US2014044A - Method of cleaning gas - Google Patents

Method of cleaning gas Download PDF

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Publication number
US2014044A
US2014044A US726404A US72640434A US2014044A US 2014044 A US2014044 A US 2014044A US 726404 A US726404 A US 726404A US 72640434 A US72640434 A US 72640434A US 2014044 A US2014044 A US 2014044A
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gas
oil
dust
blast furnace
gases
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US726404A
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Arthur B Haswell
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning

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  • This invention relates to an improved method for treating gas and aims to provide for the conservation of the sensible heat of such gas.
  • the invention will be apparent from the following detailed disclosures when read in connection with the accompanying drawings and will bedefined with particularity in the appended claims.
  • the invention is exemplified by the steps of the process in the following specification and by the apparatus shown in the drawings for performing such steps. i
  • Figul is illustrative of suitable apparatus tor practicing the invention, the view being partly in elevation and partly in vertical section;
  • Dry methods involve the use of centrifugal force and electrical precipitation and the passing of dust laden gases at slow velocities to extremely large gas containers, in order that the dust may settle by gravity at the bottom thereof.
  • cold or cool water is usually supplied in the necessary amounts by means or equipment designed to bring the hot gases into intimate contact with the washing water, care being taken to provide a sumcient volume of water for any given temperature, so as to keep the heat absorbed from the hot dust laden gases from raising the temperature of the water to 212 degrees F.
  • the hot water resulting from prior practice is usually discharged and fresh cool or cold water is continuously supplied to replace the ejected hot water. The outgoing hot water thus carries away a large percentage of the sensible heat.
  • My invention aims to overcome the shortcom- 5 ings of the prior practice and to conserve the sensible heat in the hot gases.
  • I use a liquid other than water whose boiling or vaporizing point is above the temperature of the dust laden gas to be cleaned. It is apparent that 10 such high boiling point liquid, if recirculated will not take away the sensible heat from the'gases other than that amount of sensible heat required to initially raise the temperature of the body of liquid used for the wet washing. 15
  • the invention while not limited thereto, is particularly well suited for use in cleaning blast furnace gases.
  • Suchgas on ejection from the furnace has a temperature in the neighborhood of 400 degrees F., and I- have discovered that it can 20 be effectively cleaned withoutan appreciable loss of sensible heat by subjecting the gas to the Washing action ofiinely divided jets or sprays of fuel oil, whose boiling point is approximately 570 degrees F.
  • fuel oil can be readily and 25 economically secured and the difference between its boiling point and the normal temperature of the efiuent gases from a blast furnace are such that the washing oil will not be vaporized and there will be little or no oil loss, hence the same 30 can be recirculated repeatedly, the precipitated dust being periodically withdrawn as a sludge.
  • Such sludge is useful in the process because upon withdrawal it is in excellent condition for recharging into the blast furnace. 35
  • the entrained oil and coke dust are recovered as fuel in the blast furnace and the ore dust will have the same value as the ore normally charged to the furnace. It is understood that the coke dust and ore dust just referred to are the dust 40 particles removed by the oil spray.
  • ill conventionally represents a blast furnace having a downtake it through which the dust laden 4 gases are elected. These gases are led to an annular pipe it which surrounds the cylindrical washer or tower i6 supported by suitable columns, or other structural members ill.
  • the dirty gas flows from the pipe M by Way of so tuyeres ii to the washer it.
  • the lower part of the washer, as indicated at 20, is of substan tially conical form and provides a chamber 22, in which the oil and dust particles separate as will hereinafter appear.
  • a bell it carried on a 55 7 upper part of the body of oil in the washer by way of pipe 34, such oil being forced by means of pipes 36 and branch 38 to a plurality of spray pipes 40 and 42, located in the. washer at a plane above the tuyeres 15.
  • the dust laden gas ejected from the blast furnace through the -tuyeres l5 flows upwardly and is caused to comingle with the sprays of high boiling point oil, the clean hot gas being passed out through an oiftake duct 44.
