US20130302716A1 - Fuel cell repeater unit - Google Patents
Fuel cell repeater unit Download PDFInfo
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- US20130302716A1 US20130302716A1 US13/942,763 US201313942763A US2013302716A1 US 20130302716 A1 US20130302716 A1 US 20130302716A1 US 201313942763 A US201313942763 A US 201313942763A US 2013302716 A1 US2013302716 A1 US 2013302716A1
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- United States
- Prior art keywords
- dimples
- fuel cell
- interconnector
- flow path
- fuel
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- Abandoned
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/242—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes comprising framed electrodes or intermediary frame-like gaskets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2428—Grouping by arranging unit cells on a surface of any form, e.g. planar or tubular
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
- H01M8/248—Means for compression of the fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2484—Details of groupings of fuel cells characterised by external manifolds
- H01M8/2485—Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- This disclosure relates generally to fuel cells and, more particularly, to repeater units that facilitate fuel cell fluid communication through a fuel cell stack assembly.
- Fuel cell stack assemblies are well known. Some fuel cell stack assemblies include multiple repeater units arranged in a stacked relationship.
- the repeater units each typically include a fuel cell, such as a solid oxide fuel cell (SOFC), that has an electrolyte layer positioned between a cathode electrode layer and an anode electrode layer.
- SOFC solid oxide fuel cell
- An interconnector near the anode electrode layer and another interconnector near the cathode electrode layer electrically connect the repeater unit to an adjacent repeater unit in the stack.
- each repeater unit includes an SOFC requiring an evenly distributed supply of fuel and air.
- One example prior art arrangement includes multiple repeater units that each have a complex pattern of holes for fuel delivery and another pattern of holes for air delivery. Aligning these holes is difficult and time consuming. Achieving durable hermetic sealing between complex air and fuel holes is challenging.
- An example fuel cell repeater includes a separator plate and a frame establishing at least a portion of a flow path that is configured to fluidly couple a fuel supply with at least one fuel cell held by the frame relative to the separator plate.
- the flow path has a flow path perimeter.
- the flow path is within the flow path perimeter and configured to direct flow across the at least one fuel cell within a first plane.
- a dimpled interconnector portion establishes at least a portion of an interconnector flow path operative to communicate airflow through the fuel cell repeater.
- An example fuel cell repeater unit includes a separator plate.
- a frame establishes at least a portion of a fuel flow path that is configured to fluidly couple a fuel supply with at least one fuel cell held by the frame relative to the separator plate.
- the fuel flow path has a perimeter. the fuel flow path within the perimeter is configured to direct flow across the at least one fuel cell within a first plane.
- the separator plate, the frame, or both establish at least one conduit that is positioned outside the flow path perimeter and is fluidly coupled with the flow path.
- the at least one conduit is configured to direct flow within a second, different plane.
- the planes are nonparallel.
- a dimpled interconnector portion establishes at least a portion of an interconnector flow path that is operative to communicate airflow through the fuel cell repeater unit, the dimpled interconnector having a plurality of dimples.
- An example interconnector of a fuel cell repeater unit includes a dimpled interconnector of a fuel cell repeater unit.
- the dimpled interconnector establishes at least a portion of an interconnector flow path operative to communicate airflow through the fuel cell repeater unit, the dimpled interconnector having a plurality of dimples.
- FIG. 1 shows a schematic sectional view of an example fuel cell arrangement having 6 fuel cells in a 2 ⁇ 3 matrix configuration.
- FIG. 2 shows an example fuel cell stack assembly
- FIG. 3 shows a perspective view of an example repeater unit.
- FIG. 4 shows an exploded view of the FIG. 3 repeater unit.
- FIG. 5 shows a sectional view through line 5 - 5 of FIG. 3 .
- FIG. 6 shows an example stack of the FIG. 3 repeater units.
- FIG. 7 shows a sectional view through a portion of the FIG. 6 stack.
- FIG. 8 shows a perspective view of an example fuel cell arrangement having multiple fuel cell stack assemblies.
- FIG. 9 shows a top schematic view of FIG. 8 fuel cell arrangement having multiple fuel cell stack assemblies.
- FIG. 10 shows an exploded view of another example repeater unit.
- FIG. 11 shows a top view of the FIG. 10 repeater unit.
- FIG. 12 shows a section view through line 12 - 12 of FIG. 11 .
- FIG. 13 shows an example stack assembly rig.
- FIG. 14 shows a section view of an example interconnector.
- FIG. 15 shows a section view of another example interconnector.
- an example fuel cell arrangement 10 includes a fuel cell stack assembly 14 housed within a duct 18 .
- the fuel cell stack assembly 14 includes multiple repeater units 22 .
- each of the repeater units 22 includes a plurality of tri-layer solid oxide fuel cells (SOFC) 26 that are arranged in a 2 ⁇ 3 matrix and aligned within the same plane.
- SOFCs utilize different numbers of the SOFCs 26 , such as a single SOFC, and different arrangements, such as a 3 ⁇ 3 matrix or a 4 ⁇ 2 matrix.
- the SOFCs utilize supplies of fuel and air to generate electrical power in a known manner.
- the M ⁇ N matrix of fuel cells in a plane, where M, the number of rows, or N, the number of columns, is an integer equal or greater than 1, is referred to as the window frame design.
- the tri-layer solid oxide fuel cells 26 discussed herein are planar and comprise the anode electrode layer, the electrolyte layer, and the cathode electrode layer.
- the electrolyte layer is sandwiched between the anode electrode and the cathode electrode.
- FIG. 1-9 the anode electrode faces down.
- the anode electrode may face up as another example.
- a fuel supply reservoir 30 provides fuel that is directed through at least one conduit 34 a to the repeater unit 22 .
- the at least one conduit 34 a is partially established by the repeater unit 22 in this example.
- Spent fuel is directed from the SOFC 26 to at least one second conduit 34 b and then away from the repeater unit 22 .
- a spent fuel reservoir 38 holds spent fuel.
- a fuel pump 42 facilitates moving fuel through the repeater unit 22 .
- an air supply 44 provides air that is directed to the duct 18 through an air inlet 46 .
- air inlet 46 and air outlet 54 can be located in a variety of duct 18 , any vertical face, bottom face, or top face.
- the SOFC 26 uses the oxygen in the air for the electrochemical reaction and releases spent air, i.e., air with reduced oxygen content, through the air outlet 54 .
- This example includes a spent air reservoir 56 .
- An air pump 50 facilitates moving air to the duct 18 and across the repeater unit 22 .
- the fuel supply reservoir 30 , the spent fuel reservoir 38 , the air supply 44 , and the spent air reservoir 56 also denote piping connections or junctions between the fuel cell arrangement 10 and a fuel cell system or power plant comprising multiples of the fuel cell arrangement 10 .
- the fuel cell stack assembly 14 holds multiple repeater units 22 together between end plates 58 .
- Bolts 62 or similar mechanical fasteners, or an external loading mechanism, secure the example components together.
