US20090311949A1 - Method for producing semiconductor wafer - Google Patents

Method for producing semiconductor wafer Download PDF

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Publication number
US20090311949A1
US20090311949A1 US12/475,807 US47580709A US2009311949A1 US 20090311949 A1 US20090311949 A1 US 20090311949A1 US 47580709 A US47580709 A US 47580709A US 2009311949 A1 US2009311949 A1 US 2009311949A1
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semiconductor wafer
bonded abrasive
fixed grain
grain bonded
grinding
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US12/475,807
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Tomohiro Hashii
Yuichi Kakizono
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Sumco Corp
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Sumco Corp
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Publication of US20090311949A1 publication Critical patent/US20090311949A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B7/00Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
    • B24B7/20Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground
    • B24B7/22Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain
    • B24B7/228Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain for grinding thin, brittle parts, e.g. semiconductors, wafers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/04Lapping machines or devices; Accessories designed for working plane surfaces
    • B24B37/07Lapping machines or devices; Accessories designed for working plane surfaces characterised by the movement of the work or lapping tool
    • B24B37/08Lapping machines or devices; Accessories designed for working plane surfaces characterised by the movement of the work or lapping tool for double side lapping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B7/00Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
    • B24B7/10Single-purpose machines or devices
    • B24B7/16Single-purpose machines or devices for grinding end-faces, e.g. of gauges, rollers, nuts, piston rings
    • B24B7/17Single-purpose machines or devices for grinding end-faces, e.g. of gauges, rollers, nuts, piston rings for simultaneously grinding opposite and parallel end faces, e.g. double disc grinders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02002Preparing wafers
    • H01L21/02005Preparing bulk and homogeneous wafers
    • H01L21/02008Multistep processes

Definitions

  • This invention relates to a method for producing a semiconductor wafer, and more particularly to a method for producing a semiconductor wafer by cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot and then subjecting both surfaces thereof to a mirror finishing.
  • the conventional method for producing a semiconductor wafer typically comprises a series of a slicing step ⁇ a first beveling step ⁇ a lapping step ⁇ a second beveling step ⁇ a one-side grinding step ⁇ a double-sided polishing step ⁇ a one-side finish polishing step in this order.
  • a thin disc-shaped semiconductor wafer is cut out from a crystalline ingot.
  • an outer peripheral portion of the cut semiconductor wafer is beveled to suppress the occurrence of cracking or chipping in the semiconductor wafer at the subsequent lapping step.
  • the lapping step the beveled semiconductor wafer is lapped with a grindstone of, for example, #1000 to increase a flatness of the semiconductor wafer.
  • an outer peripheral portion of the lapped semiconductor wafer is beveled to render an end face of the semiconductor wafer into a given beveled form.
  • a one-side face of the beveled semiconductor wafer is ground with a grindstone of, for example, #2000-8000 to approximate the thickness of the semiconductor wafer to a final thickness.
  • both surfaces of the one-side ground semiconductor wafer are polished.
  • a one-side face of the double-sided polished semiconductor wafer as a device face is further subjected to finish polishing.
  • a double-sided mirror finished semiconductor wafer is produced through the two beveling steps, the lapping step and the one-side grinding step, so that there are problems that a kerf loss of a semiconductor material (loss of semiconductor material due to the increase of lapped scrap and one-side ground scrap) is brought about due to a large number of steps.
  • the above problem is remarkable on a large-diameter semiconductor wafer such as a silicon wafer having a diameter of not less than 450 mm.
  • a silicon wafer having a diameter of not less than 450 mm is produced at the same machining allowance as a currently major silicon wafer having a diameter of 300 mm, the kerf loss of the silicon wafer is 2.25 times.
  • the problem of growing the size of the lapping apparatus in the production of the large-diameter semiconductor wafer is solved and the first beveling step before the double-sided grinding step can be omitted, but the double-sided grinding step and the one-side grinding step are conducted, and hence the machining allowance of the silicon material is still large, which remains as a problem about the kerf loss.
  • an object of the invention is to advantageously solve the above-mentioned problems and to provide a method for producing a semiconductor wafer wherein both surfaces of a semiconductor wafer cut out from a crystalline ingot can be mirror-finished by a simple process flow obtained by omitting at least the beveling step, and also the semiconductor wafer can be obtained cheaply by reducing the machining allowance of silicon material in the semiconductor wafer to reduce the kerf loss of the semiconductor material.
  • the invention develops a remarkable effect when the semiconductor wafer is a silicon wafer having a large diameter of not less than 450 mm.
  • the inventors have made various studies about a method for producing a semiconductor wherein the number of production steps when a semiconductor wafer cut out from a crystalline ingot is rendered into a double-sided mirror-finished semiconductor wafer is decreased but also silicon kerf loss in the semiconductor wafer is reduced as compared with those of the conventional method.
  • the number of production steps can be decreased but also the machining allowance of the semiconductor wafer can be reduced as compared with the conventional method by conducting a fixed grain bonded abrasive grinding step of simultaneously conducting a high-speed treatment from rough grinding to finish grinding on both surfaces at once, instead of the lapping step and the one-side grinding step in the above conventional method, and a chemical treating step of simultaneously conducting not only reduction of working strain on surfaces and an end face of the semiconductor wafer but also a beveling.
  • the invention is based on the above knowledge and the summary and construction thereof are as follows.
  • a method for producing a semiconductor wafer comprising a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot; and a fixed grain bonded abrasive grinding step of sandwiching the semiconductor wafer between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive to simultaneously grind both surfaces of the semiconductor wafer.
  • a method for producing a semiconductor wafer comprising a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot; a double-sided polishing step of simultaneously polishing both surfaces of the semiconductor wafer; and a one-side finish polishing step being subjected to a one-side face of the semiconductor wafer polished at the double-sided polishing step, which further comprises between the slicing step and the double-sided polishing step a fixed grain bonded abrasive grinding step wherein the semiconductor wafer is fitted into a circular hole of a carrier having a plurality of circular holes closely aligned to each other and the carrier is sandwiched between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive and then the upper and lower plates are rotated while oscillating the carrier in the same horizontal plane to simultaneously conduct a high-speed treatment from rough grinding to finish grinding on both surfaces of the semiconductor wafer at once; and a chemical treating step wherein reduction of working strain on the surfaces and an end
  • a fixed grain bonded abrasive grinding step and a chemical treating step are conducted between the slicing step and the double-sided polishing step, whereby the number of production steps for the semiconductor wafer is shortened as compared with the conventional method and the machining allowance of the semiconductor wafer can be reduced to reduce the kerf loss of the semiconductor material to thereby obtain the semiconductor wafer cheaply.
