US20140283960A1 - Air-hardenable bainitic steel with enhanced material characteristics - Google Patents

Air-hardenable bainitic steel with enhanced material characteristics Download PDF

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US20140283960A1
US20140283960A1 US13/848,829 US201313848829A US2014283960A1 US 20140283960 A1 US20140283960 A1 US 20140283960A1 US 201313848829 A US201313848829 A US 201313848829A US 2014283960 A1 US2014283960 A1 US 2014283960A1
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steel part
air cooling
microstructure
forged
controlled air
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Tianjun Liu
Matthew Thomas Kiser
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Caterpillar Inc
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Caterpillar Inc
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Priority to US13/848,829 priority Critical patent/US20140283960A1/en
Assigned to CATERPILLAR INC. reassignment CATERPILLAR INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KISER, MATTHEW THOMAS, LIU, TIANJUN
Priority to KR1020157028786A priority patent/KR20150132320A/en
Priority to CN201480016289.4A priority patent/CN105143474A/en
Priority to EP14771156.8A priority patent/EP2976437B1/en
Priority to RU2015143271A priority patent/RU2015143271A/en
Priority to JP2016504346A priority patent/JP6382937B2/en
Priority to PCT/US2014/031201 priority patent/WO2014153398A1/en
Priority to AU2014235986A priority patent/AU2014235986B2/en
Publication of US20140283960A1 publication Critical patent/US20140283960A1/en
Priority to US14/845,699 priority patent/US20150376750A1/en
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
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    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/19Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/20Isothermal quenching, e.g. bainitic hardening
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
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    • C21METALLURGY OF IRON
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    • C21D6/00Heat treatment of ferrous alloys
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/13Modifying the physical properties of iron or steel by deformation by hot working
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2261/00Machining or cutting being involved

Abstract

A method of producing a forged steel part is disclosed to include providing a steel billet having a composition including 0.25-0.40 wt. % C, 1.50-3.00 wt. % Mn, 0.30-2.00 wt. % Si, 0.00-0.150 wt. % V, 0.02-0.06 wt. % Ti, 0.010-0.04 wt. % S, 0.0050-0.0150 wt. % N, 0.00-1.00 wt. % Cr, 0.00-0.30 wt. % Mo, 0.00-0.003 wt. % B, and a balance of Fe and incidental impurities. The method may further include heating the steel billet to an austenization temperature of approximately 1150 degrees C. to 1350 degrees C., hot forging the steel billet to form the steel part, and controlled air cooling the forged steel part after the hot forging. The method may still further include induction heating select portions of the forged steel part after the controlled air cooling to increase the hardness of the select portions of the forged steel part, followed by quenching and tempering before the final machining.

Description

    TECHNICAL FIELD
  • The present disclosure relates generally to an air-hardenable bainitic steel and, more particularly, to an air-hardenable bainitic steel with enhanced material characteristics.
  • BACKGROUND
  • Structural components for machinery, such as track links used on the undercarriage of track-type earth moving machines, are required to have material characteristics that include good yield strength, good wear resistance, good toughness, and good rolling contact fatigue resistance. Track links used on the tracks of a track-type machine such as a bulldozer or other earth moving equipment are well known in the industry. A track link typically has a lower portion, or the body of the link, and an upper portion, or the rail portion of the link. It is important that the rail portion of the track link have high surface hardness, whereas the body portion of the track link can have lower surface hardness for increased machinability. A high surface hardness in the rail portion is necessary because the rail portion is subjected to severe wear and spallation from continuous contact with track rollers. A lower surface hardness in the body portion of the track link allows holes for bushings to be more easily machined into the body portion. The lower surface hardness of the body portion of the track link also allows for a press fit between a bushing and the hole in the track link body without creating excessive residual stresses.
  • The manufacturing processes for obtaining the desired material characteristics in a track link or other structural component have typically included hot forging the component from a steel billet, followed by cooling, reheating to austenization temperatures, quenching, and tempering. These heat treatment processes may then be followed by additional heating of at least select portions of the component, quenching again, and tempering again before the final machining. Processing of a track link includes first heating a steel part to approximately 1150-1350 degrees C. to bring the material to an austenite phase field, and then hot forging the part. The part is then slowly cooled to room temperature, followed by two heat treatment processes. In the first heat treatment process the track link is reheated to austenization temperature, quenched to room temperature, and then tempered to a hardness of approximately 30-39 Rockwell C hardness (HRC). In the second heat treatment process just the rail portion of the track link is locally reheated by induction, quenched to room temperature, and tempered to a hardness of 51-57 HRC. These heat treatment processes result in the track link having a hard rail and a softer body. The body of the link is then machined into final shape. The heat treatment processes add significantly to the expense of producing the components, and also require significant capital expenditures for furnaces, as well as ongoing maintenance expenses.
