
	using BPA polycarbonate standards, PCP end-capped
PC3	Linear Bisphenol A polycarbonate, produced via interfacial polymerization from BPA	SABIC
	having a purity of 99.4-99.5 wt % determined by HPLC, Mw = 18-19 kDa as determined by
	GPC using BPA polycarbonate standards, PCP end-capped.
Tosylate	Premix of 0.06 wt % of butyl tosylate in PC-2A	SABIC
Premix-1
Tosylate	Premix of 0.3 wt % of butyl tosylate in PC-2A	SABIC
Premix-2
AO-1	Tris(2,4-di-t-butylphenyl)phosphite (IRGAFOS 168)	Ciba
AO-2	Octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate IRGANOX 1076	BASF
PETS	Palmitic/stearic acid (50/50) ester of dipenta/pentaerythritol (Loxiol EP8578)	Cognis
		Oleochemicals
H₃PO₃	Premix of 0.6262 wt % of a 45 wt % of phosphorous acid aqueous solution in PC-1	Aldrich
Premix
UVA 234	2-[2-hydroxy-3,5-di-(1,1-dimethylbenzyl)]-2H-benzotriazol	BASF

Blending, Extrusion, and Molding Conditions

The compositions were made as follows. All solid were dry blended off-line as concentrates using one of the primary polymer powders as a carrier and starve-fed via gravimetric feeder(s) into the feed throat of the extruder. The remaining polymer(s) were starve-fed via gravimetric feeder(s) into the feed throat of the extruder as well. The liquid additives, if any, were fed before the vacuum using a liquid injection system. It will be recognized by one skilled in the art that the method is not limited to these processing steps or processing equipment.
Extrusion of all materials was performed on a 25 mm Werner-Pfleiderer ZAK twin-screw extruder (L/D ratio of 33/1) with a vacuum port located near the die face. The extruder has 9 zones, which were set at temperatures of 40° C. (feed zone), 200° C. (zone 1), 250° C. (zone 2), 270° C. (zone 3) and 290-330° C. (zone 4 to 8). Screw speed was 300 rpm and throughput was between 10 and 25 kg/hr. It will be recognized by one skilled in the art that the method is not limited to these temperatures or processing equipment.
The compositions were molded after drying at 100-110° C. for 6 hours on a 45-ton Engel molding machine with 22 mm screw or 75-ton Engel molding machine with 30 mm screw operating at a temperature 310 to 360° C. with a mold temperature of 80 to 150° C. It will be recognized by one skilled in the art that the method is not limited to these temperatures or processing equipment.

Testing Methods

Yellowness Index (YI) was calculated from the transmission spectrum from a MacBeth ColorEye7000A according to ASTM D1925, at 1.0 mm or 2.5 mm thickness as specified in the examples.
Tensile stress and tensile modulus were measured in accordance with ISO 527 with speed of 50 mm/min.
Flexural stress and flexural modulus were measured in accordance with ISO 178.
ASTM Izod notched impact energy was as measured at 23° C. according to ASTM D256 using a 80 mm×10 mm×4 mm specimen.
ISO notched Izod impact was measured at 23° C. according to ISO 180/1A using a multipurpose test specimen in accordance with ISO 3167 TYPE.
A Vicat B 120 softening temperature was measured according to ISO 306.
Heat deflection temperature (HDT) was measured flat on a 80 mm×10 mm×4 mm bar with a 64 mm span at 0.45 MPa according to ISO 75/Bf.
Melt volume flow rate (MVR) was measured at 330° C./2.16 Kg at 300 second dwell according to ISO 1133.
Transmission at 400 nm, 550 nm, 940 nm, or 1310 nm was measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on a molded plaque with a thickness of 1 mm, 2 mm, or 3 mm.
Haze was measured according to ASTM D1003-00 on a molded plaque with thickness between 1 and 3 mm.
Refractive index was measured according to ISO 489 on a molded plaque with a thickness of 1 mm.
Abbe number was measured according to ISO 489 on a molded plaque with a thickness of 1 mm.
Flammability tests were performed following the procedure of Underwriter's Laboratory Bulletin 94 entitled “Tests for Flammability of Plastic Materials for Parts in Devices and Appliances” (ISBN 0-7629-0082-2), Fifth Edition, Dated Oct. 29, 1996, incorporating revisions through and including Dec. 12, 2003. Several ratings can be applied based on the rate of burning, time to extinguish, ability to resist dripping, and whether or not drips are burning. According to this procedure, materials can be classified as HB, UL94 V0, V1, V2, VA, and/or VB.

BPA Purity Determination

The BPA purity was determined on the compositions and/or on the polycarbonate or copolycarbonate.
About 200 milligrams (mg) of the sample was weighed. It was dissolved in 5 ml of tetrahydrofuran (THF) and 2 ml of a 10% solution of potassium hydroxide diluted in methanol. The depolymerization of polycarbonate was carried out with the use of these solvents.
The solution was shaken for 2 hours. Then, 2 milliliters (ml) of acetic acid was added to protonate the BPA carbonate salts and decrease the pH. The solution was shaken again for half an hour for homogenization and dissolution of all precipitates.
The device used for the HPLC analysis was an Agilent 1100 system. The software used was Agilent ChemStation. The analysis was carried out on a C18 column. A gradient of polar solvents was used. It was a mixture of water and methanol. THF was used at the end of the analysis to clean the column.
The impurities concentration in the depolymerized composition is determined by HPLC. Then, the BPA purity can be deduced via the equation:
wt % of BPA purity=100%-wt % of impurities in depolymerized composition*254/228.

Examples 1 and Comparative Example 2

Example 1 and comparative example 2 demonstrate the effect of using bisphenol A homopolycarbonate made from a high purity BPA on color stability when blended with PPPBP-BPA copolycarbonate and molded under aggressive molding conditions. Formulations and results are shown in Table 2.

TABLE 2

Component	Unit	Ex 1	CEx 2

CPC-1	Wt %	63.70	63.70
PC-1B	Wt %	11.30
PC-1A	Wt %		11.30
PC-2B	Wt %	23.95
PC-2A	Wt %		23.95
PETS	Wt %	0.30	0.30
AO-1	Wt %	0.08	0.08
AO-2	Wt %	0.04	0.04
UVA 234	Wt %	0.30	0.30
Tosylate premix	Wt %	0.33	0.33
Total	Wt %	100	100
Tosylate	ppm	4	4
BPA purity	%	99.5	99.4
Property
YI after molding at 310° C./5 min		2.79	2.97
YI after molding at 335° C./10 min		3.72	4.04
YI after molding at 355° C./5 min		3.45	4.06
YI after molding at 355° C./10 min		4.21	6.87
YI after molding at 355° C./15 min		5.03	10.26

The data in Table 2 indicates that the use of bisphenol A homopolycarbonate derived from a high purity BPA (Ex1) provides improved color stability as compared to a composition containing a bisphenol A homopolycarbonate derived from a lower purity BPA (CEx2) when samples are molded at a standard temperature (310° C.) as well as at aggressive temperatures (335° C. and 355° C.). The difference is more pronounced at high temperatures, where the color improvement is almost 50% (355° C./15) and 39% at 355/10 min

Examples 3-10

Examples 3-10 demonstrate that effect of using PPPBP-BPA copolycarbonate derived from a high purity BPA on color stability under various molding conditions. Formulations and results are shown in Table 3.