  • the flatness of the semiconductor wafer can be improved by reducing the machining allowance of the semiconductor wafer.
  • a semiconductor wafer having an epitaxial layer can be obtained by conducting an epitaxial layer growing step between the chemical treating step and the double-sided polishing step or after the double-sided polishing step.
  • the production method of the semiconductor wafer according to the invention is especially suitable for the production of silicon wafers having a large diameter of not less than 450 mm.
  • FIG. 1 is a flow chart showing production steps according to a first embodiment of the invention
  • FIG. 2 ( a ) is a schematic cross-sectional view of an apparatus used in a fixed grain bonded abrasive grinding step
  • FIG. 2 ( b ) is a schematic top view of the apparatus showing a state just before the start of the fixed grain bonded abrasive grinding step
  • FIG. 2 ( c ) is a schematic top view of the apparatus showing a state after a predetermined time of the fixed grain bonded abrasive grinding step
  • FIG. 3 is a schematic cross-sectional view and a top view of an apparatus used in the conventional lapping step
  • FIG. 4 is a flow chart showing production steps according to a second embodiment of the invention.
  • FIG. 5 is a flow chart showing production steps of Conventional Example 1.
  • FIG. 6 is a flow chart showing production steps of Conventional Example 2.
  • FIG. 1 is a flow chart showing production steps according to a first embodiment of the invention.
  • the following five steps (1) to (5) are conducted in this order:
  • the slicing step is a step of cutting out a thin disc-shaped wafer by contacting a wire saw with a crystalline ingot while supplying a grinding solution, or by cutting a crystalline ingot with an inner diameter blade.
  • the semiconductor wafer after the slicing step is preferable to have a high flatness and a small surface roughness as far as possible.
  • the crystalline ingot is typically an ingot of silicon single crystal, but may be an ingot of polycrystalline silicon for solar cells.
  • the fixed grain bonded abrasive grinding step is a step of roughly grinding both surfaces of the semiconductor wafer cut in the slicing step to increase the flatness and to approximate the thickness of the semiconductor wafer to the final thickness.
  • FIG. 2 is a schematic view of a fixed grain bonded abrasive grinding apparatus 10 used in the fixed grain bonded abrasive grinding step
  • FIG. 2 ( a ) is a cross-sectional view of the apparatus 10 used in the fixed grain bonded abrasive grinding step
  • FIGS. 2 ( b ) and ( c ) are top views of the apparatus 10 used in the fixed grain bonded abrasive grinding step, respectively.
  • FIGS. 2 ( a ) and ( b ) show states just before the start of the fixed grain bonded abrasive grinding step
  • FIG. 2 ( c ) view shows a state after a predetermined time of the fixed grain bonded abrasive grinding step.
  • the fixed grain bonded abrasive grinding apparatus 10 comprises a carrier 12 having a plurality of circular holes 11 a , 11 b and 11 c closely aligned to each other, pads 13 a , 13 b each having a fixed grain bonded abrasive, a pair of upper and lower plates 14 a , 14 b having the pads 13 a and 13 b , and guide rollers 15 a , 15 b , 15 c , 15 d arranged so as to contact with a side face of the carrier 12 at four divided positions of the circumference of the carrier 12 .
  • the semiconductor wafers 16 a , 16 b , 16 c cut out in the slicing step are fitted into the circular holes 11 a , 11 b , 11 c of the carrier 12 , and thereafter the carrier 12 is sandwiched between the pair of upper and lower plates 14 a , 14 b having the pads 13 a , 13 b with the fixed grain bonded abrasive, and then the upper and lower plates 14 a , 14 b are rotated while moving the guide rollers 15 a , 15 b , 15 c , 15 d to oscillate the carrier 12 in the same horizontal plane, whereby both surfaces of each of the wafers 16 a , 16 b , 16 c are ground simultaneously.
  • the number of circular holes 11 a , 11 b , 11 c in the FIG. 2 is not limited to three. However, as shown in FIGS. 2 ( b ) and ( c ), it is important that all of the circular holes 11 a , 11 b , 11 c are disposed so as to enter into the circumferences of the upper and lower plates 14 a , 14 b even if the carrier 12 takes any positional relationship with respect to the upper and lower plates 14 a , 14 b through oscillating.
  • the circular hole 11 has the same diameter and the number thereof is 3, because as shown in FIGS.
  • the diameter of the plates 14 can be made minimum and the size of the fixed grain bonded abrasive grinding apparatus 10 is not unnecessarily grown.
  • L 1 in FIG. 2 L 1 if three silicon wafers each having a diameter of 450 mm are ground with the fixed grain bonded abrasive is approximately 985 mm.
  • the pad Since the pad has the fixed grain bonded abrasive, it is not required to supply a slurry of free abrasive grains during the fixed grain bonded abrasive grinding. Therefore, it is possible to avoid the deterioration of the flatness of the semiconductor wafer after the grinding due to non-uniform supply of the free abrasive grains, which is especially advantageous in a case that a diameter of the semiconductor wafer is large as in a silicon wafers having a diameter of not less than 450 mm and it is difficult to supply the free abrasive grains uniformly.
  • the material of the abrasive grains in the pad having the fixed grain bonded abrasive is generally diamond, but abrasive grains of SiC may be also used.
  • the pad with the fixed grain bonded abrasive may have a roughness of #1000-8000, as previously mentioned, the pressure applied to the semiconductor wafer during the fixed grain bonded abrasive grinding is uniform and the grinding action of the abrasive grains to the semiconductor wafer is uniform owing to the use of the fixed grain bonded abrasive instead of the free abrasive grains, so that it is possible to conduct a high-speed treatment from rough grinding to finish grinding at once without occurrence of cracking or chipping even if a semiconductor wafer having a rough surface state just after the slicing step is subjected to a fixed grain bonded abrasive grinding with a fine pad of about #8000.
  • the grinding margin at the fixed grain bonded abrasive grinding step is preferable to be 20-50 ⁇ m per one-side surface.
  • the lapping step will be briefly described to compare the fixed grain bonded abrasive grinding step employed in the invention with the lapping step employed in the conventional method.
  • the lapping apparatus 50 comprises carriers 52 a , 52 b , 52 c , 52 d , 52 e each having a respective circular hole 51 a , 51 b , 51 c , 51 d , or 51 e and provided on its side face with a gear, pads 53 a , 53 b , a pair of upper and lower plates 54 a , 54 b having the pads 53 a , 53 b , an outer peripheral gear 55 in the sun-and-planet motion of the carriers 52 a , 52 b , 52 c , 52 d , 52 e , and a center gear 56 engaging with the gears provided on the side faces of the carriers 52 a , 52 b , 52 c , 52 d , 52 e.
