US20120204903A1

US20120204903A1 - Loop reactor for emulsion polymerization

Info

Publication number: US20120204903A1
Application number: US13/154,781
Authority: US
Inventors: David Charles Adams
Original assignee: Celanese International Corp
Current assignee: Celanese International Corp
Priority date: 2006-01-13
Filing date: 2011-06-07
Publication date: 2012-08-16
Also published as: US7956137B2; US20100252073A1; ATE468913T1; AP2008004540A0; DE602007006754D1; CN101370578B; WO2007080161A1; MY146009A; EP1973647A1; AP2641A; ES2346362T3; CN101370578A; EP1973647B8; EP1973647B1

Abstract

A polymerization reactor comprising one or more circulation loops with one or more inlets for raw material, one or more outlets, and a circulation pump for circulating a reactor charge within the circulation loop. A by-pass line for by-passing the circulation pump connects a point of the loop upstream of the pump with a point downstream of the pump.

Description

RELATED APPLICATIONS

This patent application is a continuation of application Ser. No. 12/160,716, filed on Jul. 11, 2008, which is a National Stage Entry of PCT/EP07/50159, filed on Jan. 9, 2007 and claims foreign priority to EP 06100328.1, filed on Jan. 13, 2006, the contents of each are hereby incorporated by reference in their entirety.

FIELD

The present invention relates to a polymerization reactor comprising one or more circulation loops with one or more inlets for raw material, one or more outlets, and a circulation pump for circulating a reactor charge within the circulation loop.

BACKGROUND

WO 00/07177 discloses a loop reactor for emulsion polymerization. The loop reactor comprises a circulation pump and a tubular circulation loop connecting the pump's outlet to its inlet. Water, monomers, and stabilizers are continuously fed to the loop and circulated and polymer emulsion is continuously drawn off. The reactor is particularly suitable for the production of polymers derived from vinyl and/or acrylic monomers, used for instance in paints or adhesives.
A problem encountered in polymerization processes employing a tubular reactor is the formation of deposits from the reaction products on the internal wall of the reactor. These deposits lead to a need for an increased delivery pressure from the circulation pump and impair heat transfer from the reaction medium to, e.g., a coolant in a jacket surrounding the reactor tube, thus leading to higher and often deleterious reactor temperatures or else necessitating an increased coolant circulation rate, a lower coolant temperature, or a reduced rate of production. Fouling also reduces the reactor volume, increasing both the recycle rate and the shear on the emulsion. This shifts the process conditions, which may have been optimized on a clean reactor. In any case, product properties will drift, nullifying the advantages of consistency of production expected from continuous reactors.
In WO 00/07177 cleaning pigs are used for cleaning the inside of the reactor tubes. The cleaning pigs have a diameter which is about the inner diameter of the reactor tube. The pigs are launched from a pig station and propelled through the loop by the polymerizing emulsion. Since a pig cannot be permitted to pass through the circulation pump, a by-pass line is provided to by-pass the pigs around this pump.
To clean the parts which cannot be pigged, such as the circulation pump, the reactor is rinsed with cleaning solvent on a regular base. To this end the complete reactor has to be emptied first. Although the solvent cleaning only serves to clean the unpigged section of the loop, the complete loop is filled with cleaning solvent. After cleaning, the solvent is removed and the complete reactor needs to be recharged. This procedure leads to substantial loss of productive time and to high economical and environmental costs.
It would be advantageous to provide a loop reactor which can be cleaned more efficiently using less cleaning solvent.

