US20100270622A1 - Semiconductor Device Having a Strain Inducing Sidewall Spacer and a Method of Manufacture Therefor - Google Patents
Semiconductor Device Having a Strain Inducing Sidewall Spacer and a Method of Manufacture Therefor Download PDFInfo
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- US20100270622A1 US20100270622A1 US12/831,815 US83181510A US2010270622A1 US 20100270622 A1 US20100270622 A1 US 20100270622A1 US 83181510 A US83181510 A US 83181510A US 2010270622 A1 US2010270622 A1 US 2010270622A1
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- strain inducing
- sidewall spacer
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- 125000006850 spacer group Chemical group 0.000 title claims abstract description 114
- 230000001939 inductive effect Effects 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 45
- 239000004065 semiconductor Substances 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 31
- PHUNDLUSWHZQPF-UHFFFAOYSA-N bis(tert-butylamino)silicon Chemical compound CC(C)(C)N[Si]NC(C)(C)C PHUNDLUSWHZQPF-UHFFFAOYSA-N 0.000 claims description 46
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 24
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 18
- 150000004767 nitrides Chemical class 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
- 238000000137 annealing Methods 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 5
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims description 4
- 238000005530 etching Methods 0.000 claims 2
- 239000002019 doping agent Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000007943 implant Substances 0.000 description 9
- 230000001965 increasing effect Effects 0.000 description 8
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 6
- 229920005591 polysilicon Polymers 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910007264 Si2H6 Inorganic materials 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- PZPGRFITIJYNEJ-UHFFFAOYSA-N disilane Chemical compound [SiH3][SiH3] PZPGRFITIJYNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical group [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
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- 238000002474 experimental method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- PCLURTMBFDTLSK-UHFFFAOYSA-N nickel platinum Chemical compound [Ni].[Pt] PCLURTMBFDTLSK-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4983—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET with a lateral structure, e.g. a Polysilicon gate with a lateral doping variation or with a lateral composition variation or characterised by the sidewalls being composed of conductive, resistive or dielectric material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/6656—Unipolar field-effect transistors with an insulated gate, i.e. MISFET using multiple spacer layers, e.g. multiple sidewall spacers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/7842—Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate
- H01L29/7843—Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate the means being an applied insulating layer
Definitions
- the present invention is directed, in general, to a semiconductor device and, more specifically, to a semiconductor device having a strain inducing sidewall spacer and a method of manufacture therefore.
- a characteristic that limits scalability and device performance is electron and/or hole mobility (e.g., also referred to as channel mobility) throughout the channel region of transistors. As devices continue to shrink in size, the channel region for transistors also continues to shrink in size, which can limit channel mobility.
- electron and/or hole mobility e.g., also referred to as channel mobility
- strain is introduced into the channel region, which can improve electron and/or hole mobility.
- Different types of strain including uniaxial or biaxial tensile strain, compressive strain, etc. have been introduced into channel regions of various types of transistors in order to utilize their effect on electron and/or hole mobility.
- certain types of strain improve mobility whereas other types degrade mobility.
- FIG. 1 illustrates a conventional semiconductor device 100 at a stage of fabrication wherein a tensile strain is introduced by a silicon nitride cap-annealing process.
- the semiconductor device 100 includes a substrate 110 having a well region 120 located therein.
- the semiconductor device 100 further includes a gate structure 130 located over the substrate 110 .
- the gate structure 130 includes both a gate dielectric layer 133 and a gate electrode layer 138 .
- Source/drain sidewall spacers 140 Positioned on both sides of the gate structure 130 are source/drain sidewall spacers 140 . Additionally positioned in the substrate 110 proximate the gate structure 130 are source/drain regions 150 . The source/drain regions 150 therefore define a channel region 160 in the substrate 110 .
- a strain-inducing layer 170 is deposited over the substrate 110 and gate structure 130 . Then, a rapid thermal anneal is performed at a relatively high temperature, introducing and locking strain 180 into the channel region 160 . The strain-inducing layer 170 is then removed and silicide regions (not shown) are typically formed on the source/drain regions 150 and gate electrode layer 138 .
- a suitable silicide process is a conventional cobalt, nickel or other similar metal salicide process.
- Compressive stress from the gate electrode layer 138 is enhanced by the annealing process described above, which introduces strain 180 (e.g., tensile) across the channel region 160 .
- This strain 180 can improve the performance of the semiconductor device 100 by improving hole and/or electron mobility in the channel region 160 .
- the cap-annealing process described supra can show improvement for, among others, NMOS devices. Unfortunately, it has been observed that the introduction of strain into the channel region using such a strain-inducing layer is insufficient to support some of the next generation devices.
- the present invention provides a method for manufacturing a semiconductor device as well as a semiconductor device.
- the method may include forming a gate structure over a substrate, and forming a strain inducing sidewall spacer proximate a sidewall of the gate structure, the strain inducing sidewall spacer configured to introduce strain in a channel region below the gate structure.
- the present invention further provides a method for manufacturing an integrated circuit.
- This method includes (1) forming gate structures over a semiconductor substrate, wherein each of the gate structures includes a gate dielectric and a gate electrode, (2) forming source/drain regions in the semiconductor substrate, wherein the source/drain regions are located proximate each of the gate structures, (3) forming a strain inducing sidewall spacer proximate a sidewall of each of the gate structures, (4) annealing the strain inducing sidewall spacers to introduce strain in a channel region located below each of the gate structures, the channel regions defined by the source/drain regions, and (5) forming interconnects within dielectric layers located over the gate structures, the interconnects contacting the gate structure or source/drain regions.
- the present invention additionally provides a semiconductor device.
- the semiconductor device may include a gate structure located over a substrate, and a strain inducing sidewall spacer located proximate a sidewall of the gate structure, the strain inducing sidewall spacer configured to introduce strain in a channel region below the gate structure.
- FIG. 1 illustrates a conventional semiconductor device at a stage of fabrication wherein a compressive strain is introduced by a conventional cap-annealing process
- FIGS. 2-8 illustrate detailed manufacturing steps showing how one might manufacture a semiconductor device in accordance with one embodiment of the invention.
- FIG. 9 illustrates an integrated circuit (IC) incorporating a semiconductor device constructed according to one embodiment of the invention.