  • I may provide a settling box 46, such as shown in Figs. 2 to 4 inclusive.
  • This box will be connected with the washer tank by pipe 34 and with pump by pipe 34.
  • the pump serving to recirculate the washing oil by way of pipe 36 to the spray pipes 40 and 42.
  • the settling box will have a plurality of baflles 48 therein, so as to compel the eilluent liquid from the washer to travel in a circuitous path, in order to facilitate the settling out of the dust particles in the separate zones defined by the baffles or weirs 48. It is contemplated that the settling box 46 may be covered with suitable insulating material so as to retain the heat in the oil or to prevent its loss of heat by radiation.
  • the method which comprises subjecting such dust laden gas to the action of a spray of fuel oil whose boiling point is higher than the temperature of such gas.
  • the method which comprises subjecting a supply of said gas at a temperature of approximately 400 degrees F., to the spraying action of fuel oil whose boiling point is approximately 5'70 degrees F., and reusing the same oil for such spraying action so as to conserve the sensible heat of the hot blast furnace gas.
  • the method which comprises subjecting the dust laden gas ejected from the furnace to the action of a spray of hot oil whose boiling point is higher than the temperature of the gas.
  • the method which comprises subjecting the dust laden gas ejected from the furnace to the action of a spray of hot oil whose boiling point is higher than the temperature of the gas, collecting the oil and precipitated dust resulting from said spraying and utilizing the collected oil for such spraying.
  • the method which comprises subjecting dust laden gas ejected from a blast furnace to the action of a spray of hot oil whose boiling point is higher than the temperature of such gas, collecting the oil and precipitated dust resulting from such spraying and recirculating part of the collected oil to produce said oil spray.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Description

- Sept. 10, 1935. A. B; HASWELL 2,014,044
' METHOD OF CLEANING GAS Filed May 18, 1934 2 Sheets-Sheet l Aer/vale BfiJM ELL ATTORNEYS r P 10, 1935- A. B. HASWELL 2,014,044
METHOD OF CLEANING GAS Filed May 18, 1954 2 Sheets-Sheet 2 r r f INVENTOR 14E THU/e 5. 15 215144541.
ATTORN EYS Patented Sept. 10, 1935 UNITED STATES PATENT OFFICET Arthur B. Hasweil, Birmingham, Ala. Application May 18, 1934, Serial No. 726,404
'iClaims.
This invention relates to an improved method for treating gas and aims to provide for the conservation of the sensible heat of such gas. The invention will be apparent from the following detailed disclosures when read in connection with the accompanying drawings and will bedefined with particularity in the appended claims. The invention is exemplified by the steps of the process in the following specification and by the apparatus shown in the drawings for performing such steps. i
In the drawings Figul is illustrative of suitable apparatus tor practicing the invention, the view being partly in elevation and partly in vertical section; Figs. 2, 3 and 4 represent apparatus to be used in a slightly modified manner of practicing the inven= tion.
Heretoi'ore, blast furnace and other dust laden gases have been cleaned in many different ways. There is a main general line of distinction between known methods, namely, the dry methods and the wet methods. Dry methods involve the use of centrifugal force and electrical precipitation and the passing of dust laden gases at slow velocities to extremely large gas containers, in order that the dust may settle by gravity at the bottom thereof.
Many of the wet methods utilize water as the washing medium and various expedients have been utilized for bringing the dust laden gases into intimate contact with water so as to precipi= tate the dust. Where water is the washing medium, the same must obviously be kept below a temperature of 212 degrees F., at which temper-= ature it vaporizes. The ejected flue gases irom blast furnaces are generally of a temperature ap= proximating 400 degrees F. When such highly heated gases are brought into intimate contact with water, which essentially must be below 212' degrees F., it is clear that the gases must give up part of their sensible heat to the water. Or, if the water used is maintained at a temperature approximating its boiling point the heat from the dust laden gases will vaporize it. This is undesirable and for this reason cold or cool water is usually supplied in the necessary amounts by means or equipment designed to bring the hot gases into intimate contact with the washing water, care being taken to provide a sumcient volume of water for any given temperature, so as to keep the heat absorbed from the hot dust laden gases from raising the temperature of the water to 212 degrees F. The hot water resulting from prior practice is usually discharged and fresh cool or cold water is continuously supplied to replace the ejected hot water. The outgoing hot water thus carries away a large percentage of the sensible heat.
