US20160107416A1 - Protective film for an electronic device - Google Patents

Protective film for an electronic device Download PDF

Info

Publication number
US20160107416A1
US20160107416A1 US14/976,221 US201514976221A US2016107416A1 US 20160107416 A1 US20160107416 A1 US 20160107416A1 US 201514976221 A US201514976221 A US 201514976221A US 2016107416 A1 US2016107416 A1 US 2016107416A1
Authority
US
United States
Prior art keywords
protective film
electronic device
adhesive
screen
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/976,221
Inventor
Lewis S. Cohen
Juan Maldonado
Igor Muravyov
Brett G. Webster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Otter Products LLC
Original Assignee
Otter Products LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Otter Products LLC filed Critical Otter Products LLC
Priority to US14/976,221 priority Critical patent/US20160107416A1/en
Publication of US20160107416A1 publication Critical patent/US20160107416A1/en
Assigned to BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT reassignment BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT INTELLECTUAL PROPERTY SECURITY AGREEMENT Assignors: OTTER PRODUCTS, LLC
Assigned to OTTER PRODUCTS, LLC reassignment OTTER PRODUCTS, LLC RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY AT REEL/FRAME NO. 43681/0846 Assignors: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Abandoned legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/0047Preventing air-inclusions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • B29C63/04Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like
    • B29C63/08Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like by winding helically
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/18Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
    • B32B37/182Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only one or more of the layers being plastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/10Removing layers, or parts of layers, mechanically or chemically
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04BTRANSMISSION
    • H04B1/00Details of transmission systems, not covered by a single one of groups H04B3/00 - H04B13/00; Details of transmission systems not characterised by the medium used for transmission
    • H04B1/38Transceivers, i.e. devices in which transmitter and receiver form a structural unit and in which at least one part is used for functions of transmitting and receiving
    • H04B1/3827Portable transceivers
    • H04B1/3888Arrangements for carrying or protecting transceivers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • B29C2063/027Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material applied by a squeegee
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/48Preparation of the surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3055Cars
    • B29L2031/3061Number plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/748Releasability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00Adhesive articles, e.g. adhesive tapes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/20Displays, e.g. liquid crystal displays, plasma displays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/20Displays, e.g. liquid crystal displays, plasma displays
    • B32B2457/202LCD, i.e. liquid crystal displays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/20Displays, e.g. liquid crystal displays, plasma displays
    • B32B2457/208Touch screens
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00Protective equipment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/108Flash, trim or excess removal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1462Polymer derived from material having at least one acrylic or alkacrylic group or the nitrile or amide derivative thereof [e.g., acrylamide, acrylate ester, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1471Protective layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264Up to 3 mils
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/266Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension of base or substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848Three or more layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/2878Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2891Adhesive compositions including addition polymer from unsaturated monomer including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof

