US20180040817A1 - Embedded memory device between noncontigous interconnect metal layers - Google Patents
Embedded memory device between noncontigous interconnect metal layers Download PDFInfo
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- US20180040817A1 US20180040817A1 US15/230,690 US201615230690A US2018040817A1 US 20180040817 A1 US20180040817 A1 US 20180040817A1 US 201615230690 A US201615230690 A US 201615230690A US 2018040817 A1 US2018040817 A1 US 2018040817A1
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Images
Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B63/00—Resistance change memory devices, e.g. resistive RAM [ReRAM] devices
- H10B63/30—Resistance change memory devices, e.g. resistive RAM [ReRAM] devices comprising selection components having three or more electrodes, e.g. transistors
-
- H01L45/1233—
-
- H01L27/222—
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B61/00—Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B61/00—Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices
- H10B61/20—Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices comprising components having three or more electrodes, e.g. transistors
- H10B61/22—Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices comprising components having three or more electrodes, e.g. transistors of the field-effect transistor [FET] type
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N50/00—Galvanomagnetic devices
- H10N50/01—Manufacture or treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N50/00—Galvanomagnetic devices
- H10N50/10—Magnetoresistive devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/20—Multistable switching devices, e.g. memristors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/821—Device geometry
- H10N70/826—Device geometry adapted for essentially vertical current flow, e.g. sandwich or pillar type devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/881—Switching materials
- H10N70/883—Oxides or nitrides
- H10N70/8833—Binary metal oxides, e.g. TaOx
Definitions
- Non-volatile memory is able to store data in the absence of power, whereas volatile memory is not.
- Magnetoresistive random-access memory (MRAM) and resistive random access memory (RRAM) are promising candidates for next generation non-volatile memory technology due to relative simple structures and their compatibility with complementary metal-oxide-semiconductor (CMOS) logic fabrication processes.
- CMOS complementary metal-oxide-semiconductor
- FIG. 1A illustrates a cross-sectional view of some embodiments of an integrated circuit (IC) having a memory cell embedded in an interconnect structure.
- IC integrated circuit
- FIG. 1B illustrates a cross-sectional view of some alternative embodiments of an integrated circuit (IC) having a memory cell embedded in an interconnect structure.
- IC integrated circuit
- FIG. 2 illustrates a cross-sectional view of some alternative embodiments of an integrated circuit (IC) having a memory cell embedded in an interconnect structure.
- IC integrated circuit
- FIGS. 3-13 illustrate cross-sectional views of some embodiments showing a method of manufacturing an integrated circuit (IC).
- IC integrated circuit
- FIG. 14 illustrates a flow diagram of some embodiments of a method of manufacturing an integrated circuit (IC).
- IC integrated circuit
- first and second features are formed in direct contact
- additional features may be formed between the first and second features, such that the first and second features may not be in direct contact
- present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- spatially relative terms such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures.
- the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures.
- the apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
- a trend in semiconductor manufacturing is to integrate different types of devices on a single substrate to achieve higher integration.
- One example is a substrate having a logic region, in which logic devices are formed, and a memory region, in which magnetic random access memory (MRAM) or resistive random access memory (RRAM) devices are formed.
- MRAM magnetic random access memory
- RRAM resistive random access memory
- a bottom electrode layer can be overfilled into and over a prepared opening of an inter-level dielectric layer of the interconnect structure, and a chemical mechanical polishing (CMP) and/or a patterning process can be used to planarize the bottom electrode layer and form a bottom electrode via (also called BEVA).
- CMP chemical mechanical polishing
- BEVA bottom electrode via
- CMP chemical mechanical polishing
- portions of the metal interconnect lines in the logic region can end up being thinner than in the memory region, possibly even being removed. Consequently, these eroded metal lines can degrade the reliability of the resultant IC.
- heights of interconnection metal layers and thicknesses of the inter-metal dielectric layers also shrink. Therefore, placing a memory device between two adjacent metal layers might not be applicable.
- the present disclosure relates to an improved integrated circuit having an embedded memory device placed between two noncontiguous metal layers and abutting two interconnect metal vias, and associated fabrication methods.
- the integrated circuit comprises a memory region and a logic region.
- a lower metal layer is disposed over a substrate, and comprises a first lower metal line within the memory region and a second lower metal line within the logic region.
- An upper metal layer overlies the lower metal layer, and comprises a first upper metal line within the memory region and a second upper metal line within the logic region.
- a memory cell is disposed between the first lower metal line and the first upper metal line, and comprises a planar bottom electrode and a top electrode separated from the bottom electrode by a resistance switching element.
- the memory cell is respectively connected to the first lower metal line through a first lower metal via abutting the planar bottom electrode and the first upper metal line through a first upper metal via abutting the top electrode.
- FIG. 1A and FIG. 1B respectively show cross-sectional views of integrated circuits (ICs) 100 a and 100 b disposed over a substrate 101 according to some embodiments.
- an interconnect structure 105 is disposed over a substrate 101 and extends across a memory region 124 and a logic region 126 .
- the memory region 124 can correspond to an array of memory cells (e.g., memory cell 130 ), which are disposed in the interconnect structure 105 , while the logic region 126 can couple logic devices, such as transistors formed in the substrate 101 , to support operation of the memory cells.
- the interconnect structure 105 comprises a lower metal layer 128 surrounded by a lower inter-layer dielectric (ILD) layer 104 and an upper metal layer 152 surrounded by an upper ILD layer 146 .
- the lower metal layer 128 and the upper metal layer 152 may comprise copper.
- the lower metal layer 128 comprises a plurality of lower metal lines laterally aligned one another, such as a first lower metal line 102 a at the memory region 124 and a second lower metal line 102 b at the logic region 126 .
- the lower metal layer 128 further comprises a plurality of lower metal vias disposed over the lower metal lines, such as a first lower metal via 112 a coupled to the first lower metal line 102 a and a second lower metal via 112 b coupled to the second lower metal line 102 b .
- a lower etch stop layer 106 and/or a protective liner 108 are disposed directly along upper surfaces of the lower metal lines 102 a , 102 b and the lower ILD layer 104 .
- a lower low-k dielectric layer 110 is disposed over the protective liner 108 having an upper surface aligned with top surfaces of the lower metal vias 112 a , 112 b .
- the lower etch stop layer 106 may comprise silicon carbide, silicon nitride or combination thereof.
- the protective liner 108 may comprise dielectric material such as TEOS (Tetraethyl Orthosilicate).
- the upper metal layer 152 overlies the lower metal layer 128 and the lower ILD layer 104 .
- the upper metal layer 152 may comprise a plurality of upper metal lines laterally aligned one another, such as a first upper metal line 150 a at the memory region 124 and a second upper metal line 150 b at the logic region 126 .
- a plurality of upper metal vias are respectively coupled to the plurality of upper metal lines, including a first upper metal via 148 a coupled to the first upper metal line 150 a and a second upper metal via 148 b coupled to the second lower metal line 150 b .
- an upper etch stop layer 142 and/or a protective liner 144 are disposed surrounding a lower portion of the upper metal vias 148 a , 148 b.
- a memory cell 130 is disposed between the first lower metal via 112 a and the first upper metal via 148 a .
- the memory cell 130 comprises a bottom electrode 132 abutting the first lower metal via 112 a , a resistance switching element 134 over the bottom electrode 132 , and a top electrode 136 over the resistance switching element 134 .
- the bottom electrode 132 may have planar top and bottom surfaces and tilted sidewalls.
- the sidewalls of the bottom electrode 132 may be co-planar with sidewalls of the resistance switching element 134 and the top electrode 136 .
- the resistance switching element 134 comprises a magnetic tunnel junction (MTJ) including a bottom ferromagnetic layer 134 a , a tunnel barrier layer 134 b disposed over the bottom ferromagnetic layer 134 a , and a top ferromagnetic layer 134 c disposed over the tunnel barrier layer 134 b .
