US20140314629A1 - Hybrid gasification system - Google Patents
Hybrid gasification system Download PDFInfo
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- US20140314629A1 US20140314629A1 US14/366,007 US201214366007A US2014314629A1 US 20140314629 A1 US20140314629 A1 US 20140314629A1 US 201214366007 A US201214366007 A US 201214366007A US 2014314629 A1 US2014314629 A1 US 2014314629A1
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- reaction chamber
- synthetic gas
- gasifier
- gasification system
- flow path
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- 238000002309 gasification Methods 0.000 title claims abstract description 57
- 238000006243 chemical reaction Methods 0.000 claims abstract description 84
- 239000000446 fuel Substances 0.000 claims abstract description 27
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- 238000002347 injection Methods 0.000 claims description 14
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- 239000002910 solid waste Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 7
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- 239000002028 Biomass Substances 0.000 description 18
- 229940090044 injection Drugs 0.000 description 12
- 238000000034 method Methods 0.000 description 10
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- 230000008569 process Effects 0.000 description 8
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C10J3/56—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/482—Gasifiers with stationary fluidised bed
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/485—Entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Definitions
- the present invention relates to a hybrid gasification system, and more particularly, to a hybrid gasification system which simultaneously has the advantages of entrained-flow gasifier using pulverized fuel and a fluidized-bed gasifier utilized for gasifying fuel with relatively various properties.
- Bio-mass is an organic material derived through photosynthesis of a plant. Since bio-mass is widely distributed and used, is cleaner than fossil fuel, and generates no CO2, bio-mass attracts much attention as an important renewable energy. Bio-mass can be converted into synthetic gas or liquefied fuel through such a method as thermal chemistry or biochemistry, and can be applied to power generation, industrial fuel, or chemical industry products. Thus, bio-mass may replace a considerable amount of fossil fuel without changing the existing energy conversion systems. Therefore, bio-mass is being preferentially developed by various countries.
- Bio-mass may be converted into synthetic gas or liquefied fuel through various kinds of methods, and the bio-mass gasification technology is viable for a larger number of types of available bio-masses and has greater expandability than other technologies.
- the gasification process for bio-mass is performed through a thermal-chemistry conversion process in which a solid bio-mass material and a gasification agent (air, oxygen, vapor, or carbon dioxide) produce a chemical reaction under a high-temperature condition such that the solid bio-mass material is converted into a gas mixture based on hydrocarbon containing carbon, hydrogen, and oxygen.
- a gasification agent air, oxygen, vapor, or carbon dioxide
- the gas mixture is typically referred to as synthetic gas.
- the composition of the synthetic gas generated during the gasification process may be primarily influenced by the material characteristics of the bio-mass used during the gasification process, and differ depending on the type of the gasification agent, the type of a gasifier, and the reaction condition of temperature and pressure.
- the basic purpose of gasification is to obtain a desired synthetic gas composition, reduce the content of tar oil during the gasification, and maximize the gasification efficiency of the system, the carbon conversion rate, and the content of CO and H2 in the synthetic gas.
- an entrained-flow flow gasifier and a fluidized-bed gasifier are provided.
- the entrained-flow gasifier sprays pulverized fuel in several tens to hundreds of m with an oxidizing agent so as to form a high-temperature combustion zone at 1,600 degrees or more, and injects a large amount of pulverized fuel around the high-temperature combustion zone so as to perform gasification.
- the entrained-flow gasifier is mainly utilized for gasifying coal which may be easily pulverized, but bio-mass, bio-mass char, and pre-processed high water content bio-mass (dried sewage sludge) may be pulverized and utilized. Since the entrained-flow gasifier has a simple structure, the entrained-flow gasifier may be easily applied to a pressurized gasification system which can be operated at high pressure.
- the fluidized-bed gasifier may use fuel in several mm to several cm, and use sand as a heat medium and a fluidizing material.
- the fluidized-bed gasifier is utilized for gasifying a waste material having various properties and a low heat value (or a significant variation in heat value), bio-mass, and low-grade coal which cannot be utilized as pulverized fuel.
- gas with a predetermined pressure, a predetermined flow rate, and a predetermined temperature or more is required for fluidization, and a fluidized-bed gasification agent is supplied through a distributor so as to perform gasification.
- the synthetic gas generated from the gasification system is refined and used as fuel or utilized for producing a chemical material through a catalyst conversion process. During this process, it is necessary to treat tar, unburned matter, or dust which may be formed within the synthetic gas.