- the present invention is based, at least in part, on the recognition that gate sidewall spacers may be designed to introduce strain in a channel region below a gate structure. From this recognition, the present invention acknowledges that various different gate sidewall spacers can be designed to introduce the strain in the channel region. For example, the present invention acknowledges that by increasing the ratio of bis t-butylaminosilane (BTBAS) to ammonia (NH 3 ) during the formation of silicon nitride gate sidewall spacers to a value of 1:1 or greater, the carbon concentration in the BTBAS silicon nitride layer can be increased. As the carbon concentration in the BTBAS silicon nitride layer is increased, the stress therein is also increased, thereby increasing the strain in the underlying silicon (e.g., the channel region).
- BBAS bis t-butylaminosilane
- NH 3 ammonia
- the present invention has conducted many different experiments and determined that the aforementioned BTBAS to ammonia ratio can provide a peak carbon concentration of about 1.1E21 atoms/cm 3 or greater, or even 2.0E21 atoms/cm 3 or greater, resulting in a stress value of 1.25 GPa or greater.
- the present invention has further acknowledged that the increase in stress in the BTBAS silicon nitride layer also increases the resulting boron concentration in the substrate of the semiconductor device (e.g., for a given original boron dose and concentration).
- the increase in Boron concentration results in less source/drain resistance and increased transistor performance. Specifically, it is believed that the higher stress in the BTBAS silicon nitride layer reduces the boron outdiffusion from the substrate.
- FIGS. 2-8 illustrated are views of detailed manufacturing steps showing how one might manufacture a semiconductor device in accordance with one embodiment of the invention.
- FIG. 2 illustrates a semiconductor device 200 at an initial stage of manufacture. From the outset, it should be noted that the embodiment of FIGS. 2-8 will be discussed as an re-channel metal oxide semiconductor (NMOS) device. In an alternative embodiment, all the dopant types, except for possibly the substrate dopant, could be reversed, resulting in a p-channel metal oxide semiconductor (PMOS) device. However, at least with regard to FIGS. 2-8 , no further reference to this opposite scheme will be discussed.
- NMOS re-channel metal oxide semiconductor
- PMOS p-channel metal oxide semiconductor
- the semiconductor device 200 of FIG. 2 includes a substrate 210 .
- the substrate 210 may, in one embodiment, be any layer located in the semiconductor device 200 , including a wafer itself or a layer located above the wafer (e.g., epitaxial layer).
- the substrate 210 of FIG. 1 is a P-type substrate. Nevertheless, one skilled in the art understands that the substrate 210 could also be an N-type substrate.
- the well region 220 contains a P-type dopant.
- the well region 220 would likely be doped with a P-type dopant dose ranging from about 1E13 atoms/cm 2 to about 1E14 atoms/cm 2 and at an energy ranging from about 100 keV to about 500 keV. This may result in the well region 220 having a peak dopant concentration ranging from about 5E17 atoms/cm 3 to about 1E19 atoms/cm 3 .
- the well region 220 may be excluded.
- the gate structure 230 includes a gate dielectric 233 and a gate electrode 238 .
- the gate dielectric 233 may comprise a number of different materials and stay within the scope of the invention.
- the gate dielectric 233 may comprise silicon dioxide, or in an alternative embodiment comprise a high dielectric constant (K) material.
- the gate dielectric 233 is a silicon dioxide layer having a thickness ranging from about 0.5 nm to about 5 nm.
- the gate dielectric 233 may be either grown or deposited. Additionally, the growth or deposition steps may require a
- the gate electrode 238 comprises standard polysilicon
- the gate electrode 238 or at least a portion thereof, comprises amorphous polysilicon material, a metal material, or fully silicided metal material.
- the amorphous polysilicon embodiment may be particularly useful when a substantially planar upper surface of the gate electrode 238 is desired.
- the deposition conditions for the gate electrode 238 may vary. However, if the gate electrode 238 were to comprise standard polysilicon, such as the instance in FIG. 2 , the gate electrode 238 could be deposited using a pressure ranging from about 100 torr to about 300 torr, a temperature ranging from about 620° C. to about 700° C., and a SiH 4 or Si 2 H 6 gas flow ranging from about 50 sccm to about 150 sccm. If, however, amorphous polysilicon were desired, the amorphous polysilicon gate electrode could be deposited using a pressure ranging from about 100 torr to about 300 torr, a temperature ranging from about 450° C.
- the gate electrode 238 may have a thickness ranging from about 50 nm to about 150 nm, among others.
- FIG. 3 illustrates the semiconductor device 200 of FIG. 2 after formation of portions of gate sidewall spacers 310 .
- any or all portions of the gate sidewall spacers 310 may be strain inducing sidewall spacers configured to introduce strain in a channel region below the gate structure 230 .
- the earlier formed layers should, in one embodiment, be configured to transfer the strain of the later filed layers into the channel region. This is as compared to absorbing the strain of the later filed layers, as a conventional buffer layer might do.
- the portions of the gate sidewall spacers 310 shown in FIG. 3 include an oxide offset spacer 320 and a nitride offset spacer 330 .
- the oxide offset spacer 320 if used as a strain inducing sidewall spacer, would typically have a stress value of about 0.5 GPa or greater, or in an alternative embodiment an even higher stress value of about 2.0 GPa or greater.
- the oxide offset spacer 320 might comprise a BTBAS oxide layer, or alternatively another oxide layer, while providing such stress values.
- the oxide offset spacer 320 comprises a BTBAS oxide layer, it might have a peak carbon concentration of about 1.1E21 atoms/cm 3 or greater.
- the BTBAS oxide layer might have a peak carbon concentration of about 1.5E21 atoms/cm 3 or greater, or even a peak carbon concentration of about 2.0E21 atoms/cm 3 or greater.
- the aforementioned peak carbon concentration values are particularly beneficial in providing significant improvement in the stress values of the oxide offset spacer 320 .
- the BTBAS oxide layer might be deposited using a chemical vapor deposition (CVD) process to a thickness ranging from about 1 nm to about 50 nm.
- the BTBAS oxide layer might be deposited using a non-plasma CVD process to a thickness ranging from about 2.0 nm to about 10 nm.
- the temperature maintained during the formation of the BTBAS oxide layer in this embodiment should remain relatively low, for example a temperature of less than about 600° C. In an alternative embodiment, the temperature remains between about 500° C. and about 550° C.
- the pressure used during the formation of the BTBAS oxide layer would desirably range from about 100 mTorr to about 1 Torr.
- the non BTBAS oxide layer might also be formed using a CVD process.
- the non BTBAS oxide layer might be formed using the CVD process to a thickness ranging from about 2.0 nm to about 10 nm. It is important in this embodiment that the temperature maintained during the formation of the non BTBAS oxide layer should also remain low in order to provide the desired tensile stress therein. For instance, a temperature of less than about 600° C. should be used.