  • the semiconductor wafers 57 a , 57 b , 57 c , 57 d , 57 e cut in the slicing step are fitted into the circular holes 51 a , 51 b , 51 c , 51 d , 51 e of the carriers 52 a , 52 b , 52 c , 52 d , 52 e , and thereafter the carriers 52 a , 52 b , 52 c , 52 d , 52 e are sandwiched between the pair of the upper and lower plates 54 a , 54 b having the pads 53 a , 53 b , and then the center gear 56 is rotated to conduct the sun-and-planet motion of the carriers 52 a , 52 b , 52 c , 52 d , 52 e along the outer peripheral gear 55 while supplying free abrasive grains to the wafers 57 a , 57 b , 57 c , 57 d , 57 e
  • the area occupied by the center gear 56 is large and the area of the plate 54 becomes large accompanied therewith, and hence the whole size of the lapping apparatus 50 tends to be grown.
  • the sizes of the carriers 52 a , 52 b , 52 c , 52 d , 52 e are grown and hence the force required for the sun-and-planet motion of the carriers 52 a , 52 b , 52 c , 52 d , 52 e becomes large to grow the size of the center gear 56 , and as a result, the size of the lapping apparatus 50 becomes more larger, which is a serious problem.
  • L 2 is about 2200 mm, which is much larger than LI in the fixed grain bonded abrasive grinding apparatus 10 .
  • silicon wafers having a diameter of not less than 450 mm are produced by a method including the lapping step, it is required to use a very large lapping apparatus, which may cause a problem in the installation site and the like.
  • the size of the guide becomes larger since the lapping is conducted while supplying free abrasive grains.
  • the supply area of free abrasive grains becomes wider, and it is difficult to supply them uniformly, which may easily deteriorate the flatness of the semiconductor wafer after the lapping step but also may cause the cracking or chipping in the lapping.
  • the chemical treating step simultaneously conducts reduction of working strain on the surfaces and end face of the semiconductor wafer applied at the slicing step or both the slicing step and the fixed grain bonded abrasive grinding step, and a finish beveling of making the end face of the semiconductor wafer to a given beveled form, which may be either a batch type or a sheet-feed type chemical treatment.
  • the batch type chemical treatment is a treatment of immersing a plurality of semiconductor wafers (e.g. 24 wafers) into a vessel containing a given etching solution to simultaneously conduct the reduction of working strain on both surfaces and end faces of the semiconductor wafer and the finish beveling of making the end face of the semiconductor wafer to a given beveled form.
  • the sheet-feed type chemical treating step is a treatment that one semiconductor wafer is rotated while adding dropwise an etching solution to a one-side face of the semiconductor wafer, whereby the etching solution is extended over the both surfaces and end faces of the semiconductor wafer through centrifugal force to reduce working strain on both the surfaces and end faces of the semiconductor wafer, and at the same time the end face of the semiconductor wafer is subjected to a finish beveling to a given beveled form.
  • the sheet-feed type chemical treatment is conducted twice so that both surfaces are etched by subjecting each one-side face thereto. On the end face, conditions of etching are set for making a given form by two etchings.
  • the etching solution used in the sheet-feed type chemical treatment it is preferable to use a mixed acids of hydrofluoric acid, nitric acid and phosphoric acid, because it is required that when the etching solution is added dropwise to the rotating semiconductor wafer, it is extended over the surface of the semiconductor wafer to be etched at a proper rate to form a uniform film of the etching solution on this surface.
  • a mixed acid of hydrofluoric acid, nitric acid and acetic acid usually used as the etching solution in the batch type chemical treatment is not preferable because it is low in the viscosity and when it is added dropwise to the rotating semiconductor wafer, a rate of extending over the surface to be etched is too fast and the film of the etching solution is not formed, resulting in irregular etching.
  • the mixed acid of hydrofluoric acid, nitric acid and phosphoric acid used as the etching solution in the sheet-feed type chemical treatment is preferable to comprise 5-20 mass % of hydrofluoric acid, 5-40 mass % of nitric acid, 30-40 mass % of phosphoric acid.
  • both surfaces of the semiconductor wafer subjected to the fixed grain bonded abrasive grinding step and the chemical treating step are polished with an abrasive cloth made of urethane and the like while supplying an abrasive slurry.
  • the kind of the abrasive slurry is not particularly limited, but colloidal silica having a particle size of 0.5 to 2 ⁇ m is preferable.
  • a one-side face of the double-sided polished semiconductor wafer as a device surface is polished with an abrasive cloth made of urethane or the like while supplying an abrasive slurry.
  • the kind of the abrasive slurry is not particularly limited, but colloidal silica having a particle size of not more than 0.5 ⁇ m is preferable.
  • FIG. 4 is a flow chart showing production steps of the second embodiment according to the invention. It should be noted that the same steps as in FIG. 1 are named the same in FIG. 4
  • the second embodiment shown in FIG. 4 is common to the first embodiment shown in FIG. 1 in a point that the fixed grain bonded abrasive grinding step and the chemical treating step are conducted between the slicing step and the double-sided grinding step, but the order of conducting the fixed grain bonded abrasive grinding step and the chemical treating step differs between both the embodiments.
  • the chemical treating step has an action of finish-beveling the end face of the semiconductor wafer to a given beveled form. Therefore, it is advantageous that only the double-sided polishing step and the one-side finish polishing step are conducted after the chemical treating step in view of a point that the grinding step showing a large reduction amount of the thickness of the semiconductor wafer is avoided to suppress a variation of a beveled width in the semiconductor wafer.
  • the first embodiment according to the invention shown in FIG. 1 i.e., the order of the fixed grain bonded abrasive grinding step the chemical treating step is preferable.
  • the second embodiment according to the invention is an effective means for reducing the production cost of the semiconductor wafer.
  • a finish beveling step may be conducted after the fixed grain bonded abrasive grinding step.
  • a polishing step of beveled portion and/or an epitaxial layer growing step may be included, if desired.
  • the polishing step of beveled portion and the epitaxial layer growing step will be described below.
  • the polishing step of the beveled portion is conducted after the double-sided polishing step for polishing the beveled portion of the semiconductor wafer to reduce a variation of the beveled width in the wafer.
  • the beveled portion is polished with an abrasive cloth made of urethane or the like while supplying an abrasive slurry.
  • the kind of the abrasive slurry is not particularly limited, but colloidal silica having a particle size of about 0.5 ⁇ m is preferable.
  • a semiconductor wafer having an epitaxial layer can be obtained by conducting an epitaxial layer growing step between the chemical treating step and the double-sided polishing step or after the double-sided polishing step.