- the present invention is made by recognizing at least any one of demands or problems which occur in the related art as described above.
- An aspect of the present invention provides a hybrid gasification system which simultaneously has the advantages of an entrained-flow gasifier and a fluidized-bed gasifier, supplies high-temperature synthetic gas produced through entrained-flow gasification to an fluidized-bed gasifier through a distributor, and utilizes the synthetic gas as a gasification agent of a fluidized-bed reactor.
- Another aspect of the present invention provides a hybrid gasification system employing a structure in which a second reaction chamber operated at a temperature of 700 to 900 is surrounded by a first reaction chamber operated at high temperature, thereby minimizing heat loss.
- Another aspect of the present invention provides a hybrid gasification system having a structure in which unreacted substances and tar within synthetic gas generated from a first reaction chamber reacts within a second reaction chamber, thereby increasing the entire gasification efficiency.
- Another aspect of the present invention provides a fluidized-bed reactor provided at the bottom of an entrained flow gasifier and additionally reacts unreacted substances generated from a first reaction chamber, thereby increasing a carbon conversion rate.
- a hybrid gasification system in accordance with an embodiment of the present invention to realize at least one of the above problems may include the following features.
- a hybrid gasification system may include: a hollow gasifier; a first reaction chamber positioned in the center of the gasifier; a second reaction chamber positioned to surround the first reaction chamber within the gasifier; and a synthetic gas transfer part positioned at the bottom of the first and second reaction chambers. Pulverized fuel introduced into the first reaction chamber through a pulverized fuel injection pipe may be converted into synthetic gas through the first reaction chamber.
- the hybrid gasification system may further include a first distributor positioned at the bottom of the second reaction chamber, and the synthetic gas generated from the first reaction chamber may be introduced to the second reaction chamber through the first distributor.
- the hybrid gasification system may further include a fluidized-bed reactor positioned under the synthetic gas transfer part within the gasifier and having a second distributor formed therein.
- the fluidized-bed reactor may cause a reaction to convert unreacted substances remaining in the synthetic gas transfer part into the synthetic gas through the second distributor.
- the hybrid gasification system may further include: a synthetic gas discharge pipe communicating with the top surface of the gasifier; and a solid waste injection pipe communicating with side and bottom surfaces of the gasifier so as to inject solid wastes.
- the synthetic gas discharge pipe may discharge the synthetic gas within the second reaction chamber to the outside of the gasifier.
- the hybrid gasification system may further include a circulation flow path part communicating with the second reaction chamber and including a circulation flow path.
- a circulation flow path part communicating with the second reaction chamber and including a circulation flow path.
- One side of the circulation flow path may be inserted into a first through-hole formed at the top of the second reaction chamber, and the other side of the circulation flow path may be inserted into a second through-hole formed at the side of the second reaction chamber.
- the circulation flow path part may further include: a discharge pipe communicating with the outside; and an air nozzle supplying a gasification agent into the circulation flow path part, wherein the synthetic gas within the second reaction chamber is sequentially circulated through the second through-hole, the circulation flow path, and the first through-hole, and then discharged to the outside through the discharge pipe.
- the hybrid gasification system has the advantages of an entrained-flow gasifier and a fluidized-bed gasifier, and supplies high-temperature synthetic gas produced within the entrained-flow gasifier to the fluidized-bed gasifier through the distributor such that sensible heat of the high-temperature synthetic gas produced from entrained-flow gasifier is utilized in the fluidized bed gasifier, thereby increasing thermal efficiency.
- a hybrid gasification system employing a structure in which a second reaction chamber operated at a temperature of 700 to 900 is surrounded by a first reaction chamber operated at high temperature, thereby obtaining an insulation effect, performing additional heat exchange, and minimizing a heat loss.
- a hybrid gasification system which includes the fluidized-bed reactor provided at the bottom of the entrained-flow gasifier and additionally reacts unreacted substances generated from a first reaction chamber, thereby increasing a carbon conversion rate.
- the gas mixture may supplement the material characteristics of waste and bio-mass which have a variation in supply.
- FIG. 1 is a cross-sectional view of a hybrid gasification system in accordance with a first embodiment of the present invention, when seen from one direction.
- FIG. 2 is a flow diagram illustrating a bubbling fluidized bed of waste and pulverized fuel, which are inputted into a combustion furnace of FIG. 1 , and synthetic gas.
- FIG. 3 is a schematic view of FIG. 1 .
