US20110017195A1 - Glass melting furnace - Google Patents

Glass melting furnace Download PDF

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Publication number
US20110017195A1
US20110017195A1 US12/934,412 US93441209A US2011017195A1 US 20110017195 A1 US20110017195 A1 US 20110017195A1 US 93441209 A US93441209 A US 93441209A US 2011017195 A1 US2011017195 A1 US 2011017195A1
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furnace
burners
flue gas
melting
furnace according
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US12/934,412
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English (en)
Inventor
Olivier Douxchamps
Johan Behen
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AGC Glass Europe SA
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AGC Glass Europe SA
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Assigned to AGC GLASS EUROPE reassignment AGC GLASS EUROPE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DOUXCHAMPS, OLIVIER, BEHEN, JOHAN
Publication of US20110017195A1 publication Critical patent/US20110017195A1/en
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/235—Heating the glass
    • C03B5/2353—Heating the glass by combustion with pure oxygen or oxygen-enriched air, e.g. using oxy-fuel burners or oxygen lances
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/04—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in tank furnaces
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping

Definitions

  • the present invention relates to glass melting furnaces in which the melting energy is produced essentially by burners fed with fuel and with oxygen or a gas very rich in oxygen. These furnaces are usually termed “oxy-fuel combustion” furnaces.
  • oxy-fuel combustion burners are well known in glass melting furnaces. On furnaces operating conventionally with air, an oxy-fuel combustion burner or a limited number thereof are then added.
  • the purpose of introducing these additional burners is generally to increase the capacity of existing furnaces, possibly when their performance is seen to decline owing to their old age. This situation is found for example when the regenerators associated with such furnaces have become degraded and are no longer able to heat the air used for combustion sufficiently.
  • the capacity of a given furnace may also simply be increased by introducing additional energy sources.
  • the additional oxy-fuel combustion burners are placed close to the zone in which the batch materials are charged into the furnace. These burners thus melt the batch materials.
  • the addition of a few oxy-fuel burners in large-capacity furnaces is usually accomplished without any substantial modification to the general operation of the furnace in the sense that, in particular, the regenerators continue to operate and therefore handle both the combustion flue gas arising from burners operating with air and that arising from burners operating with oxygen.
  • Oxy-fuel combustion provides an energy saving at least for the reason that the energy of combustion gas is not partly absorbed by the nitrogen of the air.
  • the flue gas finally discharged still gives off a significant amount of energy. The presence of nitrogen contributes to this loss.
  • the invention relates to ways of implementing the oxy-fuel combustion technique in large glass furnaces that form the subject matter of the claims appended to the present description.
  • the inventors addressed the problem of the economics of this oxy-fuel combustion technique. In particular, they provide a way of ensuring that the furnace flue gas energy is largely recovered and used for preheating the oxygen and, where appropriate, the fuels consumed. Some of the flue gas heat may also be used for preheating the batch materials charged into the furnace.
  • the inventors have chosen to utilize the flue gas energy, especially to preheat the oxygen. For obvious reasons, the use of regenerators for this recovery is excluded.
  • the operation has to be carried out in specific heat exchangers, which operation is not very easy because hot oxygen is extremely corrosive for all materials with which it is in contact. This corrosive character is all the more pronounced the higher the temperature reached by the oxygen.
  • the furnaces in question are substantially free of a nitrogen-containing atmosphere. For this reason, unlike certain solutions proposed previously, it is preferable to ensure that all the burners of the furnace operate in oxy-fuel combustion mode. Although nevertheless it is possible to maintain part of the combustion in air-fuel combustion mode, the energy generated by oxy-fuel combustion represents at least 65%, preferably at least 80% and even more preferably at least 90% of the total energy consumed in the furnace.
  • an air-fuel combustion fraction may stem from a limited number of burners operating entirely in air-fuel combustion mode, but it may also stem from the use of oxygen having a certain content of air. In the latter case, because the burners used in oxy-fuel combustion mode have particular characteristics, the oxygen/air mixture must have an oxygen content of at least 80% and preferably at least 90%.
