US20160133957A1 - Fuel cell stack - Google Patents
Fuel cell stack Download PDFInfo
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- US20160133957A1 US20160133957A1 US14/936,491 US201514936491A US2016133957A1 US 20160133957 A1 US20160133957 A1 US 20160133957A1 US 201514936491 A US201514936491 A US 201514936491A US 2016133957 A1 US2016133957 A1 US 2016133957A1
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- United States
- Prior art keywords
- end part
- cell
- cells
- cell laminate
- fuel cell
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/249—Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04067—Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04052—Storage of heat in the fuel cell system
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04701—Temperature
- H01M8/04731—Temperature of other components of a fuel cell or fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a fuel cell stack constituting a fuel cell.
- a fuel cell stack includes a cell laminate composed of a plurality of stacked cells. Each cell of the cell laminate generates power from the electrochemical reaction between a hydrogen gas and the oxygen contained in air when the hydrogen gas and the air are supplied from one end of the cell laminate (refer to, for example, Patent Document 1).
- the cells at both ends of the cell laminate radiate heat more easily than the cells at a central part of the cell laminate and therefore more easily cool, causing water, which is produced during power generation, to be apt to remain in the cells. For this reason, especially in a cell on the far side from the oxygen gas inlet, at which the volume of the oxygen gas reduces due to the pressure loss, the water produced during the power generation blocks the flow of the oxygen gas in a flow path. This may lead to the shortage of the oxygen gas, resulting in deteriorated efficiency of power generation.
- the present invention has been made in view of the background described above, and an object of the invention is to provide a fuel cell stack capable of suppressing a temperature difference in a cell laminate thereby to achieve higher efficiency of power generation.
- a fuel cell stack in accordance with the present invention is a fuel cell stack including: a cell laminate composed of a plurality of stacked cells,
- the cell laminate has relatively higher thermal insulation properties at least at an end part on a far side from the gas introduction end part than at an end part closer thereto.
- the thermal insulation properties at the end part on the far side from the gas introduction end part are set to be relatively higher than the thermal insulation properties at the end part closer thereto. This makes it possible to prevent the relative decrease in the temperature of the cell at the end part on the far side, thus preventing the volume of water, which is generated by the gas and which is carried away, from becoming smaller than those of the other cells. Thus, it is possible to control the volume of the generated water that remains in the cell at the end part on the far side from the gas introduction end part of he cell laminate.
- the cell laminate may include a non-power-generating end cell which has thermal insulation properties that are higher than those of other cells and which is located at least at the end part on the far side from the gas introduction end part.
- providing the end cell at the end part on the far side from the gas introduction end part in the cell laminate restrains the radiation of heat at the end part on the far side from the gas introduction end part, resulting in higher thermal insulation properties.
- the cell laminate may have the end cells at both ends thereof, and a greater number of the end cells may be provided at the end part on the far side from the gas introduction end part than the number of the end cells provided at the gas introduction end part.
- the end cells provided at the gas introduction end part and at the end part on the far side from the gas introduction end part in the cell laminate restrain the radiation of heat at the gas introduction end part and at the end part on the far side from the gas introduction end part, resulting in higher thermal insulation properties.
- This makes it possible to suppress the volume of the generated water remaining in the cell at the gas introduction end part and at the end part on the far side from the gas introduction end part of the cell laminate, thereby restraining the blockage of the flow of the oxygen gas by the generated water and therefore restraining the shortage of the oxygen gas.
- the thermal insulation properties at the end part on the far side from the gas introduction end part, at which there are more end cells, are higher than those at the gas introduction end part. This makes it possible to suppress the volume of the generated water remaining especially in the cell at the end part on the far side from the gas introduction end part of the cell laminate, thereby restraining the blockage of the flow of the oxygen gas by the generated water and therefore restraining the shortage of the oxygen gas.
- the operational advantages described above are achieved by the end cells, which are common parts, so that an increase in cost or size can be restrained, as compared with the case where a heater, a cooling component or the like is used to achieve the same operational advantages.
