US20180179698A1

US20180179698A1 - Carbon fiber surface oiling agent changing apparatus

Info

Publication number: US20180179698A1
Application number: US15/389,707
Authority: US
Inventors: Chih-Yung Wang
Original assignee: UHT Unitech Co Ltd
Current assignee: UHT Unitech Co Ltd
Priority date: 2016-12-23
Filing date: 2016-12-23
Publication date: 2018-06-28

Abstract

A carbon fiber surface oiling agent changing apparatus includes a feeding module, a receiving module, a desizing module, a plasma surface treatment module, and a sizing module. A carbon fiber yarn released from the feeding module is sequentially processed at a predetermined speed to perform the steps of desizing, plasma surface treatment, sizing, and so on, in a relatively more active and reliable manner. Particularly, the surface of the carbon fiber yarn is roughened and is provided with functional groups, which is beneficial to achieve high-quality interface bonding of the carbon fiber yarn and the matrix resin in the subsequent sizing step, thereby enhancing the characteristics of carbon fiber composite materials.

Description

FIELD OF THE INVENTION

The present invention relates to a carbon fiber surface treatment apparatus, and more particularly to a carbon fiber surface oiling agent changing apparatus which is capable of effectively changing the oiling agent on the surface of a carbon fiber yarn.

BACKGROUND OF THE INVENTION

Carbon fibers have excellent mechanical properties and electrical properties and can be widely used in various applications. A conventional carbon fiber is achieved by bundling precursor fibers, such as polyacrylonitrile fibers, to form a carbon fiber precursor fiber bundle, and then the carbon fiber precursor fiber bundle is calcined (high-temperature carbonization) to form the carbon fiber.
The surfaces of untreated carbon fibers don't have sufficient adhesion, which have poor transverse properties such as separation strength and shear strength. Therefore, they are less directly utilized. They are usually combined with a matrix resin to form carbon fiber composite materials in accordance with their applications. On the other hand, because carbon fibers and graphite fibers are hard and brittle, they lack adhesion, bending and wear resistance. The surface of the carbon fiber or graphite fiber is always coated with a layer of oiling agent (a sizing agent) before it leaves the factory to protect the fiber from breakage due to friction.
In general, for using the excellent mechanical properties of carbon fibers, the matrix resin of the carbon fiber composite material is a thermosetting resin material to form the so-called thermosetting carbon fiber composite material. The main difference between the thermosetting carbon fiber composite material and the thermoplastic carbon fiber composite material is that the forming time of the traditional thermosetting carbon fiber composite material is long, resulting in lower utilization of the mold, so its production capacity is relatively low.
However, at present, most of the oiling agents on the surfaces of commercially available carbon fiber raw materials are thermosetting resin oiling agents designed according to the wettability of the thermosetting resin oiling agents. In case such carbon fiber raw materials are manufactured to form thermoplastic carbon fiber composite materials, the carbon fiber raw materials and the resin don't match with each to form a complete interface bonding. As a result, it cannot be applied to various kinds of electrical and electronic parts, mechanical parts and automobile parts which are formed by injection molding.
Accordingly, the inventor of the present invention has devoted himself based on his many years of practical experiences to solve these problems.