TABLE 3

Component (wt %)	Ex3	CEx4	Ex5	CEx6	Ex7	CEx8	Ex9	CEx10

CPC-1		99.59		98.58		98.25		99.47
CPC-2	99.59		98.58		98.25		99.47
PETS	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3
AO-1	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08
AO-2	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04
H₃PO₃premix							0.11	0.11
Tosylate premix-1			1.00	1.00	1.33	1.33
Tosylate premix-2
Total	100	100	100	100	100	100	100	100
Tosylate content (ppm)	0	0	6	6	8	8	0	0
H₃PO₃content (ppm)	0	0	0	0	0	0	3	3
BPA purity	99.7	99.4	99.7	99.4	99.7	99.4	99.7	99.4
YI after molding*
at 330° C./5 min	2.9	3.72	2.9	2.84	2.8	2.82	3.4	3.55
at 355° C./10 min	24.9	35.59	7.6	15.71	6.5	9.25	21.1	26.74
YI improvement vs CEx at	−30		−52		−30		−21
355° C./10 min

The results in Table 3 indicate that the use of a PPPBP-BPA copolycarbonate based on a high purity BPA improves color under all molding conditions, compared to the same composition based on less pure BPA (Ex 3 versus CEx4, Ex5 versus CEx6, and so on). The use of an acid stabilizer (butyl tosylate or H₃PO₃) can further improve the color stability of the composition (for example, Ex5 versus Ex3).

Comparative Example 11 and Example 12

Comparative example 11 and Example 12 demonstrate the effect of using BPA homopolycarbonate derived from high purity BPA on color stability after heat aging. Formulations and results are shown in Table 5.

TABLE 5

	Component	Unit	Cex 11	Cex 12

	CPC-1	Wt. %	63.7	63.7
	PC-1A	Wt. %	18.1
	PC-2A	Wt. %	17.8
	PC-1B	Wt. %		18.1
	PC-2B	Wt. %		17.8
	AO-1	Wt. %	0.08	0.08
	PETS	Wt. %	0.3	0.3
	AO-2	Wt. %	0.04	0.04
	Total	Wt. %	100.00	100.00
	BPA purity	%	99.5	99.6
	Property
	Heat aging at 140° C.; ΔYI t = 0*		0	0
	Heat aging at 140° C.; ΔYI t = 2658 hrs		11.5	8.3
	Heat aging at 140° C.; ΔYI t = 5182 hrs		30.3	22.8

*Thickness of 2.5 mm

The results in Table 5 indicate that color shifting after heat aging is significantly improved when using bisphenol A homopolycarbonate derived from a high purity BPA. Comparing Ex 12 with CEx 11, delta YI is decreased from 11.5 to 8.3 after 2658 hours of aging at 140° C. and the delta YI is decreased from 30.3 to 22.8 after 5000 hours of aging at 140° C.

Examples 13-26

Examples 13-26 demonstrate the effect of using a blend of BPA homopolycarbonate and PPPBP-BPA copolycarbonate, both derived from a high purity, on color stability after heat aging. Formulations and results are shown in Table 6.
The data indicates that blends containing bisphenol A homopolycarbonate and PPPBP-BPA copolycarbonate have excellent color stability after heat aging when both the bisphenol A homopolycarbonate and PPPBP-BPA copolycarbonate are derived from a high purity BPA. The use of a small amount of an acid stabilizer (butyl tosylate or H₃PO₃or a combination thereof) can further improve the color stability of the blends after standard or abusive molding.

Examples 27-30

Examples 27-30 compare the heat aging performance of compositions containing a standard or high purity PPPBP-BPA copolycarbonate and a standard or high purity bisphenol A homopolycarbonate, and an ultraviolet light stabilizer, with or without the presence of an acid stabilizer. Formulations and results are shown in Table 7.
The data indicates that blends containing high purity bisphenol A homopolycarbonate and high purity PPPBP-BPA copolycarbonate (99.7% purity for total composition) have better color stability after heat aging as compared to blends containing standard purity bisphenol A homopolycarbonate and standard purity PPPBP-BAP copolycarbonate (99.4% purity for total composition).

TABLE 6

Component
(wt %)	Ex 13	Ex 14	Ex 15	Ex 16	Ex 17	Ex 18	Ex 19	Ex 20	Ex 21	Ex 22	Ex 23	Ex 24	Ex 25	Ex 26

CPC-2	63.7	63.7	63.7	63.7	63.7	63.7	63.7	63.7	63.7	63.7	63.7	63.7	63.7	63.7
PC-1B					35.58	35.48	35.38	35.42	35.37	35.47
PC-2B	35.58	35.58	35.42	35.37
PC3											35.58	35.48	35.42	35.37
PETS	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3
AO-1	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08
AO-2	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04	0.04
UVA 234	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3
H₃PO₃premix			0.055	0.11				0.055	0.11	0.11			0.055	0.11
Tosylate		0.10	0.10	0.10		0.10	0.20	0.10	0.10			0.10	0.10	0.10
premix-2
Total	100	100	100	100	100	100	100	100	100	100	100	100	100	100
Property
YI after
molding*
at 310° C./	2.1	1.7	1.8	1.7	2.3	1.8	1.8	1.7	1.8	1.8	2.2	1.8	1.8	1.7
5 min
at 330° C./	3.7	2.0	2.0	2.0	4.7	2.1	1.9	2.0	1.9	2.3	3.8	2.0	1.9	1.9
10 min

YI after heat aging*

140° C./0 h	2.1	1.7	1.8	1.7	2.3	1.8	1.8	1.7	1.8	1.8	2.2	1.8	1.8	1.7
140° C./200 h	2.4	2.1	2.2	2.2	2.4	2.1	2.2	2.2	2.2	2.1	2.1	2.2	2.2	2.2
140° C./550 h	2.9	2.4	2.6	2.6	2.6	2.5	2.6	2.6	2.6	2.5	2.3	2.5	2.7	2.7
140° C./1000 h	3.9	3.0	3.2	3.4	3.0	3.1	3.2	3.2	3.2	3.0	2.7	3.1	3.4	3.4
140° C./1500 h	5.3	3.8	4.1	4.4	3.5	3.9	4.1	4.0	4.0	3.8	3.2	3.9	4.2	4.2