- the oxide offset spacer 320 might be conventionally formed, for example possibly using conventional growth, deposition or a combination of growth and deposition steps.
- the nitride offset spacer 330 which as previously discussed may function as a strain inducing film, might comprise a BTBAS silicon nitride layer while remaining within the purview of the present invention.
- the BTBAS silicon nitride layer might have a peak carbon concentration of about 1.1E21 atoms/cm 3 or greater.
- the BTBAS silicon nitride layer might have a peak carbon concentration of about 1.5E21 atoms/cm 3 or greater, or even a peak carbon concentration of about 2.0E21 atoms/cm 3 or greater. What results with such peak carbon concentrations is the BTBAS silicon nitride layer having the aforementioned stress values.
- the BTBAS silicon nitride layer would typically be deposited using a CVD process to a thickness ranging from about 1 nm to about 50 nm. In the specific embodiment shown in FIG. 3 , the BTBAS silicon nitride layer would typically be deposited using a non-plasma CVD process to a thickness ranging from about 2.0 nm to about 10 nm.
- the BTBAS silicon nitride layer as compared to conventional BTBAS silicon nitride layers, may be formed using a ratio of BTBAS to ammonia (NH 3 ) of about 1:1 or greater.
- the BTBAS silicon nitride layer is formed using a ratio of BTBAS to ammonia (NH 3 ) of about 2:1 or greater, or even 4:1 or greater, depending on the desired amount of carbon.
- the temperature maintained during the formation of the BTBAS silicon nitride layer should remain relatively low, for example a temperature of less than about 600° C. In an alternative embodiment, the temperature remains between about 500° C. and about 550° C.
- the pressure used during the formation of the BTBAS silicon nitride layer would desirably range from about 100 mTorr to about 1 Torr.
- the nitride offset spacer 320 may, in an alternative embodiment, be formed using a plasma enhanced CVD (PECVD) process.
- PECVD plasma enhanced CVD
- the nitride offset spacer 320 might comprise silicon nitride.
- the nitride offset spacer 330 might be conventionally formed.
- oxide offset spacer 320 and the nitride offset spacer 330 are shown located only along the sides of the gate structure 230 , those skilled in the art are aware that the layers may have been previously blanket formed (e.g., along an upper surface of a substantial portion of the semiconductor device 200 ) and subsequently anisotropically etched to form the oxide offset spacer 320 and the nitride offset spacer 330 .
- FIG. 4 illustrates the semiconductor device 200 of FIG. 3 after formation of source/drain extension implants 410 within the substrate 210 .
- the implants 410 may be conventionally formed and generally have a peak dopant concentration ranging from about 1E19 atoms/cm 3 to about 2E20 atoms/cm 3 .
- the implants 410 may have a dopant type opposite to that of the well region 220 they are located within. Accordingly, the implants 410 are doped with an N-type dopant, thereby forming a channel region 420 .
- FIG. 5 illustrates the semiconductor device 200 of FIG. 4 after forming additional portions of the gate sidewall spacers 310 .
- a cap oxide 510 , L-shaped source/drain spacers 520 and bulk source/drain spacers 530 complete the gate sidewall spacers 310 in this embodiment.
- any one or all of the cap oxide 510 , L-shaped source/drain spacers 520 and bulk source/drain spacers 530 may be designed to be strain inducing gate sidewall spacers.
- the cap oxide 510 in addition to
- the cap oxide 510 In the embodiment wherein it is desired for the cap oxide 510 to be a strain inducing sidewall spacer, it might be formed using a process similar to that used to form the oxide offset spacer 320 when it was designed as a strain inducing sidewall spacer. In the embodiment wherein it is not desired for the cap oxide 510 to be a strain inducing sidewall spacer, it might be formed using a process similar to that used to form the oxide offset spacer 320 when it was not designed as a strain inducing sidewall spacer.
- the L-shaped source/drain spacers 520 may, depending on whether they are designed as strain inducing sidewall spacers, be formed using many different processes and materials. For instance, in the embodiment wherein it is desired for the L-shaped source/drain spacers 520 to be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the nitride offset spacers 330 when they were designed as strain inducing sidewall spacers.
- the L-shaped source/drain spacers 520 might be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the nitride offset spacers 330 when they were not designed as strain inducing sidewall spacers.
- the bulk source/drain spacers 530 may also, depending on whether they are designed as strain inducing sidewall spacers, be formed using many different processes and materials. For instance, in the embodiment wherein it is desired for the bulk source/drain spacers 530 to be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the oxide offset spacers 320 when they were designed as strain inducing sidewall spacers. In the embodiment wherein it is not desired for the bulk source/drain spacers 530 to be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the oxide offset spacers 320 when they were not designed as strain inducing sidewall spacers.
- the layers of the gate sidewall spacers 310 will alternate between different materials, for example the alternating oxide and nitride layers of FIGS. 3-5 .
- multiple films comprising an oxide or multiple films comprising a nitride, such as shown in the discussed FIGS. will not generally be located on one another. That being said, however, in the embodiment shown in FIG. 5 , those layers that were described as oxides could be exchanged for nitrides, and vice-versa.
- gate sidewall spacers 310 While a substantial amount of detail has been given regarding the specifics of the gate sidewall spacers 310 , such should not be construed to be limiting on the present invention. For example, certain embodiments exist where only the nitride offset spacer 330 and bulk source/drain spacers 530 , or another similar structure, comprise the gate sidewall spacers 310 . Other embodiments exist where all the layers shown in FIG. 5 exist, however, the materials and thicknesses are different. In another embodiment of the invention, the material chosen for the gate sidewall spacers 310 is based on its disposable nature. Therefore, as previously noted, the details given with respect to FIGS. 3 and 5 regarding the gate sidewall spacers 310 should not be used to limit the scope of the present invention.
- FIG. 6 illustrates the semiconductor device 200 of FIG. after forming source/drain implants 610 within the substrate 210 .
- the implants 610 have a peak dopant concentration ranging from about 1E18 atoms/cm 3 to about 1E21 atoms/cm 3 .
- the implants 610 should typically have a dopant type opposite to that of the well region 220 they are located within. Accordingly, in the illustrative embodiment shown in FIG. 6 , the implants 610 are doped with an N-type dopant.
- FIG. 7 illustrates the semiconductor device 200 of FIG. 6 after subjecting it to a thermal anneal.