  • the epitaxial layer is grown on the surface of the semiconductor wafer, it is required to remove surface damage of the semiconductor wafer applied at the slicing step and optionally at the fixed grain bonded abrasive grinding step, so that the epitaxial layer growing step is preferable to be conducted between the chemical treating step and the double-sided polishing step, or after the double-sided polishing step.
  • a semiconductor wafer is prepared by the production method according to the invention as stated below.
  • a silicon wafer having a diameter of 300 mm is prepared according to a flow chart of FIG. 1 in the first embodiment according to the invention.
  • a silicon wafer having a diameter of 450 mm is prepared in the same production method as in Invention Example 1.
  • a silicon wafer having a diameter of 300 mm is prepared according to a flow chart of FIG. 4 in the second embodiment according to the invention.
  • a silicon wafer having a diameter of 450 mm is prepared in the same production method as in Invention Example 3.
  • a silicon wafer having a diameter of 300 mm is prepared by the conventional production method shown in FIG. 5 inclusive of a lapping step.
  • a silicon wafer having a diameter of 300 mm is prepared by a production method shown in FIG. 6 using a double-sided polishing step instead of the lapping step.
  • the silicon kerf loss is evaluated by a reduction quantity ( ⁇ m) of a thickness in the semiconductor wafer before and after the fixed grain bonded abrasive grinding step in Invention Examples 1 to 4, the sum of a reduction quantity ( ⁇ m) of a thickness in the semiconductor wafer before and after the lapping step and a reduction quantity ( ⁇ m) of a thickness in the semiconductor wafer before and after the one-side grinding step in Conventional Example 1, and the sum of a reduction quantity ( ⁇ m) of a thickness in the semiconductor wafer before and after the double-sided grinding step and a reduction quantity ( ⁇ m) of a thickness in the semiconductor wafer before and after the one-side grinding step in Conventional Example 2, respectively.
  • the flatness is less than 0.5 ⁇ m.
  • the flatness is not less than 0.5 ⁇ m and not more than 1 ⁇ m.
  • the flatness is more than 1 ⁇ m.
  • Example 2 Example 3
  • Example 4 Example 1
  • Example 2 Flow chart FIG. 1 FIG. 1 FIG. 4 FIG. 4 FIG. 5
  • Silicon kerf loss 40 60 40 60 100 105 (ground thickness: ( ⁇ m))
  • Ground thickness: ( ⁇ m) Flatness ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇
  • Invention Example 1 shows a minimum value of the silicon kerf loss and a good flatness
  • Invention Example 2 shows good results substantially equal to those in Invention Example 1, from which it has been confirmed that a silicon wafer having a large diameter of 450 mm is obtained by the production method according to the first embodiment of the invention.
  • good results substantially equal to those in Invention Examples 1 and 2 on the silicon kerf loss and the flatness are obtained in Examples 3 and 4 by the production method according to the second embodiment of the invention.
  • Conventional Examples 1 and 2 show a large silicon kerf loss and a poor flatness as compared with Invention Examples 1 to 4.
  • the fixed grain bonded abrasive grinding step and the chemical treating step are conducted between the slicing step and the double-sided polishing step, whereby the number of production steps for the semiconductor wafer is shortened as compared with the conventional method and the machining allowance of the semiconductor wafer can be reduced to reduce the kerf loss of the semiconductor material to thereby obtain the semiconductor wafer cheaply. Also, the flatness of the semiconductor wafer can be improved by reducing the machining allowance of the semiconductor wafer. Furthermore, a semiconductor wafer having an epitaxial layer can be obtained by conducting an epitaxial layer growing step between the chemical treating step and the double-sided polishing step, or after the double-sided polishing step.
  • the production method of the semiconductor wafer according to the invention is especially suitable for the production of silicon wafers having a large diameter of not less than 450 mm.

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Abstract

A semiconductor wafer is produced by a method comprising a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot; and a fixed grain bonded abrasive grinding step of sandwiching the semiconductor wafer between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive to simultaneously grind both surfaces of the semiconductor wafer.

Description

    BACKGROUND OF THE INVENTION 1. Field of the Invention
  • This invention relates to a method for producing a semiconductor wafer, and more particularly to a method for producing a semiconductor wafer by cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot and then subjecting both surfaces thereof to a mirror finishing. 2. Description of the Related Art
  • The conventional method for producing a semiconductor wafer typically comprises a series of a slicing step→a first beveling step→a lapping step→a second beveling step→a one-side grinding step→a double-sided polishing step→a one-side finish polishing step in this order.
  • In the slicing step, a thin disc-shaped semiconductor wafer is cut out from a crystalline ingot. In the first beveling step, an outer peripheral portion of the cut semiconductor wafer is beveled to suppress the occurrence of cracking or chipping in the semiconductor wafer at the subsequent lapping step. In the lapping step, the beveled semiconductor wafer is lapped with a grindstone of, for example, #1000 to increase a flatness of the semiconductor wafer. In the second beveling step, an outer peripheral portion of the lapped semiconductor wafer is beveled to render an end face of the semiconductor wafer into a given beveled form. In the one-side grinding step, a one-side face of the beveled semiconductor wafer is ground with a grindstone of, for example, #2000-8000 to approximate the thickness of the semiconductor wafer to a final thickness. In the double-sided polishing step, both surfaces of the one-side ground semiconductor wafer are polished. In the one-side finish polishing step, a one-side face of the double-sided polished semiconductor wafer as a device face is further subjected to finish polishing.
  • In the aforementioned conventional method, a double-sided mirror finished semiconductor wafer is produced through the two beveling steps, the lapping step and the one-side grinding step, so that there are problems that a kerf loss of a semiconductor material (loss of semiconductor material due to the increase of lapped scrap and one-side ground scrap) is brought about due to a large number of steps.
  • Particularly, the above problem is remarkable on a large-diameter semiconductor wafer such as a silicon wafer having a diameter of not less than 450 mm. For example, when a silicon wafer having a diameter of not less than 450 mm is produced at the same machining allowance as a currently major silicon wafer having a diameter of 300 mm, the kerf loss of the silicon wafer is 2.25 times.
  • In addition, when the above-mentioned lapping step is added to the production method for a silicon wafer having a diameter of not less than 450 mm, the size of the lapping apparatus is considerably grown, which will be brought question on a place of disposing the lapping apparatus or the like in the formulation of the production line.
  • In Japanese Patent No. 3,328,193, a method for producing a semiconductor wafer, which comprises a double-sided grinding step instead of the lapping step in the above conventional method, is proposed.