My invention aims to overcome the shortcom- 5 ings of the prior practice and to conserve the sensible heat in the hot gases. To these ends, I use a liquid other than water whose boiling or vaporizing point is above the temperature of the dust laden gas to be cleaned. It is apparent that 10 such high boiling point liquid, if recirculated will not take away the sensible heat from the'gases other than that amount of sensible heat required to initially raise the temperature of the body of liquid used for the wet washing. 15
The invention, while not limited thereto, is particularly well suited for use in cleaning blast furnace gases. Suchgas on ejection from the furnace has a temperature in the neighborhood of 400 degrees F., and I- have discovered that it can 20 be effectively cleaned withoutan appreciable loss of sensible heat by subjecting the gas to the Washing action ofiinely divided jets or sprays of fuel oil, whose boiling point is approximately 570 degrees F. Such fuel oil can be readily and 25 economically secured and the difference between its boiling point and the normal temperature of the efiuent gases from a blast furnace are such that the washing oil will not be vaporized and there will be little or no oil loss, hence the same 30 can be recirculated repeatedly, the precipitated dust being periodically withdrawn as a sludge. Such sludge is useful in the process because upon withdrawal it is in excellent condition for recharging into the blast furnace. 35 The entrained oil and coke dust are recovered as fuel in the blast furnace and the ore dust will have the same value as the ore normally charged to the furnace. It is understood that the coke dust and ore dust just referred to are the dust 40 particles removed by the oil spray.
Referring to the drawings which illustrate by way 0! example my gas cleaning method, ill conventionally represents a blast furnace having a downtake it through which the dust laden 4 gases are elected. These gases are led to an annular pipe it which surrounds the cylindrical washer or tower i6 supported by suitable columns, or other structural members ill. The dirty gas flows from the pipe M by Way of so tuyeres ii to the washer it. The lower part of the washer, as indicated at 20, is of substan tially conical form and provides a chamber 22, in which the oil and dust particles separate as will hereinafter appear. A bell it carried on a 55 7 upper part of the body of oil in the washer by way of pipe 34, such oil being forced by means of pipes 36 and branch 38 to a plurality of spray pipes 40 and 42, located in the. washer at a plane above the tuyeres 15. Thus the dust laden gas ejected from the blast furnace through the -tuyeres l5, flows upwardly and is caused to comingle with the sprays of high boiling point oil, the clean hot gas being passed out through an oiftake duct 44.
From the foregoing, it will be understood that, once the body of high boiling point washing oil 'is brought substantially to the temperature of the blast furnace gas being heated, by continually or repeatedly circulating or utilizing the same 011 for the washing jets or sprays, practically no further sensible heat of the dirty gases will be lost. It will also be appreciated that by utilizing oil of a higher boiling point than the temperature of the gas being handled, the same will not be vaporized and passed off. Thus the same 011 will be repeatedly used for the washing sprays.
If desired, instead of depending upon the precipitation of the dust particles or sludge in the bottom of the washer, I may provide a settling box 46, such as shown in Figs. 2 to 4 inclusive.
This box will be connected with the washer tank by pipe 34 and with pump by pipe 34. The pump serving to recirculate the washing oil by way of pipe 36 to the spray pipes 40 and 42. The settling box will have a plurality of baflles 48 therein, so as to compel the eilluent liquid from the washer to travel in a circuitous path, in order to facilitate the settling out of the dust particles in the separate zones defined by the baffles or weirs 48. It is contemplated that the settling box 46 may be covered with suitable insulating material so as to retain the heat in the oil or to prevent its loss of heat by radiation.