  • One attempt to produce alternative types of steel having good wear and rolling contact fatigue resistance coupled with improved levels of ductility toughness and weldability is described in U.S. Pat. No. 5,879,474 to Bhadeshia (“the '474 patent”) that issued on Mar. 9, 1999. The '474 patent discloses a steel for use in making a steel rail, where the steel is purported to provide a high strength, wear and rolling contact fatigue resistant microstructure comprising carbide free “bainite” with some high carbon martensite and retained austenite in the head of the rail.
  • Although the alloy steel disclosed in the '474 patent may provide improved wear and rolling contact fatigue resistance, still further improvements in manufacturing costs and material characteristics may be possible. In particular, the '474 patent describes the use of significant quantities of expensive alloying elements such as Chromium (Cr) amd Molybdenum (Mo) to achieve improved levels of rolling contact fatigue strength, ductility, bending fatigue life and fracture toughness, coupled with rolling contact wear resistance similar to or better than those of the current heat treated pearlitic rails.
  • The bainitic microalloyed steel produced in accordance with the chemistry and processes of the present disclosure solves one or more of the problems set forth above and/or other problems in the art.
  • SUMMARY
  • In one aspect, the present disclosure is directed to a method of producing a forged steel part, including providing steel billet having a composition including, on a weight basis:
      • C: 0.25-0.40 wt. %,
      • Mn: 1.50-3.00 wt. %,
      • Si: 0.30-2.00 wt. %
      • V: 0.00-0.15 wt. %,
      • Ti: 0.02-0.06 wt. %,
      • S: 0.010-0.04 wt. %,
      • N: 0.0050-0.0150 wt. %,
      • Cr: 0.00-1.00 wt. %,
      • Mo: 0.00-0.30 wt. %,
      • B: 0.00-0.005 wt. %, and
      • a balance of Fe and incidental impurities, heating the steel billet to an austenization temperature of approximately 1150 degrees C. to 1350 degrees C., hot forging the steel billet to form the steel part, and controlled air cooling the forged steel part after the hot forging.
  • In another aspect, the present disclosure is directed to an air-hardenable bainitic steel part having a composition including, on a weight basis:
      • C: 0.25-0.40 wt. %,
      • Mn: 1.50-3.00 wt. %,
      • Si: 0.30-2.00 wt. %
      • V: 0.00-0.15 wt. %,
      • Ti: 0.02-0.06 wt. %,
      • S: 0.010-0.04 wt. %,
      • N: 0.0050-0.0150 wt. %,
      • Cr: 0.00-1.00 wt. %,
      • Mo: 0.00-0.30 wt. %,
      • B: 0.00-0.003 wt. %,
      • a balance of Fe and incidental impurities, and a microstructure that is greater than 50% by volume bainitic microstructure throughout the entire steel part.
  • In yet another aspect, the present disclosure is directed to a forged steel part manufactured to have a chemical composition including, on a weight basis:
      • C: 0.25-0.40 wt. %,
      • Mn: 1.50-3.00 wt. %,
      • Si: 0.30-2.00 wt. %
      • V: 0.00-0.15 wt. %,
      • Ti: 0.02-0.06 wt. %,
      • S: 0.010-0.04 wt. %,
      • N: 0.0050-0.0150 wt. %,
      • Cr: 0.00-1.00 wt. %,
      • Mo: 0.00-0.30 wt. %,
      • B: 0.00-0.003 wt. %,
      • a balance of Fe and incidental impurities, a microstructure that is greater than 50% by volume bainitic microstructure throughout the entire steel part, and the forged steel part being manufactured by hot forging, controlled air cooling after the hot forging to produce a bainitic microstructure of greater than 50% bainite throughout the forged steel part, and final machining.
    BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic diagram of an exemplary disclosed process eliminating typical heat treating steps;
  • FIG. 2 is a continuous cooling transformation (CCT) diagram for producing the microstructure of an exemplary embodiment of the disclosure; and
  • FIG. 3 is a flowchart depicting an exemplary disclosed method that may be used to produce an exemplary microalloyed bainitic steel with enhanced characteristics.
  • DETAILED DESCRIPTION
  • A microalloyed, air-hardenable, predominantly bainitic steel with enhanced strength, wear, and toughness characteristics is disclosed. The microalloyed, bainitic steel may be economically produced without requiring many of the heat treatment processes previously thought necessary to achieve desired strength, wear, and toughness characteristics. As shown in FIG. 1, the typical heat treatment processes following hot forging of a steel part may include cooling, reheating to austenization temperature, quenching, and tempering. These heat treatment processes may then be followed by reheating select portions of the steel part a second time using induction, quenching a second time, and tempering a second time before the final machining. At least the first sequence of heat treatment steps involving reheating, quenching, and tempering may be required with conventional hot forging processes in order to obtain desired strength and toughness characteristics, while at the same time ending up with a part that is not too hard for machining. Significant cost savings may be achieved if at least some of these intermediate heat treatment processes can be eliminated. Capital investments for heat treatment capacity, and maintenance costs on the furnaces and other equipment may be reduced. In certain implementations of this disclosure the microalloyed, bainitic steel may be provided with the necessary composition and cooling after hot forging to arrive at a hardness of approximately 50-55 Rockwell C hardness (HRC) without even requiring the induction reheating, quenching, and tempering before final machining.
