US20100065162A1 - Method for Manufacturing Flat Steel Products From Aluminum Alloyed Multi-Phase Steel - Google Patents

Method for Manufacturing Flat Steel Products From Aluminum Alloyed Multi-Phase Steel Download PDF

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Publication number
US20100065162A1
US20100065162A1 US12/447,627 US44762707A US2010065162A1 US 20100065162 A1 US20100065162 A1 US 20100065162A1 US 44762707 A US44762707 A US 44762707A US 2010065162 A1 US2010065162 A1 US 2010065162A1
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US
United States
Prior art keywords
hot
rolled strip
strip
rolled
cold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/447,627
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English (en)
Inventor
Brigitte Hammer
Thomas Heller
Johann Wilhelm Schmitz
Jochen Wans
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Steel Europe AG
Original Assignee
ThyssenKrupp Steel AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp Steel AG filed Critical ThyssenKrupp Steel AG
Assigned to THYSSENKRUPP STEEL AG reassignment THYSSENKRUPP STEEL AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: WANS, JOCHEN, DR., SCHMITZ, JOHANN WILHELM, DR., HAMMER, BRIGITTE, DR., HELLER, THOMAS, DR.
Publication of US20100065162A1 publication Critical patent/US20100065162A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/041Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing involving a particular fabrication or treatment of ingot or slab
    • C21D8/0415Rapid solidification; Thin strip casting
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0421Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
    • C21D8/0426Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0447Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
    • C21D8/0473Final recrystallisation annealing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

