US20180222601A1 - Fire-and electromagnetic interference (emi)-resistant aircraft components and methods for manufacturing the same - Google Patents

Fire-and electromagnetic interference (emi)-resistant aircraft components and methods for manufacturing the same Download PDF

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US20180222601A1
US20180222601A1 US15/935,706 US201815935706A US2018222601A1 US 20180222601 A1 US20180222601 A1 US 20180222601A1 US 201815935706 A US201815935706 A US 201815935706A US 2018222601 A1 US2018222601 A1 US 2018222601A1
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Prior art keywords
fire
emi
article
material layer
electrically conductive
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Abandoned
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US15/935,706
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Anh-Tuan Ngo
Brian G. Baughman
Jim Balonis
Donald G. Godfrey
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Honeywell International Inc
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Honeywell International Inc
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Priority to US15/935,706 priority Critical patent/US20180222601A1/en
Publication of US20180222601A1 publication Critical patent/US20180222601A1/en
Abandoned legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B64AIRCRAFT; AVIATION; COSMONAUTICS
    • B64DEQUIPMENT FOR FITTING IN OR TO AIRCRAFT; FLIGHT SUITS; PARACHUTES; ARRANGEMENTS OR MOUNTING OF POWER PLANTS OR PROPULSION TRANSMISSIONS IN AIRCRAFT
    • B64D45/00Aircraft indicators or protectors not otherwise provided for
    • B64D45/02Lightning protectors; Static dischargers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/021Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K9/00Screening of apparatus or components against electric or magnetic fields
    • H05K9/0073Shielding materials
    • H05K9/0081Electromagnetic shielding materials, e.g. EMI, RFI shielding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B64AIRCRAFT; AVIATION; COSMONAUTICS
    • B64DEQUIPMENT FOR FITTING IN OR TO AIRCRAFT; FLIGHT SUITS; PARACHUTES; ARRANGEMENTS OR MOUNTING OF POWER PLANTS OR PROPULSION TRANSMISSIONS IN AIRCRAFT
    • B64D45/00Aircraft indicators or protectors not otherwise provided for
    • B64D2045/009Fire detection or protection; Erosion protection, e.g. from airborne particles

Definitions

  • the present invention generally relates to aircraft components and their protection against certain hazards, and more particularly relates to fire- and electromagnetic interference (EMI)-resistant aircraft components and methods for manufacturing the same.
  • EMI electromagnetic interference
  • Aircraft components may be exposed to risks from certain hazards, such as fire and/or electromagnetic interference (EMI).
  • EMI electromagnetic interference
  • certain aircraft components may be used in an aircraft “fire zone”, i.e., in an aircraft compartment that contains ignition sources and the potential for flammable fluid leakage.
  • Some aircraft components may be equipped with electronic devices that can be harmed or disrupted by electromagnetic interference (EMI).
  • Electromagnetic interference (EMI) is caused when electronic devices exhibit interference on other electronic equipment in their vicinity, causing negative consequences such as degradation or even malfunctioning.
  • EMI can lead to erased data, loss of connectivity for computers and cellphones, as well as more serious effects like the jamming of cockpit radios and radar signals that could ultimately hamper communication between an aircraft pilot and respective radio tower.
  • a lightning storm is one source of EMI.
  • Conventional systems and methods for providing fire resistance to aircraft components include using thermal blankets and/or fire shields positioned around the component. Components can also be shielded to protect against EMI. Unfortunately, these blankets and shields add significant weight and space requirements. Where space is too limited, they cannot be used at all. Some aircraft components are designed with fire-retardant coatings, but these coatings can fail to protect a component from fire and do not offer any protection against EMI. This is especially true for non-metallic aircraft components.
  • a method for manufacturing a fire- and EMI-resistant aircraft component comprises forming a conductive coating material layer on at least a portion of an intermediate article comprised of a non-metallic material.
  • the coating material layer is electrically and thermally conductive and comprised of metal.
  • a fire-retardant material layer is cold-sprayed on the conductive coating material layer.
  • a method for manufacturing a fire- and EMI-resistant aircraft component comprises forming an additive-manufactured intermediate article comprising a polymeric material.
  • a thermally and electrically conductive coating material layer is applied on the additive-manufactured article forming a coated article.
  • the thermally and electrically conductive coating material layer comprises a metal.
  • a fire retardant material layer is cold sprayed on the coated article.
  • a fire-and EMI-resistant aircraft component comprises an article comprised of a polymeric material.
  • a fire-retardant material layer overlies the article.
  • a thermally and electrically conductive coating material layer is disposed intermediate the article and the fire-retardant material layer.
  • at least one continuous electrically conductive element is integrated with the polymeric material of the article.
  • a fire-and EMI-resistant aircraft component which includes an article comprised of a polymeric material having a first end and a second end.
  • the component includes a fire-retardant material layer overlying the article and a conductive coating material layer intermediate the article and the fire-retardant material layer.
  • the component includes at least one continuous electrically conductive filament integrated within the polymeric material of the article that extends through the article from the first end to the second end to provide a conduction path through the article.
  • a fire-and EMI-resistant aircraft component which includes an article comprised of a polymeric material having a first end and a second end.
  • the component includes a fire-retardant material layer overlying the article, and a conductive coating material layer intermediate the article and the fire-retardant material layer.
  • the conductive coating material layer is applied locally to portions of the article.
  • the component includes at least one continuous electrically conductive filament integrated within the polymeric material of the article that extends through the article from the first end to the second end to provide a conduction path through the article.
  • FIG. 1 is a cross-sectional view of a fire- and EMI-resistant inlet duct, an exemplary aircraft component manufactured by the methods according to exemplary embodiments;
  • FIG. 2 is a flow diagram of a method for manufacturing fire- and EMI-resistant aircraft components, according to exemplary embodiments of the present invention
  • FIG. 3 is a cross sectional view of a portion of a fire- and EMI-resistant aircraft component, such as the inlet duct of FIG. 1 ;
  • FIG. 4 is a cross sectional view of a portion of a fire- and EMI-resistant aircraft component, according to another exemplary embodiment of the present invention.
