US20160093900A1 - Fuel cell and method for the production thereof - Google Patents
Fuel cell and method for the production thereof Download PDFInfo
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- US20160093900A1 US20160093900A1 US14/956,864 US201514956864A US2016093900A1 US 20160093900 A1 US20160093900 A1 US 20160093900A1 US 201514956864 A US201514956864 A US 201514956864A US 2016093900 A1 US2016093900 A1 US 2016093900A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0232—Metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/242—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes comprising framed electrodes or intermediary frame-like gaskets
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- This invention relates to a fuel cell having a porous substrate produced by powder metallurgy to which the electrochemically active cell layers are applied and which is disposed in the central area of a plate with gas passages provided in the edge area thereof. It also relates to a method for producing the fuel cell.
- the high temperature fuel cell or solid oxide fuel cell is emerging as particularly suitable on account of its high electrical efficiency and the possible utilization of the waste heat arising in the high temperature range e.g. for stationary cogeneration. It is thus possible to obtain electrical efficiencies of 60% to 70% in hybrid systems in which the SOFC is integrated into gas turbine processes.
- SOFC systems are of great interest. They offer the potential of an efficient and thus fuel-economizing power supply, whereby both conventional fuels (gasoline, diesel, natural gas) and pure hydrogen can be employed.
- planar SOFC offers advantages for decentralized stationary and mobile application because of the shorter current conducting paths and thus higher areal power density.
- the latest generation of SOFCs has a porous metallic body which performs as a substrate the support function for the electrode layers and the electrolyte layer (metal-supported cell, MSC).
- MSC metal-supported cell
- the MSC is of interest in particular for mobile applications because it possesses better thermal cyclability, high mechanical loading capacity and high reoxidation stability at a low cost of materials and small cell thickness.
- the integration of an MSC into a fuel stack can be realized by commercially available soldering and welding processes.
- the substrate it is customary to employ high-alloy chromium steel.
- the substrates employed are in particular porous bodies produced by powder metallurgy (AT 008975 U1), woven or knitted fabrics (EP 1318560 A2, WO 02/101859 A2), perforated sheet metal or expanded metal US 2005/142426 A1, GB 2400723 A, GB 2422479 A).
- the substrate can be welded into a sheet metal frame produced by fusion metallurgy and having the gas passages, e.g. the fuel gas and waste gas openings for fuel gas supply and waste gas removal to and from the fuel cell.
- the gas passages e.g. the fuel gas and waste gas openings for fuel gas supply and waste gas removal to and from the fuel cell.
- the mutual sealing of the anode-side and cathode-side gas space is effected via the gastight electrolyte which extends from the porous substrate area beyond the weld seam onto the sheet metal frame (EP 1 278 259
- the substrate can be perforated sheet metal (WO 02/35628 A1), or a body produced by powder metallurgy (EP 1278259 A2).
- porous substrates produced by powder metallurgy offer better coatability and gas distribution.
- the edge of the substrate is compressed to be gastight, according to EP 1 278 259 A2, before it is welded to the sheet metal frame to form the plate.
- the integration of the porous substrate with the sheet metal frame causes microstructurally different, often also different alloys, to be interconnected. For thermomechanical reasons this state is undesirable, because high tensions can be induced into the cell sandwich. Further, the circumferentially formed weld seam between the sheet metal frame and the substrate leads to warpage of the plate.
- the weld seam itself involves the risk of defects, which would mean a leakage path between anode side and cathode side.
- the substrate welded into a sheet metal frame leads to a high cost of materials, because a high proportion of the sheet metal becomes waste material upon cutting of the frame.
- the object of the invention is hence to provide a fuel cell which guarantees a reliable-process coating with anode, electrolyte and cathode and at the same time a suitable basis for the stack integration of the cell at low material usage.
- a one-pieced plate produced by powder metallurgy whose central area is of porous configuration to form the substrate, and whose edge area having the gas passages or the “manifold” is compressed to be gastight.
- a planar, powder-metallurgical, porous body which preferably consists of an iron-chromium alloy.
- the body can be produced here according to AT 008 975 U1.
- At least one metal of the group Y, Sc, rare earth metals and at least one metal of the group Cr, Ti, Al, Mn can form a mixed oxide.
- the selection of the powder fraction for the body must be made in such a way that defects in the surface which naturally result from deviations from an optimal packing density are kept small enough to guarantee good coatability.