- FIG. 4 is a cross-sectional view of a hybrid gasification system in accordance with a second embodiment of the present invention, when seen from one direction.
- FIG. 5 is a flow diagram illustrating a circulating fluidized bed of waste and pulverized fuel, which are inputted into a combustion furnace of FIG. 4 , and synthetic gas.
- hybrid gasification systems 100 in accordance with embodiments of the present invention will be described with reference to FIGS. 1 to 5 .
- the thickness of lines or the size of elements may be exaggerated for clarity of illustration.
- terms used herein are terms defined in consideration of functions in the present invention, and may differ depending on a user or operator's intention or custom. Thus, the definitions of the terms will be determined on the basis of the content of the present specification.
- FIGS. 1 to 3 a hybrid gasification system 100 in accordance with a first embodiment of the present invention will be described.
- the hybrid gasification system 100 in accordance with the first embodiment of the present invention includes a hollow gasifier 110 , a first reaction chamber 120 , a second reaction chamber 130 , a synthetic gas transfer part 140 , a distributor 150 , a communication part 160 , and a fluidized-bed reactor 170 .
- the first reaction chamber 120 is positioned in the center of the gasifier 110 .
- the second reaction chamber 130 is positioned to surround the first reaction chamber 120 within the gasifier 110 .
- the synthetic gas transfer part 140 is positioned under the first and second reaction chambers 120 and 130 .
- the distributor 150 is positioned at the bottom of the gasifier 110 .
- the communication part 160 communicates with the second reaction chamber 130 .
- the fluidized-bed reactor 170 is positioned under the synthetic gas transfer part 140 within the gasifier 110 .
- the gasifier 110 has a hollow structure, and may be manufactured to endure high pressure because high-pressure synthetic gas flows within the gasifier 110 . Furthermore, the gasifier 110 has a structure communicating with the outside, and the structure will be described below in more detail.
- the first reaction chamber 120 is positioned in the center of the gasifier 110 , and a pulverized fuel injection pipe 163 to be described below is positioned at the top of the first reaction chamber 120 . Inside the first reaction chamber 120 , pulverized fuel is introduced through the pulverized fuel injection pipe 163 and converted into synthetic gas.
- the second reaction chamber 130 is positioned to surround the first reaction chamber 120 inside the gasifier 110 .
- the second reaction chamber 130 includes a first through-hole 131 positioned at one side of the top surface thereof and a second through-hole 132 positioned at the upper part of a side surface thereof.
- the first through-hole 131 serves to discharge the synthetic gas generated from the second reaction chamber 130 to the outside.
- the second through-hole 132 serves as a path for supplying solid waste to the second reaction chamber 130 .
- the synthetic gas transfer part 140 is positioned under the first and second reaction chambers 120 and 130 . As the synthetic gas transfer part 140 is configured to communicate with the first and second reaction chambers 120 and 130 , the synthetic gas generated from the first reaction chamber 120 may be introduced to the synthetic gas transfer part 140 .
- the synthetic gas transfer part 140 serves to transfer the introduced synthetic gas to the second reaction chamber 130 .
- the distributor 150 includes a first distributor 151 positioned at the bottom of the second reaction chamber 130 and a second distributor 152 positioned at the bottom of the fluidized-bed reactor 170 .
- the synthetic gas which is generated from the first reaction chamber 120 and transferred through the synthetic gas transfer part 140 , is pulverized and introduced into the first distributor 151 .
- the first distributor 151 serves to prevent unreacted pulverized fuel from flowing into the second reaction chamber 130 and thus induce a reaction.
- the second distributor 152 is positioned in the center of the fluidized-bed reactor 170 , and plays the same role as the first distributor 151 .
- the second distributor 152 pulverizes unreacted fuel falling from the synthetic gas transfer part 140 into an aerosol state, and supplies the pulverized fuel to the synthetic gas transfer part 140 .
- the communication part 160 communicates with the second reaction chamber 130 , and includes a synthetic gas discharge pipe 161 , a solid waste injection pipe 162 , and a pulverized fuel inject ion pipe 163 .
- the synthetic gas discharge pipe 161 communicates with the top surface of the gasifier 110
- the solid waste injection pipe 162 communicates with the side surface and the bottom surface of the gasifier 110 so as to inject solid waste
- the pulverized injection pipe 163 is positioned in the top center of the gasifier 110 .
- the synthetic gas discharge pipe 161 communicates with the top surface of the gasifier 110 . More specifically, the synthetic gas discharge pipe 161 serves as a discharge port to discharge the synthetic gas within the second reaction chamber 130 to the outside of the gasifier 110 .