- the corner portions 64 of the repeater units 22 and the end plates 58 establish the fuel cell conduits 34 a and 34 b, which have a generally circular cross-section in this example.
- the conduits 34 a and 34 b in the example of FIG. 1 have a rectangular cross section.
- the length L of the conduits 34 a and 34 b corresponds generally to the height of the fuel cell stack assembly 14 .
- the conduits 34 a and 34 b will also be referred to as the primary fuel manifolds.
- the example individual repeater units 22 each include a cell frame 70 secured to separator plate 66 to form a cassette-like structure.
- the separator plate 66 and the cell frame 70 are welded at their outer perimeters to effectively hermetically seal the fuel gas space in the fuel cell stack assembly 14 .
- the separator plate 66 and the cell frame 70 include holes that establish a portion of the conduits 34 a and 34 b in this example. Together, a plurality of the separator plates 66 and cell frames 70 , and the sealant material 92 located therebetween and around conduits 34 a and 34 b, establish the conduits 34 when they are in a cell stack assembly 14 .
- the SOFCs 26 and corresponding flat wire mesh interconnects 74 which is also referred to as the anode-side interconnect, are held between the cell frame 70 and the separator plate 66 .
- the wire diameter ranges from 0.5 to 2 mm, and the wire composition is selected from the group of nickel, copper, and nickel-copper alloys.
- the flat wire mesh interconnects 74 comprise corrugated expanded metal.
- the wire diameter ranges from 0.125 mm to 0.250 mm, and the wire composition is selected from the group of nickel-based alloys, nickel-chromium alloys, including Haynes 230, Inconels, and Hastelloys.
- the flat wire mesh interconnects 74 are replaced with dimples extending from the separator plate 66 . In yet another example, the flat wire mesh interconnects 74 are replaced with sheets of metallic foam.
- the material is selected from nickel foams, copper foams, or nickel-copper alloy foams.
- Each repeater unit 22 holds multiple SOFCs 26 within the same plane in this example. Openings 78 through the cell frame 70 leave a portion of the SOFCs 26 exposed. In this example, the openings 78 are larger than the cathode electrode layer of the SOFCs 26 . The example openings 78 have a rectangular profile.
- the cell frame 70 contacts the electrolyte surface of the SOFCs 26 at a joint 71 made of glass, glass ceramics, ceramics, metal oxides, metal brazes or a combination of them.
- a fuel channel 72 which comprises a trough-like cavity extending along the front and the back of the repeater unit 22 , the front being ahead of the first row of cells and the back being after the last row of cells in the repeater unit.
- Fuel moving within the repeater unit 22 flows within the fuel channel 72 and across the fuel cells 26 .
- the flow channel 72 will also be referred to as the secondary fuel manifold.
- the cell frame 70 comprises a stamped piece.
- the equipment stamping the cell frame 70 is configured to deform the relatively planar stock material to establish the portion of the cell frame 70 that corresponds to the fuel channel 72 and accommodates the heights of the anode side interconnect 74 , the fuel cell 26 , the height of the bonding materials that may be used to bond the interconnect 74 to the anode electrode of the fuel cell 26 , and the height of the sealing materials that are used to bond and seal the top electrolyte surface at the periphery of the fuel cell 26 to the corresponding underside surface of cell frame 70 .
- the bonding and sealing materials are not shown in the drawings.
- the stamping operation moves a first portion 79 of the cell frame 70 away from a second portion 81 .
- the amount of movement, and relative deformation, between the first portion 79 and the second portion 81 corresponds to a height h, which is the approximate sum of the heights of the SOFC 26 , the anode side interconnect 74 , and any bonding materials that may be bond the anode side interconnect 74 to the separator plate 66 and to the anode electrode of the SOFCs 26 .
- the frame stamping operation moves second portion 181 and third portion 183 , FIG. 11 , around conduits 134 a to essentially bridge the height between the top surface of a first separator plate 66 and the bottom surface of a second separator plate disposed of immediately above said first separator plate.
- the openings 78 and the openings 34 a and 34 b are formed either during the stamping step or by machining after the stamping operation by any suitable and cost-effective machining operations such as milling, electron discharge machining (EDM), laser slicing.
- the space created between the first portion 79 and the cell frame 70 receives portions of the SOFC 26 and the anode side interconnect 74 .
- the openings 78 are smaller than the dimensions of the anode electrode and electrolyte layer, and larger than the cathode of the SOFC 26 .
- the space created between the first portion 79 and the cell frame 70 receives the anode electrode and electrolyte layer of the SOFC 26 , and the cathode of the SOFC 26 extends into or through the opening.
- the second portion 81 of the cell frame 70 is then secured to the separator plate 66 by welding a continuous welding bead along the exterior perimeter of the separator plate 66 and the cell frame 70 .
- the second portion 81 of the cell frame 70 is secured to the separator plate 66 by a sufficient number of spot welds 93 between adjacent SOFCs 26 .
- a seal 92 seals the interface between adjacent repeater units 22 that combine to establish the conduits 34 a and 34 b.
- each seal 92 comprises an O-ring-like structure having a V-, C-, or ⁇ -shaped cross-section.
- One side of the seal 92 is welded to the cell frame 70 in the openings 34 a and 34 b.
- the opposite side of the seal 92 is bonded to the underside of the separator plate 66 corresponding to the adjacent repeater unit 22 within the stack. This bonding is achieved by means of dielectric materials or through another set of materials and processes that ensure dielectric separation between adjacent repeater units 22 .
- the bonding dielectric materials for sealing may be glass, glass ceramics, glass-metal composites, glass-metal oxide composites or their combination.
- the bonding materials may also be chosen appropriate metallic materials provided that the seal 92 or the respective area of the separator plate 66 are equipped with a dielectric skin that has adequate voltage breakdown strength to ensure dielectric isolation of the repeater units 22 in a stack. These bonding materials will also be referred to as sealing materials.
- a plurality of inserts 94 that have a thickness essentially equal to the distance between the first portion 79 and the second portion 81 of the cell frame 70 are positioned between the cell frame 70 and the separator plate 66 each permit fuel flow between the respective conduit 34 a and 34 b and the fuel channel 72 .
- the inserts 94 do not seal a closed periphery and have an opening corresponding to the width of the fuel channel 72 .
- the example inserts 94 need only be spot-welded to either the cell frame 70 or the separator plate 66 in this example so as to keep the opening of the insert 94 aligned with the fuel channel 72 .
- the inserts 94 support the corresponding area of the cell frame 70 around the conduits 34 a and 34 b so that a compressive load can be applied to the seals 92 to achieve sealing around the conduits 34 a and 34 b and maintain the integrity of the seal 92 in a stack.
- the first portion 79 of the cell frame 70 is displaced, by the stamping process for example.
- the displacement is of a sufficient amount that the displaced portion, and associated bonding materials, spans between the cell frame 70 and the underside of the adjacent separator plate 66 .