Delta YI after heat ageing at 140° C. compared to 0 hrs

140° C./200 h	0.3	0.4	0.4	0.5	0.1	0.3	0.4	0.5	0.4	0.3	-0.1	0.4	0.4	0.5
140° C./550 h	0.8	0.7	0.8	0.9	0.3	0.7	0.8	0.9	0.8	0.7	0.1	0.7	0.9	1
140° C./1000 h	1.8	1.3	1.4	1.7	0.7	1.3	1.4	1.5	1.4	1.2	0.5	1.3	1.6	1.7
140° C./1500 h	3.2	2.1	2.3	2.7	1.2	2.1	2.3	2.3	2.2	2	1	2.1	2.4	2.5
155° C./0 h	2.1	1.7	1.8	1.7	2.3	1.8	1.8	1.7	1.8	1.8	2.2	1.8	1.8	1.7
155° C./150 h	2.7	2.2	2.4	2.4	2.4	2.3	2.3	2.3	2.4	2.3	2.3	2.4	2.4	2.3
155° C./300 h	3.6	2.8	2.9	3.1	2.7	3.0	3.0	3.0	3.1	2.9	2.7	3.1	3.1	3.0
155° C./550 h	5.5	3.8	4.0	4.4	3.4	4.1	4.3	4.2	4.4	4.1	3.4	4.3	4.4	4.3
155° C./1000 h	10.3	6.0	6.4	7.7	5.3	6.7	7.1	7.0	7.4	6.9	5.4	7.1	7.7	7.6
155° C./1500 h	16.6	9.3	10.1	12.5	8.6	10.4	11.3	11.3	12.0	11.2	9.1	11.4	13.0	13.0

Delta YI after heat ageing at 155° C. compared to 0 hrs

155° C./150 h	0.6	0.5	0.6	0.7	0.1	0.5	0.5	0.6	0.6	0.5	0.1	0.6	0.6	0.6
155° C./300 h	1.5	1.1	1.1	1.4	0.4	1.2	1.2	1.3	1.3	1.1	0.5	1.3	1.3	1.3
155° C./550 h	3.4	2.1	2.2	2.7	1.1	2.3	2.5	2.5	2.6	2.3	1.2	2.5	2.6	2.6
155° C./1000 h	8.2	4.3	4.6	6	3	4.9	5.3	5.3	5.6	5.1	3.2	5.3	5.9	5.9
155° C./1500 h	14.5	7.6	8.3	10.8	6.3	8.6	9.5	9.6	10.2	9.4	6.9	9.6	11.2	11.3

*All the samples tested have a thickness of 1 mm

TABLE 7

Component (wt %)	CEx 27	Ex 28	CEx 29	Ex 30

CPC-1	63.7		63.7
CPC-2		63.7		63.7
PC-1A	24.6		23.0
PC-1B		24.6		23.0
PC-2A	11.3		11.3
PC-2B		11.3		11.3
PETS	0.3	0.3	0.3	0.3
AO-1	0.08	0.08	0.08	0.08
AO-2	0.04	0.04	0.04	0.04
UVA 234	0.3	0.3	0.3	0.3
Tosylate premix-1	0	0	1.33	1.33
Total	100	100	100	100
Tosylate content (ppm)	0	0	8	8
BPA Purity	99.4	99.7	99.4	99.7
Property

YI after heat aging*

140° C./0 h	3.1	3.3	3.0	3.2
140° C./500 h	4.2	3.9	5.0	4.8
140° C./3000 h	12.0	8.2	19.1	14.5
140° C./4000 h	13.3	8.9	21.3	16.1

Delta YI after heat ageing at 140° C. compared to 0 hrs

140° C./500 h	1.1	0.6	2	1.6
140° C./3000 h	8.9	4.9	16.1	11.3
140° C./4000 h	10.2	5.6	18.3	12.9
155° C./0 h	3.1	3.3	3.0	3.1
155° C./100 h	3.7	3.4	4.0	4.1
155° C./250 h	4.7	4.0	5.8	5.4
155° C./500 h	7.3	5.1	10.1	8.2
155° C./750 h	10.2	6.4	15.1	11.0
155° C./1500 h	22.6	12.4	35.0	25.3
155° C./2000 h	30.7	17.6	46.6	35.4

Delta YI after heat ageing at 155° C. compared to 0 hrs

155° C./100 h	0.6	0.1	1	1
155° C./250 h	1.6	0.7	2.8	2.3
155° C./500 h	4.2	1.8	7.1	5.1
155° C./750 h	7.1	3.1	12.1	7.9
155° C./1500 h	19.5	9.1	32	22.2
155° C./2000 h	27.6	14.3	43.6	32.3

*All the samples tested have a thickness of 2.5 mm.

TABLE 8

Component (wt %)	Ex 31	Ex 32	Ex 33	Ex 34	Ex 35	Ex 36	Ex 37	Ex 38	Ex 39	Ex 40	CEx 41	CEx 42

CPC-2	99.28	99.21	99.18	99.16	99.15	99.09	99.08	99.01	99.22	99.17
PETS	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3
AO-1	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08	0.08
AO-2	0.03	0.03	0.03	0.03	0.03	0.03	0.03	0.03	0.03	0.03
UVA 234	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3	0.3
H₃PO₃premix			0.028	0.055		0.055			0.055	0.11
Tosylate premix-2		0.668	0.067	0.067	0.134	0.134	0.200	0.267
Total	100	100	100	100	100	100	100	100	100	100
Property
YI after molding*
at 330° C./5 min	4.89	2.79	2.42	2.38	2.54	2.17	2.36	2.34	2.83	2.55	0.75	8.69
at 355° C./10 min	14.80	10.67	11.83	7.84	7.11	5.35	5.78	7.10	12.44	10.92	0.83
at 365° C./5 min											0.87	7.11
at 375° C./5 min												1.12

YI after heat aging*

140° C./0 h	4.20	2.79	2.42	2.38	2.54	2.17	2.36	2.34	2.83	2.55	0.70	10.20
140° C./200 h	4.24	3.10	2.82	2.85	3.09	2.72	2.85	3.03	3.25	2.92
140° C./250 h											1.60	14.33
140° C./550 h	4.54	3.39	3.17	3.26	3.53	3.21	3.32	3.58	3.55	3.25	2.44	17.45
140° C./1000 h	4.99	3.89	3.72	3.93	4.25	4.02	4.13	4.39	4.09	3.80	4.54	24.11
140° C./1500 h	5.71	4.63	4.50	4.85	5.26	5.10	5.19	5.50	4.88	4.62

Delta YI after heat ageing at 140.0 compared to 0 hrs

140° C./200 h	0.04	0.31	0.4	0.47	0.55	0.55	0.49	0.69	0.42	0.37
140° C./250 h											0.9	4.13
140° C./550 h	0.34	0.6	0.75	0.88	0.99	1.04	0.96	1.24	0.72	0.7	1.74	7.25
140° C./1000 h	0.79	1.1	1.3	1.55	1.71	1.85	1.77	2.05	1.26	1.25	3.84	13.91
140° C./1500 h	1.51	1.84	2.08	2.47	2.72	2.93	2.83	3.16	2.05	2.07
155° C./0 h	4.19	2.79	2.42	2.38	2.54	2.17	2.36	2.34	2.83	2.55	0.70	10.20
155° C./100 h											1.85	16.14
155° C./150 h	4.68	3.21	2.89	2.98	3.31	2.97	3.19	3.16	3.49	3.11
155° C./250 h											3.29	21.71
155° C./300 h	5.04	3.57	3.30	3.54	3.90	3.61	3.74	3.86	3.88	3.59
155° C./500 h											6.02	30.09
155° C./550 h	5.81	4.30	4.03	4.42	4.86	4.70	4.82	5.04	4.65	4.40
155° C./1000 h	7.75	6.09	5.89	6.49	7.10	7.02	7.12	7.64	6.65	6.45	14.31	44.84
155° C./1500 h	10.76	8.93	8.87	9.60	10.22	10.38	10.39	11.32	9.64	9.60
155° C./2000 h											35.11	66.55

Delta YI after heat ageing at 155° C. compared to 0 hrs

155° C./100 h											1.15	5.94
155° C./150 h	0.49	0.42	0.47	0.6	0.77	0.8	0.83	0.82	0.66	0.56
155° C./250 h											2.59	11.51
155° C./300 h	0.85	0.78	0.88	1.16	1.36	1.44	1.38	1.52	1.05	1.04
155° C./500 h											5.32	19.89
155° C./550 h	1.62	1.51	1.61	2.04	2.32	2.53	2.46	2.7	1.82	1.85
155° C./1000 h	3.56	3.3	3.47	4.11	4.56	4.85	4.76	5.3	3.82	3.9	13.61	34.64
155° C./1500 h	6.57	6.14	6.45	7.22	7.68	8.21	8.03	8.98	6.81	7.05
155° C./2000 h											34.41	56.35

*All the samples tested have a thickness of 1 mm.