- the fuel cell stack in accordance with the present invention permits higher efficiency of power generation by suppressing a temperature difference in a cell laminate.
- FIG. 1 is a side view of a fuel cell according to a present embodiment
- FIG. 2 is a schematic exploded perspective view of a fuel cell stack constituting the fuel cell according to the present embodiment
- FIG. 3 is a sectional view of a cell constituting a cell laminate of the fuel cell stack
- FIGS. 4A and 4B present graphs illustrating the moisture content and the cell temperature in a cell laminate without any end cells
- FIG. 5 is a graph illustrating the cell temperature in the cell laminate.
- FIG. 6 is a graph illustrating the relationship between the number of the end cells and the temperature difference of a cathode end part from a central part.
- FIG. 1 is a side view of a fuel cell according to the present embodiment.
- FIG. 2 is a schematic exploded perspective view of a fuel cell stack constituting the fuel cell according to the present embodiment.
- FIG. 3 is a sectional view of a cell constituting a cell laminate of the fuel cell stack.
- a fuel cell stack 11 As illustrated in FIG. 1 , a fuel cell stack 11 according to the present embodiment has end plates 12 at both ends thereof.
- the end plates 12 are connected with each other by being fastened by a fastening rod (not illustrated).
- the fuel cell stack 11 is pressurized under a predetermined load from both ends by the fastening force of the end plates 12 .
- the fuel cell stack 11 constitutes a fuel cell used by being installed in a mobile body, such as a vehicle.
- the fuel cell stack 11 has a cell laminate 21 , current-collecting plates 22 , and a rust-proof plate 23 .
- the cell laminate 21 is formed by stacking a plurality of cells 20 , and end cells 24 are provided on both ends thereof.
- the cell laminate 21 has one end serving as a gas introduction end part and the other end serving as a gas return end part.
- each of the cells 20 has a membrane electrode assembly (hereinafter referred to as “the MEA”) 5 , which includes electrodes 4 provided on both sides of an electrolyte film 1 , each of the electrodes 4 being composed of a catalyst layer 2 and a diffusion layer 3 .
- Separators 6 are provided on both surfaces of the MEA 5 .
- the separators 6 are formed of stainless plates.
- Each of the cells 20 which is a unit module generating power in the fuel cell stack 11 , generates power by the electrochemical reaction between a hydrogen gas and the oxygen contained in the air.
- Each of the current-collecting plates 22 is formed of an electrically conductive metal material, such as aluminum or stainless steel.
- the current-collecting plates 22 are provided with output terminals (not illustrated), and the electric power generated by the fuel cell stack 11 is taken out through the output terminals.
- the current-collecting plate 22 adjacent to the gas introduction end part of the cell laminate 21 is defined as the electrode on the anode side, while the current-collecting plate 22 adjacent to the gas return end part of the cell laminate 21 is defined as the electrode on the cathode side.
- the cell laminate 21 has the gas introduction end part serving as an anode (An) end part 21 a and the gas return end part serving as a cathode (Ca) end part 21 b.
- the rust-proof plate 23 is provided between the cell laminate 21 and the current-collecting plate 22 on the cathode end part 21 b side of the cell laminate 21 .
- Air containing the oxygen gas is supplied to the cell laminate 21 from the anode end part 21 a, which is the gas introduction end part.
- the air supplied from the anode end part 21 a turns around at the cathode end part 21 b, which is the gas return end part, and is exhausted from the anode end part 21 a.
- the hydrogen gas is supplied from the anode end part 21 a of the cell laminate 21 , turns around at the cathode end part 21 b, and is exhausted from the anode end part 21 a.
- each of the cells 20 generates electric power by the electrochemical reaction between the hydrogen gas and the oxygen contained in the air.
- the both ends of the cell laminate 21 namely, the anode end part 21 a and the cathode end part 21 b, are provided with the end cells 24 .
- the anode end part 21 a has one of the end cells 24
- the cathode end part 21 b has two of the end cells 24 .
- the end cells 24 have the same configuration, which is similar to the configuration of the cells 20 .