  • A predominantly bainitic microstructure according to various implementations of this disclosure is a microstructure that consists of at least 50% by volume of a bainitic microstructure. Certain embodiments may have at least 70% by volume of a bainitic microstructure. Other embodiments may have at least 85% by volume of a bainitic microstructure. Bainite is a microstructure that forms in steels at temperatures of approximately 250-550° C. (depending on alloy content). Bainite is one of the decomposition products that may form when austenite (the face centered cubic crystal structure of iron) is cooled past a critical temperature of 727° C. (1340° F.) depending on alloy content. A bainitic microstructure may be similar in appearance and hardness characteristics to tempered martensite.
  • A fine, non-lamellar structure, bainite commonly consists of cementite and dislocation-rich ferrite. The high concentration of dislocations in the ferrite present in bainite makes this ferrite harder than it normally would be. As shown in the continuous cooling transformation (CCT) diagram of FIG. 2, the temperature range for transformation to bainite (250-550° C.) is between those for pearlite and martensite. When formed during continuous cooling, the cooling rate to form bainite is more rapid than that required to form pearlite, but less rapid than that required to form martensite (in steels of the same composition). In accordance with various implementations of this disclosure, a microalloyed steel having the chemistry discussed in more detail below may be initially heated to austenization temperatures of approximately 1150-1350° C. or greater. The steel may then be hot forged into the desired shape, and control cooled from the forging temperature to achieve a bainitic microstructure. For the cooling after hot forging, atmospheric cooling or forced air cooling using a blower may be conducted. In various alternative implementations, the steel may be cooled rapidly down to about the eutectoid transformation temperature, and then cooled slowly over a range from about 900 to 500° C. In still further alternative implementations, the steel may be cooled quickly to about 500 to 300° C. after hot forging, and may be kept at an equilibrium temperature somewhere in the range from about 500 to 300° C. to promote bainite transformation.
  • The cooling rate may be determined by reference to a CCT diagram, to know the range for cooling rates passing through the bainite transformation region and, thereby, controlling to the determined cooling rate range. The CCT diagram may have been previously prepared, stored in a database, or otherwise made available for control of the cooling process. The forged product may be air cooled using fans or other means of circulating the cooling air to achieve a cooling rate that falls approximately within the range from 0.5 to 5° C. per second, or 30 to 300° C. per minute, when cooling between approximately 900° C. and 500° C. Most alloying elements will lower the temperature required for the maximum rate of formation of bainite, though carbon is the most effective in doing so. Bainite generally has a hardness that is greater than the typical hardness of pearlite and less than the hardness of martensite. Pearlite in the microstructure may contribute to reduced toughness. The composition and processing of the microalloyed steel according to various embodiments of this disclosure are selected to avoid or at least minimize the amount of pearlite present. In commercial practice a small amount of pearlite, such as less than 2 percent by volume, may unavoidably be present, particularly in the center of large sections, but care is taken to minimize its presence and effects.
  • The bainite microstructure essentially has a two-phase microstructure composed of ferrite and iron carbide or cementite. Depending on the composition of the austenite during the hot forging process, and the cooling rate after hot forging, there is a variation in the morphology of the resulting bainite. The resulting microstructures are referred to as upper bainite or lower bainite. Upper bainite can be described as aggregates of ferrite laths that usually are found in parallel groups to form plate-shaped regions. The carbide phase associated with upper bainite is precipitated at the interlath regions, and depending on the carbon content, these carbides can form nearly complete carbide films between the lath boundaries. Lower bainite also consists of an aggregate of ferrite and carbides. The carbides precipitate inside of the ferrite plates. The carbide precipitates are on a very fine scale and in general have the shape of rods or blades. For this reason, the bainitic microstructure becomes useful in that no additional heat treatments are required after initial cooling to achieve a hardness value between that of pearlitic and martensitic steels. The material characteristics of the microalloyed and forged steel can vary over a large range depending on the particular types and quantities of alloying elements included in the composition. When steel contains sufficient amounts of Si and/or Al, the carbide formation can be significantly retarded such that carbide does not have enough time to form during the continuous cooling process, resulting in a mixed microstructure of bainitic ferrite and retained austenite. This type of bainitic microstructure may be referred to as “carbide free” bainite. It has been found that such bainite may provide superior toughness to conventional types of bainite. The composition of alloying elements included in accordance with various embodiments of this disclosure results in a steel part having the strength, hardness, and toughness characteristics previously only achieved by including the intermediate heat treatment steps following hot forging of reheating to austenization temperature, quenching, and tempering.
