US20130064483A1 - Self-lubricating bushing for a joint, which is intended to be mounted on a shaft - Google Patents
Self-lubricating bushing for a joint, which is intended to be mounted on a shaft Download PDFInfo
- Publication number
- US20130064483A1 US20130064483A1 US13/581,530 US201113581530A US2013064483A1 US 20130064483 A1 US20130064483 A1 US 20130064483A1 US 201113581530 A US201113581530 A US 201113581530A US 2013064483 A1 US2013064483 A1 US 2013064483A1
- Authority
- US
- United States
- Prior art keywords
- lip
- bushing
- bush
- shaft
- bore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/20—Sliding surface consisting mainly of plastics
- F16C33/201—Composition of the plastic
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/72—Sealings
- F16C33/74—Sealings of sliding-contact bearings
Definitions
- the invention relates to the technical field of self-lubricating hinge connections, in particular in respect of mounting a shaft in a bush or bearing, for the purpose of translatory and/or rotational guidance.
- the invention is used to advantage in the case of hinge connections that operate in an abrasive medium.
- the wear phenomenon may sometimes be highly significant. Said wear may become apparent on the shaft and/or the bush and is the result of external attack generally at the point of contact of the outside diameter of the shaft with the inside diameter of the bush or bearing.
- the bore of the bush or bearing under consideration to be fitted with at least one leak-tight protective joint, in order to try to ensure that the hinge connection continues to operate properly in an abrasive medium.
- the body of the bush is made of metal, whereas the added joint may be made of PU, PA, NBR, etc.
- the joint may be mounted in a counterbore formed coaxially to the bore of the bush.
- the set purpose of the invention is to overcome these drawbacks in a straightforward, safe, effective and rational manner.
- the problem the invention sets out to resolve is that of providing anti-abrasion protection in the case of a hinge connection against any type of external attack, without the necessity of adding an additional joint, as is apparent in the prior art analysis.
- a hinge connection bush has been designed and perfected for mounting on a shaft.
- Said bush is made out of a composite material and has at least one lip formed directly at the time of manufacture as an overrun edge of its bore to act as a leak-tight barrier after assembly on the shaft by creating a tightening effect between the inside diameter of said lip or said lips, and the outside diameter of said shaft.
- the invention can be used to particular advantage in respect of any type of hinge connection, and particularly of the pivot type, that operates in an abrasive medium.
- the composite material is an epoxy or vinylester or polyester resin.
- the epoxy or vinylester or polyester resin incorporates reinforcements in the form of thermoplastic fibres with a thickness of between 0.05 and 0.5 mm and including lubricating fillers between 5 and 50% of the volume.
- the lip is formed at one of the ends at least of the bore of the bush. Or, the lip is formed starting from an internal groove provided in the bore of the bush. Or, the lip is formed directly starting from the bore of the bush. Or, the lip defines, with the periphery of the body of the bush, a circular cut-out. Or, the lip defines, with the periphery of the body of the bush, a shoulder.
- FIG. 5 is a diagrammatic cross-section view of a hinge connection fitted with a self-lubricating bush according to the invention.
- the bush or bearing denoted in its entirety as ( 1 ), is made out of a composite material and has at least one lip ( 1 a ) formed directly when it is manufactured.
- the composite material constituting the body of the bush, has a modulus of elasticity of between 500 and 6000 N/mm2.
- This composite material is an epoxy or vinylester or polyester resin reinforced by thermoplastic fibres with a thickness of between 0.05 mm and 0.5 mm, and including lubricating fillers between 5 and 50% of the volume.
- the bush may be made by moulding and/or machining
- the lip or lips ( 1 a ) are an overrun edge in the bore ( 1 b ) of the bush to act as a leak-tight and/or protective barrier after assembly, on a shaft ( 2 ) or the like, by creating a tightening effect between the inside diameter (D 1 ) of the bush and the outside diameter (D 2 ) of the shaft ( 2 ).