- the end cell 24 does not have the electrolyte film, but has the assembly in which the catalyst layer and the diffusion layer are bonded, and both surfaces of the assembly are provided with separators similar to the separators 6 of the cells 20 .
- Each of the end cells 24 is a non-power-generating cell configured as described above.
- Providing the anode end part 21 a and the cathode end part 21 b of the cell laminate 21 with the end cells 24 causes the hydrogen gas, air and cooling water, which are supplied to the cell laminate 21 , to pass through the flow paths in the end cells 24 .
- the thermal capacity of cooling water is high, and the cooling water flowing through the end cells 24 causes the thermal capacity of the entire end cells 24 to become relatively high, so that the thermal insulation properties thereof become relatively higher than those of the cells 20 . This suppresses or shuts off the radiation of heat to the outside from the cells 20 adjacent to the end cells 24 .
- the cathode end part 21 b of the cell laminate 21 is influenced by heat radiation and the cell temperature tends to become lower than that at the central part or the anode end part 21 a throughout power generation and discharge, leading to the occurrence of a temperature difference ⁇ T from the central part.
- the volume of water generated by the power generation which is contained in the air increases in the flow path at the cathode end part 21 b, thus frequently blocking the air flow.
- the flow quantity of the air is reduced due to the pressure loss at the cathode end part 21 b, as compared with the anode end part 21 a. This may lead to an air distribution failure at the cathode end part 21 b in the cell laminate 21 .
- the fuel cell stack 11 includes the two end cells 24 installed adjacently to the cathode end part 21 b on the far side from the anode end part 21 a, which is the gas introduction end part.
- This makes it possible to enhance the thermal insulation properties of the cathode end part 21 b of the cell laminate 21 .
- the temperature difference ⁇ T of the cathode end part 21 b from the central part of the cell laminate 21 can be minimized, making it possible to suppress the volume of the generated water at the cathode end part 21 b of the cell laminate 21 so as to suppress the blockage of the air flow by the generated water, thereby restraining the shortage of the oxygen gas at the cathode end part 21 b.
- the present embodiment has the single end cell 24 located adjacently to the anode end part 21 a so as to enhance the thermal insulation properties of the anode end part 21 a of the cell laminate 21 , thus making it possible to minimize the temperature difference ⁇ T of the anode end part 21 a from the central part in the cell laminate 21 .
- the volume of the generated water at the anode end part 21 a of the cell laminate 21 can be suppressed so as to suppress the blockage of the air flow by the generated water, thereby restraining the shortage of the oxygen gas at the anode end part 21 a.
- providing the single end cell 24 adjacently to the anode end part 21 a and the two end cells 24 adjacently to the cathode end part 21 b as in the present embodiment makes it possible to suppress a decrease in the cell temperature at both ends (the temperature indicated by the solid line in FIG. 5 ) in contrast to the case where the end cells 24 are not provided and the cell temperature decreases at both ends (the temperature indicated by the dashed One in FIG. 5 ).
- the fuel cell stack 11 makes it possible to maximize the suppression of the temperature difference ⁇ T of the cell temperature in the cell laminate 21 by providing the anode end part 21 a and the cathode end part 21 b of the cell laminate 21 with the end cells 24 without using any special heat insulation members or the like.
- This arrangement permits smooth supply of the oxygen gas to the entire cell laminate 21 to achieve efficient power generation.
- the end cells 24 which are common parts, are used, thus making it possible to avoid an increase in cost or size caused by using a heater or a cooling component for suppressing the temperature difference ⁇ T of the cell temperature.
- the temperature difference ⁇ T between the cathode end part 21 b and the central part was measured using several different numbers of the end cells 24 provided adjacently to the cathode end part 21 b of the cell laminate 21 .
- the measurement of the temperature difference ⁇ T was carried out at a cooling water temperature of 60° C., a current value of 15 A, and an outside temperature of ⁇ 20° C.
- the temperature difference ⁇ T is still large in the case where the single end cell 24 is provided, whereas the temperature difference ⁇ T can be markedly reduced by providing the two end cells 24 .