Definitions

  • the invention relates to a method for manufacturing flat steel products, such as strips or sheet metal blanks, from high-tensile, aluminum alloyed steels.
  • Such steels belong to the group of multi-phase steels. These are usually steels, the properties of which are determined by type, quantity and alignment of the phases of the microstructure. Therefore at least two phases exist in the microstructure (ferrite, martensite, bainite for example). As a result, they have a superior strength/formability combination compared to conventional steels.
  • multi-phase steels are of major interest for automotive construction, since due to their high strength on the one hand they allow the use of smaller material thicknesses and consequently at the same time a reduction in the vehicle weight and on the other hand improve the safety of the vehicle body in the event of a collision (crash behavior).
  • multi-phase steels with at least equal strength of the overall body permit a reduction in the sheet metal thickness of a component made from such multi-phase steels compared to a body made from conventional steels.
  • multi-phase steels are melted in a converter steel mill and cast on a continuous casting machine into slabs or thin slabs, which are then hot-rolled into hot-rolled strip and coiled.
  • the mechanical properties of the hot-rolled strip can be varied by selectively controlled cooling of the hot-rolled strip after hot-rolling with the aim of adjusting certain microstructural fractions.
  • the hot-rolled strip can also be cold-rolled into cold-rolled strip in order to also obtain thinner sheet metal thicknesses (EP 0 910 675 B1, EP 0 966 547 B1, EP 1 169 486 B1, EP 1 319 725 B1, EP 1 398 390 A1).
  • a problem with manufacturing flat products from high-tensile multi-phase steels with a tensile strength of more than 800 MPa is that high rolling forces must be applied when rolling such steels. This requirement has the consequence that normally with the production machines at present generally available, high-tensile hot-rolled strip made from steel of the type under discussion can often only be manufactured in a width and thickness, which no longer fully meet the requirements demanded today by the automotive industry. In particular, strip of narrow thickness with sufficient width cannot be produced very well in conventional installations. Also, with conventional methods it is shown in practice that it is difficult to manufacture cold-rolled strip with a strength of more than 800 MPa from multi-phase steel.
  • the cast strip is subsequently hot-rolled in-line into a hot-rolled strip in one or more passes, the deformation degree ranging between 25% and 70%.
  • the final hot-rolling temperature in this case is above the Ara temperature.
  • the obtained hot-rolled strip is then cooled down in two steps. In the first step of this cooling a cooling rate of 5-100° C. per second is maintained until a temperature ranging between 400-550° C. is reached.
  • the hot-rolled strip is then held at this temperature for a dwell time, which is needed in order to allow bainitic transformation of the steel with a residual austenite content greater than 5%.
  • the formation of pearlite in this case is to be avoided.
  • the transformation process is interrupted by the beginning of the second cooling step, wherein the hot-rolled strip is brought to a temperature below 400° C., in order then to wind it into a coil at a coiling temperature below 350° C.
  • an aspect of the invention is to provide a method, which allows high-tensile flat steel products to be manufactured with less effort in a wide range of geometrical dimensions.
  • the aspect indicated above has been achieved by a method for manufacturing flat steel products, wherein according to the invention a steel that forms a multi-phase microstructure, which (in wt. %) contains 0.10-0.14% C, 1.30-1.70% Mn, up to 0.030% P, up to 0.004% S, 0.10-0.30% Si, 0.90-1.2% Al, up to 0.0070% N, 0.070-0.130% Ti, 0.040-0.060% Nb, 0.140-0.260% Mo and remainder iron and unavoidable impurities, is cast into a cast strip having a thickness of 1-4 mm, wherein the cast strip is hot-rolled in-line into a hot-rolled strip having a thickness of 0.5 to 3.2 mm in a continuous process at a final hot-rolling temperature ranging from 850 to 1000° C., the deformation degree being greater than 20%, and wherein the hot-rolled strip is coiled at a coiling temperature ranging from 350 to 480° C., so as to obtain a hot
  • the invention provides a method of casting to convert a particularly high-tensile, peritectically solidifying multi-phase steel into a hot-rolled strip. Since the cast strip itself in this case already possesses a narrow thickness, only relatively low deformation degrees must be maintained in the course of hot-rolling this strip, in order to manufacture flat products with narrow thicknesses, as they are needed particularly in the field of automotive construction. Thus it is possible with the method according to the invention, by specifying a corresponding initial thickness of the cast strip, to produce without any problems hot-rolled strip, which with an optimal characteristic distribution has a maximum thickness of 1.5 mm and from which components for the support structure of a vehicle for example can be manufactured.
  • the rolling forces necessary for this are low, so that hot-rolled strip of large width, which lies substantially above the width of hot-rolled strip of the same strength and thickness cast in the conventional way, can be produced without any problems with the method according to the invention.
  • the invention permits high-tensile hot-rolled strip, consisting of a martensitic steel with the composition indicated and processed according to the invention, the width of which is greater than 1,200 mm, in particular greater than 1,600 mm, to be reliably produced.
  • the application according to the invention of the strip casting process for converting high-tensile steels of the type composed according to the invention apart from the advantages mentioned above, due to their characteristics and process variables specific to the method (hot-rolling final temperature, cooling, coiling temperature for example) offers the possibility, also in respect to their solidification behavior, of reliably casting critical steel compositions of the type processed according to the invention.
  • very rapid solidification of the cast strip, characteristic of strip casting leads to a substantially reduced risk of the emergence of center liquations, compared to conventional production, with the consequence that the hot-rolled strip produced according to the invention has a particularly uniform characteristic distribution and microstructure over its cross section and its length.
  • a further special advantage of the method according to the invention is that the hot-rolled strip produced according to the invention has a high strength of at least 800 MPa, without in addition a special cooling cycle of the hot-rolled strip having to be maintained between the end of hot-rolling and coiling, which is prescribed in EP 1 072 689 B1 as the result of the need for a cooling interruption.
  • it In carrying out the method according to the invention, it must only be ensured that hot-rolling is terminated in a relatively closely confined temperature window and also that coiling is carried out in a precisely defined temperature range. Single-step cooling takes place in the interim.
  • a further advantage of the method according to the invention is that an extension in the range of mechanical properties of the strip produced according to the invention can be achieved, based on a single steel analysis, by varying the cooling and rolling conditions.
  • Hot-rolled strip produced according to the invention is particularly suitable for subsequent conversion into cold-rolled strip. Accordingly, one practical embodiment of the invention makes provision for the hot-rolled strip to be cold-rolled into cold-rolled strip having a thickness of 0.5-1.4 mm, in particular 0.7 mm up to 1.3 mm, as is needed for constructing automotive bodies.
  • the cold-rolled strip can be annealed at an annealing temperature of 750-850° C.
  • a minimum tensile strength of 800 MPa can be reliably ensured.
  • a 50 of the cold-rolled strip is 10%.
  • the flat product produced according to the invention is characterized by particularly good coatability.
  • the cold-rolled strip is provided in the way known per se with a metallic coating, in which, for example, this can be a zinc coating.
  • the strength and elongation values of hot-rolled strip produced according to the invention can be adjusted over a large range by corresponding coordination of the final hot-rolling and coiling temperatures. If for example hot-rolled strip, which has a minimum breaking elongation A 80 of the obtained hot-rolled strip of 10% and a minimum tensile strength R m of 800 MPa, is to be manufactured, this can be achieved due to the final hot-rolling temperature being 900-1000° C. and the coiling temperature being 400-480° C.
  • a hot-rolled strip with a higher tensile strength R m of at least 1100 MPa at a minimum breaking elongation A 80 of 5% is to be manufactured, in order to do this a final hot-rolling temperature ranging from 850 to 1100° C. and a coiling temperature ranging from 350 to 400° C. are selected.
  • the strips cast out of the steels A and B have been hot-rolled in-line in four different trials directly after the strip was cast into a hot-rolled strip, having a thickness of 1.25 mm, at a final hot-rolling temperature WET. Subsequently, the obtained hot-rolled strip in each case was directly cooled in a cooling step to a coiling temperature HT and coiled. After coiling the hot-rolled strips produced from the steels A and B in each case had a tensile strength R m and a breaking elongation Ago, which are indicated in Table 2 as the final hot-rolling temperature WET and coiling temperature HT maintained in each case during their production.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Metal Rolling (AREA)
  • Coating With Molten Metal (AREA)
  • Heat Treatment Of Steel (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
US12/447,627 2006-10-30 2007-10-24 Method for Manufacturing Flat Steel Products From Aluminum Alloyed Multi-Phase Steel Abandoned US20100065162A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06123140A EP1918404B1 (de) 2006-10-30 2006-10-30 Verfahren zum Herstellen von Stahl-Flachprodukten aus einem mit Aluminium legierten Mehrphasenstahl
EP06123140.3 2006-10-30
PCT/EP2007/061391 WO2008052920A1 (de) 2006-10-30 2007-10-24 Verfahren zum herstellen von stahl-flachprodukten aus einem mit aluminium legierten mehrphasenstahl