Examples 31-42

Examples 31-42 illustrate the heat aging performance of compositions containing a PPPBP-BPA copolycarbonate derived from a high purity BPA with or without the presence of an acid stabilizer. Formulations and results are shown in Table 8. CEx 41 is commercial product APEC 2097, and CEx 42 is a known formulation U-100.
The data indicates that high purity PPPBP-BPA copolycarbonate has better color stability after heat aging as compared to other known high heat compositions. The presence of a small amount of an acid stabilizer (butyl tosylate, H₃PO₃, or a combination thereof) can further improve the heat aging performance of high purity PPPBP-BPA copolycarbonate.

Examples 43-47

Examples 43-47 compare the heat aging performance of compositions containing a high purity PPPBP-BPA copolycarbonate or a standard purity PPPBP-BPA copolycarbonate with or without the presence of an acid stabilizer. Formulations and results are in Table 9.

TABLE 9

Component (wt %)	CEx 43	Ex 44	CEx 45	Ex 46	CEx 47

CPC-2		98.5801		99.47
CPC-1	98.5801		99.47		99.58
PETS	0.3	0.3	0.3	0.3	0.3
AO-1	0.08	0.08	0.08	0.08	0.08
AO-2	0.04	0.04	0.04	0.04	0.04
H₃PO₃premix			0.11	0.11
Tosylate premix-1	0.9999	0.9999
Total	100	100	100	100	100
Property
YI after heat aging*
155° C./0 h	2.8	2.9	3.5	3.4	3.7
155° C./250 h	5.6	5.1	6.5	4.6	6.1
155° C./500 h	8.2	7.1	19.6	5.8	8.7
155° C./1000 h	14.2	11.4	21.1	8.5	15.3

Delta YI after heat ageing at 155° C. compared to 0 hrs

155° C./250 h	2.8	2.2	3	1.2	2.4
155° C./500 h	5.4	4.2	16.1	2.4	5
155° C./1000 h	11.4	8.5	17.6	5.1	11.6

*The samples tested had a thickness of 2.5 mm and were molded at 330° C. at residence time of five minutes.

The data indicates that high purity PPPBP-BPA copolycarbonate has better color stability after heat aging as compared to standard purity PPPBP-BPA copolycarbonate. The data also shows that the presence of an acid stabilizer (butyl tosylate or H₃PO₃) does not improve the heat aging performance of standard purity PPPBP-BPA copolycarbonate.

Examples 48-53

Examples 48-53 illustrates various properties of compositions containing high purity PPPBP-BPA, butyl tosylate, and optionally a high purity BPA homopolycarbonate. Formulations and results are shown in Table 10. About 0.0002 wt % of a dye package was also present.

TABLE 10

Component	Unit	Ex 48	Ex 49	Ex 50	Ex 51	Ex 52	Ex 53

CPC-2	wt %	63.7	63.7	63.7	99.31	99.01	98.83
PC-1A	wt %	28.68	28.38	23.9	0	0	0
PC-2A	wt %	7	7	11.3	0	0	0
Tosylate premix-2	wt %	0.2	0.2	0.2	0.27	0.27	0.27
AO-1	wt %	0.08	0.08	0.08	0.08	0.08	0.08
AO-2	wt %	0.04	0.04	0.04	0.04	0.04	0.04
PETS	wt %	0.3	0.3	0.3	0.3	0.3	0.3
UVA234	wt %	0	0.3	0.3	0	0.3	0.3
Rimar salt	wt %	0	0	0.08	0	0	0.08
Octaphenylcyclotetrasiloxane	wt %	0	0	0.1	0	0	0.1
Tensile Modulus, 1 mn/min	MPa	2488	2511	2522	2550	2589	2571
Tensile Stress, yield, 50 mm/mm	MPa	76	77	77	82	83	82
Tensile Stress, break, 50 mm/mm	MPa	64	69	67	65	65	65
Tensile Strain, yield, 50 mm/mm	%	6.4	6.9	6.9	7.3	7.3	7.2
Tensile Strain, break, 50 mm/mm	%	60	84	78	40	30	27
Flexural Modulus, 2 mm/mm	MPa	2524	2518	2526	2547	2634	2574
Flexural Stress, yield, 2 mm/mm	MPa	116	117	114	123	125	124
Izod Impact, notched, +23° C.	J/m	89	83	80	74	72	76
Izod Impact, notched, −30° C.	J/m	NA	79	78	73	68	74
Izod Impact, notched* +23° C.	kJ/m²	8	8	8	8	7	7
Izod Impact, notched* −30° C.	kJ/m²	NA	6	7	6	6	7
Vicat Softening Temp, B/120	° C.	173.1	171.7	171.6	192.9	191.0	189.7
HDT	° C.	164.7	165.5	165.4	186.0	185.0	184.4
MVR at 330° C./2.16 kg, 300s	cm³/10 min	29.51	30.77	33.27	14.1	15.0	16.7
Transmission at 400 nm, 1 mm	%	86.5			85.5	71.4	82.9
Transmission at 400 nm, 2 mm	%	84.8			82.4	58.7	78.2
Transmission at 400 nm, 3 mm	%	82.8			79.6	48.5	73.6
Transmission at 550 nm, 1 mm	%	88.1			88.1	87.2	87.8
Transmission at 550 nm, 2 mm	%	86.8			86.7	85.2	86.5
Transmission at 550 nm, 3 mm	%	85.5			85.3	83.1	85.0
Transmission at 940 nm, 1 mm	%	90.3			90.1	90.1	90.0
Transmission at 940 nm, 2 mm	%	90.2			90.0	89.9	89.9
Transmission at 940 nm, 3 mm	%	89.9			89.8	89.8	89.6
Transmission at 1310 nm, 1 mm	%	90.0			89.8	89.8	89.8
Transmission at 1310 nm, 2 mm	%	89.3			89.2	89.1	89.1
Transmission at 1310 nm, 3 mm	%	88.6			88.5	88.5	88.4
Total transmission, 1 mm	%	89.5	89.0	90.0	89.5	88.7	89.3
Total transmission, 2 mm	%	88.4	88.7	88.9	88.1	86.6	88.0
Total transmission, 3 mm	%	87.1	7.4	87.8	86.8	84.7	86.7
Haze, 1 mm	%	0.4	0.3	0.3	0.4	0.4	0.3
Haze, 2 mm	%	0.7	0.3	0.3	0.6	0.6	0.4
Haze, 3 mm	%	0.9	0.4	0.4	0.8	0.8	0.5
Refractive index at 587.6 nm	—	1.602	1.602	NA	1.609	1.609	NA
Refractive index at 940 nm	—	1.583	1.583	NA	1.589	1.589	NA
Refractive index at 1310 nm	—	1.577	1.577	NA	1.583	1.583	NA
Abbe number	—	30	30	NA	29	29	NA
UL94 rating at 2.5 mm	—	NA	NA	V0	NA	NA	V0
UL94 rating at 2.0 mm	—	NA	NA	V2	NA	NA	V2
UL94 rating at 1.5 mm	—	NA	NA	V2	NA	NA	V2
UL94 rating at 0.8 mm	—	NA	NA	V2	NA	NA	V2

Set forth below are various embodiments of the disclosure.