  • In the production method of the semiconductor wafer disclosed in this patent document, the problem of growing the size of the lapping apparatus in the production of the large-diameter semiconductor wafer is solved and the first beveling step before the double-sided grinding step can be omitted, but the double-sided grinding step and the one-side grinding step are conducted, and hence the machining allowance of the silicon material is still large, which remains as a problem about the kerf loss.
  • Moreover, it is desired to improve the flatness of the semiconductor wafer, which will be anticipated to become more severe in future, by reducing the machining allowance of the semiconductor wafer.
  • SUMMARY OF THE INVENTION
  • It is, therefore, an object of the invention is to advantageously solve the above-mentioned problems and to provide a method for producing a semiconductor wafer wherein both surfaces of a semiconductor wafer cut out from a crystalline ingot can be mirror-finished by a simple process flow obtained by omitting at least the beveling step, and also the semiconductor wafer can be obtained cheaply by reducing the machining allowance of silicon material in the semiconductor wafer to reduce the kerf loss of the semiconductor material. Particularly, the invention develops a remarkable effect when the semiconductor wafer is a silicon wafer having a large diameter of not less than 450 mm.
  • In order to solve the above problems, the inventors have made various studies about a method for producing a semiconductor wherein the number of production steps when a semiconductor wafer cut out from a crystalline ingot is rendered into a double-sided mirror-finished semiconductor wafer is decreased but also silicon kerf loss in the semiconductor wafer is reduced as compared with those of the conventional method.
  • As a result, it has been found that the number of production steps can be decreased but also the machining allowance of the semiconductor wafer can be reduced as compared with the conventional method by conducting a fixed grain bonded abrasive grinding step of simultaneously conducting a high-speed treatment from rough grinding to finish grinding on both surfaces at once, instead of the lapping step and the one-side grinding step in the above conventional method, and a chemical treating step of simultaneously conducting not only reduction of working strain on surfaces and an end face of the semiconductor wafer but also a beveling.
  • The invention is based on the above knowledge and the summary and construction thereof are as follows.
  • 1. A method for producing a semiconductor wafer, comprising a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot; and a fixed grain bonded abrasive grinding step of sandwiching the semiconductor wafer between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive to simultaneously grind both surfaces of the semiconductor wafer.
  • 2. A method for producing a semiconductor wafer, comprising a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot; a double-sided polishing step of simultaneously polishing both surfaces of the semiconductor wafer; and a one-side finish polishing step being subjected to a one-side face of the semiconductor wafer polished at the double-sided polishing step, which further comprises between the slicing step and the double-sided polishing step a fixed grain bonded abrasive grinding step wherein the semiconductor wafer is fitted into a circular hole of a carrier having a plurality of circular holes closely aligned to each other and the carrier is sandwiched between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive and then the upper and lower plates are rotated while oscillating the carrier in the same horizontal plane to simultaneously conduct a high-speed treatment from rough grinding to finish grinding on both surfaces of the semiconductor wafer at once; and a chemical treating step wherein reduction of working strain on the surfaces and an end face of the semiconductor wafer and a finish beveling of rendering the end face of the semiconductor wafer into a given beveled form are simultaneously conducted in any order.
  • 3. A method for producing a semiconductor wafer according to the item 1 or 2, wherein the semiconductor wafer is a silicon wafer having a diameter of not less than 450 mm.
  • According to the production method of the semiconductor wafer according to the invention, a fixed grain bonded abrasive grinding step and a chemical treating step are conducted between the slicing step and the double-sided polishing step, whereby the number of production steps for the semiconductor wafer is shortened as compared with the conventional method and the machining allowance of the semiconductor wafer can be reduced to reduce the kerf loss of the semiconductor material to thereby obtain the semiconductor wafer cheaply.
  • Also, the flatness of the semiconductor wafer can be improved by reducing the machining allowance of the semiconductor wafer. Furthermore, a semiconductor wafer having an epitaxial layer can be obtained by conducting an epitaxial layer growing step between the chemical treating step and the double-sided polishing step or after the double-sided polishing step. The production method of the semiconductor wafer according to the invention is especially suitable for the production of silicon wafers having a large diameter of not less than 450 mm.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The invention will be described with reference to the accompanying drawings, wherein:
  • FIG. 1 is a flow chart showing production steps according to a first embodiment of the invention;
  • FIG. 2 (a) is a schematic cross-sectional view of an apparatus used in a fixed grain bonded abrasive grinding step;
  • FIG. 2 (b) is a schematic top view of the apparatus showing a state just before the start of the fixed grain bonded abrasive grinding step;
  • FIG. 2 (c) is a schematic top view of the apparatus showing a state after a predetermined time of the fixed grain bonded abrasive grinding step;
  • FIG. 3 is a schematic cross-sectional view and a top view of an apparatus used in the conventional lapping step;
  • FIG. 4 is a flow chart showing production steps according to a second embodiment of the invention;
  • FIG. 5 is a flow chart showing production steps of Conventional Example 1; and
  • FIG. 6 is a flow chart showing production steps of Conventional Example 2.
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • FIG. 1 is a flow chart showing production steps according to a first embodiment of the invention. In the first embodiment of the invention, the following five steps (1) to (5) are conducted in this order:
  • (1) a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot;
  • (2) a fixed grain bonded abrasive grinding step wherein the semiconductor wafer is fitted into a circular hole of a carrier having a plurality of circular holes closely aligned to each other and the carrier is sandwiched between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive and then the upper and lower plates are rotated while oscillating the carrier in the same horizontal plane to simultaneously conduct a high-speed treatment from rough grinding to finish grinding on both surfaces of the semiconductor wafer at once;
  • (3) a chemical treating step of simultaneously conducting reduction of working strain on the surfaces and an end face of the semiconductor wafer and a finish beveling of making the end face of the semiconductor wafer to a given beveled form;
  • (4) a double-sided polishing step of simultaneously polishing both surfaces of the semiconductor wafer; and
  • (5) a one-side finish polishing step of finish polishing a one-side face of the double-sided polished semiconductor wafer.
  • Next, the each step in the first embodiment of the invention will be described.
  • The slicing step is a step of cutting out a thin disc-shaped wafer by contacting a wire saw with a crystalline ingot while supplying a grinding solution, or by cutting a crystalline ingot with an inner diameter blade. In order to reduce a processing load in the subsequent fixed grain bonded abrasive grinding step and chemical treating step, the semiconductor wafer after the slicing step is preferable to have a high flatness and a small surface roughness as far as possible.
  • Moreover, the crystalline ingot is typically an ingot of silicon single crystal, but may be an ingot of polycrystalline silicon for solar cells.