- the bottom electrode 132 and the top electrode 136 may comprise titanium nitride (TiN), tantalum nitride (TaN), tantalum (Ta), and/or titanium (Ti) while the lower and upper metal vias 112 a , 148 a may comprise copper.
- a bottom etch stop layer 118 is disposed across the memory region 124 and the logic region 126 surrounding lower portions of the memory cell 130 .
- a remaining upper portion of the memory cell 130 is surrounded by a spacer layer 120 and/or a memory dielectric layer 122 , while a remaining upper portion of the logic region 126 is surrounded by an ILD layer 138 .
- an intermediate metal layer 140 is disposed between the upper metal layer 152 and the lower metal layer 128 within the logic region 126 .
- the intermediate metal layer 140 comprises an intermediate metal line 137 abutting the second upper metal via 148 b and the second lower metal via 112 b and having a height substantially equal to a height of the memory cell 130 .
- the intermediate metal line 137 and the second upper metal line 150 b may have a substantially equal height a 1 .
- the second lower metal line 102 may have a height a 2 smaller than the height a 1 of the intermediate metal line 137 and the second upper metal line 150 b .
- the upper metal vias 148 a , 148 b and the lower metal vias 112 a , 112 b may have a substantially equal height b 1 .
- the height a 1 of the metal lines e.g. 137 , 150
- the height b 1 of the corresponding metal vias e.g. 112 , 148
- a metal line may have a height greater than a height of a corresponding metal via.
- multiple intermediate metal layers 140 ′ are disposed between the upper metal layer 152 and the lower metal layer 128 .
- a first intermediate metal line 139 and a second intermediate metal line 143 are disposed between the second upper metal via 148 b and the second lower metal via 112 b and connected by an intermediate metal via 141 .
- the intermediate metal lines 143 , 139 may have heights a x , a x+1 .
- the heights a x or a x+1 may substantially equal to the height a 1 of the second upper metal line 150 b or the height a 2 of the second lower metal line 102 b .
- the upper metal vias 148 a , 148 b and the lower metal vias 112 a , 112 b may have a substantially equal height b 1 .
- the intermediate metal via 141 may have a heights b x .
- the height b x may substantially be equal to the height b 1 or a height of a metal via under the second lower metal line 102 b .
- FIG. 2 illustrates a cross-sectional view of an integrated circuit (IC) 200 according to some alternative embodiments.
- the IC 200 comprises a substrate 101 and an interconnect structure 105 disposed over the substrate 101 and extending across a memory region 124 and a logic region 126 .
- the interconnect structure 105 can include a plurality of metal layers or other conductive layers, such as first, second, third, fourth, fifth and sixth metal interconnect layers 202 , 204 , 206 , 128 , 140 and 152 stacked over one another and disposed over the substrate 101 .
- Metal lines in the metal interconnect layers can be separated from one another by interlayer dielectric (ILD) materials (e.g.
- ILD interlayer dielectric
- a memory cell 130 is disposed between the fourth interconnect metal layer 128 and the sixth interconnect metal layer 152 within the memory region 124 .
- the memory cell 130 comprises a bottom electrode 132 , and a top electrode 136 , and a resistance switching element 134 separating the top electrode 136 from the bottom electrode 132 .
- the memory cell 130 is a magnetoresistive random access memory (MRAM) cell and the resistance switching element 134 can comprise a magnetic tunnel junction (MTJ) structure having a bottom ferromagnetic layer and a top ferromagnetic layer separated by a tunnel barrier layer.
- MRAM magnetoresistive random access memory
- RRAM resistive random access memory
- An intermediate metal line 137 is disposed within the fifth metal interconnect layer 140 between the fourth interconnect metal layer 128 and the sixth interconnect metal layer 152 within the logic region 126 .
- a bottom etch stop layer 118 is disposed across the memory region 124 and the logic region 126 surrounding lower portions of the memory cell 130 and the intermediate metal line 137 .
- a remaining upper portion of the memory cell 130 is surrounded by a spacer layer 120 and/or a memory dielectric layer 122 , while a remaining upper portion of the intermediate metal line 137 is surrounded by an ILD layer 138 having a dielectric material different from the memory dielectric layer 122 .
- the spacer layer 120 may comprise dielectric material such as TEOS (Tetraethyl Orthosilicate).
- a transistor is arranged over the substrate 101 and between isolation regions 203 .
- the transistor includes a source region 221 , a drain region 239 , a gate electrode 233 , and a gate dielectric 237 .
- a source line 213 (SL) is connected to the source region 221 through a contact plug 219 , a first metal interconnect line 217 , and a first metal via 215 , which are disposed within one or more ILD layers 104 .
- a word line (WL) 235 for addressing the memory cell 130 is coupled to the gate electrode 233 .
- the bottom electrode 132 of the memory cell 130 is connected to the drain region 239 through a contact plug 205 , metal lines 201 A- 201 C and metal vias 222 A- 222 C of the first, second, and third metal interconnect layers 202 , 204 , and 206 , and a first lower metal line 102 a and a first lower metal via 112 a of the fourth metal interconnect layer 128 .
- a first upper metal via 148 a connects the top electrode 136 of the memory cell 130 to a first upper metal line as a bit line (BL) arranged within the sixth metal interconnect layer 152 .
- BL bit line
- the lower metal lines 102 a , 102 b and the lower metal vias 112 a , 112 b are located in the fourth metal interconnect layer 128
- the upper metal lines 150 a , 150 b are located in a sixth metal interconnect layer 152 .
- locations of theses metal layers are amenable to any lower or upper noncontiguous metal interconnect layers.
- FIGS. 3-13 illustrate some embodiments of cross-sectional views showing a method of forming an integrated circuit device.
- a low-k dielectric layer 110 is formed overlying a lower metal layer 128 and extending across a memory region 124 and a logic region 126 .
- the lower metal layer 128 is formed by forming a lower ILD layer 104 (e.g., an oxide, a low-k dielectric, or an ultra low-k dielectric) over a substrate 101 , followed by a damascene process to form openings within the lower ILD layer and fill a metal material (e.g., copper, aluminum, etc.) into the openings.
- a planarization process can be then performed to remove excess metal material to form the lower metal layer 128 .
- the lower metal layer 128 is formed to have a first lower metal line 102 a at the memory region 124 and a second lower metal line 102 b at the logic region 126 .
- the lower metal layer 128 may be disposed within a back-end-of-the-line (BEOL) metal interconnect stack.
- a bottom etch stop layer 106 and a protective layer 108 can be formed between the lower metal layer 128 and the low-k dielectric layer 110 .
- the bottom etch stop layer 106 may comprise silicon-nitride (SiN), silicon-carbide (SiC), or a similar composite dielectric film.
- the protective layer 108 may comprise silicon nitride, tetraethyl orthosilicate (TEOS), silicon-rich oxide (SRO), or a similar composite dielectric film.
- TEOS tetraethyl orthosilicate
- SRO silicon-rich oxide
- the bottom etch stop layer 106 and the protective layer 108 may be formed by a vapor deposition technique (e.g., physical vapor deposition, chemical vapor deposition, etc.).
- a mask layer 406 is formed and patterned over the low-k dielectric layer 110 .
- An etching process 402 is performed to form a first recess 404 a and a second recess 404 b through the low-k dielectric layer, the protective layer 108 , and the bottom etch stop layer 106 , and reach onto the lower metal layer 128 .
- the mask layer 406 can be a photoresist layer having openings corresponding to the first and second recesses 404 a , 404 b to be formed.
- the first and second recesses 404 a , 404 b can be formed through a dry etch process such as a plasma etching.