Embodiment 1

A copolycarbonate lens formed from a polycarbonate composition comprising: a copolycarbonate comprising bisphenol A carbonate units and of second carbonate units of the formula (1) wherein R^aand R^bare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy, each R³is independently a C_1-6alkyl, R⁴is hydrogen, C_2-6alkyl or phenyl optionally substituted with 1 to 5 C_1-6alkyl groups, p, q, and j are each independently 0 to 4; and optionally, a bisphenol A homopolycarbonate; wherein the second carbonate units are present in an amount of 10 to 49 mol %, preferably 13 to 40 mol % or 35 to 49 mol %, more preferably 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.6%, or at least 99.7% as determined by high performance liquid chromatography; and wherein the polycarbonate composition has: a Vicat B 120 of 155° C. or higher, preferably 165° C. or higher, more preferably 180° C. or higher as measured according to ISO 306; and an increase in yellowness index of less than 10, or of less than 7 during 1000 hours of heat aging at 155° C., as measured by ASTM D1925 on a 1 mm thick molded plaque.

Embodiment 2

A copolycarbonate lens formed from a polycarbonate composition comprising: a copolycarbonate comprising bisphenol A carbonate units and of second carbonate units of the formula (1) wherein R^aand R^bare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy, each R³is independently a C_1-6alkyl, R⁴is hydrogen, C_2-6alkyl or phenyl optionally substituted with 1 to 5 C_1-6alkyl groups, p, q, and j are each independently 0 to 4; and wherein the second carbonate units are present in an amount of 10 to 49 mol %, preferably 13 to 40 mol % or 35 to 49 mol %, more preferably 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.6%, or at least 99.7% as determined by high performance liquid chromatography; and wherein the polycarbonate composition has: a Vicat B 120 of 155° C. or higher, preferably 165° C. or higher, more preferably 180° C. or higher as measured according to ISO 306; and a yellowness index which is at least 20% or at least 30% lower compared to the same composition having a Bisphenol A purity below 99.6% or below 99.5%, as measured by ASTM D1925 on a 2.5 mm thick molded plaque with a melt temperature of 355° C. and a residence time of 10 min.

Embodiment 3

The copolycarbonate lens of Embodiment 1 or Embodiment 2, wherein the lens is a flat or planar lens, a curved lens, a cylindrical lens, a toric or sphero-cylindrical lens, a fresnel lens, a convex lens, a biconvex lens, a concave lens, a biconcave lens, a convex-concave lens, a plano-convex lens, a plano-concave lens, a lenticular lens, a gradient index lens, an axicon lens, a conical lens, an astigmatic lens, an aspheric lens, a corrective lens, a diverging lens, a converging lens, a compound lens, a photographic lens, a doublet lens, a triplet lens, an achromatic lens, or a multi-array lens.

Embodiment 4

The copolycarbonate lens of any one or more of Embodiments 1 to 3, further comprising a macrotexture, a microtexture, a nanotexture, or a combination thereof on a surface of the lens.

Embodiment 5

The copolycarbonate lens of any one or more of Embodiments 1 to 4, wherein the lens has one or more of: a thickness of 0.1 mm to 50 cm, or 0.1 mm to 10 cm, 0.1 mm to 1 cm, or 0.1 mm to 0.5 cm, or 0.1 mm to 50 mm measured at the thickest part of the lens, preferably a thickness of 0.25 to 2.5 mm, or 0.5 to 2.4 mm, or 0.8 to 2.3 mm, measured at the center of the lens; an effective lens area of 0.2 mm²to 10 m², or 0.2 mm²to 1 m², or 0.2 mm²to 10 cm², or 0.2 mm²to 5 mm², or 0.2 mm²to 100 mm²; a diameter of an effective lens area of 0.1 mm to 500 cm, or 0.25 mm to 50 cm, or 0.5 mm to 1 cm, or 0.5 mm to 10 mm; or an overall diameter of 0.1 mm to 500 cm, or 0.25 mm to 100 cm, or 0.5 mm to 2 cm, or 0.5 mm to 20 mm.

Embodiment 6

The copolycarbonate lens of any one or more of Embodiments 1 to 5, further comprising an indicia or a coating disposed on at least a portion of one or both surface of the polycarbonate lens.

Embodiment 7

The copolycarbonate lens of Embodiment 6, wherein the coating is a hard coat, a UV protective coat, an anti-refractive coat, an anti-reflective coat, a scratch resistant coat, a hydrophobic coat, a hydrophilic coat, or a combination comprising at least one of the foregoing, or wherein at least a portion of a surface of the polycarbonate lens is metallized.

Embodiment 8

The copolycarbonate lens of any Embodiments 1 to 7, wherein the copolycarbonate lens wherein the copolycarbonate lens is a camera lens, a sensor lens, an illumination lens, a safety glass lens, an ophthalmic corrective lens, or an imaging lens.

Embodiment 9

The copolycarbonate lens of Embodiment 8, wherein the camera lens is a mobile phone camera lens, a table camera lens, a security camera lens, a mobile phone camera lens, a tablet camera lens, a laptop camera lens, a security camera lens, a camera sensor lens, or a vehicle camera lens, the sensor lens can be a motion detector lens, a proximity sensor lens, a gesture control lens, an infrared sensor lens, or a camera sensor lens, the illumination lens is an indoor lighting lens, an outdoor lighting lens, vehicle headlamp lens, a vehicle foglight lens, a vehicle rearlight lens, a vehicle running light lens, a vehicle foglight lens, a vehicle interior lens, an a light emitting diode lens, or an organic light emitting diode lens, the safety glass lens is a glasses lens, a goggles lens, a visor, or a helmet lens, the ophthalmic corrective lens is a monocle lens, a corrective glasses lens, or a contact lens, or the imaging lens is a scanner lens, a projector lens, a magnifying glass lens, a microscope lens, a telescope lens, a security lens, or a reading glasses lens.

Embodiment 10

The copolycarbonate lens of any one or more of Embodiments 1 to 9, wherein the second carbonate repeating units in the copolycarbonate are of the formula (1a) wherein R⁵is hydrogen, phenyl or methyl, preferably phenyl.