- the inserts 94 in such an example have the appropriate thickness to provide structural support to the sealing portion of the cell frame sheet around the conduits 34 a and 34 b.
- the conduits 34 a and 34 b are positioned near the perimeter corners of the cell frame 70 and the separator plate 66 , and the direction of fuel flow through the conduits 34 a and 34 b is perpendicular to the direction of fuel flow across the SOFCs 26 .
- Adjusting the cross-sectional area X 2 of the conduits 34 a and 34 b alters characteristics of flow through the conduits 34 a and 34 b.
- the value of X 2 is chosen so as to ensure near uniform distribution of fuel to the repeater units in a stack.
- utilizing the round cross-sections of FIGS. 2-8 may facilitate sealing the conduits 34 a and 34 b and lead to durable, robust seals with respect to thermal cycling.
- Utilizing the rectangular cross-sections of FIG. 1 may desirably reduce the amount of material in the repeater unit 22 .
- the conduits 34 a and 34 b may include other cross-sectional geometries. Regardless the chosen geometry of the conduits 34 a and 34 b, the sum of the four conduit perimeters is smaller than the perimeter of other internally manifolded repeater units in the prior art that are sealed by dielectric materials, i.e., glass ceramics, in assembling a stack.
- a wire mesh interconnect 86 is secured to the underside of the separator plate 66 by means of welding, seam welding, brazing, diffusion bonding or a combination of these.
- the wire mesh interconnect 86 is corrugated and defines a plurality of channels 88 for directing air flow across cathode electrode side of the SOFCs 26 and of the repeater unit 22 through the stack assembly 14 .
- the channels 88 are open toward the SOFCs 26 to facilitate the transport of oxygen to the cathode electrode of the SOFCs 26 for the electrochemical reaction.
- the corrugated wire mesh interconnect 86 has a dovetail cross-sectional profile.
- the example wire mesh interconnect 86 is a compliant structure with well-defined deformation characteristics, which can be used to design the mechanical load that can be applied to the fuel cell 26 .
- This approach facilitates adequate contact between the wire mesh interconnect 86 and the SOFCs 26 and minimal interface ohmic resistance. The approach also lessens the potential for fracturing the SOFC 26 and accommodates the dimensional variability of production repeater units 22 of large footprint area, which reduces material and fabrication costs.
- the example wire mesh interconnect 86 is bonded to the cathode electrode by means of appropriate ceramic materials, such as perovskite or spinel materials.
- appropriate ceramic materials such as perovskite or spinel materials.
- This approach lessens the ohmic resistance to electron flow and resists changes to the ohmic resistance across the wire mesh interconnect 86 and cathode electrode of the SOFC 26 .
- This approach also indirectly lessens the mechanical load across the stack. Changes in the ohmic resistance typically arise from potential thermal stresses during thermal cycling. Minimization of the mechanical load or stress also leads to minimization of the potential for interconnect creep under the operating conditions, since creep deformation is a function of material properties and stress.
- the metal alloy selected for the wire mesh interconnect 86 is a nickel-based alloy that exhibits excellent oxidation and creep resistance at the fuel cell operating temperatures of 650° C. to 900° C. thus ensuring good electrochemical performance stability and long lifetime for the fuel cell stack.
- the wire mesh interconnect 86 is coated with chromia-containment materials to further enhance performance stability and lifetime in some examples.
- the wire mesh interconnect 86 is compliant and is bonded to one side or extended surface of the separator plate 66 while the flat wire mesh interconnects 74 are bonded to the opposite side of the separator plate 66 to form a bipolar plate.
- Example bonding techniques include brazing, welding, seam welding, diffusion bonding and other metal bonding methods well known in the art.
- the wire mesh interconnect 86 , the flat wire mesh interconnect 74 , and the separator plate 66 are made from different metals or alloys to provide enhanced oxidation, corrosion, and creep resistance and mitigation of thermal stresses that may arise during thermal cycling.
- the example corrugated wire mesh interconnect 86 is made of a nickel based alloy, such as Haynes 230 , which has excellent oxidation and creep resistance in air at the fuel cell operating temperatures of 650° C. to 900° C.
- the flat wire mesh interconnects 74 is made of pure nickel wire which is very stable in the fuel environment
- the separator plate 66 is made of iron-chromium alloys that offer adequate matching of thermal expansion characteristics to those of the ceramic fuel cells to ensure the integrity of the fuel cell stack under thermal cycling between the ambient and fuel cell operating temperatures.
- the wire diameter ranges from 0.125 to 0.250 mm.
- Each repeater unit 22 establishes a fuel channel perimeter 99 that surrounds all of the SOFCs 26 within that repeater unit 22 .
- the fuel channels 72 upstream, with regard to the direction of fuel flow, and downstream of the SOFCs 26 are positioned within the fuel channel perimeter 99 . That is, perimeter surrounds all of the fuel flow in a direction aligned with the SOFCs 26 .
- the conduits 34 a and 34 b are positioned outside the fuel channel perimeter 99 .
- the fuel channel perimeter 99 is aligned with the space 98 in this example, which establish the transition from the channels 34 a and 34 b to the fuel channels 72 adjacent the SOFCs 26 of the repeater unit 22 .
- the dimensions (the width and height) of the fuel channels 72 are designed so as to ensure essentially uniform flow distribution across the fuel cells 26 in each repeater unit 22 of a fuel cell 14 .
- more than one fuel cell stack assembly 14 may be arranged within a duct 18 .
- air enters in the compartment or plenum 140 via inlets 46 between the first group 90 of fuel cell stack assemblies 14 and second group 91 of fuel cell stack assemblies 14 and splits into two streams flowing in opposite directions, one stream moving through the channels 88 of a first group 90 of fuel cell stack assemblies 14 before exiting the duct 18 , and the other stream moving through a second group 91 of fuel cell stack assemblies 14 before exiting the duct 18 via outlets 54 .
- Ring seals 96 seal the interfaces between the conduits 34 a and 34 b of adjacent ones of the cell stack assemblies 14 and the inlet and outlet pipes.
- the fuel cell stack assemblies 14 are packed in the duct 18 using air seals 100 configured to seal interfaces between the fuel cell stack assemblies 14 and the duct 18 .
- the air seals 100 are made of ceramic fibrous materials that are used to provide flow resistance and essentially block air flow around the fuel cell stack assemblies 14 and in areas other than channels 88 .
- the conduits 34 a and 34 b attach to pipes (not shown) that carry fuel from the fuel supply reservoir 30 to the conduits 34 a and from the conduits 34 b to the spent fuel reservoir 38 or to corresponding connection points in a fuel cell system (not shown).
- the air inlet 46 and the air outlet 54 also attach to pipes (not shown) that carry air from the air supply 44 to the duct 18 , and to the spent air reservoir 56 .
- a person skilled in the art that has the benefit of this disclosure would understand how to suitably connect the fuel cell arrangement 10 to the fuel supply reservoir 30 , the spent fuel reservoir 38 , the air supply 44 , and the spent air reservoir 56 .