SUMMARY OF THE INVENTION

In view of the problems of the prior art, the primary object of the present invention is to provide a carbon fiber surface oiling agent changing apparatus.
In order to achieve the forgoing object, the carbon fiber surface oiling agent changing apparatus of the present invention comprises a feeding module, a receiving module, a desizing module, a plasma surface treatment module, and a sizing module. The feeding module is capable of providing a carbon fiber yarn. The carbon fiber yarn is coated with a first oiling agent. The receiving module is disposed in the vicinity of the feeding module and corresponds to the feeding module to constitute a carbon fiber yarn drag route. The receiving module includes at least one yarn winding assembly to receive the carbon fiber yarn released from the feeding module and to perform a drag action on the carbon fiber yarn. The desizing module is disposed at the carbon fiber yarn drag route between the feeding module and the receiving module for removing the first oiling agent. The plasma surface treatment module is disposed at the carbon fiber yarn drag route between the desizing module and the receiving module for providing a plasma gas flow to act on the carbon fiber yarn. The sizing module is disposed at the carbon fiber yarn drag route between the plasma surface treatment module and the receiving module for coating a second oiling agent on the carbon fiber yarn.
Thereby, the carbon fiber surface oiling agent changing apparatus of the present invention can be operated in the integrated operation of the feeding module, the desizing module, the plasma surface treatment module, the sizing module, and the receiving module. The carbon fiber yarn released from the feeding module is sequentially processed at a predetermined speed to perform the steps of desizing, plasma surface treatment, sizing, and so on, in a relatively more active and reliable manner. The oiling agent on the surface of the carbon fiber yarn can be replaced with a desired oiling agent. Particularly, the surface of the carbon fiber yarn is roughened and provided with functional groups, which is beneficial to achieve high-quality interface bonding of the carbon fiber yarn and the matrix resin in the subsequent sizing step, thereby enhancing the characteristics of carbon fiber composite materials.
Preferably, the plasma surface treatment module is provided with at least one plasma generator.
Alternatively, the plasma surface treatment module is provided with at least one plasma generator located at upper and lower positions of the carbon fiber drag route, respectively.
Preferably, the plasma generator is able to generate the plasma gas flow having a power in the range of 100-10000 Watts.
Alternatively, the plasma generator is able to generate an atmospheric plasma gas flow having a power in a range of 100-10000 Watts.
Alternatively, the plasma generator is able to generate a low-pressure plasma gas flow having a power in the range of 100-10000 Watts.
Alternatively, the plasma generator is able to generate a microwave plasma gas flow having a power in the range of 100-10000 Watts.
Alternatively, the plasma generator is able to generate a glow plasma gas flow having a power in the range of 100-10000 Watts.
Preferably, the desizing module is provided with at least one desizing furnace capable of generating a heat source having a temperature of 250-650° C.
Preferably, the sizing module is provided with at least one reservoir for storing the second oiling agent.
Preferably, the carbon fiber surface oiling agent changing apparatus further comprises a drying module. The drying module is disposed at the carbon fiber drag route between the sizing module and the receiving module, enabling the second oiling agent to be firmly adhered to the surface of the carbon fiber yarn.
The carbon fiber surface oiling agent changing apparatus of the present invention is suitable for replacing a thermosetting resin oiling agent on the surface of the existing carbon fiber raw material with a thermoplastic resin oiling agent so that it can be applied to various kinds of electrical and electronic parts, mechanical parts and automobile parts which are formed by injection molding. Particularly, the surface of the carbon fiber yarn is roughened and is provided with functional groups, which is beneficial to achieve high-quality interface bonding of the carbon fiber yarn and the matrix resin in the subsequent sizing step, thereby enhancing the characteristics of carbon fiber composite materials.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a structural schematic view of a carbon fiber surface oiling agent changing apparatus in accordance with a first embodiment of the present invention;

FIG. 2 is a sectional schematic view of a carbon fiber yarn released from a feeding module of the present invention;

FIG. 3 is a sectional schematic view of a carbon fiber yarn after finishing a desizing process through a desizing module of the present invention;

FIG. 4 is a sectional schematic view of a carbon fiber yarn after finishing a plasma surface treatment through a plasma surface treatment module of the present invention;

FIG. 5 is a sectional schematic view of a carbon fiber yarn after finishing a sizing process through a sizing module of the present invention; and