- the thermal anneal imparts a strain 710 into the substrate 210 , particularly the channel region 420 .
- the thermal anneal which happens to be a rapid thermal anneal in the illustrative embodiment of FIG. 7 , may be performed at a temperature of greater than about 350° C., and less than about 1100° C., for a time period of less than about 180 seconds.
- the anneal can be conducted as a spike anneal or millisecond anneal (e.g., laser, flash, etc.) at a temperature ranging from about 800° C. to about 1400° C.
- the anneal may furthermore be a combination of the aforementioned anneals.
- the timing of the anneal particularly in this embodiment, allows the later formed silicided source/drain regions 810 and a silicided gate electrode layer 820 to not be affected thereby.
- the semiconductor device 200 resulting after the anneal of FIG. 7 has a number of benefits over conventional devices.
- One such benefit is the increased strain 710 that results in the channel region 420 as a result of the use of one or more strain inducing sidewall spacers.
- Another benefit is the increased boron concentration in the channel region 420 , and thus decreased resistance therein, that results from the use of one or more strain inducing sidewall spacers.
- the resulting semiconductor device 200 benefit from the manufacturing process of the present invention, but existing hardware and processing steps may be used, which reduces the time and cost associated with introducing the novel aspects of the present invention.
- the use of the inventive aspects of the invention allow for a lower thermal budget, at least as compared to other alternatives that do not comprise the one or more strain inducing sidewall spacers.
- FIG. 8 illustrates the semiconductor device 200 of FIG. after forming silicided source/drain regions 810 and a silicided gate electrode layer 820 .
- the skilled artisan understands the silicided source/drain region 810 and silicided gate electrode layer 820 formation process.
- the process may include forming a metal layer, possibly cobalt, nickel, nickel platinum etc., over the substrate 210 and gate structure 230 , and subjecting the metal layer to an anneal, causing the metal to react with the silicon of the substrate 210 , and in this instance the gate electrode layer 238 , and form the silicided source/drain regions 810 and silicided gate electrode layer 820 .
- FIGS. 7-8 illustrate that the silicided source/drain regions 810 and a silicided gate electrode layer 820 are formed after the anneal that forms the strain 710 .
- the anneal is conducted after the formation of the silicided source/drain regions 810 and silicided gate electrode layer 820 . Accordingly, the present invention should not be limited to any specific order in the formation of the silicided source/drain regions 810 and a silicided gate electrode layer 820 , and the anneal.
- FIG. 9 illustrates an integrated circuit (IC) 900 incorporating a semiconductor device 910 constructed according to the principles of the invention.
- the IC 900 may include devices, such as transistors used to form CMOS devices, BiCMOS devices, Bipolar devices, or other types of devices.
- the IC 900 may further include passive devices, such as inductors or resistors, or it may also include optical devices or optoelectronic devices. Those skilled in the art are familiar with these various types of devices and their manufacture.
- the IC 900 includes semiconductor devices 910 having dielectric layers 920 located thereover. Additionally, interconnect structures 930 are located within the dielectric layers 920 and contacting the semiconductor devices 910 , thus, forming the integrated circuit 900 .
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Abstract
The present invention provides a method for manufacturing a semiconductor device as well as a semiconductor device. The method, among other steps, may include forming a gate structure over a substrate, and forming a strain inducing sidewall spacer proximate a sidewall of the gate structure, the strain inducing sidewall configured to introduce strain in a channel region below the gate structure.
Description
- This application is a continuation of U.S. application Ser. No. 11/344,998 filed on Feb. 1, 2006, entitled AA SEMICONDUCTOR DEVICE HAVING A HIGH CARBON CONTENT STRAIN INDUCING FILM AND A METHOD OF MANUFACTURE THEREFOR,@ commonly assigned with the present invention and incorporated herein by reference.
- The present invention is directed, in general, to a semiconductor device and, more specifically, to a semiconductor device having a strain inducing sidewall spacer and a method of manufacture therefore.
- There exists a continuing need to improve semiconductor device performance and further scale semiconductor devices. A characteristic that limits scalability and device performance is electron and/or hole mobility (e.g., also referred to as channel mobility) throughout the channel region of transistors. As devices continue to shrink in size, the channel region for transistors also continues to shrink in size, which can limit channel mobility.
- One technique that may improve scaling limits and device performance is to introduce strain into the channel region, which can improve electron and/or hole mobility. Different types of strain, including uniaxial or biaxial tensile strain, compressive strain, etc. have been introduced into channel regions of various types of transistors in order to utilize their effect on electron and/or hole mobility. For some devices, certain types of strain improve mobility whereas other types degrade mobility.
-
FIG. 1 illustrates aconventional semiconductor device 100 at a stage of fabrication wherein a tensile strain is introduced by a silicon nitride cap-annealing process. Thesemiconductor device 100 includes asubstrate 110 having awell region 120 located therein. Thesemiconductor device 100 further includes agate structure 130 located over thesubstrate 110. Thegate structure 130, as appreciated, includes both a gatedielectric layer 133 and agate electrode layer 138. - Positioned on both sides of the
gate structure 130 are source/drain sidewall spacers 140. Additionally positioned in thesubstrate 110 proximate thegate structure 130 are source/drain regions 150. The source/drain regions 150 therefore define achannel region 160 in thesubstrate 110. - After the source/
drain regions 150 have been formed by implanting a suitable dopant, such as arsenic in the instant case, a strain-inducinglayer 170 is deposited over thesubstrate 110 andgate structure 130. Then, a rapid thermal anneal is performed at a relatively high temperature, introducing and lockingstrain 180 into thechannel region 160. The strain-inducinglayer 170 is then removed and silicide regions (not shown) are typically formed on the source/drain regions 150 andgate electrode layer 138. A suitable silicide process is a conventional cobalt, nickel or other similar metal salicide process. - Compressive stress from the
gate electrode layer 138 is enhanced by the annealing process described above, which introduces strain 180 (e.g., tensile) across thechannel region 160. Thisstrain 180 can improve the performance of thesemiconductor device 100 by improving hole and/or electron mobility in thechannel region 160. The cap-annealing process described supra can show improvement for, among others, NMOS devices. Unfortunately, it has been observed that the introduction of strain into the channel region using such a strain-inducing layer is insufficient to support some of the next generation devices. - Accordingly, what is needed in the art is an improved method for manufacturing a semiconductor device, and a device
- To address the above-discussed deficiencies of the prior art, the present invention provides a method for manufacturing a semiconductor device as well as a semiconductor device. The method, among other steps, may include forming a gate structure over a substrate, and forming a strain inducing sidewall spacer proximate a sidewall of the gate structure, the strain inducing sidewall spacer configured to introduce strain in a channel region below the gate structure.