While the invention has been described with particular reference to the cleaning of blast furnace gases, it will be understood that it is not limited thereto, it being well applicable to the cleaning of other gases. It is also to be understood that, while I refer to the use of high boiling point fuel oil as a washing medium, high boiling point liquids other than 011 can also be used so long as they do not vaporize at the temperature of the gas being'subjected to washing treatment.
Since various modifications may be made by those skilled in the art, it is tobe understood that the drawings and description are to be construed in an illustrative rather than a limiting sense and that the claims are to be interpreted as broadly as is consistent with the teachings of the prior art.
What I claim is:-
1. In the cleaning of dust laden blast furnace gas, the method which comprises subjecting such dust laden gas to the action of a spray of fuel oil whose boiling point is higher than the temperature of such gas.
-2. In the cleaning of dust laden blast furnace gas, the method which comprises subjecting a supply of said gas at a temperature of approximately 400 degrees F., to the spraying action of fuel oil whose boiling point is approximately 5'70 degrees F., and reusing the same oil for such spraying action so as to conserve the sensible heat of the hot blast furnace gas.
3. In the cleaning of blast furnace gas, the method which comprises subjecting the dust laden gas ejected from the furnace to the action of a spray of hot oil whose boiling point is higher than the temperature of the gas.
4. In the cleaning of blast furnace gas, the method which comprises subjecting the dust laden gas ejected from the furnace to the action of a spray of hot oil whose boiling point is higher than the temperature of the gas, collecting the oil and precipitated dust resulting from said spraying and utilizing the collected oil for such spraying.
5. In the cleaning of blast furnace gas, the method which comprises subjecting dust laden gas ejected from a blast furnace to the action of a spray of hot oil whose boiling point is higher than the temperature of such gas, collecting the oil and precipitated dust resulting from such spraying and recirculating part of the collected oil to produce said oil spray.
6. In the cleaning of blast furnace gas, the method which comprises subjecting dust laden gas ejected from a blast furnace to the action of a spray of hot oil whose boiling point is higher than the temperature of such gas, collecting the 4,
oil and precipitated dust resulting from such spraying and recirculating part of the collected oil to produce said oil spray and utilizing the sludge of precipitated dust as part of the blast furnace charge.
7. In the cleaning of blast furnace gas, the
oil and precipitated dust resulting from such' .spraying and recirculating part of the collected oil to produce said 011 spray, periodically withdrawing the precipitated dust sludge and charging it to a blast furnace.
ARTHUR B. HASWELL.
US726404A 1934-05-18 1934-05-18 Method of cleaning gas Expired - Lifetime US2014044A (en)

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Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2561347A (en) * 1948-08-20 1951-07-24 Theodore G Kennard Charging top for cupola furnaces
US2831762A (en) * 1954-04-06 1958-04-22 Waagner Biro Ag Treating converter waste gases
US2868853A (en) * 1956-10-25 1959-01-13 Ethyl Corp Acid scrubber
US2868852A (en) * 1956-10-25 1959-01-13 Ethyl Corp Oil scrubber
US3527696A (en) * 1969-12-17 1970-09-08 Wallover Oil Co Method and apparatus for reclaiming waste industrial oils
US3607217A (en) * 1968-12-11 1971-09-21 Exxon Research Engineering Co Agglomeration of particulate metals
US4312646A (en) * 1977-11-17 1982-01-26 Ciba-Geigy Corporation Gas scrubbing tower
