US20160190154A1 - Methods for making a trim-rate tolerant self-aligned contact via structure array - Google Patents
Methods for making a trim-rate tolerant self-aligned contact via structure array Download PDFInfo
- Publication number
- US20160190154A1 US20160190154A1 US14/584,179 US201414584179A US2016190154A1 US 20160190154 A1 US20160190154 A1 US 20160190154A1 US 201414584179 A US201414584179 A US 201414584179A US 2016190154 A1 US2016190154 A1 US 2016190154A1
- Authority
- US
- United States
- Prior art keywords
- layer
- hard mask
- mask layer
- trimming
- layers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 229
- 239000000463 material Substances 0.000 claims abstract description 376
- 238000009966 trimming Methods 0.000 claims abstract description 131
- 239000000758 substrate Substances 0.000 claims abstract description 59
- 238000005530 etching Methods 0.000 claims abstract description 12
- 239000004065 semiconductor Substances 0.000 claims description 124
- 230000015654 memory Effects 0.000 claims description 77
- 239000003989 dielectric material Substances 0.000 claims description 76
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 31
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 31
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 23
- 238000012545 processing Methods 0.000 claims description 23
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 23
- 238000003860 storage Methods 0.000 claims description 20
- 229920002120 photoresistant polymer Polymers 0.000 claims description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 230000006870 function Effects 0.000 claims description 8
- 239000002861 polymer material Substances 0.000 claims description 7
- 238000000059 patterning Methods 0.000 claims description 6
- 230000000737 periodic effect Effects 0.000 claims description 4
- 229920000592 inorganic polymer Polymers 0.000 claims description 3
- 229920000620 organic polymer Polymers 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 17
- 239000012212 insulator Substances 0.000 description 41
- 239000004020 conductor Substances 0.000 description 26
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 238000005229 chemical vapour deposition Methods 0.000 description 15
- 238000000151 deposition Methods 0.000 description 15
- 230000000903 blocking effect Effects 0.000 description 12
- 229910044991 metal oxide Inorganic materials 0.000 description 12
- 150000004706 metal oxides Chemical class 0.000 description 12
- 125000006850 spacer group Chemical group 0.000 description 9
- 229910052721 tungsten Inorganic materials 0.000 description 9
- 238000000231 atomic layer deposition Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000010937 tungsten Substances 0.000 description 8
- 230000005641 tunneling Effects 0.000 description 8
- 239000002019 doping agent Substances 0.000 description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 7
- 230000008021 deposition Effects 0.000 description 6
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 6
- 229920005591 polysilicon Polymers 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 238000002955 isolation Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000012777 electrically insulating material Substances 0.000 description 4
- 230000002093 peripheral effect Effects 0.000 description 4
- 229910021332 silicide Inorganic materials 0.000 description 4
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 4
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000003491 array Methods 0.000 description 2
- 238000004380 ashing Methods 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 230000005669 field effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910000449 hafnium oxide Inorganic materials 0.000 description 2
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000011232 storage material Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 230000005689 Fowler Nordheim tunneling Effects 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000006117 anti-reflective coating Substances 0.000 description 1
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000011370 conductive nanoparticle Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009429 electrical wiring Methods 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000000407 epitaxy Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000001995 intermetallic alloy Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910021344 molybdenum silicide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
- 229910021334 nickel silicide Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- WQJQOUPTWCFRMM-UHFFFAOYSA-N tungsten disilicide Chemical compound [Si]#[W]#[Si] WQJQOUPTWCFRMM-UHFFFAOYSA-N 0.000 description 1
- -1 tungsten nitride Chemical class 0.000 description 1
- 229910021342 tungsten silicide Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Images
Classifications
-
- H01L27/11582—
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/20—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels
- H10B43/23—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
- H10B43/27—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02164—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon oxide, e.g. SiO2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/0217—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon nitride not containing oxygen, e.g. SixNy or SixByNz
-
- H01L21/28273—
-
- H01L21/28282—
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31105—Etching inorganic layers
- H01L21/31111—Etching inorganic layers by chemical means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31144—Etching the insulating layers by chemical or physical means using masks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76897—Formation of self-aligned vias or contact plugs, i.e. involving a lithographically uncritical step
-
- H01L27/11524—
-
- H01L27/11556—
-
- H01L27/1157—
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/20—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels
- H10B41/23—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
- H10B41/27—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/50—EEPROM devices comprising charge-trapping gate insulators characterised by the boundary region between the core and peripheral circuit regions
Definitions
- the present disclosure relates generally to the field of metal interconnect structures and specifically to metal interconnect structures including multiple electrically shorted conductive layers for vertical semiconductor devices and methods of making thereof.
- Multilevel metal interconnect structures are routinely employed to provide electrical wiring for a high density circuitry, such as semiconductor devices on a substrate. Continuous scaling of semiconductor devices leads to a higher wiring density as well as an increase in the number of wiring levels.
- a 3D NAND stacked memory device may include at least as many number of wiring levels as the total number of control gate electrodes employed for the 3D NAND stacked memory device. Each of the conductive layers in the wiring levels needs to be provided with an electrical contact.
- a method of fabricating a multilevel structure is provided.
- a stack comprising an alternating plurality of first material layers and second material layers is formed over a substrate.
- a hard mask layer is formed over the stack, and is patterned into multiple portions that are laterally spaced apart.
- a trimming material layer is formed and is patterned over the patterned hard mask layer. At least one set of process steps is performed.
- Each set of process steps includes at least a first process step of etching at least one physically exposed portion of the first material layers in a first etch process employing a combination of the patterned trimming material layer and the patterned hard mask layer as an etch mask, a second process step of trimming the trimming material layer after the first etch process, and a third process step of etching at least one physically exposed portion of the second material layers and a physically exposed portion of the patterned hard mask layer in a second etch process employing the trimming material layer as an etch mask.
- FIG. 1 is a vertical cross-sectional view of an exemplary structure after formation of a stack of an alternating plurality of material layers and memory holes through the stack according to a first embodiment of the present disclosure.
- FIG. 2 is a vertical cross-sectional view of the exemplary structure after formation of memory stack structures and a planarization stop layer according to an embodiment of the present disclosure.
- FIG. 3 is a vertical cross-sectional view of the exemplary structure after formation of an optional dielectric material portion according to an embodiment of the present disclosure.
- FIG. 4 is a vertical cross-sectional view of the exemplary structure after formation of a hard mask layer according to an embodiment of the present disclosure.
- FIG. 5 is a vertical cross-sectional view of the exemplary structure after patterning the hard mask layer according to an embodiment of the present disclosure.
- FIG. 6 is a vertical cross-sectional view of the exemplary structure after formation of a trimming material layer according to an embodiment of the present disclosure.
- FIG. 7 is a vertical cross-sectional view of the exemplary structure after performing a first process step of a first set of process steps according to an embodiment of the present disclosure.
- FIG. 8 is a vertical cross-sectional view of the exemplary structure after performing a second process step of the first set of process steps according to an embodiment of the present disclosure.
- FIG. 9 is a vertical cross-sectional view of the exemplary structure after performing a third process step of the first set of process steps according to an embodiment of the present disclosure.
- FIG. 10 is a vertical cross-sectional view of the exemplary structure after performing a fourth process step of the first set of process steps according to an embodiment of the present disclosure.
- FIG. 11 is a vertical cross-sectional view of the exemplary structure after performing a first process step of a second set of process steps according to an embodiment of the present disclosure.
- FIG. 12 is a vertical cross-sectional view of the exemplary structure after performing a second process step of the second set of process steps according to an embodiment of the present disclosure.
- FIG. 13 is a vertical cross-sectional view of the exemplary structure after performing a third process step of the second set of process steps according to an embodiment of the present disclosure.
- FIG. 14 is a vertical cross-sectional view of the exemplary structure after completion of four sets of process steps according to an embodiment of the present disclosure.
- FIG. 15 is a vertical cross-sectional view of the exemplary structure after completion of a first process step of the (n ⁇ 1)-th set of process steps according to an embodiment of the present disclosure, in which n is the total number of sacrificial material layers to be exposed after formation of a set of stepped surfaces.
- FIG. 16 is a vertical cross-sectional view of the exemplary structure after completion of a third process step of the (n ⁇ 1)-th set of process steps according to an embodiment of the present disclosure.
- FIG. 17 is a vertical cross-sectional view of the exemplary structure after completion of a fourth process step of the (n ⁇ 1)t-th set of process steps and an anisotropic etch process that removes physically exposed portions of the first material layers according to an embodiment of the present disclosure.
- FIG. 18 is a vertical cross-sectional view of the exemplary structure after formation of retro-stepped dielectric material portion according to an embodiment of the present disclosure.
- FIG. 19 is a vertical cross-sectional view of the exemplary structure after replacement of the hard mask layer with a dielectric cap layer according to an embodiment of the present disclosure.
- FIG. 20 is a vertical cross-sectional view of the exemplary structure after formation of a backside contact trench and backside recesses according to an embodiment of the present disclosure.
- FIG. 21 is a vertical cross-sectional view of the exemplary structure after formation of electrically conductive layers according to an embodiment of the present disclosure.
- FIG. 22 is a vertical cross-sectional view of the exemplary structure after formation of a backside contact via structure according to an embodiment of the present disclosure.
- FIG. 23 is a vertical cross-sectional view of the exemplary structure after formation of control gate contact via structures according to an embodiment of the present disclosure.
- the present disclosure is directed to metal interconnect structures including multiple electrically shorted conductive layers for vertical semiconductor devices and methods of making the same, the various aspects of which are described below.
- the embodiments of the disclosure can be employed to form various structures including a multilevel metal interconnect structure, a non-limiting example of which includes semiconductor devices such as three-dimensional monolithic memory array devices comprising a plurality of NAND memory strings.
- the drawings are not drawn to scale. Multiple instances of an element may be duplicated where a single instance of the element is illustrated, unless absence of duplication of elements is expressly described or clearly indicated otherwise. Ordinals such as “first,” “second,” and “third” are employed merely to identify similar elements, and different ordinals may be employed across the specification and the claims of the instant disclosure.
- a first element located “on” a second element can be located on the exterior side of a surface of the second element or on the interior side of the second element.
- a first element is located “directly on” a second element if there exist a physical contact between a surface of the first element and a surface of the second element.
- a monolithic three dimensional memory array is one in which multiple memory levels are formed above a single substrate, such as a semiconductor wafer, with no intervening substrates.
- the term “monolithic” means that layers of each level of the array are directly deposited on the layers of each underlying level of the array.
- two dimensional arrays may be formed separately and then packaged together to form a non-monolithic memory device.
- non-monolithic stacked memories have been constructed by forming memory levels on separate substrates and vertically stacking the memory levels, as described in U.S. Pat. No.
- the substrates may be thinned or removed from the memory levels before bonding, but as the memory levels are initially formed over separate substrates, such memories are not true monolithic three dimensional memory arrays.
- the various three dimensional memory devices of the present disclosure include a monolithic three-dimensional NAND string memory device, and can be fabricated employing the various embodiments described herein.
- the exemplary structure includes a substrate, which can be a semiconductor substrate.
- the substrate can include a substrate semiconductor layer 9 .
- the substrate semiconductor layer 9 is a semiconductor material layer, and can include at least one elemental semiconductor material, at least one III-V compound semiconductor material, at least one II-VI compound semiconductor material, at least one organic semiconductor material, or other semiconductor materials known in the art.
- the substrate can have a major surface 7 , which can be, for example, a topmost surface of the substrate semiconductor layer 9 .
- the major surface 7 can be a semiconductor surface. In one embodiment, the major surface 7 can be a single crystalline semiconductor surface.
- a “semiconductor material” refers to a material having electrical conductivity in the range from 1.0 ⁇ 10 ⁇ 6 S/cm to 1.0 ⁇ 10 5 S/cm, and is capable of producing a doped material having electrical resistivity in a range from 1.0 S/cm to 1.0 ⁇ 10 5 S/cm upon suitable doping with an electrical dopant.
- an “electrical dopant” refers to a p-type dopant that adds a hole to a balance band within a band structure, or an n-type dopant that adds an electron to a conduction band within a band structure.
- a “conductive material” refers to a material having electrical conductivity greater than 1.0 ⁇ 10 5 S/cm.
- an “insulator material” or a “dielectric material” refers to a material having electrical conductivity less than 1.0 ⁇ 10 ⁇ 6 S/cm. All measurements for electrical conductivities are made at the standard condition.
- at least one doped well can be formed within the substrate semiconductor layer 9 .
- At least one semiconductor device for a peripheral circuitry can be formed on a portion of the substrate semiconductor layer 9 .
- the region in which the at least one semiconductor device for the peripheral circuitry is herein referred to as a peripheral device region 200 .
- the at least one semiconductor device can include, for example, field effect transistors.
- at least one shallow trench isolation structure 120 can be formed by etching portions of the substrate semiconductor layer 9 and depositing a dielectric material therein.
- a gate dielectric layer, at least one gate conductor layer, and a gate cap dielectric layer can be formed over the substrate semiconductor layer 9 , and can be subsequently patterned to form at least one gate structure ( 150 , 152 , 154 , 158 ), each of which can include a gate dielectric 150 , at least one gate electrode ( 152 , 154 ), and a gate cap dielectric.
- a gate electrode ( 152 , 154 ) may include a stack of a first gate electrode portion 152 and a second gate electrode portion 154 .
- At least one gate spacer 156 can be formed around the at least one gate structure ( 150 , 152 , 154 , 158 ) by depositing and anisotropically etching a conformal dielectric layer.
- Active regions 130 can be formed in upper portions of the substrate semiconductor layer 9 , for example, by introducing electrical dopants employing the at least one gate structure ( 150 , 152 , 154 , 158 ) as masking structures. Additional masks may be employed as needed.
- the active region 130 can include source regions and drain regions of field effect transistors.
- a first dielectric liner 161 and a second dielectric liner 162 can be optionally formed.
- Each of the first and second dielectric liners ( 161 , 162 ) can comprise a silicon oxide layer, a silicon nitride layer, and/or a dielectric metal oxide layer.
- the first dielectric liner 161 can be a silicon oxide layer
- the second dielectric liner 162 can be a silicon nitride layer.
- the least one semiconductor device for the peripheral circuitry can contain a driver circuit for memory devices to be subsequently formed, which can include at least one NAND device.
- a dielectric material such as silicon oxide can be deposited over the at least one semiconductor device, and can be subsequently planarized to form a planarization dielectric layer 170 .
- the planarized top surface of the planarization dielectric layer 170 can be coplanar with a top surface of the dielectric liners ( 161 , 162 ). Subsequently, the planarization dielectric layer 170 and the dielectric liners ( 161 , 162 ) can be removed from an area to physically expose a top surface of the substrate semiconductor layer 9 .
- a semiconductor material layer 10 can be formed on the top surface of the substrate semiconductor layer 9 by deposition of a single crystalline semiconductor material, for example, by selective epitaxy.
- the deposited semiconductor material can be the same as, or can be different from, the semiconductor material of the substrate semiconductor layer 9 .
- the deposited semiconductor material can be any material that can be employed for the semiconductor substrate layer 9 as described above.
- the single crystalline semiconductor material of the semiconductor material layer 10 can be in epitaxial alignment with the single crystalline structure of the substrate semiconductor layer 9 .
- Portions of the deposited semiconductor material located above the top surface of the planarization dielectric layer 170 can be removed, for example, by chemical mechanical planarization (CMP).
- CMP chemical mechanical planarization
- the semiconductor material layer 10 can have a top surface that is coplanar with the top surface of the planarization dielectric layer 170 .
- a dielectric pad layer 12 can be formed above the semiconductor material layer 10 and the planarization dielectric layer 170 .
- the dielectric pad layer 12 can be, for example, silicon oxide layer.
- the thickness of the dielectric pad layer 12 can be in a range from 3 nm to 30 nm, although lesser and greater thicknesses can also be employed.
- At least one optional shallow trench can be formed through the dielectric pad layer 12 and an upper portion of the semiconductor material layer 10 .
- the pattern of the at least one shallow trench can be selected such that lower select gate electrodes can be subsequently formed therein.
- a lower select gate device level may be fabricated as described in U.S. patent application Ser. No. 14/133,979, filed on Dec. 19, 2013, U.S. patent application Ser. No. 14/225,116, filed on Mar. 25, 2014, and/or U.S. patent application Ser. No. 14/225,176, filed on Mar. 25, 2014, all of which are incorporated herein by reference.
- a lower select gate structure 20 can be formed in each of the at least one shallow trench, for example, by forming a gate dielectric layer and at least one conductive material layer, and removing portions of the gate dielectric layer and the at least one conductive material layer from above the top surface of the dielectric pad layer 12 , for example, by chemical mechanical planarization.
- Each lower select gate structure 20 can include a gate dielectric 22 and a gate electrode ( 24 , 26 ).
- each gate electrode ( 24 , 26 ) can include a metallic liner 24 and a conductive material portion 26 .
- the metallic liner 24 can include, for example, TiN, TaN, WN, or a combination thereof.
- the conductive material portion 26 can include, for example, W, Al, Cu, or combinations thereof.
- At least one optional shallow trench isolation structure (not shown) and/or at least one deep trench isolation structure (not shown) may be employed to provide electrical isolation among various semiconductor devices that are present, or are to be subsequently formed, on the substrate.
- a dielectric cap layer 31 can be optionally formed.
- the dielectric cap layer 31 includes a dielectric material, and can be formed directly on top surfaces of the gate electrodes ( 24 , 26 ).
- Exemplary materials that can be employed for the dielectric cap layer 31 include, but are not limited to, silicon oxide, a dielectric metal oxide, and silicon nitride (in case the material of second material layers to be subsequently formed is not silicon nitride).
- the dielectric cap layer 31 provides electrical isolation for the gate electrodes ( 24 , 26 ).
- a stack of an alternating plurality of first material layers (which can be insulating layers 32 ) and second material layers (which can be sacrificial material layer ( 42 L, 42 C, 42 U)) is formed over the top surface of the substrate, which can be, for example, on the top surface of the dielectric cap layer 31 .
- an alternating plurality of first elements and second elements refers to a structure in which instances of the first elements and instances of the second elements alternate. Each instance of the first elements that is not an end element of the alternating plurality is adjoined by two instances of the second elements on both sides, and each instance of the second elements that is not an end element of the alternating plurality is adjoined by two instances of the first elements on both ends.
- the first elements may have the same thickness thereamongst, or may have different thicknesses.
- the second elements may have the same thickness thereamongst, or may have different thicknesses.
- the alternating plurality of first material layers and second material layers may begin with an instance of the first material layers or with an instance of the second material layers, and may end with an instance of the first material layers or with an instance of the second material layers.
- an instance of the first elements and an instance of the second elements may form a unit that is repeated with periodicity within the alternating plurality.
- Each first material layer includes a first material
- each second material layer includes a second material that is different from the first material.