Publications (1)

Publication Number Publication Date
US20100065162A1 true US20100065162A1 (en) 2010-03-18

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US12/447,627 Abandoned US20100065162A1 (en) 2006-10-30 2007-10-24 Method for Manufacturing Flat Steel Products From Aluminum Alloyed Multi-Phase Steel

Country Status (10)

Country Link
US (1) US20100065162A1 (enExample)
EP (1) EP1918404B1 (enExample)
JP (1) JP5350254B2 (enExample)
KR (1) KR101461584B1 (enExample)
CN (1) CN101528966B (enExample)
AT (1) ATE432374T1 (enExample)
DE (1) DE502006003832D1 (enExample)
ES (1) ES2325963T3 (enExample)
PL (1) PL1918404T3 (enExample)
WO (1) WO2008052920A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090098408A1 (en) * 2007-10-10 2009-04-16 Nucor Corporation Complex metallographic structured steel and method of manufacturing same
US20100186856A1 (en) * 2005-10-20 2010-07-29 Nucor Corporation High strength thin cast strip product and method for making the same
US11193188B2 (en) 2009-02-20 2021-12-07 Nucor Corporation Nitriding of niobium steel and product made thereby
US11225697B2 (en) 2014-12-19 2022-01-18 Nucor Corporation Hot rolled light-gauge martensitic steel sheet and method for making the same

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470529A (en) * 1994-03-08 1995-11-28 Sumitomo Metal Industries, Ltd. High tensile strength steel sheet having improved formability
US6284063B1 (en) * 1996-07-12 2001-09-04 Thyssen Stahl Ag Hot-rolled steel strip and method of making it
US6328826B1 (en) * 1999-07-30 2001-12-11 Usinor Method of fabricating “TRIP” steel in the form of thin strip, and thin strip obtained in this way
US20030145911A1 (en) * 2001-06-13 2003-08-07 Harald Hoffmann Highly stable, steel and steel strips or steel sheets cold-formed, method for the production of steel strips and uses of said steel
US20030219621A1 (en) * 2000-10-19 2003-11-27 Nkk Corporation Galvanized steel sheet, method for manufacturing the same, and method for manufacturing press-formed product
US20040000633A1 (en) * 2002-06-28 2004-01-01 Casper Bryan K. Optical receiver circuit, method, and system
US6852180B1 (en) * 1999-09-24 2005-02-08 Usinor Method for making carbon steel bands, in particular packaging steel bands, and resulting bands
WO2005087965A1 (ja) * 2004-03-11 2005-09-22 Nippon Steel Corporation 成形性および穴拡げ性に優れた溶融亜鉛めっき複合高強度鋼板およびその製造方法
US7093342B2 (en) * 2000-05-26 2006-08-22 Castrip Llc Hot rolling thin strip
US20070144633A1 (en) * 2004-03-31 2007-06-28 Taro Kizu High-stiffness high-strength thin steel sheet and method for producing the same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3498504B2 (ja) * 1996-10-23 2004-02-16 住友金属工業株式会社 高延性型高張力冷延鋼板と亜鉛メッキ鋼板
WO2002026424A1 (en) * 2000-09-29 2002-04-04 Ishikawajima-Harima Heavy Industries Company Limited Production of thin steel strip
EP1396550A1 (de) * 2002-08-28 2004-03-10 ThyssenKrupp Stahl AG Verfahren zum Herstellen eines Warmbandes