  • (Fixed Grain Bonded Abrasive Grinding Step)
  • The fixed grain bonded abrasive grinding step is a step of roughly grinding both surfaces of the semiconductor wafer cut in the slicing step to increase the flatness and to approximate the thickness of the semiconductor wafer to the final thickness.
  • FIG. 2 is a schematic view of a fixed grain bonded abrasive grinding apparatus 10 used in the fixed grain bonded abrasive grinding step, wherein FIG. 2 (a) is a cross-sectional view of the apparatus 10 used in the fixed grain bonded abrasive grinding step and FIGS. 2 (b) and (c) are top views of the apparatus 10 used in the fixed grain bonded abrasive grinding step, respectively. FIGS. 2 (a) and (b) show states just before the start of the fixed grain bonded abrasive grinding step, and FIG. 2 (c) view shows a state after a predetermined time of the fixed grain bonded abrasive grinding step.
  • The fixed grain bonded abrasive grinding apparatus 10 comprises a carrier 12 having a plurality of circular holes 11 a, 11 b and 11 c closely aligned to each other, pads 13 a, 13 b each having a fixed grain bonded abrasive, a pair of upper and lower plates 14 a, 14 b having the pads 13 a and 13 b, and guide rollers 15 a, 15 b, 15 c, 15 d arranged so as to contact with a side face of the carrier 12 at four divided positions of the circumference of the carrier 12.
  • The semiconductor wafers 16 a, 16 b, 16 c cut out in the slicing step are fitted into the circular holes 11 a, 11 b, 11 c of the carrier 12, and thereafter the carrier 12 is sandwiched between the pair of upper and lower plates 14 a, 14 b having the pads 13 a, 13 b with the fixed grain bonded abrasive, and then the upper and lower plates 14 a, 14 b are rotated while moving the guide rollers 15 a, 15 b, 15 c, 15 d to oscillate the carrier 12 in the same horizontal plane, whereby both surfaces of each of the wafers 16 a, 16 b, 16 c are ground simultaneously.
  • Although there are shown three circular holes 11 a, 11 b, 11 c in the FIG. 2, the number of circular holes is not limited to three. However, as shown in FIGS. 2 (b) and (c), it is important that all of the circular holes 11 a, 11 b, 11 c are disposed so as to enter into the circumferences of the upper and lower plates 14 a, 14 b even if the carrier 12 takes any positional relationship with respect to the upper and lower plates 14 a, 14 b through oscillating. This is due to the fact that a pressure applied to the semiconductor wafer during the fixed gain bonded abrasive grinding is made uniform as far as possible, whereby the occurrence of cracking or chipping in the semiconductor wafer during the fixed grain bonded abrasive grinding is prevented but also the flatness of the semiconductor wafer after the fixed grain bonded abrasive grinding is improved without beveling an outer peripheral portion of the semiconductor wafer after the slicing step. It is preferable that the circular hole 11 has the same diameter and the number thereof is 3, because as shown in FIGS. 2 (b) and (c), if the circular holes 11 a, 11 b, 11 c are aligned closely to each other, the diameter of the plates 14 can be made minimum and the size of the fixed grain bonded abrasive grinding apparatus 10 is not unnecessarily grown. When the diameter of the plate 14 is L1 in FIG. 2, L1 if three silicon wafers each having a diameter of 450 mm are ground with the fixed grain bonded abrasive is approximately 985 mm.
  • Since the pad has the fixed grain bonded abrasive, it is not required to supply a slurry of free abrasive grains during the fixed grain bonded abrasive grinding. Therefore, it is possible to avoid the deterioration of the flatness of the semiconductor wafer after the grinding due to non-uniform supply of the free abrasive grains, which is especially advantageous in a case that a diameter of the semiconductor wafer is large as in a silicon wafers having a diameter of not less than 450 mm and it is difficult to supply the free abrasive grains uniformly.
  • The material of the abrasive grains in the pad having the fixed grain bonded abrasive is generally diamond, but abrasive grains of SiC may be also used. Although the pad with the fixed grain bonded abrasive may have a roughness of #1000-8000, as previously mentioned, the pressure applied to the semiconductor wafer during the fixed grain bonded abrasive grinding is uniform and the grinding action of the abrasive grains to the semiconductor wafer is uniform owing to the use of the fixed grain bonded abrasive instead of the free abrasive grains, so that it is possible to conduct a high-speed treatment from rough grinding to finish grinding at once without occurrence of cracking or chipping even if a semiconductor wafer having a rough surface state just after the slicing step is subjected to a fixed grain bonded abrasive grinding with a fine pad of about #8000.
  • During the fixed grain bonded abrasive grinding, it is preferable to wash out ground scraps, or to supply water or an alkali solution for the purpose of lubrication.
  • Moreover, when a grinding margin at the fixed grain bonded abrasive grinding step is less than 20 μm per one-side surface, the undulation of the wafer generated in the cutting will be a problem, while when it exceeds 50 μm, the strength of the wafer becomes lacking. Therefore, the grinding margin at the fixed grain bonded abrasive grinding step is preferable to be 20-50 μm per one-side surface.
  • Now, the lapping step will be briefly described to compare the fixed grain bonded abrasive grinding step employed in the invention with the lapping step employed in the conventional method.
  • In the FIG. 3 is schematically shown an apparatus used in the lapping step employed in the conventional method. The lapping apparatus 50 comprises carriers 52 a, 52 b, 52 c, 52 d, 52 e each having a respective circular hole 51 a, 51 b, 51 c, 51 d, or 51 e and provided on its side face with a gear, pads 53 a, 53 b, a pair of upper and lower plates 54 a, 54 b having the pads 53 a, 53 b, an outer peripheral gear 55 in the sun-and-planet motion of the carriers 52 a, 52 b, 52 c, 52 d, 52 e, and a center gear 56 engaging with the gears provided on the side faces of the carriers 52 a, 52 b, 52 c, 52 d, 52 e.
  • The semiconductor wafers 57 a, 57 b, 57 c, 57 d, 57 e cut in the slicing step are fitted into the circular holes 51 a, 51 b, 51 c, 51 d, 51 e of the carriers 52 a, 52 b, 52 c, 52 d, 52 e, and thereafter the carriers 52 a, 52 b, 52 c, 52 d, 52 e are sandwiched between the pair of the upper and lower plates 54 a, 54 b having the pads 53 a, 53 b, and then the center gear 56 is rotated to conduct the sun-and-planet motion of the carriers 52 a, 52 b, 52 c, 52 d, 52 e along the outer peripheral gear 55 while supplying free abrasive grains to the wafers 57 a, 57 b, 57 c, 57 d, 57 e, to thereby lap the wafers 57 a, 57 b, 57 c, 57 d, 57 e.