Definitions

  • the present invention relates generally to methods of applying protective films to electronic device surfaces and to devices comprising protective films.
  • Protective films are used to cover and protect a variety of materials and devices from, for example, scratches or dents that may be imparted during transport or use of the device.
  • Protective films may be used to protect, for example, the surface of digital electronic device components during manufacture, or may be adhered to a completed device to protect it from damage during normal day-to-day use.
  • a variety of protective films are known, each having properties that may be advantageous for some uses and disadvantageous for other uses.
  • One form of protective film used in the art is coated on one side with a layer of a dry pressure-sensitive adhesive that has sufficient tack to form a secure contact with the device while permitting slight repositioning of the film after adherence.
  • Protective films are often transparent, and may permit the use of touch-sensitive features of the electronic device through the film.
  • Known methods include spraying a protective film (or device surface) with water or another liquid, applying the wet film to the device surface to be protected (or applying the film to the wet device surface), and using pressure (e.g., with a squeegee) to smooth the film and force out any trapped air bubbles. In doing so, the water or other liquid is also forced out from between the film and the device surface, and collects at an edge of the film.
  • pressure e.g., with a squeegee
  • prior methods required introduction of a liquid to the outer surface of a device, requiring a user to take additional steps to remove liquid after a film is applied to a device.
  • a significant disadvantage to using a wet solution to apply a protective film is potential introduction of liquid into an electronic device, for example, through the apertures for the speaker or head set jack.
  • liquid entering an interior housing of a device may cause a device to fail.
  • device manufacturers commonly include moisture sensitive indicators within their devices to help diagnose device failure.
  • a manufacturer will void a device's warranty where inspection of a device and its moisture indicators show exposure to moisture.
  • a screen protector for protecting a screen of an electronic device.
  • the screen protector may include a protective film, a tab, an adhesive layer, and a backing layer.
  • the protective film may include a first major surface, a second major surface opposite the first major surface, and an edge.
  • the tab may extend from the edge of the protective film and be sized to form a grab handle for positioning the protective film relative to the screen of the electronic device during installation of the protective film onto the screen of the electronic device.
  • the tab may be removable from the protective film after the positioning and the installation of the protective film onto the screen of the electronic device.
  • the adhesive layer may be on the first major surface of the protective film and include an adhesive having tack sufficient to adhere the first major surface of the protective film to the screen of the electronic device and permit repositioning of the protective film during the installation of the protective film onto the screen of the electronic device.
  • the backing layer may cover the adhesive layer to protect the adhesive of the adhesive layer prior to the installation of the protective film onto of the screen of the electronic device.
  • the backing layer may be removable from the adhesive layer prior to the installation to expose the adhesive to the screen of the electronic device.
  • the adhesive layer comprises a pressure-sensitive adhesive.
  • the pressure-sensitive adhesive may include a copolymer comprising an acrylate polymer and a silicone macromer.
  • the method includes diffusing air bubbles through the protective film.
  • the method may include applying the pressure with a smoothing device.
  • the pressure may be applied to an exposed surface of a cap sheet, the cap sheet disposed on the second major surface of the protective film.
  • the method includes removing the cap sheet to expose the second major surface of the protective film.
  • the method includes repositioning the protective film.
  • the contacting step may include holding the protective adhesive film by at least one tab extending from the film.
  • the method includes removing the at least one tab from the polyurethane sheet.
  • an electronic device comprises a display surface and a protective film disposed on the display surface.
  • An adhesive layer is disposed between and in contact with at least a portion of a first major surface of the protective film and the display surface.
  • the protective film may adhere to the device without application of any liquid or solvent.
  • the electronic device further includes a bezel that is aligned along each edge of the display and a housing having a plurality of corners and sides, wherein the display surface may be disposed on the housing.
  • a second protective film may be disposed on each corner of the housing, and/or a third protective film may be disposed on the bezel.
  • a second adhesive layer may be disposed between and in contact with at least a portion of a first major surface of the second protective film and each corner of the housing.
  • a third adhesive layer may be disposed between and in contact with at least a portion of a first major surface of the third protective film and the bezel.
  • the second and third protective films adhere to the device without application of any liquid or solvent.
  • the protective film comprises polyurethane. In some embodiments, at least a portion of a second major surface of the protective film may include a micro-matte surface structure. In some embodiments, no air bubbles are visible beneath the surface of the protective adhesive film. In some embodiments, the protective film is air permeable.
  • the adhesive may include an acrylate polymer and a silicone macromer.
  • a protective adhesive film in yet another aspect, includes a polyurethane sheet and an adhesive layer disposed on at least a portion of a first major surface of the polyurethane sheet.
  • the adhesive layer includes a pressure-sensitive adhesive that comprises a copolymer comprising an acrylate polymer and a silicone macromer.
  • the protective adhesive film is configured to adhere to a display of an electronic device without the application of any liquid to the adhesive layer or the device.
  • the polyurethane sheet may be between about 75 microns and about 400 microns in thickness.
  • the polyurethane sheet comprises a polycaprolactone-based aliphatic thermoplastic urethane.
  • at least a portion of a second major surface of the polyurethane sheet comprises a micro-matte surface structure.
  • the protective adhesive film includes at least one tab extending from the polyurethane sheet.
  • a cap sheet is disposed on a second major surface of the polyurethane sheet.
  • the adhesive layer is between about 12 microns and about 75 microns in thickness.
  • the adhesive may include a copolymer of the acrylate polymer and a silicone macromer side chain.
  • FIG. 1 illustrates an exemplary adhesive film and a step for applying an adhesive film to an electronic device.
  • FIG. 2 illustrates an exemplary additional step for applying an adhesive film to an electronic device.
  • FIG. 3 illustrates an exemplary additional step for applying an adhesive film to an electronic device.
  • FIG. 4 illustrates an exemplary additional step for applying an adhesive film to an electronic device.
  • FIG. 5 illustrates an exemplary step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • FIG. 6 an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • FIG. 7 illustrates an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • FIG. 8 illustrates an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • a protective film comprising an adhesive layer (e.g., a pressure-sensitive adhesive layer) may be adhered to a device surface without the use of an aqueous solution to remove trapped air bubbles. Instead, trapped air bubbles are removed by applying pressure across the film surface to mechanically eliminate large (e.g., greater than 2-3 mm in diameter) air bubbles, while permitting smaller air bubbles to be eliminated over time.
  • the adhesive film may be disposed on a first major surface of the protective adhesive film.
  • major surface refers to a planar surface of a sheet or layer of a film. In general, a sheet will have two opposing major surfaces.
  • a protective film may comprise a polyurethane sheet, e.g., a polycaprolactone-based aliphatic thermoplastic urethane sheet.
  • a first major surface of a polyurethane sheet may be coated with one or more layers of a pressure-sensitive adhesive, such as a copolymer comprising an acrylate polymer and a silicone macromer.
  • the protective film is a polycaprolactone-based aliphatic thermoplastic urethane and comprises an adhesive layer consisting essentially of a copolymer of an acrylate polymer and silicone macromer side chains.
  • a micro-matte surface structure may be formed on at least a second major surface of the sheet, as described herein.
  • a protective film may comprise a polyurethane sheet, e.g., a polycaprolactone-based aliphatic thermoplastic urethane sheet.
  • the sheet may be coated on one side with a micro-matte layer, as described herein.
  • the protective adhesive film may comprise a polyurethane sheet, e.g., an aliphatic polyester urethane-based sheet, e.g., a polycaprolactone based aliphatic thermoplastic urethane sheet, coated on all or part of a first major surface (or “backed”) with an adhesive layer.
  • the adhesive layer is a pressure-sensitive adhesive layer.
  • the pressure-sensitive adhesive layer (or coating) may be a copolymer comprising an acrylate polymer and a silicone macromer.
  • an adhesive layer thickness may be about 10 to about 100 microns, about 12 to about 75 microns, about 25 to about 38 microns, about 30 microns, or about 35 microns.
  • the pressure-sensitive adhesive layer may comprise an acrylate-silicone copolymer based pressure-sensitive adhesive.
  • the adhesive layer may comprise additional components, e.g., a tackifier or plasticizer, and may be a self-healing adhesive.
  • the adhesive layer may be formed without the use of a cross-linker or photo-initiator.
  • the adhesive layer may be prepared using a thermal cure process.
  • the adhesive layer is made of an adhesive that does not immediately firmly secure the film to a device and thus allows for slight repositionability of the film after placement on the device.
  • the adhesive layer may include an amount of silicone to permit repositionability.
  • unpolymerized silicone, tackifier, or other low molecular weight components are included in the adhesive layer and migrate into the polyurethane sheet and modify its characteristics.
  • a polyurethane sheet comprising an adhesive layer may be made more flexible or more impact resistant by the interaction with one or more such components from an adhesive.
  • the adhesive layer comprises a polyacrylate-based pressure-sensitive adhesive layer, having silicone macromer side chain modifications of one or more acrylate ester groups.
  • the adhesive layer may be prepared from or comprise acrylic acid, methacrylic acid, esters of acrylic acid comprising 4 to 21 carbon atoms, esters of methacrylic acid comprising 5 to 21 carbon atoms, acrylamide, substituted acrylamides such as N,N-dimethyl acrylamide, styrene, substituted styrenes such as vinyl toluene, acrylonitrile, methacrylonitrile, N-vinyl pyrrolidone, N-vinyl caprolactam, vinylidene chloride, vinyl esters of carboxylic acids, 2-(2-ethoxyethoxy)ethyl acrylate, 2-ethylhexyl acrylate, butyl acrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, 2-carboxy
  • the protective film may have a thick ness from about 75 microns up to about 400 microns.
  • the protective adhesive films used may have thicknesses including about 75 microns, about 100 microns, about 150 microns, about 175 microns, about 200 microns, about 250 microns, about 300 microns, or about 350 microns. Different thicknesses may be used for different parts of a device.
  • an electronic device may use a 150 micron film for the device's optical screen and a 300 micron fi Im for the device's body.
  • Such films may provide scratch resistance, impact resistance, or both, and may provide higher impact resistance to the parts of the device that are most likely to need it, while preserving the sensitivity and/or clarity of portions of the device that are less likely to require impact resistance.
  • the protective adhesive film to be adhered to a device optical screen may have a shore hard ness of between about 85A and 99A, or between about 50D and 75D to provide a strong film with a flat surface with minimal or no surface distortion (e.g., “orange peel”). In some embodiments, the shore hardness of the protective adhesive film is about 60D or about 93A.
  • the protective adhesive film may allow for proper optical transmission and may provide a substantially smooth surface so that it best mirrors the glass surface on the device. In addition to providing an aesthetic benefit, this allows for minimal or no reduction in sensitivity and/or connectivity for touch screens.
  • the device body films may have a variety of surface types, including anti-glare, glossy, or matte, and may be optically transparent, transparent with a matte texture, translucent or opaque.
  • the film may comprise UV absorbers.
  • the films may be colored or uncolored.
  • the protective adhesive film may comprise a surface having a micro-matte structure. Surface treatments may vary over a single device, i.e., a film covering an optical screen may have an anti-glare surface while film covering a device body may have a matte surface.
  • a portion of a protective film to be adhered to the body of a device may have a matte and/or a micro-matte finish or layer which may eliminate or reduce fingerprints and adds additional “grip” to the device.
  • Suitable protective films may be manufactured by Argotec Inc. of Greenfield, Mass., or other similar manufacturing companies.
  • the adhesive coating or layer may be protected by a removable backing (e.g., prior to adhering the protective film to a device) before the protective adhesive film is adhered to a device surface.
  • a micro-matte surface structure is one that has a matte finish with an average roughness, Ra, between about 0.08 ⁇ m and about 0.22 ⁇ m, or about 0.17 ⁇ m, or about 0.135 ⁇ m.
  • a micro-matte surface structure has an average maximum height, Rz, between about 0.50 ⁇ m and about 1.20 ⁇ m, or about 1.11 ⁇ m, or about 1.23 ⁇ m.
  • a micro-matte surface structure may have an average depth, Rmax, between about 1.30 ⁇ m and about 1.50 ⁇ m, or about 1.40 ⁇ m.
  • a micro-matte protective film is prepared by extrusion of a urethane resin onto a micro-matte textured casting sheet which, in some embodiments, may be a PET multi-layer film.
  • the urethane resin forms a film that, when removed from the casting sheet, retains a micro-matte surface texture on one side (e.g., a second major surface of the protective film) that mirrors the texture of the casting sheet.
  • a film may be prepared by a single casting of urethane, rather than by addition of a micro-matte layer to a smooth urethane film.
  • a micro-matte protective film may be prepared as a co-extrusion of at least two layers.
  • a micro-matte protective film may be prepared using multiple resins of varying hardness such that its micro-matte structure may be harder and/or more durable as may be required for specific applications.
  • a micro-matte layer may be formed on a polyurethane sheet, for example, by extruding a resin onto a urethane film and contacting the resin with a micro-matte casting sheet to form a micro-matte surface texture.
  • the micro-matte protective film may comprise a pressure-sensitive adhesive layer or layers, which may be the same or similar to the pressure-sensitive adhesive layer or layers described above.
  • the micro-matte textured casting sheet is the same or different than the cap sheet described herein.