- the solid waste injection pipe 162 communicates with the side surface and the bottom surface of the gasifier 110 so as to inject solid waste, and the solid waste injection pipe 162 injects solid waste into the second reaction chamber 130 and the fluidized-bed reactor 170 within the gasifier 110 .
- the pulverized fuel injection pipe 163 is positioned in the top center of the gasifier 110 , and serves as a path through which the pulverized fuel supplied from outside is introduced into the first reaction chamber 120 .
- the fluidized-bed reactor 170 is positioned at the bottom of the synthetic gas transfer part 140 within the gasifier 110 .
- the fluidized-bed reactor 170 serves to convert unreacted substances remaining in the synthetic gas transfer part 140 into synthetic gas through the second distributor 152 .
- the hybrid gasification system in accordance with the first embodiment of the present invention is configured in a bubbling fluidized bed (BFB) and thus favorable to small and medium-scale systems.
- BFB bubbling fluidized bed
- the hybrid gasification system 100 ′ in accordance with the second embodiment of the present invention includes a gasifier 110 , a first reaction chamber 120 , a second reaction chamber 130 , a synthetic gas transfer part 140 , a distributor 150 , a fluidized-bed reactor 170 , and a circulation flow path part 180 communicating with the second reaction chamber 130 .
- the hybrid gasification system 100 ′ in accordance with the second embodiment of the present invention may further include the above-described solid waste injection pipe 162 .
- the circulation flow path part 170 includes a circulation flow path 181 connecting first and second through-holes 131 and 132 , a discharge pipe 182 communicating with the top of the circulation flow path 181 , and an air nozzle 183 communicating with the bottom of the circulation flow path 181 .
- One side of the circulation flow path 181 is inserted into the first through-hole 131 formed at the top of the second reaction chamber 130 , and the other side of the circulation flow path 181 is inserted into the second through-hole 132 formed at the side of the second reaction chamber 130 .
- the discharge pipe 182 communicates with the top of the circulation flow path 181 , and serves to discharge the synthetic gas within the first reaction chamber 120 to the outside of the gasifier 110 , like the above-described synthetic gas discharge pipe 161 .
- the air nozzle 183 communicates with the bottom of the circulation flow path 181 , and serves to supply a gasification agent to the discharge pipe 182 and the circulation flow path 181 which communicate with the outside, and adjust a circulation volume of solid waste.
- the synthetic gas within the second reaction chamber 130 is sequentially circulated through the second through-hole 132 , the circulation flow path 181 , and the first through-hole 131 , and then discharged to the outside through the discharge pipe 182 .
- the first embodiment configured in a bubbling fluidized bed (BFB) type and the second embodiment configured in a circulating fluidized bed (CFB) type may be selected and used according to the purpose.
- the hybrid gasification system in accordance with the second embodiment of the present invention is configured in a circulating fluidized bed (CFB) type, and this favorable to medium and large-scale systems.
- CFB circulating fluidized bed
- the apparatus for injecting hot air into an electric furnace may not be restrictively applied to the foregoing embodiments, but all or a portion of each embodiment may be selectively combined so that the embodiments may be variously changed.
Abstract
Description
- The present invention relates to a hybrid gasification system, and more particularly, to a hybrid gasification system which simultaneously has the advantages of entrained-flow gasifier using pulverized fuel and a fluidized-bed gasifier utilized for gasifying fuel with relatively various properties.
- The continuous reduction in reserves of fossil fuels (coal, oil, and natural gas) and the environmental pollution caused by use of fossil fuel directly threaten the survival and development of the human race. Thus, various countries' attentions are being paid to the development of renewable and environment-friendly energy.
- Bio-mass is an organic material derived through photosynthesis of a plant. Since bio-mass is widely distributed and used, is cleaner than fossil fuel, and generates no CO2, bio-mass attracts much attention as an important renewable energy. Bio-mass can be converted into synthetic gas or liquefied fuel through such a method as thermal chemistry or biochemistry, and can be applied to power generation, industrial fuel, or chemical industry products. Thus, bio-mass may replace a considerable amount of fossil fuel without changing the existing energy conversion systems. Therefore, bio-mass is being preferentially developed by various countries.
- Bio-mass may be converted into synthetic gas or liquefied fuel through various kinds of methods, and the bio-mass gasification technology is viable for a larger number of types of available bio-masses and has greater expandability than other technologies.