- each first material layer can be an insulator layer 32
- each second material layer can be a sacrificial material layer 42 .
- the stack can include an alternating plurality of insulator layers 32 and sacrificial material layers 42 .
- the stack of the alternating plurality is herein referred to as an alternating stack ( 32 , 42 ).
- the alternating stack ( 32 , 42 ) can include insulator layers 32 composed of the first material, and sacrificial material layers 42 composed of a second material different from that of insulator layers 32 .
- the first material of the insulator layers 32 can be at least one electrically insulating material.
- each insulator layer 32 can be an electrically insulating material layer.
- Electrically insulating materials that can be employed for the insulator layers 32 include, but are not limited to silicon oxide (including doped or undoped silicate glass), silicon nitride, silicon oxynitride, organosilicate glass (OSG), spin-on dielectric materials, dielectric metal oxides that are commonly known as high dielectric constant (high-k) dielectric oxides (e.g., aluminum oxide, hafnium oxide, etc.) and silicates thereof, dielectric metal oxynitrides and silicates thereof, and organic insulating materials.
- the first material of the insulator layers 32 can be silicon oxide.
- the second material of the sacrificial material layers 42 is a sacrificial material that can be removed selective to the first material of the insulator layers 32 .
- a removal of a first material is “selective to” a second material if the removal process removes the first material at a rate that is at least twice the rate of removal of the second material.
- the ratio of the rate of removal of the first material to the rate of removal of the second material is herein referred to as a “selectivity” of the removal process for the first material with respect to the second material.
- the sacrificial material layers 42 may comprise an electrically insulating material, a semiconductor material, or a conductive material.
- the second material of the sacrificial material layers 42 can be subsequently replaced with electrically conductive electrodes which can function, for example, as control gate electrodes of a vertical NAND device.
- Non-limiting examples of the second material include silicon nitride, an amorphous semiconductor material (such as amorphous silicon), and a polycrystalline semiconductor material (such as polysilicon).
- the sacrificial material layers 42 can be material layers that comprise silicon nitride or a semiconductor material including at least one of silicon and germanium.
- the insulator layers 32 can include silicon oxide, and sacrificial material layers can include silicon nitride sacrificial material layers.
- the first material of the insulator layers 32 can be deposited, for example, by chemical vapor deposition (CVD).
- CVD chemical vapor deposition
- TEOS tetraethyl orthosilicate
- the second material of the sacrificial material layers 42 can be formed, for example, CVD or atomic layer deposition (ALD).
- the sacrificial material layers 42 can be suitably patterned so that conductive material portions to be subsequently formed by replacement of the sacrificial material layers 42 can function as electrically conductive electrodes, such as the control gate electrodes of the monolithic three-dimensional NAND string memory devices to be subsequently formed.
- the sacrificial material layers 42 may comprise a portion having a strip shape extending substantially parallel to the major surface 7 of the substrate.
- the thicknesses of the insulator layers 32 and the sacrificial material layers 42 can be in a range from 20 nm to 50 nm, although lesser and greater thicknesses can be employed for each insulator layer 32 and for each sacrificial material layer 42 .
- the number of repetitions of the pairs of an insulator layer 32 and a sacrificial material layer (e.g., a control gate electrode or a sacrificial material layer) 42 can be in a range from 2 to 1,024, and typically from 8 to 256, although a greater number of repetitions can also be employed.
- the top and bottom gate electrodes in the stack may function as the select gate electrodes.
- each sacrificial material layer 42 in the alternating stack ( 32 , 42 ) can have a uniform thickness that is substantially invariant within each respective sacrificial material layer 42 .
- a lithographic material stack including at least a photoresist layer can be formed over the alternating stack ( 32 , 42 ), and can be lithographically patterned to form openings therein.
- the pattern in the lithographic material stack can be transferred through the entirety of the alternating stack ( 32 , 42 ) by at least one anisotropic etch that employs the patterned lithographic material stack as an etch mask. Portions of the alternating stack ( 32 , 42 ) underlying the openings in the patterned lithographic material stack are etched to form memory openings 49 .
- the transfer of the pattern in the patterned lithographic material stack through the alternating stack ( 32 , 42 ) forms the memory openings 49 that extend through the alternating stack ( 32 , 42 ).
- the chemistry of the anisotropic etch process employed to etch through the materials of the alternating stack ( 32 , 42 ) can alternate to optimize etching of the first and second materials in the alternating stack ( 32 , 42 ).
- the anisotropic etch can be, for example, a series of reactive ion etches.
- the dielectric cap layer 31 may be used as an etch stop layer between the alternating stack ( 32 , 42 ) and the substrate.
- the sidewalls of the memory openings 49 can be substantially vertical, or can be tapered.
- the patterned lithographic material stack can be subsequently removed, for example, by ashing.
- the region in which the memory openings 49 are formed is herein referred to as a device region 100 .
- a contact region 300 can be provided adjacent to the device region 100 .
- a set of stepped surfaces and control gate contact via structures (not shown) can be subsequently formed in the contact region 300 .
- the memory openings 49 are formed through the dielectric cap layer 31 and the dielectric pad layer 12 so that the memory openings 49 extend from the top surface of the alternating stack ( 32 , 42 ) to the top surface of the semiconductor material layer 10 within the substrate between the lower select gate electrodes ( 24 , 26 ).
- an overetch into the semiconductor material layer 10 may be optionally performed after the top surface of the semiconductor material layer 10 is physically exposed at a bottom of each memory opening 49 .
- the overetch may be performed prior to, or after, removal of the lithographic material stack.
- the recessed surfaces of the semiconductor material layer 10 may be vertically offset from the undressed top surfaces of the semiconductor material layer 10 by a recess depth.
- the recess depth can be, for example, in a range from 1 nm to 50 nm, although lesser and greater recess depths can also be employed.
- the overetch is optional, and may be omitted. If the overetch is not performed, the bottom surface of each memory opening 49 can be coplanar with the topmost surface of the semiconductor material layer 10 .
- Each of the memory openings 49 can include a sidewall (or a plurality of sidewalls) that extends substantially perpendicular to the topmost surface of the substrate.
- the region in which the array of memory openings 49 is formed is herein referred to as a device region.
- the substrate semiconductor layer 9 and the semiconductor material layer 10 collectively constitutes a substrate ( 9 , 10 ), which can be a semiconductor substrate. Alternatively, the semiconductor material layer 10 may be omitted, and the memory openings 49 can be extend to a top surface of the semiconductor material layer 10 .
- a memory stack structure 55 can be formed within each memory opening through the alternating stack ( 32 , 42 ).
- the memory stack structures 55 can be formed, for example, by depositing a memory film layer in the memory openings and over the alternating stack ( 32 , 42 ), and by anisotropically etching the memory film layer.
- the memory film layer can be a stack of contiguous material layers that overlie the entirety of the alternating stack ( 31 , 42 ,).
- the memory film layer contacts all sidewall surface(s) and all bottom surface(s) of the memory openings.
- the memory film layer is a contiguous film stack that provides the functionality of charge storage in the absence of an external electrical bias voltage, while enabling charge transfer in the presence of a suitable external electrical bias voltage.
- the memory film layer can be a stack, in the order of formation, of a blocking dielectric layer, a charge storage layer, and a tunnel dielectric layer.
- a plurality of floating gates or a charge storage dielectric can be located between the tunneling dielectric layer and the blocking dielectric layer.
- the blocking dielectric layer contacts the sidewalls of the memory openings. Specifically, the blocking dielectric layer can contact the sidewalls of the sacrificial layers 42 .
- the blocking dielectric layer may include one or more dielectric material layers that can function as the dielectric material(s) of a control gate dielectric between the sacrificial layers 42 and charge storage regions to be subsequently formed out of the charge storage layer.
- the blocking dielectric layer can include silicon oxide, a dielectric metal oxide, a dielectric metal oxynitride, or a combination thereof. In one embodiment, the blocking dielectric layer can include a stack of at least one silicon oxide layer and at least one dielectric metal oxide layer.
- the blocking dielectric layer can be formed by a conformal deposition process such as chemical vapor deposition (CVD) and/or atomic layer deposition (ALD), and/or by deposition of a conformal material layer (such as an amorphous silicon layer) and subsequent conversion of the conformal material layer into a dielectric material layer (such as a silicon oxide layer).
- the thickness of the blocking dielectric layer can be in a range from 6 nm to 24 nm, although lesser and greater thicknesses can also be employed.
- the blocking dielectric layer may be omitted from the memory opening, and instead be formed through the backside contact trench in recesses formed by removal of the sacrificial layers 42 prior to forming the metal control gate electrodes through a backside contact trench.
- the charge storage layer includes a dielectric charge trapping material, which can be, for example, silicon nitride, or a conductive material such as doped polysilicon or a metallic material. In one embodiment, the charge storage layer includes silicon nitride.
- the charge storage layer can be formed as a single charge storage layer of homogeneous composition, or can include a stack of multiple charge storage material layers.
- the multiple charge storage material layers can comprise a plurality of spaced-apart floating gate material layers that contain conductive materials (e.g., metal such as tungsten, molybdenum, tantalum, titanium, platinum, ruthenium, and alloys thereof, or a metal silicide such as tungsten silicide, molybdenum silicide, tantalum silicide, titanium silicide, nickel silicide, cobalt silicide, or a combination thereof) and/or semiconductor materials (e.g., polycrystalline or amorphous semiconductor material including at least one elemental semiconductor element or at least one compound semiconductor material).
- conductive materials e.g., metal such as tungsten, molybdenum, tantalum, titanium, platinum, ruthenium, and alloys thereof, or a metal silicide such as tungsten silicide, molybdenum silicide, tantalum silicide, titanium silicide, nickel silicide, cobalt silicide, or a combination thereof
- the charge storage layer may comprise an insulating charge trapping material, such as one or more silicon nitride segments.
- the charge storage layer may comprise conductive nanoparticles such as metal nanoparticles, which can be, for example, ruthenium nanoparticles.
- the charge storage layer can be formed, for example, by chemical vapor deposition (CVD), atomic layer deposition (ALD), physical vapor deposition (PVD), or any suitable deposition technique for the selected material(s) for the charge storage layer.
- the thickness of the charge storage layer can be in a range from 2 nm to 20 nm, although lesser and greater thicknesses can also be employed.
- the tunnel dielectric layer includes a dielectric material through which charge tunneling can be performed under suitable electrical bias conditions.
- the charge tunneling may be performed through hot-carrier injection or by Fowler-Nordheim tunneling induced charge transfer depending on the mode of operation of the monolithic three-dimensional NAND string memory device to be formed.
- the tunneling dielectric layer can include silicon oxide, silicon nitride, silicon oxynitride, dielectric metal oxides (such as aluminum oxide and hafnium oxide), dielectric metal oxynitride, dielectric metal silicates, alloys thereof, and/or combinations thereof.
- the tunneling dielectric layer can include a stack of a first silicon oxide layer, a silicon oxynitride layer, and a second silicon oxide layer, which is commonly known as an ONO stack.
- the tunneling dielectric layer can include a silicon oxide layer that is substantially free of carbon or a silicon oxynitride layer that is substantially free of carbon.
- the thickness of the tunnel dielectric layer can be in a range from 2 nm to 20 nm, although lesser and greater thicknesses can also be employed.
- a permanent channel material layer such as a polysilicon layer
- a sacrificial layer such as a dielectric material layer
- the memory film layer (and any additional layer such as a permanent channel material layer or a sacrificial layer) can be anisotropically etched so that horizontal portions of the memory film layer (and any additional layer) are removed from above the top surface of the alternating stack ( 32 , 42 ) and at the bottom of each memory opening.
- Each remaining vertical portion of the memory film layer that remains within a memory opening after the anisotropic etch constitutes a memory film 50 .
- Each memory film 50 can be homeomorphic to a torus.
- an element is homeomorphic to a geometrical shape if the shape of the element can be mapped to the geometrical shape by continuous deformation without creation or destruction of any hole. If an electrode underlies the memory openings, a top surface of the electrode can be physically exposed within the cavity defined by the inner sidewalls of an overlying memory film 50 .
- a semiconductor channel ( 601 , 602 ) can be formed by depositing at least one semiconductor material on the inner sidewalls of the memory films 50 and on semiconductor surfaces of the semiconductor material layer 10 at the bottom of the memory openings.
- a first semiconductor channel layer can be deposited directly on the surfaces of the memory films 50 by a conformal deposition method such as chemical vapor deposition (CVD).
- the first semiconductor channel layer and the memory films can be anisotropically etched to form an opening at a bottom portion of each memory opening.
- a top surface of the substrate semiconductor layer 10 is physically exposed at the bottom of each memory opening.
- Each remaining portion of the first semiconductor channel layer within a memory opening constitutes a first semiconductor channel portion 601 .
- a second semiconductor channel layer can be deposited on the sidewalls of the first semiconductor channel portions 601 , physically exposed surfaces of the substrate semiconductor layer 10 within the memory openings, and over the alternating stack ( 32 , 42 ).
- the semiconductor material of the second semiconductor channel layer can include a doped polycrystalline semiconductor material (such as doped polysilicon), or can include a doped amorphous semiconductor material (such as amorphous silicon) that can be subsequently converted into a doped polycrystalline semiconductor material after a suitable anneal at an elevated temperature.
- a dielectric core 62 can be formed within a cavity inside each semiconductor channel 60 , for example, by deposition of a dielectric material such as silicon oxide, and subsequent planarization of the dielectric material.
- the planarization of the dielectric material removes the portion of the deposited dielectric material from above the top surface of the horizontal plane including the top surface of the topmost layer of the alternating stack ( 32 , 42 ), which can be, for example, the top surface of the topmost insulator layer 32 .
- the planarization of the dielectric material can be performed, for example, by chemical mechanical planarization.
- Each remaining portion of the dielectric material inside a memory opening constitutes a dielectric core 62 .
- the dielectric core 62 is an optional component, and a combination of a memory film 50 and a semiconductor channel 60 may completely fill a memory opening.
- the horizontal portion of the second semiconductor channel layer above the top surface of the topmost layer of the alternating stack ( 32 , 42 ) can be removed, for example, by a recess etch. Each remaining portion of the second semiconductor channel layer constitutes a second semiconductor channel 602 .
- Each adjoined pair of a first semiconductor channel 601 and a second semiconductor channel vertically extend through the alternating stack ( 32 , 42 ), and collectively constitutes a portion of a semiconductor channel ( 601 , 602 ) for a memory stack structure 55 .
- a set of a memory film 50 and a semiconductor channel ( 601 , 602 ) within a same memory opening constitutes a memory stack structure 55 .
- Drain regions 63 can be formed by recessing a top portion of each dielectric core and depositing a doped semiconductor material.
- the doped semiconductor material can be, for example, doped polysilicon. Excess portions of the deposited semiconductor material can be removed from above the top surface of the alternating stack ( 32 , 42 ), for example, by chemical mechanical planarization (CMP) or a recess etch.
- CMP chemical mechanical planarization
- a planarization stop layer 71 can be formed over the alternating stack ( 32 , 42 ) and the array of memory stack structures 55 .
- the planarization stop layer 71 can include a material that can be employed as a stopping layer during a planarization process such as chemical mechanical planarization (CMP).
- CMP chemical mechanical planarization
- the planarization stop layer 71 can include silicon nitride, a dielectric metal oxide, a nitrogen-doped organosilicate glass, and/or a metallic nitride material such as TiN or WN.
- the planarization stop layer 71 can include a dielectric material that can be removed selective to the first material of the insulator layers 32 .
- the planarization stop layer 71 can include a dielectric material such as silicon nitride or a dielectric metal oxide.
- the thickness of the planarization stop layer 71 can be in a range from 5 nm to 100 nm, although lesser and greater thicknesses can also be employed.
- a portion of the alternating stack ( 32 , 42 ) can be removed, for example, by applying and patterning a photoresist layer with an opening and by transferring the pattern of the opening through the alternating stack ( 32 , 42 ) employing an etch such as an anisotropic etch.
- An optional trench extending through the entire thickness of the alternating stack ( 32 , 42 ) can be formed.
- the trench can be filled with an optional dielectric material such as silicon oxide. Excess portions of the dielectric material can be removed from above the top surface of the planarization stop layer 71 by a planarization process such as chemical mechanical planarization and/or a recess etch.
- the top surfaces of the planarization stop layer 71 can be employed as a stopping surface during the planarization.
- the planarization stop layer 71 can be removed at least partially during the planarization process. Any remaining portion of the planarization stop layer 71 can be removed in a subsequent etch process selective to the dielectric material of the topmost layer of the alternating stack ( 32 , 42 ), e.g., selective to the dielectric material of the topmost insulator layer 32 .
- the top surface of the dielectric material portion 64 may be vertically recessed so that the top surface of the dielectric material portion 64 is substantially coplanar with the top surface of the topmost layer of the alternating stack ( 32 , 42 ).
- a hard mask layer 73 is formed over the alternating stack ( 32 , 42 ).
- the hard mask layer 73 includes a material that is different from the material of the first material layers (e.g., the insulator layers 32 ).
- the material of the hard mask layer 73 can be the same as, or can be different from, the material of the second material layers (e.g., the sacrificial material layers 42 ).
- the hard mask layer 73 comprises the same material as the second material layers 42 .
- the hard mask layer 73 and the second material layers 43 can comprise silicon nitride.
- the first material layers e.g., the insulator layers 32
- the topmost layer of the alternating stack ( 32 , 42 ) can be a topmost first material layer (e.g., a topmost insulator layer 32 ), and the hard mask layer 73 can be formed directly on the topmost first material layer.
- the hard mask layer 73 can be deposited on the planar topmost surface of the alternating stack ( 32 , 42 ) by a deposition method such as chemical vapor deposition (CVD).
- the thickness of the hard mask layer 73 is selected such that the entire thickness of the hard mask layer 73 can be etched collaterally during a subsequently anisotropic etch of any one of the second material layers (e.g., the sacrificial material layers 42 ).
- the hard mask layer 73 comprises the same material as the second material layers 42 , and the hard mask layer 73 has a thickness that is not greater than (i.e., the same as or less than) the maximum thickness of the second material layers (e.g., the sacrificial material layers 42 ).
- the second material layers can have the same thickness as, or a greater thickness than, the thickness of the hard mask layer 73 .
- a photoresist layer 57 can be applied over the hard mask layer 73 , and can be lithographically patterned to form a plurality of patterned portions that are spaced apart.
- the pattern in the photoresist layer 57 is transferred through the hard mask layer 73 to pattern the hard mask layer 73 into multiple portions that are laterally spaced apart.
- the patterned multiple portions of the hard mask layer 73 comprise strips having parallel edges. The parallel edges of the strips can extend along a same horizontal direction, which can be, for example, the direction perpendicular to the vertical cross-sectional plane of FIG. 5 .