SUMMARY

The object of the invention is achieved by providing a polymerization reactor according to the opening paragraph having a by-pass line by-passing the circulation pump, which connects a point of the loop upstream with a point of the loop downstream, both points being provided with a three-way valve, to form a short loop comprising the pump, a cleaning solvent inlet and a cleaning solvent discharge. This creates the possibility to short-circuit the pump section, closing off the main coil. Cleaning solvent can be pumped around in the isolated pump section to clean the pump. Due to the fact that now only the short circuited pump section is solvent cleaned, instead of the complete loop, the amount of cleaning solvent used can be reduced dramatically by more than 90%. Moreover, the main coil does not need to be emptied anymore.
To aid solubilization of the polymer residues in the section to be cleaned, the section and/or the by-pass line can be provided with jackets connected to a heating medium source, such as heated water, to heat the solvent.
The solvent can for example be re-circulated for about 15 to 45 minutes before it is pumped out of the equipment. Optionally the circuit is refilled for a second wash or alternatively a small bleed of solvent is continuously pumped into the circuit during the cleaning cycle, such that used solvent overflows to a bin or the like.
Some typical monomers suitable for use in the present polymerization process include, e.g., butyl acrylate, methyl methacrylate, styrene, vinyl acetate, Veova® 9, Veova® 10, (each ex Shell), ethyl acrylate, 2-ethyl hexyl acrylate, ethylene, and vinyl chloride. The addition reaction is initiated by radicals to give a dispersion of high molecular weight polymer particles, usually of 50 to 3,000 rim diameter, suspended in a medium in which the polymer is insoluble, usually water. Common free radical generators include the sodium, potassium, and ammonium salts of peroxodisulphuric acid, e.g., ammonium peroxodisulphate. Alternatively, redox couples can be used. These consist of an oxidizing agent and a reducing agent. Commonly used oxidizers are the salts of peroxodisulphuric acid and t-butyl hydroperoxide and hydrogen peroxide itself.
Reducers are sodium sulphite, sodium metabisulphite, sodium formaldehyde sulphoxylate, and sodium dithionate.
Polymerization of monomers can take place in aqueous suspension and, in that case, raw materials are preferably provided by separate feed streams. These streams introduce fresh monomer and an aqueous solution of stabilizers known as the water phase or, e.g., a pre-emulsion of monomer and water and an aqueous solution in a separate small stream. At the start of the reaction the reactor is filled with water phase made up in a solution tank. Other fillings are also possible, particularly finished emulsion polymer (of the same or a different composition) from a previous run, optionally diluted to any concentration.
Agitation in the reactor is provided by virtue of the in-line circulation pump. Shortly after the feed streams start to flow, the monomers begin to react and heat is generated. The temperature is stabilized by cooling means, usually by controlled circulation of a cooling fluid (e.g. water) through a cooling jacket. The product flows to the cooling tank, where residual monomer converts to polymer.
After cooling, the emulsion polymer is filtered to remove any oversize particles or gritty material in the strainer and transferred to the product storage tank.
Optionally, the polymerization process may be carried out under pressure, for instance under a pressure of 10 to 150 bar. Alternatively, the polymerization may be carried out at ambient pressure.
Suitable circulation pumps are for instance positive displacement pumps or centrifugal pumps.

BRIEF DESCRIPTION OF THE DRAWINGS

The forms disclosed herein are illustrated by way of example, and not by way of limitation, in the figure of the accompanying drawing and in which:

FIG. 1 shows the pump section of a loop reactor 1.