- The present invention further provides a method for manufacturing an integrated circuit. This method, in one embodiment, includes (1) forming gate structures over a semiconductor substrate, wherein each of the gate structures includes a gate dielectric and a gate electrode, (2) forming source/drain regions in the semiconductor substrate, wherein the source/drain regions are located proximate each of the gate structures, (3) forming a strain inducing sidewall spacer proximate a sidewall of each of the gate structures, (4) annealing the strain inducing sidewall spacers to introduce strain in a channel region located below each of the gate structures, the channel regions defined by the source/drain regions, and (5) forming interconnects within dielectric layers located over the gate structures, the interconnects contacting the gate structure or source/drain regions.
- The present invention additionally provides a semiconductor device. The semiconductor device, without limitation, may include a gate structure located over a substrate, and a strain inducing sidewall spacer located proximate a sidewall of the gate structure, the strain inducing sidewall spacer configured to introduce strain in a channel region below the gate structure.
- For a more complete understanding of the present invention, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
- Prior Art
FIG. 1 illustrates a conventional semiconductor device at a stage of fabrication wherein a compressive strain is introduced by a conventional cap-annealing process; -
FIGS. 2-8 illustrate detailed manufacturing steps showing how one might manufacture a semiconductor device in accordance with one embodiment of the invention; and -
FIG. 9 illustrates an integrated circuit (IC) incorporating a semiconductor device constructed according to one embodiment of the invention. - The present invention is based, at least in part, on the recognition that gate sidewall spacers may be designed to introduce strain in a channel region below a gate structure. From this recognition, the present invention acknowledges that various different gate sidewall spacers can be designed to introduce the strain in the channel region. For example, the present invention acknowledges that by increasing the ratio of bis t-butylaminosilane (BTBAS) to ammonia (NH3) during the formation of silicon nitride gate sidewall spacers to a value of 1:1 or greater, the carbon concentration in the BTBAS silicon nitride layer can be increased. As the carbon concentration in the BTBAS silicon nitride layer is increased, the stress therein is also increased, thereby increasing the strain in the underlying silicon (e.g., the channel region).
- The present invention has conducted many different experiments and determined that the aforementioned BTBAS to ammonia ratio can provide a peak carbon concentration of about 1.1E21 atoms/cm3 or greater, or even 2.0E21 atoms/cm3 or greater, resulting in a stress value of 1.25 GPa or greater. The present invention has further acknowledged that the increase in stress in the BTBAS silicon nitride layer also increases the resulting boron concentration in the substrate of the semiconductor device (e.g., for a given original boron dose and concentration). The increase in Boron concentration results in less source/drain resistance and increased transistor performance. Specifically, it is believed that the higher stress in the BTBAS silicon nitride layer reduces the boron outdiffusion from the substrate.
- Turning now to
FIGS. 2-8 , illustrated are views of detailed manufacturing steps showing how one might manufacture a semiconductor device in accordance with one embodiment of the invention.FIG. 2 illustrates asemiconductor device 200 at an initial stage of manufacture. From the outset, it should be noted that the embodiment ofFIGS. 2-8 will be discussed as an re-channel metal oxide semiconductor (NMOS) device. In an alternative embodiment, all the dopant types, except for possibly the substrate dopant, could be reversed, resulting in a p-channel metal oxide semiconductor (PMOS) device. However, at least with regard toFIGS. 2-8 , no further reference to this opposite scheme will be discussed. - In the embodiment shown, the
semiconductor device 200 ofFIG. 2 includes asubstrate 210. Thesubstrate 210 may, in one embodiment, be any layer located in thesemiconductor device 200, including a wafer itself or a layer located above the wafer (e.g., epitaxial layer). Thesubstrate 210 ofFIG. 1 , however, is a P-type substrate. Nevertheless, one skilled in the art understands that thesubstrate 210 could also be an N-type substrate. - Located within the
substrate 210 is awell region 220. Thewell region 220 contains a P-type dopant. For example, thewell region 220 would likely be doped with a P-type dopant dose ranging from about 1E13 atoms/cm2 to about 1E14 atoms/cm2 and at an energy ranging from about 100 keV to about 500 keV. This may result in thewell region 220 having a peak dopant concentration ranging from about 5E17 atoms/cm3 to about 1E19 atoms/cm3. Those skilled in the art understand that in certain circumstances where the P-type substrate 210 dopant concentration is high enough, thewell region 220 may be excluded. - Located over the
substrate 210 is agate structure 230. Thegate structure 230 includes a gate dielectric 233 and agate electrode 238. Thegate dielectric 233 may comprise a number of different materials and stay within the scope of the invention. For example, thegate dielectric 233 may comprise silicon dioxide, or in an alternative embodiment comprise a high dielectric constant (K) material. In the illustrative embodiment ofFIG. 2 , however, thegate dielectric 233 is a silicon dioxide layer having a thickness ranging from about 0.5 nm to about 5 nm. - Any one of a plurality of manufacturing techniques could be used to form the
gate dielectric 233. For example, thegate dielectric 233 may be either grown or deposited. Additionally, the growth or deposition steps may require a - While the embodiment of
FIG. 2 discloses that thegate electrode 238 comprises standard polysilicon, other embodiments exist where thegate electrode 238, or at least a portion thereof, comprises amorphous polysilicon material, a metal material, or fully silicided metal material. The amorphous polysilicon embodiment may be particularly useful when a substantially planar upper surface of thegate electrode 238 is desired. - The deposition conditions for the
gate electrode 238 may vary. However, if thegate electrode 238 were to comprise standard polysilicon, such as the instance inFIG. 2 , thegate electrode 238 could be deposited using a pressure ranging from about 100 torr to about 300 torr, a temperature ranging from about 620° C. to about 700° C., and a SiH4 or Si2H6 gas flow ranging from about 50 sccm to about 150 sccm. If, however, amorphous polysilicon were desired, the amorphous polysilicon gate electrode could be deposited using a pressure ranging from about 100 torr to about 300 torr, a temperature ranging from about 450° C. to about 550° C., and a SiH4 or Si2H6 gas flow ranging from about 100 sccm to about 300 sccm. In any instance, thegate electrode 238 may have a thickness ranging from about 50 nm to about 150 nm, among others. -