- the first recess 404 a is formed at the memory region 124 reaching the first lower metal line 102 a and the second recess 404 b is formed at the logic region 126 reaching the second lower metal line 102 b.
- a metal material e.g., copper, aluminum, etc.
- a planarization process is then performed to remove excess metal material to form a first lower metal via 112 a and a second lower metal via 112 b.
- a bottom electrode layer 602 , a resistance switching layer 604 , and a top electrode layer 606 are formed over the lower metal vias 112 a , 112 b and the lower low-k dielectric layer 110 in succession.
- These layers can be formed by a series of vapor deposition techniques (e.g., physical vapor deposition, chemical vapor deposition, etc.).
- a diffusion barrier layer may be deposited prior to depositing the bottom electrode layer 602 .
- a hard mask layer and/or a photoresist layer may be formed on the top electrode layer 606 to facilitate the patterning of the memory cell.
- the resistance switching layer 604 may comprise a RRAM dielectric layer such as metal oxide composite such as hafnium oxide (HfO x ), zirconium oxide (ZrO x ), aluminum oxide (AlO x ), nickel oxide (NiO x ), tantalum oxide (TaO x ), or titanium oxide (TiO x ) as in its relative high resistance state and a metal such as titanium (Ti), hafnium (Hf), platinum (Pt), ruthenium (Ru), and/or aluminum (Al) as in its relative low resistance state.
- metal oxide composite such as hafnium oxide (HfO x ), zirconium oxide (ZrO x ), aluminum oxide (AlO x ), nickel oxide (NiO x ), tantalum oxide (TaO x ), or titanium oxide (TiO x ) as in its relative high resistance state and a metal such as titanium (Ti), hafnium (Hf), platinum (Pt), rut
- the resistance switching layer 604 may comprise a magnetic tunnel junction (MTJ) structure having a bottom ferromagnetic layer and a top ferromagnetic layer separated by a tunnel barrier layer.
- the bottom electrode layer 602 and the top electrode layer 606 may comprise a metal nitride (e.g., titanium nitride (TiN) or tantalum nitride (TaN) and/or a metal (e.g., titanium (Ti) or tantalum (Ta)).
- the top electrode layer 606 , the resistance switching layer 604 , and the bottom electrode layer 602 are patterned to form a top electrode 136 , a resistance switching element 134 and a bottom electrode 132 for a memory cell 130 at the memory region 124 .
- the sidewalls of the top electrode 136 , the resistance switching element 134 and the bottom electrode 132 can be tilted and aligned (e.g. co-planar).
- the bottom electrode layer 602 (shown in FIG.
- the patterning process can comprise a dry etching process that may have an etchant chemistry including CF 4 , CH 2 F 2 , Cl 2 , BCl 3 and/or other chemicals.
- a bottom etch stop layer 118 is formed over the low-k dielectric layer 110 , along outer sidewalls of the memory cell 130 , and may extend to cover a top surface of the top electrode 136 .
- the bottom etch stop layer 118 is a conformal dielectric liner and may extend cross the memory region 124 and the logic region 126 .
- the bottom etch stop layer 118 may comprise silicon-nitride (SiN), silicon-carbide (SiC), or a similar composite dielectric film.
- the bottom etch stop layer 118 may be formed by a vapor deposition technique (e.g., physical vapor deposition, chemical vapor deposition, etc.).
- the bottom etch stop layer 118 can be deposited on the lower low-k dielectric layer 110 prior to forming the bottom electrode layer 602 (shown in FIG. 6 ) and re-deposited after forming the memory cell 130 as described above.
- the bottom etch stop layer 118 may have a lower portion extending under the bottom electrode 132 , as shown by dotted lines.
- a memory dielectric layer 122 is formed over the bottom etch stop layer 118 .
- a spacer layer 120 can be formed along an upper surface of the bottom etch stop layer 118 prior to forming the memory dielectric layer 122 .
- the spacer layer 120 and the memory dielectric layer 122 may respectively comprise silicon nitride, tetraethyl orthosilicate (TEOS), silicon-rich oxide (SRO), or a similar composite dielectric film.
- the spacer layer 120 and the memory dielectric layer 122 may respectively be formed by a vapor deposition technique (e.g., physical vapor deposition, chemical vapor deposition, etc.).
- the memory dielectric layer 122 is patterned and removed from the logic region, and an ILD layer 138 is formed over the bottom etch stop layer 118 within the memory region 124 .
- the ILD layer 138 may comprise an oxide layer, a low-k dielectric layer, or an ultra-low-k dielectric layer formed by a deposition process (e.g., CVD, PECVD, PVD, etc.).
- a planarization process is then performed to remove excessive ILD layer 138 and/or the memory dielectric layer 122 .
- the bottom etch stop layer 118 and the spacer layer 120 are also lowered, such that a top surface of the top electrode 136 is exposed.
- the memory dielectric layer 122 , the bottom etch stop layer 118 and the spacer layer 120 can be lowered in the same planarization process or in separate planarization processes prior to forming the ILD layer 138 .
- an intermediate metal layer 140 is formed through the ILD layer 138 and the bottom etch stop layer 118 within the logic region 126 .
- a damascene process is used to form openings within the ILD layer 138 and fill a metal material (e.g., copper, aluminum, etc.) into the openings.
- a planarization process can be then performed to remove excess metal material.
- an upper ILD layer 146 and an upper metal layer 152 is formed over the memory cell 130 , the intermediate metal layer 140 , and the ILD layer 138 .
- the upper metal layer 152 may comprise a first upper metal line 150 a coupled to the memory cell 130 at the memory region 124 through a first upper metal via 148 a , and a second upper metal line 150 b coupled to the intermediate metal line 140 at the logic region 126 through a second upper metal via 148 b .
- an upper etch stop layer 142 and/or a protective liner 144 are disposed surrounding a lower portion of the upper metal vias 148 a , 148 b .
- a damascene process (including but not limited to a dual damascene process) is used to form vias of the intermediate metal layer 140 and metal lines of the upper metal layer 152 .
- Trenches and via holes are formed through the upper ILD layer 146 , and then filed with a conductive material (e.g., copper).
- a planarization is then performed.
- FIG. 14 shows some embodiments of a flow diagram of a method 1400 of forming a flash memory device.
- method 1400 is described in relation to FIGS. 3-13 , it will be appreciated that the method 1400 is not limited to such structures disclosed in FIGS. 3-13 , but instead may stand alone independent of the structures disclosed in FIGS. 3-13 .
- the structures disclosed in FIGS. 3-13 are not limited to the method 1400 , but instead may stand alone as structures independent of the method 1400 .
- disclosed methods e.g., method 1400
- a lower metal layer is formed over a substrate including a plurality of lower metal lines within a memory region and a logic region.
- the lower metal layer is formed by forming a lower ILD layer over the substrate, followed by a damascene process to form openings within the lower ILD layer and fill a metal material (e.g., copper, aluminum, etc.) into the openings.
- a low-k dielectric layer is then formed overlying the lower metal layer.
- FIG. 3 illustrates some embodiments of a cross-sectional view 300 corresponding to act 1402 .
- a lower metal via is formed within the low-k dielectric layer on the lower metal lines of the lower metal layer.
- the lower metal via is formed by a damascene process.
- FIGS. 4-5 illustrate some embodiments of cross-sectional views 400 , 500 corresponding to act 1404 .
- FIG. 6 illustrates some embodiments of a cross-sectional view 600 corresponding to act 1406 .
- the memory cell layers are patterned to form a top electrode, a resistance switching element, and a bottom electrode for a memory cell within a memory region.
- FIG. 7 illustrates some embodiments of a cross-sectional view 700 corresponding to act 1408 .
- a bottom etch stop layer is formed over the low-k dielectric layer, along outer sidewalls of the memory cell, and may extend to cover a top surface of the top electrode.