Embodiment 11

The copolycarbonate lens of any one or more of Embodiments 1 to 10, wherein the copolycarbonate comprises from 60 to 85 mol % of the bisphenol A carbonate units and 15 to 40 mol % of the second carbonate units, each based on the total number of carbonate units in the copolycarbonate.

Embodiment 12

The copolycarbonate lens of any one or more of Embodiments 1 to 11, wherein the copolycarbonate further comprises at least 5 mol % of third carbonate units different from the bisphenol A carbonate units and the second carbonate unit, based on the total number of carbonate units in the copolycarbonate, the third carbonate units comprising carbonate units of the formulas (3)-(7): wherein R^cand R^dare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy, each R⁶is independently C_1-3alkyl or phenyl, X^ais a C_6-12polycyclic aryl, C_3-18mono- or polycycloalkylene, C_3-18mono- or polycycloalkylidene, -(Q¹)_x-G-(Q²)_y- group wherein Q¹and Q²are each independently a C_1-3alkylene, G is a C_3-10cycloalkylene, x is 0 or 1, and y is 1, or —C(P)(P²)— wherein P¹is C_1-12alkyl and P²is C_6-12aryl, and m and n are each independently 0 to 4, or a combination thereof.

Embodiment 13

The copolycarbonate lens of Embodiment 5 wherein the copolycarbonate comprises from 15 to 70 mole percent of the bisphenol A carbonate units, 5 to 50 mole percent of the second carbonate units, and 5 to 50 mole percent of the third carbonate units, each based on the total number of carbonate units in the copolycarbonate.

Embodiment 14

The copolycarbonate lens of any one or more of Embodiments 1 to 14, wherein the copolycarbonate has a hydroxyl end group content of less than 200 ppm and the bisphenol A homopolycarbonate has a hydroxyl end group content of less than 150 ppm and a sulfur content of less than 2 ppm as measured by a Total Sulfur Analysis based on combustion and coulometric detection.

Embodiment 15

The copolycarbonate lens of any one or more of Embodiments 1 to 14, wherein the polycarbonate composition comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography.

Embodiment 16

The copolycarbonate lens of Embodiments 1 to 15, wherein the copolycarbonate has a hydroxyl end group content of less than 200 ppm and the optional bisphenol A homopolycarbonate has a hydroxyl end group content of less than 150 ppm.

Embodiment 17

The copolycarbonate lens of any one or more of Embodiments 1 to 16, wherein the optional bisphenol A homopolycarbonate has a sulfur content of less than 2 ppm, or the copolycarbonate, the optional bisphenol A homopolycarbonate, or both are derived from a bisphenol A having a sulfur content of less than 2 ppm, each as measured by a Total Sulfur Analysis based on combustion and coulometric detection, or the the optional bisphenol A homopolycarbonate.

Embodiment 18

The copolycarbonate lens of any one or more of Embodiments 1 to 17, wherein the polycarbonate composition further comprises 2 to 25 ppm, preferably 4 to 15 ppm, more preferably 6 to 12 ppm of an acid stabilizer, the acid stabilizer comprising a Bronsted acid, a Lewis acid, an acid or an ester thereof containing a sulfur atom, or a combination comprising at least one of the foregoing.

Embodiment 19

The copolycarbonate lens of Embodiment 18, wherein the acid stabilizer comprises phosphoric acid; phosphorus acid; hypophosphorous acid; pyrophosphoric acid; polyphosphoric acid; an organo sulfonic stabilizer of the formula (8) wherein each R⁷is independently a C_1-30alkyl, C_6-30aryl, C_7-30alkylarylene, C_7-30arylalkylene, or a polymer unit derived from a C_2-32ethylenically unsaturated aromatic sulfonic acid or its ester, and R⁸is hydrogen; or R⁸is C_1-30alkyl; or R⁸is a group of the formula —S(═O)₂—R⁷; or a combination comprising at least one of the foregoing, preferably wherein the acid stabilizer comprises phosphoric acid, phosphorus acid, butyl tosylate, p-toluene sulfonic acid, or a combination thereof.

Embodiment 20

The copolycarbonate lens of any one or more of Embodiments 1 to 19, wherein the copolycarbonate is present in an amount of 90 to 99.8 wt % or 95 to 99.8 wt % based on the total weight of the polycarbonate composition.

Embodiment 21

The copolycarbonate lens of any one or more of Embodiments 1 to 20, wherein the copolycarbonate is present in an amount of 45 to 75 wt %, preferably 50 to 70 wt % and the bisphenol A homopolycarbonate is present in an amount of 25 to 55 wt %, preferably 30 to 50 wt %, each based on the total weight of the polycarbonate composition.

Embodiment 22

The copolycarbonate lens of any one or more of Embodiments 1 to 20, wherein the polycarbonate composition comprising, based on the total weight of the polycarbonate composition: 60 to 70 wt % of a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula (1a) wherein R⁵is hydrogen, phenyl or methyl, preferably phenyl; 25 to 40 wt % of a bisphenol A homopolycarbonate; and optionally 6 to 12 ppm of butyl tosylate; wherein the second carbonate units are present in an amount of 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.7% as determined by high performance liquid chromatography; and wherein the polycarbonate composition has: an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque.

Embodiment 23

The copolycarbonate lens of any one or more of Embodiments 1 to 20, wherein the polycarbonate composition comprises, based on the total weight of the polycarbonate composition: 96 to 99.9 wt % of a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula (1a) wherein R⁵is hydrogen, phenyl or methyl, preferably phenyl; and optionally 6 to 12 ppm of butyl tosylate; wherein the second carbonate units are present in an amount of 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the polycarbonate composition has a bisphenol A purity of at least 99.7% as determined by high performance liquid chromatography; and wherein the polycarbonate composition has: a Vicat B 120 of 180° C. or higher as measured according to ISO 306; and an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque.

Embodiment 24

The copolycarbonate lens of any one or more of Embodiments 1 to 23, wherein the polycarbonate composition has one or more of the following properties: a yellowness index of less than 10 measured according to ASTM D1925 on a plaque of 2.5 mm thickness molded at a temperature of 355° C. for a residence time of 10 minutes; a heat deflection temperature of greater than 150° C. measured flat on a 80×10×4 mm bar with a 64 mm span at 0.45 MPa according to ISO 75/Bf; a haze of less than 1.5, or less than 1.0 and a total transmission greater than 86% or greater than 88%, each measured according to ASTM D1003-00 using the color space CIE1931 (Illuminant C and a 20 observer) on a molded plaque with a 1.0 mm thickness; a haze of less than 1.5, or less than 1.0 and a total transmission greater than 84% or greater than 86%, each measured according to ASTM D1003-00 using the color space CIE1931 (Illuminant C and a 2° observer) on a molded plaque with a 3.0 mm thickness; a transmission at wavelength of 400 nm of greater than 75%, or greater than 80% or greater than 85% measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on a molded plaque with a thickness of 1 mm; a transmission at wavelength of 550 nm of greater than 85%, or greater than 87% or greater than 88% measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on a molded plaque with a thickness of 1 mm; a transmission at wavelength of 940 nm of greater than 88%, or greater than 89% or greater than 90% measured with Perkin Elmer 950 spectrometer equipped with 15 cm integrated sphere on a molded plaque with a thickness of 1 mM; a refractive index of greater than 1.59 or greater than 1.60 at 587.6 nm or a refractive index of greater than 1.57 or greater than 1.58 at 940 nm measured according to ISO 489 on a molded plaque with a thickness of 1 mm; an Abbe number of less than 32 or less than 30 measured according to ISO 489 on a molded plaque with a thickness of 1 mm; a melt volume flow rate greater than 10 cc/min, measured at 330° C./2.16 Kg at 360 second dwell according to ISO 1133; an Izod notched impact energy of at least 6 kJ/m², or of at least 8 kJ/m², as measured at 23° C. according to ISO 180/1A using a multipurpose test specimen in accordance with ISO 3167 TYPE A; an Izod notched impact energy of at least 70 J/m, or of at least 88 J/m, as measured at 23° C. according to ASTM D256; an increase in yellowness index of less than 10 during 5000 hours of heat aging at 130° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque; an increase in yellowness index of less than 6, or of less than 5 during 1500 hours of heat aging at 140° C., as measured by ASTM D1925 on a 1.0 mm thick molded plaque; an increase in yellowness index of less than 0.5, or of less than 0.3 after 100 hours of hydro ageing at 121° C. in an autoclave, as measured by ASTM D1925 on a 2.5 mm thick molded plaque; a UL94-V0 rating at a thickness of 2.5 mm or higher; or a UL94-V2 rating at a thickness of 0.8 mm to 1.5 mm.