- the tightening between the diameter (D 1 ) and the diameter (D 2 ) is between 0.05 and about 4 mm and, to advantage, between 0.2 and 2 mm.
- a lip ( 1 a ) is formed at each of the ends of the bush ( 1 ). It is quite clear that, without however departing from the context of the invention, the number and arrangement of the lips are not to be considered as being restrictive.
- each of the lips ( 1 a ) is formed directly starting from the bore ( 1 b ).
- each of the lips ( 1 a ) defines, with the periphery of the body of the bush ( 1 ), a circular cut-out ( 1 c ), in order to promote the elasticity of the lip under consideration.
- each of the lips is formed starting from an internal groove ( 1 d ) provided in the bore ( 1 b ).
- the width of this groove may be variable.
- each lip ( 1 a ) defines, with the periphery of the body of the bush ( 1 ), a shoulder ( 1 e ).
- test conditions were as follows:
- PV 0.6 MPa.m/s.
- the nature of the composite material of the bush conferring a self-lubricating function thereon, in combination with the lip or lips in order to provide effective protection against all kinds of external attack; making the bush to include one or more lips provides a cost saving at assembly and during maintenance; the homogeneity of the material; the elasticity of the material allows deformation on loading, and then a return to the initial state without the load; the improvement in service life; the lack of any metal parts renders the bush compatible with some media (liquid, gaseous) or with magnetic environments such as, for example, those encountered in the field of medical instrumentation; no relative expansion, given that deformation due to heat is the same at all points on the bush; the limitation of noise pollution; the possibility of making one or more grooves that facilitate and improve the elasticity of the lip or lips.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Sliding-Contact Bearings (AREA)
- Sealing Devices (AREA)
- Sealing With Elastic Sealing Lips (AREA)
- Pivots And Pivotal Connections (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Bearings For Parts Moving Linearly (AREA)
- Lubricants (AREA)
- Sealing Of Bearings (AREA)
- Hinges (AREA)
Abstract
Description
- The invention relates to the technical field of self-lubricating hinge connections, in particular in respect of mounting a shaft in a bush or bearing, for the purpose of translatory and/or rotational guidance.
- The invention is used to advantage in the case of hinge connections that operate in an abrasive medium.
- In an abrasive medium, the wear phenomenon may sometimes be highly significant. Said wear may become apparent on the shaft and/or the bush and is the result of external attack generally at the point of contact of the outside diameter of the shaft with the inside diameter of the bush or bearing.
- In an attempt to resolve this problem, a proposal has been made for the bore of the bush or bearing under consideration to be fitted with at least one leak-tight protective joint, in order to try to ensure that the hinge connection continues to operate properly in an abrasive medium. More often than not, the body of the bush is made of metal, whereas the added joint may be made of PU, PA, NBR, etc. For example, the joint may be mounted in a counterbore formed coaxially to the bore of the bush.
- Still with the objective of creating a leak-tight protective barrier against external attack, a bush solution is clearly stated in the teaching in the document WO 2005/072387 which relates to a bush fitted with an added joint housed in a counterbore formed at each of the ends of the bore of the bush. Each joint is shaped to create a leak-tight barrier.
- But it has turned out that the fact of adding a joint relative to the bush, on the one hand, and the fact that the joint is made out of a different material from that of the bush, on the other hand, present some drawbacks. For example, there may be risks of the joint being dislodged. The fact that the hinge connection is composed of heterogeneous parts, in terms of materials, may generate dimensional variations, further in particular to phenomena of expansion in terms of the differentials between the components, humidity absorption, resumption of tightening etc.
- It is also observed that, according to the prior art, a plurality of materials are in contact with the shaft or the conflicting parts, namely the metal in respect of the bush and the material of the joint. The result is that the wear is not uniform.
- Lastly, these added joints generate a not inconsiderable cost given the number of parts required and occasional assembly difficulties.
- The set purpose of the invention is to overcome these drawbacks in a straightforward, safe, effective and rational manner.