FIG. 3 illustrates thesemiconductor device 200 ofFIG. 2 after formation of portions ofgate sidewall spacers 310. In accordance with the invention, any or all portions of thegate sidewall spacers 310 may be strain inducing sidewall spacers configured to introduce strain in a channel region below thegate structure 230. In those embodiments where later formed layers are configured to induce the strain, the earlier formed layers should, in one embodiment, be configured to transfer the strain of the later filed layers into the channel region. This is as compared to absorbing the strain of the later filed layers, as a conventional buffer layer might do. Those skilled in the art appreciate that the thickness of the earlier formed layers, as well as their material composition, may be adjusted to accommodate the transfer of strain to the channel region. The portions of thegate sidewall spacers 310 shown inFIG. 3 include an oxide offsetspacer 320 and a nitride offsetspacer 330. - The oxide offset
spacer 320, if used as a strain inducing sidewall spacer, would typically have a stress value of about 0.5 GPa or greater, or in an alternative embodiment an even higher stress value of about 2.0 GPa or greater. For instance, the oxide offsetspacer 320 might comprise a BTBAS oxide layer, or alternatively another oxide layer, while providing such stress values. In the embodiment wherein the oxide offsetspacer 320 comprises a BTBAS oxide layer, it might have a peak carbon concentration of about 1.1E21 atoms/cm3 or greater. In an alternative embodiment, the BTBAS oxide layer might have a peak carbon concentration of about 1.5E21 atoms/cm3 or greater, or even a peak carbon concentration of about 2.0E21 atoms/cm3 or greater. The aforementioned peak carbon concentration values are particularly beneficial in providing significant improvement in the stress values of the oxide offsetspacer 320. - The BTBAS oxide layer might be deposited using a chemical vapor deposition (CVD) process to a thickness ranging from about 1 nm to about 50 nm. In the specific embodiment shown in
FIG. 3 , the BTBAS oxide layer might be deposited using a non-plasma CVD process to a thickness ranging from about 2.0 nm to about 10 nm. The temperature maintained during the formation of the BTBAS oxide layer in this embodiment should remain relatively low, for example a temperature of less than about 600° C. In an alternative embodiment, the temperature remains between about 500° C. and about 550° C. Likewise, the pressure used during the formation of the BTBAS oxide layer would desirably range from about 100 mTorr to about 1 Torr. - In the embodiment wherein the oxide offset
spacer 320 does not comprise the BTBAS oxide layer but a non BTBAS oxide layer configured as a strain inducing layer, the non BTBAS oxide layer might also be formed using a CVD process. For example, the non BTBAS oxide layer might be formed using the CVD process to a thickness ranging from about 2.0 nm to about 10 nm. It is important in this embodiment that the temperature maintained during the formation of the non BTBAS oxide layer should also remain low in order to provide the desired tensile stress therein. For instance, a temperature of less than about 600° C. should be used. In those embodiments wherein a desire does not exist for the oxide offsetspacer 320 to function as a strain inducing sidewall spacer, the oxide offsetspacer 320 might be conventionally formed, for example possibly using conventional growth, deposition or a combination of growth and deposition steps. - The nitride offset
spacer 330, which as previously discussed may function as a strain inducing film, might comprise a BTBAS silicon nitride layer while remaining within the purview of the present invention. When used, the BTBAS silicon nitride layer might have a peak carbon concentration of about 1.1E21 atoms/cm3 or greater. In an alternative embodiment, the BTBAS silicon nitride layer might have a peak carbon concentration of about 1.5E21 atoms/cm3 or greater, or even a peak carbon concentration of about 2.0E21 atoms/cm3 or greater. What results with such peak carbon concentrations is the BTBAS silicon nitride layer having the aforementioned stress values. - The BTBAS silicon nitride layer would typically be deposited using a CVD process to a thickness ranging from about 1 nm to about 50 nm. In the specific embodiment shown in
FIG. 3 , the BTBAS silicon nitride layer would typically be deposited using a non-plasma CVD process to a thickness ranging from about 2.0 nm to about 10 nm. The BTBAS silicon nitride layer, as compared to conventional BTBAS silicon nitride layers, may be formed using a ratio of BTBAS to ammonia (NH3) of about 1:1 or greater. In other embodiments, however, the BTBAS silicon nitride layer is formed using a ratio of BTBAS to ammonia (NH3) of about 2:1 or greater, or even 4:1 or greater, depending on the desired amount of carbon. The temperature maintained during the formation of the BTBAS silicon nitride layer should remain relatively low, for example a temperature of less than about 600° C. In an alternative embodiment, the temperature remains between about 500° C. and about 550° C. Likewise, the pressure used during the formation of the BTBAS silicon nitride layer would desirably range from about 100 mTorr to about 1 Torr. - The nitride offset
spacer 320 may, in an alternative embodiment, be formed using a plasma enhanced CVD (PECVD) process. In this embodiment, the nitride offsetspacer 320 might comprise silicon nitride. In those embodiments wherein a desire does not exist for the nitride offsetspacer 330 to function as a strain inducing sidewall spacer, the nitride offsetspacer 330 might be conventionally formed. - While the oxide offset
spacer 320 and the nitride offsetspacer 330 are shown located only along the sides of thegate structure 230, those skilled in the art are aware that the layers may have been previously blanket formed (e.g., along an upper surface of a substantial portion of the semiconductor device 200) and subsequently anisotropically etched to form the oxide offsetspacer 320 and the nitride offsetspacer 330. -
FIG. 4 illustrates thesemiconductor device 200 ofFIG. 3 after formation of source/drain extension implants 410 within thesubstrate 210. Theimplants 410 may be conventionally formed and generally have a peak dopant concentration ranging from about 1E19 atoms/cm3 to about 2E20 atoms/cm3. As is standard in the industry, theimplants 410 may have a dopant type opposite to that of thewell region 220 they are located within. Accordingly, theimplants 410 are doped with an N-type dopant, thereby forming achannel region 420. -
FIG. 5 illustrates thesemiconductor device 200 ofFIG. 4 after forming additional portions of thegate sidewall spacers 310. Particularly, acap oxide 510, L-shaped source/drain spacers 520 and bulk source/drain spacers 530 complete thegate sidewall spacers 310 in this embodiment. Again, any one or all of thecap oxide 510, L-shaped source/drain spacers 520 and bulk source/drain spacers 530 may be designed to be strain inducing gate sidewall spacers. Thecap oxide 510, in addition to - In the embodiment wherein it is desired for the
cap oxide 510 to be a strain inducing sidewall spacer, it might be formed using a process similar to that used to form the oxide offsetspacer 320 when it was designed as a strain inducing sidewall spacer. In the embodiment wherein it is not desired for thecap oxide 510 to be a strain inducing sidewall spacer, it might be formed using a process similar to that used to form the oxide offsetspacer 320 when it was not designed as a strain inducing sidewall spacer. - The L-shaped source/