- Manipulating the positions of the conduits 34 a and 34 b and the fuel channels 72 relative to the direction of air flow through the fuel cell stack assembly 14 provides several configurations, such as a co-flow arrangement where the fuel flows in the same direction as the air, counter-flow arrangement where the fuel flows in an opposite direction from the air, or cross-flow configurations where the fuel flows transverse to the air.
- an example repeater unit 122 includes cell frame 170 .
- the repeater unit 122 is stamped to establish the contours of the repeater unit 122 .
- the repeater unit 122 holds a single fuel cell 126 and thus has a 1 ⁇ 1 matrix.
- the cell frame 170 of the repeater unit 122 has a reinforcement zone having a first portion 179 , a second portion 181 , and a third portion 183 that are spaced relative to each other.
- the first portion 179 , the second portion 181 , and the third portion 183 are examples of the types of contours stamped into the repeater unit 122 .
- the first portion 179 , the second portion 181 , and the third portion 183 correspond to steps or tiers each having a different spacing of height relative to the separator plate 166 .
- Transitions 84 between the first portion 179 , the second portion 181 , and the third portion 183 are radiused in this example.
- Other reinforcement zones may include additional portions to accommodate different spacings or stamping requirements.
- a stamping operation deforms or moves the second portion 181 of the cell frame 170 away from the third portion 183 , and the first portion 179 away from the third portion 183 and the second portion 181 .
- the stamping operation also forms the fuel channel 172 .
- the radiused transitions 84 facilitate material movement during the stamping operation.
- this design reduces the thickness of the seal 192 to the range of 0.025 mm to 0.150 mm reduces the potential for catastrophic failure of the sealant material during thermal cycling.
- the distance between the first portion 179 and the third portion 183 corresponds to a height h 1 , which is the approximate sum of the heights of the fuel cell 126 , the anode side interconnect 174 , any bonding materials that may be bond the anode side interconnect 174 to a separator plate 166 and to the anode electrode of the fuel cell 26 , plus the height of the cathode side interconnect minus the effective height of the seal 192 that seals the top portion of the frame to the bottom surface of the adjacent separator plate 166 .
- the example inserts 194 have a thickness essentially equal to the height h 1 minus the thickness of the separator place 166 and the seal 192 .
- the example inserts 194 establish a plurality of openings 95 configured to communicate flow between conduit 134 a, the conduit 134 b, and the fuel channel 172 .
- the openings 95 are positioned and sized to achieve a desired flow.
- the example inserts 194 are spot-welded to the cell frame 170 , the separator plate 166 or both to ensure that the openings 95 are properly oriented relative to the fuel channel 172 .
- the example inserts 194 support the corresponding area of the cell frame 170 around the conduits 134 a and 134 b so that a compressive load can be applied to the seals 192 to achieve sealing around the conduits 134 a and 134 b and maintain the integrity of the seal 192 in a stack. At least a portion of the example inserts 194 extending circumferentially about the entire perimeter of the conduit 134 a or 134 b.
- the example inserts 194 are formed from a planar sheet of metallic material and then bent into the cylindrical shape shown. In another example, the inserts 194 are cut from a cylinder or tube of material. Inserts 194 are made of alloys closely related to the alloys used for the separator 166 and frame 170 .
- the example repeater unit 122 includes a plurality of protrusions 97 located on both sides of the repeater unit 122 .
- a notch 130 is established on one side of the repeater unit.
- the notch 130 and protrusions 97 are positioned against alignment rods 102 in a suitable stack assembly rig 103 .
- the notch 130 is received over the alignment rod 102 in this example.
- the notch 130 and protrusions 97 facilitate positioning the repeater unit 122 relative to another repeater unit 122 a during assembly.
- Other examples of the repeater unit 122 may utilize cut-outs or other types of notches 130 and protrusions 97 to locating the repeater unit 122 during assembly.
- the alignment rods 102 are supported by the stack assembly rig 103 , which supports the weight of the rods and the repeater units 122 as they are stacked against the alignment rods 102 .
- Truss-like lattice work (not shown) provides further support to the rods 102 in some examples.
- the repeater unit 122 and 122 a are sequentially stacked against a rig base plate 104 of the stack assembly rig 103 during assembly.
- the alignment rods 102 extend at right angles relative to the rig base plate 104 .
- a stack current collector plate and an end or compression plate, not shown, against which the repeater units are stacked are preferably the first stack components placed against rig base plate 104 during stack assembly.
- the example repeater unit 122 further includes notches 101 .
- the notches 101 relieve stress during operation by separating the thermal strain experienced by the stamped geometry that make up conduits 134 a and 134 b from exerting strain to the corners of fuel cell 126 .
- an example interconnect 186 has a plurality of rounded or hemispherical dimples 106 and is laser welded to the separator plate 166 .
- the example dimples 106 have a radius of about 1.0 mm in this example, and each of the example dimples 106 is spaced about 3.0 mm from an adjacent one on the plurality of dimples 106 .
- the dimple radius ranges from 0.5 mm to 2.5 mm, while the spacing between dimples ranges from 1 mm to 4 mm.
- interconnect 186 examples include truncated hemispherical dimples, conical dimples, truncated conical dimples, prismatic, i.e., hexagonal footprint with a flat top, or prismatic with a spherical segment top.
- the footprint of the dimple that is the shape of the dimple at the flat base plane, can have a cylindrical, ellipsoid, square, tetragonal, or polygonal geometry.
- the height of the dimple ranges from 0.5 to 2.5 mm.
- the compliance of the interconnect 186 can be adjusted by modifying wire diameters, the wire design, and the geometry of the dimples 106 .
- the wire diameter for interconnect 186 ranges from 0.125 mm to 0.250 mm.
- the example interconnect 188 of FIG. 15 has a circular arc cross-section with dimples 190 that are shallower than the dimples 106 .
- the dimples 190 are spaced about 2.0 mm apart in this example and have a radius of about 2.5 mm.
- the height of the dimples 190 is about 1.0 mm.
- the dimples 190 are shown as arcs from a circle in this example. In another example, the dimples 190 are arcs from parabolas, hyperbolas, or ellipses.
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Abstract
Description
- This application is a continuation of U.S. patent application Ser. No. 12/770032, filed 29 Apr. 2010, which is a continuation-in-part of U.S. patent application Ser. No. 12/679772, filed 24 Mar. 2010, which is a National Phase application of International Application No. PCT/US2008/080671. These applications are each incorporated herein by reference.
- This invention was made with United States Government support under Contract No. DE-FC26-01NT41246 awarded by the Department of Energy. The United States Government may have certain rights in this invention.
- This disclosure relates generally to fuel cells and, more particularly, to repeater units that facilitate fuel cell fluid communication through a fuel cell stack assembly.