DETAILED DESCRIPTION

Various aspects will now be described with reference to specific forms selected for purposes of illustration. It will be appreciated that the spirit and scope of the apparatus, system and methods disclosed herein are not limited to the selected forms. Moreover, it is to be noted that the figure provided herein is not drawn to any particular proportion or scale, and that many variations can be made to the illustrated form. Reference is now made to FIG. 1, wherein like numerals are used to designate like elements throughout.
FIG. 1 shows the pump section of a loop reactor 1, having two outer ends 2, 3 connected to the outer ends 4, 5 of a tubular coiled loop (not shown). The pump section 1 comprises a monomer inlet 6, a water phase inlet 7, and an outlet 8 for finished product. A circulation pump 9 serves as a driving means for circulating a reactor charge within the circulation loop. A by-pass line 10 for by-passing the circulation pump 9 connects a point 11 of the loop upstream of the pump 9 with a point 12 downstream of the pump 9. Both points 11, 12 are provided with a three-way valve 13, 14. A second by-pass line 15 includes a pig station 16 to store one or more pigs at rest. The pig station 16 can be isolated using valves. Downstream of the valve 19, the by-pass line 15 makes a U-turn, the return line being hidden in the side view of the drawing. The second by-pass line 15 returns to the main line just upstream of the valve 14. Downstream of the U-turn is the outlet 8. A vent line 20 connects the pig station 16 to the outlet line 8. The vent line 20 serves to bring the pig to the rest position in the pig station 16 after returning from the coil. The outlet line 8 is provided with a valve 21 just upstream of the junction with the vent line 20. The vent line 20 is provided with valve 22.
To clean the circulation pump 9, the valves 13, 14 are used to close off the main coil and to open the by-pass line 10. Polymer emulsion contained within the isolated section encompassed by the actuation of the valves 13 and 14 is drained off via a valve 23 and a drain-off line 24 situated underneath the pipe running between the circulation pump 9 and the three-way valve 13.
Valves 18 and 22 are opened and valve 21 is closed. Alternatively, valve 21 is left open and valves 18 and 22 remain closed. Either of these two valve options provides an exit route for the solvent. The solvent may move up the vent line 20 to the outlet line 8 or more simply pass vertically up the line 8 through the valve 21. Above the valve 21 there is a pipe coupling 25 and immediately after this coupling 25 there is a three-way valve (not shown) which is used to transfer the solvent to a small bore line and which leads to a waste solvent bin. High temperature boiling solvent is pumped into the cleaning circuit from a solvent supply line 26 via the circulation pump 9. Air trapped inside the circuit is bled via a small valve 27 on the by-pass line 10 near the valve 14. The circulation pump 9 is then set running to provide a solvent circulation. The circulation aids the solubilization of any polymer deposits. Jackets 28 on the pipes are heated with hot water, which results in an elevated solvent temperature and this too aids solubilization. After a period of time of typically 15 to 45 minutes the solution is pumped out of the equipment via the valve 23. Optionally the circuit is refilled for a second wash or alternatively a small bleed of solvent is continuously pumped into the circuit during the cleaning cycle, such that it overflows to a bin or the like. When all the solution has been drained off, the circuit is filled with water phase, the valves 13, 14, 18 and 22 and/or 21 are returned to their original positions, after which production can be restarted.
While the present invention has been described and illustrated by reference to particular forms, those of ordinary skill in the art will appreciate that the invention lends itself to variations not necessarily illustrated herein. For this reason, then, reference should be made solely to the appended claims for purposes of determining the true scope of the present invention.

Claims

1. A system for cleaning a tubular loop reactor and circulation pump, the tubular reactor having at least one circulation loop, the circulation loop having a first end in fluid communication with an inlet side of the circulation pump and a second end in fluid communication with an outlet side of the circulation pump, the system comprising:

(a) a pigging system comprising at least one pig for cleaning the inside of the tubular reactor, the pigging system configured to allow the at least one pig to by-pass the circulation pump;

(b) a first by-pass line by-passing the circulation pump, said first by-pass line connecting a first point of the tubular loop reactor upstream with a second point of the tubular loop reactor downstream, said first by-pass line configured to form a short loop comprising the pump and a cleaning solvent inlet and a cleaning solvent discharge,

wherein the circulation pump is cleaned by introducing a cleaning solvent into the cleaning solvent inlet and circulating the cleaning solvent around said short loop.

2. The system of claim 1, wherein said pigging system further comprises a second by-pass line having a pig station for storing the at least one pig.

3. The system of claim 2, wherein said at least one pig has a diameter that is about the inner diameter of the tubular loop reactor.

4. The system of claim 3, wherein the tubular loop reactor forms a polymer emulsion which is used to propel said at least one pig through the tubular loop reactor.

5. The system of claim 4, wherein said second by-pass line by-passes the at least one pig around the circulation pump.

6. The system of claim 5, wherein at least a portion of the short loop and/or the by-pass line is provided with jackets connected to a heating medium source.

7. The system of claim 1, wherein at least a portion of the short loop and/or the by-pass line is provided with jackets connected to a heating medium source.

8. The system of claim 7, wherein the heating medium source is heated water.

9. The system of claim 8, wherein said first point of the tubular loop reactor and said second point of the tubular loop reactor are provided with valves to isolate said short loop from the remainder of the tubular loop reactor.