- a powder fraction with a particle size of ⁇ 150 ⁇ m, in particular ⁇ 100 ⁇ m there is preferably employed.
- the use of finer powder fractions would improve coatability further, but entail a worsening of the high temperature oxidation stability on account of a higher internal surface.
- a planar green body with a thickness of preferably 0.3 to 1.5 mm.
- the body is sintered, whereby it has a porosity of preferably 20 to 60%, in particular 40 to 50%, after sintering.
- the porosity is the density of the porous body based on the density of the alloy.
- the edge area of the porous body is compressed until it is gastight.
- the dimensions of the compressed edge area result from the necessary surface area for the gas passages and sealing surfaces, in particular with the electrolyte layer and the contact plate, as to be explained more closely hereinafter.
- the contact plate is often also designated an interconnector and is hence to be understood as such.
- the compression of the body in the edge area can be effected by uniaxial pressing or section rolling.
- the transition between the central porous substrate area of the plate and the compressed edge area can be configured as a step. However, there is preferably produced upon compression a continuous, stepless transition between the substrate area and the compressed edge area, because edges and similar discontinuities can cause tensions in the plate.
- an annealing or similar heat treatment there can optionally be added to obtain a tension release in the structure of the plate after the compression process.
- the tight edge area of the plate is provided with the gas passages by stamping, punching, cutting or the like.
- the edge area can be provided with the gas passages in a process step during compression.
- edge area of the plate with further structures, for example by stamping stiffening structures and/or connecting structures for example with the electrolyte layer and/or the contact plate.
- the electrochemically active cell layers are applied, i.e. normally the anode to the substrate area of the plate, the electrolyte to the anode and the cathode to the electrolyte.
- the anode can be formed for example by a cermet, for example comprising nickel and yttrium-stabilized zirconium oxide.
- the electrolyte layer is gastight and can consist for example of yttrium-stabilized zirconium oxide or another oxygen-ion-conducting ceramic.
- the cathode consists of an electronically, or electronically and ionically, conductive ceramic, for example lanthanum strontium cobalt iron oxide.
- a ceramic diffusion barrier layer for example comprising cerium gadolinium oxide.
- a diffusion barrier also between the substrate (FeCr alloy) and the nickel-containing anode.
- Coating with the electrochemically active cell layers can be effected by wet-chemical coating, for example screen printing, or wet powder spraying with subsequent sintering or by thermal spraying processes, for example high-speed flame spraying or plasma spraying.
- the gastight electrolyte layer must seal at least a part of the compressed edge area of the plate.
- the edge area is preferably roughened before coating, for example by a sandblasting process.
- the edge area can first be connected to one or more metallic components, for example the contact plate, before the coating with the electrochemically active cell layers is effected.
- the inventive fuel cell or SOFC with a one-pieced plate having a porous central area as a substrate for the electrochemically active cell layers and a compressed gastight edge area with the gas passages and optionally further structures offers considerable advantages and, above all, cost savings.
- omitting the weld seam between the porous substrate body and the sheet metal frame substantially reduces the production costs.
- a considerable material saving is attained.
- the manufacturing of said one-part plate has the advantage that no connection of microstructurally, much less chemically, different materials is carried out.
- the one-pieced plate additionally offers the possibility of reducing the overall height per cell, because the side, facing the electrochemically active cell layers, of the porous substrate area in the middle of the plate is located at least at a level with the compressed edge of the plate, while according to the prior art, for example EP 1 278259 A2, the edge area of the substrate rests on the sheet metal frame.
- FIG. 1 a perspective exploded representation of two fuel cells of a fuel cell stack
- FIG. 2 a section along the line II-II through the right-hand part of the two fuel cells according to FIG. 1 in an enlarged representation
- FIG. 3 an enlarged representation of the area A of FIG. 2 ;
- FIG. 4 an enlarged partial representation of a front view of the porous body upon pressing into a plate with a central, porous substrate area and compressed edge areas.
- each cell ( 1 ) consists of a powder-metallurgical plate ( 2 ) and a contact plate (interconnector) ( 3 ).
- the powder-metallurgical plate ( 2 ) is configured in one piece and has in the central area a porous substrate area ( 4 ) and a compressed gastight edge area ( 5 ), the porous substrate area ( 4 ) being indicated by dashed lines in FIG. 1 .
