US20120255872A1 - Electrokinetic Process And Apparatus For Consolidation Of Oil Sands Tailings - Google Patents

Electrokinetic Process And Apparatus For Consolidation Of Oil Sands Tailings Download PDF

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US20120255872A1
US20120255872A1 US13/440,386 US201213440386A US2012255872A1 US 20120255872 A1 US20120255872 A1 US 20120255872A1 US 201213440386 A US201213440386 A US 201213440386A US 2012255872 A1 US2012255872 A1 US 2012255872A1
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Prior art keywords
tailings
water
electrodes
electrode
solids
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Gregory J. Smith
Bruce S. Beattie
Robert C. Parrott
James Micak
Paul Garcia
Doug Kimzey
Thomas M. Kroll, JR.
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ELECTRO-KINETIC SOLUTIONS Inc
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Priority claimed from CA2736675A external-priority patent/CA2736675C/fr
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Assigned to DPRA CANADA INCORPORATED reassignment DPRA CANADA INCORPORATED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MICAK, JAMES, SMITH, GREGORY A., BEATTIE, BRUCE S., GARCIA, PAUL, KIMZEY, DOUG, KROLL, THOMAS M., JR., PARROTT, ROBERT C.
Publication of US20120255872A1 publication Critical patent/US20120255872A1/en
Assigned to ELECTRO-KINETIC SOLUTIONS INC. reassignment ELECTRO-KINETIC SOLUTIONS INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DPRA CANADA INCORPORATED
Priority to US14/694,302 priority Critical patent/US9896356B2/en
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/15—Treatment of sludge; Devices therefor by de-watering, drying or thickening by treatment with electric, magnetic or electromagnetic fields; by treatment with ultrasonic waves
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/006—Electrochemical treatment, e.g. electro-oxidation or electro-osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/125—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using screw filters
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4612—Controlling or monitoring
    • C02F2201/46125—Electrical variables
    • C02F2201/46135—Voltage

Definitions

  • This invention relates generally to the broad field of pollution control. More particularly, this invention relates to methods and apparatus that can be used to mitigate the persistent nature of certain types of tailings ponds, such as tailings ponds filled with waste products from tar or oil sand recovery processes. Such mitigation allows land reclamation to occur.
  • Oil or tar sands are a source of bitumen, which can be reformed into a synthetic crude or syncrude.
  • a large amount of hydrocarbon is recovered through surface mining.
  • This sand based material includes sands, clays, silts, minerals and other materials.
  • the most common separation first step used on surface mined tar sands is the hot water separation process which uses hot water to separate out the hydrocarbons.
  • the separation is not perfect and a water based waste liquid is produced as a by-product which may include small amounts of hydrocarbon, heavy metals, and other waste materials.
  • FFT Fresh Fine Tailings
  • MFT Mature Fine Tailings
  • Oil extraction has been carried out for many years on the vast reserves of oil that exists in Alberta, Canada. It is estimated that 750,000,000 m 3 of MFT have been produced. Some estimates show that 550 km 2 of land has been disturbed by surface mining yet less than 1% of this area has been certified as reclaimed.
  • MFT/FFT can typically comprise 50 to 70% water. This high water content forms, in combination with the naturally occurring clays, a thixotropic liquid. This liquid is quite stable and persistent and has been historically collected in large holding ponds. Very little has been done to treat the MFT that has been created and so it continues to build up in ever larger holding ponds. As development of the tar sands accelerates and more and more production is brought on line, more and more MFT/FFT will be produced. What is desired is a way to deal with the MFT/FFT that has been and will be generated to permit land reclamation, release of captured water and provide access to the productive ore located beneath such ponds.
  • MFT/FFT represents a mixture of clays (illite, and mainly kaolinite), water and residual bitumen resulting from the processing of oil sands.
  • MFT may also be undergoing intrinsic biodegradation.
  • the biodegradation process creates a frothy mixture, further compounding the difficulty in consolidating this material. It is estimated that between 40 and 200 years are required for these clays to sufficiently consolidate to allow for reclamation of tailings ponds. Such delays will result in unacceptably large volumes of MFT, and protracted periods of time before reclamation certification can take place unless a way to effect disposal and reclamation is found.
  • the oil sands producers are required by a directive of the Energy Resources Conversation Board to treat their tailings to a bearing capacity of 5 kPa by 2012 and 10 kPa by 2015.
  • Electrophoresis has been used in many industries, such as the pharmaceutical industry and ceramics industry to produce high grade separations. Electrostriction has been used to create high density ceramics.
  • electrical resistance heating treatment at Fargo, N.D. (Smith et al., 2006) a , electrostrictive phenomenon has been observed in the application of an electric field to already consolidated clays where the applied electric field ranged between 0.46 to 0.8 volt/cm. Examples of applications of electrical fields in various circumstances can be found in the following prior patents. a Smith, G. J., J. von Hallen, and C. Thomas (2006) Monitoring Soil Consolidation during Electrical Resistivity Heating. Proceedings of the Fifth International Conference on Remediation of Chlorinated and Recalcitrant Compounds May 22-25, 2006, Monterey, Calif.,
  • the consolidation of solids present in MFT/FFT may occur in multiple phases that can be initiated contemporaneously or sequentially under the application of an electrical field. These phases can be controlled by varying the applied voltage gradient to achieve a desired end point. For example, if water release and natural consolidation is desired, then one can apply a voltage gradient that promotes electro-osmotic flow of low pH water from the anode to neutralize the water sorption capability of the clay solids in the MFT/FFT. Or if one desires material that meets a desired bearing capacity, the electro-osmotic flow described above would occur with or be followed by an increase in the voltage gradient which facilitates the application of an electrostrictive force as the electrical resistance increases.