- it is ideal to eliminate the temperature difference ⁇ T to prevent the air distribution failure. It has been found, however, installing the two end cells 24 is effective for nearly eliminating the air distribution failure. Further, adding more of the end cells 24 (three, five and seven) permits a reduction in the temperature difference ⁇ T, but results in an inconvenient increase in the size of the cell laminate 21 .
- the number of the end cells 24 to be provided at the anode end part 21 a and the cathode end part 21 b of the cell laminate 21 is not limited to that in the foregoing embodiment, and is to be selected according to a required reduction in the temperature difference ⁇ T between the anode end part 21 a and the cathode end part 21 b and the central part of the cell laminate 21 .
- the number of the end cells 24 to be provided at the anode end part 21 a and the cathode end part 21 b of the cell laminate 21 is preferably changed, as necessary, according to the shape or the material of the cell laminate 21 , the position of the flow path of a gas or cooling water, the environment in which the fuel cell stack 11 housed in a case or the like is installed, or the like.
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Abstract
Description
- 1. Field of the Invention
- The present invention relates to a fuel cell stack constituting a fuel cell.
- 2. Background Art
- A fuel cell stack includes a cell laminate composed of a plurality of stacked cells. Each cell of the cell laminate generates power from the electrochemical reaction between a hydrogen gas and the oxygen contained in air when the hydrogen gas and the air are supplied from one end of the cell laminate (refer to, for example, Patent Document 1).
- [Patent Document 1] JP2009-158349A
- A cell located on a far side from an oxygen gas inlet, through which air containing an oxygen gas is introduced into a cell laminate, receives less oxygen gas due to a pressure loss than a cell located adjacent to the oxygen gas inlet. Further, the cells at both ends of the cell laminate radiate heat more easily than the cells at a central part of the cell laminate and therefore more easily cool, causing water, which is produced during power generation, to be apt to remain in the cells. For this reason, especially in a cell on the far side from the oxygen gas inlet, at which the volume of the oxygen gas reduces due to the pressure loss, the water produced during the power generation blocks the flow of the oxygen gas in a flow path. This may lead to the shortage of the oxygen gas, resulting in deteriorated efficiency of power generation.
- The present invention has been made in view of the background described above, and an object of the invention is to provide a fuel cell stack capable of suppressing a temperature difference in a cell laminate thereby to achieve higher efficiency of power generation.
- To this end, a fuel cell stack in accordance with the present invention is a fuel cell stack including: a cell laminate composed of a plurality of stacked cells,
- wherein an oxygen gas is introduced from a gas introduction end part on one side of the cell laminate, and
- the cell laminate has relatively higher thermal insulation properties at least at an end part on a far side from the gas introduction end part than at an end part closer thereto.
- According to the fuel cell stack configured as described above, the thermal insulation properties at the end part on the far side from the gas introduction end part are set to be relatively higher than the thermal insulation properties at the end part closer thereto. This makes it possible to prevent the relative decrease in the temperature of the cell at the end part on the far side, thus preventing the volume of water, which is generated by the gas and which is carried away, from becoming smaller than those of the other cells. Thus, it is possible to control the volume of the generated water that remains in the cell at the end part on the far side from the gas introduction end part of he cell laminate.
- With this arrangement, the blockage of the oxygen gas flow caused by the generated water can be suppressed, and therefore, the shortage of the oxygen gas at the cell on the far side from the gas introduction end part can be restrained. Hence, variations in the supply of the oxygen gas in the cell laminate can be restrained, permitting higher efficiency of power generation.
- In the fuel cell stack in accordance with the present invention, the cell laminate may include a non-power-generating end cell which has thermal insulation properties that are higher than those of other cells and which is located at least at the end part on the far side from the gas introduction end part.
- According to the fuel cell stack configured as described above, providing the end cell at the end part on the far side from the gas introduction end part in the cell laminate restrains the radiation of heat at the end part on the far side from the gas introduction end part, resulting in higher thermal insulation properties. This suppresses the volume of the generated water remaining in the cell at the end part on the far side from the gas introduction end part of the cell laminate thereby to restrain the blockage of the flow of the oxygen gas by the generated water, thus making it possible to restrain the shortage of the oxygen gas at the cell on the far side from the gas introduction end part.