  • FIG. 5 is a schematic diagram of a conventional FDM additive manufacturing process.
  • Various embodiments are directed to fire- and EMI-resistant aircraft components and methods for manufacturing the same.
  • fire-resistant or “fire-resistance” as used herein means the capacity to perform the intended functions under the heat and other conditions likely to occur when there is a fire at the place concerned.
  • Aircraft components are demonstrated to be fire resistant by meeting the requirements of a flame exposure test. Therefore, the aircraft components manufactured by the methods according to exemplary embodiments meet the requirements for the flame exposure test and are therefore deemed “fire-resistant.”
  • the flame exposure test requires that the aircraft component has the ability to withstand a 15 minute kerosene burner test.
  • aircraft components includes gas turbine engine components and other components located within an aircraft, at least a portion thereof requiring fire-resistance (i.e., a component that needs to pass the flame exposure test to be put into usage), EMI resistance (i.e., a component equipped with an electronic device that can be harmed or disrupted by EMI), or both fire-and EMI-resistance.
  • fire-resistance i.e., a component that needs to pass the flame exposure test to be put into usage
  • EMI resistance i.e., a component equipped with an electronic device that can be harmed or disrupted by EMI
  • aircraft components includes, for example, mounts, cases, brackets, ducts, inlets, sheet or structural members, fluid-carrying lines (e.g., piping), fluid system parts, wiring, fittings, and powerplant controls. Aircraft interiors and structures can also be made fire- and EMI-resistant.
  • a “fire- and EMI-resistant aircraft component” means that that
  • the aircraft component may be used inside or outside of an aircraft fire zone, i.e., an aircraft compartment that contains ignition sources and the potential for flammable fluid leakage.
  • an aircraft fire zone i.e., an aircraft compartment that contains ignition sources and the potential for flammable fluid leakage.
  • Such compartments are classified as “fire zones.”
  • the engine case around the compressor, combustor, and turbine sections of the engine define a fire zone.
  • the gearbox and its accessories are also considered potential ignition sources during failure conditions that could cause temperatures to exceed the auto ignition temperatures of fluids that may be present in the compartment.
  • the APU compartment is by definition a fire zone.
  • imparting fire-resistance also imparts electromagnetic interference (EMI) resistance.
  • EMI electromagnetic interference
  • the fire- and EMI-resistant aircraft component 10 comprises an intermediate article 12 and a fire-retardant layer 16 with a thermally and electrically conductive coating material layer 14 between the intermediate article and the fire-retardant layer.
  • This type of coating system is called a “sandwich” coating system because the thermally and electrically conductive coating material layer is bound between two structures—the intermediate article 12 and the fire-retardant material layer 16 .
  • the sandwich coating system is used here because- the fire-retardant layer (also known as a “thermally resistant layer) must be on the outside surface for maximum protection.
  • a method 100 for manufacturing a fire- and EMI-resistant aircraft component begins by providing the intermediate article 12 (step 110 ).
  • the intermediate article 12 comprises a non-metallic material of polymer or composite construction.
  • Suitable exemplary polymers include natural and synthetic rubber, polymer resins, polyimides, polyether ether ketones (PEEK), cyanate esters, bismaleimids (BMI), neoprenes, nylons, polyvinyl chlorides (PVC or vinyl), polystyrenes, polyethylenes, polypropylenes, polyacrylonitriles, polyvinyl butyrals (PVB), silicones, and many more.
  • Composite materials are defined as materials made from two or more constituent materials with significantly different physical or chemical properties, that when combined, produce a material with characteristics different from the individual components. The individual components remain separate and distinct within the finished structure.
  • Suitable exemplary engineered composite materials include composite building materials such as cements, concrete, reinforced plastics such as fiber-reinforced polymers, metal composites, and ceramic composites (composite ceramic and metal matrices).
  • Suitable exemplary fibers used to reinforce the polymers in the fiber-reinforced construction include carbon fibers (e.g., IM7, AS4, T300, etc.), fiber glass, Kevlar, and many more.
  • the non-metallic material comprises a non-fire-resistant material (i.e., the non-metallic material does not pass the flame exposure test).
  • the intermediate article 12 may be already available and obtainable from commercial sources.
  • the intermediate article may comprise an already manufactured component that fails to pass the flame certification test (i.e., the already manufactured component is non-compliant with the flame certification test and is therefore not fire-resistant).
  • the intermediate article 12 may be part of old stock and rather than scrapping the non-compliant component, a fire- and EMI-resistant component 10 may be manufactured from the non-compliant component (here, the intermediate article) by performing the forming and cold spraying steps 120 and 130 as hereinafter described.
  • the fire- and EMI-resistant component 10 may be manufactured from an intermediate article 12 formed by any suitable manufacturing process.
  • the intermediate article comprising the polymeric material may be formed by a known additive manufacturing process.
  • the polymeric material (a “build material”) may be used in an additive-manufacturing process as known in the art to form the intermediate article 12 from which the fire- and EMI-resistant component 10 is manufactured.
  • additive Manufacturing is defined by the American Society for Testing and Materials (ASTM) as the “process of joining materials to make objects from 3D model data, usually deposit layer upon deposit layer, as opposed to subtractive manufacturing methodologies, such as traditional machining and casting.”
  • ASTM American Society for Testing and Materials
  • Some examples of additive manufacturing processes include: micro-pen deposition in which liquid media is dispensed with precision at the pen tip and then cured; selective laser sintering in which a laser is used to sinter a powder media in precisely controlled locations; laser wire deposition in which a wire feedstock is melted by a laser and then deposited and solidified in precise locations to build the product; electron beam melting; laser engineered net shaping; and direct metal deposition .
  • a finishing step may be performed on the intermediate article formed by the additive-manufacturing process.