  • the micro-matte structure may cover all or part of a second major surface of a protective film.
  • a polyurethane sheet coated with a pressure-sensitive adhesive may be cut into predetermined shapes designed to fit particular portions of digital electronic devices including, but not limited to, mobile telephones, personal digital assistants, eReaders, computer notebooks, netbooks, tablets, cameras, game consoles, iPods and other MP3 players, navigation devices, and GPS devices.
  • digital electronic devices including, but not limited to, mobile telephones, personal digital assistants, eReaders, computer notebooks, netbooks, tablets, cameras, game consoles, iPods and other MP3 players, navigation devices, and GPS devices.
  • Such devices typically have a display screen and a housing.
  • the cut film pieces of the protective adhesive film may be applied to the screen and/or other portions of the digital device (such as an edge, side, corner or other portion of the housing, and/or the bezel) to protect it from damage, using methods described in this document.
  • the film may be applied to corners, edges and/or sides of the device to provide a shock-absorbing, impact-resistant skin for the device.
  • the cut film pieces may be designed such that they contain openings to correspond to various device components and thus do not block input or output ports, connections, jacks, or entry points for access to internal components of the device.
  • the cut film may be flexible, to permit its application onto curved surfaces smoothly without the appearance of gaps, wrinkles, or air bubbles.
  • the protective adhesive film includes a cap sheet (e.g., a casting film and/or a casting sheet).
  • the cap sheet may be disposed on a second major surface of the protective film.
  • the cap sheet may be formed out of a material(s) that is sufficiently rigid that the pressure applied by a mechanical smoothing device (e.g., a squeegee) does not cause the cap sheet or the protective film to deform (e.g., “orange peel”). Further, the cap sheet may withstand an increased pressure from the mechanical smoothing device, which may result in reduced air bubbles between the protective film and an electronic device. Additionally, the cap sheet may protect the second major surface of the protective film during manufacture, transport, and/or the end-user installation processes.
  • a mechanical smoothing device e.g., a squeegee
  • the secondary application/release tapes may provide an advantage over secondary application/release tapes that include a cured liquid for top coating (e.g., a polyurethane and/or an acrylic material).
  • the secondary application/release tapes include an adhesive that may roughen or distort the second major surface of the pressure adhesive layer, which may reduce the optical clarity of the protective film.
  • the cap sheet may be formed out of polyester.
  • a polyester cap sheet e.g., a laminating roll that is about 2 mils thick may have sufficient rigidity and flexibility to prevent the cap sheet and/or the protective film from deforming. Additionally, polyester may withstand the extrusion temperature of the protective film (e.g., about 320-350° F.).
  • the cap sheet may comprise polyester, polypropylene, nylon, polyimide, and similar high-temperature resistant (e.g., able to resist the temperature of the protective film extrusion, such as about 320-350° F.) and/or high melt point films e.g., a melt point greater than the temperature of the protective film extrusion, such as about 320-350° F.).
  • the cap sheet may be from about 0.92 mils (i.e., about 24 microns) to about 10 mils thick (i.e., about 254 microns). In some embodiments, the cap sheet may be about 2 mils (i.e., about 24 microns) thick.
  • the cap sheet may be embossed, brushed, or flat. In some embodiments, a micro-matte surface structure is defined in a cap sheet.
  • Suitable materials for the cap sheet and protective fi Im may include one or more of the following materials (or similar materials) manufactured by Argotec, Inc. of Greenfield, Mass. (or other polyurethane manufacturing companies): ARGOTHANE® aromatic polyethers/thermoplastic polyurethane (part numbers 17103, 17200, 18103, 18212, 18214, 18215, 18233, 18235, 18242, 18247, 18248, 18305, 18411, 18422, 18433, 18450-FR, 18452-FR), ARGOTHANE® aromatic polyesters/thermoplastic polyurethane (part numbers 19102, 19103, 19205, 19422, 19424, 19426, D7101, 27303, 27370, 28304, 29100, 29102, 29213, 29222, 29285, and/or 29300), ARGOTHANE® aliphatic polyesters (part numbers 3751 and/or AGKR), ARGOTHANE® aliphatic polycaprolactones/thermoplastic poly urethane (part number 46510) ARG
  • a surface of the cap sheet (e.g., a casting film and/or a casting sheet) has a texture (e.g., brushed, ribs, ridges, grooves, raised dots, etc.).
  • the textured surface of the cap sheet may be disposed on the second major surface of the protective film.
  • the textured surface may cause micro air pockets to fom1 between the textured surface and the second major surface of the protective film.
  • the micro air pockets are small air pockets that form in gaps between the textured surface and the second major surface of the protective film.
  • the micro air pockets may allow the cap sheet to be more easily removed from the pressure-sensitive adhesive layer (e.g., by reducing a seal caused by two substantially smooth surfaces).
  • the second major surface of the protective film may include a textured surface.
  • this may decrease the optical clarity of the protective film and, therefore, may be less desirable to the end user.
  • the cap sheet has a texture that defines a micro-matte surface on the second major surface of the protective film.
  • a mechanical smoothing device may be used to apply a pressure to an exposed surface of the cap sheet.
  • the cap sheet may allow for the use of a wider and/or more rigid mechanical smoothing device during the installation process as a result of the rigidity of the cap sheet.
  • the mechanical smoothing device may have approximately the same width as the entire electronic device (e.g., eReader, computer notebook, tablet, etc.) or a portion of the electronic device (such as a display screen) to which the protective adhesive layer is to be applied.
  • the cap sheet may be sufficiently rigid to withstand the pressure applied by the mechanical smoothing device to minimize resulting damage (e.g., distortion) to the protective adhesive film.
  • the smoothing device may be formed from a variety of materials, including a thick, heavy gauge paper (e.g., greater than about 50 mils thick, between about 50-150 mils thick, between about 50-90 mils thick, between about 50-80 mils thick, between about 60-80 mils thick, or about 70 mils thick), polyvinyl chloride acetate (PVCA), unplasticized polyvinyl chloride (uPVC), silicone rubber, ethylene propylene diene monomer (M-class) rubber (EPDM rubber), and/or other semi-rigid rubbers, and/or rigid plastics, such as rigid polyethylene (e.g., HDPE, MDPE, or LDPE), polyvinyl chloride (PVC), and/or polypropylene.
  • the smoothing device may be formed from silicone rubber and/or EPDM rubber that is about 60 to 90 Shore A durometer in hardness.
  • a wider mechanical smoothing device may provide several advantages. For example, a wider mechanical smoothing device only needs to be applied once (as it may be about the same width as a screen of an eReader, etc.), thereby decreasing installation time. Additionally, a wider mechanical smoothing device may minimize unintended skewing, repositioning and/or stretching of the protective adhesive film that may occur as a result of multiple squeegee applications (e.g., in different directions with respect to the screen of an eReader, etc.). A wider and harder mechanical smoothing device allows the user to apply an increased downward force/pressure on the cap sheet, resulting in an increased adherence of the protective adhesive film to the electronic device and/or reduced air bubbles between the protective adhesive film and the electronic device.
  • the protective film includes a body and at least one tab that extends outwardly from the body.
  • the protective film includes two tabs, for example, on opposing sides of the protective film.
  • the tabs may be positioned in the middle of each opposing side, or in any other position along the edge of the protective film.
  • the tabs may function as grab handles to allow a user to more accurately position the protective adhesive film and cap sheet on the electronic device and/or to reduce fingerprints on the protective adhesive film.
  • the tabs include perforations, allowing the user to more easily remove the tabs after installation.
  • FIG. 1 illustrates an exemplary first step for applying an adhesive film (e.g., a protective adhesive film and/or a micro-matte protective film) to an electronic device.
  • an adhesive film e.g., a protective adhesive film and/or a micro-matte protective film
  • a portion of a backing layer 20 is removed from an adhesive film 10 to expose an adhesive area 30 .
  • the adhesive area 30 is disposed on at least a port ion of a first major surface 40 of the protective adhesive film 10 .
  • the adhesive film 10 may be modified by cutting (e.g., by die cutting, plotter cutting, or other methods) to create segments matched in size and shape to chosen surface areas on a particular device to be protected.
  • the adhesive film 10 may be pre-cut to match a desired area on an electronic device.
  • the adhesive area 30 may be positioned to contact and align with an exposed surface portion 50 of an electronic device 60 (e.g., a display surface).
  • the exposed surface portion 50 may be a small, large, or an entire portion of an exposed surface 70 of the electronic device 60 .
  • the adhesive film 10 and/or the adhesive area 30 are aligned to the electronic device 60 (e.g., aligned to the surface portion 50 , e.g., an edge of the exposed surface 70 ).
  • openings 75 in the adhesive film 10 may be aligned to corresponding components 65 (e.g., input and/or output ports, buttons, etc.) of the electronic device 60 .
  • At least a portion of the exposed surface 70 of the electronic device may be cleaned, for example, by rubbing or polishing the at least a portion of exposed surface 70 with a dry tissue or towelette.
  • the film 10 (e.g., a protective adhesive fi Im and/or a micro-matte protective film) may be applied to the electronic device 60 “as is.” There is no need to apply any liquid or other additive to any portion of the exposed surface 70 or the adhesive area 30 at any time during the process.
  • the backing layer 20 is completely removed from the first major surface 40 of the film 10 , and the remaining adhesive area 30 of the film 10 is aligned to contact the device 60 .
  • a mechanical smoothing device 100 may be used to apply a pressure to the second major surface 90 of the film 10 .
  • the pressure may cause the adhesive area 30 to press against the exposed surface portion 50 of the electronic device 20 .
  • the mechanical smoothing device 100 applies the pressure from a central area 105 to an edge 110 of the second major surface 90 continuing in different radial directions from the central area 105 across the second major surface 90 .
  • the mechanical smoothing device 100 applies the pressure starting at or near a trapped air pocket or an air bubble and continues to an edge 110 . Any haze or remaining trapped air bubbles, if less than about 2-3 mm in diameter, may be left to diffuse out through the protective adhesive film 10 (e.g., an air-permeable film), generally disappearing within 24 hours.
  • the method may include repositioning the film 10 (e.g., a protective adhesive film and/or a micro-matte protective fi Im) after it has been adhered to the exposed surface portion 50 of the device 20 .
  • the method may include lifting a portion of the fi Im 10 away from the exposed surface portion 50 of the device 20 and reapplying (e.g., re-contacting) the portion to the exposed surface portion 50 of the device 20 , which may be helpful in repositioning and/or re-aligning the film 10 and/or in removing air bubbles.
  • additional mechanical smoothing e.g., by hand or with a mechanical device may be used to ensure that the film 10 is adhered to the edges 110 of the device 20 .
  • FIGS. 5-8 illustrate an alternative procedure that may be used for larger electronic devices, such as tablets, notebooks, and notebooks.
  • the protective adhesive film includes a cap sheet layer (e.g., a casting film and/or a casting sheet).
  • a portion of a backing layer 420 is removed from an adhesive film 410 to expose an adhesive area 430 .
  • the adhesive film 410 is a micro-matte protective adhesive film.
  • the adhesive area 430 is disposed on at least a portion of a first major surface 440 of the protective adhesive film 410 .
  • a cap sheet 510 is disposed on a second major surface of the protective adhesive film 410 .
  • the film 410 Prior to removing the backing layer 420 , the film 410 , together with the cap sheet 510 as one piece or separately from the cap sheet 510 , may be shaped by cutting (e.g., by die cutting, plotter cutting, or other methods) to create segments, with a cap sheet 510 layered on the adhesive film 410 , matched in size and shape to chosen surface areas on a particular device to be protected.
  • the protective adhesive film 410 and cap sheet 510 may be pre-cut to match a desired area on an electronic device.
  • FIG. 6 illustrates that the adhesive area 430 may be contacted to an exposed surface portion 40 of an electronic device 460 (e.g., a display surface).
  • the exposed surface portion 450 may be any portion of exposed surface 470 including the entire exposed surface 470 .
  • the adhesive film 410 and/or the adhesive area 430 may be positioned to contact and align with an exposed surface portion 450 of the electronic device 460 .
  • openings 475 in the adhesive film 410 may be aligned to corresponding components 465 (e.g., input and/or output ports, buttons, etc.) of the electronic device 460 .
  • at least one optional tab 415 extends from the adhesive film 410 .
  • a user may hold the at least one optional tab 415 while positioning, contacting, and/or aligning the adhesive area 430 to the exposed surface portion 450 of the electronic device 460 .
  • at least a portion of exposed surface 470 of the electronic device may be cleaned, for example, by rubbing or polishing the at least a portion of exposed surface 470 with a dry tissue or towelette.
  • no liquid or other additive is applied to the adhesive film 410 , the adhesive area 430 , and/or the electronic device 460 .
  • a mechanical smoothing device 500 (e.g., a squeegee, oversized squeegee, a device having a resilient edge, or a hand) may be used to apply a pressure to the cap sheet 510 disposed on a second major surface 490 of the film 410 .
  • the pressure may causes the adhesive area 430 to press against the exposed surface portion 450 of the electronic device 460 (as depicted in FIG. 6 ).
  • the mechanical smoothing device 500 may be applied starting at an edge 515 of the electronic device 420 and proceeding across the width 520 of the electronic device 420 .
  • An optional second mechanical smoothing step may be applied in the opposite direction of the first mechanical smoothing step.
  • the cap sheet 510 is removed (e.g., peeled off) to expose the second major surface 490 of the film 410 , as illustrated in FIG. 8 .
  • Any haze or remaining trapped air bubbles if less than about 2-3 mm in diameter, may be left to diffuse out through the protective adhesive film 410 (e.g., an air-impermeable film), generally disappearing within 24 hours.
  • air bubbles may diffuse into the first major surface 440 of the film 410 and out the second major surface 490 of the film 410 .
  • the optional hold tabs 415 may be removed from the film 410 by pulling along optional perforations (not shown) or by cutting off the hold tabs 415 .
  • the method improves the adherence of the film to the surface of the device, and provides a higher quality (e.g., less damaged, more transparent, and/or more accurately placed) protective film.
  • the method further reduces the number of remaining trapped air bubbles.
  • the method further reduces the installation time of applying a protective film to an electronic device.