- a memory dielectric layer is formed over the bottom etch stop layer within the memory region.
- FIGS. 8-9 illustrate some embodiments of cross-sectional views 800 , 900 corresponding to act 1410 .
- an ILD layer is formed over the bottom etch stop layer within the logic region.
- a planarization process is performed such that upper surfaces of the top electrode, the memory dielectric layer and the ILD layer are aligned.
- FIGS. 10-11 illustrate some embodiments of cross-sectional views 1000 , 1100 corresponding to act 1412 .
- FIG. 12 illustrates some embodiments of a cross-sectional view 1200 corresponding to act 1414 .
- FIG. 13 illustrates some embodiments of a cross-sectional view 1300 corresponding to act 1416 .
- the present disclosure relates to an integrated circuit (IC) including a memory region and a logic region.
- the IC comprises a substrate, a lower metal layer disposed over the substrate, and an upper metal layer overlying the lower metal layer.
- the lower metal layer comprises a first lower metal line within the memory region and a second lower metal line within the logic region.
- the upper metal layer comprises a first upper metal line within the memory region and a second upper metal line within the logic region.
- the IC further comprises a memory cell disposed between the first lower metal line and the first upper metal line, and comprising a planar bottom electrode and a top electrode separated from the bottom electrode by a resistance switching element.
- the memory cell is respectively connected to the first lower metal line through a first lower metal via abutting the planar bottom electrode and the first upper metal line through a first upper metal via abutting the top electrode.
- the present disclosure relates to an integrated circuit (IC) including a memory region and a logic region.
- the IC comprises a substrate and an interconnect structure disposed over the substrate.
- the interconnect structure comprises a plurality of metal layers disposed over one another and surrounded by interlayer dielectric (ILD) materials.
- the plurality of metal layers is connected by a plurality of metal vias.
- the IC further comprises a plurality of memory cells arranged within the memory region and arranged between a lower metal layer and an upper metal layer of the interconnect structure that are noncontiguous from one another.
- a memory cell comprises a bottom electrode disposed on a lower metal via of the lower metal layer and a surrounding lower ILD layer, a resistance switching element disposed over the bottom electrode, and a top electrode disposed over the resistance switching element and abutting a top metal via.
- the bottom electrode, the resistance switching element, and the top electrode have tiled sidewalls co-planar with one another.
- the present disclosure relates to a method of manufacturing an integrated circuit (IC).
- the method comprises forming a lower metal layer extending across a memory region and a logic region within a lower inter-layer dielectric (ILD) layer over a substrate and forming a lower metal via on a lower metal line of the lower metal layer within the memory region and a lower low-k dielectric layer surrounding the lower metal via.
- the method further comprises forming a bottom electrode layer, a resistance switching layer, and a top electrode layer in succession over the lower metal via and the lower low-k dielectric layer and patterning the bottom electrode layer, the resistance switching layer, and the top electrode layer to form a bottom electrode, a resistance switching element, and a top electrode for a memory cell and to remove from the logic region.
- the method further comprises forming an upper metal via on the top electrode and an upper low-k dielectric layer surrounding the upper metal via.
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Abstract
The present disclosure relates an integrated circuit (IC). The IC comprises a memory region and a logic region. A lower metal layer is disposed over a substrate, and comprises a first lower metal line within the memory region. An upper metal layer overlies the lower metal layer, and comprises a first upper metal line within the memory region. A memory cell is disposed between the first lower metal line and the first upper metal line, and comprises a planar bottom electrode. The planar bottom electrode abuts a first lower metal via of the lower metal layer. By forming the planar bottom electrode and connecting the planar bottom electrode to the lower metal layer through the lower metal via, no additional BEVA planarization and/or patterning processes are needed. As a result, risk of damaging the lower metal lines are reduced, thereby providing more reliable read/write operations and/or better performance.
Description
- Many modern electronic devices contain electronic memory configured to store data. Electronic memory may be volatile memory or non-volatile memory. Non-volatile memory is able to store data in the absence of power, whereas volatile memory is not. Magnetoresistive random-access memory (MRAM) and resistive random access memory (RRAM) are promising candidates for next generation non-volatile memory technology due to relative simple structures and their compatibility with complementary metal-oxide-semiconductor (CMOS) logic fabrication processes. As the size of on-chip components is scaled (i.e., reduced), device “shrinkage” allows engineers to integrate more components and more corresponding functionality onto newer generations of ICs. In recent technology nodes, this has allowed for non-volatile memory to be integrated on an integrated chip with logic devices.
- Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
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FIG. 1A illustrates a cross-sectional view of some embodiments of an integrated circuit (IC) having a memory cell embedded in an interconnect structure. -
FIG. 1B illustrates a cross-sectional view of some alternative embodiments of an integrated circuit (IC) having a memory cell embedded in an interconnect structure. -
FIG. 2 illustrates a cross-sectional view of some alternative embodiments of an integrated circuit (IC) having a memory cell embedded in an interconnect structure. -
FIGS. 3-13 illustrate cross-sectional views of some embodiments showing a method of manufacturing an integrated circuit (IC). -
FIG. 14 illustrates a flow diagram of some embodiments of a method of manufacturing an integrated circuit (IC). - The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
- A trend in semiconductor manufacturing is to integrate different types of devices on a single substrate to achieve higher integration. One example is a substrate having a logic region, in which logic devices are formed, and a memory region, in which magnetic random access memory (MRAM) or resistive random access memory (RRAM) devices are formed. To form these memory cells, which are formed within an interconnect structure overlying the substrate, a bottom electrode layer can be overfilled into and over a prepared opening of an inter-level dielectric layer of the interconnect structure, and a chemical mechanical polishing (CMP) and/or a patterning process can be used to planarize the bottom electrode layer and form a bottom electrode via (also called BEVA). In such manufacturing processes, however, chemical mechanical polishing (CMP) may not result in a planar surface over the entire substrate. For example, when the bottom electrode layer (which has a relatively high structural integrity and tends to “resist” CMP relatively well) is present over the memory region but does not extend over the logic region, a metal interconnect line (which has a relatively low structural integrity compared to the bottom electrode layer) may be exposed to CMP in the logic region. Because this metal interconnect line is structurally “weaker” than the bottom electrode, performing CMP on the bottom electrode layer can cause “dishing” of the metal interconnect lines in the logic region. Therefore, after bottom electrode planarization for the memory devices, portions of the metal interconnect lines in the logic region can end up being thinner than in the memory region, possibly even being removed. Consequently, these eroded metal lines can degrade the reliability of the resultant IC. In addition, as the size of on-chip components is scaled, heights of interconnection metal layers and thicknesses of the inter-metal dielectric layers also shrink. Therefore, placing a memory device between two adjacent metal layers might not be applicable.
- The present disclosure relates to an improved integrated circuit having an embedded memory device placed between two noncontiguous metal layers and abutting two interconnect metal vias, and associated fabrication methods. In some embodiments, the integrated circuit comprises a memory region and a logic region. A lower metal layer is disposed over a substrate, and comprises a first lower metal line within the memory region and a second lower metal line within the logic region. An upper metal layer overlies the lower metal layer, and comprises a first upper metal line within the memory region and a second upper metal line within the logic region. A memory cell is disposed between the first lower metal line and the first upper metal line, and comprises a planar bottom electrode and a top electrode separated from the bottom electrode by a resistance switching element. The memory cell is respectively connected to the first lower metal line through a first lower metal via abutting the planar bottom electrode and the first upper metal line through a first upper metal via abutting the top electrode. By forming the planar bottom electrode and connecting the planar bottom electrode to the lower metal layer through the lower metal via, no additional BEVA planarization and/or patterning processes are needed. As a result, risk of damaging the lower metal lines are reduced, thereby providing more reliable read/write operations and/or better performance.