  • the finishing step may include, for example, machining, etc. as long as the article is not exposed to heat. In some embodiments, the finishing step may be unnecessary and may be omitted.
  • a model such as a design model, of the component may be defined in any suitable manner
  • the model may be designed with computer aided design (CAD) software.
  • the model may include 3D numeric coordinates of the entire configuration of the component including both external and internal surfaces of an airfoil, platform and dovetail.
  • the model may include a number of successive 2D cross-sectional slices that together form the 3D component.
  • Sequential deposit layers of build material in this case, polymeric material
  • 3D model Three-dimensional (3D) model.
  • Each successive deposit layer of the intermediate article may be, for example, between about 10 ⁇ m and about 200 ⁇ m, although the thickness may be selected based on any number of parameters.
  • fused deposition modeling may be used to form the additive-manufactured intermediate article comprised of the polymeric material.
  • FDM fused deposition modeling
  • FIG. 5 A schematic of a FDM process is depicted in FIG. 5 .
  • FDM is an additive manufacturing process that works on an “additive” principle by laying down material in layers; here, the polymeric filament 18 is unwound from a coil 20 (the “material cartridge in FIG. 5 ) and is supplied through an extrusion nozzle 22 to form the intermediate article.
  • the FDM process begins with a software process which processes an STL file (stereolithography file format), mathematically slicing and orienting the 3-D model for the build process.
  • the polymeric material is heated (by heater block 24 in FIG.
  • the intermediate article 12 is built from the bottom up, one layer at a time.
  • the filament of the polymeric material is unwound from the coil and supplied to the extrusion nozzle which can turn the flow on and off.
  • the nozzle is heated to melt the polymeric material and can be moved in both horizontal and vertical directions by a numerically controlled mechanism, directly controlled by the computer-aided manufacturing (CAM) software.
  • the intermediate article is formed by extruding small beads of the polymeric material to form layers as the material hardens immediately after extrusion from the nozzle. Stepper motors or servo motors are typically employed to move the extrusion head that includes the extrusion nozzle.
  • the FDM additive manufacturing process is described herein for forming the intermediate article comprising a polymeric material, other additive manufacturing processes and other manufacturing processes in general may be employed to form the intermediate article comprising the polymeric material.
  • the intermediate article comprising the composite material may be formed by conventional composite manufacturing processes (e.g., using composite ply lay-ups).
  • the step of providing the intermediate article further comprises optionally integrating a continuous electrically conductive element 26 into the substrate of the intermediate article to be formed (step 140 ).
  • the intermediate article 12 and the fire- and EMI-resistant aircraft component 10 a to be manufactured therefrom may further comprise the continuous electrically conductive element 26 .
  • the material for the continuous electrically conductive element comprises copper, aluminum, and their alloys, as well as combinations thereof.
  • continuous electrically conductive element refers to a thin, continuous elongate electrically conductive element generally and more particularly, comprises an electrically conductive wire which may be of any cross-sectional shape such as circular, triangular, square, rectangular or polygonal or a like continuous element in the form of an electrically conductive tape, ribbon, or the like.
  • the continuous electrically conductive element has an electrical resistivity of less than about 2.75 ohm/m at room temperature (70° Fahrenheit).
  • the continuous electrically conductive element may be in a spiral form to add strength to the polymeric material or composite material in the vertical (Z) direction.
  • the continuous electrically conductive element provides EMI-resistance to the fire- and EMI-resistant component 10 a to be manufactured.
  • the continuous electrically conductive element 26 also provides a conduction path through the fire- and EMI-resistant aircraft component 10 a , thereby permitting transmission of a signal (e.g., a radio signal) from one end of the component to the other end of the component.
  • a signal e.g., a radio signal
  • the continuous electrically conductive element 26 may be integrated into the intermediate article 12 to be formed by integration with the non-metallic material of the intermediate article to be formed.
  • the extrusion nozzle 22 incorporates a twin-arc or dual-arc welding system with dual extrusion heads for simultaneously feeding the polymeric material filament 18 and the continuous electrically conductive element 26 , i.e., in this example, the extrusion head may include more than one nozzle to extrude the polymeric component material to build the intermediate article and another nozzle to feed the continuous electrically conductive element through the intermediate article as it is being built.
  • the continuous electrically conductive element extends from one end of the intermediate article to the other end of the intermediate article.
  • the continuous electrically conductive element 26 may be integrated into the intermediate article 12 comprising the polymeric material formed by manufacturing processes other than by the FDM additive manufacturing process.
  • the continuous electrically conductive element 26 may also be integrated into the composite plies when forming a composite ply lay-up (not shown).
  • the continuous electrically conductive element provides EMI-resistance and a conductive path to the fire-and EMI-resistant component 10 a to be manufactured.
  • the tensile strength of the fire- and EMI-resistant component 10 a to be manufactured with the continuous electrically conductive element 26 is improved relative to the tensile strength of the fire and EMI-resistant component 10 that does not comprise the continuous electrically conductive element.
  • the method 100 for manufacturing a fire- and EMI-resistant component continues by forming a layer 302 of conductive coating material (hereinafter “a thermally and electrically conductive coating material layer”) on at least a portion of the intermediate article forming a coated article (step 120 ).
  • the thermally and electrically conductive coating material layer has a thermal conductivity of greater than 175 W/m-K (watts/meters-Kelvin) at room temperature (70° F.) and an electrical resistivity of less than about 2.75 ohm/m at room temperature.
  • the thermally and electrically conductive coating material layer may be applied locally (“at least a portion”) or over the entire intermediate article 12 .
  • the thermally and electrically conductive coating material layer is applied only where fire resistance is needed to avoid adding unnecessary weight.
  • the thermally and electrically conductive coating material layer 14 is comprised of a pure metal or metal alloy. Suitable exemplary materials for the thermally and electrically conductive coating material layer include copper, aluminum, combinations thereof, their alloys, and brass.