FIG. 6 is a structural schematic view of a carbon fiber surface oiling agent changing apparatus in accordance with a second embodiment of the present invention.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Embodiments of the present invention will now be described, by way of example only, with reference to the accompanying drawings.
The present invention discloses a carbon fiber surface oiling agent changing apparatus which is capable of effectively changing the oiling agent on the surface of a carbon fiber yarn. As shown in FIG. 1, the carbon fiber surface oiling agent changing apparatus of the present invention comprises a feeding module 10, a receiving module 20, a desizing module 30, a plasma surface treatment module 40, and a sizing module 50.
As shown in FIG. 1 to FIG. 5, the feeding module 10 is used to provide a carbon fiber yarn 70 (shown in FIG. 2) whose surface is coated with a first oiling agent 81. The carbon fiber yarn 70 may be made of a carbon fiber precursor fiber bundle formed by bundling precursor fibers, such as rayon, poly vinyl alcohol, vinylidene chloride, polyacrylonitrile (PAN), pitch, and the like, obtained by calcination. In practice, the first oiling agent 81 may be a thermosetting resin oiling agent.
The receiving module 20 is disposed in the vicinity of the feeding module 10, and corresponds to the feeding module 10 to constitute a carbon fiber yarn drag route. The receiving module 20 includes at least one yarn winding assembly 21 to receive the carbon fiber yarn 70 released from the feeding module 10. The yarn winding assembly 21 performs a drag action on the carbon fiber yarn 70 to be received.
The desizing module 30 is disposed at the carbon fiber yarn drag route between the feeding module 10 and the receiving module 20 for removing the first oiling agent 81 from the surface of the carbon fiber yarn 70. The desizing module 30 is provided with at least one desizing furnace 31 capable of generating a heat source having a temperature of 250-650° C., such that the first oiling agent 81 can be removed from the surface of the carbon fiber yarn 70 by the action of the desizing module 30 (as shown in FIG. 3).
The plasma surface treatment module 40 is disposed at the carbon fiber yarn drag route between the desizing module 30 and the receiving module 20 to provide a plasma gas flow with a predetermined power to act on the carbon fiber yarn 70 without the first oiling agent, such that the surface of the carbon fiber yarn 70 is formed with a plasma-modified configuration 71 (shown in FIG. 4) which is relatively rougher or has functional groups.
The sizing module 50 is disposed at the carbon fiber yarn drag route between the plasma surface treatment module 40 and the receiving module 20 for the plasma-modified configuration 71 on the surface of the carbon fiber yarn 70 to be coated with a second oiling agent 82 (as shown in FIG. 5). The sizing module 50 is provided with at least one reservoir 51 for storing the second oiling agent 82.
In practice, the second oiling agent 82 may be a thermosetting resin oiling agent or a thermoplastic resin oiling agent. In an embodiment that the second oiling agent 82 is a thermoplastic resin oiling agent, the second oiling agent 82 may be one of polyurethane (PU), polyethene (PE), polypropylene (PP), and acrylic.
Thereby, the carbon fiber surface oiling agent changing apparatus of the present invention can be operated in the integrated operation of the feeding module 10, the desizing module 30, the plasma surface treatment module 40, the sizing module 50, and the receiving module 20. The carbon fiber yarn 70 released from the feeding module 10 is sequentially processed at a predetermined speed to perform the steps of desizing, plasma surface treatment, sizing, and so on, in a relatively more active and reliable manner. The oiling agent on the surface of the carbon fiber yarn 70 can be replaced with a desired oiling agent. Particularly, it is suitable for replacing a thermosetting resin oiling agent on the surface of the existing carbon fiber raw material with a thermoplastic resin oiling agent so that it can be applied to various kinds of electrical and electronic parts, mechanical parts and automobile parts which are formed by injection molding.
The plasma surface treatment module 40 is provided with at least one plasma generator 41 for generating a plasma gas flow. In this embodiment, the plasma surface treatment module 40 is provided with at least one plasma generator 41 disposed at the upper and lower positions of the carbon fiber yarn drag route, respectively.
The plasma generator generates the plasma gas flow to act on the surface of the carbon fiber yarn. Since the plasma gas flow contains particles having energy, the impurities that originally adhere to the surface of the carbon fiber yarn can be broken to form small molecules and blown away through the physical reaction (collision) and chemical reaction of the plasma gas flow, enabling the surface of the carbon fiber to be roughened and provided with functional groups, which is beneficial to achieve high-quality interface bonding of the carbon fiber and the matrix resin in the subsequent sizing step, thereby enhancing the characteristics of carbon fiber composite materials.
In practice, the plasma generator 41 is able to generate a plasma gas flow having a power in the range of 100-10000 Watts, or an atmospheric plasma gas flow having a power in a range of 100-10000 Watts, or a low-pressure plasma gas flow having a power in the range of 100-10000 Watts, or a microwave plasma gas flow having a power in the range of 100-10000 Watts, or a glow plasma gas flow having a power in the range of 100-10000 Watts.
The plasma surface treatment module of the present invention provides a dry-type surface treatment for the carbon fiber. This not only prevents the carbon fiber from generating additional impurities or sediment but also reduces the working time and working procedure for drying after the completion of the plasma surface treatment.
As shown in FIG. 6, the carbon fiber surface oiling agent changing apparatus of the present invention further comprise a drying module 60. The drying module 60 is disposed at the carbon fiber yarn drag route between the sizing module 50 and the receiving module 20 for the second oiling agent 82 to be firmly adhered to the surface of the carbon fiber yarn. In practice, the drying module 60 is provided with at least one blast furnace 61 to generate hot blast.
Specifically, the carbon fiber surface oiling agent changing apparatus of the present invention is suitable for replacing a thermosetting resin oiling agent on the surface of the existing carbon fiber raw material with a thermoplastic resin oiling agent so that it can be applied to various kinds of electrical and electronic parts, mechanical parts and automobile parts which are formed by injection molding. Particularly, the surface of the carbon fiber yarn is roughened and is provided with functional groups, which is beneficial to achieve high-quality interface bonding of the carbon fiber yarn and the matrix resin in the subsequent sizing step, thereby enhancing the characteristics of carbon fiber composite materials.
Although particular embodiments of the present invention have been described in detail for purposes of illustration, various modifications and enhancements may be made without departing from the spirit and scope of the present invention. Accordingly, the present invention is not to be limited except as by the appended claims.