- In the fuel cell stack in accordance with the present invention, the cell laminate may have the end cells at both ends thereof, and a greater number of the end cells may be provided at the end part on the far side from the gas introduction end part than the number of the end cells provided at the gas introduction end part.
- According to the fuel cell stack configured as described above, the end cells provided at the gas introduction end part and at the end part on the far side from the gas introduction end part in the cell laminate restrain the radiation of heat at the gas introduction end part and at the end part on the far side from the gas introduction end part, resulting in higher thermal insulation properties. This makes it possible to suppress the volume of the generated water remaining in the cell at the gas introduction end part and at the end part on the far side from the gas introduction end part of the cell laminate, thereby restraining the blockage of the flow of the oxygen gas by the generated water and therefore restraining the shortage of the oxygen gas.
- Furthermore, the thermal insulation properties at the end part on the far side from the gas introduction end part, at which there are more end cells, are higher than those at the gas introduction end part. This makes it possible to suppress the volume of the generated water remaining especially in the cell at the end part on the far side from the gas introduction end part of the cell laminate, thereby restraining the blockage of the flow of the oxygen gas by the generated water and therefore restraining the shortage of the oxygen gas. Further, the operational advantages described above are achieved by the end cells, which are common parts, so that an increase in cost or size can be restrained, as compared with the case where a heater, a cooling component or the like is used to achieve the same operational advantages.
- The fuel cell stack in accordance with the present invention permits higher efficiency of power generation by suppressing a temperature difference in a cell laminate.
-
FIG. 1 is a side view of a fuel cell according to a present embodiment; -
FIG. 2 is a schematic exploded perspective view of a fuel cell stack constituting the fuel cell according to the present embodiment; -
FIG. 3 is a sectional view of a cell constituting a cell laminate of the fuel cell stack; -
FIGS. 4A and 4B present graphs illustrating the moisture content and the cell temperature in a cell laminate without any end cells; -
FIG. 5 is a graph illustrating the cell temperature in the cell laminate; and -
FIG. 6 is a graph illustrating the relationship between the number of the end cells and the temperature difference of a cathode end part from a central part. - The following will describe an embodiment of a fuel cell stack in accordance with the present invention with reference to the accompanying drawings.
-
FIG. 1 is a side view of a fuel cell according to the present embodiment.FIG. 2 is a schematic exploded perspective view of a fuel cell stack constituting the fuel cell according to the present embodiment.FIG. 3 is a sectional view of a cell constituting a cell laminate of the fuel cell stack. - As illustrated in
FIG. 1 , afuel cell stack 11 according to the present embodiment hasend plates 12 at both ends thereof. Theend plates 12 are connected with each other by being fastened by a fastening rod (not illustrated). Thefuel cell stack 11 is pressurized under a predetermined load from both ends by the fastening force of theend plates 12. Thefuel cell stack 11 constitutes a fuel cell used by being installed in a mobile body, such as a vehicle. - As illustrated in
FIG. 2 , thefuel cell stack 11 has acell laminate 21, current-collecting plates 22, and a rust-proof plate 23. Thecell laminate 21 is formed by stacking a plurality ofcells 20, andend cells 24 are provided on both ends thereof. Thecell laminate 21 has one end serving as a gas introduction end part and the other end serving as a gas return end part. - As illustrated in
FIG. 3 , each of thecells 20 has a membrane electrode assembly (hereinafter referred to as “the MEA”) 5, which includes electrodes 4 provided on both sides of anelectrolyte film 1, each of the electrodes 4 being composed of acatalyst layer 2 and adiffusion layer 3. Separators 6 are provided on both surfaces of theMEA 5. The separators 6 are formed of stainless plates. Each of thecells 20, which is a unit module generating power in thefuel cell stack 11, generates power by the electrochemical reaction between a hydrogen gas and the oxygen contained in the air. - Each of the current-