  • the phases may occur in distinctly separate steps, for example, at different locations. Some phases may be replaced by other steps or processes, or omitted entirely, depending on the particular needs for each application.
  • phase include the initial water release under the influence of an electric field in a flocculation step with an accompanying release of water, followed or contemporaneously occurring with the secondary release of pore water during the electro-osmotic flow of low pH water produced at the anode which when electro-osmotically transported through the MFT/FFT neutralizes the diffuse double layer.
  • This results in the release of ions from the pores which are transported to the anode and cathode via electrophoresis, electromigration and electro-osmosis.
  • the electrical resistance of the wet tailings increases, which allows the application of higher voltage gradients at lower current draw, or improved energy efficiency to achieve compaction through electrostriction.
  • the electrokinetic remediation process involves two distinct and separate steps involving the water release/ion release/flocculation, followed by compaction through electrostriction as the electrical resistance increases.
  • the draining of water from the tailings also increases the electrical resistance and provides a means of controlling the process.
  • the present invention provides for a reduction of the moisture content of the solids such that it is no longer a thixotropic liquid, preferably by the application of an electrical field to induce flocculation, releasing pore water and pore water pressure and then to compress the MFT/FFT to express further pore water from the solids to increase the density further increasing the lithostatic loading.
  • a mechanism is provided for relief of pore pressure to accelerate the consolidation of the solids for say, the consolidation of thick deposits.
  • the present invention provides the placing of equipment in-situ in tailings ponds or ex-situ, for example, in designed treatment cells, to allow induction of an electrical field (AC, DC, or EM-induced) having a voltage gradient that can be varied resulting in electrokinetic floccing of the MFT/FFT, electro-osmotic flow of low pH water, electrophoretic flow of ions, and an electrostrictive force causing the flocculated or weakly consolidated solids to further consolidate.
  • An electrostrictive force can be varied by either the duration of application and/or the magnitude of the voltage gradient to achieve a desired bearing capacity of the MFT/FFT.
  • An appropriate magnetic force can also be applied to accomplish the same goals and is comprehended by the present invention although the electrical field is most preferred.
  • the electrical field and the low pH water neutralizes the electrostatic charges on the clay platelets, releasing water from the MFT/FFT pores during an initial flocculation step. Over time the flocculated solids will settle into a weakly consolidated mass.
  • the electrical field also creates electro-osmotic flow to the cathodes, where water can then be pumped away to a location where it can be optionally treated and recycled. Under the application of an electric field, electrophoresis results in the migration of ions to the anode and cathode, thus increasing the electrical resistance of the tailings. The water removal and increase in electrical resistance can also assist further consolidation along with the electrostriction.
  • the electrostrictive force can be applied in varying degrees to achieve the desired bearing capacity in desired zones of the MFT/FFT deposits or, to simply achieve a consolidation level sufficient to permit effective use of sand drains, wicks and the like to complete the consolidation process.
  • the latter option allows for consolidation in active tailings ponds that are not seeking certified reclamation, but where for instance, greater storage capacity is desired.
  • the tailings may be left to consolidate in tailings ponds or other settling locations to allow for natural compaction of the tailings over time.
  • the electrical field applied during the electro-kinetic treatment can be varied at different depths.
  • the electrical field applied during the electro-kinetic treatment can be varied at different depths.
  • the electrical field to the deepest depths of the MFT/FFT deposits causes the clay particles to flocculate there first.
  • the conductive zone of the electrodes which creates the electric field can be raised to higher elevations to encourage weak consolidation at a different depth.
  • the operator may wish to induce flocculation in the deeper deposits of MFT/FFT, and then electrostrictively treat a shallow zone in an amount sufficient to achieve a 5 kPa or greater bearing capacity. This area could then be re-covered with overburden to enhance the consolidation of the non-electrostriction treated depths through the use of sand drains or wicks or the like, while re-vegetation can occur on the replaced overburden.
  • the flocculation step and the subsequent consolidation step both involve the release of water from the thixotropic liquid. If this free water is removed from the tailings pond for further processing and clean-up, that frees up space in the pond for additional MFT to be added.
  • the present invention provides for a way to increase the capacity of the tailings pond to accept more MFT/FFT, by the separation and removal of water content from the MFT/FFT.
  • controlled compaction of MFT/FFT occurs at a location having semi-permanent treatment cells capable of receiving MFT/FFT.
  • Treatment of the MFT/FFT may occur in a series of batch treatments, for example, on a continuous year-round basis.