US5502245A (en) * 1995-06-07 1996-03-26 Twenty-First Century Research Corporation Methods of making intermediate oxidation products by controlling transient conversion in an atomized liquid
US5558842A (en) * 1995-06-07 1996-09-24 Twenty-First Century Research Corporation Devices for making reaction products by controlling pre-coalescing temperature and transient temperature difference in an atomized liquid
US5580531A (en) * 1995-06-07 1996-12-03 Twenty-First Century Research Corporation Devices for making reaction products by controlling transient conversion in an atomized liquid
US5654475A (en) * 1996-03-25 1997-08-05 Twenty-First Century Research Corporation Methods of making intermediate oxidation products by controlling oxidation rates in an atomized liquid
US5801282A (en) * 1995-06-07 1998-09-01 Twenty-First Century Research Corporation Methods of making intermediate oxidation products by controlling pre-coalescing temperature and transient temperature difference in an atomized liquid
US5801273A (en) * 1996-08-21 1998-09-01 Twenty-First Century Research Corporation Methods and devices for controlling the reaction rate of a hydrocarbon to an intermediate oxidation product by pressure drop adjustments
US5817868A (en) * 1996-11-12 1998-10-06 Twenty-First Century Research Corporation Method and devices for controlling the oxidation of a hydrocarbon to an acid by regulating temperature/conversion relationship in multi-stage arrangements
US5824819A (en) * 1996-12-18 1998-10-20 Twenty-First Century Research Corporation Methods of preparing an intermediate oxidation product from a hydrocarbon by utilizing an activated initiator
US5883292A (en) * 1996-01-17 1999-03-16 Twenty-First Century Research Corporation Reaction control by regulating internal condensation inside a reactor
US5908589A (en) * 1997-12-08 1999-06-01 Twenty-First Century Research Corporation Methods for separating catalyst from oxidation mixtures containing dibasic acids
US5922908A (en) * 1996-06-24 1999-07-13 Twenty-First Century Research Corporation Methods for preparing dibasic acids
US5929277A (en) * 1997-09-19 1999-07-27 Twenty-First Century Research Corporation Methods of removing acetic acid from cyclohexane in the production of adipic acid
US5938820A (en) * 1996-06-27 1999-08-17 Cmi-Schneible Company Air and gas scrubber using recycled water mixture
US6037491A (en) * 1997-07-25 2000-03-14 Rpc Inc. Methods and devices for controlling hydrocarbon oxidations to respective acids by adjusting the solvent to hydrocarbon ratio
US6039902A (en) * 1996-06-24 2000-03-21 Rpc Inc. Methods of recycling catalyst in oxidations of hydrocarbons
US6051055A (en) * 1996-02-01 2000-04-18 Mitsubishi Heavy Industries, Ltd. Exhaust gas desulfurization system
US6103933A (en) * 1996-11-07 2000-08-15 Rpc Inc. Methods for controlling the oxidation rate of a hydrocarbon by adjusting the ratio of the hydrocarbon to a rate-modulator
US6129875A (en) * 1998-02-19 2000-10-10 Rpc Inc. Process of separating catalyst from oxidation mixtures
US6143927A (en) * 1996-06-24 2000-11-07 Rpc Inc. Methods for removing catalyst after oxidation of hydrocarbons
US6218573B1 (en) 1998-07-02 2001-04-17 Rpc Inc. Methods of recovering catalyst in solution in the oxidation of cyclohexane to adipic acid
US6232495B1 (en) 1998-02-09 2001-05-15 Rpc Inc. Methods for treating cobalt catalyst in oxidation mixtures resulting from oxidation of hydrocarbons to dibasic acids
US6288270B1 (en) 1996-06-24 2001-09-11 Rpc Inc. Methods for controlling the reaction rate of a hydrocarbon to an acid by making phase-related adjustments
US6288274B1 (en) 1996-08-21 2001-09-11 Rpc Inc. Methods and devices for controlling the reaction rate and/or reactivity of hydrocarbon to an intermediate oxidation product by adjusting the oxidant consumption rate