  • the intake of the surrounding atmosphere is consequently prevented by arranging the furnace in such a way that dynamic sealing develops.
  • the flow of flue gas in the furnace has to be regulated in the manner explained in detail below.
  • the burners located on either side of the furnace operate continuously.
  • the distribution of the burners on both sides is not determined by the need for this alternation, because it does not exist, but more because of the desire to optimize the heat exchange between the flames and the glass melt or between the flames and the supernatant batch materials.
  • the flames of oxy-fuel burners are, for the same power, shorter than the flames of air-fuel burners.
  • the reason for this is in particular because the gas flow is less voluminous because of the absence of nitrogen.
  • the burners are therefore advantageously staggered.
  • oxy-fuel combustion flames to achieve combustion staging over the length of the flame, which is preferable, as in air-fuel combustion burners, it is advantageous to ensure that the flames from these burners develops as a sheet lying in a plane substantially parallel to the surface of the glass melt. This is obtained for example by means of burners having a plurality of oxygen injection nozzles located on either side of the fuel intake nozzle, all these nozzles being substantially aligned so as to be parallel with the surface of the melt.
  • the flue gas from the flames does not flow transversely, as in air-fuel combustion.
  • the flow is organized according to two objectives.
  • the residence time in the furnace is extended.
  • the provisions relating to flue gas flow also help to improve the heat transfer with the melt.
  • the flue gas or at least the major portion thereof, flow in the opposite direction to the flow of the melt.
  • the temperature of the flue gas as it progresses through the furnace decreases up to the point where it is discharged from the furnace.
  • the discharge of the flue gas, or at least the major portion thereof, is localized close to the point where the batch materials are charged into the furnace.
  • One option is to ensure that the flue gas is discharged via ducts that are separate from those via which the batch materials are fed into the furnace.
  • Another option is for this discharge to take place via the charging channels themselves, and therefore countercurrently with the batch materials. In the latter option, it is necessary in particular to avoid the risk of any agglomeration due to the water vapour contained in the flue gas condensing upon contact with these “cold” batch materials.
  • the flue gas is discharged at a point close to where the batch materials are charged into the furnace. In practice, this means at least 65%, and preferably at least 75%, of the flue gas.
  • the excess flue gas that is not discharged as indicated above, follows a path intended in particular for maintaining dynamic sealing with respect to the external atmosphere. At least part of this excess is advantageously discharged towards the downstream end of the furnace. As indicated, this fraction of the flue gas is as small as possible, advantageously being less than 35%, and preferably less than 25%, of all of the flue gas.
  • the presence of outlets downstream of the burner zone makes it possible in particular to prevent air coming from this zone passing through the burner zone, since most of the air downstream comes from the conditioning zone.
  • the NOx content is systematically detected at the upstream outlet. If the NOx content proves to be too high, it is possible to correct this content according to the invention by regulating the discharge streams. Increasing the downstream discharge entrains more air coming from the downstream of the furnace and prevents this nitrogen-containing air from passing through the flames and forming NOx.
  • these regulations result in as low a nitrogen content as possible in the flue gas discharged into upstream outlets.
  • This content is preferably maintained at below 10% and more preferably below 5%.
  • the temperature of the downstream discharge gas is generally slightly higher than the temperature of the flue gas discharged upstream, for the reason that the flue gas is in contact with the least hot zones of the furnace because, in particular, close to the furnace charging point, there are normally no burners and because the covering of supernatant batch materials absorbs a substantial portion of the energy in melting these batch materials.
  • the flue gas residence time in the furnace depends on a number of conditions. These include, apart from the organization of the flue gas flow as indicated above, the flow rate of the flue gas produced and the volume occupied by this flue gas within the furnace must also be added. For a given flue gas flow rate, the average residence time depends on the available volume. The larger the volume, the longer the residence time and, in principle, the more complete the heat transfer.
  • the discharge temperature of the flue gas is slightly reduced as a result of its residence in the furnace.
  • the flue gas is at a temperature below 1650° C., preferably below 1600° C. and particularly preferably below 1550° C.