Embodiment 25

A method of forming the copolycarbonate lens of any Embodiments 1 to 24, comprising molding, thermoforming, extruding, calendaring, or casting the polycarbonate composition to form the lens.

Embodiment 26

A device comprising the copolycarbonate lens of any one or more of Embodiments 1 to 24, wherein the device is a camera, an electronic device, a vehicle, a flashlight, a business machine, a lighting device, an imaging device, a protective article, a vision corrective article, or a toy.
The singular forms “a,” “an,” and “the” include plural referents unless the context clearly dictates otherwise. “Or” means “and/or.” The endpoints of all ranges directed to the same component or property are inclusive and independently combinable. Unless defined otherwise, technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this invention belongs. As used herein, a “combination” is inclusive of blends, mixtures, alloys, reaction products, and the like. A “combination thereof” includes any combination comprising at least one of the listed components or properties optionally together with a like component or property not listed.
Compounds are described using standard nomenclature. For example, any position not substituted by any indicated group is understood to have its valency filled by a bond as indicated, or a hydrogen atom. A dash (“-”) that is not between two letters or symbols is used to indicate a point of attachment for a substituent. For example, —CHO is attached through carbon of the carbonyl group.
As used herein, the term “hydrocarbyl” and “hydrocarbon” refers broadly to a substituent comprising carbon and hydrogen, optionally with 1 to 3 heteroatoms, for example, oxygen, nitrogen, halogen, silicon, sulfur, or a combination thereof; “alkyl” refers to a straight or branched chain, saturated monovalent hydrocarbon group; “alkylene” refers to a straight or branched chain, saturated, divalent hydrocarbon group; “alkylidene” refers to a straight or branched chain, saturated divalent hydrocarbon group, with both valences on a single common carbon atom; “alkenyl” refers to a straight or branched chain monovalent hydrocarbon group having at least two carbons joined by a carbon-carbon double bond; “cycloalkyl” refers to a non-aromatic monovalent monocyclic or multicyclic hydrocarbon group having at least three carbon atoms; “aryl” refers to an aromatic monovalent group containing only carbon in the aromatic ring or rings; “arylene” refers to an aromatic divalent group containing only carbon in the aromatic ring or rings; “alkylarylene” refers to an aryl group that has been substituted with an alkyl group as defined above, with 4-methylphenyl being an exemplary alkylarylene group; “arylalkylene” refers to an alkyl group that has been substituted with an aryl group as defined above, with benzyl being an exemplary arylalkylene group.
Unless otherwise indicated, each of the foregoing groups can be unsubstituted or substituted, provided that the substitution does not significantly adversely affect synthesis, stability, or use of the compound. The term “substituted” as used herein means that at least one hydrogen on the designated atom or group is replaced with another group, provided that the designated atom's normal valence is not exceeded. When the substituent is oxo (i.e., ═O), then two hydrogens on the atom are replaced. Combinations of substituents and/or variables are permissible provided that the substitutions do not significantly adversely affect synthesis or use of the compound. Groups that can be present on a substituted position include (—NO₂), cyano (—CN), halogen, thiocyano (—SCN), C_2-6alkanoyl (e.g., acyl (H₃CC(═O)—); carboxamido; C_1-6or C_1-3alkyl, cycloalkyl, alkenyl, and alkynyl; C_1-6or C_1-3alkoxy; C_6-10aryloxy such as phenoxy; C_1-6alkylthio; C_1-6or C_1-3alkylsulfinyl; C_1-6or C_1-3alkylsulfonyl; C_6-12aryl having at least one aromatic rings (e.g., phenyl, biphenyl, naphthyl, or the like, each ring either substituted or unsubstituted aromatic); C_7-19arylalkylene having 1 to 3 separate or fused rings and from 6 to 18 ring carbon atoms; or arylalkoxy having 1 1 to 3 separate or fused rings and from 6 to 18 ring carbon atoms. The stated number of carbon atoms includes any substituents.
All references cited herein are incorporated by reference in their entirety. While typical embodiments have been set forth for the purpose of illustration, the foregoing descriptions should not be deemed to be a limitation on the scope herein. Accordingly, various modifications, adaptations, and alternatives can occur to one skilled in the art without departing from the spirit and scope herein.

Claims

1. A copolycarbonate lens formed from a polycarbonate composition comprising:

a copolycarbonate comprising bisphenol A carbonate units and of second carbonate units of the formula

wherein

R^aand R^bare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy,

each R³is independently a C_1-6alkyl,

R⁴is hydrogen, C_2-6alkyl or phenyl optionally substituted with 1 to 5 C_1-6alkyl groups,

p, q, and j are each independently 0 to 4; and

optionally, a bisphenol A homopolycarbonate;

wherein

the second carbonate units are present in an amount of 10 to 49 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate,

the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and

the polycarbonate composition has a bisphenol A purity of at least 99.6% as determined by high performance liquid chromatography; and

wherein

the polycarbonate composition has:

a Vicat B120 of 155° C. or higher, preferably 165° C. or higher, as measured according to ISO 306; and

an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C., as measured by ASTM D1925 on a 1 mm thick molded plaque.

2. A copolycarbonate lens formed from a polycarbonate composition comprising:

wherein

each R³is independently a C_1-6alkyl,

p, q, and j are each independently 0 to 4; and

wherein

the polycarbonate composition has:

a Vicat B 120 of 155° C. or higher as measured according to ISO 306; and

a yellowness index which is at least 20% lower compared to the same composition having a Bisphenol A purity below 99.6%, as measured by ASTM D1925 on a 2.5 mm thick molded plaque with a melt temperature of 355° C. and a residence time of 10 min.