drain spacers 520 may, depending on whether they are designed as strain inducing sidewall spacers, be formed using many different processes and materials. For instance, in the embodiment wherein it is desired for the L-shaped source/drain spacers 520 to be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the nitride offsetspacers 330 when they were designed as strain inducing sidewall spacers. In the embodiment wherein it is not desired for the L-shaped source/drain spacers 520 to be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the nitride offsetspacers 330 when they were not designed as strain inducing sidewall spacers. - The bulk source/
drain spacers 530 may also, depending on whether they are designed as strain inducing sidewall spacers, be formed using many different processes and materials. For instance, in the embodiment wherein it is desired for the bulk source/drain spacers 530 to be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the oxide offsetspacers 320 when they were designed as strain inducing sidewall spacers. In the embodiment wherein it is not desired for the bulk source/drain spacers 530 to be strain inducing sidewall spacers, they might be formed using similar materials and processes as used to form the oxide offsetspacers 320 when they were not designed as strain inducing sidewall spacers. - Typically, the layers of the
gate sidewall spacers 310 will alternate between different materials, for example the alternating oxide and nitride layers ofFIGS. 3-5 . Thus, multiple films comprising an oxide or multiple films comprising a nitride, such as shown in the discussed FIGS. will not generally be located on one another. That being said, however, in the embodiment shown inFIG. 5 , those layers that were described as oxides could be exchanged for nitrides, and vice-versa. - While a substantial amount of detail has been given regarding the specifics of the
gate sidewall spacers 310, such should not be construed to be limiting on the present invention. For example, certain embodiments exist where only the nitride offsetspacer 330 and bulk source/drain spacers 530, or another similar structure, comprise thegate sidewall spacers 310. Other embodiments exist where all the layers shown inFIG. 5 exist, however, the materials and thicknesses are different. In another embodiment of the invention, the material chosen for thegate sidewall spacers 310 is based on its disposable nature. Therefore, as previously noted, the details given with respect toFIGS. 3 and 5 regarding thegate sidewall spacers 310 should not be used to limit the scope of the present invention. -
FIG. 6 illustrates thesemiconductor device 200 of FIG. after forming source/drain implants 610 within thesubstrate 210. Those skilled in the art understand that conventional processes might be used to form theimplants 610. Generally, theimplants 610 have a peak dopant concentration ranging from about 1E18 atoms/cm3 to about 1E21 atoms/cm3. Also, theimplants 610 should typically have a dopant type opposite to that of thewell region 220 they are located within. Accordingly, in the illustrative embodiment shown inFIG. 6 , theimplants 610 are doped with an N-type dopant. -
FIG. 7 illustrates thesemiconductor device 200 ofFIG. 6 after subjecting it to a thermal anneal. In the embodiment shown, the thermal anneal imparts astrain 710 into thesubstrate 210, particularly thechannel region 420. The thermal anneal, which happens to be a rapid thermal anneal in the illustrative embodiment ofFIG. 7 , may be performed at a temperature of greater than about 350° C., and less than about 1100° C., for a time period of less than about 180 seconds. In an alternative embodiment, however, the anneal can be conducted as a spike anneal or millisecond anneal (e.g., laser, flash, etc.) at a temperature ranging from about 800° C. to about 1400° C. The anneal may furthermore be a combination of the aforementioned anneals. The timing of the anneal, particularly in this embodiment, allows the later formed silicided source/drain regions 810 and a silicidedgate electrode layer 820 to not be affected thereby. - The
semiconductor device 200 resulting after the anneal ofFIG. 7 has a number of benefits over conventional devices. One such benefit is the increasedstrain 710 that results in thechannel region 420 as a result of the use of one or more strain inducing sidewall spacers. Another benefit is the increased boron concentration in thechannel region 420, and thus decreased resistance therein, that results from the use of one or more strain inducing sidewall spacers. Not only does the resultingsemiconductor device 200 benefit from the manufacturing process of the present invention, but existing hardware and processing steps may be used, which reduces the time and cost associated with introducing the novel aspects of the present invention. Likewise, the use of the inventive aspects of the invention allow for a lower thermal budget, at least as compared to other alternatives that do not comprise the one or more strain inducing sidewall spacers. -
FIG. 8 illustrates thesemiconductor device 200 of FIG. after forming silicided source/drain regions 810 and a silicidedgate electrode layer 820. The skilled artisan understands the silicided source/drain region 810 and silicidedgate electrode layer 820 formation process. In sum, the process may include forming a metal layer, possibly cobalt, nickel, nickel platinum etc., over thesubstrate 210 andgate structure 230, and subjecting the metal layer to an anneal, causing the metal to react with the silicon of thesubstrate 210, and in this instance thegate electrode layer 238, and form the silicided source/drain regions 810 and silicidedgate electrode layer 820. - It should be noted that
FIGS. 7-8 illustrate that the silicided source/drain regions 810 and a silicidedgate electrode layer 820 are formed after the anneal that forms thestrain 710. However, another embodiment exists wherein the anneal is conducted after the formation of the silicided source/drain regions 810 and silicidedgate electrode layer 820. Accordingly, the present invention should not be limited to any specific order in the formation of the silicided source/drain regions 810 and a silicidedgate electrode layer 820, and the anneal. -
FIG. 9 illustrates an integrated circuit (IC) 900 incorporating asemiconductor device 910 constructed according to the principles of the invention. TheIC 900 may include devices, such as transistors used to form CMOS devices, BiCMOS devices, Bipolar devices, or other types of devices. TheIC 900 may further include passive devices, such as inductors or resistors, or it may also include optical devices or optoelectronic devices. Those skilled in the art are familiar with these various types of devices and their manufacture. In the particular embodiment illustrated inFIG. 9 , theIC 900 includessemiconductor devices 910 havingdielectric layers 920 located thereover. Additionally,interconnect structures 930 are located within thedielectric layers 920 and contacting thesemiconductor devices 910, thus, forming theintegrated circuit 900. - Although the present invention has been described in detail, those skilled in the art should understand that they could make various changes or substitutions herein without departing from the invention.