- the photoresist layer 57 can be subsequently removed, for example, by ashing.
- the center-to-center distance dcc between each neighboring pair of patterned multiple portions of the hard mask layer 73 can be the same.
- the patterned multiple portions of the hard mask layer 73 can be a periodic one-dimensional array having a repetition of a unit pattern.
- the patterned multiple portions of the hard mask layer 73 can have a uniform pitch, which can be the same as the center-to-center distance dcc.
- a center-to-center distance between each neighboring pair of patterned multiple portions of the hard mask layer 73 can be the same, and the patterned multiple portions of the hard mask layer 73 can constitute a periodic one-dimensional array having a repetition of a unit pattern.
- neighboring pairs of patterned multiple portions of the hard mask layer 73 can have at least two different center-to-center distances, and the patterned multiple portions of the hard mask layer have at least two different widths.
- a plurality of steps to be subsequently formed can have at least two different step widths.
- the total number of laterally spaced patterned portions of the hard mask layer 73 located in a region extending from a substantially vertical interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 to the device region 100 can be the same as the total number of sacrificial material layers 42 within the alternating stack ( 32 , 42 ) less one. If the total number of sacrificial material layers 42 in the alternating stack ( 32 , 42 ) is n, the total number of laterally spaced patterned portions of the hard mask layer 73 located in the region extending from a substantially vertical interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 to the device region 100 can be n ⁇ 1.
- a trimming material layer 67 is formed and patterned over the patterned hard mask layer 73 .
- the trimming material layer 67 comprises a material that can be continually trimmed, i.e., a material that can be gradually removed over a time duration from outside to inside at a controlled removal rate.
- the trimming material layer 67 can be selected from a photoresist material, an organic polymer material, and an inorganic polymer material.
- Organic polymer materials that can be employed for the trimming material layer 67 can be an organic material made of cross-linked carbon-containing monomers, and can be carbon-based self-planarizing material known in the art.
- Inorganic polymer material that can be employed for the trimming material layer 67 include silicon-based polymer materials such as silicon-based antireflective coating materials as known in the art. A portion of the trimming material layer 67 remains after repeated trimming that shifts an outer sidewall of the trimming material layer 67 to a periphery of the contact region 300 adjoining the device region 100 .
- the trimming material layer 67 can be applied over the patterned hard mask layer 73 as a blanket material layer, i.e., as an unpatterned material layer.
- the trimming material layer 67 can be applied by a self-planarizing deposition process such as spin coating.
- the trimming material layer 67 can be directly patterned by photolithographic exposure and development if the trimming material layer 67 includes a photosensitive material, or can be patterned by application of a photoresist layer (not shown) thereupon, lithographic patterning of the photoresist layer, and transfer of the pattern of the photoresist layer through the trimming material layer 67 selective to the patterned hard mask layer 73 .
- the trimming material layer 67 can have a sidewall that adjoins a top surface of a remaining portion among the multiple portions of the hard mask layer 73 .
- a sidewall 67 A of the trimming material layer 67 can overlie a top surface of a portion 73 A of the hard mask layer 73 that overlies the alternating stack ( 32 , 42 ).
- the portion 73 A of the hard mask layer 73 that underlies the sidewall 67 A of the trimming material layer 67 is most proximate to a vertical interface 164 between the dielectric material portion 64 and the alternating stack ( 32 , 42 ) among the plurality of laterally spaced portions of the hard mask layer 73 that overlie the alternating stack ( 32 , 42 ).
- a sidewall of the trimming material layer 67 can straddle a center region of the patterned portion 73 A of the hard mask layer 73 that overlies the alternating stack ( 32 , 42 ) and is most proximal to the interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 .
- the pitch of the multiple portions of the hard mask layer 73 can be about the sum of four times a trimming width variation of the trimming material layer 67 and a variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- the pitch of the multiple portions of the hard mask layer 73 can be greater than the sum of four times a trimming width variation of the trimming material layer 67 and a variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- a “trimming width variation” refers to inherent variation in the trimming distance for a given trimming process that trims a trimming material layer.
- a set of process steps is performed at least once to sequentially transfer features of the patterned hard mask layer 73 .
- the processing step that initiates the transfer each feature of the patterned hard mask layer 73 is sequentially offset from the initial processing steps by a number of processing steps, of which the total number is correlated to the lateral distance of the features of the patterned hard mask layer 73 from the location of the initial sidewall of the trimming material layer 67 .
- each proximal sidewall 73 p of the multiple portions of the patterned hard mask layer 73 that is proximal to the interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material layer 64 are transferred as steps in the alternating stack ( 32 , 42 ) in the subsequent sets of process steps that are performed in cycles.
- Features of each distal sidewall 73 d of the multiple portions of the patterned hard mask layer 73 that is distal from the interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material layer 64 are not transferred.
- the set of process steps can be performed multiple times. For example, a first set of process steps can be performed, the second set of process steps can be performed, and so on. Each set of process steps can have an identical sequence of process steps.
- the view of FIG. 7 illustrates the exemplary structure after performing a first process step of a first set of process steps.
- the first process step can be a step of etching at least one physically exposed portion of the first material layers (e.g., the insulator layers 32 ) in a first etch process employing a combination of the patterned trimming material layer 67 and the patterned hard mask layer 73 as an etch mask.
- the trimming material layer 67 can have a sidewall 67 A that adjoins a top surface of a portion 73 A among the multiple portions of the hard mask layer 73 during the first process step of the first set of process steps.
- the first etch process can be an anisotropic etch process that etches the first material of the first material layers (e.g., the insulator layers 32 ) selective to the second material of the second material layers (e.g., the sacrificial material layers 42 ).
- the second material layers can be employed as etch stop layers for each first etch process.
- the topmost second material layer e.g., the topmost sacrificial material layer 42
- the trimming material layer 67 can have a sidewall 67 A that adjoins a top surface of a portion 73 A among the multiple portions of the hard mask layer 73 .
- a second process step of the first set of process steps can be performed.
- the second process step is a trimming step in which the trimming material layer 67 is trimmed selective to the materials of the first material layers (e.g., the insulator layers 32 ) and the second material layers (e.g., the sacrificial material layers 42 ).
- the trimming material layer 67 can be trimmed by an isotropic etch, which can be an isotropic dry etch or an isotropic wet etch.
- the trimming material layer 67 has a sidewall 67 B that is located between, and does not contact, a neighboring pair of portions ( 73 A, 73 B) of the hard mask layer 73 .
- the trimming distance for the second process step can be selected to be about one half of the pitch.
- the trimming distance is herein referred to as a first trimming distance TD 1 .
- the sidewall 67 B of the trimming material layer 67 can be shifted from above a first portion 73 A of the hard mask layer 73 that is most proximal to the interface between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 to a location between the first portion 73 A and a second portion 73 B of the hard mask layer 73 that is a neighboring portion of the first portion 73 A.
- the first portion 73 A can be the most proximate portion to the interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material portion 64
- the second portion 73 B can be a second most proximate portion to the interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 .
- the width of the patterned portion 73 A (which is herein referred to as a first portion 73 A) of the hard mask layer 73 on which an edge of the trimming material layer 67 is present at the end of the first process step can be at least twice the trimming width variation of the trimming material layer 67 (as manifested during the second process step).
- the spacing between the first portion 73 A and a neighboring portion 73 B of the hard mask layer 73 (which is herein referred to as a second portion 73 B) can be at least twice the trimming width variation of the trimming material layer 67 (to be manifested during a fourth processing step to be subsequently performed).
- the center-to-center distance between the first portion and the second portion of the hard mask layer 73 , or the pitch of the patterned portions of the hard mask layer 73 can be four times the trimming width variation of the trimming process plus the variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- the nominal value of the first trimming distance TD 1 can be equal to twice the trimming width variation (which is the inherent variation in the trimming distance in a trimming process that trims the trimming material layer 67 ) plus one half of the variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- the target value for the first trimming distance TD 1 can be modified from the nominal value by making an overlay measurement to determine the offset distance of a sidewall of the trimming material layer on the first portion of the hard mask layer with respect to an ideal position for the sidewall at the end of the first process step.
- a third process step of the first set of process steps is performed.
- the third process step is a step of etching at least one physically exposed portion of the second material layers (e.g., the sacrificial material layers 42 ) and at least one physically exposed portion 73 A of the patterned hard mask layer 73 in a second etch process employing the trimming material layer 67 as an etch mask.
- the second etch process can be an anisotropic etch process that etches the second material of the second material layers and the material of the hard mask layer 73 selective to the first material of the first material layers.
- the first material layers are employed as etch stop layers for the second etch process.
- the first portion 73 A of the hard mask layer 73 is removed during the third process step.
- At least one respective physically exposed portion of the second material layers (e.g., the sacrificial material layers 42 ) and at least one respective physically exposed portion 73 A of the patterned hard mask layer 73 can be simultaneously etched in the third process step.
- the hard mask layer 73 can comprise the same material as the second material layers.
- the hard mask layer 73 and the second material layers can comprise silicon nitride, and the first material layers can comprise silicon oxide.
- the hard mask layer 73 can have a thickness that is not greater than the maximum thickness of the second material layers so that each physically exposed portion of the hard mask layer 73 that is not covered by the trimming material layer 67 can be removed by the time each physically exposed portion of the second material layers (e.g., the sacrificial material layers 42 ) is etched through.
- a fourth process step of the first set of process steps is performed.
- the fourth process step is the step of further trimming the trimming material layer 67 .
- the trimming material layer 67 can be trimmed selective to the materials of the first material layers (e.g., the insulator layers 32 ) and the second material layers (e.g., the sacrificial material layers 42 ) during the fourth process step.
- the trimming material layer 67 can be trimmed by a second trimming distance TD 2 such that a trimmed sidewall 67 C of the trimming material layer 67 adjoins a top surface of a remaining portion 73 B among the multiple portions of the hard mask layer 73 after the fourth process step.
- the remaining portion 73 B of the hard mask layer 73 on which the trimmed sidewall of the trimming material layer 67 is formed can be the nearest neighboring portion of the portion 73 A that is removed in the preceding third process step illustrated in FIG. 9 .
- the sidewall 67 C of the trimming material layer 73 can be shifted to the second portion 73 B of the hard mask layer 73 during the fourth process step.
- the sum of the first trimming distance TD 1 and the second trimming distance TD 2 can be about the center-to-center distance between neighboring portions ( 73 A, 73 B) of the hard mask layer 73 .
- a sidewall 67 C of the trimming material layer 67 can straddle a center portion of the patterned portion 73 B of the hard mask layer 73 that is most proximal to the interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 among the portions of the hard mask layer 73 that overlie the alternating stack ( 32 , 42 ).
- the width of a patterned portion (which is herein referred to as a first portion 73 A) of the hard mask layer 73 on which an edge of the trimming material layer 67 is present at the end of the first process step can be at least twice the trimming width variation of the trimming material layer (as manifested during the second process step), and the spacing between the first portion 73 A and a neighboring portion 73 B of the hard mask layer 73 (which is herein referred to as a second portion) can be at least twice the trimming width variation of the trimming material layer 67 (to be manifested during a fourth processing step to be subsequently performed).
- the center-to-center distance between the first portion 73 A and the second portion 73 B of the hard mask layer 73 , or the pitch of the patterned portions of the hard mask layer 73 can be four times the trimming width variation of the trimming process plus the variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- the nominal value of the first trimming distance TD 1 can be equal to twice the trimming width variation (which is the inherent variation in the trimming distance in a trimming process that trims the trimming material layer 67 ) plus one half of the variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- the nominal value of the second trimming distance TD 2 can be equal to twice the trimming width variation (which is the inherent variation in the trimming distance in a trimming process that trims the trimming material layer 67 ) plus one half of the variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- the target value for the second trimming distance TD 2 can be modified from the nominal value by making an overlay measurement to determine the offset distance of a sidewall of the trimming material layer 67 with respect to an ideal position for the sidewall 67 B at the end of the third processing step.
- the pitch of the patterned portions ( 73 A, 73 B) of the hard mask layer 73 may be the same as, or can be greater than, the sum of four times the trimming width variation and the variance in critical dimension of a lithographic process employed to pattern the hard mask layer 73 .
- FIGS. 7-10 collectively constitute a set of process steps, which can be repeatedly performed to form stepped surfaces.
- a first process step of a second set of process steps can be performed.
- the second set of process steps can include an identical sequence of process steps as the first set of process steps.
- the first process step of the second set of process steps can be identical to the first process step of the first set of process steps.
- physically exposed portions of the insulator layers 32 that are not covered by the patterned trimming material layer 67 or by the patterned hard mask layer 73 are etched.
- the trimming material layer 67 can have a sidewall that adjoins a top surface of a remaining portion 73 B among the multiple portions of the hard mask layer 73 during the first process step of the second set of process steps.
- the portions of the hard mask layer 73 that the sidewall of the trimming material layer 67 straddles can be the portion of the hard mask layer 73 that is the most proximate to the interface between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 among the remaining portions of the hard mask layer 73 that overlie the alternating stack ( 32 , 42 ).
- the first etch process of the second set of process steps can be the same anisotropic etch process as the first etch process of the first set of process steps.
- the second material layers can be employed as etch stop layers for each first etch process.
- the trimming material layer 67 can have a sidewall that adjoins, and straddles, a top surface of a remaining portion among the multiple portions of the hard mask layer 73 .
- the trimming material layer 67 can be trimmed in a second process step among the second set of process steps.
- the same trimming process can be employed as the second step of the first set of process steps.
- the trimming distance can be the same as the first trimming distance TD 1 .
- the trimming distance can be changed to match the center-to-center distance between two portions ( 73 B, 73 C) of the hard mask layer 73 that are most proximate to the interface 164 among the portions of the hard mask layer 73 that overlie the alternating stack ( 32 , 42 ).
- the sidewall 67 D of the trimming material layer 67 can be shifted from above a first portion 73 B of the hard mask layer 73 that is most proximal to the interface between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 among the remaining portions of the hard mask layer 73 that overlie the alternating stack ( 32 , 42 ) to a location between the first portion 73 B and a second portion 73 C of the hard mask layer 73 that is a neighboring portion of the first portion 73 B.
- the first portion 73 B can be the most proximate portion to the interface 164 between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 among the remaining portions of the hard mask layer 73 that overlie the alternating stack ( 32 , 42 ), and the second portion 73 C can be a second most proximate portion to the interface between the alternating stack ( 32 , 42 ) and the dielectric material portion 64 among the remaining portions of the hard mask layer 73 that overlie the alternating stack ( 32 , 42 ).
- a third process step of the second set of process steps is performed.
- the third process step of the second set of process steps can be the same as the third process step of the first set of process steps.
- Physically exposed portions of the second material layers (e.g., the sacrificial material layers 42 ) and at least one physically exposed portion 73 B of the patterned hard mask layer 73 can be removed in an etch process employing the trimming material layer 67 as an etch mask.
- the etch process can be the same as the second etch process of the first set of process steps, which is an anisotropic etch process that etches the second material of the second material layers and the material of the hard mask layer 73 selective to the first material of the first material layers.
- the first material layers are employed as etch stop layers for the etch process.
- the remaining first portion 73 B of the hard mask layer 73 is removed during the third process step.
- At least one respective physically exposed portion of the second material layers e.g., the sacrificial material layers 42
- at least one respective physically exposed portion 73 B of the patterned hard mask layer 73 can be simultaneously etched in the third process step of the second set of process steps.
- the fourth process step of the second set of process steps can be performed.
- the fourth process step of the second set of process steps can be the same as the fourth process step of the first set of process steps.
- the set of process steps can be repeatedly performed, which includes a first process step (which can be the same as the first process step of the first set of process steps), a second process step (which can be the same as the second process step of the first set of process steps), a third process step (which can be the same as the third process step of the first set of process steps), and a fourth process step (which can be the same as the fourth process step of the first set of process steps).
- FIG. 14 illustrates the exemplary structure after completion of four sets of process steps.
- FIG. 15 illustrates the exemplary structure after completion of the first process step of the (n ⁇ 1)-th set of process steps, in which n is the total number of sacrificial material layers 42 to be exposed after formation of a set of stepped surfaces.
- the second and third process steps of the (n ⁇ 1)-th set of process steps can be performed to laterally recess the trimming material layer 67 , for example, by the first trimming distance TD 1 , and to remove physically exposed portions of the sacrificial material layers 42 .
- a set of stepped surfaces can be formed underneath a stepped cavity 69 .
- the set of stepped surfaces includes a top surface of each insulator layer 32 (including the topmost insulator layer 32 and bottommost insulator layer 32 which is the n-th insulator layer from the top) and vertical surfaces of each material layer within the alternating stack ( 32 , 42 ) except the bottommost insulator layer 32 and the bottommost sacrificial material layer 42 .
- stepped surfaces refer to a set of surfaces that include at least two horizontal surfaces and at least two vertical surfaces such that each horizontal surface is adjoined to a first vertical surface that extends upward from a first edge of the horizontal surface, and is adjoined to a second vertical surface that extends downward from a second edge of the horizontal surface.
- a “stepped cavity” refers to a cavity having stepped surfaces.
- the fourth process step of the (n ⁇ 1)-th set of process steps is formed to trim the trimming material layer 67 , for example, by the second trimming distance TD 2 .
- an anisotropic etch process is performed, which removes physically exposed portions of the first material layers (e.g., the insulator layers 32 ) employing the combination of the trimming material layer 67 and the second material layers (e.g., the sacrificial material layers 42 ) as an etch mask.
- the anisotropic etch can employ the same chemistry as the first anisotropic etch in the first process step of the first set of process steps.
- the remaining portion of the first material layers and second material layers constitute a stepped structure in which each overlying layer in the stack ( 32 , 42 ) does not protrude in a direction parallel to a top surface of the substrate ( 9 , 10 ) (i.e., in a horizontal direction) more than any underlying layer in the stack ( 32 , 42 ).
- a stepped cavity 69 is formed over the stepped surfaces of the alternating stack ( 32 , 42 ).
- a plurality of steps in the stepped structure can have at least two different step widths.
- the center-to-center distance between each neighboring pair of patterned multiple portions of the hard mask layer 73 is the same, and if the patterned multiple portions of the hard mask layer 73 constitutes a periodic one-dimensional array having a repetition of a unit pattern after patterning of the hard mask layer 73 , then the plurality of steps in the stepped structure can have the same step widths.
- a dielectric material portion (i.e., insulating fill material portion) can be formed in the stepped cavity 69 by deposition of a dielectric material therein.
- a dielectric material such as silicon oxide can be deposited in the stepped cavity 69 . Excess portions of the deposited dielectric material can be removed from above the top surface of the hard mask layer 73 , for example, by chemical mechanical planarization (CMP). The remaining portion of the deposited dielectric material filling the stepped cavity 69 constitutes the dielectric material portion.