- The problem the invention sets out to resolve is that of providing anti-abrasion protection in the case of a hinge connection against any type of external attack, without the necessity of adding an additional joint, as is apparent in the prior art analysis.
- To resolve said problem, a hinge connection bush has been designed and perfected for mounting on a shaft. Said bush is made out of a composite material and has at least one lip formed directly at the time of manufacture as an overrun edge of its bore to act as a leak-tight barrier after assembly on the shaft by creating a tightening effect between the inside diameter of said lip or said lips, and the outside diameter of said shaft.
- The invention can be used to particular advantage in respect of any type of hinge connection, and particularly of the pivot type, that operates in an abrasive medium.
- These characteristics allow a homogenous unit to be obtained given that the lip is cut out of the mass of the bush.
- Advantageous results have been obtained in the case of a composite material which has a modulus of elasticity of between 500 and 6000 N/mm2. Tightening between the inside diameter of the lip and the outside diameter of the shaft is between 0.05 and 4 mm, and preferably 0.2 and 2 mm.
- In a preferred embodiment, the composite material is an epoxy or vinylester or polyester resin. The epoxy or vinylester or polyester resin incorporates reinforcements in the form of thermoplastic fibres with a thickness of between 0.05 and 0.5 mm and including lubricating fillers between 5 and 50% of the volume.
- Starting with the characteristics underlying the invention, different embodiments are conceivable, particularly in terms of the lip or lips.
- Thus:
- Either, the lip is formed at one of the ends at least of the bore of the bush.
Or, the lip is formed starting from an internal groove provided in the bore of the bush.
Or, the lip is formed directly starting from the bore of the bush.
Or, the lip defines, with the periphery of the body of the bush, a circular cut-out.
Or, the lip defines, with the periphery of the body of the bush, a shoulder. - The invention is disclosed hereinafter in further detail with the help of the figures in the appended drawings wherein:
-
FIGS. 1 , 2, 3 and 4 and longitudinal cross-section views showing a plurality of examples of embodiments of a hinge connection bush in accordance with the inventive characteristics; -
FIG. 5 is a diagrammatic cross-section view of a hinge connection fitted with a self-lubricating bush according to the invention. - According to the invention, the bush or bearing, denoted in its entirety as (1), is made out of a composite material and has at least one lip (1 a) formed directly when it is manufactured. The composite material, constituting the body of the bush, has a modulus of elasticity of between 500 and 6000 N/mm2. This composite material is an epoxy or vinylester or polyester resin reinforced by thermoplastic fibres with a thickness of between 0.05 mm and 0.5 mm, and including lubricating fillers between 5 and 50% of the volume.
- The bush may be made by moulding and/or machining
- The lip or lips (1 a) are an overrun edge in the bore (1 b) of the bush to act as a leak-tight and/or protective barrier after assembly, on a shaft (2) or the like, by creating a tightening effect between the inside diameter (D1) of the bush and the outside diameter (D2) of the shaft (2).
- The tightening between the diameter (D1) and the diameter (D2) is between 0.05 and about 4 mm and, to advantage, between 0.2 and 2 mm.
- As is shown particularly by
FIGS. 1 to 4 , a lip (1 a) is formed at each of the ends of the bush (1). It is quite clear that, without however departing from the context of the invention, the number and arrangement of the lips are not to be considered as being restrictive. - In
FIG. 1 , each of the lips (1 a) is formed directly starting from the bore (1 b). - The same thing is true as regards
FIG. 2 , except that each of the lips (1 a) defines, with the periphery of the body of the bush (1), a circular cut-out (1 c), in order to promote the elasticity of the lip under consideration. - In
FIGS. 3 and 4 , each of the lips is formed starting from an internal groove (1 d) provided in the bore (1 b). The width of this groove may be variable. Still inFIGS. 3 and 4 , each lip (1 a) defines, with the periphery of the body of the bush (1), a shoulder (1 e). - Wear tests on bushes made out of a composite material, in accordance with the inventive characteristics, have been carried out in comparison particularly with bushes fitted with added joints, and as a reference relative to a bush that has no joint. These tests were carried out on a back-and-forth movement friction simulator for a maximum duration of one month.