Claims (20)
1. A method for manufacturing a semiconductor device, comprising:
forming a gate structure over a substrate; and
forming a strain inducing sidewall spacer proximate a sidewall of the gate structure by depositing a spacer material and anisotropically etching the spacer material, the strain inducing sidewall spacer configured to introduce strain in a channel region below the gate structure.
2. The method as recited in claim 1 wherein the strain inducing sidewall spacer has a tensile stress of about 0.5 GPa or greater.
3. The method as recited in claim 1 wherein forming a strain inducing sidewall spacer includes forming a strain inducing sidewall spacer using a temperature of less than about 600° C.
4. The method as recited in claim 1 wherein the strain inducing sidewall spacer comprises a nitride.
5. The method as recited in claim 1 wherein the strain inducing sidewall spacers comprises a bis t-butylaminosilane (BTBAS) silicon nitride layer formed using a flow ratio of bis t-butylaminosilane (BTBAS) to ammonia (NH3) of 1:1 or greater.
6. The method as recited in claim 5 wherein the bis t-butylaminosilane (BTBAS) silicon nitride layer has a peak carbon concentration of about 1.1E21 atoms/cm3 or greater.
7. The method as recited in claim 5 wherein the bis t-butylaminosilane (BTBAS) silicon nitride layer is a first strain inducing sidewall spacer and further including forming a second strain inducing sidewall spacer, the second strain inducing sidewall spacer located proximate the first strain inducing sidewall spacer.
8. The method as recited in claim 7 wherein the second strain inducing sidewall spacer comprises an oxide, nitride or combination thereof.
9. (canceled)
10. A method for manufacturing an integrated circuit, comprising:
forming gate structures over a semiconductor substrate, wherein each of the gate structures includes a gate dielectric and a gate electrode;
forming source/drain regions in the semiconductor substrate, wherein the source/drain regions are located proximate each of the gate structures;
forming a strain inducing sidewall spacer proximate a sidewall of each of the gate structures by depositing a spacer material and anisotropically etching the spacer material to leave spacer material on said sidewall;
annealing the strain inducing sidewall spacers to introduce strain in a channel region located below each of the gate structures, the channel regions defined by the source/drain regions; and
forming interconnects within dielectric layers located over the gate structures, the interconnects contacting the gate structure or source/drain regions.
11. A semiconductor device, comprising:
a gate structure located over a substrate; and
a strain inducing sidewall spacer located proximate a sidewall of the gate structure without overlying the gate structure, the strain inducing sidewall spacer configured to introduce strain in a channel region below the gate structure.
12. The device as recited in claim 11 wherein the strain inducing sidewall spacer has a tensile stress of about 0.5 GPa or greater.
13. The device as recited in claim 11 wherein the strain inducing sidewall spacer comprises a nitride.
14. The device as recited in claim 11 wherein the strain inducing sidewall spacers comprises a bis t-butylaminosilane (BTBAS) silicon nitride layer.
15. The device as recited in claim 14 wherein the bis t-butylaminosilane (BTBAS) silicon nitride layer has a peak carbon concentration of about 1.1E21 atoms/cm3 or greater.
16. The device as recited in claim 14 wherein the bis t-butylaminosilane (BTBAS) silicon nitride layer is a first strain inducing sidewall spacer and further including a second strain inducing sidewall spacer located proximate the first strain inducing sidewall spacer.
17. The device as recited in claim 16 wherein the second strain inducing sidewall spacer comprises an oxide, nitride or combination thereof.
18. (canceled)
19. The device as recited in claim 11 wherein the strain inducing sidewall spacer is an offset spacer, an L-shaped spacer, a source/drain spacer or a bulk spacer.
20. The device as recited in claim 11 further including a dielectric layer having one or more interconnects therein located over the gate structure, the one or more interconnects contacting the gate structure to form an integrated circuit.
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US12/831,815 US20100270622A1 (en) | 2006-02-01 | 2010-07-07 | Semiconductor Device Having a Strain Inducing Sidewall Spacer and a Method of Manufacture Therefor |
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US11/344,998 US20060172556A1 (en) | 2005-02-01 | 2006-02-01 | Semiconductor device having a high carbon content strain inducing film and a method of manufacture therefor |
US11/610,908 US20070196991A1 (en) | 2006-02-01 | 2006-12-14 | Semiconductor device having a strain inducing sidewall spacer and a method of manufacture therefor |
US12/831,815 US20100270622A1 (en) | 2006-02-01 | 2010-07-07 | Semiconductor Device Having a Strain Inducing Sidewall Spacer and a Method of Manufacture Therefor |
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-
2010
- 2010-07-07 US US12/831,815 patent/US20100270622A1/en not_active Abandoned
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US20030020111A1 (en) * | 2001-07-16 | 2003-01-30 | Bevan Malcolm J. | Economic and low thermal budget spacer nitride process |
US20060040497A1 (en) * | 2004-04-30 | 2006-02-23 | Chakravarti Ashima B | Material for contact etch layer to enhance device performance |
US20050260810A1 (en) * | 2004-05-21 | 2005-11-24 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method for selectively forming strained etch stop layers to improve FET charge carrier mobility |
US20060094194A1 (en) * | 2004-11-04 | 2006-05-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | Advanced disposable spacer process by low-temperature high-stress nitride film for sub-90NM CMOS technology |
US20070090455A1 (en) * | 2005-10-26 | 2007-04-26 | Freescale Semiconductor, Inc. | Electronic device including transistor structures with sidewall spacers and a process for forming the electronic device |
Cited By (5)
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US20110121398A1 (en) * | 2008-11-28 | 2011-05-26 | Jan Hoentschel | Technique for enhancing dopant profile and channel conductivity by millisecond anneal processes |
US8143133B2 (en) * | 2008-11-28 | 2012-03-27 | Advanced Micro Devices, Inc. | Technique for enhancing dopant profile and channel conductivity by millisecond anneal processes |
US20110024805A1 (en) * | 2009-07-31 | 2011-02-03 | Thorsten Kammler | Using high-k dielectrics as highly selective etch stop materials in semiconductor devices |
US8198166B2 (en) * | 2009-07-31 | 2012-06-12 | GlobalFoundries, Inc. | Using high-k dielectrics as highly selective etch stop materials in semiconductor devices |
US8481392B1 (en) * | 2011-12-30 | 2013-07-09 | Samsung Electronic Co., Ltd. | Methods of fabricating semiconductor device using high-K layer for spacer etch stop and related devices |
Also Published As
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US20070196991A1 (en) | 2007-08-23 |
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