collecting plates 22 is formed of an electrically conductive metal material, such as aluminum or stainless steel. The current-collecting plates 22 are provided with output terminals (not illustrated), and the electric power generated by thefuel cell stack 11 is taken out through the output terminals. The current-collecting plate 22 adjacent to the gas introduction end part of thecell laminate 21 is defined as the electrode on the anode side, while the current-collecting plate 22 adjacent to the gas return end part of thecell laminate 21 is defined as the electrode on the cathode side. In other words, thecell laminate 21 has the gas introduction end part serving as an anode (An)end part 21 a and the gas return end part serving as a cathode (Ca)end part 21 b. The rust-proof plate 23 is provided between thecell laminate 21 and the current-collecting plate 22 on thecathode end part 21 b side of thecell laminate 21. - Air containing the oxygen gas is supplied to the
cell laminate 21 from theanode end part 21 a, which is the gas introduction end part. The air supplied from theanode end part 21 a turns around at thecathode end part 21 b, which is the gas return end part, and is exhausted from theanode end part 21 a. This passes the air through each of thecells 20. As with the air, the hydrogen gas is supplied from theanode end part 21 a of thecell laminate 21, turns around at thecathode end part 21 b, and is exhausted from theanode end part 21 a. Thus, in thecell laminate 21, each of thecells 20 generates electric power by the electrochemical reaction between the hydrogen gas and the oxygen contained in the air. - The both ends of the
cell laminate 21, namely, theanode end part 21 a and thecathode end part 21 b, are provided with theend cells 24. Theanode end part 21 a has one of theend cells 24, while thecathode end part 21 b has two of theend cells 24. Theend cells 24 have the same configuration, which is similar to the configuration of thecells 20. For example, theend cell 24 does not have the electrolyte film, but has the assembly in which the catalyst layer and the diffusion layer are bonded, and both surfaces of the assembly are provided with separators similar to the separators 6 of thecells 20. - Each of the
end cells 24 is a non-power-generating cell configured as described above. - Providing the
anode end part 21 a and thecathode end part 21 b of thecell laminate 21 with theend cells 24 causes the hydrogen gas, air and cooling water, which are supplied to thecell laminate 21, to pass through the flow paths in theend cells 24. At this time, even when the air and the hydrogen gas are supplied, the oxygen gas in the air and the hydrogen gas do not contribute to power generation and bypass theend cells 24 without being consumed. Meanwhile, the thermal capacity of cooling water is high, and the cooling water flowing through theend cells 24 causes the thermal capacity of theentire end cells 24 to become relatively high, so that the thermal insulation properties thereof become relatively higher than those of thecells 20. This suppresses or shuts off the radiation of heat to the outside from thecells 20 adjacent to theend cells 24. - As illustrated in
FIGS. 4A and 4B , generally, in a fuel cell stack configured to distribute a gas from theanode end part 21 a of thecell laminate 21, thecathode end part 21 b of thecell laminate 21 is influenced by heat radiation and the cell temperature tends to become lower than that at the central part or theanode end part 21 a throughout power generation and discharge, leading to the occurrence of a temperature difference ΔT from the central part. As a result, especially when the load is low at the time of idling or the like in a low temperature environment, the volume of water generated by the power generation which is contained in the air increases in the flow path at thecathode end part 21 b, thus frequently blocking the air flow. In addition, the flow quantity of the air is reduced due to the pressure loss at thecathode end part 21 b, as compared with theanode end part 21 a. This may lead to an air distribution failure at thecathode end part 21 b in thecell laminate 21. - As the preventive measures, therefore, the