  • the thickness of the thermally and electrically conductive coating layer may be from about 10 ⁇ m to about 200 ⁇ m.
  • the conductive coating material may be applied by cold-spraying techniques. Such techniques are well known in the art.
  • the coating material may alternatively be applied by any known coating techniques such as, for example, chemical vapor deposition, plating, or the like.
  • the thermally and electrically conductive coating material layer acts to transfer heat away from the fire- and EMI-aircraft component.
  • the thermally and electrically conductive coating material layer also provides EMI resistance to the fire- and EMI-resistant component.
  • the method 100 for manufacturing a fire- and EMI-resistant aircraft component continues by thereafter cold spraying the fire-retardant coating 16 on the thermally and electrically conductive coating material layer on the intermediate article (step 130 ).
  • the fire-retardant coating 16 may be applied by known cold-spraying techniques to a thickness of about 100 ⁇ m to about 700 ⁇ m. It is preferred for the coating to be as thin as possible because of weight concerns but still provide fire-resistance. The preferred density of the fire-retardant coating is about 98 to about 100 percent.
  • the fire-retardant coating comprises a fire-retardant material.
  • Exemplary fire-retardant materials include nickel-based alloys and superalloys such as INCONEL® alloys, ferrous-based alloys (e.g., stainless steel), cobalt-based alloys, and combinations thereof.
  • Stainless steel is a ferrous-based alloy with a minimum of 10.5% chromium content by mass.
  • the compositions of the INCONEL alloys are different but all are predominantly nickel, with chromium as the second element as shown below:
  • the fire-retardant material layer 16 and the thermally and electrically conductive coating material layer 14 cooperate to provide fire-resistance to the non-metallic aircraft component 10 , i.e., the fire- and EMI-resistant aircraft component is rendered fire-resistant (i.e., able to pass the flame certification test), certifying the aircraft component for use.
  • the fire-retardant material layer does not otherwise provide sufficient fire resistance (to pass the flame exposure test) to the non-metallic aircraft component without the thermally and electrically conductive coating material layer.
  • an EMI-resistant only component may be manufactured by omitting the thermally and electrically conductive coating material layer (not shown) and corresponding forming step 120 .
  • the EMI-resistant only component comprises the intermediate article 12 including the continuous electrically conductive element 26 and the fire-retardant layer 16 disposed directly on the intermediate article.
  • Non-metallic aircraft components may be rendered fire- and EMI-resistant, certifying them for use.
  • the sandwich coating system described herein provides lightweight and effective integral fire- and EMI shielding materials for non-metallic aircraft components, eliminating the need for separate fire and EMI shielding materials that add weight and take up space.

Abstract

Fire- and electromagnetic interference (EMI)-resistant aircraft components and methods for manufacturing the same are provided. A fire-and EMI-resistant aircraft component includes an article comprised of a polymeric material. A fire-retardant material layer overlies the article. A thermally and electrically conductive coating material layer is disposed intermediate the article and the fire-retardant material layer. Optionally, at least one continuous electrically conductive element is integrated with the polymeric material of the article.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a divisional of U.S. patent application Ser. No. 14/081,009 filed on Nov. 15, 2013. The relevant disclosure of the above application is incorporated herein by reference.
  • TECHNICAL FIELD
  • The present invention generally relates to aircraft components and their protection against certain hazards, and more particularly relates to fire- and electromagnetic interference (EMI)-resistant aircraft components and methods for manufacturing the same.
  • BACKGROUND
  • Aircraft components may be exposed to risks from certain hazards, such as fire and/or electromagnetic interference (EMI). For example, certain aircraft components may be used in an aircraft “fire zone”, i.e., in an aircraft compartment that contains ignition sources and the potential for flammable fluid leakage. Some aircraft components may be equipped with electronic devices that can be harmed or disrupted by electromagnetic interference (EMI). Electromagnetic interference (EMI) is caused when electronic devices exhibit interference on other electronic equipment in their vicinity, causing negative consequences such as degradation or even malfunctioning. For example, EMI can lead to erased data, loss of connectivity for computers and cellphones, as well as more serious effects like the jamming of cockpit radios and radar signals that could ultimately hamper communication between an aircraft pilot and respective radio tower. A lightning storm is one source of EMI.
  • Conventional systems and methods for providing fire resistance to aircraft components include using thermal blankets and/or fire shields positioned around the component. Components can also be shielded to protect against EMI. Unfortunately, these blankets and shields add significant weight and space requirements. Where space is too limited, they cannot be used at all. Some aircraft components are designed with fire-retardant coatings, but these coatings can fail to protect a component from fire and do not offer any protection against EMI. This is especially true for non-metallic aircraft components.
  • Accordingly, it is desirable to provide fire- and EMI-resistant aircraft components and methods for manufacturing the same. In addition, it is also desirable to provide lightweight and effective integral and conformal fire- and EMI shielding materials for non-metallic aircraft components. Furthermore, other desirable features and characteristics of the fire- and EMI-resistant aircraft components and methods for manufacturing the same will become apparent from the subsequent detailed description and the appended claims, taken in conjunction with the accompanying drawings and the preceding background.
  • BRIEF SUMMARY
  • Methods are provided for manufacturing a fire- and electromagnetic interference (EMI)-resistant aircraft component. In accordance with one exemplary embodiment, a method for manufacturing a fire- and EMI-resistant aircraft component comprises forming a conductive coating material layer on at least a portion of an intermediate article comprised of a non-metallic material. The coating material layer is electrically and thermally conductive and comprised of metal. A fire-retardant material layer is cold-sprayed on the conductive coating material layer.
  • In accordance with another exemplary embodiment, a method for manufacturing a fire- and EMI-resistant aircraft component comprises forming an additive-manufactured intermediate article comprising a polymeric material. A thermally and electrically conductive coating material layer is applied on the additive-manufactured article forming a coated article. The thermally and electrically conductive coating material layer comprises a metal. A fire retardant material layer is cold sprayed on the coated article.