  • The advantageous material characteristics discussed above are found to be achieved to a greater extent as the percentage by volume of bainitic microstructure is increased. Accordingly, a part that is 70% by volume bainitic microstructure may exhibit greater strength, hardness, and toughness characteristics than a part that is 50% by volume bainitic microstructure balanced with ferrite and/or pearlite type of microstructure. Additionally, a part that is 85% or greater by volume bainitic microstructure may exhibit even further enhanced characteristics of strength, hardness, and toughness than the part that is 70% by volume bainitic microstructure balanced with ferrite and/or pearlite type of microstructure. As shown in FIG. 1, intermediate heat treatment steps of reheating to austenization temperature, quenching, and tempering may be eliminated before the final machining of a forged product in accordance with various implementations of this disclosure. Induction reheating of select portions of the steel part, such as the rail portion of a track link used in contact with the tracks on earth moving machinery, may be included to achieve enhanced hardness and strength characteristics for certain parts or portions of parts. The increased hardness can also improve the wear resistance of the selected portions of the steel part. The alloying elements that are added to the composition in accordance with various embodiments of this disclosure may also be selected to obtain the desired volume percentages of bainitic microstructure throughout the part, regardless of the different cooling rates that may be experienced in different sections or portions of the part having different thicknesses.
  • It has been discovered in various implementations of this disclosure that the bainitic microstructure obtained after controlled air-cooling may also exhibit the same or similar hardness and strength characteristics as were previously achieved by following hot forging with quenching, reheating, quenching again, and tempering. A microalloyed steel may exhibit a martensitic microstructure after rapid cooling from hot forging temperatures through quenching in oil or water. The martensitic microstructure may have a Rockwell C hardness (HRC) of 50 after quenching depending on the carbon content of the steel. Typical methods of processing this martensitic microstructure steel may then include reheating back up to austenitic temperatures of approximately 800° C.-950° C., quenching again, and then tempering by reheating again to approximately 500° C.-590° C. in order to soften the steel to approximately HRC 30. The controlled air cooling process for producing a predominantly bainitic microstructure according to various implementations of this disclosure may result in the same hardness of HRC 30 without all of the quenching, reheating, quenching and tempering steps previously required. As mentioned above, the predominantly bainitic microstructure may contain greater than 50% by volume of bainitic microstructure. The hardness after air cooling in accordance with this disclosure may fall within the range from approximately 35-45 HRC. The types and quantities of microalloying elements included in the composition of the air-hardenable, bainitic steel in accordance with various embodiments may also enable achievement of hardness levels after air cooling that fall approximately in the range from 40-55 HRC.
  • The microalloyed steel according to various implementations of this disclosure may have a chemical composition, by weight, as listed in Table 1:
  • TABLE 1
    Composition of microalloyed steel in weight percent.
    Constituents Concentration by weight (%)
    Carbon 0.25-0.40
    Manganese 1.50-3.00
    Titanium 0.02-0.06
    Vanadium 0.00-0.15
    Silicon 0.30-2.00
    Nitrogen 0.0050-0.0150
    Optional Sulfur 0.010-0.040
    Optional Chromium 0.00-1.00
    Optional Molybdenum 0.00-0.30
    Optional Boron  0.00-0.005
    Iron and other residual elements Balance
  • Carbon (C) contributes to the attainable hardness level as well as the depth of hardening. In accordance with various implementations of this disclosure, the carbon content is at least 0.25% by weight to maintain adequate core hardness after tempering and is no more than about 0.40% by weight to assure resistance to quench cracking and steel toughness. It has been found that if the carbon content is more than about 0.40% by weight, water quenching may cause cracking or distortion in complex-shaped articles and, in such cases, a less drastic quench medium such as oil may be required. Therefore an advantageous range of C is from approximately 0.25-0.40 wt. %. The microalloyed, bainitic steel according to various implementations of this disclosure may be air cooled in accordance with select cooling curves on the CCT diagram of FIG. 2.
  • Manganese (Mn) is a low cost allow and contributes to the deep hardenability and is therefore present in most hardenable alloy steel grades. The disclosed alloy steel contains manganese in an amount of at least 1.50% by weight to assure adequate core hardness and contains no more than about 3.00% to prevent manganese segregation and the formation of blocky retained austenite.
  • Silicon (Si) in amounts between approximately 0.30-2.00 wt. %, along with the Mn, allows the steel according to this disclosure to form a predominantly bainitic microstructure following air cooling from hot forging temperatures. The Si may also help deoxidation of the molten steel, as well as contributing to the formation of a carbide-free bainite with improved toughness when sufficient Si is added into the steel.
  • Chromium contributes to the hardenability of the present steel alloy and may be added in small amounts not exceeding 1.00% by weight in order to allow for adjustment of the CCT curve to form a predominantly bainitic microstructure after air cooling. More Chromium increases steel cost.
  • Small amounts of other elements including Molybdenum (Mo) and Boron (B) may also be added to allow for further adjustment of the CCT curve to form a predominantly bainitic microstructure after air cooling.