- The test conditions were as follows:
- Maximum test duration: 1 month.
Maximum allowable wear: 0.5 mm.
Tests carried out with 50 μm sand in contact with the shaft/bearing connection.
Initial diameter of tempered case-hardened 16NC6 shaft: 30 mm.
Initial clearance: 2 mm. - With the reference bush, in other words with no leak-tight joint, at the end of about 300,000 cycles, the maximum permitted wear (0.5 mm) is reached.
- With a bush made of metal fitted at the front with a CSWM30 joint made of PA, with a lip of diameter 29.41 mm, at the end of 300,000 cycles, the maximum permitted wear (0.5 mm) is reached.
- With a bush made of a composite material in accordance with the inventive characteristics, in other words with integrated lip, with a diameter of 29.2 mm and a tightening of 0.78 mm, at the end of 700,000 cycles, the wear reading is 0.2 mm.
- For each of the bushes tested, the wear is deduced from a daily reading on comparators placed on each simulation bench.
- The advantages are clear from the description, and in particular the following are stressed and restated:
- the nature of the composite material of the bush conferring a self-lubricating function thereon, in combination with the lip or lips in order to provide effective protection against all kinds of external attack;
making the bush to include one or more lips provides a cost saving at assembly and during maintenance;
the homogeneity of the material;
the elasticity of the material allows deformation on loading, and then a return to the initial state without the load;
the improvement in service life;
the lack of any metal parts renders the bush compatible with some media (liquid, gaseous) or with magnetic environments such as, for example, those encountered in the field of medical instrumentation;
no relative expansion, given that deformation due to heat is the same at all points on the bush;
the limitation of noise pollution;
the possibility of making one or more grooves that facilitate and improve the elasticity of the lip or lips.
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1052296A FR2957995B1 (en) | 2010-03-29 | 2010-03-29 | SELF-LUBRICATING JOINT RING FOR MOUNTING ON AXIS |
FR1052296 | 2010-03-29 | ||
PCT/FR2011/050530 WO2011121205A1 (en) | 2010-03-29 | 2011-03-16 | Self-lubricating bushing for a joint, which is intended to be mounted on a shaft |
Publications (2)
Publication Number | Publication Date |
---|---|
US20130064483A1 true US20130064483A1 (en) | 2013-03-14 |
US8770844B2 US8770844B2 (en) | 2014-07-08 |
Family
ID=42269765
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/581,530 Active US8770844B2 (en) | 2010-03-29 | 2011-03-16 | Self-lubricating bushing for a joint, which is intended to be mounted on a shaft |
Country Status (16)
Country | Link |
---|---|
US (1) | US8770844B2 (en) |
EP (1) | EP2553286B1 (en) |
JP (1) | JP5871902B2 (en) |
KR (1) | KR101805222B1 (en) |
CN (1) | CN102893042B (en) |
AU (1) | AU2011234332B2 (en) |
BR (1) | BR112012023834B1 (en) |
CA (1) | CA2794198C (en) |
ES (1) | ES2615207T3 (en) |
FR (1) | FR2957995B1 (en) |
HU (1) | HUE031500T2 (en) |
MX (1) | MX2012010206A (en) |
PL (1) | PL2553286T3 (en) |
RU (1) | RU2560219C2 (en) |
TW (1) | TWI537487B (en) |