Abstract

A screen protector for a screen of an electronic device is provided. The screen protector may include a protective film, a tab, an adhesive layer, and a backing layer. The protective film may include major surfaces and an edge. The tab may be removable and may extend from the edge of the protective film to form a grab handle for positioning the protective film. The adhesive layer may be on a first major surface of the protective film and include an adhesive having tack sufficient to permit repositioning of the protective film during installation of the protective film onto the screen. The backing layer may cover the adhesive layer to protect the adhesive prior to the installation of the protective film onto of the screen. The backing layer may be removable from the adhesive layer prior to the installation to expose the adhesive to the screen.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • This application is a continuation of application Ser. No. 13/624,499, entitled “Protective Adhesive Film, Method of Adhering Protective Adhesive Film to a Device, and Device Comprising Protective Adhesive Film,” filed Sep. 21, 2012, which is a division of application Ser. No. 13/044,275, “Protective Adhesive Film, Method of Adhering Protective Adhesive Film to a Device, and Device Comprising Protective Adhesive Film,” filed Mar. 9, 2011, which claims priority to each of: U.S. Provisional Application No. 61/313,363, entitled “Method of Adhering a Protective Adhesive Film to a Device and Device Comprising Protective Adhesive Film,” filed on Mar. 12, 2010; U.S. Provisional Application No. 61/316,185, entitled “Protective Adhesive Film, Method of Adhering Protective Adhesive Film to a Device and Device Comprising Protective Adhesive Film,” filed on Mar. 22, 2010; U.S. Provisional Application No. 61/359,690, entitled “Micro-Matte Protective Film, Method of Adhering Micro-Matte Protective Film to a Device and Device Comprising Micro-Matte Protective Film,” filed on Jun. 29, 2010; and U.S. Provisional Application No. 61/440,708, entitled “Protective Adhesive Film, Method of Adhering Protective Adhesive Film to a Device and Device Comprising Protective Adhesive Film,” filed on Feb. 8, 2011. The contents of all of the applications listed above are expressly incorporated by reference herein in their entireties.
  • BACKGROUND
  • The present invention relates generally to methods of applying protective films to electronic device surfaces and to devices comprising protective films.
  • Protective films are used to cover and protect a variety of materials and devices from, for example, scratches or dents that may be imparted during transport or use of the device. Protective films may be used to protect, for example, the surface of digital electronic device components during manufacture, or may be adhered to a completed device to protect it from damage during normal day-to-day use. A variety of protective films are known, each having properties that may be advantageous for some uses and disadvantageous for other uses. One form of protective film used in the art is coated on one side with a layer of a dry pressure-sensitive adhesive that has sufficient tack to form a secure contact with the device while permitting slight repositioning of the film after adherence. Protective films are often transparent, and may permit the use of touch-sensitive features of the electronic device through the film.
  • Typically, when a dry protective film, particularly a protective film having an adhesive layer, is applied to a surface, air is easily trapped between a device surface and the film during application, causing the appearance of bubbles. Bubbles are undesirable for aesthetic reasons but also because their presence over an optical screen distorts images on a screen viewed by a device user. Prior methods of eliminating trapped air bubbles beneath protective films utilize an aqueous solution or other solvent to temporarily reduce adherence between a film and a device, permitting trapped air to be forced out by mechanical pressure. Known methods, for example, include spraying a protective film (or device surface) with water or another liquid, applying the wet film to the device surface to be protected (or applying the film to the wet device surface), and using pressure (e.g., with a squeegee) to smooth the film and force out any trapped air bubbles. In doing so, the water or other liquid is also forced out from between the film and the device surface, and collects at an edge of the film.
  • Thus, prior methods required introduction of a liquid to the outer surface of a device, requiring a user to take additional steps to remove liquid after a film is applied to a device. A significant disadvantage to using a wet solution to apply a protective film is potential introduction of liquid into an electronic device, for example, through the apertures for the speaker or head set jack. In some cases, liquid entering an interior housing of a device may cause a device to fail. For this reason, device manufacturers commonly include moisture sensitive indicators within their devices to help diagnose device failure. In some cases, a manufacturer will void a device's warranty where inspection of a device and its moisture indicators show exposure to moisture.
  • Another drawback of many protective films is the high visibility of fingerprints, smudges, or other marks on the film, resulting, for example, from handling of a device. In particular, visibility of fingerprints or other marks on films covering electronic device bodies or display screens is aesthetically and functionally undesirable. A visible residue over a display screen, for example, may distort the transmission of light from the screen resulting in distortion of an image viewed on the screen. Matte surface treatments have been used to address this problem, but the application of typical matte surfaces over an optical screen reduces optical transmission.
  • SUMMARY
  • In one embodiment, a screen protector for protecting a screen of an electronic device is provided. The screen protector may include a protective film, a tab, an adhesive layer, and a backing layer. The protective film may include a first major surface, a second major surface opposite the first major surface, and an edge. The tab may extend from the edge of the protective film and be sized to form a grab handle for positioning the protective film relative to the screen of the electronic device during installation of the protective film onto the screen of the electronic device. The tab may be removable from the protective film after the positioning and the installation of the protective film onto the screen of the electronic device. The adhesive layer may be on the first major surface of the protective film and include an adhesive having tack sufficient to adhere the first major surface of the protective film to the screen of the electronic device and permit repositioning of the protective film during the installation of the protective film onto the screen of the electronic device. The backing layer may cover the adhesive layer to protect the adhesive of the adhesive layer prior to the installation of the protective film onto of the screen of the electronic device. The backing layer may be removable from the adhesive layer prior to the installation to expose the adhesive to the screen of the electronic device.
  • In some embodiments, the adhesive layer comprises a pressure-sensitive adhesive. The pressure-sensitive adhesive may include a copolymer comprising an acrylate polymer and a silicone macromer. In some embodiments, the method includes diffusing air bubbles through the protective film.
  • The method may include applying the pressure with a smoothing device. In some embodiments, the pressure may be applied to an exposed surface of a cap sheet, the cap sheet disposed on the second major surface of the protective film. In some embodiments, after applying the pressure to the exposed surface of the cap sheet, the method includes removing the cap sheet to expose the second major surface of the protective film. In some embodiments, after the pressure is applied to the second major surface of the protective film, the method includes repositioning the protective film.
  • The contacting step may include holding the protective adhesive film by at least one tab extending from the film. In some embodiments, after holding the protective adhesive film by the at least one tab extending from the film, the method includes removing the at least one tab from the polyurethane sheet.
  • In another general aspect, an electronic device comprises a display surface and a protective film disposed on the display surface. An adhesive layer is disposed between and in contact with at least a portion of a first major surface of the protective film and the display surface. The protective film may adhere to the device without application of any liquid or solvent.
  • In some embodiments, the electronic device further includes a bezel that is aligned along each edge of the display and a housing having a plurality of corners and sides, wherein the display surface may be disposed on the housing. A second protective film may be disposed on each corner of the housing, and/or a third protective film may be disposed on the bezel. A second adhesive layer may be disposed between and in contact with at least a portion of a first major surface of the second protective film and each corner of the housing. A third adhesive layer may be disposed between and in contact with at least a portion of a first major surface of the third protective film and the bezel. In some embodiments, the second and third protective films adhere to the device without application of any liquid or solvent.
  • In some embodiments, the protective film comprises polyurethane. In some embodiments, at least a portion of a second major surface of the protective film may include a micro-matte surface structure. In some embodiments, no air bubbles are visible beneath the surface of the protective adhesive film. In some embodiments, the protective film is air permeable. The adhesive may include an acrylate polymer and a silicone macromer.
  • In yet another aspect, a protective adhesive film includes a polyurethane sheet and an adhesive layer disposed on at least a portion of a first major surface of the polyurethane sheet. The adhesive layer includes a pressure-sensitive adhesive that comprises a copolymer comprising an acrylate polymer and a silicone macromer. In some embodiments, the protective adhesive film is configured to adhere to a display of an electronic device without the application of any liquid to the adhesive layer or the device.
  • The polyurethane sheet may be between about 75 microns and about 400 microns in thickness. In some embodiments, the polyurethane sheet comprises a polycaprolactone-based aliphatic thermoplastic urethane. In some embodiments, at least a portion of a second major surface of the polyurethane sheet comprises a micro-matte surface structure. In some embodiments, the protective adhesive film includes at least one tab extending from the polyurethane sheet. In some embodiments, a cap sheet is disposed on a second major surface of the polyurethane sheet.
  • In some embodiments, the adhesive layer is between about 12 microns and about 75 microns in thickness. The adhesive may include a copolymer of the acrylate polymer and a silicone macromer side chain.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 illustrates an exemplary adhesive film and a step for applying an adhesive film to an electronic device.
  • FIG. 2 illustrates an exemplary additional step for applying an adhesive film to an electronic device.
  • FIG. 3 illustrates an exemplary additional step for applying an adhesive film to an electronic device.
  • FIG. 4 illustrates an exemplary additional step for applying an adhesive film to an electronic device.
  • FIG. 5 illustrates an exemplary step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • FIG. 6 an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • FIG. 7 illustrates an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • FIG. 8 illustrates an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.
  • DETAILED DESCRIPTION
  • As used in the description below and in the appended claims, the singular forms “a,” “an,” and “the” include plural references unless the context clearly dictates otherwise. Unless defined otherwise, all technical and scientific terms used in this document have the same meanings as commonly understood by one of ordinary skill in the art. As used in this document, the term “comprising” means “including, but not limited to.” As used herein, the term “about,” when referring to a value, means plus or minus 10% of the value.
  • This disclosure is not limited to the particular systems, devices and methods described, as these may vary. Also, the terminology used in this document is only for the purpose of describing particular versions or embodiments, and it is not intended to limit the scope.
  • Devices and methods are disclosed that avoid the need for an aqueous solution or other liquid in applying a protective adhesive film to an electronic device and removing trapped air bubbles. As described herein, a protective film comprising an adhesive layer (e.g., a pressure-sensitive adhesive layer) may be adhered to a device surface without the use of an aqueous solution to remove trapped air bubbles. Instead, trapped air bubbles are removed by applying pressure across the film surface to mechanically eliminate large (e.g., greater than 2-3 mm in diameter) air bubbles, while permitting smaller air bubbles to be eliminated over time. The adhesive film may be disposed on a first major surface of the protective adhesive film. As used in the document, the term “major surface” refers to a planar surface of a sheet or layer of a film. In general, a sheet will have two opposing major surfaces.
  • In some embodiments, a protective film may comprise a polyurethane sheet, e.g., a polycaprolactone-based aliphatic thermoplastic urethane sheet. A first major surface of a polyurethane sheet may be coated with one or more layers of a pressure-sensitive adhesive, such as a copolymer comprising an acrylate polymer and a silicone macromer. In some embodiments, the protective film is a polycaprolactone-based aliphatic thermoplastic urethane and comprises an adhesive layer consisting essentially of a copolymer of an acrylate polymer and silicone macromer side chains. A micro-matte surface structure may be formed on at least a second major surface of the sheet, as described herein. In another embodiment, a protective film may comprise a polyurethane sheet, e.g., a polycaprolactone-based aliphatic thermoplastic urethane sheet. The sheet may be coated on one side with a micro-matte layer, as described herein.
  • The protective adhesive film may comprise a polyurethane sheet, e.g., an aliphatic polyester urethane-based sheet, e.g., a polycaprolactone based aliphatic thermoplastic urethane sheet, coated on all or part of a first major surface (or “backed”) with an adhesive layer. In some embodiments, the adhesive layer is a pressure-sensitive adhesive layer. The pressure-sensitive adhesive layer (or coating) may be a copolymer comprising an acrylate polymer and a silicone macromer. In some embodiments, an adhesive layer thickness may be about 10 to about 100 microns, about 12 to about 75 microns, about 25 to about 38 microns, about 30 microns, or about 35 microns. The pressure-sensitive adhesive layer (or coating) may comprise an acrylate-silicone copolymer based pressure-sensitive adhesive. The adhesive layer may comprise additional components, e.g., a tackifier or plasticizer, and may be a self-healing adhesive. The adhesive layer may be formed without the use of a cross-linker or photo-initiator. The adhesive layer may be prepared using a thermal cure process. In some embodiments, the adhesive layer is made of an adhesive that does not immediately firmly secure the film to a device and thus allows for slight repositionability of the film after placement on the device. For example, the adhesive layer may include an amount of silicone to permit repositionability. In some embodiments, unpolymerized silicone, tackifier, or other low molecular weight components are included in the adhesive layer and migrate into the polyurethane sheet and modify its characteristics. A polyurethane sheet comprising an adhesive layer may be made more flexible or more impact resistant by the interaction with one or more such components from an adhesive.
  • In some embodiments, the adhesive layer comprises a polyacrylate-based pressure-sensitive adhesive layer, having silicone macromer side chain modifications of one or more acrylate ester groups. In some embodiments, the adhesive layer may be prepared from or comprise acrylic acid, methacrylic acid, esters of acrylic acid comprising 4 to 21 carbon atoms, esters of methacrylic acid comprising 5 to 21 carbon atoms, acrylamide, substituted acrylamides such as N,N-dimethyl acrylamide, styrene, substituted styrenes such as vinyl toluene, acrylonitrile, methacrylonitrile, N-vinyl pyrrolidone, N-vinyl caprolactam, vinylidene chloride, vinyl esters of carboxylic acids, 2-(2-ethoxyethoxy)ethyl acrylate, 2-ethylhexyl acrylate, butyl acrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, 2-carboxyethyl acrylate, ethoxyethyl acrylate, perfluorooctyl acrylate, isooctyl acrylate, divinylbenzene, vinylbenzyl chloride, vinyl acetate, glycidyl methacylate, hydroethyl acetate, hydroxypropyl acetate, glacial acrylic acid, methyl acrylate, ethyl acrylate, butyl acrylate, isobutyl acrylate or other acrylates, or combinations thereof. In some embodiments, the pressure-sensitive adhesive comprises acrylate and silicone in other polymer configurations as known in the art. Suitable pressure-sensitive adhesives may be manufactured by 3M Company of St. Paul, Minn. or other manufacturing companies.
  • The protective film may have a thick ness from about 75 microns up to about 400 microns. For example, the protective adhesive films used may have thicknesses including about 75 microns, about 100 microns, about 150 microns, about 175 microns, about 200 microns, about 250 microns, about 300 microns, or about 350 microns. Different thicknesses may be used for different parts of a device. For example, an electronic device may use a 150 micron film for the device's optical screen and a 300 micron fi Im for the device's body. Such films may provide scratch resistance, impact resistance, or both, and may provide higher impact resistance to the parts of the device that are most likely to need it, while preserving the sensitivity and/or clarity of portions of the device that are less likely to require impact resistance.
  • The protective adhesive film to be adhered to a device optical screen may have a shore hard ness of between about 85A and 99A, or between about 50D and 75D to provide a strong film with a flat surface with minimal or no surface distortion (e.g., “orange peel”). In some embodiments, the shore hardness of the protective adhesive film is about 60D or about 93A. The protective adhesive film may allow for proper optical transmission and may provide a substantially smooth surface so that it best mirrors the glass surface on the device. In addition to providing an aesthetic benefit, this allows for minimal or no reduction in sensitivity and/or connectivity for touch screens.