- Fuel cell stack assemblies are well known. Some fuel cell stack assemblies include multiple repeater units arranged in a stacked relationship. The repeater units each typically include a fuel cell, such as a solid oxide fuel cell (SOFC), that has an electrolyte layer positioned between a cathode electrode layer and an anode electrode layer. Providing the SOFC with a supply of fuel and air generates electrical power in a known manner. An interconnector near the anode electrode layer and another interconnector near the cathode electrode layer electrically connect the repeater unit to an adjacent repeater unit in the stack.
- As known, some fuel cell stack assemblies rely on complex arrangements for delivering supplies of fuel and air to the SOFC within each repeater unit. Adding more repeater units to the fuel cell stack assembly typically increases the size and complexity of the delivery arrangement because each repeater unit includes an SOFC requiring an evenly distributed supply of fuel and air. One example prior art arrangement includes multiple repeater units that each have a complex pattern of holes for fuel delivery and another pattern of holes for air delivery. Aligning these holes is difficult and time consuming. Achieving durable hermetic sealing between complex air and fuel holes is challenging.
- What is needed is a simplified arrangement for delivering supplies of fuel and air to an SOFC and for distributing air and fuel uniformly at the electrodes.
- An example fuel cell repeater includes a separator plate and a frame establishing at least a portion of a flow path that is configured to fluidly couple a fuel supply with at least one fuel cell held by the frame relative to the separator plate. The flow path has a flow path perimeter. The flow path is within the flow path perimeter and configured to direct flow across the at least one fuel cell within a first plane. A dimpled interconnector portion establishes at least a portion of an interconnector flow path operative to communicate airflow through the fuel cell repeater.
- An example fuel cell repeater unit includes a separator plate. A frame establishes at least a portion of a fuel flow path that is configured to fluidly couple a fuel supply with at least one fuel cell held by the frame relative to the separator plate. The fuel flow path has a perimeter. the fuel flow path within the perimeter is configured to direct flow across the at least one fuel cell within a first plane. The separator plate, the frame, or both establish at least one conduit that is positioned outside the flow path perimeter and is fluidly coupled with the flow path. The at least one conduit is configured to direct flow within a second, different plane. The planes are nonparallel. A dimpled interconnector portion establishes at least a portion of an interconnector flow path that is operative to communicate airflow through the fuel cell repeater unit, the dimpled interconnector having a plurality of dimples.
- An example interconnector of a fuel cell repeater unit includes a dimpled interconnector of a fuel cell repeater unit. The dimpled interconnector establishes at least a portion of an interconnector flow path operative to communicate airflow through the fuel cell repeater unit, the dimpled interconnector having a plurality of dimples.
- These and other features of the disclosed examples can be best understood from the following specification and drawings. The following is a brief description of the drawings.
-
FIG. 1 shows a schematic sectional view of an example fuel cell arrangement having 6 fuel cells in a 2×3 matrix configuration. -
FIG. 2 shows an example fuel cell stack assembly. -
FIG. 3 shows a perspective view of an example repeater unit. -
FIG. 4 shows an exploded view of theFIG. 3 repeater unit. -
FIG. 5 shows a sectional view through line 5-5 ofFIG. 3 . -
FIG. 6 shows an example stack of theFIG. 3 repeater units. -
FIG. 7 shows a sectional view through a portion of theFIG. 6 stack. -
FIG. 8 shows a perspective view of an example fuel cell arrangement having multiple fuel cell stack assemblies. -
FIG. 9 shows a top schematic view ofFIG. 8 fuel cell arrangement having multiple fuel cell stack assemblies. -
FIG. 10 shows an exploded view of another example repeater unit. -
FIG. 11 shows a top view of theFIG. 10 repeater unit. -
FIG. 12 shows a section view through line 12-12 ofFIG. 11 . -
FIG. 13 shows an example stack assembly rig. -
FIG. 14 shows a section view of an example interconnector. -
FIG. 15 shows a section view of another example interconnector. - Referring to
FIG. 1 , an examplefuel cell arrangement 10 includes a fuelcell stack assembly 14 housed within aduct 18. The fuelcell stack assembly 14 includesmultiple repeater units 22. In this example, each of therepeater units 22 includes a plurality of tri-layer solid oxide fuel cells (SOFC) 26 that are arranged in a 2×3 matrix and aligned within the same plane. Other examples include different numbers of theSOFCs 26, such as a single SOFC, and different arrangements, such as a 3×3 matrix or a 4×2 matrix. The SOFCs utilize supplies of fuel and air to generate electrical power in a known manner. The M×N matrix of fuel cells in a plane, where M, the number of rows, or N, the number of columns, is an integer equal or greater than 1, is referred to as the window frame design. - The tri-layer solid
oxide fuel cells 26 discussed herein are planar and comprise the anode electrode layer, the electrolyte layer, and the cathode electrode layer. The electrolyte layer is sandwiched between the anode electrode and the cathode electrode. In all the drawings,FIG. 1-9 , the anode electrode faces down. The anode electrode may face up as another example. - In this example, a
fuel supply reservoir 30 provides fuel that is directed through at least oneconduit 34 a to therepeater unit 22. The at least oneconduit 34 a is partially established by therepeater unit 22 in this example. Spent fuel is directed from theSOFC 26 to at least onesecond conduit 34 b and then away from therepeater unit 22. In this example, a spentfuel reservoir 38 holds spent fuel. Afuel pump 42 facilitates moving fuel through therepeater unit 22. - In this example, an
air supply 44 provides air that is directed to theduct 18 through anair inlet 46. Within theduct 18, air moves across therepeater unit 22 and leaves theduct 18 through anair outlet 54.Air inlet 46 andair outlet 54 can be located in a variety ofduct 18, any vertical face, bottom face, or top face. TheSOFC 26 uses the oxygen in the air for the electrochemical reaction and releases spent air, i.e., air with reduced oxygen content, through theair outlet 54. This example includes a spentair reservoir 56. Anair pump 50 facilitates moving air to theduct 18 and across therepeater unit 22. In some examples, thefuel supply reservoir 30, the spentfuel reservoir 38, theair supply 44, and the spentair reservoir 56 also denote piping connections or junctions between thefuel cell arrangement 10 and a fuel cell system or power plant comprising multiples of thefuel cell arrangement 10. - Referring to
FIGS. 2-5 , the fuelcell stack assembly 14 holdsmultiple repeater units 22 together betweenend plates 58.Bolts 62, or similar mechanical fasteners, or an external loading mechanism, secure the example components together. Thecorner portions 64 of therepeater units 22 and theend plates 58 establish thefuel cell conduits conduits FIG. 1 have a rectangular cross section. The length L of theconduits cell stack assembly 14. Theconduits - The example
individual repeater units 22 each include acell frame 70 secured toseparator plate 66 to form a cassette-like structure. In one example, theseparator plate 66 and thecell frame 70 are welded at their outer perimeters to effectively hermetically seal the fuel gas space in the fuelcell stack assembly 14. - The