- the substrate area ( 4 ) is provided with the electrochemically active cell layers ( 6 ) which consist according to FIG. 3 of an anode layer ( 7 ) on the substrate area ( 4 ), a gastight electrolyte layer ( 8 ) on the anode layer ( 7 ), and a cathode layer ( 9 ) on the electrolyte layer ( 8 ).
- the contact plate ( 3 ) can be a sheet metal shaped part which is provided with a wave structure, channel structure or knobbed structure ( 11 ) or similar projections to form contact portions ( 11 a ) which electroconductively contact the powder-metallurgical plate ( 2 ) and thus the anode layer ( 7 ) of the one fuel cell ( 1 ), and a contact portion ( 11 k ) in electrical contact with the cathode layer ( 9 ) of the neighboring fuel cell ( 1 ).
- the powder-metallurgical plate ( 2 ) and the contact plate ( 3 ) are connected gastightly on the circumference at ( 10 ), for example by welding or soldering. Further, the gastight electrolyte layer ( 8 ) extends on the circumference at least over a part of the compressed edge area ( 5 ) of the powder-metallurgical plate ( 2 ), as to be seen in FIG. 3 .
- the space ( 13 ) is separated gastightly from the space ( 14 ) in which the cathode layer ( 9 ) is disposed.
- the space ( 13 ) in which the anode layer ( 7 ) is gastightly enclosed constitutes the combustion space. It is supplied the fuel gas in the direction of the arrow ( 15 ) shown from the back in FIGS. 2 and 3 .
- the fuel gas can be e.g. hydrogen, methane or another hydrocarbon.
- the space ( 14 ) is supplied the oxidant, for example air or oxygen, according to the arrow ( 16 ) shown from the back.
- the fuel e.g. hydrogen
- the oxidant e.g. oxygen
- accepts electrons in the cathode reaction so that e.g. oxygen anions are formed.
- the anions formed from the oxidant diffuse through the electrolyte layer ( 8 ) and react on the anode side with the cations formed from the fuel gas so as to form waste gas, for example water vapor or carbon dioxide.
- the gastight compressed edge area ( 5 ) of the powder-metallurgical plate ( 2 ) of each cell is provided on each side of the substrate area ( 4 ) with a plurality of gas passages ( 17 ) or ( 18 ).
- the contact plate (interconnector) ( 3 ) has gas passages ( 19 ) or ( 20 ) on the edge area.
- the gas passages ( 17 ) or ( 18 ) and the gas passages ( 19 ) or ( 20 ) of all fuel cells ( 1 ) of the stack are flush with each other.
- the waste gas is removed from the fuel gas space ( 13 ) via the gas passages ( 18 ) and ( 20 ).
- seals ( 22 ) and ( 23 ) on the gas passages ( 17 ) and ( 18 ) of two neighboring fuel cells ( 1 ) the gas passages ( 17 ) to ( 20 ) are sealed gastightly from the oxidant space ( 14 ).
- the fuel cells ( 1 ) are series-connected via the contact plate ( 3 ). That is, current is collected from the uppermost fuel cell and the lowermost fuel cell of the stack.
- a planar, sintered, porous body ( 24 ) is compressed on the edge between a pressing die ( 25 ) and a counter die ( 26 ) to form the compressed gastight edge area ( 5 ) and the intermediate uncompressed, porous substrate area ( 4 ).
- the pressing die is preferably so configured that upon compression a continuous, stepless transition arises between the compressed substrate area ( 4 ) and the edge area ( 5 ).
- the gas passages ( 17 , 18 ) can then be cut or punched on opposing sides of the substrate area ( 4 ), whereupon the electrochemically active cell layer ( 6 ) is applied to the substrate area ( 4 ), namely the electrolyte layer ( 8 ) in such a way that it extends with its total circumference onto the edge area ( 5 ), as shown in FIG. 3 .
Abstract
A fuel cell (1) has a plate (2) produced by powder metallurgy which comprises in one piece a porous substrate area (4) to which the electrochemically active cell layers (6) are applied, and a gastight edge area (5) which is provided with gas passages (17, 18).
Description
- This application is a divisional application of co-pending U.S. patent application Ser. No. 12/668,963, filed on Jan. 13, 2010, which is a 371 of PCT/EP2008/003630 filed May 6, 2008, which claim priority to DE 2007103496, filed Jul. 26, 2007, from which priority is claimed, the disclosure of which is fully incorporated herein by reference.