  • the flue gas is at a temperature below 1500° C., preferably below 1450° C. and particularly preferably below 1350° C.
  • the volume of the furnace also determines the velocity of the flue gas therein. It is preferable to ensure that the flue gas flow velocity in the furnace remains moderate so as to avoid disturbing the flames. It is also necessary to prevent the fly-off of dust as the gas passes over the batch materials, which dust would then have to be removed before the gas passes through the heat exchangers.
  • the average residence time of the flue gas in an air-fuel combustion furnace is 1-3 seconds.
  • the mean residence time of the flue gas lies between 10 and 40 seconds and more advantageously between 15 and 30 seconds.
  • the positioning of the burners, or better still the distribution of the energy supply already mentioned, is an important factor not only as regards energy consumption of the furnace but also the quality of the glass produced.
  • All large glass furnaces conventionally comprise two zones, corresponding to melting and to refining respectively. Beyond the refining zone, the glass continues to pass through a conditioning channel in which the glass temperature is gradually lowered until it reaches its forming temperature. To manufacture flat glass by the “float” technique, this temperature is around 1100° C.
  • the refining zone is separated from the conditioning zone by a neck, which makes it possible in particular to restrict the atmosphere of one zone passing into the other.
  • efforts are made to minimize the corresponding opening and consequently the flow of the atmosphere coming from the conditioning zone entering the refining zone.
  • the flue gas must not penetrate into the conditioning zone, otherwise dust still in suspension could be entrained therewith and deposited on the surface of the glass.
  • the ingress of gas not arising from the combustion, and in particular the gas penetrating via the neck, is also limited as far as possible and advantageously does not exceed 15%, and preferably is less than 10%, of the total volume of gas flowing through the furnace.
  • melting zone and refining zone involves what is conventionally called “convection currents” in the glass.
  • convection currents are generated by two phenomena: natural convection and forced convection. Firstly, natural convection movements are associated with the temperature conditions and with the power distribution along the furnace (called the “fire curve”). Secondly, the forced convection movements are associated with the modification of the flow caused for example by bubblers, mixers or dams. These two convection phenomena progress the glass, which, in the melting zone, develops forwardly flowing movements on the surface and rearwardly flowing movements close to the bottom of the furnace. In the refining zone, the direction of circulation is reversed.
  • the melting zone is that requiring the greatest energy supply, and therefore that in which the overall power of the burners is greatest.
  • the distribution is such that this supply is not less than 40%, preferably not less than 50%, of the total. It may represent up to 80% of the supply, but preferably does not represent more than 70% of the energy delivered.
  • the percentages in question relate to the power delivered by the burners that are suspended above the zone in question.
  • the burners In order for the furnace to be operated as efficiently as possible, the burners must be suitably distributed along the furnace. However this distribution is not uniform.
  • boost burners may be positioned close to the batch material charging points, either mounted in the walls of the furnace or in the roof.
  • An alternative way of minimizing the energy losses in the flue gas is to use electro-booster (the glass being heated by electrodes passing through the bottom of the furnace). Heating by means of submerged electrodes has the advantage of providing temperature control precisely adjusted to the local requirements.
  • the efficiency of this electrical energy supply is much greater than in flame heating, thereby enabling it to be maintained at relatively low levels. In general when electrical energy is supplied, it represents no more than 10% of the total amount of energy developed in the furnace, and is very often less than 5% thereof.
  • the burners are located at a certain distance away from both the batch charging points and the upstream flue gas outlets.
  • the necessary supply of energy in this zone therefore results firstly from the convection currents within the melt, these being more intense the greater the temperature difference between the surface covered with the batch materials to be melted and that further downstream in the molten glass.
  • This energy supply secondly comes from the flue gas, which flows countercurrently, being directed towards the outlets provided upstream.
  • the temperature in this upstream zone is not the highest in the furnace, but it does remain sufficient to sustain the melting.
  • the first burners are located a certain distance away from the flue gas discharge points, so as not to retard batch melting, it is nevertheless necessary to position these first burners in a zone of the furnace in which the melt is still covered with unmelted batch materials.