US20010053864A1 (en) * 1996-08-21 2001-12-20 Decoster David C. Devices for controlling the reaction rate and/or reactivity of hydrocarbon to an intermediate oxidation product by adjusting the oxidant consumption rate
US6337051B1 (en) 1996-06-24 2002-01-08 Rpc Inc. Device for detecting formation of a second liquid phase
US6340420B1 (en) 1998-07-06 2002-01-22 Rpc Inc. Methods of treating the oxidation mixture of hydrocarbons to respective dibasic acids
US6417128B1 (en) 1999-04-20 2002-07-09 Rpc, Inc. Methods and replacing water and cyclohexanone with acetic acid in aqueous solutions of catalyst

Cited By (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2561347A (en) * 1948-08-20 1951-07-24 Theodore G Kennard Charging top for cupola furnaces
US2831762A (en) * 1954-04-06 1958-04-22 Waagner Biro Ag Treating converter waste gases
US2868853A (en) * 1956-10-25 1959-01-13 Ethyl Corp Acid scrubber
US2868852A (en) * 1956-10-25 1959-01-13 Ethyl Corp Oil scrubber
US3607217A (en) * 1968-12-11 1971-09-21 Exxon Research Engineering Co Agglomeration of particulate metals
US3527696A (en) * 1969-12-17 1970-09-08 Wallover Oil Co Method and apparatus for reclaiming waste industrial oils
US4312646A (en) * 1977-11-17 1982-01-26 Ciba-Geigy Corporation Gas scrubbing tower
US5801282A (en) * 1995-06-07 1998-09-01 Twenty-First Century Research Corporation Methods of making intermediate oxidation products by controlling pre-coalescing temperature and transient temperature difference in an atomized liquid
US5502245A (en) * 1995-06-07 1996-03-26 Twenty-First Century Research Corporation Methods of making intermediate oxidation products by controlling transient conversion in an atomized liquid
US5558842A (en) * 1995-06-07 1996-09-24 Twenty-First Century Research Corporation Devices for making reaction products by controlling pre-coalescing temperature and transient temperature difference in an atomized liquid
US5580531A (en) * 1995-06-07 1996-12-03 Twenty-First Century Research Corporation Devices for making reaction products by controlling transient conversion in an atomized liquid
US5883292A (en) * 1996-01-17 1999-03-16 Twenty-First Century Research Corporation Reaction control by regulating internal condensation inside a reactor
US5939582A (en) * 1996-01-17 1999-08-17 Twenty-First Century Research Corporation Reaction control by regulating internal condensation inside a reactor
US6051055A (en) * 1996-02-01 2000-04-18 Mitsubishi Heavy Industries, Ltd. Exhaust gas desulfurization system
US5654475A (en) * 1996-03-25 1997-08-05 Twenty-First Century Research Corporation Methods of making intermediate oxidation products by controlling oxidation rates in an atomized liquid
US6337051B1 (en) 1996-06-24 2002-01-08 Rpc Inc. Device for detecting formation of a second liquid phase
US6294689B1 (en) 1996-06-24 2001-09-25 Rpc Inc. Methods for removing catalyst after oxidation of hydrocarbons
US6288270B1 (en) 1996-06-24 2001-09-11 Rpc Inc. Methods for controlling the reaction rate of a hydrocarbon to an acid by making phase-related adjustments
US5922908A (en) * 1996-06-24 1999-07-13 Twenty-First Century Research Corporation Methods for preparing dibasic acids
US6156868A (en) * 1996-06-24 2000-12-05 Rpc Inc. Methods for preparing polymers from dibasic acids
US6143927A (en) * 1996-06-24 2000-11-07 Rpc Inc. Methods for removing catalyst after oxidation of hydrocarbons
US6039902A (en) * 1996-06-24 2000-03-21 Rpc Inc. Methods of recycling catalyst in oxidations of hydrocarbons
US6359173B1 (en) 1996-06-24 2002-03-19 Rpc Inc. Methods and devices for oxidizing a hydrocarbon to form an acid
US5938820A (en) * 1996-06-27 1999-08-17 Cmi-Schneible Company Air and gas scrubber using recycled water mixture