  • Vanadium (V) and Nitrogen (N), despite their small quantities, may also be important ingredients in the present alloy steel composition, and may be added to provide precipitation hardening and to realize a consistently measurable enhancement of case and core hardness. Nitrogen combines with the titanium in the steel to form titanium carbonitrides to prevent grain coarsening during the reheat prior to forging and during the cooling after hot forging. Without Ti and N, the forged steel may have large prior austenite grain sizes, resulting in poor toughness.
  • The remainder of the alloy steel composition is essentially iron, except for nonessential or residual amounts of elements which may be present in small amounts. Titanium (Ti) may also be provided in amounts approximately between 0.02-0.06% to form titanium carbonitrides to prevent grain coarsening before and after forging. Sulphur (S), which in small amounts may be beneficial in that it promotes machining, may also be provided in small enough amounts so as to not contribute to any loss of ductility and toughness. Phosphorus (P) in an amount over 0.05% may cause embrittlement, and preferably the upper limit should not exceed 0.035%. Other elements generally regarded as incidental impurities may be present within commercially recognized allowable amounts.
  • Manufactured articles, such as track links, having the above stated composition, may be advantageously initially formed to a desired shape by hot forging after heating up the microalloyed steel to austenization temperatures of approximately 1150-1350° C. The formed articles are then controlled cooled as described above to produce a predominantly bainitic microstructure. Select portions of the hot forged articles, such as the rail portions of a track link, may then receive additional heat treatment by induction heating the select portions, quenching, and tempering before final machining to a desired final dimension.
  • FIG. 3 illustrates an exemplary method that may be used to produce a predominantly bainitic microalloyed steel part in accordance with various implementations of this disclosure. FIG. 3 will be discussed in more detail in the following section to further illustrate the disclosed concepts.
  • INDUSTRIAL APPLICABILITY
  • The steel, and method of making the steel in accordance with various implementations of the present disclosure may reduce costs by eliminating heat treatment steps typically performed after hot forging. The disclosed microalloyed, forged, air-hardenable bainitic steel may provide similar hardness, strength, and toughness characteristics to previously hot forged and heat treated steel parts, but without requiring all of the heat treatment processes. The microalloying elements in combination with the controlled air cooling may produce a predominantly bainitic microstructure after air cooling from hot forging temperatures. Select portions of the steel parts produced in accordance with the composition and processes of this disclosure may be further hardened if desired using localized induction heating followed by quenching and tempering. Alternatively, the composition of the bainitic steel in accordance with this disclosure may be adjusted within the disclosed ranges, and air cooled in order to achieve a hardness after air cooling falling in the range from approximately 50-55 HRC with no further heat treatment.
  • The steel part produced in accordance with various advantageous implementations of this disclosure exhibits material characteristics that may include a body hardness of 35-45 HRC after air cooling for good machinability with no heat treatment, a body yield strength that is greater than 1000 mega-pascals (MPa) after the air cooling, a hardness at the portions that have been additionally hardened through selective induction heating of greater than approximately 50 HRC, and a body toughness of approximately 20 Joules or greater in the Charpy impact test at room temperature.
  • As shown in FIG. 3, at step 320 a microalloyed steel having the composition shown above in Table 1 may be heated to austenization temperatures of approximately 1150 degrees C. to 1350 degrees C. The types of parts being manufactured in accordance with various implementations of this disclosure may include parts that require good machinability in at least one portion, high yield strength, good wear characteristics, and good toughness. One exemplary application of the disclosed compositions and processes is for track links used in the tracks of a track-type machine such as a bulldozer or other earth moving equipment. The size of the parts determines the size of a steel billet that is initially heated to austenization temperatures in accordance with step 320.
  • At step 322, the heated billet may be hot forged to a desired configuration. After the hot forging, step 324 may include air cooling the hot forged product at a cooling rate that results in the formation of a predominantly bainitic microstructure throughout the hot forged part. As shown by the CCT diagram of FIG. 2, the cooling rate may be chosen to avoid the formation of a large amount of martensitic microstructure or a predominantly ferrite and pearlite microstructure. In various implementations of this disclosure, the hot forged steel may be cooled at a rate that falls approximately in the range from 0.5 to 5 degrees C. per second as the steel cools from approximately 900 degrees C. to approximately 500 degrees C. In various alternative implementations, the weight percentages of the alloying elements in the composition of the steel may be varied in order to change the phase transformation curves on the CCT diagram, and achieve the desired predominantly bainitic microstructure at cooling rates achieved by transporting the hot forged steel parts along a conveyor at ambient temperatures. The microalloyed steel may also be advantageously provided with a composition that achieves the desired bainitic microstructure and hardness levels throughout the part even at the different cooling rates that may be experienced by different sections of the part having different thicknesses. The predominantly bainitic microstructure may be a microstructure with greater than 50% bainite, or more advantageously greater than 70% bainite, or still more advantageously greater than 85% bainite throughout the hot forged steel part. The hardness levels throughout the entire forged steel part after air cooling may fall within the range from approximately 35-45 HRC. In other advantageous embodiments, the hardness levels throughout the forged steel part may fall within the range from approximately 40-55 HRC after air cooling with no further heat treatment.