- This invention relates to a fuel cell having a porous substrate produced by powder metallurgy to which the electrochemically active cell layers are applied and which is disposed in the central area of a plate with gas passages provided in the edge area thereof. It also relates to a method for producing the fuel cell.
- Among the various types of fuel cell, the high temperature fuel cell or solid oxide fuel cell (SOFC) is emerging as particularly suitable on account of its high electrical efficiency and the possible utilization of the waste heat arising in the high temperature range e.g. for stationary cogeneration. It is thus possible to obtain electrical efficiencies of 60% to 70% in hybrid systems in which the SOFC is integrated into gas turbine processes. But also for mobile applications, for example for supplying onboard electrical systems (APU—auxiliary power unit) in trucks or cars, SOFC systems are of great interest. They offer the potential of an efficient and thus fuel-economizing power supply, whereby both conventional fuels (gasoline, diesel, natural gas) and pure hydrogen can be employed.
- While the tubular design is particularly suitable for stationary power plant applications, the planar SOFC offers advantages for decentralized stationary and mobile application because of the shorter current conducting paths and thus higher areal power density.
- The latest generation of SOFCs has a porous metallic body which performs as a substrate the support function for the electrode layers and the electrolyte layer (metal-supported cell, MSC). The MSC is of interest in particular for mobile applications because it possesses better thermal cyclability, high mechanical loading capacity and high reoxidation stability at a low cost of materials and small cell thickness. In addition, the integration of an MSC into a fuel stack can be realized by commercially available soldering and welding processes.
- For the substrate it is customary to employ high-alloy chromium steel. The substrates employed are in particular porous bodies produced by powder metallurgy (AT 008975 U1), woven or knitted fabrics (EP 1318560 A2, WO 02/101859 A2), perforated sheet metal or expanded metal US 2005/142426 A1, GB 2400723 A, GB 2422479 A). In a planar SOFC the substrate can be welded into a sheet metal frame produced by fusion metallurgy and having the gas passages, e.g. the fuel gas and waste gas openings for fuel gas supply and waste gas removal to and from the fuel cell. Thus there is formed a plate with the gas passages or manifold in the edge area. The mutual sealing of the anode-side and cathode-side gas space is effected via the gastight electrolyte which extends from the porous substrate area beyond the weld seam onto the sheet metal frame (
EP 1 278 259 A2). - The substrate can be perforated sheet metal (WO 02/35628 A1), or a body produced by powder metallurgy (EP 1278259 A2).
- The disadvantage of the perforated plates lies primarily in their poor coatability with a fine-structured anode, but also in an irregular gas distribution to the anode. According to US 2005/0175884 A1 it is hence proposed to provide the holes in the metal plate at an angle. However, this is difficult and cost-intensive. According to WO 2004/059765 A2 a filling of the holes of the plate with anode material is proposed to improve the coatability of the substrate. However, it has been found that all holes must be filled without error to guarantee the necessary process reliability. According to WO 2006/138257 A1 there is proposed a fine-structured transition element, e.g. a nickel mesh, between the perforated plate and the anode coating, but this involves additional costs.
- Compared to perforated sheet metal, porous substrates produced by powder metallurgy offer better coatability and gas distribution. To connect the porous substrate gastightly to the sheet metal frame, the edge of the substrate is compressed to be gastight, according to
EP 1 278 259 A2, before it is welded to the sheet metal frame to form the plate. However, the integration of the porous substrate with the sheet metal frame causes microstructurally different, often also different alloys, to be interconnected. For thermomechanical reasons this state is undesirable, because high tensions can be induced into the cell sandwich. Further, the circumferentially formed weld seam between the sheet metal frame and the substrate leads to warpage of the plate. Also, the weld seam itself involves the risk of defects, which would mean a leakage path between anode side and cathode side. Moreover, the substrate welded into a sheet metal frame leads to a high cost of materials, because a high proportion of the sheet metal becomes waste material upon cutting of the frame. - The object of the invention is hence to provide a fuel cell which guarantees a reliable-process coating with anode, electrolyte and cathode and at the same time a suitable basis for the stack integration of the cell at low material usage.