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FIG. 1A andFIG. 1B respectively show cross-sectional views of integrated circuits (ICs) 100 a and 100 b disposed over asubstrate 101 according to some embodiments. As shown inFIG. 1A andFIG. 1B , aninterconnect structure 105 is disposed over asubstrate 101 and extends across amemory region 124 and alogic region 126. Thememory region 124 can correspond to an array of memory cells (e.g., memory cell 130), which are disposed in theinterconnect structure 105, while thelogic region 126 can couple logic devices, such as transistors formed in thesubstrate 101, to support operation of the memory cells. - In some embodiments, the
interconnect structure 105 comprises alower metal layer 128 surrounded by a lower inter-layer dielectric (ILD)layer 104 and anupper metal layer 152 surrounded by anupper ILD layer 146. Thelower metal layer 128 and theupper metal layer 152 may comprise copper. Thelower metal layer 128 comprises a plurality of lower metal lines laterally aligned one another, such as a firstlower metal line 102 a at thememory region 124 and a secondlower metal line 102 b at thelogic region 126. Thelower metal layer 128 further comprises a plurality of lower metal vias disposed over the lower metal lines, such as a first lower metal via 112 a coupled to the firstlower metal line 102 a and a second lower metal via 112 b coupled to the secondlower metal line 102 b. In some embodiments, a loweretch stop layer 106 and/or aprotective liner 108 are disposed directly along upper surfaces of thelower metal lines lower ILD layer 104. A lower low-kdielectric layer 110 is disposed over theprotective liner 108 having an upper surface aligned with top surfaces of thelower metal vias etch stop layer 106 may comprise silicon carbide, silicon nitride or combination thereof. Theprotective liner 108 may comprise dielectric material such as TEOS (Tetraethyl Orthosilicate). Theupper metal layer 152 overlies thelower metal layer 128 and thelower ILD layer 104. Theupper metal layer 152 may comprise a plurality of upper metal lines laterally aligned one another, such as a firstupper metal line 150 a at thememory region 124 and a secondupper metal line 150 b at thelogic region 126. A plurality of upper metal vias are respectively coupled to the plurality of upper metal lines, including a first upper metal via 148 a coupled to the firstupper metal line 150 a and a second upper metal via 148 b coupled to the secondlower metal line 150 b. In some embodiments, an upperetch stop layer 142 and/or aprotective liner 144 are disposed surrounding a lower portion of theupper metal vias - Within the
memory region 124, amemory cell 130 is disposed between the first lower metal via 112 a and the first upper metal via 148 a. In some embodiments, thememory cell 130 comprises a bottom electrode 132 abutting the first lower metal via 112 a, aresistance switching element 134 over the bottom electrode 132, and atop electrode 136 over theresistance switching element 134. The bottom electrode 132 may have planar top and bottom surfaces and tilted sidewalls. The sidewalls of the bottom electrode 132 may be co-planar with sidewalls of theresistance switching element 134 and thetop electrode 136. In some embodiments, theresistance switching element 134 comprises a magnetic tunnel junction (MTJ) including a bottomferromagnetic layer 134 a, a tunnel barrier layer 134 b disposed over the bottomferromagnetic layer 134 a, and a top ferromagnetic layer 134 c disposed over the tunnel barrier layer 134 b. In some embodiments, the bottom electrode 132 and thetop electrode 136 may comprise titanium nitride (TiN), tantalum nitride (TaN), tantalum (Ta), and/or titanium (Ti) while the lower and upper metal vias 112 a, 148 a may comprise copper. In some embodiments, a bottometch stop layer 118 is disposed across thememory region 124 and thelogic region 126 surrounding lower portions of thememory cell 130. A remaining upper portion of thememory cell 130 is surrounded by aspacer layer 120 and/or amemory dielectric layer 122, while a remaining upper portion of thelogic region 126 is surrounded by anILD layer 138. - In some embodiments, referring to
FIG. 1A , anintermediate metal layer 140 is disposed between theupper metal layer 152 and thelower metal layer 128 within thelogic region 126. Theintermediate metal layer 140 comprises an intermediate metal line 137 abutting the second upper metal via 148 b and the second lower metal via 112 b and having a height substantially equal to a height of thememory cell 130. In some embodiments, the intermediate metal line 137 and the secondupper metal line 150 b may have a substantially equal height a1. The second lower metal line 102 may have a height a2 smaller than the height a1 of the intermediate metal line 137 and the secondupper metal line 150 b. In some embodiments, the upper metal vias 148 a, 148 b and the lower metal vias 112 a, 112 b may have a substantially equal height b1. For some further scaling nodes, such as 7 nm node and beyond, the height a1 of the metal lines (e.g. 137, 150) may be reduced to be substantially equal to the height b1 of the corresponding metal vias (e.g. 112, 148), while in some current integrated circuits a metal line may have a height greater than a height of a corresponding metal via. By forming thememory cell 130 between noncontiguous metal layers (e.g. the metal layers 152 and 128) and directly between two layers of metal vias (e.g. the metal vias 148 a and 112 a), memory cell dimension limitations are reduced and no additional BEVA structure is needed. - In some alternative embodiments, referring to
FIG. 1B , multipleintermediate metal layers 140′ are disposed between theupper metal layer 152 and thelower metal layer 128. For example, a first intermediate metal line 139 and a secondintermediate metal line 143 are disposed between the second upper metal via 148 b and the second lower metal via 112 b and connected by an intermediate metal via 141. In some embodiments, theintermediate metal lines 143, 139 may have heights ax, ax+1. The heights ax or ax+1 may substantially equal to the height a1 of the secondupper metal line 150 b or the height a2 of the secondlower metal line 102 b. The upper metal vias 148 a, 148 b and the lower metal vias 112 a, 112 b may have a substantially equal height b1. The intermediate metal via 141 may have a heights bx. The height bx may substantially be equal to the height b1 or a height of a metal via under the secondlower metal line 102 b. By incorporating thememory cell 130 to cross more than one intermediate metal layers, dimensions of metal layers and ILD layers therebetween can be further reduced without being affected by the memory cells limitations. -
FIG. 2 illustrates a cross-sectional view of an integrated circuit (IC) 200 according to some alternative embodiments. As shown inFIG. 2 , theIC 200 comprises asubstrate 101 and aninterconnect structure 105 disposed over thesubstrate 101 and extending across amemory region 124 and alogic region 126. Theinterconnect structure 105 can include a plurality of metal layers or other conductive layers, such as first, second, third, fourth, fifth and sixth metal interconnect layers 202, 204, 206, 128, 140 and 152 stacked over one another and disposed over thesubstrate 101. Metal lines in the metal interconnect layers can be separated from one another by interlayer dielectric (ILD) materials (e.g. 104, 138, 146), such as silicon dioxide or one or more kinds of low-k dielectric materials, and etch stop layers and protective layers (e.g. 118, 142, 144) such as silicon carbide silicon nitride or other dielectric layers. In some embodiments, amemory cell 130 is disposed between the fourthinterconnect metal layer 128 and the sixthinterconnect metal layer 152 within thememory region 124. In some embodiments, thememory cell 130 comprises a bottom electrode 132, and atop electrode 136, and aresistance switching element 134 separating thetop electrode 136 from the bottom electrode 132. In some embodiments, thememory cell 130 is a magnetoresistive random access memory (MRAM) cell and theresistance switching element 134 can comprise a magnetic tunnel junction (MTJ) structure having a bottom ferromagnetic layer and a top ferromagnetic layer separated by a tunnel barrier layer. In some other embodiments, thememory cell 130 is a resistive random access memory (RRAM) cell and theresistance switching element 134 can comprise a RRAM dielectric layer. An intermediate metal line 137 is disposed within the fifthmetal interconnect layer 140 between the fourthinterconnect metal layer 128 and the sixthinterconnect metal layer 152 within thelogic region 126. In some embodiments, a bottometch stop layer 118 is disposed across thememory region 124 and thelogic region 126 surrounding lower portions of thememory cell 130 and the intermediate metal line 137. A remaining upper portion of thememory cell 130 is surrounded by aspacer layer 120 and/or amemory dielectric layer 122, while a remaining upper portion of the intermediate metal line 137 is surrounded by anILD layer 138 having a dielectric material different from thememory dielectric layer 122. Thespacer layer 120 may comprise dielectric material such as TEOS (Tetraethyl Orthosilicate). - In some embodiments, within the