  • FIG. 1 a is a graph depicting an estimation of pressure at depth for a sample tailings pond
  • FIG. 1 b is a graph depicting an estimate of lithostatic pressures resulting from an electrostriction treatment according to the present invention at various depths;
  • FIG. 2 is a depiction of a graph showing a change in pressure with electrical field variance according to the present invention
  • FIG. 3 is a layout of electrodes in a three spot treatment pattern according to the present invention.
  • FIG. 4 is a schematic of a further electrode layout with a neutral pumping well according to a further aspect of the present invention.
  • FIG. 5 is a tubular electrode connection according to the present invention.
  • FIGS. 5 a and 5 b are enlarged views of a portion of FIG. 5 .
  • FIG. 6 is an enlarged view of an alternate connection
  • FIG. 7 is a schematic of a drain of the type that can be used in the present invention.
  • FIG. 8 is a schematic of a first embodiment of a combined cathode well structure
  • FIG. 9 is a schematic of a second embodiment of a combined cathode well structure
  • FIG. 10 is a schematic of a variable depth electrode according to a further aspect of the present invention.
  • FIG. 11 is a perspective view of an embodiment of a conveyor having rotating electrode screws
  • FIG. 12 is a partial perspective view of the conveyor in FIG. 11 having a removable insulated panel
  • FIG. 13 is a top view of the conveyor in FIG. 11 ;
  • FIG. 14 is a perspective top view of the conveyor in FIG. 11 ;
  • FIG. 15 is a flow diagram of a method of treating liquid tailings using electro-kinetics.
  • FIG. 16 shows the distribution of bearing capacities and moisture content for MFT after flocculation and electrostriction.
  • MFT MFT/FFT or FFT shall mean the tailings that exist in tailings ponds that arise from the extraction of hydrocarbons, such as bitumen, from tar or oil sands, or fly ash tailings ponds.
  • hydrocarbons such as bitumen
  • tar or oil sands tar or oil sands
  • fly ash tailings ponds the exact composition of MFT/FFT will vary, depending upon the composition of the ore being mined due to local variations in such ore.
  • the term is intended to include compositions of material that include water, clays, silts, and residual hydrocarbons and hydrocarbon by-products among other things.
  • electro-kinetic phenomena including electro-osmosis, the movement of water from an anode to a cathode; electrophoresis, the movement of ions in the water to oppositely charged electrodes, and electrostriction, a result of the application of an electrical field that results in mechanical work which deforms the dielectric material.
  • the present invention comprehends the application of an electromagnetic field and most preferably an electrical field to the MFT.
  • an electric field to neutralize the diffuse double layer that is formed between the clay particles and the water, further neutralization as a result of the electrolytic breakdown of water under the application of an electric field, whereby acidic conditions are produced at the anode and basic conditions are created at the cathode, whereby the acidic water migrates from the anode under electro-osmotic flow to reduce the pH in the wet tailings to the point of zero charge of the tailings minerals, releasing water and ions from the tailings minerals, and electrophoretic transport of the released ions from the tailings mineral surfaces.
  • the second aspect occurs where a second electric field is applied such that an electric field can be used to exert a force on the solids present in the MFT/FFT due to electrostriction.
  • the second electric field to induce electrostriction may be created by the same source as the first electric field mentioned above, or may be created by a separate source.
  • Electrostriction b occurs where dielectric materials are subjected to an electric field. When an electric field is applied to a dielectric material such as clay particles, the opposite sides of the domains become differently charged and attract each other, reducing material thickness in the direction of the applied field, and simultaneously increasing thickness in orthogonal directions due to Poisson's ratio c .
  • the resulting strain (ratio of deformation to the original dimension) is proportional to the square of the polarization (i.e., the voltage gradient). Reversal of the electric field (e.g., under the application of alternating current) does not reverse the direction of the deformation. Therefore, the same phenomenon is observed under a magnetic field, DC or AC currents, and under electro-magnetically-induced current flow, again, either alternating or direct all of which are comprehended by the present invention.
  • b A phenomenon first reported by Reuss in 1807 to the Moscow Academy of Science c When a material is compressed in one direction, it usually tends to expand in the other two directions perpendicular to the direction of compression. This phenomenon is called the “Poisson effect”. Poisson's ratio v is a measure of the Poisson effect.
  • the electric force density under an applied electrical field to induce electrostriction is governed by the square of the electrical gradient. From Brevik (1982) d , to determine the electric force density f el , one can make use of the Helmholtz variational principle under reversible, isothermal conditions. From this, f el is defined as: d Brevik, I. (1982). Fluids in electric and magnetic fields: Pressure variation and stability. Canadian J. Physics, 60, pp 449-455.
  • ⁇ refers to the vector in the direction of the application of the field
  • ⁇ mass density (kg ⁇ m ⁇ 3 );
  • E electric gradient (volt ⁇ m ⁇ 1 ); and the system is operating at constant temperature.
  • the second term in this equation is the electrostriction term.
  • the application of a preferred electrical field results in flocculation of the clay particles by said electric field, with pH neutralization of the sorbtive capability of the clay as a result of the electro-osmotic flow of low pH water from the anode. This releases water that was otherwise bound to the clay particles to form the persistent gel or thixotropic MFT/FFT liquid.
  • the present invention provides for further water release and consolidation of the clay solids as explained in more detail below.