- The gasification process for bio-mass is performed through a thermal-chemistry conversion process in which a solid bio-mass material and a gasification agent (air, oxygen, vapor, or carbon dioxide) produce a chemical reaction under a high-temperature condition such that the solid bio-mass material is converted into a gas mixture based on hydrocarbon containing carbon, hydrogen, and oxygen. The gas mixture is typically referred to as synthetic gas.
- The composition of the synthetic gas generated during the gasification process may be primarily influenced by the material characteristics of the bio-mass used during the gasification process, and differ depending on the type of the gasification agent, the type of a gasifier, and the reaction condition of temperature and pressure. The basic purpose of gasification is to obtain a desired synthetic gas composition, reduce the content of tar oil during the gasification, and maximize the gasification efficiency of the system, the carbon conversion rate, and the content of CO and H2 in the synthetic gas.
- In order to accomplish the above-described purpose, an entrained-flow flow gasifier and a fluidized-bed gasifier are provided.
- The entrained-flow gasifier sprays pulverized fuel in several tens to hundreds of m with an oxidizing agent so as to form a high-temperature combustion zone at 1,600 degrees or more, and injects a large amount of pulverized fuel around the high-temperature combustion zone so as to perform gasification. The entrained-flow gasifier is mainly utilized for gasifying coal which may be easily pulverized, but bio-mass, bio-mass char, and pre-processed high water content bio-mass (dried sewage sludge) may be pulverized and utilized. Since the entrained-flow gasifier has a simple structure, the entrained-flow gasifier may be easily applied to a pressurized gasification system which can be operated at high pressure.
- The fluidized-bed gasifier may use fuel in several mm to several cm, and use sand as a heat medium and a fluidizing material. Thus, the fluidized-bed gasifier is utilized for gasifying a waste material having various properties and a low heat value (or a significant variation in heat value), bio-mass, and low-grade coal which cannot be utilized as pulverized fuel.
- In order to operate the fluidized-bed gasifier, gas with a predetermined pressure, a predetermined flow rate, and a predetermined temperature or more is required for fluidization, and a fluidized-bed gasification agent is supplied through a distributor so as to perform gasification.
- The synthetic gas generated from the gasification system is refined and used as fuel or utilized for producing a chemical material through a catalyst conversion process. During this process, it is necessary to treat tar, unburned matter, or dust which may be formed within the synthetic gas.
- During the refining process, however, the synthetic gas is cooled down. At this time, sensible heat escaping during the refining process may be reused through waste heat recovery, but waste heat recovery efficiency is not very high.
- The present invention is made by recognizing at least any one of demands or problems which occur in the related art as described above.
- An aspect of the present invention provides a hybrid gasification system which simultaneously has the advantages of an entrained-flow gasifier and a fluidized-bed gasifier, supplies high-temperature synthetic gas produced through entrained-flow gasification to an fluidized-bed gasifier through a distributor, and utilizes the synthetic gas as a gasification agent of a fluidized-bed reactor.
- Another aspect of the present invention provides a hybrid gasification system employing a structure in which a second reaction chamber operated at a temperature of 700 to 900 is surrounded by a first reaction chamber operated at high temperature, thereby minimizing heat loss.
- Another aspect of the present invention provides a hybrid gasification system having a structure in which unreacted substances and tar within synthetic gas generated from a first reaction chamber reacts within a second reaction chamber, thereby increasing the entire gasification efficiency.
- Another aspect of the present invention provides a fluidized-bed reactor provided at the bottom of an entrained flow gasifier and additionally reacts unreacted substances generated from a first reaction chamber, thereby increasing a carbon conversion rate.
- A hybrid gasification system in accordance with an embodiment of the present invention to realize at least one of the above problems may include the following features.
- According to one aspect of the present invention, a hybrid gasification system may include: a hollow gasifier; a first reaction chamber positioned in the center of the gasifier; a second reaction chamber positioned to surround the first reaction chamber within the gasifier; and a synthetic gas transfer part positioned at the bottom of the first and second reaction chambers. Pulverized fuel introduced into the first reaction chamber through a pulverized fuel injection pipe may be converted into synthetic gas through the first reaction chamber.
- The hybrid gasification system may further include a first distributor positioned at the bottom of the second reaction chamber, and the synthetic gas generated from the first reaction chamber may be introduced to the second reaction chamber through the first distributor.
- The hybrid gasification system may further include a fluidized-bed reactor positioned under the synthetic gas transfer part within the gasifier and having a second distributor formed therein.