WO (1) | WO2011121205A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160312896A1 (en) * | 2013-12-13 | 2016-10-27 | O.S.C. Offshore Systems Concepts | Seal with elastic lips |
DE102015117754A1 (en) * | 2015-10-19 | 2017-04-20 | Federal-Mogul Deva Gmbh | Plain bearing bush with integrated sealing lip |
US9765808B2 (en) | 2016-01-22 | 2017-09-19 | Caterpillar Inc. | Self-lubricating oscillating pin joint |
EP3837101A4 (en) * | 2018-08-14 | 2022-05-11 | Cerniglia, Anthony | Angle pin bushing and injection mold slide having same |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104533626A (en) * | 2014-11-26 | 2015-04-22 | 成都博世德能源科技股份有限公司 | Rotating-vane type coarse filtering apparatus |
KR20220108657A (en) | 2021-01-27 | 2022-08-03 | 이원석 | Multi-layer structure for manufacturing self-lubricating bushing |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3330605A (en) * | 1963-10-23 | 1967-07-11 | Kupfer Asbest Co | Seal with bearing and guiding sections |
US3366425A (en) * | 1963-10-04 | 1968-01-30 | Garlock Inc | Bearing with integral wiper or scraper |
US5480937A (en) * | 1989-05-12 | 1996-01-02 | Mitsui Petrochemical Industries, Ltd. | Thermoplastic resin composition and use thereof |
US5880043A (en) * | 1991-04-03 | 1999-03-09 | Hoechst Aktiengesellschaft | Fiber-reinforced material and production and use thereof |
US20020012482A1 (en) * | 1996-03-12 | 2002-01-31 | Pridgeon David Kenneth | Bearings |
US20040066993A1 (en) * | 2001-01-24 | 2004-04-08 | Celine Mahieux | Hydrodynamic axial slide bearing for a generator |
Family Cites Families (13)
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US3527507A (en) * | 1968-02-12 | 1970-09-08 | Garlock Inc | Unitary bearing element with improved,integral scraper-sealing lip |
EP0050949A1 (en) * | 1980-10-29 | 1982-05-05 | JAMES WALKER & COMPANY LIMITED | Combined seal, bearing and wiper/scraper ring |
CA2089460A1 (en) * | 1992-04-02 | 1993-10-03 | Michael D. Dierks | Self-locking metal cap and plastic bearing |
GB9213008D0 (en) * | 1992-06-19 | 1992-08-05 | Surgicarft Ltd | Knee surgery |
JP3770714B2 (en) * | 1996-10-31 | 2006-04-26 | Ntn株式会社 | Fiber reinforced resin composition |
JP2968225B2 (en) * | 1997-02-12 | 1999-10-25 | ヤマウチ株式会社 | Pinch roller and pinch roller device |
JP2003239976A (en) * | 2001-12-12 | 2003-08-27 | Ntn Corp | High precision sliding bearing |
JP2005076723A (en) * | 2003-08-29 | 2005-03-24 | Ntn Corp | Railway axle-box bearing |
JP2007519875A (en) | 2004-01-29 | 2007-07-19 | グラシア ガーロック ベアリングス インコーポレイテッド | Bearing with integral seal |
CN1301298C (en) * | 2005-07-22 | 2007-02-21 | 南京工业大学 | self-lubricating bearing material and preparation method thereof |
JP4811342B2 (en) * | 2007-05-02 | 2011-11-09 | オイレス工業株式会社 | Synthetic plastic plain bearing |
ATE463692T1 (en) * | 2007-05-09 | 2010-04-15 | Freudenberg Carl Kg | SEAL RING |
JP2009257366A (en) * | 2008-04-14 | 2009-11-05 | Starlite Co Ltd | Slide bearing with seal, and its manufacturing method |
-
2010
- 2010-03-29 FR FR1052296A patent/FR2957995B1/en not_active Expired - Fee Related
-
2011
- 2011-03-16 RU RU2012145795/11A patent/RU2560219C2/en active
- 2011-03-16 EP EP11714067.3A patent/EP2553286B1/en active Active