10. The system of claim 1, wherein said first point of the tubular loop reactor and said second point of the tubular loop reactor are provided with valves to isolate said short loop from the remainder of the tubular loop reactor.

11. A tubular loop reactor comprising:

(a) at least one circulation loop, the circulation loop having a first end in fluid communication with an inlet side of a circulation pump and a second end in fluid communication with an outlet side of the circulation pump;

(b) a pigging system comprising at least one pig for cleaning the inside of the tubular reactor, the pigging system configured to allow the at least one pig to by-pass the circulation pump;

(c) a first by-pass line by-passing the circulation pump, said first by-pass line connecting a first point of the tubular loop reactor upstream with a second point of the tubular loop reactor downstream, said first by-pass line configured to form a short loop comprising the pump and a cleaning solvent inlet and a cleaning solvent discharge,

12. The tubular loop reactor of claim 11, wherein said pigging system further comprises a second by-pass line having a pig station for storing the at least one pig.

13. The tubular loop reactor of claim 12, wherein said at least one pig has a diameter that is about the inner diameter of the tubular loop reactor.

14. The tubular loop reactor of claim 13, wherein the tubular loop reactor forms a polymer emulsion which is used to propel said at least one pig through the tubular loop reactor.

15. The tubular loop reactor of claim 14, wherein said second by-pass line by-passes the at least one pig around the circulation pump.

16. The tubular loop reactor of claim 15, wherein at least a portion of the short loop and/or the by-pass line is provided with jackets connected to a heating medium source.

17. The tubular loop reactor of claim 11, wherein at least a portion of the short loop and/or the by-pass line is provided with jackets connected to a heating medium source.

18. The tubular loop reactor of claim 17, wherein the heating medium source is heated water.

19. The tubular loop reactor of claim 18, wherein said first point of the tubular loop reactor and said second point of the tubular loop reactor are provided with valves to isolate said short loop from the remainder of the tubular loop reactor.

20. The tubular loop reactor of claim 11, wherein said first point of the tubular loop reactor and said second point of the tubular loop reactor are provided with valves to isolate said short loop from the remainder of the tubular loop reactor.

21. A method for cleaning a tubular loop reactor and circulation pump, the tubular loop reactor having at least one circulation loop, the circulation loop having a first end in fluid communication with an inlet side of the circulation pump and a second end in fluid communication with an outlet side of the circulation pump, the method comprising:

(a) using a pigging system having at least one pig to clean a first portion of the tubular loop reactor, the first portion of the tubular loop reactor bypassing the circulation pump so that the at least one pig does not pass through the circulation pump; and

(b) solvent cleaning a second portion of the tubular loop reactor, the second portion forming a short loop including the circulation pump, a first by-pass line connecting a first point of the tubular loop reactor upstream with a second point of the tubular loop reactor downstream, a cleaning solvent inlet and a cleaning solvent discharge,

wherein the second portion of the tubular loop reactor is cleaned by introducing a cleaning solvent into the cleaning solvent inlet and circulating the cleaning solvent around the short loop.

22. The method of claim 21, wherein said pigging system further includes a second by-pass line having a pig station for storing the at least one pig.

23. The method of claim 22, wherein said at least one pig has a diameter that is about the inner diameter of the tubular loop reactor.

24. The method of claim 23, wherein the tubular loop reactor forms a polymer emulsion for propelling the at least one pig through the tubular loop reactor.

25. The method of claim 24, wherein the second by-pass line by-passes the at least one pig around the circulation pump.

26. The method of claim 25, further comprising heating at least a portion of the short loop and/or the by-pass line using jackets connected to a heating medium source.

27. The method of claim 26, further comprising heating at least a portion of the short loop and/or the by-pass line using jackets connected to a heating medium source.

28. The method of claim 27, wherein the heating medium source is heated water.

29. The method of claim 28, wherein the first point of the tubular loop reactor and the second point of the tubular loop reactor are provided with valves to isolate the short loop from the remainder of the tubular loop reactor.

30. The method of claim 21, wherein the first point of the tubular loop reactor and the second point of the tubular loop reactor are provided with valves to isolate the short loop from the remainder of the tubular loop reactor.