memory region 124, a transistor is arranged over thesubstrate 101 and betweenisolation regions 203. The transistor includes asource region 221, adrain region 239, agate electrode 233, and agate dielectric 237. A source line 213 (SL) is connected to thesource region 221 through acontact plug 219, a firstmetal interconnect line 217, and a first metal via 215, which are disposed within one or more ILD layers 104. A word line (WL) 235 for addressing thememory cell 130 is coupled to thegate electrode 233. The bottom electrode 132 of thememory cell 130 is connected to thedrain region 239 through acontact plug 205,metal lines 201A-201C andmetal vias 222A-222C of the first, second, and third metal interconnect layers 202, 204, and 206, and a firstlower metal line 102 a and a first lower metal via 112 a of the fourthmetal interconnect layer 128. In some embodiments, a first upper metal via 148 a connects thetop electrode 136 of thememory cell 130 to a first upper metal line as a bit line (BL) arranged within the sixthmetal interconnect layer 152. - It is appreciated that in this example, the
lower metal lines metal interconnect layer 128, and theupper metal lines metal interconnect layer 152. However, locations of theses metal layers are amenable to any lower or upper noncontiguous metal interconnect layers. -
FIGS. 3-13 illustrate some embodiments of cross-sectional views showing a method of forming an integrated circuit device. - As shown in
cross-sectional view 300 ofFIG. 3 , a low-k dielectric layer 110 is formed overlying alower metal layer 128 and extending across amemory region 124 and alogic region 126. In some embodiments, thelower metal layer 128 is formed by forming a lower ILD layer 104 (e.g., an oxide, a low-k dielectric, or an ultra low-k dielectric) over asubstrate 101, followed by a damascene process to form openings within the lower ILD layer and fill a metal material (e.g., copper, aluminum, etc.) into the openings. A planarization process can be then performed to remove excess metal material to form thelower metal layer 128. Thelower metal layer 128 is formed to have a firstlower metal line 102 a at thememory region 124 and a secondlower metal line 102 b at thelogic region 126. In some embodiments, thelower metal layer 128 may be disposed within a back-end-of-the-line (BEOL) metal interconnect stack. A bottometch stop layer 106 and aprotective layer 108 can be formed between thelower metal layer 128 and the low-k dielectric layer 110. In some embodiments, the bottometch stop layer 106 may comprise silicon-nitride (SiN), silicon-carbide (SiC), or a similar composite dielectric film. In some embodiments, theprotective layer 108 may comprise silicon nitride, tetraethyl orthosilicate (TEOS), silicon-rich oxide (SRO), or a similar composite dielectric film. In some embodiments, the bottometch stop layer 106 and theprotective layer 108 may be formed by a vapor deposition technique (e.g., physical vapor deposition, chemical vapor deposition, etc.). - As shown in
cross-sectional view 400 ofFIG. 4 , amask layer 406 is formed and patterned over the low-k dielectric layer 110. Anetching process 402 is performed to form afirst recess 404 a and asecond recess 404 b through the low-k dielectric layer, theprotective layer 108, and the bottometch stop layer 106, and reach onto thelower metal layer 128. Themask layer 406 can be a photoresist layer having openings corresponding to the first andsecond recesses second recesses first recess 404 a is formed at thememory region 124 reaching the firstlower metal line 102 a and thesecond recess 404 b is formed at thelogic region 126 reaching the secondlower metal line 102 b. - As shown in
cross-sectional view 500 ofFIG. 5 , a metal material (e.g., copper, aluminum, etc.) is filled into the openings (404 a, 404 b ofFIG. 4 ). A planarization process is then performed to remove excess metal material to form a first lower metal via 112 a and a second lower metal via 112 b. - As shown in
cross-sectional view 600 ofFIG. 6 , abottom electrode layer 602, aresistance switching layer 604, and a top electrode layer 606 are formed over the lower metal vias 112 a, 112 b and the lower low-k dielectric layer 110 in succession. These layers can be formed by a series of vapor deposition techniques (e.g., physical vapor deposition, chemical vapor deposition, etc.). Though not shown in figures, in some embodiments, a diffusion barrier layer may be deposited prior to depositing thebottom electrode layer 602. A hard mask layer and/or a photoresist layer (not shown) may be formed on the top electrode layer 606 to facilitate the patterning of the memory cell. In some embodiments, theresistance switching layer 604 may comprise a RRAM dielectric layer such as metal oxide composite such as hafnium oxide (HfOx), zirconium oxide (ZrOx), aluminum oxide (AlOx), nickel oxide (NiOx), tantalum oxide (TaOx), or titanium oxide (TiOx) as in its relative high resistance state and a metal such as titanium (Ti), hafnium (Hf), platinum (Pt), ruthenium (Ru), and/or aluminum (Al) as in its relative low resistance state. In some embodiments, theresistance switching layer 604 may comprise a magnetic tunnel junction (MTJ) structure having a bottom ferromagnetic layer and a top ferromagnetic layer separated by a tunnel barrier layer. In various embodiments, thebottom electrode layer 602 and the top electrode layer 606 may comprise a metal nitride (e.g., titanium nitride (TiN) or tantalum nitride (TaN) and/or a metal (e.g., titanium (Ti) or tantalum (Ta)). - As shown in
cross-sectional view 700 ofFIG. 7 , the top electrode layer 606, theresistance switching layer 604, and the bottom electrode layer 602 (shown inFIG. 6 ) are patterned to form atop electrode 136, aresistance switching element 134 and a bottom electrode 132 for amemory cell 130 at thememory region 124. In some embodiments, the sidewalls of thetop electrode 136, theresistance switching element 134 and the bottom electrode 132 can be tilted and aligned (e.g. co-planar). In some other embodiments, the bottom electrode layer 602 (shown inFIG. 6 ) can be patterned according to thetop electrode 136 and theresistance switching element 134, and according to an additional spacer alongside thetop electrode 136 and the resistance switching element 134 (not shown). In some embodiments, the patterning process can comprise a dry etching process that may have an etchant chemistry including CF4, CH2F2, Cl2, BCl3 and/or other chemicals. - As shown in
cross-sectional view 800 ofFIG. 8 , a bottometch stop layer 118 is formed over the low-k dielectric layer 110, along outer sidewalls of thememory cell 130, and may extend to cover a top surface of thetop electrode 136. In some embodiments, the bottometch stop layer 118 is a conformal dielectric liner and may extend cross thememory region 124 and thelogic region 126. The bottometch stop layer 118 may comprise silicon-nitride (SiN), silicon-carbide (SiC), or a similar composite dielectric film. In some embodiments, the bottometch stop layer 118 may be formed by a vapor deposition technique (e.g., physical vapor deposition, chemical vapor deposition, etc.). In some alternative embodiments, the bottometch stop layer 118 can be deposited on the lower low-k dielectric layer 110 prior to forming the bottom electrode layer 602 (shown inFIG. 6 ) and re-deposited after forming thememory cell 130 as described above. In this case, the bottometch stop layer 118 may have a lower portion extending under the bottom electrode 132, as shown by dotted lines. - As shown in
cross-sectional view 900 ofFIG. 9 , amemory dielectric layer 122 is formed over the bottometch stop layer 118. In some embodiments, aspacer layer 120 can be formed along an upper surface of the bottometch stop layer 118 prior to forming thememory dielectric layer 122. In some embodiments, thespacer layer 120 and thememory dielectric layer 122 may respectively comprise silicon nitride, tetraethyl orthosilicate (TEOS), silicon-rich oxide (SRO), or a similar composite dielectric film. In some embodiments, thespacer layer 120 and thememory dielectric layer 122 may respectively be formed by a vapor deposition technique (e.g., physical vapor deposition, chemical vapor deposition, etc.). - As shown in