Claims

What is claimed is:

1. A carbon fiber surface oiling agent changing apparatus, comprising:

a feeding module, capable of providing a carbon fiber yarn, the carbon fiber yarn being coated with a first oiling agent;

a receiving module, disposed in the vicinity of the feeding module and corresponding to the feeding module to constitute a carbon fiber yarn drag route, the receiving module including at least one yarn winding assembly to receive the carbon fiber yarn released from the feeding module and to perform a drag action on the carbon fiber yarn;

a desizing module, disposed at the carbon fiber yarn drag route between the feeding module and the receiving module for removing the first oiling agent;

a plasma surface treatment module, disposed at the carbon fiber yarn drag route between the desizing module and the receiving module for providing a plasma gas flow to act on the carbon fiber yarn; and

a sizing module, disposed at the carbon fiber yarn drag route between the plasma surface treatment module and the receiving module for coating a second oiling agent on the carbon fiber yarn.

2. The carbon fiber surface oiling agent changing apparatus as claimed in claim 1, wherein the plasma surface treatment module is provided with at least one plasma generator.

3. The carbon fiber surface oiling agent changing apparatus as claimed in claim 1, wherein the plasma surface treatment module is provided with at least one plasma generator located at upper and lower positions of the carbon fiber drag route, respectively.

4. The carbon fiber surface oiling agent changing apparatus as claimed in claim 2, wherein the plasma generator is able to generate the plasma gas flow having a power in the range of 100-10000 Watts.

5. The carbon fiber surface oiling agent changing apparatus as claimed in claim 2, wherein the plasma generator is able to generate an atmospheric plasma gas flow having a power in a range of 100-10000 Watts.

6. The carbon fiber surface oiling agent changing apparatus as claimed in claim 2, wherein the plasma generator is able to generate a low-pressure plasma gas flow having a power in the range of 100-10000 Watts.

7. The carbon fiber surface oiling agent changing apparatus as claimed in claim 2, wherein the plasma generator is able to generate a microwave plasma gas flow having a power in the range of 100-10000 Watts.

8. The carbon fiber surface oiling agent changing apparatus as claimed in claim 2, wherein the plasma generator is able to generate a glow plasma gas flow having a power in the range of 100-10000 Watts.

9. The carbon fiber surface oiling agent changing apparatus as claimed in claim 1, wherein the desizing module is provided with at least one desizing furnace capable of generating a heat source having a temperature of 250-650° C.

10. The carbon fiber surface oiling agent changing apparatus as claimed in claim 1, wherein the sizing module is provided with at least one reservoir for storing the second oiling agent.

11. The carbon fiber surface oiling agent changing apparatus as claimed in claim 1, further comprising a drying module, the drying module being disposed at the carbon fiber drag route between the sizing module and the receiving module, enabling the second oiling agent to be firmly adhered to the surface of the carbon fiber yarn.