- This is achieved according to the invention by a one-pieced plate produced by powder metallurgy whose central area is of porous configuration to form the substrate, and whose edge area having the gas passages or the “manifold” is compressed to be gastight.
- For producing the plate of the inventive SOFC there is first produced a planar, powder-metallurgical, porous body which preferably consists of an iron-chromium alloy. The body can be produced here according to AT 008 975 U1.
- That is, it can consist of an alloy comprising
- 15 to 35 wt. % Cr;
- 0.01 to 2 wt. % one or more elements of the group Ti, Zr, Hf. Mn, Y, Sc, rare earth metals;
- 0 to 10 wt. % Mo and/or Al; 0 to 5 wt. % one or more metals of the group Ni, W, Nb, Ta;
- 0.1 to 1 wt. % 0;
- balance Fe and impurities, whereby at least one metal of the group Y, Sc, rare earth metals and at least one metal of the group Cr, Ti, Al, Mn can form a mixed oxide.
- The selection of the powder fraction for the body must be made in such a way that defects in the surface which naturally result from deviations from an optimal packing density are kept small enough to guarantee good coatability. For forming the planar, powder-metallurgical, porous body there is preferably employed a powder fraction with a particle size of <150 μm, in particular <100 μm. The use of finer powder fractions would improve coatability further, but entail a worsening of the high temperature oxidation stability on account of a higher internal surface.
- From powder and a binding agent there is produced a planar green body with a thickness of preferably 0.3 to 1.5 mm. After the debindering of the green body the body is sintered, whereby it has a porosity of preferably 20 to 60%, in particular 40 to 50%, after sintering. The porosity is the density of the porous body based on the density of the alloy.
- Subsequently, the edge area of the porous body is compressed until it is gastight. The dimensions of the compressed edge area result from the necessary surface area for the gas passages and sealing surfaces, in particular with the electrolyte layer and the contact plate, as to be explained more closely hereinafter. The contact plate is often also designated an interconnector and is hence to be understood as such.
- The compression of the body in the edge area can be effected by uniaxial pressing or section rolling. The transition between the central porous substrate area of the plate and the compressed edge area can be configured as a step. However, there is preferably produced upon compression a continuous, stepless transition between the substrate area and the compressed edge area, because edges and similar discontinuities can cause tensions in the plate. To obtain a tension release in the structure of the plate after the compression process, there can optionally be added an annealing or similar heat treatment.
- Subsequently, the tight edge area of the plate is provided with the gas passages by stamping, punching, cutting or the like. Optionally, the edge area can be provided with the gas passages in a process step during compression.
- Also, it is possible to provide the edge area of the plate with further structures, for example by stamping stiffening structures and/or connecting structures for example with the electrolyte layer and/or the contact plate.
- Finally, the electrochemically active cell layers are applied, i.e. normally the anode to the substrate area of the plate, the electrolyte to the anode and the cathode to the electrolyte. The anode can be formed for example by a cermet, for example comprising nickel and yttrium-stabilized zirconium oxide. The electrolyte layer is gastight and can consist for example of yttrium-stabilized zirconium oxide or another oxygen-ion-conducting ceramic. The cathode consists of an electronically, or electronically and ionically, conductive ceramic, for example lanthanum strontium cobalt iron oxide.
- Between the electrolyte layer and the cathode there can be provided a ceramic diffusion barrier layer, for example comprising cerium gadolinium oxide. Further, there can be provided a diffusion barrier also between the substrate (FeCr alloy) and the nickel-containing anode.
- Coating with the electrochemically active cell layers can be effected by wet-chemical coating, for example screen printing, or wet powder spraying with subsequent sintering or by thermal spraying processes, for example high-speed flame spraying or plasma spraying.
- To seal the cathode-side oxidant space from the opposing fuel gas space of the plate, the gastight electrolyte layer must seal at least a part of the compressed edge area of the plate. To achieve better adhesion of the electrolyte layer on the compressed edge area, the edge area is preferably roughened before coating, for example by a sandblasting process.
- As an alternative to the direct coating of the substrate area of the one-pieced plate produced by powder metallurgy with a compressed edge area, the edge area can first be connected to one or more metallic components, for example the contact plate, before the coating with the electrochemically active cell layers is effected.