3. The copolycarbonate lens of claim 1, wherein the lens is a flat or planar lens, a curved lens, a cylindrical lens, a toric or sphero-cylindrical lens, a fresnel lens, a convex lens, a biconvex lens, a concave lens, a biconcave lens, a convex-concave lens, a plano-convex lens, a plano-concave lens, a lenticular lens, a gradient index lens, an axicon lens, a conical lens, an astigmatic lens, an aspheric lens, a corrective lens, a diverging lens, a converging lens, a compound lens, a photographic lens, a doublet lens, a triplet lens, an achromatic lens, or a multi-array lens.

4. The copolycarbonate lens of claim 1, further comprising a macrotexture, a microtexture, a nanotexture, or a combination thereof on a surface of the lens.

5. (canceled)

6. The copolycarbonate lens of claim 1, further comprising an indicia or a coating disposed on at least a portion of one or both surface of the polycarbonate lens.

7. The copolycarbonate lens of claim 6, wherein the coating is a hard coat, a UV protective coat, an anti-refractive coat, an anti-reflective coat, a scratch resistant coat, a hydrophobic coat, a hydrophilic coat, or a combination comprising at least one of the foregoing, or wherein at least a portion of a surface of the polycarbonate lens is metallized.

8. The copolycarbonate lens of claim 1, wherein the copolycarbonate lens is a camera lens, a sensor lens, an illumination lens, a safety glass lens, an ophthalmic corrective lens, or an imaging lens.

9. The copolycarbonate lens of claim 8, wherein

the camera lens is a mobile phone camera lens, a table camera lens, a security camera lens, a mobile phone camera lens, a tablet camera lens, a laptop camera lens, a security camera lens, a camera sensor lens, or a vehicle camera lens,

the sensor lens can be a motion detector lens, a proximity sensor lens, a gesture control lens, an infrared sensor lens, or a camera sensor lens,

the illumination lens is an indoor lighting lens, an outdoor lighting lens, vehicle headlamp lens, a vehicle foglight lens, a vehicle rearlight lens, a vehicle running light lens, a vehicle foglight lens, a vehicle interior lens, an a light emitting diode lens, or an organic light emitting diode lens,

the safety glass lens is a glasses lens, a goggles lens, a visor, or a helmet lens,

the ophthalmic corrective lens is a monocle lens, a corrective glasses lens, or a contact lens, or

the imaging lens is a scanner lens, a projector lens, a magnifying glass lens, a microscope lens, a telescope lens, a security lens, or a reading glasses lens.

10. The copolycarbonate lens of claims 1 to 9, wherein the second carbonate repeating units in the copolycarbonate are of the formula

wherein R⁵is hydrogen, phenyl or methyl.

11. The copolycarbonate lens of claim 1, wherein the copolycarbonate comprises from 60 to 85 mol % of the bisphenol A carbonate units and 15 to 40 mol % of the second carbonate units, each based on the total number of carbonate units in the copolycarbonate.

12. The copolycarbonate lens of claim 1, wherein the copolycarbonate further comprises at least 5 mol % of third carbonate units different from the bisphenol A carbonate units and the second carbonate unit, based on the total number of carbonate units in the copolycarbonate, the third carbonate units comprising carbonate units of the formula:

or a combination thereof, wherein

R^cand R^dare each independently a C_1-12alkyl, C_1-12alkenyl, C_3-8cycloalkyl, or C_1-12alkoxy,

each R⁶is independently C_1-3alkyl or phenyl,

X^ais a C_6-12polycyclic aryl, C_3-18mono- or polycycloalkylene, C_3-18mono- or polycycloalkylidene, -(Q¹)_x-G-(Q²)_y- group wherein Q¹and Q²are each independently a C_1-3alkylene, G is a C_3-10cycloalkylene, x is 0 or 1, and y is 1, or —C(P¹)(P²)— wherein P¹is C_1-12alkyl and P²is C_6-12aryl, and

m and n are each independently 0 to 4, or a combination thereof.

13. (canceled)

14. The copolycarbonate lens of claim 1, wherein the copolycarbonate has a hydroxyl end group content of less than 200 ppm and the bisphenol A homopolycarbonate has a hydroxyl end group content of less than 150 ppm and a sulfur content of less than 2 ppm as measured by a Total Sulfur Analysis based on combustion and coulometric detection.

15. (canceled)

16. (canceled)

17. The copolycarbonate lens of claim 1, wherein the optional bisphenol A homopolycarbonate has a sulfur content of less than 2 ppm, or the copolycarbonate, the optional bisphenol A homopolycarbonate, or both are derived from a bisphenol A having a sulfur content of less than 2 ppm, each as measured by a Total Sulfur Analysis based on combustion and coulometric detection, or the the optional bisphenol A homopolycarbonate.

18. The copolycarbonate lens of claim 1, wherein the polycarbonate composition further comprises 2 to 25 ppm of an acid stabilizer, the acid stabilizer comprising a Bronsted acid, a Lewis acid, an acid or an ester thereof containing a sulfur atom, or a combination comprising at least one of the foregoing.

19. The copolycarbonate lens of claim 18, wherein the acid stabilizer comprises phosphoric acid; phosphorus acid; hypophosphorous acid; pyrophosphoric acid; polyphosphoric acid; an organo sulfonic stabilizer of the formula

wherein each R⁷is independently a C_1-30alkyl, C_6-30aryl, C_7-30alkylarylene, C_7-30arylalkylene, or a polymer unit derived from a C_2-32ethylenically unsaturated aromatic sulfonic acid or its ester, and R⁸is hydrogen; or R⁸is C_1-30alkyl; or R⁸is a group of the formula —S(═O)₂—R⁷; or a combination comprising at least one of the foregoing.

20. The copolycarbonate lens of claim 1, wherein the copolycarbonate is present in an amount of 90 to 99.8 wt % based on the total weight of the polycarbonate composition.

21. The copolycarbonate lens of claim 1, wherein the copolycarbonate is present in an amount of 45 to 75 wt % and the bisphenol A homopolycarbonate is present in an amount of 25 to 55 wt %, each based on the total weight of the polycarbonate composition.

22. The copolycarbonate lens of claim 1, wherein the polycarbonate composition comprising, based on the total weight of the polycarbonate composition:

60 to 70 wt % of a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula

wherein R⁵is hydrogen, phenyl or methyl, preferably phenyl;

25 to 40 wt % of a bisphenol A homopolycarbonate; and

optionally 6 to 12 ppm of butyl tosylate;

wherein the second carbonate units are present in an amount of 18 to 35 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate,

the polycarbonate composition has a bisphenol A purity of at least 99.7% as determined by high performance liquid chromatography; and

wherein the polycarbonate composition has:

an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C., as measured by ASTM D1925 on a 2.5 mm thick molded plaque.

23. The copolycarbonate lens of claim 1, wherein the polycarbonate composition comprises, based on the total weight of the polycarbonate composition:

96 to 99.9 wt % of a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula

wherein R⁵is hydrogen, phenyl or methyl, preferably phenyl; and

optionally 6 to 12 ppm of butyl tosylate;

wherein the polycarbonate composition has:

a Vicat B120 of 180° C. or higher as measured according to ISO 306; and

24. (canceled)

25. (canceled)

26. A device comprising the copolycarbonate lens of claim 1, wherein the device is a camera, an electronic device, a vehicle, a flashlight, a business machine, a lighting device, an imaging device, a protective article, a vision corrective article, or a toy.