  • At step 326, select portions of the steel part may be induction heated in order to achieve higher hardness levels. In the exemplary implementation of a track link, a high surface hardness may be desired for the rail portion because the rail portion may be subjected to severe wear from continuous contact with track rollers. A lower surface hardness in the body portion of the track link allows holes for bushings, pins, and bolts to be more easily machined into the body portion. The lower surface hardness of the body portion of the track link also allows for a press fit between a bushing and the hole in the track link body without creating excessive residual stresses. In various exemplary embodiments, the hardness of the induction heated portions of the steel part may fall within the range from approximately 50-57 HRC.
  • At step 328, after select portions of the steel part have been induction heated, at least these heated portions of the steel part may be quenched, using techniques such as directed sprays of quenching fluids onto the induction heated areas of the part. Following quenching, at step 330, the steel part may be reheated to tempering temperatures in order to improve its toughness. Final machining may then occur at step 332.
  • It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed microalloyed steel and method of forming the steel into a finished part without departing from the scope of the disclosure. Alternative implementations will be apparent to those skilled in the art from consideration of the specification and practice disclosed herein. It is intended that the specification and examples be considered as exemplary only, with a true scope of the disclosure being indicated by the following claims and their equivalents.

Claims (20)

What is claimed is:
1. A method of producing a forged steel part, comprising:
providing steel billet having a composition comprising, on a weight basis:
C: 0.25-0.40 wt. %,
Mn: 1.50-3.00 wt. %,
Si: 0.30-2.00 wt. %
V: 0.00-0.15 wt. %,
Ti: 0.02-0.06 wt. %,
S: 0.015-0.04 wt. %,
N: 0.0050-0.0150 wt. %,
Cr: 0.00-1.00 wt. %,
Mo: 0.00-0.30 wt. %,
B: 0.00-0.005 wt. %, and
a balance of Fe and incidental impurities;
heating the steel billet to an austenization temperature of approximately 1150 degrees C. to 1350 degrees C.;
hot forging the steel billet to form the steel part; and
controlled air cooling the forged steel part after the hot forging.
2. The method according to claim 1, wherein the controlled air cooling is performed at a rate to produce a body hardness for the steel part of approximately 35-45 Rockwell C hardness (HRC) after the controlled air cooling.
3. The method according to claim 1, wherein the controlled air cooling is performed at a rate to produce a yield strength for the steel part of approximately greater than 1000 mega-pascals (MPa) after the controlled air cooling.
4. The method according to claim 1, wherein the controlled air cooling is performed by moving the forged steel part along a conveyor at ambient temperatures.
5. The method according to claim 1, wherein the composition of the steel billet is selected such that the controlled air cooling of the forged steel part and resultant different rates of cooling of sections of the forged steel part having different thicknesses results in a microstructure throughout the entire forged steel part after the controlled air cooling of approximately greater than 50% by volume of bainitic microstructure.
6. The method according to claim 1, wherein the composition of the steel billet is selected such that the controlled air cooling of the forged steel part and resultant different rates of cooling of sections of the forged steel part having different thicknesses results in a hardness level throughout the entire forged steel part after the controlled air cooling of approximately greater than 35-45 HRC.
7. The method according to claim 1, wherein a toughness of at least an inner portion of a body of the steel part after the controlled air cooling is approximately greater than or equal to 20 Joules at room temperature in accordance with the Charpy impact test.
8. The method according to claim 1, further including induction heating select portions of the forged steel part after the controlled air cooling to increase hardness of the select portions of the forged steel part.
9. The method according to claim 8, wherein the hardness of the select portions of the forged steel part after induction heating is greater than approximately 50 HRC.
10. The method according to claim 8, further including quenching at least the induction heated portions of the forged steel part and reheating to temper the select portions of the forged steel part for enhanced toughness.
11. The method according to claim 1, wherein the composition of the steel billet and the controlled air cooling of the forged steel part result in a microstructure of the forged steel part after the controlled air cooling of approximately greater than 50% by volume of bainitic microstructure.
12. An air-hardenable bainitic steel part having a composition comprising:
C: 0.25-0.40 wt. %,
Mn: 1.50-3.00 wt. %,
Si: 0.30-2.00 wt. %
V: 0.00-0.15 wt. %,
Ti: 0.02-0.06 wt. %,
S: 0.010-0.04 wt. %,
N: 0.0050-0.0150 wt. %,
Cr: 0.00-1.00 wt. %,
Mo: 0.00-0.30 wt. %,
B: 0.00-0.003 wt. %,
a balance of Fe and incidental impurities; and
a microstructure that is greater than 50% by volume bainitic microstructure throughout the entire steel part.