  • This zone preferably does not exceed one half of the length of the furnace, and more particularly preferably no more than one third thereof. This is because it is necessary, apart from melting this “blanket”, to ensure that the particles of material dispersed in the melt have melted perfectly and to ensure that the temperature has risen up to the highest point that enables not only the melting process to be completed but also the melt to be homogenized.
  • the distribution of the delivered power is significant.
  • the power of the burners is highest in that part of the melting zone close to the refining zone, in which part the temperature reached is the highest.
  • the temperature of the melt must be generally maintained, the necessary energy supply therefore being more limited.
  • the burners in this zone are located in the part closest to the melting zone.
  • the energy supply decreases in the direction of advance through the refining zone.
  • the burners are placed in the side walls of the furnace in such a way that the flames develop close to the surface of the melt.
  • This arrangement stems partly from the limited residence time in the furnace of the flue gas, which is essentially discharged directly on that side of the furnace facing the burner. It appears to be necessary to maximize heat exchange, including convective heat exchange, during this brief residence time and therefore necessary to ensure that the flames are also in contact with the surface of the melt.
  • the positioning of the burners results in flames being developed in planes approximately parallel to the surface of the melt and at a distance of at least 0.25 m above this surface, and preferably at least 0.40 m above it. This distance may be up to 1.0 m, but is preferably less than 0.80 m.
  • the use of oxy-fuel combustion modifies the furnace atmosphere, which contains practically no nitrogen.
  • it is relatively richer in water vapour. This feature has a significant effect on the melting behaviour.
  • an increase in the water content above the melt is accompanied by an increase thereof in the glass.
  • Another means for minimizing the risk of foam formation in the zones where it may be particularly problematic, especially in the refining zone, consists in limiting the water vapour content by the choice of fuel used in this part of the furnace.
  • Oxy-fuel combustion may be carried out with various types of fuel without losing the benefit of the abovementioned advantages.
  • the fuels most often used are either natural gas or liquid fuels.
  • the economic assessment of oxy-fuel combustion is based, on the one hand, on the cost of oxygen and the cost of the adapted refractories and, on the other hand, on the fuel savings and the savings relating to the partial elimination of flue gas decontamination.
  • To have a positive outcome it is necessary to recover a significant portion of the heat contained in the flue gas exiting the furnace.
  • the most efficient use consists in heating the reactants introduced into the furnace, namely oxygen, fuel and possibly batch materials.
  • regenerators can receive the flue gas practically as collected at the outlet of the furnace.
  • the materials of which the regenerators are made, especially the linings, generally made of refractory ceramics, have no difficulty in withstanding the temperatures of the flue gas and the dust that this gas may convey. Subsequently, the preheating of the air in the hot regenerators requires no special precautions to be taken. In contrast, much more stringent precautions are required when heating products used for oxy-fuel combustion, particularly when heating oxygen.
  • the installations in which oxygen flows must be completely gastight, resistant to the high temperatures and resistant to oxygen conveyed at these temperatures.
  • the average velocity of the flue gas in the longitudinal direction does not as a general rule exceed 3 m/s and is usually less than 2 m/s. In the flames, this velocity is much higher, around 30 to 100 m/s, this velocity being normally lower than that in air-fuel combustion flames.
  • the oxygen is preheated advantageously in heat exchangers made of steel exhibiting excellent hot oxygen resistance.
  • Heat exchangers and materials suitable for this usage are described in the unpublished European Patent application No. 07/107 942 filed on 10 May 2007.
  • the hot oxygen delivered by the heat exchanger is brought to a temperature which may be at most 650° C. This value depends on the resistance that can be achieved with metal alloys having the best characteristics. This limit makes it possible to guarantee a duration of use in relation to the type of installation in question.
  • a temperature that is not below 350° C.
  • the fuel used is advantageously preheated, whether this is natural gas or liquid fuel.
  • the temperatures reached by the fuel do not depend on the resistance of the installations. However, they may depend on possible degradation of these fuels. In particular, it is necessary to prevent them “cracking”, even partially, which would have the result of fouling the installations.
  • the preheat temperature is advantageously below 650° C. and preferably below 550° C.