- the dielectric material portion is retro-stepped, and is herein referred to as a retro-stepped dielectric material portion 65 .
- a “retro-stepped” element refers to an element that has stepped surfaces and a horizontal cross-sectional area that increases monotonically as a function of a vertical distance from a top surface of a substrate on which the element is present.
- the retro-stepped dielectric material portion 65 is formed over the stepped structure of the alternating stack ( 32 , 42 ), and can have a planar top surface. If silicon oxide is employed for the retro-stepped dielectric material portion 65 , the silicon oxide of the retro-stepped dielectric material portion 65 may, or may not, be doped with dopants such as B, P, and/or F.
- the hard mask layer 73 can be optionally replaced with a dielectric cap layer 80 .
- the hard mask layer 73 can be removed, for example, by a wet etch process that is selective to the dielectric material of the retro-stepped dielectric material portion 65 .
- the dielectric cap layer 80 can include a dielectric material that is different from the material of the sacrificial material layers 42 .
- the dielectric material layer 80 can include silicon oxide.
- the dielectric cap layer 80 may, or may not, be planarized. Depending on whether the dielectric cap layer 80 is planarized or not, the dielectric cap layer 80 can be formed only in the region(s) from which a remaining portion of the hard mask layer 73 at the process step of FIG. 18 is removed, or can be formed in the device region 100 and in the contact region 300 .
- At least one dielectric support pillar may be optionally formed through the retro-stepped dielectric material portion 65 and/or through the alternating stack ( 32 , 42 ).
- a photoresist layer (not shown) can be applied over the alternating stack ( 32 , 42 ) and/or the retro-stepped dielectric material portion 65 , and lithographically patterned to form at least one backside contact trench 79 in an area in which formation of a backside contact via structure is desired.
- the pattern in the photoresist layer can be transferred through the alternating stack ( 32 , 42 ) and/or the retro-stepped dielectric material portion 65 employing an anisotropic etch to form the at least one backside contact trench 79 , which extends at least to the top surface of the substrate ( 9 , 10 ).
- the at least one backside contact trench 79 can include a source contact opening in which a source contact via structure can be subsequently formed. If desired, a source region (not shown) may be formed by implantation of dopant atoms into a portion of the substrate semiconductor layer 10 through the backside contact trench 79 .
- An etchant that selectively etches the second material of the sacrificial material layers 42 with respect to the first material of the insulator layers 32 can be introduced into the at least one backside contact trench 79 , for example, employing an etch process.
- Backside recesses 43 are formed in volumes from which the sacrificial material layers 42 are removed. The removal of the second material of the sacrificial material layers 42 can be selective to the first material of the insulator layers 32 , the material of the at least one dielectric support pillar 7 P, the material of the retro-stepped dielectric material portion 65 , the semiconductor material of the substrate semiconductor layer 10 , and the material of the outermost layer of the memory films 50 .
- the sacrificial material layers 42 can include silicon nitride, and the materials of the insulator layers 32 , the at least one dielectric support pillar (if present), and the retro-stepped dielectric material portion 65 can be selected from silicon oxide and dielectric metal oxides.
- the sacrificial material layers 42 can include a semiconductor material such as polysilicon, and the materials of the insulator layers 32 , the at least one dielectric support pillar (if present), and the retro-stepped dielectric material portion 65 can be selected from silicon oxide, silicon nitride, and dielectric metal oxides.
- the depth of the at least one backside contact trench 79 can be modified so that the bottommost surface of the at least one backside contact trench 79 is located within the dielectric pad layer 12 , i.e., to avoid physical exposure of the top surface of the semiconductor substrate layer 10 until after formation of electrically conductive layers.
- the etch process that removes the second material selective to the first material and the outermost layer of the memory films 50 can be a wet etch process employing a wet etch solution, or can be a gas phase (dry) etch process in which the etchant is introduced in a vapor phase into the at least one backside contact trench 79 .
- the etch process can be a wet etch process in which the exemplary structure is immersed within a wet etch tank including phosphoric acid, which etches silicon nitride selective to silicon oxide, silicon, and various other materials employed in the art.
- the at least one dielectric support pillar (if present), the retro-stepped dielectric material portion 65 , and the memory stack structures 55 provide structural support while the backside recesses 43 are present within volumes previously occupied by the sacrificial material layers 42 .
- Each backside recess 43 can be a laterally extending cavity having a lateral dimension that is greater than the vertical extent of the cavity. In other words, the lateral dimension of each backside recess 43 can be greater than the height of the backside recess 43 .
- a plurality of backside recesses 43 can be formed in the volumes from which the second material of the sacrificial material layers 42 is removed.
- the memory openings in which the memory stack structures 55 are formed are herein referred to as front side recesses or front side cavities in contrast with the backside recesses 43 .
- the device region comprises an array of monolithic three dimensional NAND strings having a plurality of device levels disposed above the substrate ( 9 , 10 ). In this case, each backside recess 43 can define a space for receiving a respective word line of the array of monolithic three dimensional NAND strings.
- Each of the plurality of backside recesses 43 can extend substantially parallel to the top surface of the substrate ( 9 , 10 ).
- a backside recess 43 can be vertically bounded by a top surface of an underlying insulator layer 32 and a bottom surface of an overlying insulator layer 32 .
- each backside recess 43 can have a uniform height throughout.
- a conductive material can be deposited in the plurality of backside recesses 43 , on sidewalls of the at least one the backside contact trench 79 , and over the retro-stepped dielectric material portion 65 and the dielectric cap layer 80 .
- a conductive material refers to an electrically conductive material.
- the conductive material can be deposited by a conformal deposition method, which can be, for example, chemical vapor deposition (CVD), atomic layer deposition (ALD), electroless plating, electroplating, or a combination thereof.
- the conductive material can be an elemental metal, an intermetallic alloy of at least two elemental metals, a conductive nitride of at least one elemental metal, a conductive metal oxide, a conductive doped semiconductor material, a conductive metal-semiconductor alloy such as a metal silicide, alloys thereof, and combinations or stacks thereof.
- Non-limiting exemplary conductive materials that can be deposited in the plurality of backside recesses 43 include tungsten, tungsten nitride, titanium, titanium nitride, tantalum, and tantalum nitride.
- the conductive material can comprise a metal such as tungsten and/or metal nitride.
- the conductive material for filling the plurality of backside recesses 43 can be selected from tungsten and a combination of titanium nitride and tungsten. In one embodiment, the conductive material can be deposited by chemical vapor deposition. A plurality of electrically conductive layers 46 is formed in the backside recesses 43 .
- the deposited conductive material can be etched back from the sidewalls of each backside contact trench 79 and from above the retro-stepped dielectric material portion 65 and the dielectric cap layer 80 .
- Each electrically conductive layer 46 which is located outside the volume of the backside contact cavity, can remain in its respective level.
- the electrically conductive layers 46 can include at least control gate level electrically conductive layers, which function as a combination of a plurality of control gate electrodes and a word line electrically connecting, i.e., electrically shorting, the plurality of control gate electrodes.
- Each control gate level electrically conductive layer can be a word line that functions as a common control gate electrode for the plurality of vertical memory devices.
- An insulating spacer 74 can be formed on the sidewalls of the backside contact trench 79 by deposition of a contiguous dielectric material layer and an anisotropic etch of its horizontal portions.
- the insulating spacer 74 includes a dielectric material, which can comprise, for example, silicon oxide, silicon nitride, a dielectric metal oxide, a dielectric metal oxynitride, or a combination thereof.
- the thickness of the insulating spacer 74 as measured at a bottom portion thereof, can be in a range from 1 nm to 50 nm, although lesser and greater thicknesses can also be employed. In one embodiment, the thickness of the insulating spacer 74 can be in a range from 3 nm to 10 nm.
- a conductive material can be deposited within the cavity surrounded by the insulating spacer 74 to fill the cavity.
- the deposited conductive material can be removed from above the topmost layer of the exemplary structure (which can be, for example, the dielectric pillar material layer 73 ) by a planarization process, which can be, for example, a chemical mechanical planarization (CMP) process.
- CMP chemical mechanical planarization
- the backside contact via structure 76 can be a source line that extends through a dielectric insulated trench, i.e., the backside contact trench 79 filled with the dielectric spacer 74 and the backside contact via structure 76 , in the stack to electrically contact a source region (not shown) within the substrate ( 9 , 10 ).
- the source region can be in contact with the horizontal portion of the semiconductor channel in an upper portion of the substrate semiconductor layer 10 .
- contact via structures contacting the electrically conductive layers 46 can be formed.
- a photoresist layer (not shown) can be applied over the topmost layer of the exemplary structure (which can be, for example, the dielectric cap layer 80 ), and can be lithographically patterned to form opening therein.
- the locations and sizes of the openings through the photoresist layer can be selected such that a plurality of openings is formed in the contact region 300 so that each area of the opening is entirely within an area of a top surface of an electrically conductive layer 46 that contacts the retro-stepped dielectric material portion 65 .
- the shapes of the openings in the contact region 300 can be substantially circular or substantially elliptical.
- the plurality of openings in the contact region 300 can be arranged as a linear array or an m ⁇ n two-dimensional rectangular array in which m is a positive integer, and n is the total number of levels of the electrically conductive layers 46 . Additional openings can be formed over each drain region 63 in the device region 100
- the pattern in the photoresist layer can be transferred through the retro-stepped dielectric material portion 65 or through the dielectric cap layer 80 by an anisotropic etch to form via cavities that extend from the top surface of the retro-stepped dielectric material portion 65 to the top surface of a respective electrically conductive layer 46 or from the top surface of the dielectric cap layer 80 to the top surface of a respective drain region 63 .
- At least one conductive material is deposited in the via cavities, and excess portions of the at least one conductive material can be removed from above the top surface of the retro-stepped dielectric material portion 65 and from above the top surface of the dielectric cap layer 80 .
- Contact via structures 8 C are formed in the contact region 300 .
- the contact via structures 8 C contact the top surface of a respective electrically conductive layer 46 , and are herein referred to as control gate contact via structures.
- Drain contact via structures 88 can be formed, which contact the top surface of a respective drain region 63 .
- the plurality of contact via structures 8 C can have different heights through the retro-stepped dielectric material portion 65 .
- the plurality of contact via structures 8 C can have top surfaces located within a same horizontal plane, which can be the horizontal plane including the top surface of the retro-stepped dielectric material layer 65 .
- Each of the plurality of contact via structures 8 C can be formed directly on a top surface of a respective electrically conductive layer 46 .
- the plurality of contact via structures 8 C can comprise control gate contact via structures that contact respective electrically conductive layers 46 within the subset of electrically conductive layers 46 .
- the backside contact via structure 76 can be a source line that extends through a dielectric insulated trench, i.e., the backside contact trench 79 filled with the dielectric spacer 74 and the backside contact via structure 76 , in the stack to electrically contact the source region (not shown).
- the source region can be in contact with the horizontal portion of the semiconductor channel in an upper portion of the semiconductor material layer 10 .
- An array of drain regions 63 contacts a respective semiconductor channel ( 601 , 602 ) within the array of memory stack structures 55 .
- a top surface of the dielectric material layer, i.e., the insulator cap layer 70 can be coplanar with top surfaces of the drain regions 63 .
- a drain line as embodied as a conductive line structure that contacts a drain contact via structure, can electrically contact an upper portion of the semiconductor channel ( 601 , 602 ).
- a first element “electrically contacts” a second element if the first element is electrically shorted to the second element.
- a subset of the electrically conductive layers 46 comprises control gate electrodes for the at least one memory stack structure 55 .
- one or more of the electrically conductive layers 46 can comprise select gate electrodes located above, or underneath, the control gate electrodes.
- electrically conductive layers 46 located at the lowest level(s) can comprise lower level select gate electrodes located below the control gate electrodes.
- the lower level electrically conductive layer(s) 46 can comprise source select gate electrodes, which can be employed to select a semiconductor channel ( 601 , 602 ) to be activated from the source side.
- Electrically conductive layers 46 located at the highest level(s) can comprise upper level select gate electrodes located above the control gate electrodes.
- the upper level electrically conductive layer(s) 46 can comprise drain select gate electrodes, which can be employed to select a semiconductor channel ( 601 , 602 ) to be activated from the drain side.
- the device located over the semiconductor substrate can include a vertical NAND device located in the device region, and at least one of the electrically conductive layers 46 in the stack ( 32 , 46 ) can comprise, or can be electrically connected to, a word line of the NAND device.
- the device region can include a plurality of semiconductor channels ( 601 , 602 ). At least one end portion of each of the plurality of semiconductor channels ( 601 , 602 ) extends substantially perpendicular to a top surface of the semiconductor substrate.
- the device region further includes a plurality of charge storage regions located within each memory layer 50 . Each charge storage region is located adjacent to a respective one of the plurality of semiconductor channels ( 601 , 602 ).
- the device region further includes a plurality of control gate electrodes having a strip shape extending substantially parallel to the top surface of the substrate ( 9 , 10 ).
- the plurality of control gate electrodes comprise at least a first control gate electrode located in the first device level and a second control gate electrode located in the second device level.
- the plurality of electrically conductive layers 46 in the stack ( 32 , 45 ) can be in electrical contact with, or can comprise, the plurality of control gate electrodes, and extends from the device region to a contact region including a plurality of electrically conductive contact via structures.
- a stack ( 32 , 45 ) of an alternating plurality of word lines 46 and insulating layers 32 can be located over a semiconductor substrate.
- Each of the word lines 46 and insulating layers 32 is located at different levels that are vertically spaced from a top surface of the semiconductor substrate by different distances.
- An array of memory stack structures 55 is embedded within the stack ( 32 , 45 ).
- Each memory stack structure 55 comprises a semiconductor channel ( 601 , 602 ) and at least one charge storage region located adjacent to the semiconductor channel ( 601 , 602 ). At least one end portion of the semiconductor channel ( 601 , 602 ) extends substantially perpendicular to the top surface of the semiconductor substrate through the stack ( 32 , 45 ).
- the insulating layers 32 can comprise silicon oxide layers
- the plurality of word lines 46 can comprise tungsten or a combination of titanium nitride and tungsten
- the memory film 50 can comprises a tunneling dielectric, a blocking dielectric layer, and either a plurality of floating gates or a charge trapping layer located between the tunneling dielectric layer and the blocking dielectric layer.
- An end portion of each of the plurality of word lines 46 in a device region can comprise a control gate electrode located adjacent to the at least one charge storage region.
- a plurality of contact via structures contacting the word lines 46 can be located in a contact region. The plurality of word lines 46 extends from the device region to the contact region.
Landscapes
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Semiconductor Memories (AREA)
- Non-Volatile Memory (AREA)
Abstract
Description
- The present disclosure relates generally to the field of metal interconnect structures and specifically to metal interconnect structures including multiple electrically shorted conductive layers for vertical semiconductor devices and methods of making thereof.
- Multilevel metal interconnect structures are routinely employed to provide electrical wiring for a high density circuitry, such as semiconductor devices on a substrate. Continuous scaling of semiconductor devices leads to a higher wiring density as well as an increase in the number of wiring levels. For example, a 3D NAND stacked memory device may include at least as many number of wiring levels as the total number of control gate electrodes employed for the 3D NAND stacked memory device. Each of the conductive layers in the wiring levels needs to be provided with an electrical contact.
- According to an aspect of the present disclosure, a method of fabricating a multilevel structure is provided. A stack comprising an alternating plurality of first material layers and second material layers is formed over a substrate. A hard mask layer is formed over the stack, and is patterned into multiple portions that are laterally spaced apart. A trimming material layer is formed and is patterned over the patterned hard mask layer. At least one set of process steps is performed. Each set of process steps includes at least a first process step of etching at least one physically exposed portion of the first material layers in a first etch process employing a combination of the patterned trimming material layer and the patterned hard mask layer as an etch mask, a second process step of trimming the trimming material layer after the first etch process, and a third process step of etching at least one physically exposed portion of the second material layers and a physically exposed portion of the patterned hard mask layer in a second etch process employing the trimming material layer as an etch mask.
-
FIG. 1 is a vertical cross-sectional view of an exemplary structure after formation of a stack of an alternating plurality of material layers and memory holes through the stack according to a first embodiment of the present disclosure. -
FIG. 2 is a vertical cross-sectional view of the exemplary structure after formation of memory stack structures and a planarization stop layer according to an embodiment of the present disclosure. -
FIG. 3 is a vertical cross-sectional view of the exemplary structure after formation of an optional dielectric material portion according to an embodiment of the present disclosure. -
FIG. 4 is a vertical cross-sectional view of the exemplary structure after formation of a hard mask layer according to an embodiment of the present disclosure. -
FIG. 5 is a vertical cross-sectional view of the exemplary structure after patterning the hard mask layer according to an embodiment of the present disclosure. -
FIG. 6 is a vertical cross-sectional view of the exemplary structure after formation of a trimming material layer according to an embodiment of the present disclosure. -
FIG. 7 is a vertical cross-sectional view of the exemplary structure after performing a first process step of a first set of process steps according to an embodiment of the present disclosure. -
FIG. 8 is a vertical cross-sectional view of the exemplary structure after performing a second process step of the first set of process steps according to an embodiment of the present disclosure. -
FIG. 9 is a vertical cross-sectional view of the exemplary structure after performing a third process step of the first set of process steps according to an embodiment of the present disclosure. -
FIG. 10 is a vertical cross-sectional view of the exemplary structure after performing a fourth process step of the first set of process steps according to an embodiment of the present disclosure. -
FIG. 11 is a vertical cross-sectional view of the exemplary structure after performing a first process step of a second set of process steps according to an embodiment of the present disclosure. -
FIG. 12 is a vertical cross-sectional view of the exemplary structure after performing a second process step of the second set of process steps according to an embodiment of the present disclosure. -
FIG. 13 is a vertical cross-sectional view of the exemplary structure after performing a third process step of the second set of process steps according to an embodiment of the present disclosure. -
FIG. 14 is a vertical cross-sectional view of the exemplary structure after completion of four sets of process steps according to an embodiment of the present disclosure. -
FIG. 15 is a vertical cross-sectional view of the exemplary structure after completion of a first process step of the (n−1)-th set of process steps according to an embodiment of the present disclosure, in which n is the total number of sacrificial material layers to be exposed after formation of a set of stepped surfaces. -
FIG. 16 is a vertical cross-sectional view of the exemplary structure after completion of a third process step of the (n−1)-th set of process steps according to an embodiment of the present disclosure. -
FIG. 17 is a vertical cross-sectional view of the exemplary structure after completion of a fourth process step of the (n−1)t-th set of process steps and an anisotropic etch process that removes physically exposed portions of the first material layers according to an embodiment of the present disclosure. -
FIG. 18 is a vertical cross-sectional view of the exemplary structure after formation of retro-stepped dielectric material portion according to an embodiment of the present disclosure. -
FIG. 19 is a vertical cross-sectional view of the exemplary structure after replacement of the hard mask layer with a dielectric cap layer according to an embodiment of the present disclosure. -
FIG. 20 is a vertical cross-sectional view of the exemplary structure after formation of a backside contact trench and backside recesses according to an embodiment of the present disclosure. -
FIG. 21 is a vertical cross-sectional view of the exemplary structure after formation of electrically conductive layers according to an embodiment of the present disclosure. -
FIG. 22 is a vertical cross-sectional view of the exemplary structure after formation of a backside contact via structure according to an embodiment of the present disclosure. -
FIG. 23 is a vertical cross-sectional view of the exemplary structure after formation of control gate contact via structures according to an embodiment of the present disclosure. - As discussed above, the present disclosure is directed to metal interconnect structures including multiple electrically shorted conductive layers for vertical semiconductor devices and methods of making the same, the various aspects of which are described below. The embodiments of the disclosure can be employed to form various structures including a multilevel metal interconnect structure, a non-limiting example of which includes semiconductor devices such as three-dimensional monolithic memory array devices comprising a plurality of NAND memory strings. The drawings are not drawn to scale. Multiple instances of an element may be duplicated where a single instance of the element is illustrated, unless absence of duplication of elements is expressly described or clearly indicated otherwise. Ordinals such as “first,” “second,” and “third” are employed merely to identify similar elements, and different ordinals may be employed across the specification and the claims of the instant disclosure. As used herein, a first element located “on” a second element can be located on the exterior side of a surface of the second element or on the interior side of the second element. As used herein, a first element is located “directly on” a second element if there exist a physical contact between a surface of the first element and a surface of the second element.