US5877341A (en) * 1996-08-21 1999-03-02 Twenty-First Century Research Corporation Methods and devices for controlling the reaction rate of a hydrocarbon to an intermediate oxidation product by pressure drop adjustments
US6288274B1 (en) 1996-08-21 2001-09-11 Rpc Inc. Methods and devices for controlling the reaction rate and/or reactivity of hydrocarbon to an intermediate oxidation product by adjusting the oxidant consumption rate
US6183698B1 (en) 1996-08-21 2001-02-06 Rpc Inc. Devices for controlling the reaction rate of a hydrocarbon to an intermediate oxidation product by pressure drop adjustments
US20010053864A1 (en) * 1996-08-21 2001-12-20 Decoster David C. Devices for controlling the reaction rate and/or reactivity of hydrocarbon to an intermediate oxidation product by adjusting the oxidant consumption rate
US5801273A (en) * 1996-08-21 1998-09-01 Twenty-First Century Research Corporation Methods and devices for controlling the reaction rate of a hydrocarbon to an intermediate oxidation product by pressure drop adjustments
US6103933A (en) * 1996-11-07 2000-08-15 Rpc Inc. Methods for controlling the oxidation rate of a hydrocarbon by adjusting the ratio of the hydrocarbon to a rate-modulator
US5998572A (en) * 1996-11-12 1999-12-07 Rpc Inc. Methods and devices for controlling the oxidation of a hydrocarbon to an acid by regulating temperature/conversion relationship in multi-stage arrangements
US5817868A (en) * 1996-11-12 1998-10-06 Twenty-First Century Research Corporation Method and devices for controlling the oxidation of a hydrocarbon to an acid by regulating temperature/conversion relationship in multi-stage arrangements
US5980801A (en) * 1996-12-18 1999-11-09 Twenty-First Century Research Corporation Methods of preparing an intermediate oxidation product from a hydrocarbon by utilizing an activated initiator
US5824819A (en) * 1996-12-18 1998-10-20 Twenty-First Century Research Corporation Methods of preparing an intermediate oxidation product from a hydrocarbon by utilizing an activated initiator
US6037491A (en) * 1997-07-25 2000-03-14 Rpc Inc. Methods and devices for controlling hydrocarbon oxidations to respective acids by adjusting the solvent to hydrocarbon ratio
US5929277A (en) * 1997-09-19 1999-07-27 Twenty-First Century Research Corporation Methods of removing acetic acid from cyclohexane in the production of adipic acid
US6177053B1 (en) 1997-09-19 2001-01-23 Rpc Inc. Devices for removing acetic acid from cyclohexane in the production of adipic acid
US5908589A (en) * 1997-12-08 1999-06-01 Twenty-First Century Research Corporation Methods for separating catalyst from oxidation mixtures containing dibasic acids
US6326455B2 (en) 1998-02-09 2001-12-04 Rpc Inc. Methods for treating cobalt catalyst in oxidation mixtures resulting from oxidation of hydrocarbons to dibasic acids
US6232495B1 (en) 1998-02-09 2001-05-15 Rpc Inc. Methods for treating cobalt catalyst in oxidation mixtures resulting from oxidation of hydrocarbons to dibasic acids
US6129875A (en) * 1998-02-19 2000-10-10 Rpc Inc. Process of separating catalyst from oxidation mixtures
US6218573B1 (en) 1998-07-02 2001-04-17 Rpc Inc. Methods of recovering catalyst in solution in the oxidation of cyclohexane to adipic acid
US6433220B1 (en) 1998-07-02 2002-08-13 Rpc Inc. Methods of extracting catalyst from a reaction mixture in the oxidation of cyclohexane to adipic acid
US6433221B1 (en) 1998-07-02 2002-08-13 Rpc Inc. Methods of separating catalyst in solution from a reaction mixture produced by oxidation of cyclohexane to adipic acid
US6340420B1 (en) 1998-07-06 2002-01-22 Rpc Inc. Methods of treating the oxidation mixture of hydrocarbons to respective dibasic acids
US6417128B1 (en) 1999-04-20 2002-07-09 Rpc, Inc. Methods and replacing water and cyclohexanone with acetic acid in aqueous solutions of catalyst

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