13. The air-hardenable bainitic steel part of claim 12, wherein the microstructure is greater than 70% by volume bainitic microstructure throughout the entire steel part.
14. The air-hardenable bainitic steel part of claim 12, wherein the bainitic microstructure is at least partially the result of controlled air cooling of the steel part after the steel part has been hot forged.
15. The air-hardenable bainitic steel part of claim 12, wherein the bainitic microstructure is at least partially the result of the composition of the steel part.
16. The air-hardenable bainitic steel part of claim 12, wherein the microstructure of the steel part is greater than 85% by volume bainitic microstructure.
17. The air-hardenable bainitic steel part of claim 14, wherein a hardness throughout the forged steel part falls within a range between approximately 40 HRC to 55 HRC after hot forging and air cooling of the steel part.
18. A forged steel part manufactured to have a chemical composition comprising:
C: 0.25-0.40 wt. %,
Mn: 1.50-3.00 wt. %,
Si: 0.30-2.00 wt. %
V: 0.00-0.15 wt. %,
Ti: 0.02-0.06 wt. %,
S: 0.010-0.04 wt. %,
N: 0.0050-0.0150 wt. %,
Cr: 0.00-1.00 wt. %,
Mo: 0.00-0.30 wt. %,
B: 0.00-0.003 wt. %,
a balance of Fe and incidental impurities;
a microstructure that is greater than 50% by volume bainitic microstructure throughout the entire steel part; and
the forged steel part being manufactured by hot forging, controlled air cooling after the hot forging to produce a microstructure of greater than 50% bainite throughout the forged steel part, and final machining.
19. The forged steel part of claim 18, further including induction heating of select portions of the forged steel part after the controlled air cooling to increase the hardness of the select portions of the forged steel part, followed by quenching and tempering before the final machining.
20. The forged steel part of claim 18, wherein the composition and controlled air cooling after hot forging results in a hardness of approximately 50-55 HRC before final machining with no additional heat treatment except tempering.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150266526A1 (en) * 2014-03-20 2015-09-24 Caterpillar Inc. Air-hardenable bainitic steel part
CN106048149A (en) * 2016-07-16 2016-10-26 柳州科尔特锻造机械有限公司 Heat treatment process of low-alloy steel
CN107385156A (en) * 2017-06-29 2017-11-24 江南工业集团有限公司 The Strengthening and Toughening composite heat treating method of 30CrMnSiA steel
US20180029653A1 (en) * 2016-07-26 2018-02-01 Caterpillar Inc. Method of track link manufacture
WO2018066997A1 (en) * 2016-10-06 2018-04-12 Aboytes Trejo Juan Process and system for thermal treatment of low- and medium-carbon alloyed steel parts for the production of a desired crystalline structure
WO2018215923A1 (en) * 2017-05-22 2018-11-29 Arcelormittal Method for producing a steel part and corresponding steel part
CN112008031A (en) * 2020-08-25 2020-12-01 无锡继平锻造有限公司 Forging and heat treatment process of valve body for shale gas exploitation
WO2021009543A1 (en) * 2019-07-16 2021-01-21 Arcelormittal Method for producing a steel part and steel part
CN114850365A (en) * 2022-04-19 2022-08-05 中国恩菲工程技术有限公司 Bainite-based grinding medium and preparation method and application thereof
RU2788982C1 (en) * 2019-07-16 2023-01-26 Арселормиттал Steel part and method for its production

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6782060B2 (en) * 2015-01-22 2020-11-11 臼井国際産業株式会社 How to manufacture fuel rails
JP6789611B2 (en) * 2015-01-22 2020-11-25 臼井国際産業株式会社 Manufacturing method of fuel rail for gasoline direct injection

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040238081A1 (en) * 2001-08-24 2004-12-02 Naoki Yoshinaga Steel plate exhibiting excellent workability and method for producing the same

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60215743A (en) * 1984-04-11 1985-10-29 Sumitomo Metal Ind Ltd Wear-resistant steel
JP3139876B2 (en) * 1993-04-05 2001-03-05 新日本製鐵株式会社 Method of manufacturing non-heat treated steel for hot forging and non-heat treated hot forged product, and non-heat treated hot forged product
JP3300500B2 (en) * 1993-10-12 2002-07-08 新日本製鐵株式会社 Method for producing hot forging steel excellent in fatigue strength, yield strength and machinability
JP2979987B2 (en) * 1994-12-20 1999-11-22 住友金属工業株式会社 Steel for soft nitriding