  • The device body films may have a variety of surface types, including anti-glare, glossy, or matte, and may be optically transparent, transparent with a matte texture, translucent or opaque. The film may comprise UV absorbers. The films may be colored or uncolored. In some embodiments, the protective adhesive film may comprise a surface having a micro-matte structure. Surface treatments may vary over a single device, i.e., a film covering an optical screen may have an anti-glare surface while film covering a device body may have a matte surface. A portion of a protective film to be adhered to the body of a device (portions not including the optical screen), the optical screen, or both may have a matte and/or a micro-matte finish or layer which may eliminate or reduce fingerprints and adds additional “grip” to the device. Suitable protective films may be manufactured by Argotec Inc. of Greenfield, Mass., or other similar manufacturing companies. In some embodiments, the adhesive coating or layer may be protected by a removable backing (e.g., prior to adhering the protective film to a device) before the protective adhesive film is adhered to a device surface.
  • A micro-matte surface structure is one that has a matte finish with an average roughness, Ra, between about 0.08 μm and about 0.22 μm, or about 0.17 μm, or about 0.135 μm. In some embodiments, a micro-matte surface structure has an average maximum height, Rz, between about 0.50 μm and about 1.20 μm, or about 1.11 μm, or about 1.23 μm. A micro-matte surface structure may have an average depth, Rmax, between about 1.30 μm and about 1.50 μm, or about 1.40 μm.
  • In some embodiments, a micro-matte protective film is prepared by extrusion of a urethane resin onto a micro-matte textured casting sheet which, in some embodiments, may be a PET multi-layer film. The urethane resin forms a film that, when removed from the casting sheet, retains a micro-matte surface texture on one side (e.g., a second major surface of the protective film) that mirrors the texture of the casting sheet. Thus, a film may be prepared by a single casting of urethane, rather than by addition of a micro-matte layer to a smooth urethane film. Alternatively, a micro-matte protective film may be prepared as a co-extrusion of at least two layers. Accordingly, a micro-matte protective film may be prepared using multiple resins of varying hardness such that its micro-matte structure may be harder and/or more durable as may be required for specific applications. Alternatively, a micro-matte layer may be formed on a polyurethane sheet, for example, by extruding a resin onto a urethane film and contacting the resin with a micro-matte casting sheet to form a micro-matte surface texture. The micro-matte protective film may comprise a pressure-sensitive adhesive layer or layers, which may be the same or similar to the pressure-sensitive adhesive layer or layers described above. In some embodiments, the micro-matte textured casting sheet is the same or different than the cap sheet described herein. The micro-matte structure may cover all or part of a second major surface of a protective film.
  • In some embodiments, a polyurethane sheet coated with a pressure-sensitive adhesive (e.g., to create a protective adhesive film) may be cut into predetermined shapes designed to fit particular portions of digital electronic devices including, but not limited to, mobile telephones, personal digital assistants, eReaders, computer notebooks, netbooks, tablets, cameras, game consoles, iPods and other MP3 players, navigation devices, and GPS devices. Such devices typically have a display screen and a housing. The cut film pieces of the protective adhesive film may be applied to the screen and/or other portions of the digital device (such as an edge, side, corner or other portion of the housing, and/or the bezel) to protect it from damage, using methods described in this document. In some embodiments, the film may be applied to corners, edges and/or sides of the device to provide a shock-absorbing, impact-resistant skin for the device. The cut film pieces may be designed such that they contain openings to correspond to various device components and thus do not block input or output ports, connections, jacks, or entry points for access to internal components of the device. The cut film may be flexible, to permit its application onto curved surfaces smoothly without the appearance of gaps, wrinkles, or air bubbles.
  • In some embodiments, the protective adhesive film includes a cap sheet (e.g., a casting film and/or a casting sheet). The cap sheet may be disposed on a second major surface of the protective film. The cap sheet may be formed out of a material(s) that is sufficiently rigid that the pressure applied by a mechanical smoothing device (e.g., a squeegee) does not cause the cap sheet or the protective film to deform (e.g., “orange peel”). Further, the cap sheet may withstand an increased pressure from the mechanical smoothing device, which may result in reduced air bubbles between the protective film and an electronic device. Additionally, the cap sheet may protect the second major surface of the protective film during manufacture, transport, and/or the end-user installation processes. This may provide an advantage over secondary application/release tapes that include a cured liquid for top coating (e.g., a polyurethane and/or an acrylic material). The secondary application/release tapes include an adhesive that may roughen or distort the second major surface of the pressure adhesive layer, which may reduce the optical clarity of the protective film.
  • The cap sheet may be formed out of polyester. A polyester cap sheet (e.g., a laminating roll) that is about 2 mils thick may have sufficient rigidity and flexibility to prevent the cap sheet and/or the protective film from deforming. Additionally, polyester may withstand the extrusion temperature of the protective film (e.g., about 320-350° F.). The cap sheet may comprise polyester, polypropylene, nylon, polyimide, and similar high-temperature resistant (e.g., able to resist the temperature of the protective film extrusion, such as about 320-350° F.) and/or high melt point films e.g., a melt point greater than the temperature of the protective film extrusion, such as about 320-350° F.). The cap sheet may be from about 0.92 mils (i.e., about 24 microns) to about 10 mils thick (i.e., about 254 microns). In some embodiments, the cap sheet may be about 2 mils (i.e., about 24 microns) thick. The cap sheet may be embossed, brushed, or flat. In some embodiments, a micro-matte surface structure is defined in a cap sheet.
  • Suitable materials for the cap sheet and protective fi Im may include one or more of the following materials (or similar materials) manufactured by Argotec, Inc. of Greenfield, Mass. (or other polyurethane manufacturing companies): ARGOTHANE® aromatic polyethers/thermoplastic polyurethane (part numbers 17103, 17200, 18103, 18212, 18214, 18215, 18233, 18235, 18242, 18247, 18248, 18305, 18411, 18422, 18433, 18450-FR, 18452-FR), ARGOTHANE® aromatic polyesters/thermoplastic polyurethane (part numbers 19102, 19103, 19205, 19422, 19424, 19426, D7101, 27303, 27370, 28304, 29100, 29102, 29213, 29222, 29285, and/or 29300), ARGOTHANE® aliphatic polyesters (part numbers 3751 and/or AGKR), ARGOTHANE® aliphatic polycaprolactones/thermoplastic poly urethane (part number 46510) ARGOTHANE® waterproof breathable films/thermoplastic polyurethane (part numbers TX1540 and/or TX2060), ARGOFLEX® waterproof-breathable films/thermoplastic polyurethane (part numbers TX1300, TX1500, and/or TX2000), and/or ARGOTEC® film no. 49522.
  • In some embodiments, at least a portion of a surface of the cap sheet (e.g., a casting film and/or a casting sheet) has a texture (e.g., brushed, ribs, ridges, grooves, raised dots, etc.). The textured surface of the cap sheet may be disposed on the second major surface of the protective film. The textured surface may cause micro air pockets to fom1 between the textured surface and the second major surface of the protective film. The micro air pockets are small air pockets that form in gaps between the textured surface and the second major surface of the protective film. The micro air pockets may allow the cap sheet to be more easily removed from the pressure-sensitive adhesive layer (e.g., by reducing a seal caused by two substantially smooth surfaces). In the alternative, the second major surface of the protective film may include a textured surface. However, this may decrease the optical clarity of the protective film and, therefore, may be less desirable to the end user. In some embodiments, the cap sheet has a texture that defines a micro-matte surface on the second major surface of the protective film.
  • A mechanical smoothing device may be used to apply a pressure to an exposed surface of the cap sheet. The cap sheet may allow for the use of a wider and/or more rigid mechanical smoothing device during the installation process as a result of the rigidity of the cap sheet. For example, the mechanical smoothing device may have approximately the same width as the entire electronic device (e.g., eReader, computer notebook, tablet, etc.) or a portion of the electronic device (such as a display screen) to which the protective adhesive layer is to be applied. Additionally, the cap sheet may be sufficiently rigid to withstand the pressure applied by the mechanical smoothing device to minimize resulting damage (e.g., distortion) to the protective adhesive film. The smoothing device may be formed from a variety of materials, including a thick, heavy gauge paper (e.g., greater than about 50 mils thick, between about 50-150 mils thick, between about 50-90 mils thick, between about 50-80 mils thick, between about 60-80 mils thick, or about 70 mils thick), polyvinyl chloride acetate (PVCA), unplasticized polyvinyl chloride (uPVC), silicone rubber, ethylene propylene diene monomer (M-class) rubber (EPDM rubber), and/or other semi-rigid rubbers, and/or rigid plastics, such as rigid polyethylene (e.g., HDPE, MDPE, or LDPE), polyvinyl chloride (PVC), and/or polypropylene. For example, the smoothing device may be formed from silicone rubber and/or EPDM rubber that is about 60 to 90 Shore A durometer in hardness.
  • A wider mechanical smoothing device may provide several advantages. For example, a wider mechanical smoothing device only needs to be applied once (as it may be about the same width as a screen of an eReader, etc.), thereby decreasing installation time. Additionally, a wider mechanical smoothing device may minimize unintended skewing, repositioning and/or stretching of the protective adhesive film that may occur as a result of multiple squeegee applications (e.g., in different directions with respect to the screen of an eReader, etc.). A wider and harder mechanical smoothing device allows the user to apply an increased downward force/pressure on the cap sheet, resulting in an increased adherence of the protective adhesive film to the electronic device and/or reduced air bubbles between the protective adhesive film and the electronic device.
  • In some embodiments, the protective film includes a body and at least one tab that extends outwardly from the body. In some embodiments, the protective film includes two tabs, for example, on opposing sides of the protective film. The tabs may be positioned in the middle of each opposing side, or in any other position along the edge of the protective film. The tabs may function as grab handles to allow a user to more accurately position the protective adhesive film and cap sheet on the electronic device and/or to reduce fingerprints on the protective adhesive film. In some embodiments, the tabs include perforations, allowing the user to more easily remove the tabs after installation.
  • FIG. 1 illustrates an exemplary first step for applying an adhesive film (e.g., a protective adhesive film and/or a micro-matte protective film) to an electronic device. In this step, a portion of a backing layer 20 is removed from an adhesive film 10 to expose an adhesive area 30. The adhesive area 30 is disposed on at least a port ion of a first major surface 40 of the protective adhesive film 10. Prior to removing the backing layer 20, the adhesive film 10 may be modified by cutting (e.g., by die cutting, plotter cutting, or other methods) to create segments matched in size and shape to chosen surface areas on a particular device to be protected. Alternatively, the adhesive film 10 may be pre-cut to match a desired area on an electronic device.
  • Referring to FIG. 2, after the backing layer 20 is partially or fully removed, the adhesive area 30 may be positioned to contact and align with an exposed surface portion 50 of an electronic device 60 (e.g., a display surface). In some embodiments, the exposed surface portion 50 may be a small, large, or an entire portion of an exposed surface 70 of the electronic device 60. In some embodiments, the adhesive film 10 and/or the adhesive area 30 are aligned to the electronic device 60 (e.g., aligned to the surface portion 50, e.g., an edge of the exposed surface 70). For example, openings 75 in the adhesive film 10 may be aligned to corresponding components 65 (e.g., input and/or output ports, buttons, etc.) of the electronic device 60. In some embodiments, prior to contacting the adhesive film 10 to the electronic device 60, at least a portion of the exposed surface 70 of the electronic device may be cleaned, for example, by rubbing or polishing the at least a portion of exposed surface 70 with a dry tissue or towelette.
  • The film 10 (e.g., a protective adhesive fi Im and/or a micro-matte protective film) may be applied to the electronic device 60 “as is.” There is no need to apply any liquid or other additive to any portion of the exposed surface 70 or the adhesive area 30 at any time during the process.
  • As illustrated in FIG. 3, after the film 10 is aligned to the device 60, the backing layer 20 is completely removed from the first major surface 40 of the film 10, and the remaining adhesive area 30 of the film 10 is aligned to contact the device 60.
  • Referring to FIG. 4, a mechanical smoothing device 100 (e.g., a squeegee, a device having a resilient edge, or a hand) may be used to apply a pressure to the second major surface 90 of the film 10. The pressure may cause the adhesive area 30 to press against the exposed surface portion 50 of the electronic device 20. In some embodiments, the mechanical smoothing device 100 applies the pressure from a central area 105 to an edge 110 of the second major surface 90 continuing in different radial directions from the central area 105 across the second major surface 90. In some embodiments, the mechanical smoothing device 100 applies the pressure starting at or near a trapped air pocket or an air bubble and continues to an edge 110. Any haze or remaining trapped air bubbles, if less than about 2-3 mm in diameter, may be left to diffuse out through the protective adhesive film 10 (e.g., an air-permeable film), generally disappearing within 24 hours.
  • In some embodiments, the method may include repositioning the film 10 (e.g., a protective adhesive film and/or a micro-matte protective fi Im) after it has been adhered to the exposed surface portion 50 of the device 20. For example, the method may include lifting a portion of the fi Im 10 away from the exposed surface portion 50 of the device 20 and reapplying (e.g., re-contacting) the portion to the exposed surface portion 50 of the device 20, which may be helpful in repositioning and/or re-aligning the film 10 and/or in removing air bubbles. In some embodiments, additional mechanical smoothing (e.g., by hand or with a mechanical device) may be used to ensure that the film 10 is adhered to the edges 110 of the device 20.
  • FIGS. 5-8 illustrate an alternative procedure that may be used for larger electronic devices, such as tablets, notebooks, and notebooks. In this embodiment, the protective adhesive film includes a cap sheet layer (e.g., a casting film and/or a casting sheet). Referring to FIG. 5, a portion of a backing layer 420 is removed from an adhesive film 410 to expose an adhesive area 430. In some embodiments, the adhesive film 410 is a micro-matte protective adhesive film. The adhesive area 430 is disposed on at least a portion of a first major surface 440 of the protective adhesive film 410. A cap sheet 510 is disposed on a second major surface of the protective adhesive film 410. Prior to removing the backing layer 420, the film 410, together with the cap sheet 510 as one piece or separately from the cap sheet 510, may be shaped by cutting (e.g., by die cutting, plotter cutting, or other methods) to create segments, with a cap sheet 510 layered on the adhesive film 410, matched in size and shape to chosen surface areas on a particular device to be protected. Alternatively, the protective adhesive film 410 and cap sheet 510 may be pre-cut to match a desired area on an electronic device.
  • After the adhesive is exposed, FIG. 6 illustrates that the adhesive area 430 may be contacted to an exposed surface portion 40 of an electronic device 460 (e.g., a display surface). In some embodiments, the exposed surface portion 450 may be any portion of exposed surface 470 including the entire exposed surface 470. In some embodiments, the adhesive film 410 and/or the adhesive area 430 may be positioned to contact and align with an exposed surface portion 450 of the electronic device 460. For example, openings 475 in the adhesive film 410 may be aligned to corresponding components 465 (e.g., input and/or output ports, buttons, etc.) of the electronic device 460. In some embodiments, at least one optional tab 415 extends from the adhesive film 410. A user may hold the at least one optional tab 415 while positioning, contacting, and/or aligning the adhesive area 430 to the exposed surface portion 450 of the electronic device 460. In some embodiments, prior to contacting the adhesive film 410 to the electronic device 460, at least a portion of exposed surface 470 of the electronic device may be cleaned, for example, by rubbing or polishing the at least a portion of exposed surface 470 with a dry tissue or towelette. In some embodiments, no liquid or other additive is applied to the adhesive film 410, the adhesive area 430, and/or the electronic device 460.
  • Referring to FIG. 7, a mechanical smoothing device 500 (e.g., a squeegee, oversized squeegee, a device having a resilient edge, or a hand) may be used to apply a pressure to the cap sheet 510 disposed on a second major surface 490 of the film 410. The pressure may causes the adhesive area 430 to press against the exposed surface portion 450 of the electronic device 460 (as depicted in FIG. 6). The mechanical smoothing device 500 may be applied starting at an edge 515 of the electronic device 420 and proceeding across the width 520 of the electronic device 420. An optional second mechanical smoothing step may be applied in the opposite direction of the first mechanical smoothing step. After pressure is applied with the mechanical smoothing device 500, the cap sheet 510 is removed (e.g., peeled off) to expose the second major surface 490 of the film 410, as illustrated in FIG. 8. Any haze or remaining trapped air bubbles, if less than about 2-3 mm in diameter, may be left to diffuse out through the protective adhesive film 410 (e.g., an air-impermeable film), generally disappearing within 24 hours. For example, air bubbles may diffuse into the first major surface 440 of the film 410 and out the second major surface 490 of the film 410. In some embodiments, after the mechanical smoothing step, the optional hold tabs 415 may be removed from the film 410 by pulling along optional perforations (not shown) or by cutting off the hold tabs 415.
  • The method improves the adherence of the film to the surface of the device, and provides a higher quality (e.g., less damaged, more transparent, and/or more accurately placed) protective film. The method further reduces the number of remaining trapped air bubbles. The method further reduces the installation time of applying a protective film to an electronic device.