  • In the lapping apparatus 50, the area occupied by the center gear 56 is large and the area of the plate 54 becomes large accompanied therewith, and hence the whole size of the lapping apparatus 50 tends to be grown. In the lapping of the large-diameter semiconductor wafers, the sizes of the carriers 52 a, 52 b, 52 c, 52 d, 52 e are grown and hence the force required for the sun-and-planet motion of the carriers 52 a, 52 b, 52 c, 52 d, 52 e becomes large to grow the size of the center gear 56, and as a result, the size of the lapping apparatus 50 becomes more larger, which is a serious problem. In FIG. 3, when the diameter of the plate 54 is L2, if three semiconductor wafers of 450 mm in diameter are lapped, L2 is about 2200 mm, which is much larger than LI in the fixed grain bonded abrasive grinding apparatus 10. Thus, when silicon wafers having a diameter of not less than 450 mm are produced by a method including the lapping step, it is required to use a very large lapping apparatus, which may cause a problem in the installation site and the like.
  • Also, in the lapping step, the size of the guide becomes larger since the lapping is conducted while supplying free abrasive grains. As a result, the supply area of free abrasive grains becomes wider, and it is difficult to supply them uniformly, which may easily deteriorate the flatness of the semiconductor wafer after the lapping step but also may cause the cracking or chipping in the lapping.
  • (Chemical Treating Step)
  • The chemical treating step simultaneously conducts reduction of working strain on the surfaces and end face of the semiconductor wafer applied at the slicing step or both the slicing step and the fixed grain bonded abrasive grinding step, and a finish beveling of making the end face of the semiconductor wafer to a given beveled form, which may be either a batch type or a sheet-feed type chemical treatment.
  • The batch type chemical treatment is a treatment of immersing a plurality of semiconductor wafers (e.g. 24 wafers) into a vessel containing a given etching solution to simultaneously conduct the reduction of working strain on both surfaces and end faces of the semiconductor wafer and the finish beveling of making the end face of the semiconductor wafer to a given beveled form.
  • The sheet-feed type chemical treating step is a treatment that one semiconductor wafer is rotated while adding dropwise an etching solution to a one-side face of the semiconductor wafer, whereby the etching solution is extended over the both surfaces and end faces of the semiconductor wafer through centrifugal force to reduce working strain on both the surfaces and end faces of the semiconductor wafer, and at the same time the end face of the semiconductor wafer is subjected to a finish beveling to a given beveled form. The sheet-feed type chemical treatment is conducted twice so that both surfaces are etched by subjecting each one-side face thereto. On the end face, conditions of etching are set for making a given form by two etchings.
  • As the etching solution used in the sheet-feed type chemical treatment, it is preferable to use a mixed acids of hydrofluoric acid, nitric acid and phosphoric acid, because it is required that when the etching solution is added dropwise to the rotating semiconductor wafer, it is extended over the surface of the semiconductor wafer to be etched at a proper rate to form a uniform film of the etching solution on this surface. A mixed acid of hydrofluoric acid, nitric acid and acetic acid usually used as the etching solution in the batch type chemical treatment is not preferable because it is low in the viscosity and when it is added dropwise to the rotating semiconductor wafer, a rate of extending over the surface to be etched is too fast and the film of the etching solution is not formed, resulting in irregular etching.
  • Moreover, the mixed acid of hydrofluoric acid, nitric acid and phosphoric acid used as the etching solution in the sheet-feed type chemical treatment is preferable to comprise 5-20 mass % of hydrofluoric acid, 5-40 mass % of nitric acid, 30-40 mass % of phosphoric acid.
  • (Double-sided Polishing Step)
  • In the double-side polishing step, both surfaces of the semiconductor wafer subjected to the fixed grain bonded abrasive grinding step and the chemical treating step are polished with an abrasive cloth made of urethane and the like while supplying an abrasive slurry. The kind of the abrasive slurry is not particularly limited, but colloidal silica having a particle size of 0.5 to 2 μm is preferable.
  • (One-side Finish Polishing Step)
  • In the one-side finish polishing step, a one-side face of the double-sided polished semiconductor wafer as a device surface is polished with an abrasive cloth made of urethane or the like while supplying an abrasive slurry. The kind of the abrasive slurry is not particularly limited, but colloidal silica having a particle size of not more than 0.5 μm is preferable.
  • Next, the second embodiment according to the invention will be described. FIG. 4 is a flow chart showing production steps of the second embodiment according to the invention. It should be noted that the same steps as in FIG. 1 are named the same in FIG. 4
  • Here, the second embodiment shown in FIG. 4 is common to the first embodiment shown in FIG. 1 in a point that the fixed grain bonded abrasive grinding step and the chemical treating step are conducted between the slicing step and the double-sided grinding step, but the order of conducting the fixed grain bonded abrasive grinding step and the chemical treating step differs between both the embodiments.
  • As mentioned in the explanation of the chemical treating step, the chemical treating step has an action of finish-beveling the end face of the semiconductor wafer to a given beveled form. Therefore, it is advantageous that only the double-sided polishing step and the one-side finish polishing step are conducted after the chemical treating step in view of a point that the grinding step showing a large reduction amount of the thickness of the semiconductor wafer is avoided to suppress a variation of a beveled width in the semiconductor wafer.
  • That is, the first embodiment according to the invention shown in FIG. 1, i.e., the order of the fixed grain bonded abrasive grinding step the chemical treating step is preferable.
  • Even when the semiconductor wafer is produced by the order of the chemical treating step the fixed grain bonded abrasive grinding step in the second embodiment according to the invention shown in FIG. 2, the effects on the reduction of the production step number and the reduction of the kerf loss in the semiconductor wafer similar to those of the first embodiment are advantageously obtained as compared with the conventional method though the variation of the beveled width in the semiconductor wafer becomes somewhat big to retain working strain caused at the fixed grain bonded abrasive grinding step. Therefore, when the variation of the beveled width and the residual working strain in the semiconductor wafer are included in a quality standard required for the semiconductor wafer, the second embodiment according to the invention is an effective means for reducing the production cost of the semiconductor wafer. In addition, if it is emphasized to mitigate the working strain on the end face of the wafer, a finish beveling step may be conducted after the fixed grain bonded abrasive grinding step.
  • Although the above is described with respect to the main steps in the production method according to the invention, a polishing step of beveled portion and/or an epitaxial layer growing step may be included, if desired. The polishing step of beveled portion and the epitaxial layer growing step will be described below.