- A monolithic three dimensional memory array is one in which multiple memory levels are formed above a single substrate, such as a semiconductor wafer, with no intervening substrates. The term “monolithic” means that layers of each level of the array are directly deposited on the layers of each underlying level of the array. In contrast, two dimensional arrays may be formed separately and then packaged together to form a non-monolithic memory device. For example, non-monolithic stacked memories have been constructed by forming memory levels on separate substrates and vertically stacking the memory levels, as described in U.S. Pat. No. 5,915,167 titled “Three Dimensional Structure Memory.” The substrates may be thinned or removed from the memory levels before bonding, but as the memory levels are initially formed over separate substrates, such memories are not true monolithic three dimensional memory arrays. The various three dimensional memory devices of the present disclosure include a monolithic three-dimensional NAND string memory device, and can be fabricated employing the various embodiments described herein.
- Referring to
FIG. 1 , an exemplary structure according to an embodiment of the present disclosure is illustrated, which can be employed, for example, to fabricate a device structure containing vertical NAND memory devices. The exemplary structure includes a substrate, which can be a semiconductor substrate. The substrate can include a substrate semiconductor layer 9. The substrate semiconductor layer 9 is a semiconductor material layer, and can include at least one elemental semiconductor material, at least one III-V compound semiconductor material, at least one II-VI compound semiconductor material, at least one organic semiconductor material, or other semiconductor materials known in the art. The substrate can have amajor surface 7, which can be, for example, a topmost surface of the substrate semiconductor layer 9. Themajor surface 7 can be a semiconductor surface. In one embodiment, themajor surface 7 can be a single crystalline semiconductor surface. - As used herein, a “semiconductor material” refers to a material having electrical conductivity in the range from 1.0×10−6 S/cm to 1.0×105 S/cm, and is capable of producing a doped material having electrical resistivity in a range from 1.0 S/cm to 1.0×105 S/cm upon suitable doping with an electrical dopant. As used herein, an “electrical dopant” refers to a p-type dopant that adds a hole to a balance band within a band structure, or an n-type dopant that adds an electron to a conduction band within a band structure. As used herein, a “conductive material” refers to a material having electrical conductivity greater than 1.0×105 S/cm. As used herein, an “insulator material” or a “dielectric material” refers to a material having electrical conductivity less than 1.0×10−6 S/cm. All measurements for electrical conductivities are made at the standard condition. Optionally, at least one doped well (not expressly shown) can be formed within the substrate semiconductor layer 9.
- At least one semiconductor device for a peripheral circuitry can be formed on a portion of the substrate semiconductor layer 9. The region in which the at least one semiconductor device for the peripheral circuitry is herein referred to as a
peripheral device region 200. The at least one semiconductor device can include, for example, field effect transistors. For example, at least one shallowtrench isolation structure 120 can be formed by etching portions of the substrate semiconductor layer 9 and depositing a dielectric material therein. A gate dielectric layer, at least one gate conductor layer, and a gate cap dielectric layer can be formed over the substrate semiconductor layer 9, and can be subsequently patterned to form at least one gate structure (150, 152, 154, 158), each of which can include agate dielectric 150, at least one gate electrode (152, 154), and a gate cap dielectric. A gate electrode (152, 154) may include a stack of a firstgate electrode portion 152 and a secondgate electrode portion 154. At least onegate spacer 156 can be formed around the at least one gate structure (150, 152, 154, 158) by depositing and anisotropically etching a conformal dielectric layer.Active regions 130 can be formed in upper portions of the substrate semiconductor layer 9, for example, by introducing electrical dopants employing the at least one gate structure (150, 152, 154, 158) as masking structures. Additional masks may be employed as needed. Theactive region 130 can include source regions and drain regions of field effect transistors. Afirst dielectric liner 161 and asecond dielectric liner 162 can be optionally formed. Each of the first and second dielectric liners (161, 162) can comprise a silicon oxide layer, a silicon nitride layer, and/or a dielectric metal oxide layer. In an illustrative example, thefirst dielectric liner 161 can be a silicon oxide layer, and thesecond dielectric liner 162 can be a silicon nitride layer. The least one semiconductor device for the peripheral circuitry can contain a driver circuit for memory devices to be subsequently formed, which can include at least one NAND device. - A dielectric material such as silicon oxide can be deposited over the at least one semiconductor device, and can be subsequently planarized to form a
planarization dielectric layer 170. In one embodiment the planarized top surface of theplanarization dielectric layer 170 can be coplanar with a top surface of the dielectric liners (161, 162). Subsequently, theplanarization dielectric layer 170 and the dielectric liners (161, 162) can be removed from an area to physically expose a top surface of the substrate semiconductor layer 9. - Optionally, a
semiconductor material layer 10 can be formed on the top surface of the substrate semiconductor layer 9 by deposition of a single crystalline semiconductor material, for example, by selective epitaxy. The deposited semiconductor material can be the same as, or can be different from, the semiconductor material of the substrate semiconductor layer 9. The deposited semiconductor material can be any material that can be employed for the semiconductor substrate layer 9 as described above. The single crystalline semiconductor material of thesemiconductor material layer 10 can be in epitaxial alignment with the single crystalline structure of the substrate semiconductor layer 9. Portions of the deposited semiconductor material located above the top surface of theplanarization dielectric layer 170 can be removed, for example, by chemical mechanical planarization (CMP). In this case, thesemiconductor material layer 10 can have a top surface that is coplanar with the top surface of theplanarization dielectric layer 170. - Optionally, a
dielectric pad layer 12 can be formed above thesemiconductor material layer 10 and theplanarization dielectric layer 170. Thedielectric pad layer 12 can be, for example, silicon oxide layer. The thickness of thedielectric pad layer 12 can be in a range from 3 nm to 30 nm, although lesser and greater thicknesses can also be employed. - At least one optional shallow trench can be formed through the
dielectric pad layer 12 and an upper portion of thesemiconductor material layer 10. The pattern of the at least one shallow trench can be selected such that lower select gate electrodes can be subsequently formed therein. For example, a lower select gate device level may be fabricated as described in U.S. patent application Ser. No. 14/133,979, filed on Dec. 19, 2013, U.S. patent application Ser. No. 14/225,116, filed on Mar. 25, 2014, and/or U.S. patent application Ser. No. 14/225,176, filed on Mar. 25, 2014, all of which are incorporated herein by reference. - A lower
select gate structure 20 can be formed in each of the at least one shallow trench, for example, by forming a gate dielectric layer and at least one conductive material layer, and removing portions of the gate dielectric layer and the at least one conductive material layer from above the top surface of thedielectric pad layer 12, for example, by chemical mechanical planarization. Each lowerselect gate structure 20 can include agate dielectric 22 and a gate electrode (24, 26). In one embodiment, each gate electrode (24, 26) can include ametallic liner 24 and aconductive material portion 26. Themetallic liner 24 can include, for example, TiN, TaN, WN, or a combination thereof. Theconductive material portion 26 can include, for example, W, Al, Cu, or combinations thereof. At least one optional shallow trench isolation structure (not shown) and/or at least one deep trench isolation structure (not shown) may be employed to provide electrical isolation among various semiconductor devices that are present, or are to be subsequently formed, on the substrate. - A
dielectric cap layer 31 can be optionally formed. Thedielectric cap layer 31 includes a dielectric material, and can be formed directly on top surfaces of the gate electrodes (24, 26). Exemplary materials that can be employed for thedielectric cap layer 31 include, but are not limited to, silicon oxide, a dielectric metal oxide, and silicon nitride (in case the material of second material layers to be subsequently formed is not silicon nitride). Thedielectric cap layer 31 provides electrical isolation for the gate electrodes (24, 26). - A stack of an alternating plurality of first material layers (which can be insulating layers 32) and second material layers (which can be sacrificial material layer (42L, 42C, 42U)) is formed over the top surface of the substrate, which can be, for example, on the top surface of the
dielectric cap layer 31. As used herein, an alternating plurality of first elements and second elements refers to a structure in which instances of the first elements and instances of the second elements alternate. Each instance of the first elements that is not an end element of the alternating plurality is adjoined by two instances of the second elements on both sides, and each instance of the second elements that is not an end element of the alternating plurality is adjoined by two instances of the first elements on both ends. The first elements may have the same thickness thereamongst, or may have different thicknesses. The second elements may have the same thickness thereamongst, or may have different thicknesses. The alternating plurality of first material layers and second material layers may begin with an instance of the first material layers or with an instance of the second material layers, and may end with an instance of the first material layers or with an instance of the second material layers. In one embodiment, an instance of the first elements and an instance of the second elements may form a unit that is repeated with periodicity within the alternating plurality. - Each first material layer includes a first material, and each second material layer includes a second material that is different from the first material. In one embodiment, each first material layer can be an
insulator layer 32, and each second material layer can be asacrificial material layer 42. In this case, the stack can include an alternating plurality of insulator layers 32 and sacrificial material layers 42. - The stack of the alternating plurality is herein referred to as an alternating stack (32, 42). In one embodiment, the alternating stack (32, 42) can include insulator layers 32 composed of the first material, and sacrificial material layers 42 composed of a second material different from that of insulator layers 32. The first material of the insulator layers 32 can be at least one electrically insulating material. As such, each
insulator layer 32 can be an electrically insulating material layer. Electrically insulating materials that can be employed for the insulator layers 32 include, but are not limited to silicon oxide (including doped or undoped silicate glass), silicon nitride, silicon oxynitride, organosilicate glass (OSG), spin-on dielectric materials, dielectric metal oxides that are commonly known as high dielectric constant (high-k) dielectric oxides (e.g., aluminum oxide, hafnium oxide, etc.) and silicates thereof, dielectric metal oxynitrides and silicates thereof, and organic insulating materials. In one embodiment, the first material of the insulator layers 32 can be silicon oxide. - The second material of the sacrificial material layers 42 is a sacrificial material that can be removed selective to the first material of the insulator layers 32. As used herein, a removal of a first material is “selective to” a second material if the removal process removes the first material at a rate that is at least twice the rate of removal of the second material. The ratio of the rate of removal of the first material to the rate of removal of the second material is herein referred to as a “selectivity” of the removal process for the first material with respect to the second material.
- The sacrificial material layers 42 may comprise an electrically insulating material, a semiconductor material, or a conductive material. The second material of the sacrificial material layers 42 can be subsequently replaced with electrically conductive electrodes which can function, for example, as control gate electrodes of a vertical NAND device. Non-limiting examples of the second material include silicon nitride, an amorphous semiconductor material (such as amorphous silicon), and a polycrystalline semiconductor material (such as polysilicon). In one embodiment, the sacrificial material layers 42 can be material layers that comprise silicon nitride or a semiconductor material including at least one of silicon and germanium.
- In one embodiment, the insulator layers 32 can include silicon oxide, and sacrificial material layers can include silicon nitride sacrificial material layers. The first material of the insulator layers 32 can be deposited, for example, by chemical vapor deposition (CVD). For example, if silicon oxide is employed for the insulator layers 32, tetraethyl orthosilicate (TEOS) can be employed as the precursor material for the CVD process. The second material of the sacrificial material layers 42 can be formed, for example, CVD or atomic layer deposition (ALD).
- The sacrificial material layers 42 can be suitably patterned so that conductive material portions to be subsequently formed by replacement of the sacrificial material layers 42 can function as electrically conductive electrodes, such as the control gate electrodes of the monolithic three-dimensional NAND string memory devices to be subsequently formed. The sacrificial material layers 42 may comprise a portion having a strip shape extending substantially parallel to the
major surface 7 of the substrate. - The thicknesses of the insulator layers 32 and the sacrificial material layers 42 can be in a range from 20 nm to 50 nm, although lesser and greater thicknesses can be employed for each
insulator layer 32 and for eachsacrificial material layer 42. The number of repetitions of the pairs of aninsulator layer 32 and a sacrificial material layer (e.g., a control gate electrode or a sacrificial material layer) 42 can be in a range from 2 to 1,024, and typically from 8 to 256, although a greater number of repetitions can also be employed. The top and bottom gate electrodes in the stack may function as the select gate electrodes. In one embodiment, eachsacrificial material layer 42 in the alternating stack (32, 42) can have a uniform thickness that is substantially invariant within each respectivesacrificial material layer 42. - Subsequently, a lithographic material stack (not shown) including at least a photoresist layer can be formed over the alternating stack (32, 42), and can be lithographically patterned to form openings therein. The pattern in the lithographic material stack can be transferred through the entirety of the alternating stack (32, 42) by at least one anisotropic etch that employs the patterned lithographic material stack as an etch mask. Portions of the alternating stack (32, 42) underlying the openings in the patterned lithographic material stack are etched to form
memory openings 49. In other words, the transfer of the pattern in the patterned lithographic material stack through the alternating stack (32, 42) forms thememory openings 49 that extend through the alternating stack (32, 42). The chemistry of the anisotropic etch process employed to etch through the materials of the alternating stack (32, 42) can alternate to optimize etching of the first and second materials in the alternating stack (32, 42). The anisotropic etch can be, for example, a series of reactive ion etches. Optionally, thedielectric cap layer 31 may be used as an etch stop layer between the alternating stack (32, 42) and the substrate. The sidewalls of thememory openings 49 can be substantially vertical, or can be tapered. The patterned lithographic material stack can be subsequently removed, for example, by ashing. The region in which thememory openings 49 are formed is herein referred to as adevice region 100. Acontact region 300 can be provided adjacent to thedevice region 100. A set of stepped surfaces and control gate contact via structures (not shown) can be subsequently formed in thecontact region 300. - The
memory openings 49 are formed through thedielectric cap layer 31 and thedielectric pad layer 12 so that thememory openings 49 extend from the top surface of the alternating stack (32, 42) to the top surface of thesemiconductor material layer 10 within the substrate between the lower select gate electrodes (24, 26). In one embodiment, an overetch into thesemiconductor material layer 10 may be optionally performed after the top surface of thesemiconductor material layer 10 is physically exposed at a bottom of eachmemory opening 49. The overetch may be performed prior to, or after, removal of the lithographic material stack. In other words, the recessed surfaces of thesemiconductor material layer 10 may be vertically offset from the undressed top surfaces of thesemiconductor material layer 10 by a recess depth. The recess depth can be, for example, in a range from 1 nm to 50 nm, although lesser and greater recess depths can also be employed. The overetch is optional, and may be omitted. If the overetch is not performed, the bottom surface of each memory opening 49 can be coplanar with the topmost surface of thesemiconductor material layer 10. Each of thememory openings 49 can include a sidewall (or a plurality of sidewalls) that extends substantially perpendicular to the topmost surface of the substrate. The region in which the array ofmemory openings 49 is formed is herein referred to as a device region. The substrate semiconductor layer 9 and thesemiconductor material layer 10 collectively constitutes a substrate (9, 10), which can be a semiconductor substrate. Alternatively, thesemiconductor material layer 10 may be omitted, and thememory openings 49 can be extend to a top surface of thesemiconductor material layer 10. - Referring to
FIG. 2 , amemory stack structure 55 can be formed within each memory opening through the alternating stack (32, 42). Thememory stack structures 55 can be formed, for example, by depositing a memory film layer in the memory openings and over the alternating stack (32, 42), and by anisotropically etching the memory film layer. The memory film layer can be a stack of contiguous material layers that overlie the entirety of the alternating stack (31, 42,). The memory film layer contacts all sidewall surface(s) and all bottom surface(s) of the memory openings. The memory film layer is a contiguous film stack that provides the functionality of charge storage in the absence of an external electrical bias voltage, while enabling charge transfer in the presence of a suitable external electrical bias voltage. - In one embodiment, the memory film layer can be a stack, in the order of formation, of a blocking dielectric layer, a charge storage layer, and a tunnel dielectric layer. In one embodiment, a plurality of floating gates or a charge storage dielectric can be located between the tunneling dielectric layer and the blocking dielectric layer.
- The blocking dielectric layer contacts the sidewalls of the memory openings. Specifically, the blocking dielectric layer can contact the sidewalls of the sacrificial layers 42. The blocking dielectric layer may include one or more dielectric material layers that can function as the dielectric material(s) of a control gate dielectric between the
sacrificial layers 42 and charge storage regions to be subsequently formed out of the charge storage layer. The blocking dielectric layer can include silicon oxide, a dielectric metal oxide, a dielectric metal oxynitride, or a combination thereof. In one embodiment, the blocking dielectric layer can include a stack of at least one silicon oxide layer and at least one dielectric metal oxide layer. The blocking dielectric layer can be formed by a conformal deposition process such as chemical vapor deposition (CVD) and/or atomic layer deposition (ALD), and/or by deposition of a conformal material layer (such as an amorphous silicon layer) and subsequent conversion of the conformal material layer into a dielectric material layer (such as a silicon oxide layer). The thickness of the blocking dielectric layer can be in a range from 6 nm to 24 nm, although lesser and greater thicknesses can also be employed. Alternatively, the blocking dielectric layer may be omitted from the memory opening, and instead be formed through the backside contact trench in recesses formed by removal of thesacrificial layers 42 prior to forming the metal control gate electrodes through a backside contact trench. - The charge storage layer includes a dielectric charge trapping material, which can be, for example, silicon nitride, or a conductive material such as doped polysilicon or a metallic material. In one embodiment, the charge storage layer includes silicon nitride. The charge storage layer can be formed as a single charge storage layer of homogeneous composition, or can include a stack of multiple charge storage material layers. The multiple charge storage material layers, if employed, can comprise a plurality of spaced-apart floating gate material layers that contain conductive materials (e.g., metal such as tungsten, molybdenum, tantalum, titanium, platinum, ruthenium, and alloys thereof, or a metal silicide such as tungsten silicide, molybdenum silicide, tantalum silicide, titanium silicide, nickel silicide, cobalt silicide, or a combination thereof) and/or semiconductor materials (e.g., polycrystalline or amorphous semiconductor material including at least one elemental semiconductor element or at least one compound semiconductor material). Alternatively or additionally, the charge storage layer may comprise an insulating charge trapping material, such as one or more silicon nitride segments. Alternatively, the charge storage layer may comprise conductive nanoparticles such as metal nanoparticles, which can be, for example, ruthenium nanoparticles. The charge storage layer can be formed, for example, by chemical vapor deposition (CVD), atomic layer deposition (ALD), physical vapor deposition (PVD), or any suitable deposition technique for the selected material(s) for the charge storage layer. The thickness of the charge storage layer can be in a range from 2 nm to 20 nm, although lesser and greater thicknesses can also be employed.