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470529A (en) * 1994-03-08 1995-11-28 Sumitomo Metal Industries, Ltd. High tensile strength steel sheet having improved formability
US6284063B1 (en) * 1996-07-12 2001-09-04 Thyssen Stahl Ag Hot-rolled steel strip and method of making it
US6328826B1 (en) * 1999-07-30 2001-12-11 Usinor Method of fabricating “TRIP” steel in the form of thin strip, and thin strip obtained in this way
US6852180B1 (en) * 1999-09-24 2005-02-08 Usinor Method for making carbon steel bands, in particular packaging steel bands, and resulting bands
US7093342B2 (en) * 2000-05-26 2006-08-22 Castrip Llc Hot rolling thin strip
US20030219621A1 (en) * 2000-10-19 2003-11-27 Nkk Corporation Galvanized steel sheet, method for manufacturing the same, and method for manufacturing press-formed product
US20030145911A1 (en) * 2001-06-13 2003-08-07 Harald Hoffmann Highly stable, steel and steel strips or steel sheets cold-formed, method for the production of steel strips and uses of said steel
US20040000633A1 (en) * 2002-06-28 2004-01-01 Casper Bryan K. Optical receiver circuit, method, and system
WO2005087965A1 (ja) * 2004-03-11 2005-09-22 Nippon Steel Corporation 成形性および穴拡げ性に優れた溶融亜鉛めっき複合高強度鋼板およびその製造方法
US20070190353A1 (en) * 2004-03-11 2007-08-16 Hirokazu Taniguchi Hot dip galvanized composite high strength steel sheet excellent in shapeability and hole enlargement ability and method of production of same
US20070144633A1 (en) * 2004-03-31 2007-06-28 Taro Kizu High-stiffness high-strength thin steel sheet and method for producing the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100186856A1 (en) * 2005-10-20 2010-07-29 Nucor Corporation High strength thin cast strip product and method for making the same
US10071416B2 (en) 2005-10-20 2018-09-11 Nucor Corporation High strength thin cast strip product and method for making the same
US20090098408A1 (en) * 2007-10-10 2009-04-16 Nucor Corporation Complex metallographic structured steel and method of manufacturing same
US8435363B2 (en) 2007-10-10 2013-05-07 Nucor Corporation Complex metallographic structured high strength steel and manufacturing same
US9157138B2 (en) 2007-10-10 2015-10-13 Nucor Corporation Complex metallographic structured high strength steel and method of manufacturing
US11193188B2 (en) 2009-02-20 2021-12-07 Nucor Corporation Nitriding of niobium steel and product made thereby
US11225697B2 (en) 2014-12-19 2022-01-18 Nucor Corporation Hot rolled light-gauge martensitic steel sheet and method for making the same

Also Published As

Publication number Publication date
KR101461584B1 (ko) 2014-11-13
CN101528966B (zh) 2011-06-15
JP2010508436A (ja) 2010-03-18
ES2325963T3 (es) 2009-09-25
KR20090090302A (ko) 2009-08-25
PL1918404T3 (pl) 2009-10-30
CN101528966A (zh) 2009-09-09
EP1918404A1 (de) 2008-05-07
DE502006003832D1 (de) 2009-07-09
EP1918404B1 (de) 2009-05-27
JP5350254B2 (ja) 2013-11-27
ATE432374T1 (de) 2009-06-15
WO2008052920A1 (de) 2008-05-08

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Owner name: THYSSENKRUPP STEEL AG,GERMANY

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HAMMER, BRIGITTE, DR.;HELLER, THOMAS, DR.;SCHMITZ, JOHANN WILHELM, DR.;AND OTHERS;SIGNING DATES FROM 20090508 TO 20090602;REEL/FRAME:023035/0077

STCB Information on status: application discontinuation

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