  • the further consolidation of the solids occurs through electrostriction.
  • the change in permittivity relative to the change in mass density under a defined electric gradient (E, volt/m) is determined. Therefore, the present invention provides that it is possible to correlate changes in the permittivity and as a result density under an applied electrical field to track the progress of the electrostriction treatment of the MFT/FFT.
  • ⁇ the change in density under the applied electrical field (kg ⁇ m ⁇ 3 )
  • ⁇ the density of clay (kg ⁇ m ⁇ ⁇ 3 )
  • ⁇ 0 dielectric constant (permittivity; unit-less) for clay
  • E electric field (volts ⁇ m ⁇ 1 )
  • the electrostriction coefficient used was 0.902 (Melloni, 1998).
  • One known dielectric constant for kaolinite is 5.3 ⁇ 0.6 (Ishida, et al., 2000 f ).
  • the permittivity of water is 80.37 g . Therefore, for MFT/FFT which comprises 50% to 70% water content, the estimated permittivity for MFT/FFT is expected to range between 43.1 and 58.7.
  • MFT/FFT are reported to typically have between 50% and 70% water (by weight) but this is an estimated range only and the present invention can be applied to materials having either higher or lower water contents without departing from the scope of the invention.
  • Bearing capacities are dependent on compaction effort, which is governed by the applied force and the duration of the application of the desired force. Either parameter can be varied to achieve the desired bearing capacity. This is expected to vary as to the mineralogy of the MFT/FFT and the pore water chemistry varies as a result of variations in the ore from one location to the next.
  • ⁇ p 1 ⁇ 2 E 2 ⁇ (( ⁇ 0 ) 2 /6 ⁇ 0 )
  • the applied electric field is estimated to range from 1 volt/cm to 4 volt/cm (within the linear range of the equations describing electrostriction). From the above equation, this translates into an electrostriction pressure of between 1.23 and 19.7 kPa, which can be varied by the applied gradient or time of treatment to achieve the desired compaction effort for the desired bearing capacity.
  • FIG. 1 a depicts in schematic form the pressure-depth relationship in a notional tailings pond filled with MFT or FFT.
  • the x axis is pressure and the y axis is depth.
  • FIG. 1 b is a schematic of the pressure distribution with depth after an electro-kinetic treatment according to the present invention, where there is a 30% reduction in MFT volume as a result of the electro-kinetic treatment of the present invention.
  • the MFT is now denser and there has been a gravity-separation of the water from the flocked particles within the MFT.
  • the line 16 is the hydrostatic pressure and the lines 18 and 20 represent the pressures at depth for reduced water content solids, such as solids having 15% water content in line 18 and 18% water content in line 20 . These water contents are expressed as a percentage of the total weight.
  • the present invention provides a step-wise advance in consolidating the solids within the MFT, with these steps providing options as the treatment progresses.
  • the invention involves a process and apparatus to create and apply an electrical (or magnetic) field with a voltage gradient that can be varied and is maintained over a treatment period, and then providing for release of pore water to increase the density of the material ( FIGS. 1 a, and 1 b ) while the material consolidates.
  • the method of treating liquid tailings is applied in situ at a tailings pond in which there are two main steps.
  • the first part is to place the necessary equipment in position to deliver the desired electrical field to the MFT. This is explained in more detail below.
  • the second aspect is to identify what happens to the MFT once the electrical field is applied in a treatment process according to the present invention.
  • the first result of the application of the electrical field according to the present treatment process is that the MFT will begin to flocculate and water is released through this flocculation process as a result of the electrical field and through electro-osmotic flow of low pH water.
  • the operator has the option to continue with electrostriction (described below) or allow the MFT to consolidate assisted by such techniques as sand drain, wick drains, etc. This may be useful to the operator where the tailings pond is in operation and he wishes to increase capacity to accept additional tailings.
  • This feature of drain-assisted consolidation further enhances and takes advantage of natural consolidation started by the application of an electrical field.
  • FIG. 2 shows a schematic relationship between a change in the applied electrical field and the pressure.
  • the change in pressure is plotted along the y axis and the change in electrical field is plotted on the x axis.
  • the greater the electrical field the greater the pressure.
  • the voltage gradients and number and spacing of electrodes need to be evaluated on a case-by-case basis to determine the most economical design compared against the timeframe for treatment.
  • One apparatus used to effect the action of the present invention on MFT/FFT is described below.
  • One embodiment of this invention involves the use of a variable voltage power supply connected to a network of electrodes.
  • the power source is an AC source
  • the electrodes are arranged in a triangular ( FIG. 3 ) or hexagonal pattern ( FIG. 4 ).
  • FIG. 3 there are three electrodes denoted with the numbers 1 , 2 , or 3 . These electrodes would be charged out of phase with one another, with the phase charge varying with time.
  • the spacing between electrodes and the desire voltage gradient is determined through the conductivity of the pore water in the thixotropic liquid, the desired degree of consolidation and time to achieve, the volume and geometry of the treatment volume, and the capability of the power supply.
  • FIG. 4 shows an embodiment of an apparatus for applying an electrical field to induce a voltage gradient across the area to be treated, or subsections of the area to be treated.