- The tunnel dielectric layer includes a dielectric material through which charge tunneling can be performed under suitable electrical bias conditions. The charge tunneling may be performed through hot-carrier injection or by Fowler-Nordheim tunneling induced charge transfer depending on the mode of operation of the monolithic three-dimensional NAND string memory device to be formed. The tunneling dielectric layer can include silicon oxide, silicon nitride, silicon oxynitride, dielectric metal oxides (such as aluminum oxide and hafnium oxide), dielectric metal oxynitride, dielectric metal silicates, alloys thereof, and/or combinations thereof. In one embodiment, the tunneling dielectric layer can include a stack of a first silicon oxide layer, a silicon oxynitride layer, and a second silicon oxide layer, which is commonly known as an ONO stack. In one embodiment, the tunneling dielectric layer can include a silicon oxide layer that is substantially free of carbon or a silicon oxynitride layer that is substantially free of carbon. The thickness of the tunnel dielectric layer can be in a range from 2 nm to 20 nm, although lesser and greater thicknesses can also be employed.
- Optionally, a permanent channel material layer (such as a polysilicon layer) and/or a sacrificial layer (such as a dielectric material layer) may be formed on the memory film layer. The memory film layer (and any additional layer such as a permanent channel material layer or a sacrificial layer) can be anisotropically etched so that horizontal portions of the memory film layer (and any additional layer) are removed from above the top surface of the alternating stack (32, 42) and at the bottom of each memory opening. Each remaining vertical portion of the memory film layer that remains within a memory opening after the anisotropic etch constitutes a
memory film 50. Eachmemory film 50 can be homeomorphic to a torus. As used herein, an element is homeomorphic to a geometrical shape if the shape of the element can be mapped to the geometrical shape by continuous deformation without creation or destruction of any hole. If an electrode underlies the memory openings, a top surface of the electrode can be physically exposed within the cavity defined by the inner sidewalls of anoverlying memory film 50. - A semiconductor channel (601, 602) can be formed by depositing at least one semiconductor material on the inner sidewalls of the
memory films 50 and on semiconductor surfaces of thesemiconductor material layer 10 at the bottom of the memory openings. In an illustrative example, a first semiconductor channel layer can be deposited directly on the surfaces of thememory films 50 by a conformal deposition method such as chemical vapor deposition (CVD). The first semiconductor channel layer and the memory films can be anisotropically etched to form an opening at a bottom portion of each memory opening. A top surface of thesubstrate semiconductor layer 10 is physically exposed at the bottom of each memory opening. Each remaining portion of the first semiconductor channel layer within a memory opening constitutes a firstsemiconductor channel portion 601. A second semiconductor channel layer can be deposited on the sidewalls of the firstsemiconductor channel portions 601, physically exposed surfaces of thesubstrate semiconductor layer 10 within the memory openings, and over the alternating stack (32, 42). The semiconductor material of the second semiconductor channel layer can include a doped polycrystalline semiconductor material (such as doped polysilicon), or can include a doped amorphous semiconductor material (such as amorphous silicon) that can be subsequently converted into a doped polycrystalline semiconductor material after a suitable anneal at an elevated temperature. - Optionally, a
dielectric core 62 can be formed within a cavity inside each semiconductor channel 60, for example, by deposition of a dielectric material such as silicon oxide, and subsequent planarization of the dielectric material. The planarization of the dielectric material removes the portion of the deposited dielectric material from above the top surface of the horizontal plane including the top surface of the topmost layer of the alternating stack (32, 42), which can be, for example, the top surface of thetopmost insulator layer 32. The planarization of the dielectric material can be performed, for example, by chemical mechanical planarization. Each remaining portion of the dielectric material inside a memory opening constitutes adielectric core 62. Thedielectric core 62 is an optional component, and a combination of amemory film 50 and a semiconductor channel 60 may completely fill a memory opening. - The horizontal portion of the second semiconductor channel layer above the top surface of the topmost layer of the alternating stack (32, 42) can be removed, for example, by a recess etch. Each remaining portion of the second semiconductor channel layer constitutes a
second semiconductor channel 602. Each adjoined pair of afirst semiconductor channel 601 and a second semiconductor channel vertically extend through the alternating stack (32, 42), and collectively constitutes a portion of a semiconductor channel (601, 602) for amemory stack structure 55. A set of amemory film 50 and a semiconductor channel (601, 602) within a same memory opening constitutes amemory stack structure 55. -
Drain regions 63 can be formed by recessing a top portion of each dielectric core and depositing a doped semiconductor material. The doped semiconductor material can be, for example, doped polysilicon. Excess portions of the deposited semiconductor material can be removed from above the top surface of the alternating stack (32, 42), for example, by chemical mechanical planarization (CMP) or a recess etch. - Optionally, a
planarization stop layer 71 can be formed over the alternating stack (32, 42) and the array ofmemory stack structures 55. Theplanarization stop layer 71 can include a material that can be employed as a stopping layer during a planarization process such as chemical mechanical planarization (CMP). In one embodiment, theplanarization stop layer 71 can include silicon nitride, a dielectric metal oxide, a nitrogen-doped organosilicate glass, and/or a metallic nitride material such as TiN or WN. In one embodiment, theplanarization stop layer 71 can include a dielectric material that can be removed selective to the first material of the insulator layers 32. For example, theplanarization stop layer 71 can include a dielectric material such as silicon nitride or a dielectric metal oxide. The thickness of theplanarization stop layer 71 can be in a range from 5 nm to 100 nm, although lesser and greater thicknesses can also be employed. - Referring to
FIG. 3 , a portion of the alternating stack (32, 42) can be removed, for example, by applying and patterning a photoresist layer with an opening and by transferring the pattern of the opening through the alternating stack (32, 42) employing an etch such as an anisotropic etch. An optional trench extending through the entire thickness of the alternating stack (32, 42) can be formed. Subsequently, the trench can be filled with an optional dielectric material such as silicon oxide. Excess portions of the dielectric material can be removed from above the top surface of theplanarization stop layer 71 by a planarization process such as chemical mechanical planarization and/or a recess etch. The top surfaces of theplanarization stop layer 71 can be employed as a stopping surface during the planarization. Theplanarization stop layer 71 can be removed at least partially during the planarization process. Any remaining portion of theplanarization stop layer 71 can be removed in a subsequent etch process selective to the dielectric material of the topmost layer of the alternating stack (32, 42), e.g., selective to the dielectric material of thetopmost insulator layer 32. Optionally, the top surface of thedielectric material portion 64 may be vertically recessed so that the top surface of thedielectric material portion 64 is substantially coplanar with the top surface of the topmost layer of the alternating stack (32, 42). - Referring to
FIG. 4 , ahard mask layer 73 is formed over the alternating stack (32, 42). Thehard mask layer 73 includes a material that is different from the material of the first material layers (e.g., the insulator layers 32). The material of thehard mask layer 73 can be the same as, or can be different from, the material of the second material layers (e.g., the sacrificial material layers 42). In one embodiment, thehard mask layer 73 comprises the same material as the second material layers 42. In one embodiment, thehard mask layer 73 and the second material layers 43 can comprise silicon nitride. In one embodiment, the first material layers (e.g., the insulator layers 32) can comprise silicon oxide. - In one embodiment, the topmost layer of the alternating stack (32, 42) can be a topmost first material layer (e.g., a topmost insulator layer 32), and the
hard mask layer 73 can be formed directly on the topmost first material layer. Thehard mask layer 73 can be deposited on the planar topmost surface of the alternating stack (32, 42) by a deposition method such as chemical vapor deposition (CVD). The thickness of thehard mask layer 73 is selected such that the entire thickness of thehard mask layer 73 can be etched collaterally during a subsequently anisotropic etch of any one of the second material layers (e.g., the sacrificial material layers 42). In one embodiment, thehard mask layer 73 comprises the same material as the second material layers 42, and thehard mask layer 73 has a thickness that is not greater than (i.e., the same as or less than) the maximum thickness of the second material layers (e.g., the sacrificial material layers 42). In another embodiment, the second material layers can have the same thickness as, or a greater thickness than, the thickness of thehard mask layer 73. - Referring to
FIG. 5 , aphotoresist layer 57 can be applied over thehard mask layer 73, and can be lithographically patterned to form a plurality of patterned portions that are spaced apart. The pattern in thephotoresist layer 57 is transferred through thehard mask layer 73 to pattern thehard mask layer 73 into multiple portions that are laterally spaced apart. In one embodiment, the patterned multiple portions of thehard mask layer 73 comprise strips having parallel edges. The parallel edges of the strips can extend along a same horizontal direction, which can be, for example, the direction perpendicular to the vertical cross-sectional plane ofFIG. 5 . Thephotoresist layer 57 can be subsequently removed, for example, by ashing. - In one embodiment, the center-to-center distance dcc between each neighboring pair of patterned multiple portions of the
hard mask layer 73 can be the same. In one embodiment, the patterned multiple portions of thehard mask layer 73 can be a periodic one-dimensional array having a repetition of a unit pattern. In this case, the patterned multiple portions of thehard mask layer 73 can have a uniform pitch, which can be the same as the center-to-center distance dcc. In one embodiment, a center-to-center distance between each neighboring pair of patterned multiple portions of thehard mask layer 73 can be the same, and the patterned multiple portions of thehard mask layer 73 can constitute a periodic one-dimensional array having a repetition of a unit pattern. - In one embodiment, neighboring pairs of patterned multiple portions of the
hard mask layer 73 can have at least two different center-to-center distances, and the patterned multiple portions of the hard mask layer have at least two different widths. In this case, a plurality of steps to be subsequently formed can have at least two different step widths. - In one embodiment, the total number of laterally spaced patterned portions of the
hard mask layer 73 located in a region extending from a substantiallyvertical interface 164 between the alternating stack (32, 42) and thedielectric material portion 64 to thedevice region 100 can be the same as the total number of sacrificial material layers 42 within the alternating stack (32, 42) less one. If the total number of sacrificial material layers 42 in the alternating stack (32, 42) is n, the total number of laterally spaced patterned portions of thehard mask layer 73 located in the region extending from a substantiallyvertical interface 164 between the alternating stack (32, 42) and thedielectric material portion 64 to thedevice region 100 can be n−1. - Referring to
FIG. 6 , a trimmingmaterial layer 67 is formed and patterned over the patternedhard mask layer 73. The trimmingmaterial layer 67 comprises a material that can be continually trimmed, i.e., a material that can be gradually removed over a time duration from outside to inside at a controlled removal rate. For example, the trimmingmaterial layer 67 can be selected from a photoresist material, an organic polymer material, and an inorganic polymer material. Organic polymer materials that can be employed for the trimmingmaterial layer 67 can be an organic material made of cross-linked carbon-containing monomers, and can be carbon-based self-planarizing material known in the art. Inorganic polymer material that can be employed for the trimmingmaterial layer 67 include silicon-based polymer materials such as silicon-based antireflective coating materials as known in the art. A portion of the trimmingmaterial layer 67 remains after repeated trimming that shifts an outer sidewall of the trimmingmaterial layer 67 to a periphery of thecontact region 300 adjoining thedevice region 100. - The trimming
material layer 67 can be applied over the patternedhard mask layer 73 as a blanket material layer, i.e., as an unpatterned material layer. In one embodiment, the trimmingmaterial layer 67 can be applied by a self-planarizing deposition process such as spin coating. The trimmingmaterial layer 67 can be directly patterned by photolithographic exposure and development if the trimmingmaterial layer 67 includes a photosensitive material, or can be patterned by application of a photoresist layer (not shown) thereupon, lithographic patterning of the photoresist layer, and transfer of the pattern of the photoresist layer through the trimmingmaterial layer 67 selective to the patternedhard mask layer 73. As initially patterned, the trimmingmaterial layer 67 can have a sidewall that adjoins a top surface of a remaining portion among the multiple portions of thehard mask layer 73. In one embodiment, asidewall 67A of the trimmingmaterial layer 67 can overlie a top surface of aportion 73A of thehard mask layer 73 that overlies the alternating stack (32, 42). In one embodiment, theportion 73A of thehard mask layer 73 that underlies thesidewall 67A of the trimmingmaterial layer 67 is most proximate to avertical interface 164 between thedielectric material portion 64 and the alternating stack (32, 42) among the plurality of laterally spaced portions of thehard mask layer 73 that overlie the alternating stack (32, 42). In one embodiment, a sidewall of the trimmingmaterial layer 67 can straddle a center region of the patternedportion 73A of thehard mask layer 73 that overlies the alternating stack (32, 42) and is most proximal to theinterface 164 between the alternating stack (32, 42) and thedielectric material portion 64. - In one embodiment, the pitch of the multiple portions of the
hard mask layer 73 can be about the sum of four times a trimming width variation of the trimmingmaterial layer 67 and a variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. Alternatively, the pitch of the multiple portions of thehard mask layer 73 can be greater than the sum of four times a trimming width variation of the trimmingmaterial layer 67 and a variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. As used herein, a “trimming width variation” refers to inherent variation in the trimming distance for a given trimming process that trims a trimming material layer. - Referring to
FIG. 7 , a set of process steps is performed at least once to sequentially transfer features of the patternedhard mask layer 73. The processing step that initiates the transfer each feature of the patternedhard mask layer 73 is sequentially offset from the initial processing steps by a number of processing steps, of which the total number is correlated to the lateral distance of the features of the patternedhard mask layer 73 from the location of the initial sidewall of the trimmingmaterial layer 67. Specifically, features of eachproximal sidewall 73 p of the multiple portions of the patternedhard mask layer 73 that is proximal to theinterface 164 between the alternating stack (32, 42) and thedielectric material layer 64 are transferred as steps in the alternating stack (32, 42) in the subsequent sets of process steps that are performed in cycles. Features of eachdistal sidewall 73 d of the multiple portions of the patternedhard mask layer 73 that is distal from theinterface 164 between the alternating stack (32, 42) and thedielectric material layer 64 are not transferred. - The set of process steps can be performed multiple times. For example, a first set of process steps can be performed, the second set of process steps can be performed, and so on. Each set of process steps can have an identical sequence of process steps. The view of
FIG. 7 illustrates the exemplary structure after performing a first process step of a first set of process steps. - Specifically, the first process step can be a step of etching at least one physically exposed portion of the first material layers (e.g., the insulator layers 32) in a first etch process employing a combination of the patterned
trimming material layer 67 and the patternedhard mask layer 73 as an etch mask. Thus, at least one physically exposed portion of thetopmost insulator layer 32 that is not covered by the patternedtrimming material layer 67 or by the patternedhard mask layer 73 is etched. In one embodiment, the trimmingmaterial layer 67 can have asidewall 67A that adjoins a top surface of aportion 73A among the multiple portions of thehard mask layer 73 during the first process step of the first set of process steps. The first etch process can be an anisotropic etch process that etches the first material of the first material layers (e.g., the insulator layers 32) selective to the second material of the second material layers (e.g., the sacrificial material layers 42). In one embodiment, the second material layers can be employed as etch stop layers for each first etch process. Specifically, the topmost second material layer (e.g., the topmost sacrificial material layer 42) can be employed as an etch stop layer for the first etch process of the first set of process steps. Throughout the duration of the first process step of the first set of process steps, the trimmingmaterial layer 67 can have asidewall 67A that adjoins a top surface of aportion 73A among the multiple portions of thehard mask layer 73. - Referring to
FIG. 8 , a second process step of the first set of process steps can be performed. The second process step is a trimming step in which the trimmingmaterial layer 67 is trimmed selective to the materials of the first material layers (e.g., the insulator layers 32) and the second material layers (e.g., the sacrificial material layers 42). The trimmingmaterial layer 67 can be trimmed by an isotropic etch, which can be an isotropic dry etch or an isotropic wet etch. After the second process step, the trimmingmaterial layer 67 has asidewall 67B that is located between, and does not contact, a neighboring pair of portions (73A, 73B) of thehard mask layer 73. In case the patterned portions of thehard mask layer 73 comprise a one-dimensional array having a pitch, the trimming distance for the second process step can be selected to be about one half of the pitch. The trimming distance is herein referred to as a first trimming distance TD1. In one embodiment, thesidewall 67B of the trimmingmaterial layer 67 can be shifted from above afirst portion 73A of thehard mask layer 73 that is most proximal to the interface between the alternating stack (32, 42) and thedielectric material portion 64 to a location between thefirst portion 73A and asecond portion 73B of thehard mask layer 73 that is a neighboring portion of thefirst portion 73A. In other words, thefirst portion 73A can be the most proximate portion to theinterface 164 between the alternating stack (32, 42) and thedielectric material portion 64, and thesecond portion 73B can be a second most proximate portion to theinterface 164 between the alternating stack (32, 42) and thedielectric material portion 64. - In one embodiment, the width of the patterned
portion 73A (which is herein referred to as afirst portion 73A) of thehard mask layer 73 on which an edge of the trimmingmaterial layer 67 is present at the end of the first process step can be at least twice the trimming width variation of the trimming material layer 67 (as manifested during the second process step). The spacing between thefirst portion 73A and a neighboringportion 73B of the hard mask layer 73 (which is herein referred to as asecond portion 73B) can be at least twice the trimming width variation of the trimming material layer 67 (to be manifested during a fourth processing step to be subsequently performed). The center-to-center distance between the first portion and the second portion of thehard mask layer 73, or the pitch of the patterned portions of thehard mask layer 73, can be four times the trimming width variation of the trimming process plus the variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. In this case, the nominal value of the first trimming distance TD1 can be equal to twice the trimming width variation (which is the inherent variation in the trimming distance in a trimming process that trims the trimming material layer 67) plus one half of the variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. The target value for the first trimming distance TD1 can be modified from the nominal value by making an overlay measurement to determine the offset distance of a sidewall of the trimming material layer on the first portion of the hard mask layer with respect to an ideal position for the sidewall at the end of the first process step. - Referring to