  • the temperature is generally lower, not exceeding 180° C. and preferably not exceeding 150° C.
  • Flue gas heat recovery is largely sufficient to allow the oxygen and the fuel to be heated to the temperatures indicted, independently of the efficiency of the heat exchange when this is carried out under the conditions given in the abovementioned patent application. It is also possible with the excess to preheat the batch materials or to feed boilers, whatever the usage of the steam produced.
  • FIG. 1 is a perspective schematic view of a furnace according to the invention
  • FIG. 2 illustrates schematically, in top view, the arrangements shown in FIG. 1 ;
  • FIG. 3 is an overall schematic diagram of the heat exchange circuits used for a furnace according to the invention.
  • FIG. 4 is a detail of a schematic diagram relating to flow in an embodiment for preheating the oxygen.
  • FIG. 5 shows a partial top view of the arrangements of the burners in a furnace according to the invention.
  • the furnace shown in FIG. 1 is of the type used for high-volume glass productions, such as those serving for feeding flat glass production units employing the float technique. Furnaces of this type operate continuously and produce glass in quantities that may be up to 1000 tonnes/day. To achieve this performance, furnaces must have a power of up to 60 MW.
  • the furnace 1 comprises a tank placed in an enclosed chamber.
  • the assembly is made of refractory materials that are resistant to high temperatures, to flue gas corrosion and to attack by the molten materials.
  • the level of the melt in the tank is shown by a dotted line 2 .
  • the furnace is fed with batch materials at one of its ends.
  • the opening via which these batch materials are charged is shown at 3 .
  • several charging points are usually provided.
  • the output of molten glass, represented by the arrow V, is at the opposite end via a neck 4 of small width compared to that of the tank. Most usually, the bottom of the neck 4 is level with the bottom of the furnace.
  • the neck is not completely submerged in the molten glass—a gap remains between the top of the neck and the surface of the glass layer.
  • the operating conditions, as regards the gas streams in the furnace, are regulated in such a way that the furnace atmosphere does not pass through the neck, so as to avoid any risk of entraining suspended dust.
  • Burners positioned as indicated at 6 are placed along the side walls of the furnace, on each side thereof, so that the flames extend practically over the entire width of the tank.
  • the burners are spaced apart so as to distribute the energy supply over a major portion of the length of this melting/refining tank.
  • the combustion gas F is discharged predominantly via the outlets 7 located near the furnace charging zone and at a certain distance from the closest burners.
  • two outlets 7 are placed symmetrically on the side walls, whereas the batch materials (MP) are charged along the axis of the furnace.
  • MP batch materials
  • These outlets may also be distributed differently, the important point being to ensure that the flue gas flows back countercurrently with the flow of glass V in the furnace.
  • the discharge of the flue gas may especially take place, at least partly, via the batch charging opening or openings.
  • a large-capacity glass furnace conventionally comprises two zones one called the melting zone and the other the refining zone. These two zones are not delimited in FIGS. 1 and 2 .
  • the boundary between melting and refining is not generally apparent in the structure of the furnace.
  • this dam does not ordinarily coincide with this boundary, even though it does play a part in determining where this boundary is located.
  • melting zone in all cases a functional distinction. It corresponds to the glass circulation in the tank. This comprises a first convection current in the melting part and a second convection current in the refining part that rotates in the opposite direction to the first current.
  • the position of the melting zone/refining zone boundary is determined by a number of operating parameters that include, in particular, the distribution of the energy by the burners. In FIG. 2 , these two zones are shown as I and II.
  • the energy supply needed to melt the batch materials is greater than that to keep the glass at temperature for refining.
  • first burners are positioned in such a way that they are located above the supernatant materials.
  • the first burners may especially operate at lower power than that of the burners positioned further downstream.
  • the “fire curve”, i.e. the temperature distribution along the furnace, firstly progresses from the upstream end as far as a central part close to the start of the refining zone. Thereafter, the temperature varies a little, decreasing slightly as far as the neck 4 preparing the passage into the conditioning zone. For this reason, the downstream end of the furnace normally has no burners.