  • a source of AC power 40 is shown and connected by electrical conductors 42 , 44 , 46 , 48 , 50 and 52 to each electrode in turn.
  • each of the electrodes E 1 through E 6 will be charged at 60 degrees out of phase with the adjacent electrode, with the phased charging varying with time. This results in a maximum electrical field being generated across the long diagonals of the hexagon (e.g.
  • Electrodes E 2 to E 5 are also 180 degrees out of phase, as are electrodes E 3 to E 6 , and so on).
  • the electrical field will be preferably initiated at less than 200 V/m, increasing as the water and ions are released resulting in increased electrical resistance, allowing for greater voltage gradients to be applied more efficiently, across the longest diagonals to efficiently apply electrostriction.
  • This phased charging is also charged sequentially with time to ensure even application of the electrical field, thus the hexagonal pattern noted provides for a useful pattern for applying the desired electrical field across a substantial area for an AC power source 40 .
  • the AC power source 40 will be provided with a power controller to permit the voltages being applied to be varied. Most preferably it provides a six phase for the hexagonal geometry and a three phase time distributed and interphase synchronization power control for the three phase geometry. While the present description is with respect to an AC power source, the present invention comprehends the use of a direct current, or electro-magnetically induced current using a variable voltage transformer as well.
  • the voltages applied are to be determined based on the most economic use of electrodes (number and spacing) the capabilities of the power supply, but the hexagonal pattern is believed to provide good results (for illustration of an AC application where the volume of MFT to be treated has simple geometry approximating a cylinder); and, the timing of the water release from the MFT/FFT and the subsequent increase in electrical resistance.
  • the desired voltage supplied by the transformer is dependent on the spacing of the electrodes, and the conductivity of the interstitial water in the MFT/FFT, which will vary during the treatment as electrophoresis and electro-migration causes the movement of ions in the pore water.
  • the present invention provides that the voltage applied may be adjusted throughout the treatment period to respond to changes in the electrical field resulting from changes in the electrical properties of the MFT/FFT as the treatment progresses.
  • the present invention contemplates that the transformer will be kept in a safe locked housing and operatively connected to a portable computer with remote access communication features, such as for example through a cellular network communications grid. This combination permits remote monitoring and access to operate the system.
  • the electrical field generating equipment will include the capability of monitoring the electrical conductivity of the pore water and voltage drops, both overall and throughout the treatment area. Overall, the electrical conductivity will be monitored through variations in current draw at the transformers. Throughout the treatment area, periodic conductivity measurements through such means as small diameter slotted CPVC tubing embedded in the MFT/FFT will permit the operator to track and optimize the application of the electrical field.
  • a neutral electrode 54 located at the center of the hexagonal spacing of the electrodes.
  • this electrode can also function as a water recovery device.
  • a pump 56 is used to draw the water out of the hexagon, through a conduit 58 .
  • This water is the water that is freed from the MFT/FFT by the flocculation step, the electro-osmotic flow of low pH water, and the electrostrictive compaction of the MFT/FFT and reduction in pore volume outlined above.
  • the reclaimed water can then be optionally treated and recycled as desired using conventional processes.
  • FIG. 5 shows an electrode 58 according to one aspect of the present invention.
  • the electrode includes an electrical connection wire 60 which connects to an electrode head connection 62 .
  • the electrode itself is in the form of hollow tube or pipe 64 .
  • a non-electrically conductive sleeve 66 to protect against accidental electrical shocks to people or the like.
  • the sleeve 66 can be of any reasonable length but is preferred to provide enough freeboard above the level of the tailings pond or treatment cell that the electrodes do not become totally submerged in the pond/cell.
  • FIGS. 5 a and 5 b there is shown the details of the electrical head connection which can take the form of a welded flange 70 with a bolt hole 72 for electrical connection.
  • the flange 70 is welded to the side of the pipe 64 and the pipe 64 has closed capped top.
  • the welded bolt connection 74 is placed centrally on a cap 76 which covers the open top of the pipe 64 .
  • the present invention comprehends that it is usually desirable to remove supernatant water and or water being electro-osmotically drawn towards the cathode. In some cases it may be desirable to leave the water in place, above the flocculated solids, as a means to provide access to the treatment area by floating barge or the like. In most cases the removal of water to increase the electrical resistance of the MFT/FFT facilitates increasing the voltage gradient to increase the electrostrictive force as desired. As an option the present invention contemplates the use of a wick or drain to help remove additional pore water from consolidating solids within the pond. An example of such a drain 88 is depicted in FIG. 7 , in which the hollow skeleton 90 supports a water permeable mesh 92 . Essentially this drain provides a leak path for pore water to be expressed through the consolidation process.
  • the present invention provides as shown in FIG. 8 a dual purpose electrode and well.
  • the cathode tubing 100 includes an upper section 102 and a lower section 104 .
  • the lower section is made water permeable, such as by being formed from a wire wound screen.
  • a submersible pump 106 is located within the lower section 104 to pump the water collecting at the cathode out of the tubing 100 through a riser pipe 108 .
  • the tubing 100 is provided with a centralizer 110 to keep the pump located within the middle of the tubing 100 and would electrically isolate the pump from the wall of the tubing 100 .