fuel cell stack 11 according to the present embodiment includes the twoend cells 24 installed adjacently to thecathode end part 21 b on the far side from theanode end part 21 a, which is the gas introduction end part. This makes it possible to enhance the thermal insulation properties of thecathode end part 21 b of thecell laminate 21. Thus, the temperature difference ΔT of thecathode end part 21 b from the central part of thecell laminate 21 can be minimized, making it possible to suppress the volume of the generated water at thecathode end part 21 b of thecell laminate 21 so as to suppress the blockage of the air flow by the generated water, thereby restraining the shortage of the oxygen gas at thecathode end part 21 b. - Further, a decrease in the flow quantity of the air due to the pressure loss does not take place at the
anode end part 21 a, which is the gas introduction end part of thecell laminate 21. However, as with thecathode end part 21 b, theanode end part 21 a tends to radiate heat and therefore, the cell temperature thereof tends to become lower than that at the central part. Hence, the present embodiment has thesingle end cell 24 located adjacently to theanode end part 21 a so as to enhance the thermal insulation properties of theanode end part 21 a of thecell laminate 21, thus making it possible to minimize the temperature difference ΔT of theanode end part 21 a from the central part in thecell laminate 21. With this arrangement, the volume of the generated water at theanode end part 21 a of thecell laminate 21 can be suppressed so as to suppress the blockage of the air flow by the generated water, thereby restraining the shortage of the oxygen gas at theanode end part 21 a. - As illustrated in
FIG. 5 , providing thesingle end cell 24 adjacently to theanode end part 21 a and the twoend cells 24 adjacently to thecathode end part 21 b as in the present embodiment makes it possible to suppress a decrease in the cell temperature at both ends (the temperature indicated by the solid line inFIG. 5 ) in contrast to the case where theend cells 24 are not provided and the cell temperature decreases at both ends (the temperature indicated by the dashed One inFIG. 5 ). - As described above, the
fuel cell stack 11 according to the present embodiment makes it possible to maximize the suppression of the temperature difference ΔT of the cell temperature in thecell laminate 21 by providing theanode end part 21 a and thecathode end part 21 b of thecell laminate 21 with theend cells 24 without using any special heat insulation members or the like. This arrangement permits smooth supply of the oxygen gas to theentire cell laminate 21 to achieve efficient power generation. Furthermore, theend cells 24, which are common parts, are used, thus making it possible to avoid an increase in cost or size caused by using a heater or a cooling component for suppressing the temperature difference ΔT of the cell temperature. - The temperature difference ΔT between the
cathode end part 21 b and the central part was measured using several different numbers of theend cells 24 provided adjacently to thecathode end part 21 b of thecell laminate 21. The measurement of the temperature difference ΔT was carried out at a cooling water temperature of 60° C., a current value of 15 A, and an outside temperature of −20° C. - As illustrated in
FIG. 6 , which shows the measurement results, the temperature difference ΔT is still large in the case where thesingle end cell 24 is provided, whereas the temperature difference ΔT can be markedly reduced by providing the twoend cells 24. Theoretically, it is ideal to eliminate the temperature difference ΔT to prevent the air distribution failure. It has been found, however, installing the twoend cells 24 is effective for nearly eliminating the air distribution failure. Further, adding more of the end cells 24 (three, five and seven) permits a reduction in the temperature difference ΔT, but results in an inconvenient increase in the size of thecell laminate 21. - Based on the measurement results, it has been concluded that providing two of the
end cells 24 is appropriate for achieving a sufficiently reduced temperature difference ΔT while restraining thecell laminate 21 from becoming larger. - The number of the