- The fluidized-bed reactor may cause a reaction to convert unreacted substances remaining in the synthetic gas transfer part into the synthetic gas through the second distributor.
- The hybrid gasification system may further include: a synthetic gas discharge pipe communicating with the top surface of the gasifier; and a solid waste injection pipe communicating with side and bottom surfaces of the gasifier so as to inject solid wastes. The synthetic gas discharge pipe may discharge the synthetic gas within the second reaction chamber to the outside of the gasifier.
- The hybrid gasification system may further include a circulation flow path part communicating with the second reaction chamber and including a circulation flow path. One side of the circulation flow path may be inserted into a first through-hole formed at the top of the second reaction chamber, and the other side of the circulation flow path may be inserted into a second through-hole formed at the side of the second reaction chamber.
- The circulation flow path part may further include: a discharge pipe communicating with the outside; and an air nozzle supplying a gasification agent into the circulation flow path part, wherein the synthetic gas within the second reaction chamber is sequentially circulated through the second through-hole, the circulation flow path, and the first through-hole, and then discharged to the outside through the discharge pipe.
- According to the embodiments of the present invention, the hybrid gasification system has the advantages of an entrained-flow gasifier and a fluidized-bed gasifier, and supplies high-temperature synthetic gas produced within the entrained-flow gasifier to the fluidized-bed gasifier through the distributor such that sensible heat of the high-temperature synthetic gas produced from entrained-flow gasifier is utilized in the fluidized bed gasifier, thereby increasing thermal efficiency.
- Furthermore, it is possible to provide a hybrid gasification system employing a structure in which a second reaction chamber operated at a temperature of 700 to 900 is surrounded by a first reaction chamber operated at high temperature, thereby obtaining an insulation effect, performing additional heat exchange, and minimizing a heat loss.
- Furthermore, it is possible to provide a hybrid gasification system which includes the fluidized-bed reactor provided at the bottom of the entrained-flow gasifier and additionally reacts unreacted substances generated from a first reaction chamber, thereby increasing a carbon conversion rate.
- Furthermore, while the synthetic gas produced through the entrained-flow gasifier passes through the fluidized-bed gasifier, an additional gasification reaction occurs to refine tar and dust.
- Furthermore, when a material suitable for decomposing tar, such as dolomite or olivine, is used as a fluidization material instead of sand, an additional refinement effect may be acquired.
- Furthermore, when coal, waste, and biomass are mixed and gasified, the gas mixture may supplement the material characteristics of waste and bio-mass which have a variation in supply.
-
FIG. 1 is a cross-sectional view of a hybrid gasification system in accordance with a first embodiment of the present invention, when seen from one direction. -
FIG. 2 is a flow diagram illustrating a bubbling fluidized bed of waste and pulverized fuel, which are inputted into a combustion furnace ofFIG. 1 , and synthetic gas. -
FIG. 3 is a schematic view ofFIG. 1 . -
FIG. 4 is a cross-sectional view of a hybrid gasification system in accordance with a second embodiment of the present invention, when seen from one direction. -
FIG. 5 is a flow diagram illustrating a circulating fluidized bed of waste and pulverized fuel, which are inputted into a combustion furnace ofFIG. 4 , and synthetic gas. - Elements included in a hybrid gasification system in accordance with an embodiment of the present invention may be used integrally or separately, if necessary. Furthermore, a part of the elements may be omitted depending on the intended use.