  • FIG. 8 a there is shown a top view of the cathode of FIG. 8 in which the top 112 is shown with the riser pipe 108 , which is protected by an insulator 114 .
  • FIG. 9 shows an alternate embodiment in which the wire screen has been replaced with a perforated pipe section 116 .
  • the present invention also comprehends being able to selectively treat sections of the tailings pond/treatment cell as local requirements demand.
  • the tailings ponds tend to be vast in area and to facilitate the treatment
  • the present invention contemplates creating smaller treatment areas by means of sheet piling or the like, or by providing hydraulic control by manipulating the electro-osmotic flow to create pressure barriers around the treatment area. This can be used to divide the area of the pond up into smaller areas or cells to facilitate treatment.
  • the sheet pile may also be used as an electrode in some cases.
  • the use of the sheet pile wall is used to hydraulically and hydrologically isolate the treatment cell from the rest of the pond to also allow the supernatant water to be removed to the extent desirable prior to or during treatment within the treatment cell.
  • FIG. 10 shows a cable electrode 200 which includes an electric cable 202 connected to a source of power and at the free end is an electrode 204 .
  • the electrode 204 can be an electrically conductive plate, bar, tube, or other electrically conductive element and can be made of any desired length depending upon the depth of the zone which is to be treated.
  • Most preferable the cable electrode is inserted within a hollow tube 206 to which water can be added to maintain good electrical contact with the electrode 204 , which is further maintained as the pore water is released during treatment.
  • the electrode 204 can be positioned at any depth within the tailings pond to permit the flocculation, water release and/or electrostriction to occur at such depth.
  • a 100,000 bbl/day production facility produces 50,000 tonnes per day of FFT, which is equivalent to approximately 33,500 m 3 of FFT per day.
  • the water release/ion release/flocculation step operates at a lower voltage gradient than the compaction step.
  • One means of accomplishing this difference voltage gradient in a quasi-continuous operating mode is envisaged in FIGS. 11-14 .
  • a central canal (not shown) will feed wet tailings to a series of conveyors 300 , 302 .
  • the conveyors 300 , 302 are composed of two counter-rotating intermeshed electrode screws or augers, with one representing an anode and the other a cathode.
  • the conveyors 300 , 302 lie within a conduit 304 .
  • the conduit 304 is a canal.
  • serviceable dewatering screens 306 separate the main conduit 304 from a pair of troughs 326 , 328 .
  • Service doors 308 are connected to the pair of troughs 326 , 328 .
  • the conveyors 300 , 302 are powered by electric motors 310 .
  • Removable insulated panels 314 may be used to cover the conduit 304 .
  • an intake 312 lies on the upstream end of the canal 300 and a discharge 316 lies on the downstream end of the canal.
  • incoming tailings arrive through the intake 312 into the upstream end 318 of the conduit 304 .
  • flocculation begins to occur, as generally shown at 320 .
  • water is removed for treatment at the downstream end 322 of the canal.
  • the troughs 326 and 328 may lie on the downstream end 322 of the conduit 304 adjacent to the discharge.
  • the troughs 326 , 328 function as a water extraction outlet.
  • Denser tailings 324 are discharged through the discharge 316 to the next treatment step.
  • the electrodes 300 , 302 have a water-filled core, with screens to allow the low pH water generated at the anode to migrate to the cathode.
  • a water extraction outlet may be connected directly to the hollow core of the cathode of the conveyors 300 , 302 to allow for water removal. Any outlet allowing for the removal of water from the tailings reservoir may be used as a water extraction outlet.
  • the spacing between the screw blades dictates the residence time needed to achieve the deflocculation.
  • the conveyors 300 , 302 may be powered by any suitable means for causing rotation of the screws.
  • movement of the tailings through the conduit 304 may be caused by other means, such as a conveyor belt or a rotary pump, so long as the means cause the tailings to pass through the tailings reservoir from the intake opening to the discharge opening.
  • the conduit 304 may be a pipeline to transport tailings.
  • Separate cathodes may be placed into the canal instead of the counter-rotating screws.
  • the cathodes may be distinct from the means for causing the tailings to pass through the tailings reservoir and may only function as cathodes and, or may, as in the example in FIGS. 11-14 , function as both a cathode and a conveyor. In other embodiments, more than two cathodes may be used to induce flocculation of the tailings.
  • tailings may be treated using flocculation and compaction.
  • a method 400 of treating liquid tailings using electro-kinetics At 402 , at least two electrodes are caused to come into contact with the tailings. The electrodes may be placed into a tailings pond or ex-situ treatment cell or FFT/MFT may be moved into contact with the electrodes.
  • flocculation of particles and releasing of water from the tailings is induced in the tailings by establishing an electrical field between the two electrodes.
  • the two electrodes are connected to a source of electrical power having a variable voltage to create at least one cathode and at least one anode.
  • Compaction and further water release may be induced through the application of a second variable voltage; a reapplication of the variable voltage from the flocculation step, for example, at a higher variable voltage; or through a non-electrokinetic process such as natural consolidation or forced compaction, such as through the application of wicks or sand drains.
  • the compaction and further water release step may be carried out at a separate location using separate electrodes to induce the second variable voltage. The separate location may be in situ in a tailings pond or ex-situ at additional treatment cells.