Claims (20)

What is claimed is:
1. A screen protector for protecting a screen of an electronic device, the screen protector comprising:
a protective film including a first major surface, a second major surface opposite the first major surface, and an edge;
a tab extending from the edge of the protective film, the tab sized to form a grab handle for positioning the protective film relative to the screen of the electronic device during installation of the protective film onto the screen of the electronic device, the tab being removable from the protective film after the positioning and the installation of the protective film onto the screen of the electronic device;
an adhesive layer on the first major surface of the protective film, the adhesive layer including an adhesive providing tack sufficient to adhere the first major surface of the protective film to the screen of the electronic device and permitting repositioning of the protective film during the installation of the protective film onto the screen of the electronic device; and
a backing layer covering the adhesive layer to protect the adhesive of the adhesive layer prior to the installation of the protective film onto of the screen of the electronic device, the backing layer removable from the adhesive layer prior to the installation.
2. The screen protector of claim 1 further comprising a cap sheet adjacent to the second major surface of the protective film, the cap sheet sized based on the screen of the electronic device, the cap sheet withstanding a pressure applied by a mechanical smoothing device during the installation of the protective film onto the screen of the electronic device.
3. The screen protector of claim 1, wherein the protective film comprises polyurethane.
4. The screen protector of claim 1, wherein the protective film comprises a polycaprolactone based aliphatic thermoplastic urethane.
5. The screen protector of claim 1, wherein the adhesive layer comprises an acrylate polymer and a silicon monomer.
6. The screen protector of claim 1, wherein the adhesive layer comprises a copolymer of an acrylate polymer and a silicone macromer side chain.
7. The screen protector of claim 1, wherein at least a portion of the second major surface of the protective film comprises a micro-matte surface finish.
8. The screen protector of claim 2, wherein the cap sheet comprises polyester.
9. The screen protector of claim 2, wherein at least a portion of a surface of the cap sheet adjacent to the second major surface of the protective film comprises a micro-matte surface finish.
10. The screen protector of claim 2, wherein the cap sheet is between about 24 microns and about 254 microns in thickness.
11. The screen protector of claim 1, wherein the adhesive layer adheres to the screen of the electronic device without application of a liquid to the adhesive layer or to the screen of the electronic device.
12. The screen protector of claim 1, further comprising an opening in the protective film to provide access to a component of the electronic device after the installation of the protective film onto the screen of the electronic device.
13. The screen protector of claim 1, wherein the protective film is at least partially air permeable.
14. The screen protector of claim 1, wherein the protective film is between about 150 microns and about 400 microns in thickness.
15. The screen protector of claim 1, wherein the adhesive layer is between about 12 microns and about 150 microns in thickness.
16. A protective film for protecting a surface of an electronic device, the protective film comprising:
a protective film layer including a first major surface, a second major surface opposite the first major surface, and an edge;
a tab extending from the edge of the protective film layer, the tab for positioning the protective film layer relative to the surface of the electronic device during installation of the protective film on the surface of the electronic device, the tab being removable from the protective film layer after the positioning and the installation of the protective film on the surface of the electronic device;
an adhesive on the first major surface of the protective film layer, the adhesive having sufficient tack to adhere the first major surface of the protective film layer to the surface of the electronic device and allowing repositioning of the protective film layer on the surface of the electronic device during the installation of the protective film on the surface of the electronic device; and
a backing layer over the adhesive to protect the adhesive prior to the installation of the protective film on the surface of the electronic device, the backing layer removable from the adhesive prior to the installation to expose the adhesive to the surface of the electronic device.
17. The protective film of claim 16 further comprising a cap sheet adjacent to the second major surface of the protective film layer, the cap sheet withstanding a pressure applied by a mechanical smoothing device during the installation of the protective film on the surface of the electronic device.
18. The protective film of claim 16 wherein the adhesive includes a pressure sensitive adhesive.
19. The protective film of claim 16 further comprising an ultraviolet (UV) light absorber.
20. The protective film of claim 16, wherein the adhesive adheres to the surface of the electronic device without application of a liquid to the adhesive or to the surface of the electronic device.
US14/976,221 2010-03-12 2015-12-21 Protective film for an electronic device Abandoned US20160107416A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/976,221 US20160107416A1 (en) 2010-03-12 2015-12-21 Protective film for an electronic device

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US31336310P 2010-03-12 2010-03-12
US31618510P 2010-03-22 2010-03-22
US35969010P 2010-06-29 2010-06-29
US201161440708P 2011-02-08 2011-02-08
US13/044,275 US8940122B2 (en) 2010-03-12 2011-03-09 Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film
US13/624,499 US9248634B2 (en) 2010-03-12 2012-09-21 Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film
US14/976,221 US20160107416A1 (en) 2010-03-12 2015-12-21 Protective film for an electronic device

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US13/624,499 Continuation US9248634B2 (en) 2010-03-12 2012-09-21 Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film

Publications (1)

Publication Number Publication Date
US20160107416A1 true US20160107416A1 (en) 2016-04-21

Family

ID=44563846

Family Applications (5)

Application Number Title Priority Date Filing Date
US13/044,275 Active 2031-11-15 US8940122B2 (en) 2010-03-12 2011-03-09 Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film
US13/624,499 Active US9248634B2 (en) 2010-03-12 2012-09-21 Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film
US14/564,718 Active US9346251B2 (en) 2010-03-12 2014-12-09 Protective adhesive film product
US14/564,093 Active 2031-05-30 US9421745B2 (en) 2010-03-12 2014-12-24 Method of adhering protective adhesive film to a device
US14/976,221 Abandoned US20160107416A1 (en) 2010-03-12 2015-12-21 Protective film for an electronic device

Family Applications Before (4)

Application Number Title Priority Date Filing Date
US13/044,275 Active 2031-11-15 US8940122B2 (en) 2010-03-12 2011-03-09 Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film
US13/624,499 Active US9248634B2 (en) 2010-03-12 2012-09-21 Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film
US14/564,718 Active US9346251B2 (en) 2010-03-12 2014-12-09 Protective adhesive film product
US14/564,093 Active 2031-05-30 US9421745B2 (en) 2010-03-12 2014-12-24 Method of adhering protective adhesive film to a device

Country Status (5)

Country Link
US (5) US8940122B2 (en)
EP (1) EP2574218B1 (en)
AU (1) AU2011224276B2 (en)
CA (1) CA2807056C (en)
WO (1) WO2011112817A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109016481A (en) * 2018-06-26 2018-12-18 深圳市康成泰实业有限公司 A kind of Mobile phone film method for adhering film
TWI658942B (en) * 2018-01-09 2019-05-11 大陸商業成科技(成都)有限公司 Protective film for protecting optical hole of cover glass