- Hereafter,
hybrid gasification systems 100 in accordance with embodiments of the present invention will be described with reference toFIGS. 1 to 5 . In the drawings, the thickness of lines or the size of elements may be exaggerated for clarity of illustration. Furthermore, terms used herein are terms defined in consideration of functions in the present invention, and may differ depending on a user or operator's intention or custom. Thus, the definitions of the terms will be determined on the basis of the content of the present specification. - Referring to
FIGS. 1 to 3 , ahybrid gasification system 100 in accordance with a first embodiment of the present invention will be described. - The
hybrid gasification system 100 in accordance with the first embodiment of the present invention includes ahollow gasifier 110, afirst reaction chamber 120, asecond reaction chamber 130, a syntheticgas transfer part 140, adistributor 150, acommunication part 160, and a fluidized-bed reactor 170. Thefirst reaction chamber 120 is positioned in the center of thegasifier 110. Thesecond reaction chamber 130 is positioned to surround thefirst reaction chamber 120 within thegasifier 110. The syntheticgas transfer part 140 is positioned under the first andsecond reaction chambers distributor 150 is positioned at the bottom of thegasifier 110. Thecommunication part 160 communicates with thesecond reaction chamber 130. The fluidized-bed reactor 170 is positioned under the syntheticgas transfer part 140 within thegasifier 110. - The
gasifier 110 has a hollow structure, and may be manufactured to endure high pressure because high-pressure synthetic gas flows within thegasifier 110. Furthermore, thegasifier 110 has a structure communicating with the outside, and the structure will be described below in more detail. - The
first reaction chamber 120 is positioned in the center of thegasifier 110, and a pulverizedfuel injection pipe 163 to be described below is positioned at the top of thefirst reaction chamber 120. Inside thefirst reaction chamber 120, pulverized fuel is introduced through the pulverizedfuel injection pipe 163 and converted into synthetic gas. - The
second reaction chamber 130 is positioned to surround thefirst reaction chamber 120 inside thegasifier 110. Thesecond reaction chamber 130 includes a first through-hole 131 positioned at one side of the top surface thereof and a second through-hole 132 positioned at the upper part of a side surface thereof. - As illustrated in
FIG. 1 , the first through-hole 131 serves to discharge the synthetic gas generated from thesecond reaction chamber 130 to the outside. - The second through-
hole 132 serves as a path for supplying solid waste to thesecond reaction chamber 130. - The synthetic
gas transfer part 140 is positioned under the first andsecond reaction chambers gas transfer part 140 is configured to communicate with the first andsecond reaction chambers first reaction chamber 120 may be introduced to the syntheticgas transfer part 140. - The synthetic
gas transfer part 140 serves to transfer the introduced synthetic gas to thesecond reaction chamber 130. - The
distributor 150 includes afirst distributor 151 positioned at the bottom of thesecond reaction chamber 130 and asecond distributor 152 positioned at the bottom of the fluidized-bed reactor 170. - The synthetic gas, which is generated from the
first reaction chamber 120 and transferred through the syntheticgas transfer part 140, is pulverized and introduced into thefirst distributor 151. - The
first distributor 151 serves to prevent unreacted pulverized fuel from flowing into thesecond reaction chamber 130 and thus induce a reaction. - The
second distributor 152 is positioned in the center of the fluidized-bed reactor 170, and plays the same role as thefirst distributor 151. - In other words, the
second distributor 152 pulverizes unreacted fuel falling from the syntheticgas transfer part 140 into an aerosol state, and supplies the pulverized fuel to the syntheticgas transfer part 140. - The
communication part 160 communicates with thesecond reaction chamber 130, and includes a syntheticgas discharge pipe 161, a solidwaste injection pipe 162, and a pulverized fuel injection pipe 163. The syntheticgas discharge pipe 161 communicates with the top surface of thegasifier 110, the solidwaste injection pipe 162 communicates with the side surface and the bottom surface of thegasifier 110 so as to inject solid waste, and the pulverizedinjection pipe 163 is positioned in the top center of thegasifier 110. - The synthetic
gas discharge pipe 161 communicates with the top surface of thegasifier 110. More specifically, the syntheticgas discharge pipe 161 serves as a discharge port to discharge the synthetic gas within thesecond reaction chamber 130 to the outside of thegasifier 110. - The solid
waste injection pipe 162 communicates with the side surface and the bottom surface of thegasifier 110 so as to inject solid waste, and the solidwaste injection pipe 162 injects solid waste into thesecond reaction chamber 130 and the fluidized-bed reactor 170 within thegasifier 110. - The pulverized
fuel injection pipe 163 is positioned in the top center of thegasifier 110, and serves as a path through which the pulverized fuel supplied from outside is introduced into thefirst reaction chamber 120. - The fluidized-
bed reactor 170 is positioned at the bottom of the syntheticgas transfer part 140 within thegasifier 110. The fluidized-bed reactor 170 serves to convert unreacted substances remaining in the syntheticgas transfer part 140 into synthetic gas through thesecond distributor 152. - The hybrid gasification system in accordance with the first embodiment of the present invention is configured in a bubbling fluidized bed (BFB) and thus favorable to small and medium-scale systems.