  • MFT may be pumped into intermediate cells in which flocculation of the material may be applied prior to electrostriction of the material.
  • Flocculation and water removal may be applied during transportation of MFT or FFT from location to location, for example using a processing cell such as described in FIGS. 11-14 .
  • the transportation of FFT may be challenging and steps would need to be taken to ensure that material does not settle out and damage any equipment used to transport the FFT.
  • the flocculation step may be followed by compaction and further water removal in which the compaction step does not include the application of electrostriction.
  • the properties of fly ash tailings may prevent the effective use of electrostriction to compact the tailings.
  • Other techniques for compacting tailings such as those discussed throughout this specification may be used.
  • the electrokinetic test cells used for the experiments in this study include a reactor which consists of an electrokinetic cell, two electrode compartments, two electrode reservoirs, a power supply, a multi-meter, flow control valves, and gas vents.
  • the reactor was designed to simulate one-dimensional transport of contaminants under an induced electric potential and was also used to determine the compaction achieved under higher voltage gradients (up to 4.3 V DC/cm ) and the volume of water that can be recovered.
  • a Plexiglas tube measuring approximately 3.8 cm in diameter and 14.2 cm long was filled with MFT.
  • filter paper discs were placed between the MFT and the porous stones capping each end.
  • Each end was then sealed with an integrated end cap equipped with an electrode providing even distribution of voltage from one end of the tube to the other.
  • MFT material was placed into the cell with no headspace.
  • the voltage gradient can be varied up to 4.3 V DC/cm , which is at the mid-range of the linear range of the equations for describing electrostriction. Water drainage was provided at the cathode end of the apparatus.
  • the 2-D test cells measure 20 cm high by 20 cm wide, by 5 cm deep. On either side of the test cells are located the anode and cathode in water-filled reservoirs. In the 2-D cell, approximately 0.5 cm of sand was place for drainage during the treatment. Across the top of the sand layer and over the plastic screens separating the electrode reservoirs from the sample, a geotextile material was placed and a silicone sealant applied where the fabric met the walls of the test cell to maintain separation of the materials. The MFT was filled to a level of approximately 18 cm from the base of the cell. The remainder of the cell was filled with tap water to a height of approximately 18 cm from the base of the cell to mimic conditions in a tailings pond and ensure current flow throughout the MFT.
  • the MFT was placed in the cell, placed in layers to minimize void spaces while filling.
  • the MFT was measured at approximately 18 cm thick, with the electrode reservoirs filled with tap water to approximately the same level as the MFT.
  • the voltage gradient could be applied up to 2.36 V DC/cm (236 V DC/m ) with the available equipment and for the most part, the maximum voltage gradient was used.
  • Vane shear testing (ASTM 2573-08) as a screening tool to evaluate whether the MFT had achieved the desired strength
  • a 1-D test set-up was used to determine if there may be an optimal voltage gradient for electrostrictive treatment. Three tests were planned, but after conducting the second test, it was apparent that the ideal voltage gradient may be outside the range allowed by the equipment. Two voltage tests were conducted: 1) 2.92 V DC/cm and 2) 3.2 V DC/cm . An additional test at approximately 2.5 V DC/cm was planned, but cancelled when the trend in Table 1 was observed.
  • the test cell had plainly evident shrinkage cracks that result from the electro-kinetic compaction (EKC) treatment, as well as the mineral precipitate that forms on the surface.
  • EKC electro-kinetic compaction
  • Compaction effort is a term used to denote a specific compaction operation.
  • a specific compaction operation may specify the number of passes that a sheepsfoot roller moves over a section of fill.
  • the compaction effort is defined as the applied compaction pressure multiplied by duration.
  • Electrostrictive force is proportional to the square of the voltage gradient as noted above. Therefore, according to the present invention, it is desirable to maximize the voltage gradient and to apply the highest compactive force practical, to increase the bearing capacity while also reducing the moisture content. Unlike conventional compaction, the present invention does not seek to compact at the optimum moisture content. At a voltage gradient of 2.34 V/cm, the change in pressure is 4.69 kPa.
  • the change in pressure is 19.7 kPa or almost 3 times higher than at a gradient of 2.34 V DC/cm . Further, when the higher voltage gradient is applied at the latter stages of treatment, the power consumption is less. If compaction effort is defined as applied force times duration (kPa-hrs) the present invention provides a means of maximizing the compaction effort, while minimizing the time to achieve the desired bearing capacity. This operation can be performed in a manner where a higher compaction effort occurs at conditions of lower current draw (and hence lower power consumption).
  • the overall power consumption is reduced by operating at a lower voltage gradient initially and then increasing the voltage gradient as the electrical resistance increases.
  • the experimented results indicate that 2.34 VDC/cm provides more than adequate compaction, so a reduced compaction effort to 1,082 kPa-hrs would result in a further reduction in energy consumption of 19.9%.
  • the savings in energy arise by operating at higher voltage gradients (higher electrostrictive pressure) and higher electrical resistances.
  • a continuous feedback loop on the applied current can be used to provide real-time control on the power input. In this way power consumption can be optimized in real time as the MFT is being treated using compaction effort as a guide.