GB2297094B (en) * 1995-01-20 1998-09-23 British Steel Plc Improvements in and relating to Carbide-Free Bainitic Steels
CN1074468C (en) * 1997-01-28 2001-11-07 山东工业大学 Multielement micro-alloyed air cooled bainitic steel
JP3762543B2 (en) * 1998-04-02 2006-04-05 新日本製鐵株式会社 Manufacturing method of non-tempered steel for hot forging and non-tempered hot forged product and hot forged non-tempered product
CN1091164C (en) * 1998-12-30 2002-09-18 宝山钢铁股份有限公司 Making process of microalloyed plastic-mould steel
JP2000199041A (en) * 1999-01-07 2000-07-18 Nippon Steel Corp Bainitic rail excellent in rolling fatigue damaging resistance and inside fatigue damaging resistance
CA2323952A1 (en) 1999-01-28 2000-08-03 Yasutaka Okada Machine structural steel product
JP4038361B2 (en) * 2001-11-14 2008-01-23 新日本製鐵株式会社 Non-tempered high strength and high toughness forged product and its manufacturing method
FR2847910B1 (en) * 2002-12-03 2006-06-02 Ascometal Sa METHOD FOR MANUFACTURING A FORGED STEEL PIECE AND PART THUS OBTAINED
US20070227634A1 (en) * 2005-03-16 2007-10-04 Mittal Steel Gandrange Forged or Stamped Average or Small Size Mechanical Part
JP5268225B2 (en) * 2005-10-07 2013-08-21 トピー工業株式会社 Method for manufacturing roller shell of lower traveling body of construction machine
JP4385019B2 (en) * 2005-11-28 2009-12-16 新日本製鐵株式会社 Manufacturing method for steel nitrocarburized machine parts
US20080189930A1 (en) * 2007-02-13 2008-08-14 Yung-Shou Chen Method for making a hammer
JP2009197314A (en) * 2007-05-18 2009-09-03 Jfe Steel Corp Component for machine structure
JP5332371B2 (en) * 2008-07-23 2013-11-06 株式会社ジェイテクト Manufacturing method of bearing device and bearing device
BRPI0901378A2 (en) * 2009-04-03 2010-12-21 Villares Metals Sa baintically mold steel
JP5245997B2 (en) * 2009-04-06 2013-07-24 新日鐵住金株式会社 High strength hot forged non-tempered steel with excellent toughness and method for producing the same
JP5327106B2 (en) * 2010-03-09 2013-10-30 Jfeスチール株式会社 Press member and manufacturing method thereof
FR2958660B1 (en) * 2010-04-07 2013-07-19 Ascometal Sa STEEL FOR MECHANICAL PIECES WITH HIGH CHARACTERISTICS AND METHOD FOR MANUFACTURING THE SAME.
JP5764383B2 (en) 2011-05-12 2015-08-19 Jfe条鋼株式会社 Steel for spring parts for vehicle suspension, spring part for vehicle suspension, and manufacturing method thereof
JP5678833B2 (en) * 2011-07-28 2015-03-04 新日鐵住金株式会社 Induction hardening steel and crankshaft manufactured using the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040238081A1 (en) * 2001-08-24 2004-12-02 Naoki Yoshinaga Steel plate exhibiting excellent workability and method for producing the same

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150266526A1 (en) * 2014-03-20 2015-09-24 Caterpillar Inc. Air-hardenable bainitic steel part
US9440693B2 (en) * 2014-03-20 2016-09-13 Caterpillar Inc. Air-hardenable bainitic steel part
CN106048149A (en) * 2016-07-16 2016-10-26 柳州科尔特锻造机械有限公司 Heat treatment process of low-alloy steel
US10882574B2 (en) * 2016-07-26 2021-01-05 Caterpillar Inc. Method of track link manufacture
US20180029653A1 (en) * 2016-07-26 2018-02-01 Caterpillar Inc. Method of track link manufacture
WO2018066997A1 (en) * 2016-10-06 2018-04-12 Aboytes Trejo Juan Process and system for thermal treatment of low- and medium-carbon alloyed steel parts for the production of a desired crystalline structure
WO2018215923A1 (en) * 2017-05-22 2018-11-29 Arcelormittal Method for producing a steel part and corresponding steel part
WO2018215813A1 (en) * 2017-05-22 2018-11-29 Arcelormittal Method for producing a steel part and corresponding steel part
CN107385156A (en) * 2017-06-29 2017-11-24 江南工业集团有限公司 The Strengthening and Toughening composite heat treating method of 30CrMnSiA steel
WO2021009543A1 (en) * 2019-07-16 2021-01-21 Arcelormittal Method for producing a steel part and steel part
WO2021009705A1 (en) * 2019-07-16 2021-01-21 Arcelormittal Method for producing a steel part and steel part
RU2788982C1 (en) * 2019-07-16 2023-01-26 Арселормиттал Steel part and method for its production
CN112008031A (en) * 2020-08-25 2020-12-01 无锡继平锻造有限公司 Forging and heat treatment process of valve body for shale gas exploitation
CN114850365A (en) * 2022-04-19 2022-08-05 中国恩菲工程技术有限公司 Bainite-based grinding medium and preparation method and application thereof

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