Families Citing this family (81)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7957524B2 (en) * 2006-03-02 2011-06-07 Zagg Incorporated Protective covering for an electronic device
US8567596B1 (en) 2006-04-01 2013-10-29 Zagg Intellectual Property Holding Co., Inc. Electronic device protective film application kit and method
US8940122B2 (en) * 2010-03-12 2015-01-27 Wrapsol Acquisition, Llc Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film
US9274625B2 (en) 2010-05-14 2016-03-01 Racing Optics, Inc. Touch screen shield
US20170031525A1 (en) 2010-05-14 2017-02-02 Racing Optics, Inc. Touch screen shield
US9128545B2 (en) 2010-05-14 2015-09-08 Racing Optics, Inc. Touch screen shield
US9777195B2 (en) 2010-06-22 2017-10-03 Zagg Intellectual Property Holding Co., Inc. Dry apply protective systems and methods
US11472098B2 (en) 2010-06-22 2022-10-18 Zagg Inc Protective layers for dry application to protected surfaces, installation assemblies and kits including the layers, devices protected with the layers, and associated methods
US9580626B2 (en) * 2010-06-22 2017-02-28 Zagg Intellectual Property Holding Co., Inc. Systems for securing protective films to surfaces of substrates
US20120043015A1 (en) * 2010-07-20 2012-02-23 Kirk Feller Method and apparatus for protecting an electronic device
US20120110868A1 (en) * 2010-07-27 2012-05-10 Matthew Lucianno Abbondanzio protective cover and system for electronic devices technical field
WO2012031127A2 (en) 2010-09-01 2012-03-08 Timothy Andrew Chaves Protective covering for an electronic device
US20130045371A1 (en) * 2011-08-18 2013-02-21 Dennis P. O'Donnell Screen protector film
US9120954B2 (en) * 2012-02-08 2015-09-01 Nlu Products, L.L.C. Method, apparatus, and kit for protecting an electronic device
US20140162009A1 (en) * 2012-12-12 2014-06-12 She Hwa P&C Co., Ltd Shock absorption film and method of making the same
US20140234615A1 (en) * 2013-02-19 2014-08-21 Senyan Meng Fuel Dispenser Protectors for Digital Display Screens and Graphic Panels
USD734311S1 (en) * 2013-04-04 2015-07-14 Nintendo Co., Ltd. Screen protection sheet
US11772320B2 (en) 2013-08-08 2023-10-03 Belkin International, Inc. Overlay applicator tray and method of using the same
US9902111B2 (en) 2013-08-08 2018-02-27 Belkin International, Inc. Cradle device, method of using the same, and overlay applicator machine
US10155370B2 (en) 2013-08-08 2018-12-18 Belkin International, Inc. Overlay applicator machine and method of using the same
USD811406S1 (en) 2016-05-27 2018-02-27 Belkin International, Inc. Overlay tray
US10675817B2 (en) 2013-08-08 2020-06-09 Belkin International, Inc. Overlay applicator tray and method of using the same
US10782746B2 (en) 2013-08-08 2020-09-22 Belkin International, Inc. Overlay for an electronic device
USD812061S1 (en) 2016-05-27 2018-03-06 Belkin International, Inc. Overlay tray
WO2015021430A1 (en) 2013-08-08 2015-02-12 Belkin International, Inc Overlay applicator, applicator machine, and cradle, and method of providing and using the same
WO2015038883A1 (en) * 2013-09-12 2015-03-19 Eshields, Llc Protective covering applicator for electronic devices
US9001502B1 (en) * 2013-11-12 2015-04-07 Randy G. Cowan Device screen protector article
US9542866B1 (en) 2013-11-12 2017-01-10 Randy G. Cowan Device screen protector article
US10194723B2 (en) * 2013-11-12 2019-02-05 Cynthia Lisa Skepton Compostable composite multipanel smartphone, tablet and mobile electronic device cover kits for consumer print personalization and structural customization
USD740626S1 (en) * 2013-11-14 2015-10-13 Jiangman iGuarder Electronic Co., Ltd. Film sticking device
USD738172S1 (en) * 2013-11-18 2015-09-08 Jiangmen Iguarder Electronic Co., Ltd. Film sticking locator for a mobile phone
USD759640S1 (en) 2013-12-20 2016-06-21 Belkin International, Inc. Overlay
USD751556S1 (en) 2013-12-20 2016-03-15 Belkin International, Inc. Overlay
USD751557S1 (en) 2013-12-20 2016-03-15 Belkin International, Inc. Overlay
US20150202847A1 (en) 2014-01-17 2015-07-23 3M Innovative Properties Company Successively peelable coextruded polymer film with extended uv stability
USD767550S1 (en) 2014-01-27 2016-09-27 Belkin International, Inc. Overlay for electronic device
US20150286327A1 (en) * 2014-04-07 2015-10-08 Deven Charles Chakrabarti Method and Apparatus for Protecting Touch-Screen Electronic Devices
US9295297B2 (en) 2014-06-17 2016-03-29 Racing Optics, Inc. Adhesive mountable stack of removable layers
USD767955S1 (en) * 2014-10-16 2016-10-04 Tzumi Electronics LLC Protective smartphone cover glass applicator
EP3088179A1 (en) 2015-04-30 2016-11-02 Impact Protection Technology AG Multilayer polyurethane protective films
USD800131S1 (en) 2016-05-27 2017-10-17 Belkin International, Inc. Overlay
USD811407S1 (en) 2016-05-27 2018-02-27 Belkin International, Inc. Overlay
USD811404S1 (en) 2016-05-27 2018-02-27 Belkin International, Inc. Overlay
USD800130S1 (en) 2016-05-27 2017-10-17 Belkin International, Inc. Overlay
USD802594S1 (en) 2016-05-27 2017-11-14 Belkin International, Inc. Overlay
USD811408S1 (en) 2016-05-27 2018-02-27 Belkin International, Inc. Overlay
USD817945S1 (en) 2016-05-27 2018-05-15 Belkin International, Inc. Overlay
USD800126S1 (en) 2016-05-27 2017-10-17 Belkin International, Inc. Overlay
USD800127S1 (en) 2016-05-27 2017-10-17 Belkin International, Inc. Overlay
USD811405S1 (en) 2016-05-27 2018-02-27 Belkin International, Inc. Overlay
USD800128S1 (en) 2016-05-27 2017-10-17 Belkin International, Inc. Overlay
USD800129S1 (en) 2016-05-27 2017-10-17 Belkin International, Inc. Overlay
SE540253C2 (en) * 2016-07-01 2018-05-15 Expertus Kemiteknik Ab Device for surface sampling with removal device
USD833439S1 (en) 2016-09-15 2018-11-13 Belkin International, Inc. Overlay tray
USD812062S1 (en) 2016-09-15 2018-03-06 Belkin International, Inc. Overlay tray
US10231799B1 (en) 2016-12-05 2019-03-19 Arun Kalava Overhead light shield
CH713579A1 (en) * 2017-03-17 2018-09-28 Fgp Capital Sa System comprising an ice cream or a screen.
WO2018167582A1 (en) * 2017-03-17 2018-09-20 Fgp Capital Sa Apparatus comprising a glass or a screen
KR102301005B1 (en) * 2017-03-21 2021-09-10 삼성전자 주식회사 Protective film for electric device and window assembly using the same
US20190202619A1 (en) * 2017-12-28 2019-07-04 Huizhou China Star Optoelectronics Technology Co., Ltd. Spacing sheet for protecting liquid crystal panel
CN113166590A (en) 2018-11-07 2021-07-23 伊士曼性能薄膜有限责任公司 Tackifying solutions and their use in applying films to substrates
US10841409B2 (en) 2018-12-21 2020-11-17 Otter Products, Llc Tool for installing a screen protector on an electronic device
US11665269B2 (en) 2018-12-21 2023-05-30 Otter Products, Llc Tool for installing a screen protector on an electronic device
CN109735254A (en) * 2018-12-28 2019-05-10 深圳市康成泰实业有限公司 Pad pasting and method for adhering film
EP3917768A4 (en) 2019-02-01 2022-10-26 Racing Optics, Inc. Thermoform windshield stack with integrated formable mold
US11846788B2 (en) 2019-02-01 2023-12-19 Racing Optics, Inc. Thermoform windshield stack with integrated formable mold
US11364715B2 (en) 2019-05-21 2022-06-21 Racing Optics, Inc. Polymer safety glazing for vehicles
US11186031B2 (en) 2019-08-12 2021-11-30 Otter Products, Llc Apparatus for installing a screen protector on an electronic device
USD938428S1 (en) * 2019-11-22 2021-12-14 Apple Inc. Cover for an electronic device
US11648723B2 (en) 2019-12-03 2023-05-16 Racing Optics, Inc. Method and apparatus for reducing non-normal incidence distortion in glazing films
USD915415S1 (en) * 2019-12-30 2021-04-06 Right Group Central Co., Ltd. Screen protection filter
US11407616B2 (en) * 2020-01-24 2022-08-09 Otis Elevator Company Elevator belt surface protection for installation
US11548356B2 (en) 2020-03-10 2023-01-10 Racing Optics, Inc. Protective barrier for safety glazing
US11840051B2 (en) 2020-11-03 2023-12-12 Curio Holding Company Apparatus and method for installing a screen protector on an electronic device
US11490667B1 (en) 2021-06-08 2022-11-08 Racing Optics, Inc. Low haze UV blocking removable lens stack
US11791238B2 (en) 2021-06-23 2023-10-17 Infineon Technologies Austria Ag Semiconductor package with releasable isolation layer protection
US11709296B2 (en) 2021-07-27 2023-07-25 Racing Optics, Inc. Low reflectance removable lens stack
US11307329B1 (en) 2021-07-27 2022-04-19 Racing Optics, Inc. Low reflectance removable lens stack
US11933943B2 (en) 2022-06-06 2024-03-19 Laminated Film Llc Stack of sterile peelable lenses with low creep
USD976915S1 (en) * 2022-06-15 2023-01-31 Shengjie Zhou Protective film comprised of three layers
US11808952B1 (en) 2022-09-26 2023-11-07 Racing Optics, Inc. Low static optical removable lens stack

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070029773A1 (en) * 2005-08-04 2007-02-08 Key Safety Systems, Inc. Seat Belt Assembly and Method of Installation
US20090000447A1 (en) * 2002-08-09 2009-01-01 Fabio Perini Apparatus for trimming paper rolls or logs and an operating method for treating the logs
US20090186181A1 (en) * 2008-01-18 2009-07-23 Power Support Co., Ltd. Screen Protector Film with Particulate Removal Means and Method of Applying the Same
US20090257189A1 (en) * 2008-04-11 2009-10-15 Wang Erik L Portable electronic device housing structures
US20100068446A1 (en) * 2006-10-23 2010-03-18 Mcguire James E Articles Comprising Protective Sheets and Related Methods