  • (Polishing Step of Beveled Portion)
  • The polishing step of the beveled portion is conducted after the double-sided polishing step for polishing the beveled portion of the semiconductor wafer to reduce a variation of the beveled width in the wafer. In this case, the beveled portion is polished with an abrasive cloth made of urethane or the like while supplying an abrasive slurry. The kind of the abrasive slurry is not particularly limited, but colloidal silica having a particle size of about 0.5 μm is preferable.
  • (Epitaxial Layer Growing Step)
  • A semiconductor wafer having an epitaxial layer can be obtained by conducting an epitaxial layer growing step between the chemical treating step and the double-sided polishing step or after the double-sided polishing step. When the epitaxial layer is grown on the surface of the semiconductor wafer, it is required to remove surface damage of the semiconductor wafer applied at the slicing step and optionally at the fixed grain bonded abrasive grinding step, so that the epitaxial layer growing step is preferable to be conducted between the chemical treating step and the double-sided polishing step, or after the double-sided polishing step.
  • Although the above is merely described with respect to one embodiment of the invention, various modifications may be made without departing from the scope of the appended claims.
  • A semiconductor wafer is prepared by the production method according to the invention as stated below.
  • INVENTION EXAMPLE 1
  • A silicon wafer having a diameter of 300 mm is prepared according to a flow chart of FIG. 1 in the first embodiment according to the invention.
  • INVENTION EXAMPLE 2
  • A silicon wafer having a diameter of 450 mm is prepared in the same production method as in Invention Example 1.
  • INVENTION EXAMPLE 3
  • A silicon wafer having a diameter of 300 mm is prepared according to a flow chart of FIG. 4 in the second embodiment according to the invention.
  • INVENTION EXAMPLE 4
  • A silicon wafer having a diameter of 450 mm is prepared in the same production method as in Invention Example 3.
  • CONVENTIONAL EXAMPLE 1
  • A silicon wafer having a diameter of 300 mm is prepared by the conventional production method shown in FIG. 5 inclusive of a lapping step.
  • CONVENTIONAL EXAMPLE 2
  • A silicon wafer having a diameter of 300 mm is prepared by a production method shown in FIG. 6 using a double-sided polishing step instead of the lapping step.
  • With respect to each of the thus obtained samples are evaluated the silicon kerf loss and flatness. The evaluation method will be described below.
  • (Silicon Kerf Loss)
  • The silicon kerf loss is evaluated by a reduction quantity (μm) of a thickness in the semiconductor wafer before and after the fixed grain bonded abrasive grinding step in Invention Examples 1 to 4, the sum of a reduction quantity (μm) of a thickness in the semiconductor wafer before and after the lapping step and a reduction quantity (μm) of a thickness in the semiconductor wafer before and after the one-side grinding step in Conventional Example 1, and the sum of a reduction quantity (μm) of a thickness in the semiconductor wafer before and after the double-sided grinding step and a reduction quantity (μm) of a thickness in the semiconductor wafer before and after the one-side grinding step in Conventional Example 2, respectively.
  • (Flatness)
  • The flatness of each sample is measured with a capacitance type thickness sensing meter and is evaluated as follows:
  • ◯: The flatness is less than 0.5 μm.
  • Δ: The flatness is not less than 0.5 μm and not more than 1 μm.
  • X: The flatness is more than 1 μm.
  • The evaluation results of the each sample are shown in Table 1.
  • TABLE 1
    Invention Invention Invention Invention Conventional Conventional
    Example 1 Example 2 Example 3 Example 4 Example 1 Example 2
    Flow chart FIG. 1 FIG. 1 FIG. 4 FIG. 4 FIG. 5 FIG. 6
    Diameter (mm) 300 450 300 450 300 300
    Silicon kerf loss 40 60 40 60 100 105
    (ground thickness: (μm))
    Flatness Δ Δ
  • As seen from Table 1, Invention Example 1 shows a minimum value of the silicon kerf loss and a good flatness, and Invention Example 2 shows good results substantially equal to those in Invention Example 1, from which it has been confirmed that a silicon wafer having a large diameter of 450 mm is obtained by the production method according to the first embodiment of the invention. Moreover, good results substantially equal to those in Invention Examples 1 and 2 on the silicon kerf loss and the flatness are obtained in Examples 3 and 4 by the production method according to the second embodiment of the invention. On the other hand, Conventional Examples 1 and 2 show a large silicon kerf loss and a poor flatness as compared with Invention Examples 1 to 4.
  • According to the production method of the semiconductor wafer according to the invention, the fixed grain bonded abrasive grinding step and the chemical treating step are conducted between the slicing step and the double-sided polishing step, whereby the number of production steps for the semiconductor wafer is shortened as compared with the conventional method and the machining allowance of the semiconductor wafer can be reduced to reduce the kerf loss of the semiconductor material to thereby obtain the semiconductor wafer cheaply. Also, the flatness of the semiconductor wafer can be improved by reducing the machining allowance of the semiconductor wafer. Furthermore, a semiconductor wafer having an epitaxial layer can be obtained by conducting an epitaxial layer growing step between the chemical treating step and the double-sided polishing step, or after the double-sided polishing step. The production method of the semiconductor wafer according to the invention is especially suitable for the production of silicon wafers having a large diameter of not less than 450 mm.

Claims (3)

1. A method for producing a semiconductor wafer, comprising a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot; and a fixed grain bonded abrasive grinding step of sandwiching the semiconductor wafer between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive to simultaneously grind both surfaces of the semiconductor wafer.
2. A method for producing a semiconductor wafer, comprising a slicing step of cutting out a thin disc-shaped semiconductor wafer from a crystalline ingot; a double-sided polishing step of simultaneously polishing both surfaces of the semiconductor wafer; and a one-side finish polishing step being subjected to a one-side face of the semiconductor wafer polished at the double-sided polishing step, which further comprises between the slicing step and the double-sided polishing step a fixed grain bonded abrasive grinding step wherein the semiconductor wafer is fitted into a circular hole of a carrier having a plurality of circular holes closely aligned to each other and the carrier is sandwiched between a pair of upper and lower plates each having a pad of fixed grain bonded abrasive and then the upper and lower plates are rotated while oscillating the carrier in the same horizontal plane to simultaneously conduct a high-speed treatment from rough grinding to finish grinding on both surfaces of the semiconductor wafer at once; and a chemical treating step wherein reduction of working strain on the surfaces and an end face of the semiconductor wafer and a finish beveling of rendering the end face of the semiconductor wafer into a given beveled form are simultaneously conducted in any order.
3. A method for producing a semiconductor wafer according to claim 1 or 2, wherein the semiconductor wafer is a silicon wafer having a diameter of not less than 450 mm.
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