cross-sectional view 1000 ofFIG. 10 , thememory dielectric layer 122 is patterned and removed from the logic region, and anILD layer 138 is formed over the bottometch stop layer 118 within thememory region 124. In some embodiments, theILD layer 138 may comprise an oxide layer, a low-k dielectric layer, or an ultra-low-k dielectric layer formed by a deposition process (e.g., CVD, PECVD, PVD, etc.). - As shown in
cross-sectional view 1100 ofFIG. 11 , a planarization process is then performed to removeexcessive ILD layer 138 and/or thememory dielectric layer 122. In some embodiments, the bottometch stop layer 118 and thespacer layer 120 are also lowered, such that a top surface of thetop electrode 136 is exposed. Thememory dielectric layer 122, the bottometch stop layer 118 and thespacer layer 120 can be lowered in the same planarization process or in separate planarization processes prior to forming theILD layer 138. - As shown in
cross-sectional view 1200 ofFIG. 12 , anintermediate metal layer 140, including anintermediate metal line 140, is formed through theILD layer 138 and the bottometch stop layer 118 within thelogic region 126. In some embodiments, a damascene process is used to form openings within theILD layer 138 and fill a metal material (e.g., copper, aluminum, etc.) into the openings. A planarization process can be then performed to remove excess metal material. - As shown in
cross-sectional view 1300 ofFIG. 13 , anupper ILD layer 146 and anupper metal layer 152 is formed over thememory cell 130, theintermediate metal layer 140, and theILD layer 138. Theupper metal layer 152 may comprise a firstupper metal line 150 a coupled to thememory cell 130 at thememory region 124 through a first upper metal via 148 a, and a secondupper metal line 150 b coupled to theintermediate metal line 140 at thelogic region 126 through a second upper metal via 148 b. In some embodiments, an upperetch stop layer 142 and/or aprotective liner 144 are disposed surrounding a lower portion of the upper metal vias 148 a, 148 b. In some embodiments, a damascene process (including but not limited to a dual damascene process) is used to form vias of theintermediate metal layer 140 and metal lines of theupper metal layer 152. Trenches and via holes are formed through theupper ILD layer 146, and then filed with a conductive material (e.g., copper). A planarization is then performed. -
FIG. 14 shows some embodiments of a flow diagram of amethod 1400 of forming a flash memory device. Althoughmethod 1400 is described in relation toFIGS. 3-13 , it will be appreciated that themethod 1400 is not limited to such structures disclosed inFIGS. 3-13 , but instead may stand alone independent of the structures disclosed inFIGS. 3-13 . Similarly, it will be appreciated that the structures disclosed inFIGS. 3-13 are not limited to themethod 1400, but instead may stand alone as structures independent of themethod 1400. Also, while disclosed methods (e.g., method 1400) are illustrated and described below as a series of acts or events, it will be appreciated that the illustrated ordering of such acts or events are not to be interpreted in a limiting sense. For example, some acts may occur in different orders and/or concurrently with other acts or events apart from those illustrated and/or described herein. In addition, not all illustrated acts may be required to implement one or more aspects or embodiments of the description herein. Further, one or more of the acts depicted herein may be carried out in one or more separate acts and/or phases. - At 1402, a lower metal layer is formed over a substrate including a plurality of lower metal lines within a memory region and a logic region. In some embodiments, the lower metal layer is formed by forming a lower ILD layer over the substrate, followed by a damascene process to form openings within the lower ILD layer and fill a metal material (e.g., copper, aluminum, etc.) into the openings. A low-k dielectric layer is then formed overlying the lower metal layer.
FIG. 3 illustrates some embodiments of across-sectional view 300 corresponding to act 1402. - At 1404, a lower metal via is formed within the low-k dielectric layer on the lower metal lines of the lower metal layer. In some embodiments, the lower metal via is formed by a damascene process.
FIGS. 4-5 illustrate some embodiments ofcross-sectional views - At 1406, memory cell layers including a bottom electrode layer, a resistance switching layer, and a top electrode layer are formed over the lower metal via and the lower low-k dielectric layer in succession.
FIG. 6 illustrates some embodiments of across-sectional view 600 corresponding to act 1406. - At 1408, the memory cell layers are patterned to form a top electrode, a resistance switching element, and a bottom electrode for a memory cell within a memory region.
FIG. 7 illustrates some embodiments of across-sectional view 700 corresponding to act 1408. - At 1410, a bottom etch stop layer is formed over the low-k dielectric layer, along outer sidewalls of the memory cell, and may extend to cover a top surface of the top electrode. A memory dielectric layer is formed over the bottom etch stop layer within the memory region.
FIGS. 8-9 illustrate some embodiments ofcross-sectional views - At 1412, an ILD layer is formed over the bottom etch stop layer within the logic region. In some embodiments, a planarization process is performed such that upper surfaces of the top electrode, the memory dielectric layer and the ILD layer are aligned.
FIGS. 10-11 illustrate some embodiments ofcross-sectional views - At 1414, an intermediate metal line is formed through the ILD layer within the logic region to reach on one of the lower metal lines.
FIG. 12 illustrates some embodiments of across-sectional view 1200 corresponding to act 1414. - At 1416, a first upper metal via and a second upper metal via are formed directly abutting the top electrode of the memory cell or the intermediate metal line. The upper metal vias respectively connect the memory cell and the intermediate metal line to upper metal lines formed there above.
FIG. 13 illustrates some embodiments of across-sectional view 1300 corresponding to act 1416. - It will be appreciated that while reference is made throughout this document to exemplary structures in discussing aspects of methodologies described herein that those methodologies are not to be limited by the corresponding structures presented. Rather, the methodologies (and structures) are to be considered independent of one another and able to stand alone and be practiced without regard to any of the particular aspects depicted in the Figs. Additionally, layers described herein, can be formed in any suitable manner, such as with spin on, sputtering, growth and/or deposition techniques, etc.
- Also, equivalent alterations and/or modifications may occur to those skilled in the art based upon a reading and/or understanding of the specification and annexed drawings. The disclosure herein includes such modifications and alterations and is generally not intended to be limited thereby. For example, although the figures provided herein are illustrated and described to have a particular doping type, it will be appreciated that alternative doping types may be utilized as will be appreciated by one of ordinary skill in the art.
- In some embodiment, the present disclosure relates to an integrated circuit (IC) including a memory region and a logic region. The IC comprises a substrate, a lower metal layer disposed over the substrate, and an upper metal layer overlying the lower metal layer. The lower metal layer comprises a first lower metal line within the memory region and a second lower metal line within the logic region. The upper metal layer comprises a first upper metal line within the memory region and a second upper metal line within the logic region. The IC further comprises a memory cell disposed between the first lower metal line and the first upper metal line, and comprising a planar bottom electrode and a top electrode separated from the bottom electrode by a resistance switching element. The memory cell is respectively connected to the first lower metal line through a first lower metal via abutting the planar bottom electrode and the first upper metal line through a first upper metal via abutting the top electrode.