Family Cites Families (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2610635B1 (en) 1987-02-10 1989-06-23 Extrusion Calandrage Ste Fse POLYURETHANE COMPOSITIONS FOR CALENDERING BIODEGRADABLE MATERIALS
US5083979A (en) 1988-09-29 1992-01-28 Burt Dennis M Protective label form and method
US5132588A (en) 1989-02-13 1992-07-21 Warman William J Viewing screen protective shield
WO1992016593A2 (en) 1991-03-20 1992-10-01 Minnesota Mining And Manufacturing Company Radiation-curable acrylate/silicone pressure-sensitive adhesive compositions
FR2697206A1 (en) * 1992-10-22 1994-04-29 Moore Business Forms Inc Packing label training set.
US5388691A (en) 1993-10-21 1995-02-14 White; Nona J. Protective case for remote control transmitter
US5548306A (en) 1994-04-28 1996-08-20 At&T Global Information Solutions Company Visible and touchable touch screen shield
US5499713A (en) 1994-11-16 1996-03-19 Huffer; Richard L. Transparent remote control flexible envelope
US6227599B1 (en) 1996-05-07 2001-05-08 Edgeguard, Inc. Means and method for protecting a windshield from cracks
US5732414A (en) 1997-02-12 1998-03-31 Creative Football Concepts, Inc. Helmet having a readily removable and replaceable protective layer
US6054009A (en) * 1997-06-03 2000-04-25 Armron Corporation Method of applying a disc surface protective cover
US5965256A (en) * 1997-10-14 1999-10-12 Minnesota Mining And Manufacturing Company Protective films and coatings
FI104928B (en) 1997-11-27 2000-04-28 Nokia Mobile Phones Ltd Wireless Communication and a Method of Making a Wireless Communication Device
US6017079A (en) 1998-01-23 2000-01-25 Warner; Joseph Vehicle camouflage conversion kit and method of using same
US6800378B2 (en) 1998-02-19 2004-10-05 3M Innovative Properties Company Antireflection films for use with displays
US7351470B2 (en) 1998-02-19 2008-04-01 3M Innovative Properties Company Removable antireflection film
CA2278832A1 (en) 1999-01-06 2000-07-06 Vtech Communications, Ltd. Touch screen overlay apparatus
JP3388437B2 (en) 2000-02-18 2003-03-24 大日本印刷株式会社 Decorative sheet
US20060019113A1 (en) * 2000-03-24 2006-01-26 Cyro Industries Plastic sheet product offering matte appearance and method of preparation
US7229665B2 (en) 2001-05-22 2007-06-12 Millipore Corporation Process of forming multilayered structures
US6491775B1 (en) 2000-06-27 2002-12-10 3M Innovative Properties Method of applying a semi-rigid film to a substrate
US6406758B1 (en) 2000-07-25 2002-06-18 3M Innovative Properties Company Method of applying a protective coating to a touch screen panel
US6614423B1 (en) 2000-08-21 2003-09-02 Symbol Technologies, Inc. Touch-pad cover protecting against wear, spills and abuse
JP2004513483A (en) 2000-11-02 2004-04-30 スリーエム イノベイティブ プロパティズ カンパニー Bright and contrast enhanced direct-view luminescent display
KR100512082B1 (en) 2000-11-13 2005-09-02 아사히 가세이 가부시키가이샤 Light guide and method for producing transparent thermoplastic resin composition for light guide
AU2002237671A1 (en) * 2000-11-16 2003-09-29 Avery Dennison Corporation Sheet structure and method for adhesive image transfer
US7054441B2 (en) 2000-12-12 2006-05-30 Research In Motion Limited Mobile device having a protective user interface cover
DE60228958D1 (en) 2001-06-21 2008-10-30 Ericsson Telefon Ab L M METHOD FOR SECURE FILE TRANSMISSION TO A VARIETY OF TARGET ADDRESSES WITH INTEGRITY TESTING
CN1516949A (en) 2001-06-22 2004-07-28 Protective sealable transparent flexible membrane for electronic touch screens
US20030110613A1 (en) 2001-08-08 2003-06-19 Mark Ross Screen protector
US20030080947A1 (en) 2001-10-31 2003-05-01 Genest Leonard J. Personal digital assistant command bar
US7158376B2 (en) 2001-11-19 2007-01-02 Otter Products, Llc Protective enclosure for an interactive flat-panel controlled device
US7180735B2 (en) 2001-11-19 2007-02-20 Otter Products, Llc Protective enclosure and watertight adapter for an interactive flat-panel controlled device
US7151532B2 (en) * 2002-08-09 2006-12-19 3M Innovative Properties Company Multifunctional multilayer optical film
EP1426428A1 (en) * 2002-12-06 2004-06-09 Ucb S.A. Aqueous polymer dispersions as pressure sensitive adhesives
EP1569988A1 (en) 2002-12-12 2005-09-07 Denki Kagaku Kogyo Kabushiki Kaisha Surface protective film
US20050022924A1 (en) 2002-12-27 2005-02-03 Blackburn James B. Adhesive article for and method of applying a decorative finish to a phone
TWI310230B (en) 2003-01-22 2009-05-21 Lintec Corp Adhesive sheet, method for protecting surface of semiconductor wafer and method for processing work
CA2430399A1 (en) 2003-05-28 2004-11-28 Ruth Marie Smith Decorative pattern application kit
US20040246386A1 (en) 2003-06-04 2004-12-09 THOMAS Judith M. Screen protection kit having a sizing grid
US20050047589A1 (en) 2003-08-26 2005-03-03 Yuan Chang User definable adhesive personal electronics cover
US7214432B2 (en) 2003-09-30 2007-05-08 General Electric Company Coating compositions, their preparation, and coated articles made therefrom
US20050279661A1 (en) 2003-11-12 2005-12-22 Hodges Richard P Cover for remote control device
US7290654B2 (en) 2003-11-12 2007-11-06 Hodges Richard P Cover for remote control device
US7529364B2 (en) 2003-11-19 2009-05-05 Imbibo, Inc. Protective cover for electronic device
CA2449951A1 (en) 2003-11-19 2005-05-19 Imbibo Inc. Protective cover for electronic device
US7400917B2 (en) 2004-01-30 2008-07-15 Nokia Corporation Protective devices for a mobile terminal
US7413787B2 (en) 2004-10-20 2008-08-19 Agwest, Llc Adhesive sheet
US7339635B2 (en) 2005-01-14 2008-03-04 3M Innovative Properties Company Pre-stacked optical films with adhesive layer
TWI383003B (en) 2005-02-02 2013-01-21 Mitsubishi Gas Chemical Co Polyester film, the process thereof, and the use thereof
US20060219347A1 (en) * 2005-04-04 2006-10-05 Essilor International Compagnie Generale D'optique Process for transferring coatings onto a surface of a lens substrate with most precise optical quality
DE202006021212U1 (en) 2005-04-29 2013-10-24 3M Innovative Properties Co. Multilayer polyurethane protective films
US7629052B2 (en) 2005-05-05 2009-12-08 Larry Brumwell Protective cover system
WO2006123616A1 (en) 2005-05-16 2006-11-23 Nissha Printing Co., Ltd. Removable protection panel mount structure and mounting sheet for use therein
US7799853B2 (en) * 2005-09-05 2010-09-21 Nitto Denko Corporation Adhesive composition, adhesive sheet, and surface protective film
US20070115387A1 (en) 2005-11-21 2007-05-24 Ho Kenneth K Underwater camera combination
WO2007074662A1 (en) 2005-12-28 2007-07-05 Konica Minolta Opto, Inc. Optical film and process for producing optical film
US7957524B2 (en) 2006-03-02 2011-06-07 Zagg Incorporated Protective covering for an electronic device
US20070205118A1 (en) 2006-03-03 2007-09-06 The Procter & Gamble Company Kit for applying a decorative laminate to a target surface
US7784610B2 (en) 2006-04-01 2010-08-31 Andrew Mason Protective film application kit and method
US7389869B2 (en) 2006-04-01 2008-06-24 Mason Jr Andrew C Display protective film application kit
US8128779B2 (en) * 2006-10-04 2012-03-06 3M Innovative Properties Company Method of making multilayer polyurethane protective film
US8110268B2 (en) 2006-11-03 2012-02-07 Skinit, Inc. Adhesive cover for consumer devices
US20080156423A1 (en) 2006-12-29 2008-07-03 3M Innovative Properties Company Apparatus for mounting laminates on substrates and methods thereof
US20090110861A1 (en) * 2007-10-29 2009-04-30 3M Innovative Properties Company Pressure sensitive adhesive article
WO2009105297A2 (en) 2008-02-21 2009-08-27 3M Innovative Properties Company Temporarily repositionable pressure sensitive adhesive blends
TWI352567B (en) 2008-04-21 2011-11-11 Wistron Corp Waterproof casing
US8940122B2 (en) * 2010-03-12 2015-01-27 Wrapsol Acquisition, Llc Protective adhesive film, method of adhering protective adhesive film to a device, and device comprising protective adhesive film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090000447A1 (en) * 2002-08-09 2009-01-01 Fabio Perini Apparatus for trimming paper rolls or logs and an operating method for treating the logs
US20070029773A1 (en) * 2005-08-04 2007-02-08 Key Safety Systems, Inc. Seat Belt Assembly and Method of Installation
US20100068446A1 (en) * 2006-10-23 2010-03-18 Mcguire James E Articles Comprising Protective Sheets and Related Methods
US20090186181A1 (en) * 2008-01-18 2009-07-23 Power Support Co., Ltd. Screen Protector Film with Particulate Removal Means and Method of Applying the Same
US20090257189A1 (en) * 2008-04-11 2009-10-15 Wang Erik L Portable electronic device housing structures

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI658942B (en) * 2018-01-09 2019-05-11 大陸商業成科技(成都)有限公司 Protective film for protecting optical hole of cover glass
CN109016481A (en) * 2018-06-26 2018-12-18 深圳市康成泰实业有限公司 A kind of Mobile phone film method for adhering film
US20190394317A1 (en) * 2018-06-26 2019-12-26 Shenzhen Kangchengtai Industrial Co., Ltd. Method for applying cell phone screen protector
US10785355B2 (en) * 2018-06-26 2020-09-22 Shenzhen Kangchengtai Industrial Co., Ltd. Method for applying cell phone screen protector

Also Published As

Publication number Publication date
AU2011224276A1 (en) 2013-07-11
EP2574218A1 (en) 2013-04-03
US9248634B2 (en) 2016-02-02
US9421745B2 (en) 2016-08-23
US20150183201A1 (en) 2015-07-02
AU2011224276B2 (en) 2015-04-02
CA2807056A1 (en) 2011-09-15
EP2574218B1 (en) 2016-04-27
US8940122B2 (en) 2015-01-27
US20130033808A1 (en) 2013-02-07
US20110267793A1 (en) 2011-11-03
EP2574218A4 (en) 2013-08-28
WO2011112817A1 (en) 2011-09-15
CA2807056C (en) 2016-02-23
US9346251B2 (en) 2016-05-24
US20150093532A1 (en) 2015-04-02

Similar Documents

Publication Publication Date Title
US9346251B2 (en) Protective adhesive film product
US11485880B2 (en) Dry apply protective methods
US20230042526A1 (en) Methods for protecting portable electronic devices
US20220040909A1 (en) Methods, systems, and devices for applying a protective film to a device
KR100707411B1 (en) Protection film and method of making the same
TW201625758A (en) Adhesive sheet
US20150291854A1 (en) Systems for securing protective films to surfaces of substrates
WO2011163151A1 (en) Assembly, kit and related method for applying a polymeric film to a device
TW201425049A (en) Double-sided adhesive sheet for image display device, double-sided adhesive sheet with release film for image display device and image display device using same
WO2012031127A2 (en) Protective covering for an electronic device
JP5060058B2 (en) Protective sheet for information display surface and method for manufacturing protective sheet
JP4622545B2 (en) Functional film for application
JP6778562B2 (en) Adhesive sheet with release liner
KR102096501B1 (en) Protecting sheet having excellent adhesive property of edge portion and display device comprising the same
KR102013642B1 (en) Protecting sheet having excellent adhesive property of edge portion and display device comprising the same
JP2006119186A (en) Screen protection sheet
WO2011005659A2 (en) Decorative article
JP2011178032A (en) Laminate
KR20160086188A (en) Case for smart device
KR20160126263A (en) Adhesive sheet for detachably fixing adherend and protective case for mobile terminal including the same
JP2014205295A (en) Laminated sheet

Legal Events

Date Code Title Description
AS Assignment

Owner name: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT, ILLINOIS

Free format text: INTELLECTUAL PROPERTY SECURITY AGREEMENT;ASSIGNOR:OTTER PRODUCTS, LLC;REEL/FRAME:043681/0846

Effective date: 20170825

Owner name: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT, IL

Free format text: INTELLECTUAL PROPERTY SECURITY AGREEMENT;ASSIGNOR:OTTER PRODUCTS, LLC;REEL/FRAME:043681/0846

Effective date: 20170825

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION

AS Assignment

Owner name: OTTER PRODUCTS, LLC, COLORADO

Free format text: RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY AT REEL/FRAME NO. 43681/0846;ASSIGNOR:BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:051693/0484

Effective date: 20200124