  • In accordance with another exemplary embodiment, a fire-and EMI-resistant aircraft component is provided. The fire- and EMI-resistant aircraft component comprises an article comprised of a polymeric material. A fire-retardant material layer overlies the article. A thermally and electrically conductive coating material layer is disposed intermediate the article and the fire-retardant material layer. Optionally, at least one continuous electrically conductive element is integrated with the polymeric material of the article.
  • Further provided is a fire-and EMI-resistant aircraft component, which includes an article comprised of a polymeric material having a first end and a second end. The component includes a fire-retardant material layer overlying the article and a conductive coating material layer intermediate the article and the fire-retardant material layer. The component includes at least one continuous electrically conductive filament integrated within the polymeric material of the article that extends through the article from the first end to the second end to provide a conduction path through the article.
  • Also provided is a fire-and EMI-resistant aircraft component, which includes an article comprised of a polymeric material having a first end and a second end. The component includes a fire-retardant material layer overlying the article, and a conductive coating material layer intermediate the article and the fire-retardant material layer. The conductive coating material layer is applied locally to portions of the article. The component includes at least one continuous electrically conductive filament integrated within the polymeric material of the article that extends through the article from the first end to the second end to provide a conduction path through the article.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The present invention will hereinafter be described in conjunction with the following drawing figures, wherein like numerals denote like elements, and wherein:
  • FIG. 1 is a cross-sectional view of a fire- and EMI-resistant inlet duct, an exemplary aircraft component manufactured by the methods according to exemplary embodiments;
  • FIG. 2 is a flow diagram of a method for manufacturing fire- and EMI-resistant aircraft components, according to exemplary embodiments of the present invention;
  • FIG. 3 is a cross sectional view of a portion of a fire- and EMI-resistant aircraft component, such as the inlet duct of FIG. 1;
  • FIG. 4 is a cross sectional view of a portion of a fire- and EMI-resistant aircraft component, according to another exemplary embodiment of the present invention; and
  • FIG. 5 is a schematic diagram of a conventional FDM additive manufacturing process.
  • DETAILED DESCRIPTION
  • The following detailed description is merely exemplary in nature and is not intended to limit the invention or the application and uses of the invention. As used herein, the word “exemplary” means “serving as an example, instance, or illustration.” Thus, any embodiment described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other embodiments. All of the embodiments described herein are exemplary embodiments provided to enable persons skilled in the art to make or use the invention and not to limit the scope of the invention which is defined by the claims. Furthermore, there is no intention to be bound by any expressed or implied theory presented in the preceding technical field, background, brief summary, or the following detailed description.
  • Various embodiments are directed to fire- and EMI-resistant aircraft components and methods for manufacturing the same. The definition of the terms “fire-resistant” or “fire-resistance” as used herein means the capacity to perform the intended functions under the heat and other conditions likely to occur when there is a fire at the place concerned. Aircraft components are demonstrated to be fire resistant by meeting the requirements of a flame exposure test. Therefore, the aircraft components manufactured by the methods according to exemplary embodiments meet the requirements for the flame exposure test and are therefore deemed “fire-resistant.” The flame exposure test requires that the aircraft component has the ability to withstand a 15 minute kerosene burner test. The term “aircraft components” as used herein includes gas turbine engine components and other components located within an aircraft, at least a portion thereof requiring fire-resistance (i.e., a component that needs to pass the flame exposure test to be put into usage), EMI resistance (i.e., a component equipped with an electronic device that can be harmed or disrupted by EMI), or both fire-and EMI-resistance. The term “aircraft components” includes, for example, mounts, cases, brackets, ducts, inlets, sheet or structural members, fluid-carrying lines (e.g., piping), fluid system parts, wiring, fittings, and powerplant controls. Aircraft interiors and structures can also be made fire- and EMI-resistant. As used herein, a “fire- and EMI-resistant aircraft component” means that that the entire component or at least a portion thereof, is fire- and EMI-resistant.
  • As noted previously, the aircraft component may be used inside or outside of an aircraft fire zone, i.e., an aircraft compartment that contains ignition sources and the potential for flammable fluid leakage. Such compartments are classified as “fire zones.” For example, the engine case around the compressor, combustor, and turbine sections of the engine define a fire zone. The gearbox and its accessories are also considered potential ignition sources during failure conditions that could cause temperatures to exceed the auto ignition temperatures of fluids that may be present in the compartment. The APU compartment is by definition a fire zone. There are other fire zones aboard an aircraft. In accordance with exemplary embodiments, imparting fire-resistance also imparts electromagnetic interference (EMI) resistance.
  • Referring to FIGS. 1 and 3, according to exemplary embodiments, the fire- and EMI-resistant aircraft component 10 comprises an intermediate article 12 and a fire-retardant layer 16 with a thermally and electrically conductive coating material layer 14 between the intermediate article and the fire-retardant layer. This type of coating system is called a “sandwich” coating system because the thermally and electrically conductive coating material layer is bound between two structures—the intermediate article 12 and the fire-retardant material layer 16. The sandwich coating system is used here because- the fire-retardant layer (also known as a “thermally resistant layer) must be on the outside surface for maximum protection.
  • Referring now to FIG. 2, in accordance with exemplary embodiments, a method 100 for manufacturing a fire- and EMI-resistant aircraft component, such as the inlet duct of FIG. 1 (identified as an exemplary fire- and EMI-resistant aircraft component 10 ), begins by providing the intermediate article 12 (step 110 ). The intermediate article 12 comprises a non-metallic material of polymer or composite construction. Suitable exemplary polymers (polymer materials) include natural and synthetic rubber, polymer resins, polyimides, polyether ether ketones (PEEK), cyanate esters, bismaleimids (BMI), neoprenes, nylons, polyvinyl chlorides (PVC or vinyl), polystyrenes, polyethylenes, polypropylenes, polyacrylonitriles, polyvinyl butyrals (PVB), silicones, and many more.