  • Electro-osmotic velocities were calculated at 1.5 V DC/cm and 2.34 V DC/cm to determine whether a lower voltage gradient would impact on treatment time and costs. It was determined that the electro-osmotic flow velocity at 2.34 V DC/cm was 19% faster (or a 6 hour difference in pH wave travel time) than at a voltage gradient of 1.5 V DC/cm . Therefore, a slower travel time in the electro-osmotic water release portion of the treatment is expected.
  • the 2-D test cell has septum ports spaced 5 cm apart that allow for the insertion of metal probes to measure voltage drops within the MFT as it is being treated. These voltage drops can be used to determine permittivity and the electrostrictive pressure. With this, real-time pressure measurements can be determined. This is important in the application of EKC, since electrostrictive (ES) forces can be both positive and negative, and monitoring requires that the forces result in compaction of the MFT. When the pressure becomes negative, the polarity can be reversed to increase the pressure.
  • ES electrostrictive
  • EKC Only a limited amount of EKC occurs during the first 24 hrs, yet the most significant power consumption occurs; greater compaction occurs during the period from 48 to approximately 96 hrs. Reversing the polarity also results in increasing the compaction pressure. As a result, the present invention comprehends that EKC be operated in a mode focusing on electro-osmosis to release water for approximately the first 24 hours, increasing the voltage gradient thereafter.
  • Unconfined compression testing was performed by obtaining samples from the 1 and 2-D test cells.
  • the sample was pushed from the apparatus and trimmed to form a right angle cylinder.
  • samples were prepared using two methods: 1) a tube was inserted into the MFT in the test cell apparatus, which allowed for some testing in different orientations; and, 2) the EKC treated MFT was removed from the test cell and re-molded into right-angle cylinders for testing.
  • the application of the electrostrictive force is from anode to cathode.
  • the unconfined compression test shows greater bearing capacity in the horizontal direction versus the vertical. This was seen in the failure planes in the unconfined compression testing.
  • An observed main diagonal failure plane represented the failure occurring that is being measured as the bearing capacity.
  • Observed subvertical failure planes were the result of the electrostrictive compactive force being applied horizontally across the sample.
  • Vane shear testing as noted above was used as both a screening tool to add to the database on bearing capacities. Vane shear testing as a screening tool, involved opening up the test cell during treatment and obtaining the data. At the completion of treatment, the vane shear measurements were made both in the test cell and as with the unconfined compression tests, then remolded material in a bowl.
  • Naphthenic acids are natural constituents of petroleum, formed through the oxidation of naphthenes, representing as much as 4% of raw petroleum by weight, and represents an important component of the waste generated during petroleum processing.
  • naphthenic acids become dissolved and concentrated in tailings water as a result of the hot-water process used to extract bitumen from mined oil sands.
  • pKa ⁇ 5 solubilization of naphthenic acids
  • the actual amounts of naphthenic acids in the tailings ponds are typically between 80 and 110 mg/l.
  • the present invention contemplates monitoring leaching of naphthenic acid in the vicinity of the cathode and evaluating if compounds form, such as sodium naphthenic. Adequate treatment of any such compounds is desirable.
  • the charge balance error shows that there are more anions than cations. This is to be expected given that water is recovered from the cathode reservoir where the water and anions are drawn to the cathode reservoir as a result of the attractive forces. Given the faint chlorine odour, it is expected that chloride is electrolyzed to chlorine gas. It is also believed that the water chemistry is also out of balance because of the fate of sodium chloride. As noted above, sodium is expected to be consumed in the reaction of naphthalenic acid to sodium naphthenate:
  • the present invention also provides that multi-stage application of electro-kinetics processes, such as the application of separate flocculation and electrostriction steps may be employed to achieve the same benefits. Due to the volume of material being treated, a few pennies savings per cubic meter can result in significant overall cost savings or improved operating margins.
  • MFT/FFT are subjected to the application a flocculation step prior to the application of an electrostriction step through the application of a single electric field.
  • the applied voltage gradient is increased over time.
  • the application of the electric field is applied in a preferred voltage gradient range between 100 V/m and 200 V/m.
  • the voltage gradients increased slowly over time.
  • the voltage gradient might begin at 100 V/m and will increase as flocculation occurs until it eventually reaches 400 V/m at the conclusion of the electrostriction step.
  • the voltage gradient will preferably be increased until it reaches a value around 400 V/m. To achieve even results, it is preferable that increases to the voltage gradient are done slowly.
  • Electrostriction will generally occur at voltage gradients above 200 V/m. An initial voltage gradient of 50 V/m or lower is possible, but lower voltage gradients would mean that the process as a whole would take longer. Increasing the voltage above 400 V/m during the electrostriction step is also possible, but a voltage gradient higher than 400 V/m may result in inefficiencies because the end product would achieve a level of compactification higher than that is required by current Alberta regulations.
  • the distance between the electrodes will have an impact on the time it takes for flocculation and electrostriction to occur. The farther the distance between the electrodes the longer the process will take.
  • the exact voltage gradient to be applied at any time can be determined by a feedback loop which is dependent on observations of the properties of the materials being flocculated and compacted. Generally, the voltage gradient will increase over time, but those increases may not be linear.

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