  • the distribution of the burners is shown in FIG. 2 by the axis thereof. They are preferably staggered on either side of the tank so as to ensure that the flames emanating in opposite directions do not impinge on one another. They are separated from one another laterally so as to best cover the surface of the melt. In this sense too, the burners used are advantageously of the type that develops a flame in the form of a sheet approximately parallel to the surface of the melt. A nominal power of each burner depends on what burners are chosen and on the number of burners used.
  • the space available on the side walls of the furnace 11 is limited by the presence of the metal reinforcement 12 supporting the roof of the furnace.
  • the beams constituting this reinforcement are closer together the wider the furnace and the heavier the refractory ceramic materials.
  • only two flat burners 13 of the type described in the publication WO 2004/094902 may be fitted between two successive beams, one on each side of the furnace.
  • These burners organize the staged combustion, starting from a central fuel feed 14 , concentric with a first oxygen feed 15 , then by means of several secondary oxygen feeds 16 , 17 parallel to the first, these being spaced apart and lying in the same approximately horizontal plane.
  • These staged-combustion burners 13 produce a flame that develops in a plane approximately parallel to the surface of the melt. By their construction, these burners have a certain width, hence the limited number thereof between two beams.
  • the burners open into the enclosure of the furnace at a certain distance above the surface of the melt.
  • This arrangement enables the radiated energy from the flame to be correctly distributed and it also makes it possible, combined with the height of the roof, to ensure correct flow of the combustion gases, especially those directed towards the main outlets 7 returning towards the upstream end of the furnace.
  • the flue gas of which follows an essentially transverse path in the case of oxy-fuel combustion furnaces according to the invention the flue gas is directed along the length of the furnace and therefore transversely to the direction of the flames that the flue gas must not disturb. By providing space both beneath the flames and above them, the flue gas can travel without excessive turbulence prejudicial to correct development of the flames.
  • the flue gas discharged from the furnace is used in devices intended to recover some of the energy carried out by this gas. Although in principle it is possible to carry out direct heat exchange between the flue gas and the product to be preheated, for the sake of operating optimally, in terms of efficiency and safety, more complex heat exchange installations are used.
  • the heat exchange installations are shown overall as 18 and 19 .
  • oxygen and/or fuel is heated before being conveyed to the burners by the lines 20 , 21 .
  • Flue gas on leaving the furnace is initially at temperatures of around 1200 to 1400° C. At such temperatures, it is preferable for the flue gas to pass through a recuperator, in other words a summary heat exchanger that enables the temperature of the flue gas to be lowered with a view to treating it before it is discharged into the atmosphere via a chimney 24 .
  • the recuperator is a system in which a fluid flows countercurrently with the flue gas. In its most elementary form, this comprises two concentric pipes. A more elaborate system is formed by a bundle of tubes passing through a chamber in which the heat-transfer fluid flows. The two types may be combined.
  • the flue gas is still at a high temperature, generally not below 700° C. except in the case of very large recuperators being used.
  • the flue gas undergoes a decontamination treatment so as in particular to remove sulphur oxides. This removal operation is performed for example in electrofilters. To avoid damaging these filters, the temperature must be lowered further, down to about 300-400° C.
  • One economic way of doing this consists in diluting the flue gas with ambient air.
  • the mixture can still be used, for example as a means for feeding steam-generating boilers.
  • the steam in question can be used in particular to preheat liquid fuels. These are advantageously preheated to temperatures of between 100 and 150° C., preferably between 120 and 140° C.
  • the fluid heat exchanger used in the recuperators is for its part used as indicated below with reference to FIG. 4 .
  • Lines 27 and 28 are used, where appropriate, to avoid passing the flue gas through the recuperators, sending them directly to the discharge point 24 .
  • the flue gas F′ exiting downstream is not shown as pipes to the heat exchangers. Depending on the configuration of the installation, it is also possible to connect these outlets in such a way that all the flue gas is recovered. If the “recoverable” energy is more than that which can be utilized, this recovery may where appropriate be omitted.