  • “Composite materials” are defined as materials made from two or more constituent materials with significantly different physical or chemical properties, that when combined, produce a material with characteristics different from the individual components. The individual components remain separate and distinct within the finished structure. Suitable exemplary engineered composite materials include composite building materials such as cements, concrete, reinforced plastics such as fiber-reinforced polymers, metal composites, and ceramic composites (composite ceramic and metal matrices). Suitable exemplary fibers used to reinforce the polymers in the fiber-reinforced construction include carbon fibers (e.g., IM7, AS4, T300, etc.), fiber glass, Kevlar, and many more. The non-metallic material comprises a non-fire-resistant material (i.e., the non-metallic material does not pass the flame exposure test).
  • In one embodiment, the intermediate article 12 may be already available and obtainable from commercial sources. For example, the intermediate article may comprise an already manufactured component that fails to pass the flame certification test (i.e., the already manufactured component is non-compliant with the flame certification test and is therefore not fire-resistant). For example, the intermediate article 12 may be part of old stock and rather than scrapping the non-compliant component, a fire- and EMI-resistant component 10 may be manufactured from the non-compliant component (here, the intermediate article) by performing the forming and cold spraying steps 120 and 130 as hereinafter described.
  • In an alternative embodiment, the fire- and EMI-resistant component 10 may be manufactured from an intermediate article 12 formed by any suitable manufacturing process. For example, the intermediate article comprising the polymeric material may be formed by a known additive manufacturing process. The polymeric material (a “build material”) may be used in an additive-manufacturing process as known in the art to form the intermediate article 12 from which the fire- and EMI-resistant component 10 is manufactured. Additive Manufacturing (AM) is defined by the American Society for Testing and Materials (ASTM) as the “process of joining materials to make objects from 3D model data, usually deposit layer upon deposit layer, as opposed to subtractive manufacturing methodologies, such as traditional machining and casting.” Some examples of additive manufacturing processes include: micro-pen deposition in which liquid media is dispensed with precision at the pen tip and then cured; selective laser sintering in which a laser is used to sinter a powder media in precisely controlled locations; laser wire deposition in which a wire feedstock is melted by a laser and then deposited and solidified in precise locations to build the product; electron beam melting; laser engineered net shaping; and direct metal deposition . In general, additive manufacturing processes provide flexibility in free-form fabrication without geometric constraints, fast material processing time, and innovative joining techniques. A finishing step may be performed on the intermediate article formed by the additive-manufacturing process. The finishing step may include, for example, machining, etc. as long as the article is not exposed to heat. In some embodiments, the finishing step may be unnecessary and may be omitted.
  • In an additive-manufacturing process, a model, such as a design model, of the component may be defined in any suitable manner For example, the model may be designed with computer aided design (CAD) software. The model may include 3D numeric coordinates of the entire configuration of the component including both external and internal surfaces of an airfoil, platform and dovetail. The model may include a number of successive 2D cross-sectional slices that together form the 3D component. Sequential deposit layers of build material (in this case, polymeric material) are fused and solidified according to the three-dimensional (3D) model. Each successive deposit layer of the intermediate article may be, for example, between about 10 μm and about 200 μm, although the thickness may be selected based on any number of parameters.
  • In one exemplary embodiment, fused deposition modeling (FDM) may be used to form the additive-manufactured intermediate article comprised of the polymeric material. A schematic of a FDM process is depicted in FIG. 5. FDM is an additive manufacturing process that works on an “additive” principle by laying down material in layers; here, the polymeric filament 18 is unwound from a coil 20 (the “material cartridge in FIG. 5) and is supplied through an extrusion nozzle 22 to form the intermediate article. The FDM process begins with a software process which processes an STL file (stereolithography file format), mathematically slicing and orienting the 3-D model for the build process. The polymeric material is heated (by heater block 24 in FIG. 5) past its glass transition temperature and the molten polymeric material is then deposited by an extrusion head, which follows a tool-path defined by computer-aided manufacturing (CAM) software, and the intermediate article 12 is built from the bottom up, one layer at a time. The filament of the polymeric material is unwound from the coil and supplied to the extrusion nozzle which can turn the flow on and off. The nozzle is heated to melt the polymeric material and can be moved in both horizontal and vertical directions by a numerically controlled mechanism, directly controlled by the computer-aided manufacturing (CAM) software. The intermediate article is formed by extruding small beads of the polymeric material to form layers as the material hardens immediately after extrusion from the nozzle. Stepper motors or servo motors are typically employed to move the extrusion head that includes the extrusion nozzle.
  • Although the FDM additive manufacturing process is described herein for forming the intermediate article comprising a polymeric material, other additive manufacturing processes and other manufacturing processes in general may be employed to form the intermediate article comprising the polymeric material. The intermediate article comprising the composite material may be formed by conventional composite manufacturing processes (e.g., using composite ply lay-ups).
  • Still referring to FIG. 2 and now to FIG. 4, in an embodiment, the step of providing the intermediate article further comprises optionally integrating a continuous electrically conductive element 26 into the substrate of the intermediate article to be formed (step 140). Thus, the intermediate article 12 and the fire- and EMI-resistant aircraft component 10 a to be manufactured therefrom may further comprise the continuous electrically conductive element 26. The material for the continuous electrically conductive element comprises copper, aluminum, and their alloys, as well as combinations thereof. The term “continuous electrically conductive element” as used herein refers to a thin, continuous elongate electrically conductive element generally and more particularly, comprises an electrically conductive wire which may be of any cross-sectional shape such as circular, triangular, square, rectangular or polygonal or a like continuous element in the form of an electrically conductive tape, ribbon, or the like. The continuous electrically conductive element has an electrical resistivity of less than about 2.75 ohm/m at room temperature (70° Fahrenheit). The continuous electrically conductive element may be in a spiral form to add strength to the polymeric material or composite material in the vertical (Z) direction. The continuous electrically conductive element provides EMI-resistance to the fire- and EMI-resistant component 10 a to be manufactured. In addition to providing EMI-resistance, the continuous electrically conductive element 26 also provides a conduction path through the fire- and EMI-resistant aircraft component 10 a, thereby permitting transmission of a signal (e.g., a radio signal) from one end of the component to the other end of the component.