FIG. 9 , a third process step of the first set of process steps is performed. The third process step is a step of etching at least one physically exposed portion of the second material layers (e.g., the sacrificial material layers 42) and at least one physically exposedportion 73A of the patternedhard mask layer 73 in a second etch process employing the trimmingmaterial layer 67 as an etch mask. The second etch process can be an anisotropic etch process that etches the second material of the second material layers and the material of thehard mask layer 73 selective to the first material of the first material layers. The first material layers are employed as etch stop layers for the second etch process. Thefirst portion 73A of thehard mask layer 73 is removed during the third process step. - In one embodiment, at least one respective physically exposed portion of the second material layers (e.g., the sacrificial material layers 42) and at least one respective physically exposed
portion 73A of the patternedhard mask layer 73 can be simultaneously etched in the third process step. In one embodiment, thehard mask layer 73 can comprise the same material as the second material layers. In one embodiment, thehard mask layer 73 and the second material layers can comprise silicon nitride, and the first material layers can comprise silicon oxide. In one embodiment, thehard mask layer 73 can have a thickness that is not greater than the maximum thickness of the second material layers so that each physically exposed portion of thehard mask layer 73 that is not covered by the trimmingmaterial layer 67 can be removed by the time each physically exposed portion of the second material layers (e.g., the sacrificial material layers 42) is etched through. - Referring to
FIG. 10 , a fourth process step of the first set of process steps is performed. The fourth process step is the step of further trimming the trimmingmaterial layer 67. The trimmingmaterial layer 67 can be trimmed selective to the materials of the first material layers (e.g., the insulator layers 32) and the second material layers (e.g., the sacrificial material layers 42) during the fourth process step. In one embodiment, the trimmingmaterial layer 67 can be trimmed by a second trimming distance TD2 such that a trimmedsidewall 67C of the trimmingmaterial layer 67 adjoins a top surface of a remainingportion 73B among the multiple portions of thehard mask layer 73 after the fourth process step. In a specific example, the remainingportion 73B of thehard mask layer 73 on which the trimmed sidewall of the trimmingmaterial layer 67 is formed can be the nearest neighboring portion of theportion 73A that is removed in the preceding third process step illustrated inFIG. 9 . Thus, if afirst portion 73A and asecond portion 73B are neighboring portions of thehard mask layer 73 at the second process step (corresponding toFIG. 8 ), and if thefirst portion 73A is removed during the third process step (corresponding toFIG. 9 ), thesidewall 67C of the trimmingmaterial layer 73 can be shifted to thesecond portion 73B of thehard mask layer 73 during the fourth process step. In one embodiment, the sum of the first trimming distance TD1 and the second trimming distance TD2 can be about the center-to-center distance between neighboring portions (73A, 73B) of thehard mask layer 73. In one embodiment, asidewall 67C of the trimmingmaterial layer 67 can straddle a center portion of the patternedportion 73B of thehard mask layer 73 that is most proximal to theinterface 164 between the alternating stack (32, 42) and thedielectric material portion 64 among the portions of thehard mask layer 73 that overlie the alternating stack (32, 42). - In one embodiment, the width of a patterned portion (which is herein referred to as a
first portion 73A) of thehard mask layer 73 on which an edge of the trimmingmaterial layer 67 is present at the end of the first process step can be at least twice the trimming width variation of the trimming material layer (as manifested during the second process step), and the spacing between thefirst portion 73A and a neighboringportion 73B of the hard mask layer 73 (which is herein referred to as a second portion) can be at least twice the trimming width variation of the trimming material layer 67 (to be manifested during a fourth processing step to be subsequently performed). The center-to-center distance between thefirst portion 73A and thesecond portion 73B of thehard mask layer 73, or the pitch of the patterned portions of thehard mask layer 73, can be four times the trimming width variation of the trimming process plus the variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. In this case, the nominal value of the first trimming distance TD1 can be equal to twice the trimming width variation (which is the inherent variation in the trimming distance in a trimming process that trims the trimming material layer 67) plus one half of the variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. The nominal value of the second trimming distance TD2 can be equal to twice the trimming width variation (which is the inherent variation in the trimming distance in a trimming process that trims the trimming material layer 67) plus one half of the variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. The target value for the second trimming distance TD2 can be modified from the nominal value by making an overlay measurement to determine the offset distance of a sidewall of the trimmingmaterial layer 67 with respect to an ideal position for thesidewall 67B at the end of the third processing step. The pitch of the patterned portions (73A, 73B) of thehard mask layer 73 may be the same as, or can be greater than, the sum of four times the trimming width variation and the variance in critical dimension of a lithographic process employed to pattern thehard mask layer 73. - The process steps of
FIGS. 7-10 collectively constitute a set of process steps, which can be repeatedly performed to form stepped surfaces. - Referring to
FIG. 11 , a first process step of a second set of process steps can be performed. The second set of process steps can include an identical sequence of process steps as the first set of process steps. Specifically, the first process step of the second set of process steps can be identical to the first process step of the first set of process steps. Thus, physically exposed portions of the insulator layers 32 that are not covered by the patternedtrimming material layer 67 or by the patternedhard mask layer 73 are etched. In one embodiment, the trimmingmaterial layer 67 can have a sidewall that adjoins a top surface of a remainingportion 73B among the multiple portions of thehard mask layer 73 during the first process step of the second set of process steps. The portions of thehard mask layer 73 that the sidewall of the trimmingmaterial layer 67 straddles can be the portion of thehard mask layer 73 that is the most proximate to the interface between the alternating stack (32, 42) and thedielectric material portion 64 among the remaining portions of thehard mask layer 73 that overlie the alternating stack (32, 42). The first etch process of the second set of process steps can be the same anisotropic etch process as the first etch process of the first set of process steps. In one embodiment, the second material layers can be employed as etch stop layers for each first etch process. During the first process step of the second set of process steps or any of the subsequent first process steps, the trimmingmaterial layer 67 can have a sidewall that adjoins, and straddles, a top surface of a remaining portion among the multiple portions of thehard mask layer 73. - Referring to
FIG. 12 , the trimmingmaterial layer 67 can be trimmed in a second process step among the second set of process steps. The same trimming process can be employed as the second step of the first set of process steps. In one embodiment, the trimming distance can be the same as the first trimming distance TD1. In another embodiment, the trimming distance can be changed to match the center-to-center distance between two portions (73B, 73C) of thehard mask layer 73 that are most proximate to theinterface 164 among the portions of thehard mask layer 73 that overlie the alternating stack (32, 42). In one embodiment, thesidewall 67D of the trimmingmaterial layer 67 can be shifted from above afirst portion 73B of thehard mask layer 73 that is most proximal to the interface between the alternating stack (32, 42) and thedielectric material portion 64 among the remaining portions of thehard mask layer 73 that overlie the alternating stack (32, 42) to a location between thefirst portion 73B and asecond portion 73C of thehard mask layer 73 that is a neighboring portion of thefirst portion 73B. In other words, thefirst portion 73B can be the most proximate portion to theinterface 164 between the alternating stack (32, 42) and thedielectric material portion 64 among the remaining portions of thehard mask layer 73 that overlie the alternating stack (32, 42), and thesecond portion 73C can be a second most proximate portion to the interface between the alternating stack (32, 42) and thedielectric material portion 64 among the remaining portions of thehard mask layer 73 that overlie the alternating stack (32, 42). - Referring to
FIG. 13 , a third process step of the second set of process steps is performed. The third process step of the second set of process steps can be the same as the third process step of the first set of process steps. Physically exposed portions of the second material layers (e.g., the sacrificial material layers 42) and at least one physically exposedportion 73B of the patternedhard mask layer 73 can be removed in an etch process employing the trimmingmaterial layer 67 as an etch mask. The etch process can be the same as the second etch process of the first set of process steps, which is an anisotropic etch process that etches the second material of the second material layers and the material of thehard mask layer 73 selective to the first material of the first material layers. The first material layers are employed as etch stop layers for the etch process. The remainingfirst portion 73B of thehard mask layer 73 is removed during the third process step. - In one embodiment, at least one respective physically exposed portion of the second material layers (e.g., the sacrificial material layers 42) and at least one respective physically exposed
portion 73B of the patternedhard mask layer 73 can be simultaneously etched in the third process step of the second set of process steps. - Referring to
FIG. 14 , the fourth process step of the second set of process steps can be performed. The fourth process step of the second set of process steps can be the same as the fourth process step of the first set of process steps. - Subsequently, the set of process steps can be repeatedly performed, which includes a first process step (which can be the same as the first process step of the first set of process steps), a second process step (which can be the same as the second process step of the first set of process steps), a third process step (which can be the same as the third process step of the first set of process steps), and a fourth process step (which can be the same as the fourth process step of the first set of process steps).
FIG. 14 illustrates the exemplary structure after completion of four sets of process steps. - Referring to
FIG. 15 , the set of process steps can further be repeatedly performed.FIG. 15 illustrates the exemplary structure after completion of the first process step of the (n−1)-th set of process steps, in which n is the total number of sacrificial material layers 42 to be exposed after formation of a set of stepped surfaces. - Referring to
FIG. 16 , the second and third process steps of the (n−1)-th set of process steps can be performed to laterally recess the trimmingmaterial layer 67, for example, by the first trimming distance TD1, and to remove physically exposed portions of the sacrificial material layers 42. A set of stepped surfaces can be formed underneath a steppedcavity 69. The set of stepped surfaces includes a top surface of each insulator layer 32 (including thetopmost insulator layer 32 andbottommost insulator layer 32 which is the n-th insulator layer from the top) and vertical surfaces of each material layer within the alternating stack (32, 42) except thebottommost insulator layer 32 and the bottommostsacrificial material layer 42. - As used herein, “stepped surfaces” refer to a set of surfaces that include at least two horizontal surfaces and at least two vertical surfaces such that each horizontal surface is adjoined to a first vertical surface that extends upward from a first edge of the horizontal surface, and is adjoined to a second vertical surface that extends downward from a second edge of the horizontal surface. A “stepped cavity” refers to a cavity having stepped surfaces.
- Referring to
FIG. 17 , the fourth process step of the (n−1)-th set of process steps is formed to trim the trimmingmaterial layer 67, for example, by the second trimming distance TD2. - Subsequently, an anisotropic etch process is performed, which removes physically exposed portions of the first material layers (e.g., the insulator layers 32) employing the combination of the trimming
material layer 67 and the second material layers (e.g., the sacrificial material layers 42) as an etch mask. In one embodiment, the anisotropic etch can employ the same chemistry as the first anisotropic etch in the first process step of the first set of process steps. The remaining portion of the first material layers and second material layers constitute a stepped structure in which each overlying layer in the stack (32, 42) does not protrude in a direction parallel to a top surface of the substrate (9, 10) (i.e., in a horizontal direction) more than any underlying layer in the stack (32, 42). A steppedcavity 69 is formed over the stepped surfaces of the alternating stack (32, 42). - In one embodiment, if neighboring pairs of patterned multiple portions of the
hard mask layer 73 have at least two different center-to-center distances, and if the patterned multiple portions of thehard mask layer 73 have at least two different widths immediately after patterning of thehard mask layer 73, a plurality of steps in the stepped structure can have at least two different step widths. Alternatively, if the center-to-center distance between each neighboring pair of patterned multiple portions of thehard mask layer 73 is the same, and if the patterned multiple portions of thehard mask layer 73 constitutes a periodic one-dimensional array having a repetition of a unit pattern after patterning of thehard mask layer 73, then the plurality of steps in the stepped structure can have the same step widths. - Referring to
FIG. 18 , a dielectric material portion (i.e., insulating fill material portion) can be formed in the steppedcavity 69 by deposition of a dielectric material therein. A dielectric material such as silicon oxide can be deposited in the steppedcavity 69. Excess portions of the deposited dielectric material can be removed from above the top surface of thehard mask layer 73, for example, by chemical mechanical planarization (CMP). The remaining portion of the deposited dielectric material filling the steppedcavity 69 constitutes the dielectric material portion. - The dielectric material portion is retro-stepped, and is herein referred to as a retro-stepped
dielectric material portion 65. As used herein, a “retro-stepped” element refers to an element that has stepped surfaces and a horizontal cross-sectional area that increases monotonically as a function of a vertical distance from a top surface of a substrate on which the element is present. The retro-steppeddielectric material portion 65 is formed over the stepped structure of the alternating stack (32, 42), and can have a planar top surface. If silicon oxide is employed for the retro-steppeddielectric material portion 65, the silicon oxide of the retro-steppeddielectric material portion 65 may, or may not, be doped with dopants such as B, P, and/or F. - Referring to
FIG. 19 , thehard mask layer 73 can be optionally replaced with adielectric cap layer 80. Thehard mask layer 73 can be removed, for example, by a wet etch process that is selective to the dielectric material of the retro-steppeddielectric material portion 65. Thedielectric cap layer 80 can include a dielectric material that is different from the material of the sacrificial material layers 42. In one embodiment, thedielectric material layer 80 can include silicon oxide. Thedielectric cap layer 80 may, or may not, be planarized. Depending on whether thedielectric cap layer 80 is planarized or not, thedielectric cap layer 80 can be formed only in the region(s) from which a remaining portion of thehard mask layer 73 at the process step ofFIG. 18 is removed, or can be formed in thedevice region 100 and in thecontact region 300. - Referring to
FIG. 20 , at least one dielectric support pillar (not shown) may be optionally formed through the retro-steppeddielectric material portion 65 and/or through the alternating stack (32, 42). A photoresist layer (not shown) can be applied over the alternating stack (32, 42) and/or the retro-steppeddielectric material portion 65, and lithographically patterned to form at least onebackside contact trench 79 in an area in which formation of a backside contact via structure is desired. The pattern in the photoresist layer can be transferred through the alternating stack (32, 42) and/or the retro-steppeddielectric material portion 65 employing an anisotropic etch to form the at least onebackside contact trench 79, which extends at least to the top surface of the substrate (9, 10). In one embodiment, the at least onebackside contact trench 79 can include a source contact opening in which a source contact via structure can be subsequently formed. If desired, a source region (not shown) may be formed by implantation of dopant atoms into a portion of thesubstrate semiconductor layer 10 through thebackside contact trench 79. - An etchant that selectively etches the second material of the sacrificial material layers 42 with respect to the first material of the insulator layers 32 can be introduced into the at least one
backside contact trench 79, for example, employing an etch process. Backside recesses 43 are formed in volumes from which the sacrificial material layers 42 are removed. The removal of the second material of the sacrificial material layers 42 can be selective to the first material of the insulator layers 32, the material of the at least one dielectric support pillar 7P, the material of the retro-steppeddielectric material portion 65, the semiconductor material of thesubstrate semiconductor layer 10, and the material of the outermost layer of thememory films 50. In one embodiment, the sacrificial material layers 42 can include silicon nitride, and the materials of the insulator layers 32, the at least one dielectric support pillar (if present), and the retro-steppeddielectric material portion 65 can be selected from silicon oxide and dielectric metal oxides. In another embodiment, the sacrificial material layers 42 can include a semiconductor material such as polysilicon, and the materials of the insulator layers 32, the at least one dielectric support pillar (if present), and the retro-steppeddielectric material portion 65 can be selected from silicon oxide, silicon nitride, and dielectric metal oxides. In this case, the depth of the at least onebackside contact trench 79 can be modified so that the bottommost surface of the at least onebackside contact trench 79 is located within thedielectric pad layer 12, i.e., to avoid physical exposure of the top surface of thesemiconductor substrate layer 10 until after formation of electrically conductive layers. - The etch process that removes the second material selective to the first material and the outermost layer of the
memory films 50 can be a wet etch process employing a wet etch solution, or can be a gas phase (dry) etch process in which the etchant is introduced in a vapor phase into the at least onebackside contact trench 79. For example, if the sacrificial material layers 42 include silicon nitride, the etch process can be a wet etch process in which the exemplary structure is immersed within a wet etch tank including phosphoric acid, which etches silicon nitride selective to silicon oxide, silicon, and various other materials employed in the art. The at least one dielectric support pillar (if present), the retro-steppeddielectric material portion 65, and thememory stack structures 55 provide structural support while the backside recesses 43 are present within volumes previously occupied by the sacrificial material layers 42. - Each
backside recess 43 can be a laterally extending cavity having a lateral dimension that is greater than the vertical extent of the cavity. In other words, the lateral dimension of eachbackside recess 43 can be greater than the height of thebackside recess 43. A plurality of backside recesses 43 can be formed in the volumes from which the second material of the sacrificial material layers 42 is removed. The memory openings in which thememory stack structures 55 are formed are herein referred to as front side recesses or front side cavities in contrast with the backside recesses 43. In one embodiment, the device region comprises an array of monolithic three dimensional NAND strings having a plurality of device levels disposed above the substrate (9, 10). In this case, eachbackside recess 43 can define a space for receiving a respective word line of the array of monolithic three dimensional NAND strings. - Each of the plurality of backside recesses 43 can extend substantially parallel to the top surface of the substrate (9, 10). A
backside recess 43 can be vertically bounded by a top surface of anunderlying insulator layer 32 and a bottom surface of anoverlying insulator layer 32. In one embodiment, eachbackside recess 43 can have a uniform height throughout. - Referring to