- The inventive fuel cell or SOFC with a one-pieced plate having a porous central area as a substrate for the electrochemically active cell layers and a compressed gastight edge area with the gas passages and optionally further structures offers considerable advantages and, above all, cost savings. Thus, omitting the weld seam between the porous substrate body and the sheet metal frame substantially reduces the production costs. At the same time, a considerable material saving is attained. Further, the manufacturing of said one-part plate has the advantage that no connection of microstructurally, much less chemically, different materials is carried out. In addition, there is no danger of leaks due to cracks or pores in the weld seam. Depending on the construction of the stack, the one-pieced plate additionally offers the possibility of reducing the overall height per cell, because the side, facing the electrochemically active cell layers, of the porous substrate area in the middle of the plate is located at least at a level with the compressed edge of the plate, while according to the prior art, for
example EP 1 278259 A2, the edge area of the substrate rests on the sheet metal frame. - Hereinafter an embodiment of the inventive fuel cell will be explained more closely by way of example with reference to the drawing. Therein are shown:
-
FIG. 1 a perspective exploded representation of two fuel cells of a fuel cell stack; -
FIG. 2 a section along the line II-II through the right-hand part of the two fuel cells according toFIG. 1 in an enlarged representation; -
FIG. 3 an enlarged representation of the area A ofFIG. 2 ; and, -
FIG. 4 an enlarged partial representation of a front view of the porous body upon pressing into a plate with a central, porous substrate area and compressed edge areas. - According to
FIGS. 1 to 3 , each cell (1) consists of a powder-metallurgical plate (2) and a contact plate (interconnector) (3). - The powder-metallurgical plate (2) is configured in one piece and has in the central area a porous substrate area (4) and a compressed gastight edge area (5), the porous substrate area (4) being indicated by dashed lines in
FIG. 1 . - The substrate area (4) is provided with the electrochemically active cell layers (6) which consist according to
FIG. 3 of an anode layer (7) on the substrate area (4), a gastight electrolyte layer (8) on the anode layer (7), and a cathode layer (9) on the electrolyte layer (8). - The contact plate (3) can be a sheet metal shaped part which is provided with a wave structure, channel structure or knobbed structure (11) or similar projections to form contact portions (11 a) which electroconductively contact the powder-metallurgical plate (2) and thus the anode layer (7) of the one fuel cell (1), and a contact portion (11 k) in electrical contact with the cathode layer (9) of the neighboring fuel cell (1).
- According to
FIGS. 2 and 3 , the powder-metallurgical plate (2) and the contact plate (3) are connected gastightly on the circumference at (10), for example by welding or soldering. Further, the gastight electrolyte layer (8) extends on the circumference at least over a part of the compressed edge area (5) of the powder-metallurgical plate (2), as to be seen inFIG. 3 . - Thus, the space (13) is separated gastightly from the space (14) in which the cathode layer (9) is disposed. The space (13) in which the anode layer (7) is gastightly enclosed constitutes the combustion space. It is supplied the fuel gas in the direction of the arrow (15) shown from the back in
FIGS. 2 and 3 . The fuel gas can be e.g. hydrogen, methane or another hydrocarbon. In contrast, the space (14) is supplied the oxidant, for example air or oxygen, according to the arrow (16) shown from the back. - On the anode (7) the fuel, e.g. hydrogen, is oxidized and thus there are extracted therefrom electrons with cation formation which are supplied via the contact plate (3) to the cathode (9) of the neighboring cell (1). The oxidant, e.g. oxygen, accepts electrons in the cathode reaction, so that e.g. oxygen anions are formed. The anions formed from the oxidant diffuse through the electrolyte layer (8) and react on the anode side with the cations formed from the fuel gas so as to form waste gas, for example water vapor or carbon dioxide.
- According to
FIG. 1 , the gastight compressed edge area (5) of the powder-metallurgical plate (2) of each cell is provided on each side of the substrate area (4) with a plurality of gas passages (17) or (18). Likewise, the contact plate (interconnector) (3) has gas passages (19) or (20) on the edge area. The gas passages (17) or (18) and the gas passages (19) or (20) of all fuel cells (1) of the stack are flush with each other. - While the fuel gas is supplied to the fuel gas space (13) through the gas passages (17) and (19), the waste gas is removed from the fuel gas space (13) via the gas passages (18) and (20). By seals (22) and (23) on the gas passages (17) and (18) of two neighboring fuel cells (1) the gas passages (17) to (20) are sealed gastightly from the oxidant space (14).