  • The continuous electrically conductive element 26 may be integrated into the intermediate article 12 to be formed by integration with the non-metallic material of the intermediate article to be formed. For example, when forming the intermediate article comprised of the polymeric material by the FDM additive manufacturing process, the extrusion nozzle 22 (FIG. 5) incorporates a twin-arc or dual-arc welding system with dual extrusion heads for simultaneously feeding the polymeric material filament 18 and the continuous electrically conductive element 26, i.e., in this example, the extrusion head may include more than one nozzle to extrude the polymeric component material to build the intermediate article and another nozzle to feed the continuous electrically conductive element through the intermediate article as it is being built. The continuous electrically conductive element extends from one end of the intermediate article to the other end of the intermediate article.
  • The continuous electrically conductive element 26 may be integrated into the intermediate article 12 comprising the polymeric material formed by manufacturing processes other than by the FDM additive manufacturing process. The continuous electrically conductive element 26 may also be integrated into the composite plies when forming a composite ply lay-up (not shown). As noted previously, the continuous electrically conductive element provides EMI-resistance and a conductive path to the fire-and EMI-resistant component 10 a to be manufactured. Additionally, the tensile strength of the fire- and EMI-resistant component 10 a to be manufactured with the continuous electrically conductive element 26 is improved relative to the tensile strength of the fire and EMI-resistant component 10 that does not comprise the continuous electrically conductive element.
  • Referring again to FIGS. 2 through 4, in accordance with exemplary embodiments, the method 100 for manufacturing a fire- and EMI-resistant component continues by forming a layer 302 of conductive coating material (hereinafter “a thermally and electrically conductive coating material layer”) on at least a portion of the intermediate article forming a coated article (step 120). The thermally and electrically conductive coating material layer has a thermal conductivity of greater than 175 W/m-K (watts/meters-Kelvin) at room temperature (70° F.) and an electrical resistivity of less than about 2.75 ohm/m at room temperature. The thermally and electrically conductive coating material layer may be applied locally (“at least a portion”) or over the entire intermediate article 12. The thermally and electrically conductive coating material layer is applied only where fire resistance is needed to avoid adding unnecessary weight. The thermally and electrically conductive coating material layer 14 is comprised of a pure metal or metal alloy. Suitable exemplary materials for the thermally and electrically conductive coating material layer include copper, aluminum, combinations thereof, their alloys, and brass. The thickness of the thermally and electrically conductive coating layer may be from about 10 μm to about 200 μm. The conductive coating material may be applied by cold-spraying techniques. Such techniques are well known in the art. The coating material may alternatively be applied by any known coating techniques such as, for example, chemical vapor deposition, plating, or the like. As the thermal conductivity of the conductive coating material is high (greater than 175 W/m-K), the thermally and electrically conductive coating material layer acts to transfer heat away from the fire- and EMI-aircraft component. The thermally and electrically conductive coating material layer also provides EMI resistance to the fire- and EMI-resistant component.
  • Still referring to FIGS. 2 through 4, in accordance with exemplary embodiments, the method 100 for manufacturing a fire- and EMI-resistant aircraft component continues by thereafter cold spraying the fire-retardant coating 16 on the thermally and electrically conductive coating material layer on the intermediate article (step 130). The fire-retardant coating 16 may be applied by known cold-spraying techniques to a thickness of about 100 μm to about 700 μm. It is preferred for the coating to be as thin as possible because of weight concerns but still provide fire-resistance. The preferred density of the fire-retardant coating is about 98 to about 100 percent. The fire-retardant coating comprises a fire-retardant material. Exemplary fire-retardant materials include nickel-based alloys and superalloys such as INCONEL® alloys, ferrous-based alloys (e.g., stainless steel), cobalt-based alloys, and combinations thereof. Stainless steel is a ferrous-based alloy with a minimum of 10.5% chromium content by mass. The compositions of the INCONEL alloys are different but all are predominantly nickel, with chromium as the second element as shown below:
  • Element (% by mass)
    Inconel Ni Cr Fe Mo Nb Co Mn Cu
    600 72.0 14.0-17.0 6.0-10.0 1.0  0.5
    617 44.2-56.0 20.0-24.0 3.0 8.0-10.0 10.0-15.0 0.5  0.5
    625 58.0 20.0-23.0 5.0 8.0-10.0 3.15-4.15 1.0 0.5 
    718 50.0-55.0 17.0-21.0 balance 2.8-3.3  4.75-5.5  1.0 0.35 0.2-0.8
    X-750 70.0 14.0-17.0 5.0-9.0  0.7-1.2 1.0 1.0  0.5
    Element (% by mass)
    Inconel Al Ti Si C S P B
    600 0.5  0.15 0.015
    617 0.8-1.5 0.6 0.5  0.15 0.015 0.015 0.006
    625 0.4 0.4 0.5  0.1  0.015 0.015
    718 0.65-1.15 0.3 0.35 0.08 0.015 0.015 0.006
    X-750 0.4-1.0 2.25-2.75 0.5  0.08 0.01 
  • The fire-retardant material layer 16 and the thermally and electrically conductive coating material layer 14 cooperate to provide fire-resistance to the non-metallic aircraft component 10, i.e., the fire- and EMI-resistant aircraft component is rendered fire-resistant (i.e., able to pass the flame certification test), certifying the aircraft component for use. The fire-retardant material layer does not otherwise provide sufficient fire resistance (to pass the flame exposure test) to the non-metallic aircraft component without the thermally and electrically conductive coating material layer.
  • While manufacture of a fire- and EMI-resistant component has been described, it is to be understood that an EMI-resistant only component may be manufactured by omitting the thermally and electrically conductive coating material layer (not shown) and corresponding forming step 120. The EMI-resistant only component comprises the intermediate article 12 including the continuous electrically conductive element 26 and the fire-retardant layer 16 disposed directly on the intermediate article.