separator plate 66 and thecell frame 70 include holes that establish a portion of theconduits separator plates 66 and cell frames 70, and thesealant material 92 located therebetween and aroundconduits cell stack assembly 14. - The
SOFCs 26 and corresponding flat wire mesh interconnects 74, which is also referred to as the anode-side interconnect, are held between thecell frame 70 and theseparator plate 66. For the flat wire mesh interconnect the wire diameter ranges from 0.5 to 2 mm, and the wire composition is selected from the group of nickel, copper, and nickel-copper alloys. In another example, the flat wire mesh interconnects 74 comprise corrugated expanded metal. For the corrugated wire mesh, the wire diameter ranges from 0.125 mm to 0.250 mm, and the wire composition is selected from the group of nickel-based alloys, nickel-chromium alloys, including Haynes 230, Inconels, and Hastelloys. In yet another example, the flat wire mesh interconnects 74 are replaced with dimples extending from theseparator plate 66. In yet another example, the flat wire mesh interconnects 74 are replaced with sheets of metallic foam. For metallic foam, the material is selected from nickel foams, copper foams, or nickel-copper alloy foams. - Each
repeater unit 22 holdsmultiple SOFCs 26 within the same plane in this example.Openings 78 through thecell frame 70 leave a portion of theSOFCs 26 exposed. In this example, theopenings 78 are larger than the cathode electrode layer of theSOFCs 26. Theexample openings 78 have a rectangular profile. Thecell frame 70 contacts the electrolyte surface of theSOFCs 26 at a joint 71 made of glass, glass ceramics, ceramics, metal oxides, metal brazes or a combination of them. - Some portions of the
cell frame 70 are spaced from theseparator plate 66 to provide afuel channel 72, which comprises a trough-like cavity extending along the front and the back of therepeater unit 22, the front being ahead of the first row of cells and the back being after the last row of cells in the repeater unit. Fuel moving within therepeater unit 22 flows within thefuel channel 72 and across thefuel cells 26. Theflow channel 72 will also be referred to as the secondary fuel manifold. - In some examples, the
cell frame 70 comprises a stamped piece. The equipment stamping thecell frame 70 is configured to deform the relatively planar stock material to establish the portion of thecell frame 70 that corresponds to thefuel channel 72 and accommodates the heights of theanode side interconnect 74, thefuel cell 26, the height of the bonding materials that may be used to bond theinterconnect 74 to the anode electrode of thefuel cell 26, and the height of the sealing materials that are used to bond and seal the top electrolyte surface at the periphery of thefuel cell 26 to the corresponding underside surface ofcell frame 70. The bonding and sealing materials are not shown in the drawings. The stamping operation moves afirst portion 79 of thecell frame 70 away from asecond portion 81. In this example, the amount of movement, and relative deformation, between thefirst portion 79 and thesecond portion 81 corresponds to a height h, which is the approximate sum of the heights of theSOFC 26, theanode side interconnect 74, and any bonding materials that may be bond theanode side interconnect 74 to theseparator plate 66 and to the anode electrode of theSOFCs 26. - The frame stamping operation moves
second portion 181 andthird portion 183,FIG. 11 , aroundconduits 134 a to essentially bridge the height between the top surface of afirst separator plate 66 and the bottom surface of a second separator plate disposed of immediately above said first separator plate. - The
openings 78 and theopenings first portion 79 and thecell frame 70 receives portions of theSOFC 26 and theanode side interconnect 74. Theopenings 78 are smaller than the dimensions of the anode electrode and electrolyte layer, and larger than the cathode of theSOFC 26. Thus, the space created between thefirst portion 79 and thecell frame 70 receives the anode electrode and electrolyte layer of theSOFC 26, and the cathode of theSOFC 26 extends into or through the opening. - The
second portion 81 of thecell frame 70 is then secured to theseparator plate 66 by welding a continuous welding bead along the exterior perimeter of theseparator plate 66 and thecell frame 70. Thesecond portion 81 of thecell frame 70 is secured to theseparator plate 66 by a sufficient number ofspot welds 93 betweenadjacent SOFCs 26. - A
seal 92 seals the interface betweenadjacent repeater units 22 that combine to establish theconduits seal 92 comprises an O-ring-like structure having a V-, C-, or ε-shaped cross-section. One side of theseal 92 is welded to thecell frame 70 in theopenings seal 92 is bonded to the underside of theseparator plate 66 corresponding to theadjacent repeater unit 22 within the stack. This bonding is achieved by means of dielectric materials or through another set of materials and processes that ensure dielectric separation betweenadjacent repeater units 22. The bonding dielectric materials for sealing may be glass, glass ceramics, glass-metal composites, glass-metal oxide composites or their combination. The bonding materials may also be chosen appropriate metallic materials provided that theseal 92 or the respective area of theseparator plate 66 are equipped with a dielectric skin that has adequate voltage breakdown strength to ensure dielectric isolation of therepeater units 22 in a stack. These bonding materials will also be referred to as sealing materials. - In another example, a plurality of
inserts 94 that have a thickness essentially equal to the distance between thefirst portion 79 and thesecond portion 81 of thecell frame 70 are positioned between thecell frame 70 and theseparator plate 66 each permit fuel flow between therespective conduit fuel channel 72. Theinserts 94 do not seal a closed periphery and have an opening corresponding to the width of thefuel channel 72. The example inserts 94 need only be spot-welded to either thecell frame 70 or theseparator plate 66 in this example so as to keep the opening of theinsert 94 aligned with thefuel channel 72. Theinserts 94 support the corresponding area of thecell frame 70 around theconduits seals 92 to achieve sealing around theconduits seal 92 in a stack. - In another example, the
first portion 79 of thecell frame 70 is displaced, by the stamping process for example. The displacement is of a sufficient amount that the displaced portion, and associated bonding materials, spans between thecell frame 70 and the underside of theadjacent separator plate 66. Theinserts 94 in such an example have the appropriate thickness to provide structural support to the sealing portion of the cell frame sheet around theconduits - In this example, the
conduits cell frame 70 and theseparator plate 66, and the direction of fuel flow through theconduits SOFCs 26. Adjusting the cross-sectional area X2 of theconduits conduits FIGS. 2-8 may facilitate sealing theconduits FIG. 1 may desirably reduce the amount of material in therepeater unit 22. - The
conduits conduits - A
wire mesh interconnect 86 is secured to the underside of theseparator plate 66 by means of welding, seam welding, brazing, diffusion bonding or a combination of these. Thewire mesh interconnect 86 is corrugated and defines a plurality ofchannels 88 for directing air flow across cathode electrode side of theSOFCs 26 and of therepeater unit 22 through thestack assembly 14. Thechannels 88 are open toward theSOFCs 26 to facilitate the transport of oxygen to the cathode electrode of theSOFCs 26 for the electrochemical reaction. In this example, the corrugatedwire mesh interconnect 86 has a dovetail cross-sectional profile. - The example