- The fuel cells (1) are series-connected via the contact plate (3). That is, current is collected from the uppermost fuel cell and the lowermost fuel cell of the stack.
- According to
FIG. 4 , for producing the powder-metallurgical plate (2) a planar, sintered, porous body (24) is compressed on the edge between a pressing die (25) and a counter die (26) to form the compressed gastight edge area (5) and the intermediate uncompressed, porous substrate area (4). - The pressing die is preferably so configured that upon compression a continuous, stepless transition arises between the compressed substrate area (4) and the edge area (5). In the edge area (5) the gas passages (17, 18) can then be cut or punched on opposing sides of the substrate area (4), whereupon the electrochemically active cell layer (6) is applied to the substrate area (4), namely the electrolyte layer (8) in such a way that it extends with its total circumference onto the edge area (5), as shown in
FIG. 3 .
Claims (10)
1. A method for producing a fuel cell having a porous substrate (4) produced by powder metallurgy to which the electrochemically active cell layers (6) are applied and which is disposed in the central area of a plate (2) having gas passages (17, 18) provided in the edge area (5) thereof, the plate (2) being configured in one piece so as to form a substrate area (4) and the edge area (5), and the edge area (5) being gas-tightly compressed, wherein a planar, powder-metallurgical, porous body (24) is produced for forming the plate (2), the edge area of the body (24) is compressed to the point of gas-tightness and is provided with the gas passages (17, 18), and the electrochemically active cell layers (6) are applied to the substrate area (4) of the plate (2), characterized in that the compression of the edge area of the body (24) to the edge area (5) of the plate (2) is effected by uniaxial pressing or rolling.
2. The method according to claim 1 , wherein the electrolyte layer (8) of the electrochemically active cell layers (6) borders gas-tightly on the gas-tight edge area (5) of the plate (2).
3. The method according to claim 1 , wherein the electrolyte layer (8) of the electrochemically active cell layers (6) extends with its total circumference at least on a part of the compressed edge area (5) of the plate (2).
4. The method according to claim 1 , wherein the plate (2) is connected on the circumference gas-tightly to a contact plate (3).
5. The method according to claim 1 , wherein a powder with a particle size of <150 μm is employed for forming the planar, powder-metallurgical, porous body (24).
6. The method according to claim 1 , characterized in that the porous body (24) has a porosity of 20 to 60%.
7. The method according to claim 1 , characterized in that upon compression a continuous transition is produced between the compressed edge area (5) and the intermediate substrate area (4) of the plate (2).
8. The method according to claim 1 , characterized in that the electrolyte layer (8) of the electrochemically active cell layers (6) is so applied that it extends at least onto a part of the compressed edge area (5) of the plate (2).
9. The method according to claim 8 , characterized in that the edge area (5) of the plate (2) is roughened before application of the electrolyte layer (8).
10. The method according to claim 1 , wherein the body is first sintered to obtain a porous body, and the compression of the edge area of the body (24) to the edge area (5) of the plate (2) is then effected by uniaxial pressing or rolling.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/956,864 US20160093900A1 (en) | 2007-07-26 | 2015-12-02 | Fuel cell and method for the production thereof |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007034967A DE102007034967A1 (en) | 2007-07-26 | 2007-07-26 | Fuel cell and process for its production |
DE2007103496 | 2007-07-26 | ||
PCT/EP2008/003630 WO2009012829A1 (en) | 2007-07-26 | 2008-05-06 | Fuel cell and method for the production thereof |
US12/668,963 US9680163B2 (en) | 2007-07-26 | 2008-05-06 | Fuel cell and method for production thereof |
US14/956,864 US20160093900A1 (en) | 2007-07-26 | 2015-12-02 | Fuel cell and method for the production thereof |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/003630 Division WO2009012829A1 (en) | 2007-07-26 | 2008-05-06 | Fuel cell and method for the production thereof |