  • It is to be appreciated that fire- and EMI-resistant aircraft components with lightweight and effective integral fire- and EMI shielding materials and methods for manufacturing the same have been provided. Non-metallic aircraft components may be rendered fire- and EMI-resistant, certifying them for use. The sandwich coating system described herein provides lightweight and effective integral fire- and EMI shielding materials for non-metallic aircraft components, eliminating the need for separate fire and EMI shielding materials that add weight and take up space.
  • In this document, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Numerical ordinals such as “first,” “second,” “third,” etc. simply denote different singles of a plurality and do not imply any order or sequence unless specifically defined by the claim language. The sequence of the text in any of the claims does not imply that process steps must be performed in a temporal or logical order according to such sequence unless it is specifically defined by the language of the claim. The process steps may be interchanged in any order without departing from the scope of the invention as long as such an interchange does not contradict the claim language and is not logically nonsensical.
  • Furthermore, depending on the context, words such as “connect” or “coupled to” used in describing a relationship between different elements do not imply that a direct physical connection must be made between these elements. For example, two elements may be connected to each other physically, electronically, logically, or in any other manner, through one or more additional elements.
  • While at least one exemplary embodiment has been presented in the foregoing detailed description of the invention, it should be appreciated that a vast number of variations exist. It should also be appreciated that the exemplary embodiment or exemplary embodiments are only examples, and are not intended to limit the scope, applicability, or configuration of the invention in any way. Rather, the foregoing detailed description will provide those skilled in the art with a convenient road map for implementing an exemplary embodiment of the invention. It being understood that various changes may be made in the function and arrangement of elements described in an exemplary embodiment without departing from the scope of the invention as set forth in the appended claims.

Claims (20)

What is claimed is:
1. A fire-and EMI-resistant aircraft component comprising:
an article comprised of a polymeric material;
a fire-retardant material layer overlying the article;
a conductive coating material layer intermediate the article and the fire-retardant material layer; and
optionally, at least one continuous electrically conductive element integrated with the polymeric material of the article.
2. The fire and EMI-resistant aircraft component of claim 1, wherein the article includes the at least one continuous electrically conductive element comprising an electrically conductive filament integrated with the polymeric material.
3. The fire and EMI-resistant aircraft component of claim 1, wherein the at least one continuous electrically conductive element comprises a material selected from the group consisting of copper, aluminum, alloys thereof, brass, and combinations thereof.
4. The fire and EMI-resistant aircraft component of claim 1, wherein the conductive coating material layer is comprised of a metal selected from the group consisting of copper, aluminum, alloys thereof, brass, and combinations thereof.
5. The fire and EMI-resistant aircraft component of claim 1, wherein the at least one continuous electrically conductive element extends from a first end of the article to a second end of the article to provide a conduction path through the article.
6. The fire and EMI-resistant aircraft component of claim 5, wherein the at least one continuous electrically conductive element is in a spiral form.
7. The fire and EMI-resistant aircraft component of claim 1, wherein the fire-retardant material is selected from the group consisting of a nickel-based alloy or superalloy, a ferrous-based alloy, a cobalt-based alloy, and combinations thereof.
8. The fire and EMI-resistant aircraft component of claim 1, wherein the conductive coating material layer is applied locally to portions of the article.
9. A fire-and EMI-resistant aircraft component comprising:
an article comprised of a polymeric material having a first end and a second end;
a fire-retardant material layer overlying the article;
a conductive coating material layer intermediate the article and the fire-retardant material layer; and
at least one continuous electrically conductive filament integrated within the polymeric material of the article that extends through the article from the first end to the second end to provide a conduction path through the article.
10. The fire and EMI-resistant aircraft component of claim 9, wherein the at least one continuous electrically conductive element comprises a material selected from the group consisting of copper, aluminum, alloys thereof, brass, and combinations thereof.
11. The fire and EMI-resistant aircraft component of claim 9, wherein the conductive coating material layer is comprised of a metal selected from the group consisting of copper, aluminum, alloys thereof, brass, and combinations thereof.
12. The fire and EMI-resistant aircraft component of claim 9, wherein the at least one continuous electrically conductive element is in a spiral form.
13. The fire and EMI-resistant aircraft component of claim 9, wherein the fire-retardant material is selected from the group consisting of a nickel-based alloy or superalloy, a ferrous-based alloy, a cobalt-based alloy, and combinations thereof.
14. The fire and EMI-resistant aircraft component of claim 9, wherein the article is an inlet duct.
15. The fire and EMI-resistant aircraft component of claim 9, wherein the conductive coating material layer is applied locally to portions of the article.
16. A fire-and EMI-resistant aircraft component comprising:
an article comprised of a polymeric material having a first end and a second end;
a fire-retardant material layer overlying the article;
a conductive coating material layer intermediate the article and the fire-retardant material layer, the conductive coating material layer applied locally to portions of the article; and
at least one continuous electrically conductive filament integrated within the polymeric material of the article that extends through the article from the first end to the second end to provide a conduction path through the article.
17. The fire and EMI-resistant aircraft component of claim 16, wherein the at least one continuous electrically conductive element comprises a material selected from the group consisting of copper, aluminum, alloys thereof, brass, and combinations thereof.
18. The fire and EMI-resistant aircraft component of claim 16, wherein the conductive coating material layer is comprised of a metal selected from the group consisting of copper, aluminum, alloys thereof, brass, and combinations thereof.
19. The fire and EMI-resistant aircraft component of claim 16, wherein the at least one continuous electrically conductive element is in a spiral form.
20. The fire and EMI-resistant aircraft component of claim 16, wherein the fire-retardant material is selected from the group consisting of a nickel-based alloy or superalloy, a ferrous-based alloy, a cobalt-based alloy, and combinations thereof.
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