  • a first “recuperator” the flue gas heats up an intermediate fluid, for example air, nitrogen, CO 2 or any appropriate fluid which for example circulates in a loop between this recuperator and a heat exchanger, or better still several heat exchangers, in which heat exchanger(s) it heats the oxygen or the fuel.
  • an intermediate fluid for example air, nitrogen, CO 2 or any appropriate fluid which for example circulates in a loop between this recuperator and a heat exchanger, or better still several heat exchangers, in which heat exchanger(s) it heats the oxygen or the fuel.
  • An alternative situation as regards the intermediate fluid, such as air is not to use the loop but to recover the hot air at the outlet of the secondary heat exchangers by a boiler or another energy recovery means.
  • FIG. 4 illustrates this principle.
  • the recuperator 25 receives the flue gas F and, countercurrently thereto, the fluid A, for example air.
  • the heated air is sent to a series of heat exchangers 26 in which it flows countercurrently with the oxygen, which is heated before being sent to the burners 13 .
  • each burner 13 is fed by a heat exchanger 26 .
  • the air after preheating the oxygen, is returned to the recuperator 25 or returned to the flue gas duct of the furnace, to be sent into a boiler.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Furnace Details (AREA)
  • Combustion Of Fluid Fuel (AREA)
  • Tunnel Furnaces (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
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PCT/EP2009/053518 WO2009118337A1 (fr) 2008-03-25 2009-03-25 Four de fusion du verre

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100258263A1 (en) * 2007-05-10 2010-10-14 Agc Flat Glass Europe Sa Oxygen heat exchanger
US20110072857A1 (en) * 2008-06-05 2011-03-31 Agc Glass Europe Glass melting furnace
US9260334B2 (en) 2008-03-25 2016-02-16 Agc Glass Europe Glass melting furnace
US20180035360A1 (en) * 2015-02-12 2018-02-01 Nokia Solutions And Networks Oy Access control to services in a network
US20200255315A1 (en) * 2016-06-22 2020-08-13 Jushi Group Co., Ltd. Glass tank furnace and glass melting method

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2948929A1 (fr) * 2009-08-07 2011-02-11 Fives Stein Four de fusion de matieres premieres vitrifiables avec zone de prechauffage optimisee
FR3002025B1 (fr) * 2013-02-12 2015-02-20 Air Liquide Methode de combustion dans un four avec recuperation de chaleur
MX2017008389A (es) * 2014-12-23 2017-11-28 Praxair Technology Inc Quemadores con angulo ascendentes en hornos para vidrio.
BR112018012053B1 (pt) * 2015-12-23 2023-04-04 Praxair Technology, Inc Método para produção de vidro fundido
CN113716839B (zh) * 2021-08-20 2022-05-20 西安交通大学 一种利用高温烟气助熔玻璃的玻璃窑炉及方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4432780A (en) * 1982-08-27 1984-02-21 Owens-Corning Fiberglas Corporation Glass fiber scrap reclamation
US4599100A (en) * 1985-04-01 1986-07-08 Ppg Industries, Inc. Melting glass with port and melter burners for NOx control
US5123942A (en) * 1991-03-21 1992-06-23 Frazier-Simplex, Inc. System for charging batch/cullet in a glass furnace
US5655464A (en) * 1993-11-02 1997-08-12 Saint-Gobain Vitrage Apparatus for melting glass
US5755846A (en) * 1992-06-06 1998-05-26 Beteiligungen Sorg Gmbh & Co. Kg Regenerative glass melting furnace with minimum NOx formation and method of operating it
US5766296A (en) * 1995-08-03 1998-06-16 Saint-Gobain Vitrage Furnace for melting glass and method for using glass produced therein
US6253578B1 (en) * 1996-04-12 2001-07-03 Praxair Technology, Inc. Glass melting process and apparatus with reduced emissions and refractory corrosion