wire mesh interconnect 86 is a compliant structure with well-defined deformation characteristics, which can be used to design the mechanical load that can be applied to thefuel cell 26. This approach facilitates adequate contact between thewire mesh interconnect 86 and theSOFCs 26 and minimal interface ohmic resistance. The approach also lessens the potential for fracturing theSOFC 26 and accommodates the dimensional variability ofproduction repeater units 22 of large footprint area, which reduces material and fabrication costs. - The example
wire mesh interconnect 86 is bonded to the cathode electrode by means of appropriate ceramic materials, such as perovskite or spinel materials. This approach lessens the ohmic resistance to electron flow and resists changes to the ohmic resistance across thewire mesh interconnect 86 and cathode electrode of theSOFC 26. This approach also indirectly lessens the mechanical load across the stack. Changes in the ohmic resistance typically arise from potential thermal stresses during thermal cycling. Minimization of the mechanical load or stress also leads to minimization of the potential for interconnect creep under the operating conditions, since creep deformation is a function of material properties and stress. - In this example, the metal alloy selected for the
wire mesh interconnect 86 is a nickel-based alloy that exhibits excellent oxidation and creep resistance at the fuel cell operating temperatures of 650° C. to 900° C. thus ensuring good electrochemical performance stability and long lifetime for the fuel cell stack. Thewire mesh interconnect 86 is coated with chromia-containment materials to further enhance performance stability and lifetime in some examples. - In one example, the
wire mesh interconnect 86 is compliant and is bonded to one side or extended surface of theseparator plate 66 while the flat wire mesh interconnects 74 are bonded to the opposite side of theseparator plate 66 to form a bipolar plate. Example bonding techniques include brazing, welding, seam welding, diffusion bonding and other metal bonding methods well known in the art. Thewire mesh interconnect 86, the flatwire mesh interconnect 74, and theseparator plate 66 are made from different metals or alloys to provide enhanced oxidation, corrosion, and creep resistance and mitigation of thermal stresses that may arise during thermal cycling. - The example corrugated
wire mesh interconnect 86 is made of a nickel based alloy, such as Haynes 230, which has excellent oxidation and creep resistance in air at the fuel cell operating temperatures of 650° C. to 900° C., the flat wire mesh interconnects 74 is made of pure nickel wire which is very stable in the fuel environment, and theseparator plate 66 is made of iron-chromium alloys that offer adequate matching of thermal expansion characteristics to those of the ceramic fuel cells to ensure the integrity of the fuel cell stack under thermal cycling between the ambient and fuel cell operating temperatures. For thewire mesh interconnect 86, the wire diameter ranges from 0.125 to 0.250 mm. - Referring now to
FIGS. 6 and 7 , stacking a plurality ofrepeater units 22 with anotherrepeater unit 22 establishes a length L of theconduits conduits 34 a through thespace 98 in theinserts 94 into thefuel channels 72 to theSOFCs 26. - Each
repeater unit 22 establishes afuel channel perimeter 99 that surrounds all of theSOFCs 26 within thatrepeater unit 22. In this example, thefuel channels 72 upstream, with regard to the direction of fuel flow, and downstream of theSOFCs 26 are positioned within thefuel channel perimeter 99. That is, perimeter surrounds all of the fuel flow in a direction aligned with theSOFCs 26. Theconduits fuel channel perimeter 99. Thefuel channel perimeter 99 is aligned with thespace 98 in this example, which establish the transition from thechannels fuel channels 72 adjacent theSOFCs 26 of therepeater unit 22. The dimensions (the width and height) of thefuel channels 72 are designed so as to ensure essentially uniform flow distribution across thefuel cells 26 in eachrepeater unit 22 of afuel cell 14. - Referring now to
FIGS. 8 and 9 , more than one fuelcell stack assembly 14 may be arranged within aduct 18. In this example, air enters in the compartment orplenum 140 viainlets 46 between thefirst group 90 of fuelcell stack assemblies 14 andsecond group 91 of fuelcell stack assemblies 14 and splits into two streams flowing in opposite directions, one stream moving through thechannels 88 of afirst group 90 of fuelcell stack assemblies 14 before exiting theduct 18, and the other stream moving through asecond group 91 of fuelcell stack assemblies 14 before exiting theduct 18 viaoutlets 54. - Ring seals 96 seal the interfaces between the
conduits cell stack assemblies 14 and the inlet and outlet pipes. The fuelcell stack assemblies 14 are packed in theduct 18 usingair seals 100 configured to seal interfaces between the fuelcell stack assemblies 14 and theduct 18. The air seals 100 are made of ceramic fibrous materials that are used to provide flow resistance and essentially block air flow around the fuelcell stack assemblies 14 and in areas other thanchannels 88. - In one example, the
conduits fuel supply reservoir 30 to theconduits 34 a and from theconduits 34 b to the spentfuel reservoir 38 or to corresponding connection points in a fuel cell system (not shown). Theair inlet 46 and theair outlet 54 also attach to pipes (not shown) that carry air from theair supply 44 to theduct 18, and to the spentair reservoir 56. A person skilled in the art that has the benefit of this disclosure would understand how to suitably connect thefuel cell arrangement 10 to thefuel supply reservoir 30, the spentfuel reservoir 38, theair supply 44, and the spentair reservoir 56. - Manipulating the positions of the
conduits fuel channels 72 relative to the direction of air flow through the fuelcell stack assembly 14 provides several configurations, such as a co-flow arrangement where the fuel flows in the same direction as the air, counter-flow arrangement where the fuel flows in an opposite direction from the air, or cross-flow configurations where the fuel flows transverse to the air. - Referring to
FIGS. 10-15 , anexample repeater unit 122 includescell frame 170. Therepeater unit 122 is stamped to establish the contours of therepeater unit 122. Therepeater unit 122 holds asingle fuel cell 126 and thus has a 1×1 matrix. - In this example, the
cell frame 170 of therepeater unit 122 has a reinforcement zone having a first portion 179, asecond portion 181, and athird portion 183 that are spaced relative to each other. The first portion 179, thesecond portion 181, and thethird portion 183 are examples of the types of contours stamped into therepeater unit 122. - The first portion 179, the
second portion 181, and thethird portion 183 correspond to steps or tiers each having a different spacing of height relative to theseparator plate 166.Transitions 84 between the first portion 179, thesecond portion 181, and thethird portion 183 are radiused in this example. Other reinforcement zones may include additional portions to accommodate different spacings or stamping requirements. - To form the
cell frame 170, a stamping operation deforms or moves thesecond portion 181 of thecell frame 170 away from thethird portion 183, and the first portion 179 away from thethird portion 183 and thesecond portion 181. The stamping operation also forms thefuel channel 172. The radiused transitions 84 facilitate material movement during the stamping operation. The multistep design of the frame stamping around the periphery ofconduits seal 192 to the range of 0.025 mm to 0.150 mm reduces the potential for catastrophic failure of the sealant material during thermal cycling. These features render the window frame stack design more durable and robust under both steady state conditions as well as under thermal cycling. - In this example, the distance between the first portion 179 and the