FIG. 21 , a conductive material can be deposited in the plurality of backside recesses 43, on sidewalls of the at least one thebackside contact trench 79, and over the retro-steppeddielectric material portion 65 and thedielectric cap layer 80. As used herein, a conductive material refers to an electrically conductive material. The conductive material can be deposited by a conformal deposition method, which can be, for example, chemical vapor deposition (CVD), atomic layer deposition (ALD), electroless plating, electroplating, or a combination thereof. The conductive material can be an elemental metal, an intermetallic alloy of at least two elemental metals, a conductive nitride of at least one elemental metal, a conductive metal oxide, a conductive doped semiconductor material, a conductive metal-semiconductor alloy such as a metal silicide, alloys thereof, and combinations or stacks thereof. Non-limiting exemplary conductive materials that can be deposited in the plurality of backside recesses 43 include tungsten, tungsten nitride, titanium, titanium nitride, tantalum, and tantalum nitride. In one embodiment, the conductive material can comprise a metal such as tungsten and/or metal nitride. In one embodiment, the conductive material for filling the plurality of backside recesses 43 can be selected from tungsten and a combination of titanium nitride and tungsten. In one embodiment, the conductive material can be deposited by chemical vapor deposition. A plurality of electricallyconductive layers 46 is formed in the backside recesses 43. - Referring to
FIG. 22 , the deposited conductive material can be etched back from the sidewalls of eachbackside contact trench 79 and from above the retro-steppeddielectric material portion 65 and thedielectric cap layer 80. Each electricallyconductive layer 46, which is located outside the volume of the backside contact cavity, can remain in its respective level. The electricallyconductive layers 46 can include at least control gate level electrically conductive layers, which function as a combination of a plurality of control gate electrodes and a word line electrically connecting, i.e., electrically shorting, the plurality of control gate electrodes. Each control gate level electrically conductive layer can be a word line that functions as a common control gate electrode for the plurality of vertical memory devices. - An insulating
spacer 74 can be formed on the sidewalls of thebackside contact trench 79 by deposition of a contiguous dielectric material layer and an anisotropic etch of its horizontal portions. The insulatingspacer 74 includes a dielectric material, which can comprise, for example, silicon oxide, silicon nitride, a dielectric metal oxide, a dielectric metal oxynitride, or a combination thereof. The thickness of the insulatingspacer 74, as measured at a bottom portion thereof, can be in a range from 1 nm to 50 nm, although lesser and greater thicknesses can also be employed. In one embodiment, the thickness of the insulatingspacer 74 can be in a range from 3 nm to 10 nm. - A conductive material can be deposited within the cavity surrounded by the insulating
spacer 74 to fill the cavity. The deposited conductive material can be removed from above the topmost layer of the exemplary structure (which can be, for example, the dielectric pillar material layer 73) by a planarization process, which can be, for example, a chemical mechanical planarization (CMP) process. The remaining portion of the conductive material below the topmost layer of the exemplary structure and within the insulatingspacer 74 constitutes a backside contact via structure 76. The backside contact via structure 76 can be a source line that extends through a dielectric insulated trench, i.e., thebackside contact trench 79 filled with thedielectric spacer 74 and the backside contact via structure 76, in the stack to electrically contact a source region (not shown) within the substrate (9, 10). The source region can be in contact with the horizontal portion of the semiconductor channel in an upper portion of thesubstrate semiconductor layer 10. - Prior to, concurrently with, or after, formation of the backside contact via structure 76 by deposition and planarization of a conductive material, contact via structures contacting the electrically
conductive layers 46 can be formed. - Referring to
FIG. 23 , a photoresist layer (not shown) can be applied over the topmost layer of the exemplary structure (which can be, for example, the dielectric cap layer 80), and can be lithographically patterned to form opening therein. - In one embodiment, the locations and sizes of the openings through the photoresist layer can be selected such that a plurality of openings is formed in the
contact region 300 so that each area of the opening is entirely within an area of a top surface of an electricallyconductive layer 46 that contacts the retro-steppeddielectric material portion 65. In one embodiment, the shapes of the openings in thecontact region 300 can be substantially circular or substantially elliptical. In one embodiment, the plurality of openings in thecontact region 300 can be arranged as a linear array or an m×n two-dimensional rectangular array in which m is a positive integer, and n is the total number of levels of the electricallyconductive layers 46. Additional openings can be formed over eachdrain region 63 in thedevice region 100 - The pattern in the photoresist layer can be transferred through the retro-stepped
dielectric material portion 65 or through thedielectric cap layer 80 by an anisotropic etch to form via cavities that extend from the top surface of the retro-steppeddielectric material portion 65 to the top surface of a respective electricallyconductive layer 46 or from the top surface of thedielectric cap layer 80 to the top surface of arespective drain region 63. At least one conductive material is deposited in the via cavities, and excess portions of the at least one conductive material can be removed from above the top surface of the retro-steppeddielectric material portion 65 and from above the top surface of thedielectric cap layer 80. Contact viastructures 8C are formed in thecontact region 300. The contact viastructures 8C contact the top surface of a respective electricallyconductive layer 46, and are herein referred to as control gate contact via structures. Drain contact viastructures 88 can be formed, which contact the top surface of arespective drain region 63. - The plurality of contact via
structures 8C can have different heights through the retro-steppeddielectric material portion 65. In one embodiment, the plurality of contact viastructures 8C can have top surfaces located within a same horizontal plane, which can be the horizontal plane including the top surface of the retro-steppeddielectric material layer 65. Each of the plurality of contact viastructures 8C can be formed directly on a top surface of a respective electricallyconductive layer 46. The plurality of contact viastructures 8C can comprise control gate contact via structures that contact respective electricallyconductive layers 46 within the subset of electricallyconductive layers 46. - The backside contact via structure 76 can be a source line that extends through a dielectric insulated trench, i.e., the
backside contact trench 79 filled with thedielectric spacer 74 and the backside contact via structure 76, in the stack to electrically contact the source region (not shown). The source region can be in contact with the horizontal portion of the semiconductor channel in an upper portion of thesemiconductor material layer 10. An array ofdrain regions 63 contacts a respective semiconductor channel (601, 602) within the array ofmemory stack structures 55. A top surface of the dielectric material layer, i.e., theinsulator cap layer 70, can be coplanar with top surfaces of thedrain regions 63. A drain line, as embodied as a conductive line structure that contacts a drain contact via structure, can electrically contact an upper portion of the semiconductor channel (601, 602). As used herein, a first element “electrically contacts” a second element if the first element is electrically shorted to the second element. - A subset of the electrically
conductive layers 46 comprises control gate electrodes for the at least onememory stack structure 55. Optionally, one or more of the electricallyconductive layers 46 can comprise select gate electrodes located above, or underneath, the control gate electrodes. For example, electricallyconductive layers 46 located at the lowest level(s) can comprise lower level select gate electrodes located below the control gate electrodes. In this case, the lower level electrically conductive layer(s) 46 can comprise source select gate electrodes, which can be employed to select a semiconductor channel (601, 602) to be activated from the source side. Electricallyconductive layers 46 located at the highest level(s) can comprise upper level select gate electrodes located above the control gate electrodes. In this case, the upper level electrically conductive layer(s) 46 can comprise drain select gate electrodes, which can be employed to select a semiconductor channel (601, 602) to be activated from the drain side. - In one embodiment, the device located over the semiconductor substrate can include a vertical NAND device located in the device region, and at least one of the electrically
conductive layers 46 in the stack (32, 46) can comprise, or can be electrically connected to, a word line of the NAND device. The device region can include a plurality of semiconductor channels (601, 602). At least one end portion of each of the plurality of semiconductor channels (601, 602) extends substantially perpendicular to a top surface of the semiconductor substrate. The device region further includes a plurality of charge storage regions located within eachmemory layer 50. Each charge storage region is located adjacent to a respective one of the plurality of semiconductor channels (601, 602). The device region further includes a plurality of control gate electrodes having a strip shape extending substantially parallel to the top surface of the substrate (9, 10). The plurality of control gate electrodes comprise at least a first control gate electrode located in the first device level and a second control gate electrode located in the second device level. The plurality of electricallyconductive layers 46 in the stack (32, 45) can be in electrical contact with, or can comprise, the plurality of control gate electrodes, and extends from the device region to a contact region including a plurality of electrically conductive contact via structures. - In case the exemplary structure includes a three-dimensional NAND device, a stack (32, 45) of an alternating plurality of
word lines 46 and insulatinglayers 32 can be located over a semiconductor substrate. Each of the word lines 46 and insulatinglayers 32 is located at different levels that are vertically spaced from a top surface of the semiconductor substrate by different distances. An array ofmemory stack structures 55 is embedded within the stack (32, 45). Eachmemory stack structure 55 comprises a semiconductor channel (601, 602) and at least one charge storage region located adjacent to the semiconductor channel (601, 602). At least one end portion of the semiconductor channel (601, 602) extends substantially perpendicular to the top surface of the semiconductor substrate through the stack (32, 45). - In a non-limiting illustrative example, the insulating
layers 32 can comprise silicon oxide layers, the plurality ofword lines 46 can comprise tungsten or a combination of titanium nitride and tungsten, thememory film 50 can comprises a tunneling dielectric, a blocking dielectric layer, and either a plurality of floating gates or a charge trapping layer located between the tunneling dielectric layer and the blocking dielectric layer. An end portion of each of the plurality ofword lines 46 in a device region can comprise a control gate electrode located adjacent to the at least one charge storage region. A plurality of contact via structures contacting the word lines 46 can be located in a contact region. The plurality of word lines 46 extends from the device region to the contact region. - Although the foregoing refers to particular preferred embodiments, it will be understood that the disclosure is not so limited. It will occur to those of ordinary skill in the art that various modifications may be made to the disclosed embodiments and that such modifications are intended to be within the scope of the disclosure. All of the publications, patent applications and patents cited herein are incorporated herein by reference in their entirety.
Claims (33)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/584,179 US9397115B1 (en) | 2014-12-29 | 2014-12-29 | Methods for making a trim-rate tolerant self-aligned contact via structure array |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/584,179 US9397115B1 (en) | 2014-12-29 | 2014-12-29 | Methods for making a trim-rate tolerant self-aligned contact via structure array |
Publications (2)
Publication Number | Publication Date |
---|---|
US20160190154A1 true US20160190154A1 (en) | 2016-06-30 |
US9397115B1 US9397115B1 (en) | 2016-07-19 |
Family
ID=56165133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/584,179 Expired - Fee Related US9397115B1 (en) | 2014-12-29 | 2014-12-29 | Methods for making a trim-rate tolerant self-aligned contact via structure array |
Country Status (1)
Country | Link |
---|---|
US (1) | US9397115B1 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107731836A (en) * | 2017-08-28 | 2018-02-23 | 长江存储科技有限责任公司 | The forming method of ledge structure |
CN107742605A (en) * | 2017-11-23 | 2018-02-27 | 长江存储科技有限责任公司 | A kind of method and structure for preventing step contact hole etching break-through |
US9972641B1 (en) * | 2016-11-17 | 2018-05-15 | Sandisk Technologies Llc | Three-dimensional memory device having a multilevel drain select gate electrode and method of making thereof |
US10083982B2 (en) * | 2016-11-17 | 2018-09-25 | Sandisk Technologies Llc | Three-dimensional memory device having select gate electrode that is thicker than word lines and method of making thereof |
CN108630696A (en) * | 2017-03-15 | 2018-10-09 | 旺宏电子股份有限公司 | The forming method of semiconductor structure and the semiconductor structure thereby formed |
TWI638430B (en) * | 2017-03-10 | 2018-10-11 | 旺宏電子股份有限公司 | Method for forming a semiconductor structure and the semiconductor structure formed thereby |
US10134754B2 (en) | 2017-03-13 | 2018-11-20 | Macronix International Co., Ltd. | Method for forming a 3-D memory device and the 3-D memory device formed thereby |
CN110114875A (en) * | 2017-03-08 | 2019-08-09 | 长江存储科技有限责任公司 | The mixing bonding contacts structure of three-dimensional storage part |
KR20190119140A (en) * | 2017-03-08 | 2019-10-21 | 양쯔 메모리 테크놀로지스 씨오., 엘티디. | Cascade Etching Forms Three-Dimensional Memory Devices |
WO2021087735A1 (en) * | 2019-11-05 | 2021-05-14 | Yangtze Memory Technologies Co., Ltd. | Method and structure for forming stairs in three-dimensional memory devices |
US11515324B2 (en) * | 2018-12-19 | 2022-11-29 | Applied Materials, Inc. | 3D NAND structures with decreased pitch |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016225614A (en) | 2015-05-26 | 2016-12-28 | 株式会社半導体エネルギー研究所 | Semiconductor device |
US9853050B2 (en) * | 2016-03-14 | 2017-12-26 | Toshiba Memory Corporation | Semiconductor memory device and method for manufacturing the same |
US10192929B2 (en) | 2017-03-24 | 2019-01-29 | Sandisk Technologies Llc | Three-dimensional memory devices having through-stack contact via structures and method of making thereof |
US10283566B2 (en) | 2017-06-01 | 2019-05-07 | Sandisk Technologies Llc | Three-dimensional memory device with through-stack contact via structures and method of making thereof |
US10224373B2 (en) | 2017-06-28 | 2019-03-05 | Sandisk Technologies Llc | Three-dimensional ReRAM memory device employing replacement word lines and methods of making the same |
KR102624633B1 (en) | 2018-08-09 | 2024-01-12 | 삼성전자주식회사 | Vertical memory devices |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7935464B2 (en) * | 2008-10-30 | 2011-05-03 | Applied Materials, Inc. | System and method for self-aligned dual patterning |
KR20140009189A (en) | 2010-10-18 | 2014-01-22 | 아이엠이씨 | Vertical semiconductor memory device and manufacturing method thereof |
US8759217B1 (en) * | 2013-01-07 | 2014-06-24 | Macronix International Co., Ltd. | Method for forming interlayer connectors to a stack of conductive layers |
-
2014
- 2014-12-29 US US14/584,179 patent/US9397115B1/en not_active Expired - Fee Related
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9972641B1 (en) * | 2016-11-17 | 2018-05-15 | Sandisk Technologies Llc | Three-dimensional memory device having a multilevel drain select gate electrode and method of making thereof |
US10083982B2 (en) * | 2016-11-17 | 2018-09-25 | Sandisk Technologies Llc | Three-dimensional memory device having select gate electrode that is thicker than word lines and method of making thereof |
KR102337626B1 (en) * | 2017-03-08 | 2021-12-09 | 양쯔 메모리 테크놀로지스 씨오., 엘티디. | Step Etching to Form a 3D Memory Device |
US10923491B2 (en) | 2017-03-08 | 2021-02-16 | Yangtze Memory Technologies Co., Ltd. | Hybrid bonding contact structure of three-dimensional memory device |
US11758732B2 (en) | 2017-03-08 | 2023-09-12 | Yangtze Memory Technologies Co., Ltd. | Hybrid bonding contact structure of three-dimensional memory device |
US11527547B2 (en) | 2017-03-08 | 2022-12-13 | Yangtze Memory Technologies Co., Ltd. | Hybrid bonding contact structure of three-dimensional memory device |
CN110114875A (en) * | 2017-03-08 | 2019-08-09 | 长江存储科技有限责任公司 | The mixing bonding contacts structure of three-dimensional storage part |
KR20190119140A (en) * | 2017-03-08 | 2019-10-21 | 양쯔 메모리 테크놀로지스 씨오., 엘티디. | Cascade Etching Forms Three-Dimensional Memory Devices |
CN111354733A (en) * | 2017-03-08 | 2020-06-30 | 长江存储科技有限责任公司 | Etching control method for ladder in three-dimensional storage component forming process |
TWI638430B (en) * | 2017-03-10 | 2018-10-11 | 旺宏電子股份有限公司 | Method for forming a semiconductor structure and the semiconductor structure formed thereby |
US10134754B2 (en) | 2017-03-13 | 2018-11-20 | Macronix International Co., Ltd. | Method for forming a 3-D memory device and the 3-D memory device formed thereby |
CN108630696A (en) * | 2017-03-15 | 2018-10-09 | 旺宏电子股份有限公司 | The forming method of semiconductor structure and the semiconductor structure thereby formed |
CN107731836A (en) * | 2017-08-28 | 2018-02-23 | 长江存储科技有限责任公司 | The forming method of ledge structure |
CN107742605A (en) * | 2017-11-23 | 2018-02-27 | 长江存储科技有限责任公司 | A kind of method and structure for preventing step contact hole etching break-through |
US11515324B2 (en) * | 2018-12-19 | 2022-11-29 | Applied Materials, Inc. | 3D NAND structures with decreased pitch |
WO2021087735A1 (en) * | 2019-11-05 | 2021-05-14 | Yangtze Memory Technologies Co., Ltd. | Method and structure for forming stairs in three-dimensional memory devices |
US11552097B2 (en) | 2019-11-05 | 2023-01-10 | Yangtze Memory Technologies Co., Ltd. | Method and structure for forming stairs in three-dimensional memory devices |
US11950418B2 (en) | 2019-11-05 | 2024-04-02 | Yangtze Memory Technologies Co., Ltd. | Method and structure for forming stairs in three-dimensional memory devices |
Also Published As
Publication number | Publication date |
---|---|
US9397115B1 (en) | 2016-07-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9397115B1 (en) | Methods for making a trim-rate tolerant self-aligned contact via structure array | |
US9530787B2 (en) | Batch contacts for multiple electrically conductive layers | |
US9691778B2 (en) | Multiheight contact via structures for a multilevel interconnect structure | |
US9583500B2 (en) | Multilevel memory stack structure and methods of manufacturing the same | |
US9601502B2 (en) | Multiheight contact via structures for a multilevel interconnect structure | |
US9543320B2 (en) | Three-dimensional memory structure having self-aligned drain regions and methods of making thereof | |
EP3262684B1 (en) | Three-dimensional memory device with stress compensation layer within a word line stack | |
US9478558B2 (en) | Semiconductor structure with concave blocking dielectric sidewall and method of making thereof by isotropically etching the blocking dielectric layer | |
US9728499B2 (en) | Set of stepped surfaces formation for a multilevel interconnect structure | |
US9502429B2 (en) | Set of stepped surfaces formation for a multilevel interconnect structure | |
US9711524B2 (en) | Three-dimensional memory device containing plural select gate transistors having different characteristics and method of making thereof | |
US9305934B1 (en) | Vertical NAND device containing peripheral devices on epitaxial semiconductor pedestal | |
US9236392B1 (en) | Multiheight electrically conductive via contacts for a multilevel interconnect structure | |
US9613975B2 (en) | Bridge line structure for bit line connection in a three-dimensional semiconductor device | |
US9437543B2 (en) | Composite contact via structure containing an upper portion which fills a cavity within a lower portion | |
US9524981B2 (en) | Three dimensional memory device with hybrid source electrode for wafer warpage reduction | |
US9305937B1 (en) | Bottom recess process for an outer blocking dielectric layer inside a memory opening | |
US9530785B1 (en) | Three-dimensional memory devices having a single layer channel and methods of making thereof | |
US9484296B2 (en) | Self-aligned integrated line and via structure for a three-dimensional semiconductor device | |
EP3224865B1 (en) | Set of stepped surfaces formation for a multilevel interconnect structure |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SANDISK TECHNOLOGIES INC., TEXAS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:NOZAWA, KEI;REEL/FRAME:034860/0322 Effective date: 20141226 |
|
AS | Assignment |
Owner name: SANDISK TECHNOLOGIES LLC, TEXAS Free format text: CHANGE OF NAME;ASSIGNOR:SANDISK TECHNOLOGIES INC;REEL/FRAME:038807/0807 Effective date: 20160516 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
MAFP | Maintenance fee payment |
Free format text: PAYMENT OF MAINTENANCE FEE, 4TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1551); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Year of fee payment: 4 |
|
FEPP | Fee payment procedure |
Free format text: MAINTENANCE FEE REMINDER MAILED (ORIGINAL EVENT CODE: REM.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
LAPS | Lapse for failure to pay maintenance fees |
Free format text: PATENT EXPIRED FOR FAILURE TO PAY MAINTENANCE FEES (ORIGINAL EVENT CODE: EXP.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
|
FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20240719 |