- In another embodiment, the present disclosure relates to an integrated circuit (IC) including a memory region and a logic region. The IC comprises a substrate and an interconnect structure disposed over the substrate. The interconnect structure comprises a plurality of metal layers disposed over one another and surrounded by interlayer dielectric (ILD) materials. The plurality of metal layers is connected by a plurality of metal vias. The IC further comprises a plurality of memory cells arranged within the memory region and arranged between a lower metal layer and an upper metal layer of the interconnect structure that are noncontiguous from one another. A memory cell comprises a bottom electrode disposed on a lower metal via of the lower metal layer and a surrounding lower ILD layer, a resistance switching element disposed over the bottom electrode, and a top electrode disposed over the resistance switching element and abutting a top metal via. The bottom electrode, the resistance switching element, and the top electrode have tiled sidewalls co-planar with one another.
- In yet another embodiment, the present disclosure relates to a method of manufacturing an integrated circuit (IC). The method comprises forming a lower metal layer extending across a memory region and a logic region within a lower inter-layer dielectric (ILD) layer over a substrate and forming a lower metal via on a lower metal line of the lower metal layer within the memory region and a lower low-k dielectric layer surrounding the lower metal via. The method further comprises forming a bottom electrode layer, a resistance switching layer, and a top electrode layer in succession over the lower metal via and the lower low-k dielectric layer and patterning the bottom electrode layer, the resistance switching layer, and the top electrode layer to form a bottom electrode, a resistance switching element, and a top electrode for a memory cell and to remove from the logic region. The method further comprises forming an upper metal via on the top electrode and an upper low-k dielectric layer surrounding the upper metal via.
- The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
Claims (21)
1. An integrated circuit (IC) including a memory region and a logic region, comprising:
a substrate;
a lower metal layer disposed over the substrate, and comprising a first lower metal line within the memory region and a second lower metal line within the logic region;
an upper metal layer overlying the lower metal layer, and comprising a first upper metal line within the memory region and a second upper metal line within the logic region;
a memory cell disposed between the first lower metal line and the first upper metal line, and comprising a bottom electrode and a top electrode separated from the bottom electrode by a resistance switching element, wherein the memory cell is respectively connected to the first lower metal line through a first lower metal via abutting the bottom electrode and the first upper metal line through a first upper metal via abutting the top electrode; and
an intermediate metal line disposed between the second lower metal line and the second upper metal line, and connected to the second lower metal line through a second lower metal via and the second upper metal line through a second upper metal via;
wherein the intermediate metal line has a height substantially equal to a height of the memory cell.
2. (canceled)
3. The IC of claim 1 , wherein the first lower metal via and the first upper metal via respectively have heights equal to a height of the memory cell.
4. The IC of claim 1 , further comprising:
a lower interlayer dielectric (ILD) layer surrounding the lower metal layer; and
a bottom etch stop layer disposed over the lower ILD layer and the lower metal layer and extending upwardly along sidewalls of the memory cell.
5. The IC of claim 4 , further comprising:
a spacer layer disposed along an upper surface of the bottom etch stop layer within the memory region; and
a memory dielectric layer disposed over the spacer layer and having an upper surface laterally aligned with an upper surface of the top electrode.
6. The IC of claim 5 , further comprising:
a low-k dielectric layer disposed over the bottom etch stop layer within the logic region and having an upper surface laterally aligned with an upper surface of the top electrode;
wherein the low-k dielectric layer has a dielectric constant smaller than that of the memory dielectric layer.
7. The IC of claim 5 , wherein the bottom etch stop layer comprises silicon carbide.
8. The IC of claim 5 , wherein the spacer layer comprises silicon nitride.
9. The IC of claim 5 , wherein the memory dielectric layer comprises TEOS (Tetraethyl Orthosilicate).
10. The IC of claim 1 ,
wherein the lower metal layer and the upper metal layer are made of copper;
wherein the bottom electrode and the top electrode comprise titanium nitride (TiN), tantalum nitride (TaN), tantalum (Ta), and/or titanium (Ti).
11. The IC of claim 1 , wherein the memory cell is a magnetoresistive random access memory (MRAM) cell, the resistance switching element of the MRAM cell comprising:
a bottom ferromagnetic layer disposed over the bottom electrode;
a tunnel barrier layer disposed over the bottom ferromagnetic layer; and
a top ferromagnetic layer disposed over the tunnel barrier layer.
12. The IC of claim 1 , wherein the memory cell is a resistive random access memory (RRAM) cell comprising a bottom electrode and a top electrode separated by a RRAM dielectric layer.
13. An integrated circuit (IC) including a memory region and a logic region, comprising:
a substrate;
an interconnect structure disposed over the substrate, the interconnect structure comprising a plurality of metal layers stacked over one another and surrounded by interlayer dielectric (ILD) materials, the plurality of metal layers including a plurality of metal lines being connected by a plurality of metal vias;
a plurality of memory cells arranged within the memory region and arranged between a lower metal layer and an upper metal layer of the interconnect structure that are noncontiguous from one another, a memory cell comprising:
a bottom electrode disposed on a lower metal via of the lower metal layer and a lower ILD layer surrounding the lower metal via;
a resistance switching element disposed over the bottom electrode; and
a top electrode disposed over the resistance switching element and abutting an upper metal via;
a bottom etch stop layer disposed on the lower ILD layer within the memory region and the logic region, and extending upwardly along sidewalls of the memory cell; and
a spacer layer disposed along an upper surface of the bottom etch stop layer within the memory region.
14. The IC of claim 13 , further comprising:
a memory dielectric layer disposed within the memory region overlying and surrounding the bottom etch stop layer; and
a low-k dielectric layer disposed within the logic region overlying the bottom etch stop layer.
15. The IC of claim 13 , wherein the lower ILD layer comprises a low-k dielectric material and is separated from a lower metal line of the lower metal layer disposed underlying the lower metal via.
16. A method for manufacturing an integrated circuit, comprising:
forming a lower metal layer extending across a memory region and a logic region within a lower inter-layer dielectric (ILD) layer over a substrate;
forming a lower metal via on a lower metal line of the lower metal layer within the memory region and a lower low-k dielectric layer surrounding the lower metal via;
forming a bottom electrode layer, a resistance switching layer, and a top electrode layer in succession over the lower metal via and the lower low-k dielectric layer;
patterning the bottom electrode layer, the resistance switching layer, and the top electrode layer to form a bottom electrode, a resistance switching element, and a top electrode for a memory cell and to remove from the logic region;
forming a bottom etch stop layer on the lower low-k dielectric layer surrounding the memory cell;
forming a memory dielectric layer over the bottom etch stop layer;
patterning the memory dielectric layer to remove from the logic region; and
forming an upper metal via on the top electrode and an upper low-k dielectric layer surrounding the upper metal via.
17. The method of claim 16 , further comprising:
forming a low-k dielectric layer overlying the memory dielectric layer within the memory region and on the bottom etch stop layer within the logic region; and
performing a planarization process to remove excessive portions of the low-k dielectric layer and/or the memory dielectric layer and to form upper surfaces of the low-k dielectric layer and the memory dielectric layer laterally aligned.
18. The method of claim 17 , further comprising:
forming an intermediate metal line through the lower low-k dielectric layer to reach on the lower metal layer within the logic region;
wherein the intermediate metal line has a substantially equal height with the memory cell.
19. The method of claim 17 , further comprising:
forming a spacer layer between the bottom etch stop layer and the memory dielectric layer;
wherein an outer sidewall of the spacer layer is vertically aligned with that of the memory dielectric layer.
20. The method of claim 19 , wherein the top electrode of the memory cell, the spacer layer, and the memory dielectric layer are formed to have top surfaces laterally aligned.
21. The IC of claim 1 , wherein the first lower metal via has a height substantially equal to a height of the second lower metal via.
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CN107706204A (en) | 2018-02-16 |
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US9893278B1 (en) | 2018-02-13 |
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