third portion 183 corresponds to a height h1, which is the approximate sum of the heights of thefuel cell 126, theanode side interconnect 174, any bonding materials that may be bond theanode side interconnect 174 to aseparator plate 166 and to the anode electrode of thefuel cell 26, plus the height of the cathode side interconnect minus the effective height of theseal 192 that seals the top portion of the frame to the bottom surface of theadjacent separator plate 166. - The example inserts 194 have a thickness essentially equal to the height h1 minus the thickness of the
separator place 166 and theseal 192. The example inserts 194 establish a plurality ofopenings 95 configured to communicate flow betweenconduit 134 a, theconduit 134 b, and thefuel channel 172. Theopenings 95 are positioned and sized to achieve a desired flow. - During assembly, the example inserts 194 are spot-welded to the
cell frame 170, theseparator plate 166 or both to ensure that theopenings 95 are properly oriented relative to thefuel channel 172. - The example inserts 194 support the corresponding area of the
cell frame 170 around theconduits seals 192 to achieve sealing around theconduits seal 192 in a stack. At least a portion of the example inserts 194 extending circumferentially about the entire perimeter of theconduit - The example inserts 194 are formed from a planar sheet of metallic material and then bent into the cylindrical shape shown. In another example, the
inserts 194 are cut from a cylinder or tube of material.Inserts 194 are made of alloys closely related to the alloys used for theseparator 166 andframe 170. - The
example repeater unit 122 includes a plurality ofprotrusions 97 located on both sides of therepeater unit 122. Anotch 130 is established on one side of the repeater unit. When assembling a fuel cell stack assembly 114, thenotch 130 andprotrusions 97 are positioned againstalignment rods 102 in a suitablestack assembly rig 103. Thenotch 130 is received over thealignment rod 102 in this example. Thenotch 130 andprotrusions 97 facilitate positioning therepeater unit 122 relative to anotherrepeater unit 122 a during assembly. Other examples of therepeater unit 122 may utilize cut-outs or other types ofnotches 130 andprotrusions 97 to locating therepeater unit 122 during assembly. - In this example, the
alignment rods 102 are supported by thestack assembly rig 103, which supports the weight of the rods and therepeater units 122 as they are stacked against thealignment rods 102. Truss-like lattice work (not shown) provides further support to therods 102 in some examples. - In this example, the
repeater unit rig base plate 104 of thestack assembly rig 103 during assembly. Thealignment rods 102 extend at right angles relative to therig base plate 104. A stack current collector plate and an end or compression plate, not shown, against which the repeater units are stacked are preferably the first stack components placed againstrig base plate 104 during stack assembly. - The
example repeater unit 122 further includesnotches 101. In this example, thenotches 101 relieve stress during operation by separating the thermal strain experienced by the stamped geometry that make upconduits fuel cell 126. - Referring to
FIG. 14 , anexample interconnect 186 has a plurality of rounded orhemispherical dimples 106 and is laser welded to theseparator plate 166. The example dimples 106 have a radius of about 1.0 mm in this example, and each of the example dimples 106 is spaced about 3.0 mm from an adjacent one on the plurality ofdimples 106. The dimple radius ranges from 0.5 mm to 2.5 mm, while the spacing between dimples ranges from 1 mm to 4 mm. Other examples of theinterconnect 186 include truncated hemispherical dimples, conical dimples, truncated conical dimples, prismatic, i.e., hexagonal footprint with a flat top, or prismatic with a spherical segment top. In general, the footprint of the dimple, that is the shape of the dimple at the flat base plane, can have a cylindrical, ellipsoid, square, tetragonal, or polygonal geometry. In these other examples ofinterconnect 186 geometry the height of the dimple ranges from 0.5 to 2.5 mm. Notably, the compliance of theinterconnect 186 can be adjusted by modifying wire diameters, the wire design, and the geometry of thedimples 106. The wire diameter forinterconnect 186 ranges from 0.125 mm to 0.250 mm. - The
example interconnect 188 ofFIG. 15 has a circular arc cross-section withdimples 190 that are shallower than thedimples 106. Thedimples 190 are spaced about 2.0 mm apart in this example and have a radius of about 2.5 mm. The height of thedimples 190 is about 1.0 mm. Thedimples 190 are shown as arcs from a circle in this example. In another example, thedimples 190 are arcs from parabolas, hyperbolas, or ellipses. - Although a preferred embodiment has been disclosed, a worker of ordinary skill in this art would recognize that certain modifications would come within the scope of this invention. For that reason, the following claims should be studied to determine the true scope and content of this invention.
Claims (18)
Priority Applications (1)
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US13/942,763 US20130302716A1 (en) | 2008-10-22 | 2013-07-16 | Fuel cell repeater unit |
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US12/770,032 US8574782B2 (en) | 2008-10-22 | 2010-04-29 | Fuel cell repeater unit including frame and separator plate |
US13/942,763 US20130302716A1 (en) | 2008-10-22 | 2013-07-16 | Fuel cell repeater unit |
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US13/942,763 Abandoned US20130302716A1 (en) | 2008-10-22 | 2013-07-16 | Fuel cell repeater unit |
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WO2015015046A1 (en) * | 2013-07-31 | 2015-02-05 | Convion Oy | High temperature cell arrangement and method |
DK3096381T3 (en) * | 2014-01-15 | 2019-02-18 | Ngk Spark Plug Co | Fuel cell cartridge and fuel cell stack |
PL3103153T3 (en) * | 2014-02-05 | 2018-02-28 | Elcogen Oy | Assembly method and arrangement for a cell system |
WO2016178394A1 (en) * | 2015-05-01 | 2016-11-10 | 日本特殊陶業株式会社 | Fuel-cell power generation unit and fuel-cell stack |
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KR100649219B1 (en) * | 2005-09-28 | 2006-11-24 | 삼성에스디아이 주식회사 | Direct oxydation fuel cell and fuel cell system with the same |
US20070087248A1 (en) * | 2005-10-18 | 2007-04-19 | Samsung Sdi Co., Ltd. | Proton conductive electrolyte membrane, method of preparing the same and fuel cell including the proton conductive electrolyte membrane |
WO2007083838A1 (en) * | 2006-01-19 | 2007-07-26 | Toyota Jidosha Kabushiki Kaisha | Fuel cell |
US7829218B2 (en) * | 2006-03-09 | 2010-11-09 | Samsung Sdi Co., Ltd | Proton conductive electrolyte and fuel cell comprising the same |
-
2010
- 2010-04-29 US US12/770,032 patent/US8574782B2/en active Active
-
2013
- 2013-07-16 US US13/942,763 patent/US20130302716A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US6472094B1 (en) * | 1998-07-10 | 2002-10-29 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Separator for fuel cell and manufacture thereof |
US20040219423A1 (en) * | 2001-04-27 | 2004-11-04 | Tunney Cathal Joseph | Metal-supported solid electrolyte electrochemical cell and multi cell reactors incorporating same |
Also Published As
Publication number | Publication date |
---|---|
US20100209800A1 (en) | 2010-08-19 |
US8574782B2 (en) | 2013-11-05 |
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