US6532771B1 (en) * 2001-08-21 2003-03-18 Praxair Technology, Inc. Method for controlling glass furnace atmosphere

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4029489A (en) * 1976-02-17 1977-06-14 Owens-Corning Fiberglas Corporation Method of and apparatus for melting of glass
DE3718276A1 (de) * 1987-05-30 1988-12-08 Sorg Gmbh & Co Kg Glasschmelzofen
FR2728254B1 (fr) * 1994-11-08 1997-01-31 Saint Gobain Vitrage Procede et dispositif pour la fusion du verre
FR2736347B1 (fr) * 1995-07-06 1997-10-24 Air Liquide Procede et four a boucle pour la fusion du verre
FR2757845B1 (fr) * 1996-12-31 1999-01-29 Air Liquide Procede pour ameliorer le profil thermique des fours de verre et four de fusion de verre pour sa mise en oeuvre
US6071116A (en) * 1997-04-15 2000-06-06 American Air Liquide, Inc. Heat recovery apparatus and methods of use
US6519973B1 (en) * 2000-03-23 2003-02-18 Air Products And Chemicals, Inc. Glass melting process and furnace therefor with oxy-fuel combustion over melting zone and air-fuel combustion over fining zone
US7143610B2 (en) * 2001-03-23 2006-12-05 Vitro Global, S.A. Method and system for feeding and burning a pulverized fuel in a glass melting furnace, and burner for use in the same
EA020084B1 (ru) * 2008-03-25 2014-08-29 Агк Гласс Юроп Способ ведения плавки в стеклоплавильной печи

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4432780A (en) * 1982-08-27 1984-02-21 Owens-Corning Fiberglas Corporation Glass fiber scrap reclamation
US4599100A (en) * 1985-04-01 1986-07-08 Ppg Industries, Inc. Melting glass with port and melter burners for NOx control
US5123942A (en) * 1991-03-21 1992-06-23 Frazier-Simplex, Inc. System for charging batch/cullet in a glass furnace
US5755846A (en) * 1992-06-06 1998-05-26 Beteiligungen Sorg Gmbh & Co. Kg Regenerative glass melting furnace with minimum NOx formation and method of operating it
US5655464A (en) * 1993-11-02 1997-08-12 Saint-Gobain Vitrage Apparatus for melting glass
US5766296A (en) * 1995-08-03 1998-06-16 Saint-Gobain Vitrage Furnace for melting glass and method for using glass produced therein
US6253578B1 (en) * 1996-04-12 2001-07-03 Praxair Technology, Inc. Glass melting process and apparatus with reduced emissions and refractory corrosion
US6532771B1 (en) * 2001-08-21 2003-03-18 Praxair Technology, Inc. Method for controlling glass furnace atmosphere

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100258263A1 (en) * 2007-05-10 2010-10-14 Agc Flat Glass Europe Sa Oxygen heat exchanger
US9803860B2 (en) 2007-05-10 2017-10-31 Agc Glass Europe Oxygen heat exchanger
US10422529B2 (en) 2007-05-10 2019-09-24 Agc Glass Europe Oxygen heat exchanger
US9260334B2 (en) 2008-03-25 2016-02-16 Agc Glass Europe Glass melting furnace
US20110072857A1 (en) * 2008-06-05 2011-03-31 Agc Glass Europe Glass melting furnace
US8904823B2 (en) 2008-06-05 2014-12-09 Agc Glass Europe Method for operating a glass melting furnace
US20180035360A1 (en) * 2015-02-12 2018-02-01 Nokia Solutions And Networks Oy Access control to services in a network
US20200255315A1 (en) * 2016-06-22 2020-08-13 Jushi Group Co., Ltd. Glass tank furnace and glass melting method

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WO2009118337A1 (fr) 2009-10-01
JP5454810B2 (ja) 2014-03-26
EA018516B1 (ru) 2013-08-30
MX2010010555A (es) 2011-04-05
KR20110015515A (ko) 2011-02-16
JP2011519804A (ja) 2011-07-14
EA201001538A1 (ru) 2011-04-29
US8943856B2 (en) 2015-02-03
BRPI0909081A2 (pt) 2015-08-25
CN101980974B (zh) 2018-04-24
EP2257500A1 (fr) 2010-12-08
CN101980974A (zh) 2011-02-23
KR101600109B1 (ko) 2016-03-04

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