US12/668,963 Division US9680163B2 (en) | 2007-07-26 | 2008-05-06 | Fuel cell and method for production thereof |
Publications (1)
Publication Number | Publication Date |
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US20160093900A1 true US20160093900A1 (en) | 2016-03-31 |
Family
ID=39560900
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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US12/668,963 Expired - Fee Related US9680163B2 (en) | 2007-07-26 | 2008-05-06 | Fuel cell and method for production thereof |
US14/956,864 Abandoned US20160093900A1 (en) | 2007-07-26 | 2015-12-02 | Fuel cell and method for the production thereof |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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US12/668,963 Expired - Fee Related US9680163B2 (en) | 2007-07-26 | 2008-05-06 | Fuel cell and method for production thereof |
Country Status (8)
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US (2) | US9680163B2 (en) |
EP (1) | EP2174371B1 (en) |
JP (1) | JP5529734B2 (en) |
KR (1) | KR101531538B1 (en) |
CN (1) | CN101790808B (en) |
DE (1) | DE102007034967A1 (en) |
DK (1) | DK2174371T3 (en) |
WO (1) | WO2009012829A1 (en) |
Cited By (2)
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US10978714B2 (en) | 2017-07-31 | 2021-04-13 | Nissan Motor Co., Ltd. | Fuel battery cell |
US11088381B2 (en) | 2017-08-01 | 2021-08-10 | Nissan Motor Co., Ltd. | Cell unit |
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DE102009006925B4 (en) | 2009-02-02 | 2023-03-23 | Sunfire Gmbh | Interconnector arrangement for a fuel cell stack |
WO2012097286A1 (en) * | 2011-01-13 | 2012-07-19 | Deeya Energy, Inc. | Flow cell stack |
DE102013008473A1 (en) * | 2013-05-21 | 2014-11-27 | Plansee Composite Materials Gmbh | FUEL CELL |
JP6521064B2 (en) * | 2015-06-09 | 2019-05-29 | 日産自動車株式会社 | Solid oxide fuel cell |
AT14455U3 (en) | 2015-07-14 | 2017-05-15 | Plansee Se | Electrochemical module |
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DE102016223781A1 (en) | 2016-11-30 | 2018-05-30 | Robert Bosch Gmbh | Fuel cell with improved robustness |
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AT15921U1 (en) | 2017-03-16 | 2018-09-15 | Plansee Se | Porous molding for electrochemical module |
AT16015U1 (en) * | 2017-04-19 | 2018-11-15 | Plansee Se | Electrode-electrolyte unit |
DE102017215549A1 (en) | 2017-09-05 | 2019-03-07 | Robert Bosch Gmbh | Fuel cell with improved robustness |
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GB2368450B (en) * | 2000-10-25 | 2004-05-19 | Imperial College | Fuel cells |
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- 2007-07-26 DE DE102007034967A patent/DE102007034967A1/en not_active Withdrawn
-
2008
- 2008-05-06 WO PCT/EP2008/003630 patent/WO2009012829A1/en active Application Filing
- 2008-05-06 CN CN2008801006309A patent/CN101790808B/en not_active Expired - Fee Related
- 2008-05-06 KR KR1020107001347A patent/KR101531538B1/en active IP Right Grant
- 2008-05-06 US US12/668,963 patent/US9680163B2/en not_active Expired - Fee Related
- 2008-05-06 EP EP08749351.6A patent/EP2174371B1/en not_active Not-in-force
- 2008-05-06 DK DK08749351.6T patent/DK2174371T3/en active
- 2008-05-06 JP JP2010517278A patent/JP5529734B2/en not_active Expired - Fee Related
-
2015
- 2015-12-02 US US14/956,864 patent/US20160093900A1/en not_active Abandoned
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US10978714B2 (en) | 2017-07-31 | 2021-04-13 | Nissan Motor Co., Ltd. | Fuel battery cell |
US11088381B2 (en) | 2017-08-01 | 2021-08-10 | Nissan Motor Co., Ltd. | Cell unit |
Also Published As
Publication number | Publication date |
---|---|
KR101531538B1 (en) | 2015-06-25 |
KR20100036332A (en) | 2010-04-07 |
JP2010534901A (en) | 2010-11-11 |
CN101790808B (en) | 2013-11-27 |
EP2174371B1 (en) | 2013-07-24 |
CN101790808A (en) | 2010-07-28 |
US20100173217A1 (en) | 2010-07-08 |
WO2009012829A1 (en) | 2009-01-29 |
US9680163B2 (en) | 2017-06-13 |
EP2174371A1 (en) | 2010-04-14 |
DK2174371T3 (en) | 2013-08-26 |
DE102007034967A1 (en) | 2009-01-29 |
JP5529734B2 (en) | 2014-06-25 |
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