- Hereafter, a
hybrid gasification system 100′ in accordance with a second embodiment of the present invention will be described with reference toFIG. 4 . At this time, the detailed descriptions of the same elements as those of the first embodiment are omitted, and additional elements will be described in detail. - The
hybrid gasification system 100′ in accordance with the second embodiment of the present invention includes agasifier 110, afirst reaction chamber 120, asecond reaction chamber 130, a syntheticgas transfer part 140, adistributor 150, a fluidized-bed reactor 170, and a circulationflow path part 180 communicating with thesecond reaction chamber 130. - The
hybrid gasification system 100′ in accordance with the second embodiment of the present invention may further include the above-described solidwaste injection pipe 162. - The circulation
flow path part 170 includes acirculation flow path 181 connecting first and second through-holes discharge pipe 182 communicating with the top of thecirculation flow path 181, and anair nozzle 183 communicating with the bottom of thecirculation flow path 181. - One side of the
circulation flow path 181 is inserted into the first through-hole 131 formed at the top of thesecond reaction chamber 130, and the other side of thecirculation flow path 181 is inserted into the second through-hole 132 formed at the side of thesecond reaction chamber 130. - The
discharge pipe 182 communicates with the top of thecirculation flow path 181, and serves to discharge the synthetic gas within thefirst reaction chamber 120 to the outside of thegasifier 110, like the above-described syntheticgas discharge pipe 161. - The
air nozzle 183 communicates with the bottom of thecirculation flow path 181, and serves to supply a gasification agent to thedischarge pipe 182 and thecirculation flow path 181 which communicate with the outside, and adjust a circulation volume of solid waste. - In the second embodiment of the present invention, the synthetic gas within the
second reaction chamber 130 is sequentially circulated through the second through-hole 132, thecirculation flow path 181, and the first through-hole 131, and then discharged to the outside through thedischarge pipe 182. - The first embodiment configured in a bubbling fluidized bed (BFB) type and the second embodiment configured in a circulating fluidized bed (CFB) type may be selected and used according to the purpose.
- The hybrid gasification system in accordance with the second embodiment of the present invention is configured in a circulating fluidized bed (CFB) type, and this favorable to medium and large-scale systems.
- As set forth above, the apparatus for injecting hot air into an electric furnace may not be restrictively applied to the foregoing embodiments, but all or a portion of each embodiment may be selectively combined so that the embodiments may be variously changed.
Claims (6)
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Cited By (4)
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CN104762107A (en) * | 2015-04-20 | 2015-07-08 | 新奥科技发展有限公司 | Entrained-flow bed gasification system and entrained-flow bed gasification process |
CN111088078A (en) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | Entrained flow gasifier and gasification method of carbonaceous raw material |
US10948180B2 (en) * | 2018-12-12 | 2021-03-16 | Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.O.C. | Gasification reactor with shared partial reactor vessels |
US20210155860A1 (en) * | 2019-11-25 | 2021-05-27 | Wormser Energy Solutions, Inc. | Char Preparation System and Gasifier for All-Steam Gasification with Carbon Capture |
Families Citing this family (3)
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KR101522213B1 (en) | 2014-09-19 | 2015-05-21 | 한국생산기술연구원 | Gasifying apparatus and gasifying method |
KR101598982B1 (en) * | 2014-11-13 | 2016-03-02 | 한국에너지기술연구원 | Hybrid gasification reactor employing high temperature thermal plasma/dual fluidized-bed and syngas production method using it |
CN104531222B (en) * | 2014-12-26 | 2017-03-01 | 北京雷浩环保能源技术有限公司 | Pyrolysis of coal system and method using spouted bed reactor |
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US20120000175A1 (en) * | 2008-12-23 | 2012-01-05 | Wormser Energy Solutions, Inc. | Mild gasification combined-cycle powerplant |
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US3840354A (en) * | 1972-03-23 | 1974-10-08 | Us Interior | Three-stage gasification of coal |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104762107A (en) * | 2015-04-20 | 2015-07-08 | 新奥科技发展有限公司 | Entrained-flow bed gasification system and entrained-flow bed gasification process |
CN111088078A (en) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | Entrained flow gasifier and gasification method of carbonaceous raw material |
US10948180B2 (en) * | 2018-12-12 | 2021-03-16 | Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.O.C. | Gasification reactor with shared partial reactor vessels |
US20210155860A1 (en) * | 2019-11-25 | 2021-05-27 | Wormser Energy Solutions, Inc. | Char Preparation System and Gasifier for All-Steam Gasification with Carbon Capture |
US11572518B2 (en) * | 2019-11-25 | 2023-02-07 | Wormser Energy Solutions, Inc. | Char preparation system and gasifier for all-steam gasification with carbon capture |
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