end cells 24 to be provided at theanode end part 21 a and thecathode end part 21 b of thecell laminate 21 is not limited to that in the foregoing embodiment, and is to be selected according to a required reduction in the temperature difference ΔT between theanode end part 21 a and thecathode end part 21 b and the central part of thecell laminate 21. For example, the number of theend cells 24 to be provided at theanode end part 21 a and thecathode end part 21 b of thecell laminate 21 is preferably changed, as necessary, according to the shape or the material of thecell laminate 21, the position of the flow path of a gas or cooling water, the environment in which thefuel cell stack 11 housed in a case or the like is installed, or the like. -
- 11 fuel cell stack
- 20 cell
- 21 cell laminate
- 21 a anode end part (gas introduction end part)
- 21 b cathode end part (end part on the far side from the gas introduction end part)
- 24 end cell
Claims (3)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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US15/950,652 US20180233754A1 (en) | 2014-11-10 | 2018-04-11 | Fuel cell stack |
US16/371,876 US10998560B2 (en) | 2014-11-10 | 2019-04-01 | Fuel cell stack |
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JP2014228191A JP6160982B2 (en) | 2014-11-10 | 2014-11-10 | Manufacturing method of fuel cell stack |
JP2014-228191 | 2014-11-10 |
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US15/950,652 Division US20180233754A1 (en) | 2014-11-10 | 2018-04-11 | Fuel cell stack |
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US20160133957A1 true US20160133957A1 (en) | 2016-05-12 |
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US14/936,491 Abandoned US20160133957A1 (en) | 2014-11-10 | 2015-11-09 | Fuel cell stack |
US15/950,652 Abandoned US20180233754A1 (en) | 2014-11-10 | 2018-04-11 | Fuel cell stack |
US16/371,876 Active 2036-02-12 US10998560B2 (en) | 2014-11-10 | 2019-04-01 | Fuel cell stack |
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US15/950,652 Abandoned US20180233754A1 (en) | 2014-11-10 | 2018-04-11 | Fuel cell stack |
US16/371,876 Active 2036-02-12 US10998560B2 (en) | 2014-11-10 | 2019-04-01 | Fuel cell stack |
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US (3) | US20160133957A1 (en) |
JP (1) | JP6160982B2 (en) |
KR (1) | KR101837250B1 (en) |
CN (2) | CN110061276A (en) |
CA (1) | CA2909837C (en) |
DE (1) | DE102015118491A1 (en) |
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KR102088555B1 (en) | 2017-08-29 | 2020-03-12 | 건국대학교 산학협력단 | Drug delivery system for targeting lymph node using exosome from serum |
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JP2010244946A (en) * | 2009-04-08 | 2010-10-28 | Japan Steel Works Ltd:The | Fuel cell power generation system |
US20130164646A1 (en) * | 2011-12-21 | 2013-06-27 | Honda Motor Co., Ltd. | Fuel cell stack |
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JP4515631B2 (en) * | 1997-10-28 | 2010-08-04 | 株式会社東芝 | Fuel cell with gas manifold |
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2014
- 2014-11-10 JP JP2014228191A patent/JP6160982B2/en active Active
-
2015
- 2015-10-20 CA CA2909837A patent/CA2909837C/en active Active
- 2015-10-22 KR KR1020150147099A patent/KR101837250B1/en active IP Right Grant
- 2015-10-29 DE DE102015118491.5A patent/DE102015118491A1/en not_active Withdrawn
- 2015-11-09 CN CN201910231512.1A patent/CN110061276A/en active Pending
- 2015-11-09 US US14/936,491 patent/US20160133957A1/en not_active Abandoned
- 2015-11-09 CN CN201510756493.6A patent/CN105591145B/en active Active
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2018
- 2018-04-11 US US15/950,652 patent/US20180233754A1/en not_active Abandoned
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US20030215693A1 (en) * | 2002-05-20 | 2003-11-20 | Yasuyuki Asai | Fuel cell stack structure |
JP2010244946A (en) * | 2009-04-08 | 2010-10-28 | Japan Steel Works Ltd:The | Fuel cell power generation system |
US20130164646A1 (en) * | 2011-12-21 | 2013-06-27 | Honda Motor Co., Ltd. | Fuel cell stack |
Also Published As
Publication number | Publication date |
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JP6160982B2 (en) | 2017-07-12 |
KR20160055687A (en) | 2016-05-18 |
CN105591145A (en) | 2016-05-18 |
CA2909837A1 (en) | 2016-05-10 |
KR101837250B1 (en) | 2018-03-09 |
US10998560B2 (en) | 2021-05-04 |
US20180233754A1 (en) | 2018-08-16 |
DE102015118491A1 (en) | 2016-05-12 |
US20190229353A1 (en) | 2019-07-25 |
CN105591145B (en) | 2019-04-19 |
CN110061276A (en) | 2019-07-26 |
JP2016091944A (en) | 2016-05-23 |
CA2909837C (en) | 2018-04-24 |
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