- 2011-03-16 CN CN201180017641.2A patent/CN102893042B/en active Active
- 2011-03-16 HU HUE11714067A patent/HUE031500T2/en unknown
- 2011-03-16 CA CA2794198A patent/CA2794198C/en active Active
- 2011-03-16 US US13/581,530 patent/US8770844B2/en active Active
- 2011-03-16 WO PCT/FR2011/050530 patent/WO2011121205A1/en active Application Filing
- 2011-03-16 BR BR112012023834-5A patent/BR112012023834B1/en active IP Right Grant
- 2011-03-16 KR KR1020127027937A patent/KR101805222B1/en active IP Right Grant
- 2011-03-16 JP JP2013501891A patent/JP5871902B2/en active Active
- 2011-03-16 ES ES11714067.3T patent/ES2615207T3/en active Active
- 2011-03-16 PL PL11714067T patent/PL2553286T3/en unknown
- 2011-03-16 AU AU2011234332A patent/AU2011234332B2/en active Active
- 2011-03-16 MX MX2012010206A patent/MX2012010206A/en active IP Right Grant
- 2011-03-23 TW TW100109898A patent/TWI537487B/en active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3366425A (en) * | 1963-10-04 | 1968-01-30 | Garlock Inc | Bearing with integral wiper or scraper |
US3330605A (en) * | 1963-10-23 | 1967-07-11 | Kupfer Asbest Co | Seal with bearing and guiding sections |
US5480937A (en) * | 1989-05-12 | 1996-01-02 | Mitsui Petrochemical Industries, Ltd. | Thermoplastic resin composition and use thereof |
US5880043A (en) * | 1991-04-03 | 1999-03-09 | Hoechst Aktiengesellschaft | Fiber-reinforced material and production and use thereof |
US20020012482A1 (en) * | 1996-03-12 | 2002-01-31 | Pridgeon David Kenneth | Bearings |
US20040066993A1 (en) * | 2001-01-24 | 2004-04-08 | Celine Mahieux | Hydrodynamic axial slide bearing for a generator |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160312896A1 (en) * | 2013-12-13 | 2016-10-27 | O.S.C. Offshore Systems Concepts | Seal with elastic lips |
DE102015117754A1 (en) * | 2015-10-19 | 2017-04-20 | Federal-Mogul Deva Gmbh | Plain bearing bush with integrated sealing lip |
US9765808B2 (en) | 2016-01-22 | 2017-09-19 | Caterpillar Inc. | Self-lubricating oscillating pin joint |
EP3837101A4 (en) * | 2018-08-14 | 2022-05-11 | Cerniglia, Anthony | Angle pin bushing and injection mold slide having same |
US12049034B2 (en) | 2018-08-14 | 2024-07-30 | Anthony Cerniglia | Angle pin bushing and injection mold slide having same |
Also Published As
Publication number | Publication date |
---|---|
CA2794198A1 (en) | 2011-10-06 |
MX2012010206A (en) | 2013-01-29 |
JP5871902B2 (en) | 2016-03-01 |
EP2553286B1 (en) | 2016-11-30 |
HUE031500T2 (en) | 2017-07-28 |
CN102893042B (en) | 2015-04-08 |
AU2011234332A1 (en) | 2012-11-08 |
WO2011121205A1 (en) | 2011-10-06 |
ES2615207T3 (en) | 2017-06-05 |
FR2957995A1 (en) | 2011-09-30 |
FR2957995B1 (en) | 2012-06-29 |
CN102893042A (en) | 2013-01-23 |
KR101805222B1 (en) | 2017-12-05 |
TWI537487B (en) | 2016-06-11 |
TW201207259A (en) | 2012-02-16 |
RU2012145795A (en) | 2014-05-10 |
US8770844B2 (en) | 2014-07-08 |
PL2553286T3 (en) | 2017-05-31 |
CA2794198C (en) | 2017-09-12 |
BR112012023834A2 (en) | 2016-08-02 |
RU2560219C2 (en) | 2015-08-20 |
AU2011234332B2 (en) | 2016-03-03 |
BR112012023834B1 (en) | 2020-11-10 |
EP2553286A1 (en) | 2013-02-06 |
KR20130041791A (en) | 2013-04-25 |
JP2013524113A (en) | 2013-06-17 |
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